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Time-dependent ground stability of inclined backfilled stope characterized by creep behavior
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作者 Ruofan Wang Yujie Zhu +3 位作者 Lang Liu Mengbo Zhu Baoxu Yan Hao Cui 《International Journal of Minerals,Metallurgy and Materials》 2026年第2期479-491,共13页
Backfill is routinely adopted as a ground support measure for underground mines.However,ground stability enhancement by backfill has received limited research attention.This is likely to be because of the conventional... Backfill is routinely adopted as a ground support measure for underground mines.However,ground stability enhancement by backfill has received limited research attention.This is likely to be because of the conventional assumption that the fill material exhibits a significantly lower stiffness than the host rocks.Significantly,a recent pioneering work revealed the time-dependent ground stability around a backfilled stope with vertical walls through numerical modeling.In practice,underground stopes typically exhibit a higher or lower degree of inclination.This alters the stress state in peripheral rocks and may induce severe instability and dilution,particularly in stope-hanging walls.Hence,it is imperative to analyze the time-dependent ground stability of inclined backfilled stopes for backfill structure design.Therefore,comprehensive numerical simulations were performed using FLAC3D to address this knowledge deficiency by incorporating a coupled analysis of the backfill consolidation behavior and long-term creep deformation in surrounding rocks.The ground stability was evaluated based on the confinement effectiveness,strength-stress ratio,stress path relative to the yield surface,and time-dependent stress redistribution in the rocks.A parametric study revealed that the inclination angle of the backfilled stope reduced the confinement effectiveness in the host rocks when the wall creep was minor.This exacerbated the rock mass sloughing potential.However,a backfilled stope with a shallower dip angle achieved superior ground stability enhancement when the creep deformation was substantial,by applying a more significant compression on the backfill and effectively mobilizing its passive support performance during consolidation.Additional simulations were conducted to analyze the effects of stope height and width,mine depth,mechanical properties of rocks,backfill compressibility,and filling gap on the time-dependent stress redistribution and stability around the inclined backfilled stope. 展开更多
关键词 inclined backfilled stope ground stability time-dependency creep CONSOLIDATION
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Time-dependent behavior of deep roadway surrounding rock considering damage induced by excavation and mining disturbances:Experiments,modeling,and simulation
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作者 Qingzhe Cui Rongbin Hou +4 位作者 Zhenhua Li Feng Du Xu Chen Boyang Zhang Lielie Li 《International Journal of Mining Science and Technology》 2026年第2期439-456,共18页
In deep coal mining,surrounding rock is subjected to both high in-situ stress and intense mining disturbances,leading to significant time-dependent behavior.Accurately capturing this behavior is essential for predicti... In deep coal mining,surrounding rock is subjected to both high in-situ stress and intense mining disturbances,leading to significant time-dependent behavior.Accurately capturing this behavior is essential for predicting long-term roadway stability,necessitating the development of a reliable constitutive creep model and numerical simulation approach.In this study,creep experiments were conducted on pre-damaged rock with varying initial damage levels to investigate the time-dependent mechanical properties.Based on the experimental results,an accelerated-creep criterion was proposed,and an elastic-viscoplastic creep damage model(EVPCD)was established that simultaneously considers the effects of time-dependent damage and instantaneous damage caused by stress disturbances on rock creep behavior.Subsequently,the effectiveness of the proposed creep model was verified using experimental data,and the secondary development of the EVPCD model was completed based on the FLAC3D platform.Following this,a long-term stability analysis method of deep surrounding rock that accounts for excavation-and mining-induced disturbances was proposed.Using the main roadway of Xutuan Coal Mine as a case study,numerical simulations were carried out to investigate the time-dependent deformation and failure characteristics of the surrounding rock following excavation and mining disturbance.Combined with on-site monitoring of the surrounding rock damage areas,the results indicate that the EVPCD outperforms the CVISC and Nishihara models in predicting the time-dependent behavior of deep surrounding rock. 展开更多
关键词 Initial damage time-dependent damage Creep model Numerical implementation Damage evolution
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Strain localization and time-dependent deformation in granodiorite characterized by distributed optical fiber sensing
