At zero temperature, based on the Ising model, the phase transition in a two-dimensional square lattice is studied using the generalized zero-temperature Glauber dynamics. Using Monte Carlo （MC） renormalization grou...At zero temperature, based on the Ising model, the phase transition in a two-dimensional square lattice is studied using the generalized zero-temperature Glauber dynamics. Using Monte Carlo （MC） renormalization group methods, the static critical exponents and the dynamic exponent are studied; the type of phase transition is found to be of the first order.展开更多
Increasing the utilization efficiency of platinum is critical for advancing proton exchange-membrane fuel cells(PEMFCs).Despite extensive research on catalysts for the cathodic oxygen reduction reaction(ORR),developin...Increasing the utilization efficiency of platinum is critical for advancing proton exchange-membrane fuel cells(PEMFCs).Despite extensive research on catalysts for the cathodic oxygen reduction reaction(ORR),developing highly active and durable Pt-based catalysts that can suppress surface dealloying in corrosive acid conditions remains challenging.Herein,we report a facile synthesis of bimetallic ultrathin PtM(M=Mo,W,and Cr)nanowires(NWs)composed of group VI B transition metal atomic sites anchored on the surface.These NWs possess uniform sizes and well-controlled atomic arrangements.Compared to PtW and PtCr catalysts,the PtMo0.05 NWs exhibit the highest half-wave potential of 0.935 V and a mass activity of 1.43 A·mgPt^(−1).Remarkably,they demonstrate a remarkable 23.8-fold enhancement in mass activity compared to commercial Pt/C for ORR,surpassing previously reported Pt-based catalysts.Additionally,the PtMo NWs cathode in membrane electrode assembly tests achieves a remarkable peak power density of 1.443 W·cm^(−2)(H_(2)-O_(2)conditions at 80℃),which is 1.09 times that of commercial Pt/C.The ligand effect in the bimetallic surface not only facilitates strong coupling between Mo(4d)and Pt(5d)atomic orbitals to hinder atom leaching but also modulates the d-states of active site,significantly optimizing the adsorption of key oxygen(*O and*OH)species and accelerating the rate-determining step in ORR pathways.展开更多
As one of the primary business centers of China, Guangzhou has been undergoing rapid growth and expansion. Over the past decade, the Guangzhou Municipality Government has significantly upgraded its transport infrastru...As one of the primary business centers of China, Guangzhou has been undergoing rapid growth and expansion. Over the past decade, the Guangzhou Municipality Government has significantly upgraded its transport infrastructure, especially with the highly beneficial expansion of its Subway Mass Rapid Transit(MRT) system.Positive steps have also been taken to continue planning the construction of new roads, a Bus Rapid Transit(BRT)system and other transportation facilities. Further administrative and regulatory measures have also been implemented to control the situation, such as the banning of motorcycles from the central city area and the limitation of new automobile registrations. However, Guangzhou continues to face serious challenges of traffic congestion in and around the city center owing to further intensification of its population with economic growth. The need to ease Guangzhou's stretched public transportation resources,and at the same time to support the realization of its"Eastward Advance" strategy, presents a unique challenge and opportunity to develop an advanced high-efficiency public transportation modality for Guangzhou, viz. the Group Rapid Transit(GRT) involving the use of automation-guided(driverless) smart-vehicles. This paper outlines the PRT/GRT(PRT: Personal Rapid Transit) smart-vehicle modality and also puts forth a proposal of Guangzhou's first GRT route as the city's first dedicated transportation link to the scenic landscape of the Eastern Tourism Zone.This GRT route will help in diffusing the city's traffic congestion as well as support the effectuation of Guangzhou's "Eastern Expansion" strategy, supplementing the ongoing expansion of the Guangzhou Municipality's subway MRT networks.展开更多
We show that a doped spin-1/2 ladder with antiferromagnetic intra-chain and ferromagnetic inter-chain coupling is a symmetry protected topologically non-trivial Luttinger liquid.Turning on a large easy-plane spin anis...We show that a doped spin-1/2 ladder with antiferromagnetic intra-chain and ferromagnetic inter-chain coupling is a symmetry protected topologically non-trivial Luttinger liquid.Turning on a large easy-plane spin anisotropy drives the system to a topologically-trivial Luttinger liquid.Both phases have full spin gaps and exhibit power-law superconducting pair correlation.The Cooper pair symmetry is singlet dxy in the non-trivial phase and triplet Sz? 0 in the trivial phase.The topologically non-trivial Luttinger liquid exhibits gapless spin excitations in the presence of a boundary,and it has no non-interacting or mean-field theory analog even when the fluctuating phase in the charge sector is pinned.As a function of the strength of spin anisotropy there is a topological phase transition upon which the spin gap closes.We speculate these Luttinger liquids are relevant to the superconductivity in metalized integer spin ladders or chains.展开更多
文摘At zero temperature, based on the Ising model, the phase transition in a two-dimensional square lattice is studied using the generalized zero-temperature Glauber dynamics. Using Monte Carlo （MC） renormalization group methods, the static critical exponents and the dynamic exponent are studied; the type of phase transition is found to be of the first order.
