In order to discuss the content distributions and fluxes of heavy metals in suspended matters during a tidal cycle in the turbidity maximum around the Changjiang （Yangtze） Estuary, the contents of heavy metals （Zn,...In order to discuss the content distributions and fluxes of heavy metals in suspended matters during a tidal cycle in the turbidity maximum around the Changjiang （Yangtze） Estuary, the contents of heavy metals （Zn, Pb, Cd, Co and Ni） have been analyzed. During a tidal cycle, the average contents of heavy metals are in the order of Zn〉Ni〉Pb〉Co〉〉Cd. The average contents in ebb tide are generally higher than that in flood tide. However, at the inshore Sta. 11, influenced by the contamination from the nearby waste treatment plant, the average contents of Zn and Ni in flood tide are higher than those in ebb fide and at the offshore Sta. 10, the content of Cd in flood tide higher than that in ebb tide due to marine-derived materials. The five heavy metals, mainly terrigenous, are transported towards east-northeast, and settle down with suspended matters in the area between Sta. 11 and Sta. 10. Influenced by marine-derived materials, the flux value of Cd does not alter significantly with obviously changing in flux direction towards northwest. The source of heavy metals, the salinity of water and the concentration of suspended matters are the main factors controlling the content distributions of heavy metals during a tidal cycle. There is a positive correlation between the contents of heavy metals （Zn, Pb, Co and Ni） and the salinity of water, while the opposite correlation between the contents and the concentrations of suspended matters. Because of marine-derived materials, the content of Cd is not correlated with the concentration of suspended matters and the salinity of water.展开更多
Estuaries are often a significant source of atmospheric CO_(2).However,studies of carbonate systems have predominantly focused on large estuaries,while smaller estuaries have scarcely been documented.In this study,we ...Estuaries are often a significant source of atmospheric CO_(2).However,studies of carbonate systems have predominantly focused on large estuaries,while smaller estuaries have scarcely been documented.In this study,we collected surface and bottom seawater carbonate samples in the subtropical Jiulong River Estuary across different tidal levels from 2019 to 2021.The results showed that estuarine mixing of freshwater from the river with seawater was the dominant factor influencing the estuarine carbonate system.Moreover,estuarine mixing is concomitantly impacted by the net metabolism of biological production and decomposition,groundwater input,release of CO_(2)from the estuary,and precipitation or dissolution of calcium carbonate.The estuarine partial pressure of CO_(2)(pCO_(2))varied from 530μatm to 7715μatm,which represents a strong source of atmospheric CO_(2).The mean annual air-sea CO_(2)flux estimated from three different parameterized equations was approximately(25.63±10.25)mol/(m2·a).Furthermore,the annual emission to the atmosphere was approximately(0.031±0.012)Tg C,which accounts for a mere 0.0077%−0.015%of global estuarine emissions.Dissolved inorganic carbon(DIC),total alkalinity(TA)and the pCO_(2)exhibited high variability throughout the tidal cycle across all cruises.Specifically,the disparities observed between DIC and TA during low and high tides at identical stations during all cruises ranged from approximately 15%to 30%.The variance in the pCO_(2)was even more pronounced,ranging from approximately 30%to 40%.Thus,tidal discrepancies may need to be taken into consideration to estimate the CO_(2)flux from estuarine systems more accurately.展开更多
Tidally induced resuspension processes play an important role in the release of mercury (Hg) into the water column, which increases the risk of Hg exposure to estuarine eco-systems. In order to further understand the ...Tidally induced resuspension processes play an important role in the release of mercury (Hg) into the water column, which increases the risk of Hg exposure to estuarine eco-systems. In order to further understand the geochemical activities of Hg in the intertidal area, the temporal variations of dissolved Hg (Hg D ) and particulate Hg (Hg P ) in the water column during the course of a tidal cycle and its geochemical processes were studied in the southern intertidal zone of the Yangtze Estuary, China. The concentrations of Hg D and Hg P varied between 37-612 ng/L and 51-638 ng/L respectively during the tidal cycle. The increase of Hg D was distinguished at the early flood tide and late ebb tide when the water flow rates were higher. The Hg D concentrations were negatively correlated with Hg P (r = 0.523, p < 0.05) and positively correlated with dissolved organic carbon (DOC) (r = 0.605, p < 0.05) in the bottom water, indicating that the Hg D released from the sediments into the overlying water was associated with the simultaneously released colloidal material in the bottom water. The main pathways for the translocation of Hg from the sediments to the overlying water include the processes of desorption from resuspended particles, advection or diffusion from sediments, and the oxidation of resuspended sulfide. The results of principal components analysis (PCA) and Pearson correlation analysis showed that the combined effects of the total suspended substrate (TSS), DOC, pH and dissolved oxygen (DO) influenced the geochemical activities of Hg in the water column during the course of a tidal cycle.展开更多
