Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of va...Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of vanadium species on conventional carbon electrodes remains a major limitation to their performance.We investigated the deposition of carbon black,carbon nanotubes,and electrochemically exfoliated graphene(Exf-Gr)onto thermally-activated carbon paper(ACP)by spray coating to increase the electrode electrocatalytic activity.The modified electrodes were characterized using scanning electron microscopy,X-ray diffraction,Raman spectroscopy,X-ray photoelectron microscopy,and surface area analysis,while their electrochemical properties were evaluated by cyclic voltammetry,electrochemical impedance spectroscopy,and singlecell VRFB testing.Among the modified electrodes,Exf-Gr/ACP had the best performance,achieving a 2.9-fold reduction in charge transfer resistance compared to pristine ACP and delivering 2.5 times the discharge capacity in single-cell tests.This improvement is attributed to Exf-Gr’s high surface area,favorable catalytic activity,and excellent dispersion on the ACP substrate.Surface modification with electrochemically exfoliated graphene is a highly effective strategy for improving the electrode performance in VRFB systems,with significant implications for large-scale energy storage.展开更多
The development of shape-customizable and bulk flexible electrochemical devices through processing technologies as versatile as those used for plastics promises to revolutionize the future of battery technology.Howeve...The development of shape-customizable and bulk flexible electrochemical devices through processing technologies as versatile as those used for plastics promises to revolutionize the future of battery technology.However,this pursuit has been fundamentally hindered by the absence of transformative battery materials capable of delivering the necessary electrochemical functions,robust interface adhesion,and,crucially,the suitable rheological properties required for on-demand shaping.In this work,we introduce a concept of a multifunctional plasticine electrode matrix(PEM)featuring nano-interpenetrating networks(nano-IPN)to address this challenge.Utilizing the nonflammable liquid-electrolyte hydration combined with conductive nanomaterials,we have realized a PEM in the form of a multifunctional nanocomposite that integrates ion and electron conduction,component binding,non-flammability,and plasticine-like moldability.With this PEM,we have successfully fabricated a variety of bulk-flexible electrodes with high mass loading of active material(AM)(>70 wt%)using industry-friendly extrusion and compression molding techniques.Moreover,these high AM-loading composite electrodes achieve an unparalleled bulk conformability and flexibility,remaining structurally intact even under severe mechanical stress.Ultimately,we have successfully produced shape-patternable and flexible batteries via extrusion molding.This study underscores the potential of the PEM to revolutionize battery microstructures,interfaces,manufacturing processes,and performance characteristics.展开更多
Thermocells are garnering increasing attention as a promising thermoelectric technology for harvesting low-grade heat.However,their performance is often limited by the scarcity of high-performance redox couples that p...Thermocells are garnering increasing attention as a promising thermoelectric technology for harvesting low-grade heat.However,their performance is often limited by the scarcity of high-performance redox couples that possess both high thermopower and rapid redox kinetics.This work addresses this challenge by leveraging our recently developed copper(Ⅰ/Ⅱ)(Cu^(+)/Cu^(2+))redox couple.We significantly enhance the performance of Cu-based liquid thermocells by integrating a thermosensitive crystallization process with etched carbon cloth electrodes,achieving synergistic improvements in thermodynamic and kinetic performance.The thermosensitive crystallization process establishes a persistent Cu^(2+)concentration gradient,boosting the thermopower from 1.47 to 2.93 mV K^(-1).Moreover,the etched carbon cloth electrodes provide a larger electroactive surface area and demonstrate a higher current density.Consequently,the optimized Cu^(+)/Cu^(2+)system achieved an exceptional normalized power density P_(max)(ΔT)^(-2)of 3.97 mW m^(-2)K^(-2).A thermocell module comprised of 20 cells directly power various electronic devices at a temperature difference of 40 K.This work successfully exhibits potential of Cu^(+)/Cu^(2+)redox couple in thermoelectric conversion and introduces a valuable redox couple for highperformance thermocells.展开更多
To enhance the electrochemical performance of lithium-ion battery anodes with higher silicon content,it is essential to engineer their microstructure for better lithium-ion transport and mitigated volume change as wel...To enhance the electrochemical performance of lithium-ion battery anodes with higher silicon content,it is essential to engineer their microstructure for better lithium-ion transport and mitigated volume change as well.Herein,we suggest an effective approach to control the micropore structure of silicon oxide(SiO_(x))/artificial graphite(AG)composite electrodes using a perforated current collector.The electrode features a unique pore structure,where alternating high-porosity domains and low-porosity domains markedly reduce overall electrode resistance,leading to a 20%improvement in rate capability at a 5C-rate discharge condition.Using microstructure-resolved modeling and simulations,we demonstrate that the patterned micropore structure enhances lithium-ion transport,mitigating the electrolyte concentration gradient of lithium-ion.Additionally,perforating current collector with a chemical etching process increases the number of hydrogen bonding sites and enlarges the interface with the SiO_(x)/AG composite electrode,significantly improving adhesion strength.This,in turn,suppresses mechanical degradation and leads to a 50%higher capacity retention.Thus,regularly arranged micropore structure enabled by the perforated current collector successfully improves both rate capability and cycle life in SiO_(x)/AG composite electrodes,providing valuable insights into electrode engineering.展开更多
Ceramic cells promise ideal energy conversion and storage devices,making the development of efficient and robust air electrodes crucial for their application.In this study,a Ba_(0.4)Sr_(0.5)Cs_(0.1)Co_(0.7)Fe_(0.2)Nb_...Ceramic cells promise ideal energy conversion and storage devices,making the development of efficient and robust air electrodes crucial for their application.In this study,a Ba_(0.4)Sr_(0.5)Cs_(0.1)Co_(0.7)Fe_(0.2)Nb_(0.1)O_(3−δ)(BSCCFN)air electrode,based on Ba_(0.5)Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3−δ)(BSCF),is designed using a perovskite A-B-site ionic Lewis acid strength(ISA)polarization distribution strategy and is successfully applied in both oxygen-ion conducting solid oxide fuel cells(O-SOFCs)and proton-conducting reversible protonic ceramic cells(R-PCCs).When BSCCFN is used as the air electrode in O-SOFCs,a peak power density(PPD)of 1.45 W cm^(−2)is achieved at 650°C,whereas in R-PCCs,a PPD of 1.13 W cm^(−2)and a current density of−1.8 A cm^(−2)at 1.3 V are achieved at the same temperature and show stable reversibility over 100 h.Experimental measurements and theoretical calculations demonstrate that low-ISA Cs+doping accelerates the reaction kinetics of both oxygen ions and protons,while high-ISA Nb^(5+)doping enhances electrode stability.The synergistic effect of Cs^(+)and Nb^(5+)co-doping in the BSCCFN electrode lies in the ISA polarization distribution,which weakens the Co/Fe–O bond covalency,thereby promoting oxygen vacancy formation and facilitating the conduction of oxygen ions and protons.展开更多