基金the National Natural Science Foundation of China(No.22275009)SINOPEC(contact No.421028)Fundamental Research Funds for the Central Universities(No.XK2020-02).
文摘Increasing the utilization efficiency of platinum is critical for advancing proton exchange-membrane fuel cells(PEMFCs).Despite extensive research on catalysts for the cathodic oxygen reduction reaction(ORR),developing highly active and durable Pt-based catalysts that can suppress surface dealloying in corrosive acid conditions remains challenging.Herein,we report a facile synthesis of bimetallic ultrathin PtM(M=Mo,W,and Cr)nanowires(NWs)composed of group VI B transition metal atomic sites anchored on the surface.These NWs possess uniform sizes and well-controlled atomic arrangements.Compared to PtW and PtCr catalysts,the PtMo0.05 NWs exhibit the highest half-wave potential of 0.935 V and a mass activity of 1.43 A·mgPt^(−1).Remarkably,they demonstrate a remarkable 23.8-fold enhancement in mass activity compared to commercial Pt/C for ORR,surpassing previously reported Pt-based catalysts.Additionally,the PtMo NWs cathode in membrane electrode assembly tests achieves a remarkable peak power density of 1.443 W·cm^(−2)(H_(2)-O_(2)conditions at 80℃),which is 1.09 times that of commercial Pt/C.The ligand effect in the bimetallic surface not only facilitates strong coupling between Mo(4d)and Pt(5d)atomic orbitals to hinder atom leaching but also modulates the d-states of active site,significantly optimizing the adsorption of key oxygen(*O and*OH)species and accelerating the rate-determining step in ORR pathways.
文摘As one of the primary business centers of China, Guangzhou has been undergoing rapid growth and expansion. Over the past decade, the Guangzhou Municipality Government has significantly upgraded its transport infrastructure, especially with the highly beneficial expansion of its Subway Mass Rapid Transit(MRT) system.Positive steps have also been taken to continue planning the construction of new roads, a Bus Rapid Transit(BRT)system and other transportation facilities. Further administrative and regulatory measures have also been implemented to control the situation, such as the banning of motorcycles from the central city area and the limitation of new automobile registrations. However, Guangzhou continues to face serious challenges of traffic congestion in and around the city center owing to further intensification of its population with economic growth. The need to ease Guangzhou's stretched public transportation resources,and at the same time to support the realization of its"Eastward Advance" strategy, presents a unique challenge and opportunity to develop an advanced high-efficiency public transportation modality for Guangzhou, viz. the Group Rapid Transit(GRT) involving the use of automation-guided(driverless) smart-vehicles. This paper outlines the PRT/GRT(PRT: Personal Rapid Transit) smart-vehicle modality and also puts forth a proposal of Guangzhou's first GRT route as the city's first dedicated transportation link to the scenic landscape of the Eastern Tourism Zone.This GRT route will help in diffusing the city's traffic congestion as well as support the effectuation of Guangzhou's "Eastern Expansion" strategy, supplementing the ongoing expansion of the Guangzhou Municipality's subway MRT networks.
基金supported by the U.S.Department of Energy,Office of Science,Office of Advanced Scientific Computing Research,Scientific Discovery through Advanced Computing(SciDAC)program
文摘We show that a doped spin-1/2 ladder with antiferromagnetic intra-chain and ferromagnetic inter-chain coupling is a symmetry protected topologically non-trivial Luttinger liquid.Turning on a large easy-plane spin anisotropy drives the system to a topologically-trivial Luttinger liquid.Both phases have full spin gaps and exhibit power-law superconducting pair correlation.The Cooper pair symmetry is singlet dxy in the non-trivial phase and triplet Sz? 0 in the trivial phase.The topologically non-trivial Luttinger liquid exhibits gapless spin excitations in the presence of a boundary,and it has no non-interacting or mean-field theory analog even when the fluctuating phase in the charge sector is pinned.As a function of the strength of spin anisotropy there is a topological phase transition upon which the spin gap closes.We speculate these Luttinger liquids are relevant to the superconductivity in metalized integer spin ladders or chains.