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作者 Shuting Miao Arno Zang +3 位作者 Guido Blöcher Yinlin Ji Hannes Hofmann Pengzhi Pan 《Journal of Rock Mechanics and Geotechnical Engineering》 2026年第1期166-178,共13页
A multi-stage stress relaxation test was performed on a granodiorite sample to understand the deformation process prior to the macroscopic failure of brittle rocks,as well as the transient response during stress relax... A multi-stage stress relaxation test was performed on a granodiorite sample to understand the deformation process prior to the macroscopic failure of brittle rocks,as well as the transient response during stress relaxation.Distributed optical fiber sensing was used to measure strains across the sample surface by helically wrapping the single-mode fiber around the cylindrical sample.Close agreement was observed between the circumferential strains obtained from the optical fibers and the extensometer.The reconstructed full-field strain contours show strain heterogeneity from the crack closure phase,and the strains in the later deformation phase are dominantly localized within the former high-strain zone.The Gini coefficient was used to quantify the degree of strain localization and shows an initial increase during the crack closure phase,a decrease during the linear elastic phase,and a subsequent increase during the post-yielding phase.This behavior corresponds to a process of initial localization from an imperfect boundary condition,homogenization,and eventual relocalization prior to the macroscopic failure of the sample.The transient strain rate decay during the stress relaxation phase was quantified using the p-value in the“Omori-like"power law function.A higher initial stress at the onset of relaxation results in a lower p-value,indicating a slower strain rate decay.As the sample approaches macroscopic failure,the lowest p-value shifts from the most damaged zone to adjacent areas,suggesting stress redistribution or crack propagation in deformed crystalline rocks under stress relaxation conditions. 展开更多
关键词 Distributed optical fiber sensing Stress relaxation Strain localization time-dependent deformation
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In-situ stress solution theory for borehole overcoring technique incorporating time-dependent effect of stress relief and its applications
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作者 Daohong Xia Shengjun Miao +5 位作者 Lianjun Chen Yuan Li Zejing Liu Rongmin Zhang Pengjin Yang Pengcheng Li 《International Journal of Mining Science and Technology》 2026年第1期187-203,共17页
In-situ stress is a key parameter for underground mine design and rock stability analysis.The borehole overcoring technique is widely used for in-situ stress measurement,but the rheological recovery deformation of roc... In-situ stress is a key parameter for underground mine design and rock stability analysis.The borehole overcoring technique is widely used for in-situ stress measurement,but the rheological recovery deformation of rocks after stress relief introduces errors.To improve accuracy,this study proposes an in-situ stress solution theory that incorporates time-dependent stress relief effects.Triaxial stepwise loadingunloading rheological tests on granite and siltstone established quantitative relationships between instantaneous elastic recovery and viscoelastic recovery under different stress levels,confirming their impact on measurement accuracy.By integrating a dual-class elastic deformation recovery model,an improved in-situ stress solution theory was derived.Additionally,accounting for the nonlinear characteristics of rock masses,a determination method for time-dependent nonlinear mechanical parameters was proposed.Based on the CSIRO hollow inclusion strain cell,time-dependent strain correction equations and long-term confining pressure calibration equations were formulated.Finally,the proposed theory was successfully applied at one iron mine(736 m depth)in Xinjiang,China,and one coal mine(510 m depth)in Ningxia,China.Compared to classical theory,the calculated mean stress values showed accuracy improvements of 6.0%and 9.4%,respectively,validating the applicability and reliability of the proposed theory. 展开更多
关键词 In-situ stress solution theory Borehole overcoring technique time-dependent effect of stress relief Viscoelastic recovery strain of rock In-situ stress measurement
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A streamline diffusion nonconforming finite element method for the time-dependent linearized Navier-Stokes equations 被引量:1
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作者 陈豫眉 谢小平 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2010年第7期861-874,共14页
A nonconforming finite element method of finite difference streamline diffusion type is proposed to solve the time-dependent linearized Navier-Stokes equations. The backward Euler scheme is used for time discretizatio... A nonconforming finite element method of finite difference streamline diffusion type is proposed to solve the time-dependent linearized Navier-Stokes equations. The backward Euler scheme is used for time discretization. Crouzeix-Raviart nonconforming finite element approximation, namely, nonconforming (P1)2 - P0 element, is used for the velocity and pressure fields with the streamline diffusion technique to cope with usual instabilities caused by the convection and time terms. Stability and error estimates are derived with suitable norms. 展开更多