Based on experiment in tidal flume, this paper analyzes the sediment rarefactive phenomenon and hydraulic characteristics of sediment resuspension with different physical properties under the effect of tidal current. ...Based on experiment in tidal flume, this paper analyzes the sediment rarefactive phenomenon and hydraulic characteristics of sediment resuspension with different physical properties under the effect of tidal current. According to this experiment, sediment resuspension is related to the hydraulic characteristics of overlying water and its own dry density, namely the moisture content of sediment and deposition time. Generally, river sediment can be classified into the upper layer of floating sludge and lower layer of deposit sediment. Incipient velocity goes higher as the sediment layer goes thicker. Based on the experiment, incipient velocity formula of sediment can be obtained. There is a cohesive force among natural fine sediment whose resuspension is almost irrelevant to their diameters. Therefore, the critical incipient velocity is determined by the cohesive force instead of particle diameter. The lower layer of deposit sediment is generally not so easy to start up. And it will be rarified and release into the overlying water when contacting with overlying water. However, this rarefaction release velocity is gentle and slow. Under the same flow condition, annual loss amount of lower layer deposited sediment is about one fifth of upper layer of floating sediment. Flow velocity of tidal river and variation of the water level are asymmetrical, both of which vary under different tidal cycles. During long tidal cycle, flow velocity and water level change in the same phase and amplitude with tide. During the whole ebb and flow, flow direction does not change as the water level goes under the influence of acceleration and deceleration. As the tide cycle increases, the incipient velocity of sediment goes higher. This means that the long period tide cycle plays buffer effect on the resuspension of sediment, which makes the sediment not so easy both to start up and to suspend.展开更多
The Pechora is the greatest river of the European Russian Arctic,flowing into the Barents Sea.Its estuarine area includes a vast delta,represented by extensive lowlands that are dissected by the complicated network of...The Pechora is the greatest river of the European Russian Arctic,flowing into the Barents Sea.Its estuarine area includes a vast delta,represented by extensive lowlands that are dissected by the complicated network of arms and branches.Despite the Pechora Delta is considered to be microtidal,tides with a range of 0.5-1 m during the low water period have a significant impact on the nature of currents in the main branches and the distribution of runoff among them during the tidal cycle.Tidal sea level fluctuations as well as storm surges determine the reversing pattern of currents over a significant extent of the delta branches.The modern field equipment combined with 2D hydrodynamic modeling has allowed to understand the contemporary flow features and evaluate their possible alterations under climate changes.The climate impact under considered scenarios is more pronounced during the low flow period,and this can lead to the propagation of tidal currents and an increase in water levels in the city of Naryan-Mar(100 km upstream from the mouth).From a flood risk perspective,sea level rise can be offset by a reduction in flood runoff.展开更多
基金The National Natural Science Foundation of China under contract No.41076022the National Basic Research Program(973Program)of China under contract No.2002CB412400
文摘In order to discuss the content distributions and fluxes of heavy metals in suspended matters during a tidal cycle in the turbidity maximum around the Changjiang （Yangtze） Estuary, the contents of heavy metals （Zn, Pb, Cd, Co and Ni） have been analyzed. During a tidal cycle, the average contents of heavy metals are in the order of Zn〉Ni〉Pb〉Co〉〉Cd. The average contents in ebb tide are generally higher than that in flood tide. However, at the inshore Sta. 11, influenced by the contamination from the nearby waste treatment plant, the average contents of Zn and Ni in flood tide are higher than those in ebb fide and at the offshore Sta. 10, the content of Cd in flood tide higher than that in ebb tide due to marine-derived materials. The five heavy metals, mainly terrigenous, are transported towards east-northeast, and settle down with suspended matters in the area between Sta. 11 and Sta. 10. Influenced by marine-derived materials, the flux value of Cd does not alter significantly with obviously changing in flux direction towards northwest. The source of heavy metals, the salinity of water and the concentration of suspended matters are the main factors controlling the content distributions of heavy metals during a tidal cycle. There is a positive correlation between the contents of heavy metals （Zn, Pb, Co and Ni） and the salinity of water, while the opposite correlation between the contents and the concentrations of suspended matters. Because of marine-derived materials, the content of Cd is not correlated with the concentration of suspended matters and the salinity of water.
基金The Scientific Research Foundation of Third Institute of Oceanography,MNR under contract Nos.2022001,2020017,2023008 and 2019018the Natural Science Foundation of Fujian Province of China under contract No.2023J01209+1 种基金the National Natural Science Foundation of China under contract No.4237061213the Fujian Science and Technology Innovation Leader Project.
文摘Estuaries are often a significant source of atmospheric CO_(2).However,studies of carbonate systems have predominantly focused on large estuaries,while smaller estuaries have scarcely been documented.In this study,we collected surface and bottom seawater carbonate samples in the subtropical Jiulong River Estuary across different tidal levels from 2019 to 2021.The results showed that estuarine mixing of freshwater from the river with seawater was the dominant factor influencing the estuarine carbonate system.Moreover,estuarine mixing is concomitantly impacted by the net metabolism of biological production and decomposition,groundwater input,release of CO_(2)from the estuary,and precipitation or dissolution of calcium carbonate.The estuarine partial pressure of CO_(2)(pCO_(2))varied from 530μatm to 7715μatm,which represents a strong source of atmospheric CO_(2).The mean annual air-sea CO_(2)flux estimated from three different parameterized equations was approximately(25.63±10.25)mol/(m2·a).Furthermore,the annual emission to the atmosphere was approximately(0.031±0.012)Tg C,which accounts for a mere 0.0077%−0.015%of global estuarine emissions.Dissolved inorganic carbon(DIC),total alkalinity(TA)and the pCO_(2)exhibited high variability throughout the tidal cycle across all cruises.Specifically,the disparities observed between DIC and TA during low and high tides at identical stations during all cruises ranged from approximately 15%to 30%.The variance in the pCO_(2)was even more pronounced,ranging from approximately 30%to 40%.Thus,tidal discrepancies may need to be taken into consideration to estimate the CO_(2)flux from estuarine systems more accurately.