Economical,stable,and corrosion-resistant catalytic electrodes are still urgently needed for the oxygen evolution reaction(OER)in water and seawater.Herein,a mild electroless plating strategy is used to achieve large-...Economical,stable,and corrosion-resistant catalytic electrodes are still urgently needed for the oxygen evolution reaction(OER)in water and seawater.Herein,a mild electroless plating strategy is used to achieve large-scale preparation of the“integrated”phosphorus-based precatalyst(FeP-NiP)on nickel foam(NF),which is in situ reconstructed into a highly active and corrosion-resistant(Fe)NiOOH phase for OER.The interaction between phosphate anions(PO_(x)^(y-))and iron ions(Fe^(3+))tunes the electronic structure of the catalytic phase to further enhance OER kinetics.The integrated FeP-NiP@NF electrode exhibits low overpotentials for OER in alkaline water/seawater,requiring only 275/289,320/336,and 349/358 mV to reach 0.1,0.5,and 1.0 A cm^(−2),respectively.The in situ reconstructed PO_(x)^(y-)anion electrostatically repels Cl−in seawater electrolytes,allowing stable operation for over 7 days at 1.0 A cm^(−2) in extreme electrolytes(1.0 M KOH+seawater and 6.0 M KOH+seawater),demonstrating industrial-level stability.This study overcomes the complex synthesis limitations of P-based materials through innovative material design,opening new avenues for electrochemical energy conversion.展开更多
High-entropy materials represent a new category of high-performance materials,first proposed in 2004 and extensively investigated by researchers over the past two decades.The definition of high-entropy materials has c...High-entropy materials represent a new category of high-performance materials,first proposed in 2004 and extensively investigated by researchers over the past two decades.The definition of high-entropy materials has continuously evolved.In the last ten years,the discovery of an increasing number of high-entropy materials has led to significant advancements in their utilization in energy storage,electrocatalysis,and related domains,accompanied by a rise in techniques for fabricating high-entropy electrode materials.Recently,the research emphasis has shifted from solely improving the performance of high-entropy materials toward exploring their reaction mechanisms and adopting cleaner preparation approaches.However,the current definition of high-entropy materials remains relatively vague,and the preparation method of high-entropy materials is based on the preparation method of single metal/low-or medium-entropy materials.It should be noted that not all methods applicable to single metal/low-or medium-entropy materials can be directly applied to high-entropy materials.In this review,the definition and development of high-entropy materials are briefly reviewed.Subsequently,the classification of high-entropy electrode materials is presented,followed by a discussion of their applications in energy storage and catalysis from the perspective of synthesis methods.Finally,an evaluation of the advantages and disadvantages of various synthesis methods in the production process of different high-entropy materials is provided,along with a proposal for potential future development directions for high-entropy materials.展开更多
Solid oxide cells(SOCs)are emerging devices for efficient energy storage and conversion.However,during SOC operation,gaseous chromium(Cr)species released from Fe-Cr alloy interconnect can lead to Cr deposition and poi...Solid oxide cells(SOCs)are emerging devices for efficient energy storage and conversion.However,during SOC operation,gaseous chromium(Cr)species released from Fe-Cr alloy interconnect can lead to Cr deposition and poisoning of air electrodes,causing substantial degradation in electrochemical performance and compromising the longterm stability of SOCs.This mini-review examines the mechanism of Cr deposition and poisoning in air electrodes under both fuel-cell and electrolysis modes.Furthermore,emphasis is placed on the recent advancements in strategies to mitigate Cr poisoning,offering insights into the rational design and development of active and Cr-tolerant air electrodes for SOCs.展开更多
Reversible solid oxide cell(RSOC)is a new energy conversion device with significant applications,especially for power grid peaking shaving.However,the reversible conversion process of power generation/energy storage p...Reversible solid oxide cell(RSOC)is a new energy conversion device with significant applications,especially for power grid peaking shaving.However,the reversible conversion process of power generation/energy storage poses challenges for the performance and stability of air electrodes.In this work,a novel high-entropy perovskite oxide La_(0.2)Pr_(0.2)Gd_(0.2)Sm_(0.2)Sr_(0.2)Co_(0.8)Fe_(0.2)O_(3−δ)(HE-LSCF)is proposed and investigated as an air electrode in RSOC.The electrochemical behavior of HE-LSCF was studied as an air electrode in both fuel cell and electrolysis modes.The polarization impedance(Rp)of the HE-LSCF electrode is only 0.25Ω·cm^(2) at 800℃ in an air atmosphere.Notably,at an electrolytic voltage of 2 V and a temperature of 800℃,the current density reaches up to 1.68 A/cm^(2).The HE-LSCF air electrode exhibited excellent reversibility and stability,and its electrochemical performance remains stable after 100 h of reversible operation.With these advantages,HE-LSCF is shown to be an excellent air electrode for RSOC.展开更多
In a pulsed plasma thruster,the voltage distribution between the electrodes is a key factor that influences the ionization process.However,few researchers have conducted in-depth studies of this phenomenon in the past...In a pulsed plasma thruster,the voltage distribution between the electrodes is a key factor that influences the ionization process.However,few researchers have conducted in-depth studies of this phenomenon in the past.Reported here are measurements of the voltage distribution between the plates of a parallel-plate pulsed plasma thruster under different discharge voltages,based on which the variations in the total circuit inductance and resistance as well as those between the plates are calculated.The results show that the time-averaged voltage across the plates accounts for 28.7%-50.4%of the capacitor voltage.As the capacitor initial voltage increases from 1250 V to 2000 V,the voltage across the plates rises,but its proportion relative to the capacitor voltage decreases.For every 250 V increase in the capacitor initial voltage,the average voltage proportion across the plates decreases by approximately 2%-3%.Additionally,the voltage proportion decreases gradually from the end near the propellant outward.The voltage distribution ratio between the plates is correlated with the proportions of the resistance and inductance between the plates relative to the total circuit.展开更多
This paper describes severe plastic deformation(SPD)procedures,which are utilized to form an ultrafine-grained structure in metallic biomaterials.During the SPD process,a solid material sample is subjected to very hig...This paper describes severe plastic deformation(SPD)procedures,which are utilized to form an ultrafine-grained structure in metallic biomaterials.During the SPD process,a solid material sample is subjected to very high loads without a significant change in sample dimensions.In the present work,the high-pressure torsion(HPT)process,as one of the SPD techniques,which achieves a high degree of deformation and ensures refinement of the microstructure,will be discussed in more detail.Considering that grain size control is accepted as a method to obtain materials with desired characteristics,an overview of the properties of ultrafine-grained titanium-based biomaterials to be used in medicine is given.Moreover,particular attention is dedicated to the influences of HPT process parameters,primarily hydrostatic pressure,and number of revolutions during torsion,on the grain size and physical and mechanical characteristics(modulus of elasticity,microhardness,and tensile properties),corrosion resistance,and biocompatibility of the titanium-based biomaterials.A review of the literature indicates that titanium-based materials obtained by the SPD process show improved mechanical and physical properties without losing biocompatibility and corrosion resistance,which suggests that these methods of obtaining implants are something that should be further developed in the future.展开更多