关键词 streamline diffusion method finite difference method nonconforming finite element method time-dependent linearized Navier-Stokes equations error estimate
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A unique time-dependent deformation behavior of coral reef limestone 被引量:1
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作者 Kai Wu Qingshan Meng +5 位作者 Le Luo Qinglong Qin Chi Wang Xinzhi Wang Tianli Shen Haozhen Ding 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第3期1862-1875,共14页
Catastrophic failure in engineering structures of island reefs would occur when the tertiary creep initiates in coral reef limestone with a transition from short-to long-term load.Due to the complexity of biological s... Catastrophic failure in engineering structures of island reefs would occur when the tertiary creep initiates in coral reef limestone with a transition from short-to long-term load.Due to the complexity of biological structures,the underlying micro-behaviors involving time-dependent deformation are poorly understood.For this,an abnormal phenomenon was observed where the axial and lateral creep deformations were mutually independent by a series of triaxial tests under constant stress and strain rate conditions.The significantly large lateral creep deformation implies that the creep process cannot be described in continuum mechanics regime.Herein,it is hypothesized that sliding mechanism of crystal cleavages dominates the lateral creep deformation in coral reef limestone.Then,approaches of polarizing microscope(PM)and scanning electronic microscope(SEM)are utilized to validate the hypothesis.It shows that the sliding behavior of crystal cleavages combats with conventional creep micro-mechanisms at certain condition.The former is sensitive to time and strain rate,and is merely activated in the creep regime. 展开更多
关键词 Coral reef limestone time-dependent deformation Creep mechanism Constitutive model
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In an Ocean or a River:Bilinear Auto-Backlund Transformations and Similarity Reductions on an Extended Time-Dependent(3+1)-Dimensional Shallow Water Wave Equation 被引量:1
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作者 GAO Xin-yi 《China Ocean Engineering》 2025年第1期160-165,共6页
With respect to oceanic fluid dynamics,certain models have appeared,e.g.,an extended time-dependent(3+1)-dimensional shallow water wave equation in an ocean or a river,which we investigate in this paper.Using symbolic... With respect to oceanic fluid dynamics,certain models have appeared,e.g.,an extended time-dependent(3+1)-dimensional shallow water wave equation in an ocean or a river,which we investigate in this paper.Using symbolic computation,we find out,on one hand,a set of bilinear auto-Backlund transformations,which could connect certain solutions of that equation with other solutions of that equation itself,and on the other hand,a set of similarity reductions,which could go from that equation to a known ordinary differential equation.The results in this paper depend on all the oceanic variable coefficients in that equation. 展开更多
关键词 OCEAN RIVER extended time-dependent(3+1)-dimensional shallow water wave equation bilinear auto-Bäcklund transformation similarity reduction symbolic computation
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Revisiting classical diffusion magnetic resonance methods as a means to measure time-dependent diffusion
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作者 Teddy X.Cai Nathan H.Williamson Peter J.Basser 《Magnetic Resonance Letters》 2025年第4期28-39,共12页
The field of diffusion micro structural magnetic resonance(MR)aims to probe timedependent diffusion,i.e.,an ensemble-averaged mean-squared displacement that is not linear in time.This time-dependence contains rich inf... The field of diffusion micro structural magnetic resonance(MR)aims to probe timedependent diffusion,i.e.,an ensemble-averaged mean-squared displacement that is not linear in time.This time-dependence contains rich information about the surrounding microenvironment.MR methods to measure time-dependent diffusion quantitatively,however,require either non-standard pulse sequences,such as oscillating gradients,or make non-physical assumptions,such as infinitely narrow gradient pulses.Here,we argue that standard spin echo and stimulated echo MR sequences can be used to probe directly.In particular,we propose a framework in which the log-signal ratio obtained from a pair of measurements with different inter-pulse spacingΔis proportional to the MSD between these twoΔvalues along the gradient direction x:-.The framework is quantitative for short,finite-duration gradient pulses and under the Gaussian phase approximation(GPA).To validate the framework,we consider onedimensional diffusion between impermeable,parallel planes,as well as periodicallyspaced,permeable planes.Excellent agreement is obtained between the estimation and the ground truth in the regime where the GPA is expected to hold.Importantly,the GPA can be made to hold for any underlying microstructure,making the proposed framework widely applicable. 展开更多