基金supported by the National Natural Science Foundation of China (40701164, 40971259)the National Key Water Special Project of China (2009ZX07317-006)the Program of Shanghai Subject Chief Scientist (10XD1401600)
文摘Tidally induced resuspension processes play an important role in the release of mercury (Hg) into the water column, which increases the risk of Hg exposure to estuarine eco-systems. In order to further understand the geochemical activities of Hg in the intertidal area, the temporal variations of dissolved Hg (Hg D ) and particulate Hg (Hg P ) in the water column during the course of a tidal cycle and its geochemical processes were studied in the southern intertidal zone of the Yangtze Estuary, China. The concentrations of Hg D and Hg P varied between 37-612 ng/L and 51-638 ng/L respectively during the tidal cycle. The increase of Hg D was distinguished at the early flood tide and late ebb tide when the water flow rates were higher. The Hg D concentrations were negatively correlated with Hg P (r = 0.523, p < 0.05) and positively correlated with dissolved organic carbon (DOC) (r = 0.605, p < 0.05) in the bottom water, indicating that the Hg D released from the sediments into the overlying water was associated with the simultaneously released colloidal material in the bottom water. The main pathways for the translocation of Hg from the sediments to the overlying water include the processes of desorption from resuspended particles, advection or diffusion from sediments, and the oxidation of resuspended sulfide. The results of principal components analysis (PCA) and Pearson correlation analysis showed that the combined effects of the total suspended substrate (TSS), DOC, pH and dissolved oxygen (DO) influenced the geochemical activities of Hg in the water column during the course of a tidal cycle.
基金supported by the National Key Program of National Natural Science Foundation of China(Grant No.11032007)
文摘Based on experiment in tidal flume, this paper analyzes the sediment rarefactive phenomenon and hydraulic characteristics of sediment resuspension with different physical properties under the effect of tidal current. According to this experiment, sediment resuspension is related to the hydraulic characteristics of overlying water and its own dry density, namely the moisture content of sediment and deposition time. Generally, river sediment can be classified into the upper layer of floating sludge and lower layer of deposit sediment. Incipient velocity goes higher as the sediment layer goes thicker. Based on the experiment, incipient velocity formula of sediment can be obtained. There is a cohesive force among natural fine sediment whose resuspension is almost irrelevant to their diameters. Therefore, the critical incipient velocity is determined by the cohesive force instead of particle diameter. The lower layer of deposit sediment is generally not so easy to start up. And it will be rarified and release into the overlying water when contacting with overlying water. However, this rarefaction release velocity is gentle and slow. Under the same flow condition, annual loss amount of lower layer deposited sediment is about one fifth of upper layer of floating sediment. Flow velocity of tidal river and variation of the water level are asymmetrical, both of which vary under different tidal cycles. During long tidal cycle, flow velocity and water level change in the same phase and amplitude with tide. During the whole ebb and flow, flow direction does not change as the water level goes under the influence of acceleration and deceleration. As the tide cycle increases, the incipient velocity of sediment goes higher. This means that the long period tide cycle plays buffer effect on the resuspension of sediment, which makes the sediment not so easy both to start up and to suspend.
基金supported by the Russian Foundation for Basic Research(Projects No.18-05-60021)supported by Governmental Assignments to the Water Problems Institute,Russian Academy of Sciences(FMWZ-2022-0001)+1 种基金Dept.of Hydrology,Faculty of Geography,Lomonosov Moscow State University(I.10)The scenarios of Pechora runoff changes were developed under support of RSF№24-17-00084.
文摘The Pechora is the greatest river of the European Russian Arctic,flowing into the Barents Sea.Its estuarine area includes a vast delta,represented by extensive lowlands that are dissected by the complicated network of arms and branches.Despite the Pechora Delta is considered to be microtidal,tides with a range of 0.5-1 m during the low water period have a significant impact on the nature of currents in the main branches and the distribution of runoff among them during the tidal cycle.Tidal sea level fluctuations as well as storm surges determine the reversing pattern of currents over a significant extent of the delta branches.The modern field equipment combined with 2D hydrodynamic modeling has allowed to understand the contemporary flow features and evaluate their possible alterations under climate changes.The climate impact under considered scenarios is more pronounced during the low flow period,and this can lead to the propagation of tidal currents and an increase in water levels in the city of Naryan-Mar(100 km upstream from the mouth).From a flood risk perspective,sea level rise can be offset by a reduction in flood runoff.