Membrane electrode assembly(MEA)is widely considered to be the most promising type of electrolyzer for the practical application of electrochemical CO_(2) reduction reaction(CO_(2)RR).In MEAs,a square-shaped cross-sec...Membrane electrode assembly(MEA)is widely considered to be the most promising type of electrolyzer for the practical application of electrochemical CO_(2) reduction reaction(CO_(2)RR).In MEAs,a square-shaped cross-section in the flow channel is normally adopted,the configuration optimization of which could potentially enhance the performance of the electrolyzer.This paper describes the numerical simulation study on the impact of the flow-channel cross-section shapes in the MEA electrolyzer for CO_(2)RR.The results show that wide flow channels with low heights are beneficial to the CO_(2)RR by providing a uniform flow field of CO_(2),especially at high current densities.Moreover,the larger the electrolyzer,the more significant the effect is.This study provides a theoretical basis for the design of high-performance MEA electrolyzers for CO_(2)RR.展开更多
Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS)is a highly successful conductive polymer utilized as an electrode material in energy storage units for portable and wearable electronic de-vices.Neve...Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS)is a highly successful conductive polymer utilized as an electrode material in energy storage units for portable and wearable electronic de-vices.Nevertheless,employing PEDOT:PSS in supercapacitors(SC)in its pristine state presents challenges due to its suboptimal electrochemical performance and operational instability.To surmount these limita-tions,PEDOT:PSS has been integrated with carbon-based materials to form flexible electrodes,which ex-hibit physical and chemical stability during SC operation.We developed a streamlined fabrication process for high-performance SC electrodes composed of PEDOT:PSS and carbon quantum dots(CQDs).The CQDs were synthesized under microwave irradiation,yielding green-and red-light emissions.Through optimiz-ing the ratios of CQDs to PEDOT:PSS,the SC electrodes were prepared using a spray-coating technique,marking a significant improvement in device performance with a high volumetric capacitance(104.10 F cm-3),impressive energy density(19.68 Wh cm^(-3)),and excellent cyclic stability,retaining~85% of its original volumetric capacitance after 15,000 repeated GCD cycles.Moreover,the SCs,when utilized as a flexible substrate,demonstrated the ability to maintain up to~85% of their electrochemical performance even after 3,000 bending cycles(at a bending angle of 60°).These attributes render this hybrid composite an ideal candidate for a lightweight smart energy storage component in portable and wearable electronic technologies.展开更多
Improvements in aero-engine performance have made the structures of the aero-engine components increasingly complex.To better adapt to the processing requirements of narrow twisted channels such as an integral shroude...Improvements in aero-engine performance have made the structures of the aero-engine components increasingly complex.To better adapt to the processing requirements of narrow twisted channels such as an integral shrouded blisk,this study proposes an innovative method of electrochemical cutting in which a flexible tube electrode is controlled by online deformation during processing.In this study,the processing principle of electrochemical cutting with a flexible electrode for controlled online deformation(FECC)was revealed for the first time.The online deformation process of flexible electrodes and the machining process of profiles were analysed in depth,and the corresponding theoretical models were established.Conventional electrochemical machining(ECM)is a multi-physical field-coupled process involving electric and flow fields.In FECC,classical mechanics are introduced into the tool cathode,which must be loaded at all times during the machining process.Therefore,in this study,before and after the deformation of the flexible electrode,a corresponding simulation study was conducted to understand the influence of the online deformation of the flexible electrode on the flow and electric fields.The feasibility of flexible electrodes for online deformation and the validity of the theoretical model were verified by deformation measurements and in situ observation experiments.Finally,the method was successfully applied to the machining of nickel-based high-temperature alloys,and different specifications of flexible electrodes were used to complete the machining of the corresponding complex profiles,thereby verifying the feasibility and versatility of the method.The method proposed in this study breaks the tradition of using a non-deformable cathode for ECM and adopts a flexible electrode that can be deformed during the machining process as the tool cathode,which improves machining flexibility and provides a valuable reference to promote the ECM of complex profiles.展开更多
Sodium(Na)and magnesium(Mg)are becoming important for making energy-storage batteries and structural materials.Herein,we develop a liquid-metal-electrode-assisted electrolysis route to producing Na and Mg with low-car...Sodium(Na)and magnesium(Mg)are becoming important for making energy-storage batteries and structural materials.Herein,we develop a liquid-metal-electrode-assisted electrolysis route to producing Na and Mg with low-carbon emissions and no chlorine gas evolution.The clean production stems from the choice of a molten NaCl-Na_(2)CO_(3) electrolyte to prevent chlorine gas evolution,an inert nickel-based anode to produce oxygen,and a liquid metal cathode to make the cathodic product sit at the bottom of the electrolytic cell.We achieve a current efficiency of>90%for the electrolytic production of liquid Na-Sn alloy.Later,Mg-Sn alloy is prepared using the obtained Na-Sn alloy to displace Mg from molten NaCl-MgCl_(2) with a displacement efficiency of>96%.Further,Na and Mg are separated from the electrolytic Na-Sn and displaced Mg-Sn alloys by vacuum distillation with a recovery rate of>92%and Sn can be reused.Using this electrolysisdisplacement-distillation(EDD)approach,we prepare Mg from seawater.The CO_(2)emission of the EDD approach is~20.6 kg CO_(2)per kg Mg,which is less than that of the Australian Magnesium(AM)electrolysis process(~25.0 kg CO_(2)per kg Mg)and less than half that of the Pidgeon process(~45.2 kg CO_(2)per kg Mg).展开更多
Improving the volumetric energy density of supercapacitors is essential for practical applications,which highly relies on the dense storage of ions in carbon-based electrodes.The functional units of carbon-based elect...Improving the volumetric energy density of supercapacitors is essential for practical applications,which highly relies on the dense storage of ions in carbon-based electrodes.The functional units of carbon-based electrode exhibit multi-scale structural characteristics including macroscopic electrode morphologies,mesoscopic microcrystals and pores,and microscopic defects and dopants in the carbon basal plane.Therefore,the ordered combination of multi-scale structures of carbon electrode is crucial for achieving dense energy storage and high volumetric performance by leveraging the functions of various scale structu re.Considering that previous reviews have focused more on the discussion of specific scale structu re of carbon electrodes,this review takes a multi-scale perspective in which recent progresses regarding the structureperformance relationship,underlying mechanism and directional design of carbon-based multi-scale structures including carbon morphology,pore structure,carbon basal plane micro-environment and electrode technology on dense energy storage and volumetric property of supercapacitors are systematically discussed.We analyzed in detail the effects of the morphology,pore,and micro-environment of carbon electrode materials on ion dense storage,summarized the specific effects of different scale structures on volumetric property and recent research progress,and proposed the mutual influence and trade-off relationship between various scale structures.In addition,the challenges and outlooks for improving the dense storage and volumetric performance of carbon-based supercapacitors are analyzed,which can provide feasible technical reference and guidance for the design and manufacture of dense carbon-based electrode materials.展开更多