关键词 DIFFUSION time-dependent Stimulated echo Spin echo RESTRICTION Mean-squared displacement
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Study on the Application and Time-Dependent Effects of Antibiotics in the Treatment of Neonatal Pneumonia
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作者 Zhao Lu 《Asia Pacific Journal of Clinical Medical Research》 2025年第6期5-8,共4页
This article first outlines the fundamental definitions of Mycoplasma pneumoniae and the basic principles of antibiotics. It then analyzes and discusses the progress in antibiotic application and time-eff ect studies ... This article first outlines the fundamental definitions of Mycoplasma pneumoniae and the basic principles of antibiotics. It then analyzes and discusses the progress in antibiotic application and time-eff ect studies for neonatal pneumonia treatment, specifically comparing conventional antibiotic therapy with stepwise treatment regimens, and contrasting monotherapy with penicillin, monotherapy with cephalosporins, and combination therapy. Finally, it offers a prospective outlook on antibiotic application and time-effect research in neonatal pneumonia treatment, aiming to provide valuable reference for further scholarly investigations. 展开更多
关键词 Neonatal Pneumonia ANTIBIOTICS Clinical Application time-dependent Effects Research Progress Future Outlook
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Interfacial thermal contact model for consolidation of multilayered saturated soils subjected to time-dependent heating and loading
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作者 TANG Ke-jie WEN Min-jie +4 位作者 TU Yuan WU Wen-bing XIE Jia-hao LIU Kai-fu WU Da-zhi 《Journal of Central South University》 2025年第6期2239-2255,共17页
Heat transfers at the interface of adjacent saturated soil primarily through the soil particles and the water in the voids.The presence of water induces the contraction of heat flow lines at the interface,leading to t... Heat transfers at the interface of adjacent saturated soil primarily through the soil particles and the water in the voids.The presence of water induces the contraction of heat flow lines at the interface,leading to the emergence of the thermal contact resistance effect.In this paper,four thermal contact models were developed to predict the thermal contact resistance at the interface of multilayered saturated soils.Based on the theory of thermal-hydro-mechanical coupling,semi-analytical solutions of thermal consolidation subjected to time-dependent heating and loading were obtained by employing Laplace transform and its inverse transformation.Thermal consolidation characteristics of multilayered saturated soils under four different thermal contact models were discussed,and the effects of thermal resistance coefficient,partition thermal contact coefficient,and temperature amplitude on the thermal consolidation process were investigated.The outcomes indicate that the general thermal contact model results in the most pronounced thermal gradient at the interface,which can be degenerated to the other three thermal contact models.The perfect thermal contact model overestimates the deformation of the saturated soil during the thermal consolidation.Moreover,the effect of temperature on consolidation properties decreases gradually with increasing interfacial contact thermal resistance. 展开更多
关键词 multilayered saturated soils thermal consolidation thermal contact resistance time-dependent loading Laplace transform
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Geological characteristics of coal mines in the Zagros Basin of Iran:Unveiling rock mechanical properties and time-dependent behavior
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作者 Alireza Khoshmagham Navid Hosseini Alaee +3 位作者 Reza Shirinabadi Amir Hossein Bangian Tabrizi Mehran Gholinejad Pooria Kianoush 《Energy Geoscience》 2025年第1期68-88,共21页
The Zagros Basin in southwestern Iran is a significant source of coal,with numerous coal mines operating in the region.Ensuring the stability of coal mines is crucial for safe and efficient mining operations.This stud... The Zagros Basin in southwestern Iran is a significant source of coal,with numerous coal mines operating in the region.Ensuring the stability of coal mines is crucial for safe and efficient mining operations.This study investigates the time-varying response of rocks and roof resistance in coal mines in the Zagros Mountains using a novel approach that combines numerical simulation,relaxation testing,and rock displacement studies.The results show that rocks exhibit significant time-dependent behavior,with changes in rock mechanical properties over time.A comprehensive viscoelastic-plastic model is devel-oped to accurately describe the time-varying strain-softening response of rocks and simulate laboratory tests.The model integrates the Burgers and strain-softening models,simulating stress relaxation curves and rock displacement over time.The study reveals that the rock mass displays significant nonlinear behavior,with changes in rock mechanical properties over time.The findings of this study highlight the importance of considering the time-varying response of rocks and roof resistance in coal mine stability analysis.The results provide valuable insights into the time-dependent behavior of rock mass in coal mines in Iran,which can inform mining practices and mitigate potential hazards.Results in this study can contribute to developing strategies for improving roof stability and reducing the likelihood of roof collapses. 展开更多
