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In-situ stress solution theory for borehole overcoring technique incorporating time-dependent effect of stress relief and its applications
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作者 Daohong Xia Shengjun Miao +5 位作者 Lianjun Chen Yuan Li Zejing Liu Rongmin Zhang Pengjin Yang Pengcheng Li 《International Journal of Mining Science and Technology》 2026年第1期187-203,共17页
In-situ stress is a key parameter for underground mine design and rock stability analysis.The borehole overcoring technique is widely used for in-situ stress measurement,but the rheological recovery deformation of roc... In-situ stress is a key parameter for underground mine design and rock stability analysis.The borehole overcoring technique is widely used for in-situ stress measurement,but the rheological recovery deformation of rocks after stress relief introduces errors.To improve accuracy,this study proposes an in-situ stress solution theory that incorporates time-dependent stress relief effects.Triaxial stepwise loadingunloading rheological tests on granite and siltstone established quantitative relationships between instantaneous elastic recovery and viscoelastic recovery under different stress levels,confirming their impact on measurement accuracy.By integrating a dual-class elastic deformation recovery model,an improved in-situ stress solution theory was derived.Additionally,accounting for the nonlinear characteristics of rock masses,a determination method for time-dependent nonlinear mechanical parameters was proposed.Based on the CSIRO hollow inclusion strain cell,time-dependent strain correction equations and long-term confining pressure calibration equations were formulated.Finally,the proposed theory was successfully applied at one iron mine(736 m depth)in Xinjiang,China,and one coal mine(510 m depth)in Ningxia,China.Compared to classical theory,the calculated mean stress values showed accuracy improvements of 6.0%and 9.4%,respectively,validating the applicability and reliability of the proposed theory. 展开更多
关键词 In-situ stress solution theory Borehole overcoring technique time-dependent effect of stress relief Viscoelastic recovery strain of rock In-situ stress measurement
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Study on the Application and Time-Dependent Effects of Antibiotics in the Treatment of Neonatal Pneumonia
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作者 Zhao Lu 《Asia Pacific Journal of Clinical Medical Research》 2025年第6期5-8,共4页
This article first outlines the fundamental definitions of Mycoplasma pneumoniae and the basic principles of antibiotics. It then analyzes and discusses the progress in antibiotic application and time-eff ect studies ... This article first outlines the fundamental definitions of Mycoplasma pneumoniae and the basic principles of antibiotics. It then analyzes and discusses the progress in antibiotic application and time-eff ect studies for neonatal pneumonia treatment, specifically comparing conventional antibiotic therapy with stepwise treatment regimens, and contrasting monotherapy with penicillin, monotherapy with cephalosporins, and combination therapy. Finally, it offers a prospective outlook on antibiotic application and time-effect research in neonatal pneumonia treatment, aiming to provide valuable reference for further scholarly investigations. 展开更多
关键词 Neonatal Pneumonia ANTIBIOTICS Clinical Application time-dependent effects Research Progress Future Outlook
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Strength weakening effect of high static pre-stressed granite subjected to low-frequency dynamic disturbance under uniaxial compression 被引量:16
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作者 Wu-xing WU Feng-qiang GONG Quan JIANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第7期2353-2369,共17页