Thick electrodes can reduce the ratio of inactive constituents in a holistic energy storage system while improving energy and power densities.Unfortunately,traditional slurry-casting electrodes induce high-tortuous io...Thick electrodes can reduce the ratio of inactive constituents in a holistic energy storage system while improving energy and power densities.Unfortunately,traditional slurry-casting electrodes induce high-tortuous ionic diffusion routes that directly depress the capacitance with a thickening design.To overcome this,a novel 3D low-tortuosity,self-supporting,wood-structured ultrathick electrode(NiMoN@WC,a thickness of~1400 mm)with hierarchical porosity and artificial array-distributed small holes was constructed via anchoring bimetallic nitrides into the monolithic wood carbons.Accompanying the embedded NiMoN nanoclusters with well-designed geometric and electronic structure,the vertically low-tortuous channels,enlarged specific surface area and pore volume,superhydrophilic interface,and excellent charge conductivities,a superior capacitance of NiMoN@WC thick electrodes(~5350 mF cm^(-2)and 184.5 F g^(-1))is achieved without the structural deformation.In especial,monolithic wood carbons with gradient porous network not only function as the high-flux matrices to ameliorate the NiMoN loading via cell wall engineering but also allow fully-exposed electroactive substance and efficient current collection,thereby deliver an acceptable rate capability over 75%retention even at a high sweep rate of 20 mA cm^(-2).Additionally,an asymmetric NiMoN@WC//WC supercapacitor with an available working voltage of 1.0-1.8 V is assembled to demonstrate a maximum energy density of~2.04 mWh cm^(-2)(17.4 Wh kg^(-1))at a power density of 1620 mW cm^(-2),along with a decent long-term lifespan over 10,000 charging-discharging cycles.As a guideline,the rational design of wood ultrathick electrode with nanostructured transition metal nitrides sketch a promising blueprint for alleviating global energy scarcity while expanding carbon-neutral technologies.展开更多
This study explores the potential of Michelia champaca wood as a sustainable and locally available precursor for the fabrication of high-performance supercapacitor electrodes.Activated carbons were synthesized through...This study explores the potential of Michelia champaca wood as a sustainable and locally available precursor for the fabrication of high-performance supercapacitor electrodes.Activated carbons were synthesized through single-step carbonization at 400℃ and 500℃(SSC-400℃ and SSC-500℃) and double-step carbonization at 400℃(DSC-400℃),with all samples activated using H_(3)PO_(4).The effects of carbonization stratergy on the structural,morphological,and electrochemical characteristics of the resulting carbon materials were systematically evaluated,using techniques such as BET,SEM,TEM,XRD,Raman scattering,FTIR,CV,GCD and EIS.Among the samples,SSC-400℃ exhibited the best electrochemical performance,achieving a specific capacitance of 292.2 Fg^(-1),an energy density of 6.4 Wh kg^(-1),and a power density of 198.4 W kg^(-1).This superior performance is attributed to its optimized pore structure,improved sur-face functionality and enhanced conductivity.SSC-500℃showed marginally lower performance,whereas,DSC-400℃ displayed the least favorable results,indicating that double-step carbonization process may negatively affect material quality by disrupting the pore network.This work highlights a strong correlation between synthesis methodology and electrochemical efficiency,directly reinforcing the importance of process optimization in electrode material develop-ment.The findings contribute to the broader goal of developing cost-effective,renewable and environmentally friendly energy storage systems.By valorizing biomass waste,the study supports global movements toward green energy technologies and circular carbon economies,offering a viable pathway for sustainable supercapacitor development and practical applications in energy storage devices.展开更多
With the continuous development of wearable electronics,wireless sensor networks and other micro-electronic devices,there is an increasingly urgent need for miniature,flexible and efficient nanopower generation techno...With the continuous development of wearable electronics,wireless sensor networks and other micro-electronic devices,there is an increasingly urgent need for miniature,flexible and efficient nanopower generation technology.Triboelectric nanogenerator(TENG)technology can convert small mechanical energy into electricity,which is expected to address this problem.As the core component of TENG,the choice of electrode materials significantly affects its performance.Traditional metal electrode materials often suffer from problems such as durability,which limits the further application of TENG.Graphene,as a novel electrode material,shows excellent prospects for application in TENG owing to its unique structure and excellent electrical properties.This review systematically summarizes the recent research progress and application prospects of TENGs based on graphene electrodes.Various precision processing methods of graphene electrodes are introduced,and the applications of graphene electrode-based TENGs in various scenarios as well as the enhancement of graphene electrodes for TENG performance are discussed.In addition,the future development of graphene electrode-based TENGs is also prospectively discussed,aiming to promote the continuous advancement of graphene electrode-based TENGs.展开更多
Graphite-silicon species(Gr-Si)hybrid anodes have merged as potential candidates for high-energy lithium-ion batteries(LIBs),yet long been plagued by rapid capacity fading due to their unstable mechano-electrochemistr...Graphite-silicon species(Gr-Si)hybrid anodes have merged as potential candidates for high-energy lithium-ion batteries(LIBs),yet long been plagued by rapid capacity fading due to their unstable mechano-electrochemistry.The dominant approach to enhance electrochemical stability of the Gr-Si hybrid anodes typically involves the optimization of the electrode material structures and the employment of low active Si species content in electrode(<10 wt%in most instances).However,the electrode structure design,a factor of equal importance in determining the electrochemical performance of Gr-Si hybrid anodes,has received scant attention.In this study,three Gr-Si hybrid anodes with the identical material composition but distinct electrode structures are designed to investigate the mechanoelectrochemistry of the electrodes.It is revealed that the substantial volume change of Si species particles in Gr-Si hybrid anodes led to the local lattice stress of Gr at their contact interface during the charge/discharge processes,thereby increasing thermodynamic and kinetic barrier of Li-ion migration.Furthermore,the huge disparity in volume change of Si species and Gr particles trigger the separate agglomeration of these two materials,resulting in a considerable electrode volume change and increased electrochemical resistance.An advanced Gr/Si hybrid anode with upper Gr and lower Si species layer structure design addresses the above challenges using photovoltaic waste silicon sources under high Si species content(17 wt%)and areal capacity(2.0 mA h cm^(-2))in Ah-level full pouch cells with a low negative/positive(N/P)ratio of 1.09.The cell shows stable cycling for 100 cycles at 0.3 C with an impressively low capacity decay rate of 0.0546%per cycle,outperforming most reported Gr-Si hybrid anodes.展开更多
基金supported by the University of Seoul’s 2025 Research Fund.