关键词 Coal mine Rock mechanical property time-dependent behavior Stability analysis Viscoelastic-plastic modeling Geological characteristics Zagros Basin
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Local and parallel finite element algorithms for time-dependent convection-diffusion equations
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作者 刘庆芳 侯延仁 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2009年第6期787-794,共8页
Local and parallel finite element algorithms based on two-grid discretization for the time-dependent convection-diffusion equations are presented. These algorithms are motivated by the observation that, for a solution... Local and parallel finite element algorithms based on two-grid discretization for the time-dependent convection-diffusion equations are presented. These algorithms are motivated by the observation that, for a solution to the convection-diffusion problem, low frequency components can be approximated well by a relatively coarse grid and high frequency components can be computed on a fine grid by some local and parallel proce- dures. Hence, these local and parallel algorithms only involve one small original problem on the coarse mesh and some correction problems on the local fine grid. One technical tool for the analysis is the local a priori estimates that are also obtained. Some numerical examples are given to support our theoretical analvsis. 展开更多
关键词 local and parallel algorithms finite element method convection-diffusionequations
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Time-dependent quantum wave packet simulation for strong laser-induced molecular dynamics in multiple electronic states of H_(2) molecules
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作者 Jin-Peng Ma Xiao-Qing Hu +1 位作者 Yong Wu Jian-Guo Wang 《Chinese Physics B》 2025年第10期149-157,共9页
We present a fully time-dependent quantum wave packet evolution method for investigating molecular dynamics in intense laser fields.This approach enables the simultaneous treatment of interactions among multiple elect... We present a fully time-dependent quantum wave packet evolution method for investigating molecular dynamics in intense laser fields.This approach enables the simultaneous treatment of interactions among multiple electronic states while simultaneously tracking their time-dependent electronic,vibrational,and rotational dynamics.As an illustrative example,we consider neutral H_(2)molecules and simulate the laser-induced excitation dynamics of electronic and rotational states in strong laser fields,quantitatively distinguishing the respective contributions of electronic dipole transitions(within the classical-field approximation)and non-resonant Raman processes to the overall molecular dynamics.Furthermore,we precisely evaluate the relative contributions of direct tunneling ionization from the ground state and ionization following electronic excitation in the strong-field ionization of H_(2).The developed methodology shows strong potential for performing high-precision theoretical simulations of electronic-vibrational-rotational state excitations,ionization,and dissociation dynamics in molecules and their ions under intense laser fields. 展开更多
关键词 time-dependent quantum wave packet evolution method laser-induced excitation dynamics electronic dipole transitions non-resonant Raman processes direct tunneling ionization ionization following electronic excitation
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A Robust Direct-Discretized RNN for Time-Dependent Optimization Constrained by Nonlinear Equalities and Its Applications
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作者 Guangfeng Cheng Binbin Qiu +1 位作者 Jinjin Guo Yu Han 《IEEE/CAA Journal of Automatica Sinica》 2025年第9期1866-1877,共12页
In recent years,numerous recurrent neural network(RNN)models have been reported for solving time-dependent nonlinear optimization problems.However,few existing RNN models simultaneously involve nonlinear equality cons... In recent years,numerous recurrent neural network(RNN)models have been reported for solving time-dependent nonlinear optimization problems.However,few existing RNN models simultaneously involve nonlinear equality constraints,direct discretization,and noise suppression.This limitation presents challenges when existing models are applied to practical engineering problems.Additionally,most current discrete-time RNN models are derived from continuous-time models,which may not perform well for solving essentially discrete problems.To handle these issues,a robust direct-discretized RNN(RDD-RNN)model is proposed to efficiently realize time-dependent optimization constrained by nonlinear equalities(TDOCNE)in the presence of various time-dependent noises.Theoretical analyses are provided to reveal that the proposed RDD-RNN model possesses excellent convergence and noise-suppressing capability.Furthermore,numerical experiments and manipulator control instances are conducted and analyzed to validate the superior robustness of the proposed RDD-RNN model under various time-dependent noises,particularly quadratic polynomial noise.Eventually,small target detection experiments further demonstrate the practicality of the RDD-RNN model in image processing applications. 展开更多