This study aimed to elucidate the strength weakening effect of high static pre-stressed rocks subjected to low-frequency disturbances under uniaxial compression.Based on the uniaxial compressive strength(UCS)of granit... This study aimed to elucidate the strength weakening effect of high static pre-stressed rocks subjected to low-frequency disturbances under uniaxial compression.Based on the uniaxial compressive strength(UCS)of granite under static loading,70%,80%,and 90%of UCS were selected as the initial high static pre-stress(σ_(p)),and then the pre-stressed rock specimens were disturbed by sinusoidal stress with amplitudes of 30%,20%,and 10%of UCS under low-frequency frequencies(f)of 1,2,5,and 10 Hz,respectively.The results show that the rockburst failure of pre-stressed granite is caused by low-frequency disturbance,and the failure strength is much lower than UCS.When theσp or f is constant,the specimen strength gradually decreases as the f or σ_(p) increases.The experimental study illustrates the influence mechanism of the strength weakening effect of high static pre-stress rocks under low-frequency dynamic disturbance,that is,high static pre-stress is the premise and leading factor of rock strength weakening,while low-frequency dynamic disturbance induces rock failure and affects the strength weakening degree. 展开更多
关键词 deep rock high static pre-stress low-frequency dynamic disturbance strength weakening effect uniaxial compression ROCKBURST
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Weakening effect of plastic yielding inception in thin hard coating systems 被引量:1
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作者 Xiao Huang Shujun Zhou Tianmin Shao 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第3期493-501,共9页
Hard coatings have been widely applied to enhance tribological performance of mechanical components.However,it was predicted that thin hard coatings may have a weakening effect which could reduce the coating/substrate... Hard coatings have been widely applied to enhance tribological performance of mechanical components.However,it was predicted that thin hard coatings may have a weakening effect which could reduce the coating/substrate system’s resistance to plastic yielding compared with the uncoated substrate material.In this paper,analytical simulation is utilized to investigate the origin of weakening effect.The functions of material mechanical properties and coating thickness on the weakening effect are theoretically investigated.Partial-unloading spherical nanoindentation tests are performed on tungsten coated single crystalline silicon and copper to acquire the stress-strain curves and compared with the uncoated cases.The experimental results are in consistence with the analytical solutions,demonstrating the presence of weakening effect. 展开更多
关键词 plastic yielding weakening effect spherical nanoindentation PVD coating
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Influencing factors analysis of hard limestone reformation and strength weakening under acidic effect 被引量:1
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作者 HOU Ming-xiao HUANG Bing-xiang +2 位作者 ZHAO Xing-long JIAO Xue-jie ZHENG Chen-yang 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第7期2446-2466,共21页
Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way t... Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way to control the hard limestone roof.In this study,the effects of various factors on the reaction characteristics and mechanical properties of limestone were analyzed.The results show that the acid with stronger hydrogen production capacity after ionization(pK_(a)<0)has more prominent damage to the mineral grains of limestone.When pKa increases from−8.00 to 15.70,uniaxial compressive strength and elastic modulus of limestone increase by 117.22%and 75.98%.The influence of acid concentration is manifested in the dissolution behavior of mineral crystals,the crystal defects caused by large-scale acid action will lead to the deterioration of limestone strength,and the strength after 15%concentration reformation can be reduced by 59.42%.The effect of acidification time on limestone has stages and is the most obvious in the initial metathesis reaction stage(within 60 min).The key to the strength damage of acidified limestone is the participation of hydrogen ions in the reaction system.Based on the analytic hierarchy process method,the influence weights of acid type,acid concentration and acidification time on strength are 24.30%,59.54% and 16.16%,respectively.The research results provide theoretical support for the acidification control of hard limestone roofs in coal mines. 展开更多
关键词 hard roof acidic effect structural reformation strength weakening influencing factors