文摘Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of vanadium species on conventional carbon electrodes remains a major limitation to their performance.We investigated the deposition of carbon black,carbon nanotubes,and electrochemically exfoliated graphene(Exf-Gr)onto thermally-activated carbon paper(ACP)by spray coating to increase the electrode electrocatalytic activity.The modified electrodes were characterized using scanning electron microscopy,X-ray diffraction,Raman spectroscopy,X-ray photoelectron microscopy,and surface area analysis,while their electrochemical properties were evaluated by cyclic voltammetry,electrochemical impedance spectroscopy,and singlecell VRFB testing.Among the modified electrodes,Exf-Gr/ACP had the best performance,achieving a 2.9-fold reduction in charge transfer resistance compared to pristine ACP and delivering 2.5 times the discharge capacity in single-cell tests.This improvement is attributed to Exf-Gr’s high surface area,favorable catalytic activity,and excellent dispersion on the ACP substrate.Surface modification with electrochemically exfoliated graphene is a highly effective strategy for improving the electrode performance in VRFB systems,with significant implications for large-scale energy storage.
基金financial support from the National Natural Science Foundation of China(52473248,52203123,52125301,22279070 and U21A20170)the State Key Laboratory of Polymer Materials Engineering(Grant No:sklpme 2023-1-05 and sklpme 2024-2-04)+2 种基金the Ministry of Science and Technology of China(No.2019YFA0705703)the Sichuan Science and Technology Program(2023NSFSC0991 and 2025ZNSFSC1411)the Fundamental Research Funds for the Central Universities.This research was partially sponsored by the Double First-Class Construction Funds of Sichuan University.
文摘The development of shape-customizable and bulk flexible electrochemical devices through processing technologies as versatile as those used for plastics promises to revolutionize the future of battery technology.However,this pursuit has been fundamentally hindered by the absence of transformative battery materials capable of delivering the necessary electrochemical functions,robust interface adhesion,and,crucially,the suitable rheological properties required for on-demand shaping.In this work,we introduce a concept of a multifunctional plasticine electrode matrix(PEM)featuring nano-interpenetrating networks(nano-IPN)to address this challenge.Utilizing the nonflammable liquid-electrolyte hydration combined with conductive nanomaterials,we have realized a PEM in the form of a multifunctional nanocomposite that integrates ion and electron conduction,component binding,non-flammability,and plasticine-like moldability.With this PEM,we have successfully fabricated a variety of bulk-flexible electrodes with high mass loading of active material(AM)(>70 wt%)using industry-friendly extrusion and compression molding techniques.Moreover,these high AM-loading composite electrodes achieve an unparalleled bulk conformability and flexibility,remaining structurally intact even under severe mechanical stress.Ultimately,we have successfully produced shape-patternable and flexible batteries via extrusion molding.This study underscores the potential of the PEM to revolutionize battery microstructures,interfaces,manufacturing processes,and performance characteristics.
基金financially supported by research grants from Innovative Research Group Project of National Natural Science Foundation of China(52021004)the National Key Research and Development Program of China(2022YFB3803300)+1 种基金the National Natural Science Foundation of China(62474026,62205140,12204071)the China Postdoctoral Science Foundation(2022M710532)。
文摘Thermocells are garnering increasing attention as a promising thermoelectric technology for harvesting low-grade heat.However,their performance is often limited by the scarcity of high-performance redox couples that possess both high thermopower and rapid redox kinetics.This work addresses this challenge by leveraging our recently developed copper(Ⅰ/Ⅱ)(Cu^(+)/Cu^(2+))redox couple.We significantly enhance the performance of Cu-based liquid thermocells by integrating a thermosensitive crystallization process with etched carbon cloth electrodes,achieving synergistic improvements in thermodynamic and kinetic performance.The thermosensitive crystallization process establishes a persistent Cu^(2+)concentration gradient,boosting the thermopower from 1.47 to 2.93 mV K^(-1).Moreover,the etched carbon cloth electrodes provide a larger electroactive surface area and demonstrate a higher current density.Consequently,the optimized Cu^(+)/Cu^(2+)system achieved an exceptional normalized power density P_(max)(ΔT)^(-2)of 3.97 mW m^(-2)K^(-2).A thermocell module comprised of 20 cells directly power various electronic devices at a temperature difference of 40 K.This work successfully exhibits potential of Cu^(+)/Cu^(2+)redox couple in thermoelectric conversion and introduces a valuable redox couple for highperformance thermocells.
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(No.NRF-2021M3H4A1A02048529)the Ministry of Trade,Industry and Energy(MOTIE)of the Korean government under grant No.RS-2022-00155854support from the DGIST Supercomputing and Big Data Center.
文摘To enhance the electrochemical performance of lithium-ion battery anodes with higher silicon content,it is essential to engineer their microstructure for better lithium-ion transport and mitigated volume change as well.Herein,we suggest an effective approach to control the micropore structure of silicon oxide(SiO_(x))/artificial graphite(AG)composite electrodes using a perforated current collector.The electrode features a unique pore structure,where alternating high-porosity domains and low-porosity domains markedly reduce overall electrode resistance,leading to a 20%improvement in rate capability at a 5C-rate discharge condition.Using microstructure-resolved modeling and simulations,we demonstrate that the patterned micropore structure enhances lithium-ion transport,mitigating the electrolyte concentration gradient of lithium-ion.Additionally,perforating current collector with a chemical etching process increases the number of hydrogen bonding sites and enlarges the interface with the SiO_(x)/AG composite electrode,significantly improving adhesion strength.This,in turn,suppresses mechanical degradation and leads to a 50%higher capacity retention.Thus,regularly arranged micropore structure enabled by the perforated current collector successfully improves both rate capability and cycle life in SiO_(x)/AG composite electrodes,providing valuable insights into electrode engineering.
基金funding from the National Natural Science Foundation of China(Award 91745203)supplemented by Central Universities'Basic Research Funds.We gratefully acknowledge the National Synchrotron Radiation Laboratory(NSRL,Hefei,China)for providing MCD-A and MCD-B beamlines for Soft XAS characterization.The authors are grateful to the Instrument and equipment sharing platform,College of Physics,Jilin University,for providing technical assistance in HT-XRD measurements.
文摘Ceramic cells promise ideal energy conversion and storage devices,making the development of efficient and robust air electrodes crucial for their application.In this study,a Ba_(0.4)Sr_(0.5)Cs_(0.1)Co_(0.7)Fe_(0.2)Nb_(0.1)O_(3−δ)(BSCCFN)air electrode,based on Ba_(0.5)Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3−δ)(BSCF),is designed using a perovskite A-B-site ionic Lewis acid strength(ISA)polarization distribution strategy and is successfully applied in both oxygen-ion conducting solid oxide fuel cells(O-SOFCs)and proton-conducting reversible protonic ceramic cells(R-PCCs).When BSCCFN is used as the air electrode in O-SOFCs,a peak power density(PPD)of 1.45 W cm^(−2)is achieved at 650°C,whereas in R-PCCs,a PPD of 1.13 W cm^(−2)and a current density of−1.8 A cm^(−2)at 1.3 V are achieved at the same temperature and show stable reversibility over 100 h.Experimental measurements and theoretical calculations demonstrate that low-ISA Cs+doping accelerates the reaction kinetics of both oxygen ions and protons,while high-ISA Nb^(5+)doping enhances electrode stability.The synergistic effect of Cs^(+)and Nb^(5+)co-doping in the BSCCFN electrode lies in the ISA polarization distribution,which weakens the Co/Fe–O bond covalency,thereby promoting oxygen vacancy formation and facilitating the conduction of oxygen ions and protons.
