Recovery of scandium from titanium white waste acid is an essential source of scandium.Simple and economical production of high purity scandium remains a challenge.A new extractant,N,N,N’,N’-tetracyclohexyl-diglycol...Recovery of scandium from titanium white waste acid is an essential source of scandium.Simple and economical production of high purity scandium remains a challenge.A new extractant,N,N,N’,N’-tetracyclohexyl-diglycolamide(TCHDGA),was synthesized,and the separation performance of scandium from impurity metal ions(Ti,Mn,Ba,Fe,Al and Mg)was investigated,The effects of mixing time,acid concentration and temperature on the scandium extraction were considered.The extraction mechanism was studied by infrared spectroscopy and the Equimole Series Method.Under optimized conditions,the extractant shows a strong affinity to scandium in the nitric acid medium and high extraction separation factors between scandium and these impurity metal ions,A process for the purification of scandium was established.The crude product obtained from titanium white waste acid,95%purity scandium oxide,can be purified to 99.99%after only one step of extraction,scrubbing,and stripping:This technology is economical and straightforward and can realize the high-value recovery of scandium in the titanium white waste acid.展开更多
Titanium oxide that has the photocatalytic activity is used as the white pigment for cosmetics. A certain degree of sebum on the skin is decomposed by the ultraviolet radiation in sunlight. In this work, as a novel wh...Titanium oxide that has the photocatalytic activity is used as the white pigment for cosmetics. A certain degree of sebum on the skin is decomposed by the ultraviolet radiation in sunlight. In this work, as a novel white pigment, titanium phosphates were prepared from titanium sulfate and phosphoric acid at pH 5, 7, and 9, with/without ultrasonic treatment for cosmetics. Their chemical composition, powder properties, photocatalytic activity, color phase, moisture retention, and smoothness were studied. These titanium phosphates had less photocatalytic activity to protect the sebum on the skin. Sample prepared at pH 7 without ultrasonic treatment had higher moisture retention than other samples. All samples obtained in this work had the suitable smoothness for cosmetics.展开更多
基金supported by the National Natural Science Foundation of China(21876062)。
文摘Recovery of scandium from titanium white waste acid is an essential source of scandium.Simple and economical production of high purity scandium remains a challenge.A new extractant,N,N,N’,N’-tetracyclohexyl-diglycolamide(TCHDGA),was synthesized,and the separation performance of scandium from impurity metal ions(Ti,Mn,Ba,Fe,Al and Mg)was investigated,The effects of mixing time,acid concentration and temperature on the scandium extraction were considered.The extraction mechanism was studied by infrared spectroscopy and the Equimole Series Method.Under optimized conditions,the extractant shows a strong affinity to scandium in the nitric acid medium and high extraction separation factors between scandium and these impurity metal ions,A process for the purification of scandium was established.The crude product obtained from titanium white waste acid,95%purity scandium oxide,can be purified to 99.99%after only one step of extraction,scrubbing,and stripping:This technology is economical and straightforward and can realize the high-value recovery of scandium in the titanium white waste acid.
文摘Titanium oxide that has the photocatalytic activity is used as the white pigment for cosmetics. A certain degree of sebum on the skin is decomposed by the ultraviolet radiation in sunlight. In this work, as a novel white pigment, titanium phosphates were prepared from titanium sulfate and phosphoric acid at pH 5, 7, and 9, with/without ultrasonic treatment for cosmetics. Their chemical composition, powder properties, photocatalytic activity, color phase, moisture retention, and smoothness were studied. These titanium phosphates had less photocatalytic activity to protect the sebum on the skin. Sample prepared at pH 7 without ultrasonic treatment had higher moisture retention than other samples. All samples obtained in this work had the suitable smoothness for cosmetics.
基金Chinese National Programs for High Technology Research and Development(2010AA03A405,2012AA062303)National Natural Science Foundation of China(51004033,51204040)+1 种基金National Science and Technology Support Program(2012BAE01B02)Doctoral Fund Project(20120042110011)