关键词 Manipulator control quadratic polynomial noise robust direct-discretized recurrent neural network(RDD-RNN) small target detection time-dependent optimization constrained by nonlinear equalities(TDOCNE)
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Effects of Element Y on Grain Refinement and Mechanical Properties of Cast Al-2.2Li-1.5Cu-Based Alloy
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作者 Wang Xu Dang Qian +3 位作者 Ma Hongyao Liu Guohuai Zhang Chi Wang Zhaodong 《稀有金属材料与工程》 北大核心 2026年第3期602-614,共13页
The effect of trace addition of 0.1wt%Y on the grain refinement and mechanical properties of Al-2.2Li-1.5Cu-0.5Mg-1Zn-0.2Zr-0.2Sc alloys at as-cast and heat-treated states was investigated.Results show that the additi... The effect of trace addition of 0.1wt%Y on the grain refinement and mechanical properties of Al-2.2Li-1.5Cu-0.5Mg-1Zn-0.2Zr-0.2Sc alloys at as-cast and heat-treated states was investigated.Results show that the addition of 0.1wt%Y into the Al-2.2Li-1.5Cu-0.5Mg-1Zn-0.2Zr-0.2Sc alloys can elevate the nucleation temperature of the Al_(3)(Sc,Zr)phase,leading to the preferential precipitation of the Al_(3)(Sc,Zr)phase and increasing the amount of Al_(3)(Sc,Zr)phase in the matrix.Al_(3)(Sc,Zr)phase can also act as a heterogeneous nucleation site in theα-Al matrix to promote nucleation and refine grains.The addition of element Y changes the precipitation phase characteristics at the grain boundaries in the as-cast alloy,which changes the distribution characteristics of secondary phases from initially continuous and coarse strip-like distribution at grain boundaries into the discontinuous dot-like and rod-like distribution.Besides,the size of secondary phases becomes smaller and their amount increases.Under the combined effects of grain refinement strengthening and precipitation strengthening,the Al-2.2Li-1.5Cu-0.5Mg-1Zn-0.2Zr-0.2Sc-0.1Y alloy after 175℃/10 h aging treatment achieves an ultimate tensile strength of 412 MPa and an elongation of 6.3%.Compared with those of the alloy without Y addition,the ultimate tensile strength and elongation of the added alloy increase by 16.1%and 53.7%,respectively. 展开更多
关键词 Al-Li alloy element Y heat treatment grain refinement
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Analysis of DC Aging Characteristics of Stable ZnO Varistors Based on Voronoi Network and Finite Element Simulation Model
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作者 ZHANG Ping LU Mingtai +1 位作者 LU Tiantian YUE Yinghu 《材料导报》 北大核心 2026年第2期20-28,共9页
In modern ZnO varistors,traditional aging mechanisms based on increased power consumption are no longer relevant due to reduced power consumption during DC aging.Prolonged exposure to both AC and DC voltages results i... In modern ZnO varistors,traditional aging mechanisms based on increased power consumption are no longer relevant due to reduced power consumption during DC aging.Prolonged exposure to both AC and DC voltages results in increased leakage current,decreased breakdown voltage,and lower nonlinearity,ultimately compromising their protective performance.To investigate the evolution in electrical properties during DC aging,this work developed a finite element model based on Voronoi networks and conducted accelerated aging tests on commercial varistors.Throughout the aging process,current-voltage characteristics and Schottky barrier parameters were measured and analyzed.The results indicate that when subjected to constant voltage,current flows through regions with larger grain sizes,forming discharge channels.As aging progresses,the current focus increases on these channels,leading to a decline in the varistor’s overall performance.Furthermore,analysis of the Schottky barrier parameters shows that the changes in electrical performance during aging are non-monotonic.These findings offer theoretical support for understanding the aging mechanisms and condition assessment of modern stable ZnO varistors. 展开更多
关键词 ZnO varistors Voronoi network DC aging finite element method(FEM) current distribution double Schottky barrier theory
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Light elements in the Martian core
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作者 Yinfang Yang Shuangmeng Zhai 《Acta Geochimica》 2026年第1期1-14,共14页