基金funding support from Natural Science Foundation of Shanghai(Grant No.23ZR1443900)the National Natural Science Foundation of China(Grant Nos.22178309,22476131 and 22176127)。
文摘Economical,stable,and corrosion-resistant catalytic electrodes are still urgently needed for the oxygen evolution reaction(OER)in water and seawater.Herein,a mild electroless plating strategy is used to achieve large-scale preparation of the“integrated”phosphorus-based precatalyst(FeP-NiP)on nickel foam(NF),which is in situ reconstructed into a highly active and corrosion-resistant(Fe)NiOOH phase for OER.The interaction between phosphate anions(PO_(x)^(y-))and iron ions(Fe^(3+))tunes the electronic structure of the catalytic phase to further enhance OER kinetics.The integrated FeP-NiP@NF electrode exhibits low overpotentials for OER in alkaline water/seawater,requiring only 275/289,320/336,and 349/358 mV to reach 0.1,0.5,and 1.0 A cm^(−2),respectively.The in situ reconstructed PO_(x)^(y-)anion electrostatically repels Cl−in seawater electrolytes,allowing stable operation for over 7 days at 1.0 A cm^(−2) in extreme electrolytes(1.0 M KOH+seawater and 6.0 M KOH+seawater),demonstrating industrial-level stability.This study overcomes the complex synthesis limitations of P-based materials through innovative material design,opening new avenues for electrochemical energy conversion.
基金supported by the National Natural Science Foundation of China(22378431,52004338,51622406,21673298)Hunan Provincial Natural Science Foundation(2023JJ40210,2022JJ20075)+3 种基金the Science and Technology Innovation Program of Hunan Province(2023RC3259)the Key R&D plan of Hunan Province(2024JK2096)Scientifc Research Fund of Hunan Provincial Education Department(23B0699)Central South University Innovation-Driven Research Programme(2023CXQD008).
文摘High-entropy materials represent a new category of high-performance materials,first proposed in 2004 and extensively investigated by researchers over the past two decades.The definition of high-entropy materials has continuously evolved.In the last ten years,the discovery of an increasing number of high-entropy materials has led to significant advancements in their utilization in energy storage,electrocatalysis,and related domains,accompanied by a rise in techniques for fabricating high-entropy electrode materials.Recently,the research emphasis has shifted from solely improving the performance of high-entropy materials toward exploring their reaction mechanisms and adopting cleaner preparation approaches.However,the current definition of high-entropy materials remains relatively vague,and the preparation method of high-entropy materials is based on the preparation method of single metal/low-or medium-entropy materials.It should be noted that not all methods applicable to single metal/low-or medium-entropy materials can be directly applied to high-entropy materials.In this review,the definition and development of high-entropy materials are briefly reviewed.Subsequently,the classification of high-entropy electrode materials is presented,followed by a discussion of their applications in energy storage and catalysis from the perspective of synthesis methods.Finally,an evaluation of the advantages and disadvantages of various synthesis methods in the production process of different high-entropy materials is provided,along with a proposal for potential future development directions for high-entropy materials.
基金supported by National Natural Science Foundation of China(22279018)National Natural Science Foundation of China(22005055)Natural Science Foundation of Fujian Province(2022J01085).
文摘Solid oxide cells(SOCs)are emerging devices for efficient energy storage and conversion.However,during SOC operation,gaseous chromium(Cr)species released from Fe-Cr alloy interconnect can lead to Cr deposition and poisoning of air electrodes,causing substantial degradation in electrochemical performance and compromising the longterm stability of SOCs.This mini-review examines the mechanism of Cr deposition and poisoning in air electrodes under both fuel-cell and electrolysis modes.Furthermore,emphasis is placed on the recent advancements in strategies to mitigate Cr poisoning,offering insights into the rational design and development of active and Cr-tolerant air electrodes for SOCs.
基金supported by Fundamental Research Funds for the Central Universities(2023KYJD1008)the Science Research Projects of the Anhui Higher Education Institutions of China(2022AH051582).
文摘Reversible solid oxide cell(RSOC)is a new energy conversion device with significant applications,especially for power grid peaking shaving.However,the reversible conversion process of power generation/energy storage poses challenges for the performance and stability of air electrodes.In this work,a novel high-entropy perovskite oxide La_(0.2)Pr_(0.2)Gd_(0.2)Sm_(0.2)Sr_(0.2)Co_(0.8)Fe_(0.2)O_(3−δ)(HE-LSCF)is proposed and investigated as an air electrode in RSOC.The electrochemical behavior of HE-LSCF was studied as an air electrode in both fuel cell and electrolysis modes.The polarization impedance(Rp)of the HE-LSCF electrode is only 0.25Ω·cm^(2) at 800℃ in an air atmosphere.Notably,at an electrolytic voltage of 2 V and a temperature of 800℃,the current density reaches up to 1.68 A/cm^(2).The HE-LSCF air electrode exhibited excellent reversibility and stability,and its electrochemical performance remains stable after 100 h of reversible operation.With these advantages,HE-LSCF is shown to be an excellent air electrode for RSOC.
基金supported by the Beijing Natural Science Foundation(No.QY24166).
文摘In a pulsed plasma thruster,the voltage distribution between the electrodes is a key factor that influences the ionization process.However,few researchers have conducted in-depth studies of this phenomenon in the past.Reported here are measurements of the voltage distribution between the plates of a parallel-plate pulsed plasma thruster under different discharge voltages,based on which the variations in the total circuit inductance and resistance as well as those between the plates are calculated.The results show that the time-averaged voltage across the plates accounts for 28.7%-50.4%of the capacitor voltage.As the capacitor initial voltage increases from 1250 V to 2000 V,the voltage across the plates rises,but its proportion relative to the capacitor voltage decreases.For every 250 V increase in the capacitor initial voltage,the average voltage proportion across the plates decreases by approximately 2%-3%.Additionally,the voltage proportion decreases gradually from the end near the propellant outward.The voltage distribution ratio between the plates is correlated with the proportions of the resistance and inductance between the plates relative to the total circuit.
基金Funded by the Ministry of Science,Technological Development and Innovation of the Republic of Serbia(Nos.451-03-47/2023-01/200135,451-03-47/2023-01/200017 and 451-03-47/2023-01/200287)。
文摘This paper describes severe plastic deformation(SPD)procedures,which are utilized to form an ultrafine-grained structure in metallic biomaterials.During the SPD process,a solid material sample is subjected to very high loads without a significant change in sample dimensions.In the present work,the high-pressure torsion(HPT)process,as one of the SPD techniques,which achieves a high degree of deformation and ensures refinement of the microstructure,will be discussed in more detail.Considering that grain size control is accepted as a method to obtain materials with desired characteristics,an overview of the properties of ultrafine-grained titanium-based biomaterials to be used in medicine is given.Moreover,particular attention is dedicated to the influences of HPT process parameters,primarily hydrostatic pressure,and number of revolutions during torsion,on the grain size and physical and mechanical characteristics(modulus of elasticity,microhardness,and tensile properties),corrosion resistance,and biocompatibility of the titanium-based biomaterials.A review of the literature indicates that titanium-based materials obtained by the SPD process show improved mechanical and physical properties without losing biocompatibility and corrosion resistance,which suggests that these methods of obtaining implants are something that should be further developed in the future.
