To recover titanium from tionite, a new process consisting of NaOH hydrothermal conversion, water washing, and H2SO4 leaching for TiO2 preparation was developed. The experimental results show that under the optimum ...To recover titanium from tionite, a new process consisting of NaOH hydrothermal conversion, water washing, and H2SO4 leaching for TiO2 preparation was developed. The experimental results show that under the optimum hydrothermal conversion conditions, i.e., 50% NaOH （mass fraction） solution, NaOH/tionite mass ratio of 4：1, reaction temperature of 240 ℃reaction time of 1 h and oxygen partial pressure of 0.25 MPa, the titanium was mainly converted into Na2TiO3, and the conversion was 97.2%. The unwanted product Na2TiSiO5 remained stable in water washing, and its formation was prevented by improving NaOH concentration. In water washing process, about 97.6% of Na＋ could be recycled by washing the hydrothermal product. The NaOH solutions could be reused after concentration. 96.7% of titanium in the washed product was easily leached in H2SO4 solution at low temperatures, forming titanyl sulfate solution to further prepare TiO2.展开更多
The blast furnace slag bearing Ti02 in Panzhihua, China, is an important resource to be utilized. In the present paper, the effects of the ratio of slag to H2S04, the reaction temperature, the particle size of the sla...The blast furnace slag bearing Ti02 in Panzhihua, China, is an important resource to be utilized. In the present paper, the effects of the ratio of slag to H2S04, the reaction temperature, the particle size of the slag, and the concentration of H2S04 on the reaction rate and the acidolysis ratio of Ti were studied. The results indicated that the maximum acidolysis ratio reached 98%, which can serve as an experimental basis for the production of titania from the slag.展开更多
基金Project(51090380)supported by the National Natural Science Foundation of ChinaProjects(2013CB632604,2013CB632601)supported by the National Basic Research Program of China+2 种基金Project(51125018)supported by the National Science Foundation for Distinguished Young Scholars of ChinaProject(KGZD-EW-201-2)supported by the Key Research Program of the Chinese Academy of SciencesProjects(51374191,51402303)supported by the Natural Science Foundation for the Youth,China
文摘To recover titanium from tionite, a new process consisting of NaOH hydrothermal conversion, water washing, and H2SO4 leaching for TiO2 preparation was developed. The experimental results show that under the optimum hydrothermal conversion conditions, i.e., 50% NaOH （mass fraction） solution, NaOH/tionite mass ratio of 4：1, reaction temperature of 240 ℃reaction time of 1 h and oxygen partial pressure of 0.25 MPa, the titanium was mainly converted into Na2TiO3, and the conversion was 97.2%. The unwanted product Na2TiSiO5 remained stable in water washing, and its formation was prevented by improving NaOH concentration. In water washing process, about 97.6% of Na＋ could be recycled by washing the hydrothermal product. The NaOH solutions could be reused after concentration. 96.7% of titanium in the washed product was easily leached in H2SO4 solution at low temperatures, forming titanyl sulfate solution to further prepare TiO2.
文摘The blast furnace slag bearing Ti02 in Panzhihua, China, is an important resource to be utilized. In the present paper, the effects of the ratio of slag to H2S04, the reaction temperature, the particle size of the slag, and the concentration of H2S04 on the reaction rate and the acidolysis ratio of Ti were studied. The results indicated that the maximum acidolysis ratio reached 98%, which can serve as an experimental basis for the production of titania from the slag.