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Influence of Auxiliary Equation on Wave Functions for Time-Dependent Pauli Equation in Presence of Aharonov-Bohm Effect 被引量:1
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作者 M.Maamache C.Lahoulou Y.Saadi 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第5期803-810,共8页
Invariant operator method for discrete or continuous spectrum eigenvalue and unitary transformation approach are employed to study the two-dimensional time-dependent Pauli equation in presence of the Aharonov-Bohm eff... Invariant operator method for discrete or continuous spectrum eigenvalue and unitary transformation approach are employed to study the two-dimensional time-dependent Pauli equation in presence of the Aharonov-Bohm effect (AB) and external scalar potential. For the spin particles the problem with the magnetic field is that it introduces a singularity into wave equation at the origin. A physical motivation is to replace the zero radius flux tube by one of radius R, with the additional condition that the magnetic field be confined to the surface of the tube, and then taking the limit R → 0 at the end of the computations. We point that the invariant operator must contain the step function θ(r - R). Consequently, the problem becomes more complicated. In order to avoid this dimculty, we replace the radius R by ρ(t)R, where ρ(t) is a positive time-dependent function. Then at the end of calculations we take the limit R →0. The qualitative properties for the invariant operator spectrum are described separately for the different values of the parameter C appearing in the nonlinear auxiliary equation satisfied by p(t), i.e., C 〉 0, C = 0, and C 〈0. Following the C's values the spectrum of quantum states is discrete (C 〉 0) or continuous (C ≤ 0). 展开更多
关键词 time-dependent systems invariant theory Aharonov-Bohm effect Pauli equation
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Fault-weakening effect of reservoir temperature of hot spring and its influence on seismic activities
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作者 林元武 《Acta Seismologica Sinica(English Edition)》 CSCD 1994年第2期321-330,共10页
In this paper, the reservoir temperatures of 14 hot spring samples collected from the northern segment of theRed River Fault are calculated by using the mixing-model of SiO2-geothermometer. Based on the features ofres... In this paper, the reservoir temperatures of 14 hot spring samples collected from the northern segment of theRed River Fault are calculated by using the mixing-model of SiO2-geothermometer. Based on the features ofreservoir temperatures and densities of hot springs, the northern segment of the Red River Fault is furtherdivided into 4 sub-segments. The influence of weakening effect of water on seismic activities is discussed fromthe view point of fault-weakening effect of water. It is suggested that the difference in seismic activity between various sub-segments is principally caused by the difference in intensity of the fault-weakening effect ofwater of these sub-segments. The Eryuan sub-segment where the reservoir temperatures are high and the hotsprings are dense corresponds to a slipped region, however, the Jianchuan and Midu sub-segments where thereservoir temperatures are lower and the hot springs are fewer as well as the Dan sub-segment where the hotspring are very few all correspond to locked regions. It is suggested that Dan sub-segment is the riskiest region for strong earthquake preparation, while the possibility for strong earthquake preparation is very little inthe Eryuan sub-segment. 展开更多
关键词 northern segment of the Red River Fault SiO_2-geothermometer reservoir temperature of hot Spring weakening effect seismicity potential earthquake source region
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The Relativistic Time-Dependent Aharonov-Bohm Effect
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作者 Athanasios N. Petridis Zachary Kertzman Khinlay Win 《Journal of Modern Physics》 2014年第16期1640-1651,共12页
The relativistic Aharonov-Bohm (AB) effect is studied using the time-dependent Dirac equation. It is shown that if the initial electron distribution is a pulse it is possible to define time-dependent signals that dist... The relativistic Aharonov-Bohm (AB) effect is studied using the time-dependent Dirac equation. It is shown that if the initial electron distribution is a pulse it is possible to define time-dependent signals that distinguish the AB effect from dipole and induced Coulomb interactions. 展开更多
