Sliding mode control(SMC) becomes a common tool in designing robust nonlinear control systems, due to its inherent characteristics such as insensitivity to system uncertainties and fast dynamic response.Two modes are ...Sliding mode control(SMC) becomes a common tool in designing robust nonlinear control systems, due to its inherent characteristics such as insensitivity to system uncertainties and fast dynamic response.Two modes are involved in the SMC operation, namely reaching mode and sliding mode.In the reaching mode, the system state is forced to reach the sliding surface in a finite time.The major drawback of the SMC approach is the occurrence of chattering in the sliding mode, which is undesirable in most applications.Generally, the trade-off between chattering reduction and fast reaching time must be considered in the conventional SMC design.This paper proposes SMC design with a novel reaching law called the exponential rate reaching law(ERRL) to reduce chattering, and the control structure of the converter is designed based on the multiinput SMC that is applied to a three-phase AC/DC power converter.The simulation and experimental results show the effectiveness of the proposed technique.展开更多
Due to the decrease in the number of switches for the four-switch three-phase alternating current-direct current(FSTP AC-DC)converter,it can easily lead to DC-link capacitor voltage imbalance and the system stability ...Due to the decrease in the number of switches for the four-switch three-phase alternating current-direct current(FSTP AC-DC)converter,it can easily lead to DC-link capacitor voltage imbalance and the system stability reduction.In order to solve these problems,a finite control set model predictive control(FCS-MPC)for FSTP AC-DC converters with DC-link capacitor voltage balancing is proposed.In this strategy,in order to facilitate calculation,theαβcoordinate system model is established and all voltage vectors are evaluated by establishing a cost function.During the whole process,phase locked loop(PLL)and complex modulation strategy are not required.In the new established cost function,the additional objective term of suppressing capacitor voltage fluctuation is to eliminate effectively the capacitor voltages oscillations and deviations and improve the system reliability.The simulation results show that the proposed strategy can keep the capacitor voltage balancing and has good dynamic and static performance.展开更多
International standards impose several constraints concerning the electric power quality and require that the harmonic content of the line current of grid connected equipment is below assigned limits; for this reason,...International standards impose several constraints concerning the electric power quality and require that the harmonic content of the line current of grid connected equipment is below assigned limits; for this reason, operating of AC-DC converters with high power factor and low line current distortion has become essential. In this paper, the prototypal realization of a three-phase AC-DC 48 V power electronic converter for telecom system supplying is described and experimental testing results are discussed. The main constraints in the power supply design are the required power density of about 900 W per dm3 as well as the absence of the neutral wire in the supply grid. The carried out investigation is focused on three-level power converter configurations which are considered in order to reduce voltage rating of power switches. As a result of the reduced voltage, low on-resistance metal-oxide-semiconductor field effect transistors can be used in the power stage, solution which allows to achieve improved efficiency as well as increased switching frequency with respect to the insulated gate bipolar transistors based two-level topologies.展开更多
This paper presents an optimal operation method for embedded DC interconnections based on low-voltage AC/DC distribution areas(EDC-LVDA)under three-phase unbalanced compensation conditions.It can optimally determine t...This paper presents an optimal operation method for embedded DC interconnections based on low-voltage AC/DC distribution areas(EDC-LVDA)under three-phase unbalanced compensation conditions.It can optimally determine the transmission power of the DC and AC paths to simultaneously improve voltage quality and reduce losses.First,considering the embedded interconnected,unbalanced power structure of the distribution area,a power flow calculation method for EDC-LVDA that accounts for three-phase unbalanced compensation is introduced.This method accurately describes the power flow distribution characteristics under both AC and DC power allocation scenarios.Second,an optimization scheduling model for EDC-LVDA under three-phase unbalanced conditions is developed,incorporating network losses,voltage quality,DC link losses,and unbalance levels.The proposed model employs an improved particle swarm optimization(IPSO)two-layer algorithm to autonomously select different power allocation coefficients for the DC link and AC section under various operating conditions.This enables embedded economic optimization scheduling while maintaining compensation for unbalanced conditions.Finally,a case study based on the IEEE 13-node system for EDC-LVDA is conducted and tested.The results show that the proposed optimal operation method achieves a 100%voltage compliance rate and reduces network losses by 13.8%,while ensuring three-phase power balance compensation.This provides a practical solution for the modernization and upgrading of low-voltage power grids.展开更多