The Martian core mainly contains iron,nickel and some light elements.However,controversies remain about the structure and chemical composition of the Martian core due to a lack of samples and marsquake data.Recently,t... The Martian core mainly contains iron,nickel and some light elements.However,controversies remain about the structure and chemical composition of the Martian core due to a lack of samples and marsquake data.Recently,the InSight lander collected long-term marsquake data,which improved the Martian interior structure model.B ased on the preliminary analysis of marsquake data,Mars has a molten liquid core with a radius of around 1700 km.As the Martian core has a smaller density and lower temperature than pure iron at corresponding pressure and temperature conditions,some light elements are introduced to reduce the density and liquidus temperature.With various methods for seismic analysis,in-situ high-pressure and high-temperature experiments,and first-principal calculations,the Martian core composition and evolution models have been updated in the past few years.Here,we review those studies on the light elements in the Martian core from four aspects including(1)high-temperature and high-pressure experiments,(2)marsquake data,(3)mineral physics model with molecular dynamics simulations and(4)cosmochemistry investigation.We discussed the effect of different light elements on the Martian core s density,sound velocity and liquidus temperature.Moreover,the review examines the varieties,abundances and forms of light elements in the Martian core. 展开更多
关键词 Martian core Chemical composition IRON Light elements
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Photocatalyzed hydrogen transfer enabled three-component radical cascade reactions:Direct access to thioesters from primary alcohols,elemental sulfur and alkenes
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作者 Tingting Zhang Jing Zhang 《Chinese Chemical Letters》 2026年第1期253-258,共6页
The development of catalytic multicomponent reactions for constructing complex organic scaffolds from readily accessible commodity chemicals is a key pursuit in contemporary synthetic chemistry.Current methods for syn... The development of catalytic multicomponent reactions for constructing complex organic scaffolds from readily accessible commodity chemicals is a key pursuit in contemporary synthetic chemistry.Current methods for synthesizing thioesters primarily rely on the acylation of thiols,which produces substantial waste and requires malodorous,unstable sulfur sources.In this work,we introduce a photocatalyzed hydrogen transfer strategy that enables a three-component synthesis of thioesters using abundant primary alcohols,easily available alkenes and elemental sulfur under mild conditions.This protocol demonstrates broad applicability and high chemo-and regioselectivity for both primary alcohols and alkenes,highlighting the advantage and potential of photo-mediated hydrogen transfer in facilitating multicomponent reactions using primary alcohol and elemental sulfur feedstocks. 展开更多
关键词 PHOTOCATALYSIS Hydrogen atom transfer Primary alcohol THIOESTER elemental sulfur
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A Full Predictor-Corrector Finite Element Method for the One-Dimensional Heat Equation with Time-Dependent Singularities
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作者 Jake L. Nkeck 《Journal of Applied Mathematics and Physics》 2024年第4期1364-1382,共19页
The energy norm convergence rate of the finite element solution of the heat equation is reduced by the time-regularity of the exact solution. This paper presents an adaptive finite element treatment of time-dependent ... The energy norm convergence rate of the finite element solution of the heat equation is reduced by the time-regularity of the exact solution. This paper presents an adaptive finite element treatment of time-dependent singularities on the one-dimensional heat equation. The method is based on a Fourier decomposition of the solution and an extraction formula of the coefficients of the singularities coupled with a predictor-corrector algorithm. The method recovers the optimal convergence rate of the finite element method on a quasi-uniform mesh refinement. Numerical results are carried out to show the efficiency of the method. 展开更多
关键词 SINGULARITIES Finite element Methods Heat Equation Predictor-Corrector Algorithm
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Effect of trace impurity elements on high-temperature corrosion resistance of DD98M alloy
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作者 Geng-yi DONG Yijiala YILITI +6 位作者 Run-ze YU Jie MENG Wen-jun HAN Kai CHANG Qi-fei ZHANG Xiao-gang YOU Yi-nong WANG 《Transactions of Nonferrous Metals Society of China》 2026年第2期522-537,共16页
The influence of varying levels of impurity elements on the hot corrosion resistance of the DD98M alloy in Na_(2)SO_(4)+NaCl salt at 950℃ was investigated.The results indicate that the corrosion resistance of the DD9... The influence of varying levels of impurity elements on the hot corrosion resistance of the DD98M alloy in Na_(2)SO_(4)+NaCl salt at 950℃ was investigated.The results indicate that the corrosion resistance of the DD98M alloy significantly decreases with an increase in impurity content,and the presence of nitrogen leads to an increase in alloy porosity.These porosities promote the rapid diffusion of molten salt and oxygen into the alloy,resulting in a bilateral diffusion of oxygen and sulfur,which leads to an accumulation of these elements at the oxide−matrix interface.This process contributes to the formation and propagation of interfacial cracks.A growth model was developed for hot corrosion products in alloys with varying impurity elements. 展开更多
关键词 molten salts DD98M alloy hot corrosion impurity element
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