关键词 AHARONOV-BOHM effect DIRAC EQUATION time-dependent Quantum MECHANICS
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The Harmonic Potential Theorem for a Quantum System with Time-Dependent Effective Mass
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作者 赖梦云 肖端亮 潘孝胤 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第11期1-4,共4页
We investigate the many-body wave function of a quantum system with time-dependent effective mass, confined by a harmonic potential with time-dependent frequency, and perturbed by a time-dependent spatially homogeneou... We investigate the many-body wave function of a quantum system with time-dependent effective mass, confined by a harmonic potential with time-dependent frequency, and perturbed by a time-dependent spatially homogeneous electric field. It is found that the wave function is comprised of a phase factor times the solution to the unperturbed time-dependent Schr6dinger equation with the latter being translated by a time-dependent value that satisfies the classical driven equation of motion. The wave function reduces to that of the harmonic potential theorem wave function when both the effective mass and frequency are static. An example of application is also given. 展开更多
关键词 The Harmonic Potential Theorem for a Quantum System with time-dependent effective Mass
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Rashba Effect in Presence of Time-Dependent Interaction
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作者 Hadi Sobhani Hassan Hassanabadi 《Communications in Theoretical Physics》 SCIE CAS CSCD 2016年第5期543-545,共3页
Rashba effect in presence of a time-dependent interaction has been considered.Then time-evolution of such a system has been studied by using Lewis–Riesenfeld dynamical invariant and unitary transformation method.So a... Rashba effect in presence of a time-dependent interaction has been considered.Then time-evolution of such a system has been studied by using Lewis–Riesenfeld dynamical invariant and unitary transformation method.So appropriate dynamical invariant and unitary transformation according the considered system have been constructed as well as some special cases have come into this article which are common in physics. 展开更多
关键词 Rashba effect time-dependent interaction Lewis–Riesenfeld dynamical invariant unitary transformation method
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Evaluation of the weakening behavior of gas on the coal strength and its quantitative influence on the coal deformation 被引量:7
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作者 Haijun Guo Kai Wang +5 位作者 Yuchen Wu Hanlu Tang Jianguo Wu Lianhe Guan Chenyang Chang Chao Xu 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2021年第3期451-462,共12页
The coal strength and deformation properties are key factors affecting safe coal mining and highefficiency coalbed methane(CBM)development.In this paper,reconstituted coal samples are chosen to investigate the weakeni... The coal strength and deformation properties are key factors affecting safe coal mining and highefficiency coalbed methane(CBM)development.In this paper,reconstituted coal samples are chosen to investigate the weakening behavior of gas on coal strength,meanwhile,its effects on coal deformation are quantitatively evaluated.The results indicate that the weakening degree of gas on coal strength is closely related to the confining stress and gas pressure.Compared with non-gas-saturated coals,the maximum weakening ratios of adsorbed gas to coal strength are 10.58%,18.12%,8.55%and 14.65%under the conditions of confining stress CS=3 MPa and gas pressure GP=1 MPa,CS=3 MPa and GP=2 MPa,CS=4 MPa and GP=1 MPa,and CS=4 MPa and GP=2 MPa,respectively.Furthermore,the maximum weakening ratios of free gas to coal strength are 18.27%,36.54%,14.79%and 29.58%,respectively,under above four conditions.The maximum coal bulk strain decreases as particle sizes of coal powders increase,and it has a maximum value of 0.0227 and a minimum value of 0.0191 in particle size ranges of 0.01–0.041 and 0.5–1 mm.Under the same conditions,the coal bulk strain increases with increasing gas pressure,revealing that coal deformation properties can be enhanced by gas. 展开更多