基金the National Key R&D Program of China(No.2021YFA1501503)the National Natural Science Foundation of China(Nos.22250008,22121004,22108197)+3 种基金the Haihe Laboratory of Sustainable Chemical Transformations(No.CYZC202107)the Natural Science Foundation of Tianjin City(No.21JCZXJC00060)the Program of Introducing Talents of Discipline to Universities(No.BP0618007)the Xplorer Prize for financial support。
文摘Membrane electrode assembly(MEA)is widely considered to be the most promising type of electrolyzer for the practical application of electrochemical CO_(2) reduction reaction(CO_(2)RR).In MEAs,a square-shaped cross-section in the flow channel is normally adopted,the configuration optimization of which could potentially enhance the performance of the electrolyzer.This paper describes the numerical simulation study on the impact of the flow-channel cross-section shapes in the MEA electrolyzer for CO_(2)RR.The results show that wide flow channels with low heights are beneficial to the CO_(2)RR by providing a uniform flow field of CO_(2),especially at high current densities.Moreover,the larger the electrolyzer,the more significant the effect is.This study provides a theoretical basis for the design of high-performance MEA electrolyzers for CO_(2)RR.
基金supported by the National Research Foundation of Korea(NRF)through a grant provided by the Korean government(No.NRF-2021R1F1A1063451).
文摘Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS)is a highly successful conductive polymer utilized as an electrode material in energy storage units for portable and wearable electronic de-vices.Nevertheless,employing PEDOT:PSS in supercapacitors(SC)in its pristine state presents challenges due to its suboptimal electrochemical performance and operational instability.To surmount these limita-tions,PEDOT:PSS has been integrated with carbon-based materials to form flexible electrodes,which ex-hibit physical and chemical stability during SC operation.We developed a streamlined fabrication process for high-performance SC electrodes composed of PEDOT:PSS and carbon quantum dots(CQDs).The CQDs were synthesized under microwave irradiation,yielding green-and red-light emissions.Through optimiz-ing the ratios of CQDs to PEDOT:PSS,the SC electrodes were prepared using a spray-coating technique,marking a significant improvement in device performance with a high volumetric capacitance(104.10 F cm-3),impressive energy density(19.68 Wh cm^(-3)),and excellent cyclic stability,retaining~85% of its original volumetric capacitance after 15,000 repeated GCD cycles.Moreover,the SCs,when utilized as a flexible substrate,demonstrated the ability to maintain up to~85% of their electrochemical performance even after 3,000 bending cycles(at a bending angle of 60°).These attributes render this hybrid composite an ideal candidate for a lightweight smart energy storage component in portable and wearable electronic technologies.
基金supported by the National Natural Science Foundation of China(52375443)the Innovative Research Group Project of the National Natural Science Foundation of China(51921003).
文摘Improvements in aero-engine performance have made the structures of the aero-engine components increasingly complex.To better adapt to the processing requirements of narrow twisted channels such as an integral shrouded blisk,this study proposes an innovative method of electrochemical cutting in which a flexible tube electrode is controlled by online deformation during processing.In this study,the processing principle of electrochemical cutting with a flexible electrode for controlled online deformation(FECC)was revealed for the first time.The online deformation process of flexible electrodes and the machining process of profiles were analysed in depth,and the corresponding theoretical models were established.Conventional electrochemical machining(ECM)is a multi-physical field-coupled process involving electric and flow fields.In FECC,classical mechanics are introduced into the tool cathode,which must be loaded at all times during the machining process.Therefore,in this study,before and after the deformation of the flexible electrode,a corresponding simulation study was conducted to understand the influence of the online deformation of the flexible electrode on the flow and electric fields.The feasibility of flexible electrodes for online deformation and the validity of the theoretical model were verified by deformation measurements and in situ observation experiments.Finally,the method was successfully applied to the machining of nickel-based high-temperature alloys,and different specifications of flexible electrodes were used to complete the machining of the corresponding complex profiles,thereby verifying the feasibility and versatility of the method.The method proposed in this study breaks the tradition of using a non-deformable cathode for ECM and adopts a flexible electrode that can be deformed during the machining process as the tool cathode,which improves machining flexibility and provides a valuable reference to promote the ECM of complex profiles.
基金support from the National Natural Science Foundation of China(No’s.U22B2071,51874211,52031008)the Chilwee Group(CWDY-ZH-YJY-202101-001).
文摘Sodium(Na)and magnesium(Mg)are becoming important for making energy-storage batteries and structural materials.Herein,we develop a liquid-metal-electrode-assisted electrolysis route to producing Na and Mg with low-carbon emissions and no chlorine gas evolution.The clean production stems from the choice of a molten NaCl-Na_(2)CO_(3) electrolyte to prevent chlorine gas evolution,an inert nickel-based anode to produce oxygen,and a liquid metal cathode to make the cathodic product sit at the bottom of the electrolytic cell.We achieve a current efficiency of>90%for the electrolytic production of liquid Na-Sn alloy.Later,Mg-Sn alloy is prepared using the obtained Na-Sn alloy to displace Mg from molten NaCl-MgCl_(2) with a displacement efficiency of>96%.Further,Na and Mg are separated from the electrolytic Na-Sn and displaced Mg-Sn alloys by vacuum distillation with a recovery rate of>92%and Sn can be reused.Using this electrolysisdisplacement-distillation(EDD)approach,we prepare Mg from seawater.The CO_(2)emission of the EDD approach is~20.6 kg CO_(2)per kg Mg,which is less than that of the Australian Magnesium(AM)electrolysis process(~25.0 kg CO_(2)per kg Mg)and less than half that of the Pidgeon process(~45.2 kg CO_(2)per kg Mg).
基金funded by the Joint Fund for Regional Innovation and Development of National Natural Science Foundation of China(U21A20143)the National Science Fund for Excellent Young Scholars(52322607)the Excellent Youth Foundation of Heilongjiang Scientific Committee(YQ2022E028)。
文摘Improving the volumetric energy density of supercapacitors is essential for practical applications,which highly relies on the dense storage of ions in carbon-based electrodes.The functional units of carbon-based electrode exhibit multi-scale structural characteristics including macroscopic electrode morphologies,mesoscopic microcrystals and pores,and microscopic defects and dopants in the carbon basal plane.Therefore,the ordered combination of multi-scale structures of carbon electrode is crucial for achieving dense energy storage and high volumetric performance by leveraging the functions of various scale structu re.Considering that previous reviews have focused more on the discussion of specific scale structu re of carbon electrodes,this review takes a multi-scale perspective in which recent progresses regarding the structureperformance relationship,underlying mechanism and directional design of carbon-based multi-scale structures including carbon morphology,pore structure,carbon basal plane micro-environment and electrode technology on dense energy storage and volumetric property of supercapacitors are systematically discussed.We analyzed in detail the effects of the morphology,pore,and micro-environment of carbon electrode materials on ion dense storage,summarized the specific effects of different scale structures on volumetric property and recent research progress,and proposed the mutual influence and trade-off relationship between various scale structures.In addition,the challenges and outlooks for improving the dense storage and volumetric performance of carbon-based supercapacitors are analyzed,which can provide feasible technical reference and guidance for the design and manufacture of dense carbon-based electrode materials.