关键词 Gas-saturated coal Coal strength weakening effect Coal deformation Quantitative evaluation Mechanical loading
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Time-dependent behaviors and volumetric recovery phenomenon of sandstone under triaxial loading and unloading 被引量:5
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作者 SONG Zhi-xiang ZHANG Jun-wen +3 位作者 DONG Xu-kai ZHANG Yang ZHANG Yu-jie AN Sai 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第12期4002-4020,共19页
The time-dependent behaviors of coal and rocks were easily ignored. Besides, “three-stage” triaxial loading and unloading mechanics tests of sandstone were conducted based on the idea of the initial high in-situ str... The time-dependent behaviors of coal and rocks were easily ignored. Besides, “three-stage” triaxial loading and unloading mechanics tests of sandstone were conducted based on the idea of the initial high in-situ stress state recovery according to the full-life cycle evolution characteristics of surrounding rocks in deep mines(pre-excavation,excavation and post-excavation). The time-dependent stress-strain curves of sandstone were obtained. Meanwhile, the deformation and strength fitting relationships with time of sandstone were also built. Furthermore, the dilatancy and volumetric recovery mechanical mechanisms of sandstone were revealed. The results showed that: 1) There were significant time-dependent evolution characteristics on the deformation and strength of sandstone;2) There were significant correlations among the internal friction angle, cohesion and the simulated depths;3) Volumetric recovery phenomenon of sandstone was observed for the first time, which mainly occurred at the simulated depth of 2000 m. The above research conclusions could provide a certain theoretical basis for the stability control of surrounding rocks in deep mines. 展开更多
关键词 initial high in-situ stress state SANDSTONE time-dependent behaviors depth effect volumetric recovery
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TIME-DEPENDENT FATIGUE AND ITS MICROMECHANISM OF SUPERALLOY GH169 UNDER OXIDATION
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作者 HE Jinrui LU Younian WANG Qingsui SU Hansheng ZHANG Xueduo WU Mingchang ZHU Qiao Beijing Institute of Aeronautical Materials,Beijing,China P.O.No.81—23,Beijing 100095,China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1990年第5期364-368,共5页
The time-dependent fatigue and its micromechanism of superalloy GH169 at 650℃ have been studied.Under the same stress and duration,its cyclic life in Ar is shorter than that in air.The damage mechanism is mainly of t... The time-dependent fatigue and its micromechanism of superalloy GH169 at 650℃ have been studied.Under the same stress and duration,its cyclic life in Ar is shorter than that in air.The damage mechanism is mainly of the interaction between high temperature oxidation and fa- tigue.The fracture surface of GH169 specimen oxidized at 650℃ in air is revealed to be cov- ered with a dense and even oxide film,but in Ar,with uncontinuous oxide particles.As the time prolonged,the Cr_2O_3 content in the surface oxides increases in air and decreases in Ar. 展开更多
关键词 superalloy GH169 time-dependent fatigue oxidation effect creepfatigue-environment interaction
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ONE-DIMENSIONAL CONSOLIDATION OF LAYERED SOILS WITH IMPEDED BOUNDARIES UNDER TIME-DEPENDENT LOADINGS
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作者 蔡袁强 梁旭 吴世明 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2004年第8期937-944,共8页
On the basis of Terzaghi's one-dimensional consolidation theory, the variation of effective stress ratio in layered saturated soils with impeded boundaries under time-dependent loading was studied. By the method o... On the basis of Terzaghi's one-dimensional consolidation theory, the variation of effective stress ratio in layered saturated soils with impeded boundaries under time-dependent loading was studied. By the method of Laplace transform, the solution was presented. Influences of different kinds of cyclic loadings and impeded boundaries conditions were discussed. Through numerical inversion of Laplace transform, useful illustrations were given considering several common time-dependent loadings. Pervious or impervious boundary condition is just the special case of the problem considered here. Compared with average index method,the results from the method illustrated are more accurate. 展开更多