基金support from the National Natural Science Foundation of China(32171728)Wuhan Knowledge Innovation Project(2022020801020312).
文摘Thick electrodes can reduce the ratio of inactive constituents in a holistic energy storage system while improving energy and power densities.Unfortunately,traditional slurry-casting electrodes induce high-tortuous ionic diffusion routes that directly depress the capacitance with a thickening design.To overcome this,a novel 3D low-tortuosity,self-supporting,wood-structured ultrathick electrode(NiMoN@WC,a thickness of~1400 mm)with hierarchical porosity and artificial array-distributed small holes was constructed via anchoring bimetallic nitrides into the monolithic wood carbons.Accompanying the embedded NiMoN nanoclusters with well-designed geometric and electronic structure,the vertically low-tortuous channels,enlarged specific surface area and pore volume,superhydrophilic interface,and excellent charge conductivities,a superior capacitance of NiMoN@WC thick electrodes(~5350 mF cm^(-2)and 184.5 F g^(-1))is achieved without the structural deformation.In especial,monolithic wood carbons with gradient porous network not only function as the high-flux matrices to ameliorate the NiMoN loading via cell wall engineering but also allow fully-exposed electroactive substance and efficient current collection,thereby deliver an acceptable rate capability over 75%retention even at a high sweep rate of 20 mA cm^(-2).Additionally,an asymmetric NiMoN@WC//WC supercapacitor with an available working voltage of 1.0-1.8 V is assembled to demonstrate a maximum energy density of~2.04 mWh cm^(-2)(17.4 Wh kg^(-1))at a power density of 1620 mW cm^(-2),along with a decent long-term lifespan over 10,000 charging-discharging cycles.As a guideline,the rational design of wood ultrathick electrode with nanostructured transition metal nitrides sketch a promising blueprint for alleviating global energy scarcity while expanding carbon-neutral technologies.
文摘This study explores the potential of Michelia champaca wood as a sustainable and locally available precursor for the fabrication of high-performance supercapacitor electrodes.Activated carbons were synthesized through single-step carbonization at 400℃ and 500℃(SSC-400℃ and SSC-500℃) and double-step carbonization at 400℃(DSC-400℃),with all samples activated using H_(3)PO_(4).The effects of carbonization stratergy on the structural,morphological,and electrochemical characteristics of the resulting carbon materials were systematically evaluated,using techniques such as BET,SEM,TEM,XRD,Raman scattering,FTIR,CV,GCD and EIS.Among the samples,SSC-400℃ exhibited the best electrochemical performance,achieving a specific capacitance of 292.2 Fg^(-1),an energy density of 6.4 Wh kg^(-1),and a power density of 198.4 W kg^(-1).This superior performance is attributed to its optimized pore structure,improved sur-face functionality and enhanced conductivity.SSC-500℃showed marginally lower performance,whereas,DSC-400℃ displayed the least favorable results,indicating that double-step carbonization process may negatively affect material quality by disrupting the pore network.This work highlights a strong correlation between synthesis methodology and electrochemical efficiency,directly reinforcing the importance of process optimization in electrode material develop-ment.The findings contribute to the broader goal of developing cost-effective,renewable and environmentally friendly energy storage systems.By valorizing biomass waste,the study supports global movements toward green energy technologies and circular carbon economies,offering a viable pathway for sustainable supercapacitor development and practical applications in energy storage devices.
基金supported by the National Natural Science Foundation of China(grant No.52422511,U20A6004)the Guangdong Basic and Applied Basic Research Foundation(grant No.2022B1515120011)Guangzhou Basic and Applied Basic Research Foundation(grant No.2024A04J6362).
文摘With the continuous development of wearable electronics,wireless sensor networks and other micro-electronic devices,there is an increasingly urgent need for miniature,flexible and efficient nanopower generation technology.Triboelectric nanogenerator(TENG)technology can convert small mechanical energy into electricity,which is expected to address this problem.As the core component of TENG,the choice of electrode materials significantly affects its performance.Traditional metal electrode materials often suffer from problems such as durability,which limits the further application of TENG.Graphene,as a novel electrode material,shows excellent prospects for application in TENG owing to its unique structure and excellent electrical properties.This review systematically summarizes the recent research progress and application prospects of TENGs based on graphene electrodes.Various precision processing methods of graphene electrodes are introduced,and the applications of graphene electrode-based TENGs in various scenarios as well as the enhancement of graphene electrodes for TENG performance are discussed.In addition,the future development of graphene electrode-based TENGs is also prospectively discussed,aiming to promote the continuous advancement of graphene electrode-based TENGs.
基金the financial support by the National Natural Science Foundation of China(52072137)the National Natural Science Foundation of China(22205068)the"CUG Scholar"Scientific Research Funds at China University of Geosciences(Wuhan)(2022118)。
文摘Graphite-silicon species(Gr-Si)hybrid anodes have merged as potential candidates for high-energy lithium-ion batteries(LIBs),yet long been plagued by rapid capacity fading due to their unstable mechano-electrochemistry.The dominant approach to enhance electrochemical stability of the Gr-Si hybrid anodes typically involves the optimization of the electrode material structures and the employment of low active Si species content in electrode(<10 wt%in most instances).However,the electrode structure design,a factor of equal importance in determining the electrochemical performance of Gr-Si hybrid anodes,has received scant attention.In this study,three Gr-Si hybrid anodes with the identical material composition but distinct electrode structures are designed to investigate the mechanoelectrochemistry of the electrodes.It is revealed that the substantial volume change of Si species particles in Gr-Si hybrid anodes led to the local lattice stress of Gr at their contact interface during the charge/discharge processes,thereby increasing thermodynamic and kinetic barrier of Li-ion migration.Furthermore,the huge disparity in volume change of Si species and Gr particles trigger the separate agglomeration of these two materials,resulting in a considerable electrode volume change and increased electrochemical resistance.An advanced Gr/Si hybrid anode with upper Gr and lower Si species layer structure design addresses the above challenges using photovoltaic waste silicon sources under high Si species content(17 wt%)and areal capacity(2.0 mA h cm^(-2))in Ah-level full pouch cells with a low negative/positive(N/P)ratio of 1.09.The cell shows stable cycling for 100 cycles at 0.3 C with an impressively low capacity decay rate of 0.0546%per cycle,outperforming most reported Gr-Si hybrid anodes.