关键词 one-dimensional consolidation impeded boundary layered soil time-dependent loadling Laplace transform effective stress ratio average index method
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深部岩石水软化效应的多因素模拟实验与评价方法
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作者 杨星宇 刘小玲 +3 位作者 贾哲强 张朝鹏 刘洋 张泽天 《实验室研究与探索》 北大核心 2026年第2期1-8,共8页
为揭示长期地下水作用下深部围岩稳定性的劣化规律,依托自主研发设备模拟深部地下水环境,并通过力学测试,系统分析了含水状态、浸水时间及静水压力对岩石水软化效应的综合影响。结果表明,随岩石从非饱和到饱和的状态转变、浸水时长延长... 为揭示长期地下水作用下深部围岩稳定性的劣化规律,依托自主研发设备模拟深部地下水环境,并通过力学测试,系统分析了含水状态、浸水时间及静水压力对岩石水软化效应的综合影响。结果表明,随岩石从非饱和到饱和的状态转变、浸水时长延长及浸水水压的升高,岩石强度和弹性模量均逐渐下降,并最终趋于稳定阈值。基于试验数据、结合水岩相互作用机理开展系统分析,进一步剥离了压力与时间因素对水软化效应的贡献权重,最终构建了多因素耦合的水软化评估模型。该模型可用于预测不同地下水环境下岩石的软化程度,为深部工程围岩稳定性评价与设计提供理论依据。 展开更多
关键词 深部岩石 水软化 分层实验 高压浸水 预测模型
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Manifestation of external field effect in time-resolved photo-dissociation dynamics of LiF 被引量:1
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作者 孟庆田 A. J. C. Varandas 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第7期140-147,共8页
The photo-dissociation dynamics of LiF is investigated with newly constructed accurate ab initio potential energy curves (PECs) using the time-dependent quantum wave packet method. The oscillations and decay of the ... The photo-dissociation dynamics of LiF is investigated with newly constructed accurate ab initio potential energy curves (PECs) using the time-dependent quantum wave packet method. The oscillations and decay of the wave packet on the adiabats as a function of time are given, which can be compared with the femtosecond transition-state (FTS) spectroscopy. The photo-absorption spectra and the kinetic-energy distribution of the dissociation fragments, which can exhibit the vibration-level structure and the dispersion of the wave packet, respectively, are also obtained. The investigation shows a blue shift of the band center for the photo-absorption spectrum and multiple peaks in the kinetic-energy spectrum with increasing laser intensity, which can be attributed to external field effects. By analyzing the oscillations of the wave packet evolving on the upper adiabat, an approximate inversion scheme is devised to roughly deduce its shape. 展开更多
关键词 photo-dissociation dynamics time-dependent wave packet method photo-absorption spectra external field effect
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Solvent Effect of Water on the UV-B Absorption of Plant Sunscreen Agents
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作者 Min Hu Ke Ye +1 位作者 Jun Jiang Guozhen Zhang 《Chinese Journal of Chemical Physics》 SCIE EI CAS CSCD 2023年第4期453-459,I0006-I0019,I0035,共22页
UV-B(280-320 nm)sunscreening is crucial for lives on Earth.Examining the role of surrounding of UV-B ter understand UV-B absorption.screening molecules can help us better is ubiquitous in cells as the solvent,but its ... UV-B(280-320 nm)sunscreening is crucial for lives on Earth.Examining the role of surrounding of UV-B ter understand UV-B absorption.screening molecules can help us better is ubiquitous in cells as the solvent,but its impacts on UV-B absorption of sunscreen agents are underexplored.Herein,we report a firstprinciple study on UV-B absorption of sinapate malate(SM)and rele vant molecular species,with a focus on the solvent effect of water.The capability of UV-B screening by anions of SM,the proposed species for actual sunscreening,is shaped by water.Both the implicit water providing the dielectric environment of solvation and the explicit water molecules forming hydrogen bonding to SM anion can appreciably alter the nature of transition orbitals responsible to the UV-B absorption of the anion.Finally,we find the molecular dipole moment of an organic UV-B screening agent can be an indicator of its UV-B screening sensitivity to the surrounding water.Our work may serve as a starting point of developing new water-soluble UV-B screening agent. 展开更多
关键词 UV-B Sunscreen agent Solvent effect time-dependent density functional theory
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Effect of Environment on Photo-detachment Dynamics of Halide Ions: A Model Approach
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作者 Bikram Nath Chandan Kumar Mondal 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第1期30-38,I0001,共10页
A two dimensional model approach for the photodetachment dynamics of closed shell an-ionic systems in presence of external light field have been proposed in the context of polar environmental media. The effects of str... A two dimensional model approach for the photodetachment dynamics of closed shell an-ionic systems in presence of external light field have been proposed in the context of polar environmental media. The effects of strong coupling between the solvent polarization and the extra charge in the system were studied by a simple model. The electronic states of con-cerned halide ions are represented by a two dimensional model Hamiltonian with a potential V(x,y)=-V0e^-σ(x^2+y^2). The time dependent Fourier grid Hamiltonian method have been used to follow the detachment process with fairly high intensities of light. The environmental effects on the dynamics are sought to be modeled by two different ways. The first one was the presence of polar solvents which perturb the energy levels of anionic systems by changing the effective potential surface and the second one was allowing the fluctuation of the well depth randomly to mimic the system in a more realistic view point. The average detachment rate constant is calculated as a function of important parameters of the used light field to explain the effects of solvent field on the dynamical behavior of dipole bound anionic system at least in a qualitative way. 展开更多
关键词 Photodetachment dynamics Environmental effect time-dependent Fourier grid Hamiltonian Stochastic deactivation
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Hydrogen Bonding Effects on the Photophysical Properties of 2,3-dihydro-3-keto- 1H-pyrido[3,2,1-kl] phenothiazine
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作者 Song-qiu Yang Guo-zhong He 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2012年第3期254-260,373,共8页
Time-dependent density functional theory (TDDFT) and femtosecond transient absorption spectroscopy were used to investigate the photophysical properties of 2,3-dihydro-3-keto-lH- pyrido[3,2,1-kl]phenothiazine (PTZ4... Time-dependent density functional theory (TDDFT) and femtosecond transient absorption spectroscopy were used to investigate the photophysical properties of 2,3-dihydro-3-keto-lH- pyrido[3,2,1-kl]phenothiazine (PTZ4) and 3-keto-lH-pyrido[3,2,1-kl]phenothiazine (PTZ5). The calculated results obtained from TDDFT suggest that the red-shifts of the absorption spectra of these two fluorophores in methanol are due to the formation of hydrogen-bonded complexes at the ground state. Four conformers of PTZ4 were obtained by TDDFT. The two fluorescence peaks of PTZ4 in tetrahydrofuran (THF) came from the ICT states of the four conformers. The fluorescence of PTZ4 in THF showed a dependence on the excitation wavelength because of butterfly bending. The excited state dynamics of PTZ4 in THF and methanol were obtained by transient absorption spectroscopy. The lifetime of the excited PTZ4 in methanol was 53.8 ps, and its relaxation from the LE state to the ICT state was completed within several picoseconds. The short lifetime of excited PTZ4 in methanol was due to the formation of out-of-plane model hydrogen bonds between PTZ4 and methanol at the excited state. 展开更多
关键词 2 3-dihydro-3-keto-lH-pyrido[3 2 1-kl]phenothiazine time-dependent densityfunctional theory Femtosecond transient absorption spectroscopy Hydrogen bonding effect
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考虑软黏土循环弱化效应的桩基承载力计算方法 被引量:2
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作者 张小玲 张晓伟 许成顺 《岩土工程学报》 北大核心 2025年第7期1365-1372,共8页
在循环荷载的作用下,软黏土的强度与刚度会随着循环荷载的持续作用而降低。目前针对循环荷载作用下软黏土地基中的桩侧荷载传递模型的研究大多基于双曲线模型提出的,模型较为复杂且计算效率低,针对该问题,首先引入一个可以描述软黏土循... 在循环荷载的作用下,软黏土的强度与刚度会随着循环荷载的持续作用而降低。目前针对循环荷载作用下软黏土地基中的桩侧荷载传递模型的研究大多基于双曲线模型提出的,模型较为复杂且计算效率低,针对该问题,首先引入一个可以描述软黏土循环弱化特性的土体力学模型,利用ABAQUS子程序二次开发实现了土体的循环弱化特性并引入到桩土相互作用模型的计算中。同时对传统静力桩侧荷载传递模型进行了改进,提出了一个可考虑软黏土循环弱化效应的桩侧荷载传递三折线模型;然后基于荷载传递法的思路建立了桩基承载力的计算方法,该方法可以考虑软黏土的循环弱化效应;将该方法得到的计算结果与相关文献中的模型试验结果进行对比验证,证明了提出的考虑软黏土循环弱化效应的桩基承载力计算方法的正确性和有效性。最后,在海上风电桩基的实际工程中应用该方法进行桩基极限承载力的计算,并分析了循环次数以及循环荷载水平对极限承载力的影响。 展开更多
关键词 循环弱化效应 桩基承载力 桩土作用模型 三折线模型
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