The transient phenomena of re-oxidation and slag entrapment occurring in the tundish during the ladle change-over process have been proven detrimental to clean steel production.Therefore,an unsteady three-phase turbul...The transient phenomena of re-oxidation and slag entrapment occurring in the tundish during the ladle change-over process have been proven detrimental to clean steel production.Therefore,an unsteady three-phase turbulence model,coupling velocity,temperature,and phase field was established to study the effect of the ladle shroud immersion depth on the slag eye formation,slag entrainment,slag dragging,air dragging,and flow characteristics during the ladle change-over process of a two-strand tundish.The results showed that reducing the immersion depth decreases the high-velocity region area under the slag layer in the quasi-steady process.During the emptying stage,as the molten bath level gradually decreases,the outlet temperature exhibits a trend of initially decreasing and subsequently increasing across all three shroud immersion depths.However,under a 210 mm shroud immersion depth,molten slag and air are dragged into the shroud,forming slag droplets and causing significant fluctuations,with a maximum scalar velocity of 0.0764 m/s at the monitoring point.In the filling stage,air and molten slag are dragged into the molten bath,forming bubbles and slag droplets at an immersion depth of 210 mm.Bubbles are observed within the molten slag layer,which can readily cause an emulsification phenomenon,making it easier to be dragged as slag droplets.Additionally,the slag eye area measured under 210 mm immersion depth at 45 s is 0.303 m^(2),while the maximum scalar velocity of 2.4259 m/s is detected at 12 s.At an immersion depth of 360 mm,the average area of the slag eye is minimized to 0.06268 m2,with corresponding variances of 0.006753,representing the optimal immersion depth.展开更多
A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit....A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit.With the application of two-stage three-phase continuous power supply structure,the electrical characteristics exhibit new features differing from the existing traction system.In this work,the principle for voltage levels determining two-stage network is dissected in accordance with the requirements of traction network and electric locomotive.The equivalent model of three-phase traction system is built for deducing the formula of current distribution and voltage losses.Based on the chain network model of the traction network,a simulation model is established to analyze the electrical characteristics such as traction current distribution,voltage losses,system equivalent impedance,voltage distribution,voltage unbalance and regenerative energy utilization.In a few words,quite a lot traction current of about 99%is undertaken by long-section cable network.The proportion of system voltage losses is small attributed to the two-stage three-phase power supply structure,and the voltage unbal-ance caused by impedance asymmetry of traction network is less than 1‰.In addition,the utilization rate of regenerative energy for locomotive achieves a significant promotion of over 97%.展开更多
In this paper,a wind energy conversion system(WECS)is presented for the electrification of rural areas with wind energy availability.A three-phase AC-DC converter based on a bridgeless Cuk converter is used for power ...In this paper,a wind energy conversion system(WECS)is presented for the electrification of rural areas with wind energy availability.A three-phase AC-DC converter based on a bridgeless Cuk converter is used for power extraction from the permanent magnet synchronous generator(PMSG).The bridgeless topology enables the elimination of the front-end diode bridge rectifier(DBR).Moreover,the converter has fewer components,simple control,and high efficiency,making it suitable for a small-scale WECS.A squirrel cage induction motor(SCIM)is used to emulate a MOD-2 wind turbine to implement the PMSG-based WECS.A direct-drive eight-pole PMSG is used in this study;thus,a low-input-voltage system is designed.The converter is designed to operate in the discontinuous inductor current mode(DICM)for inherent power factor correction(PFC)and the maximum power point tracking(MPPT)is achieved through the tip-speed ratio(TSR)following.The performance of the developed system is analyzed through simulation,and a 500 W hardware prototype is developed and tested in different wind speed conditions.展开更多
For three phase four-wire active power filters （APFs）, several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor （UPF） and instantaneous act...For three phase four-wire active power filters （APFs）, several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor （UPF） and instantaneous active current （IAC） methods are analyzed and compared with each other. The interpretation of active and reactive currents in non-sinusoidal and unbalanced three-phase four-wire systems is given based on the generalized instantaneous reactive power theory. The performance and the characteristic are evaluated, and the application conditions of current reference generation strategies are concluded. Simulation results under different source voltages and loads verify the evaluation result.展开更多
The paper proposes a novel three-phase voltage-fed quasi-Z-source ac-ac converter topology to overcome the shortcomings of the traditional three-phase AC-AC chopper.The quantitative relationship between the output vol...The paper proposes a novel three-phase voltage-fed quasi-Z-source ac-ac converter topology to overcome the shortcomings of the traditional three-phase AC-AC chopper.The quantitative relationship between the output voltage and duty-ratio is deduced by investigating the topology and operating principle.It can provide buck-boost function,and the output voltage of the circuit can keep stable in the case of voltage sagging.Simulation is performed using the MATLAB software,and the experimental circuit is built based on the simulation results,the simulation and experimental results verify the correctness and feasibility of the proposed ac-ac converter topology.展开更多
As an alternative to conventional energy conversion and storage reactions,gas-involved electrochemical reactions,including the carbon dioxide reduction reaction(CO_(2)RR),nitrogen reduction reaction(NRR)and hydrogen e...As an alternative to conventional energy conversion and storage reactions,gas-involved electrochemical reactions,including the carbon dioxide reduction reaction(CO_(2)RR),nitrogen reduction reaction(NRR)and hydrogen evolution reaction(HER),have become an emerging research direction and have gained increasing attention due to their advantages of environmental friendliness and sustainability.Various studies have been designed to accelerate sluggish kinetics but with limited results.Most of them promote the reaction by modulating the intrinsic properties of the catalyst,ignoring the synergistic effect of the reaction as a whole.Due to the introduction of gas,traditional liquid-solid two-phase reactions are no longer applicable to future research.Since gas-involved electrochemical reactions mostly occur at the junctions of gaseous reactants,liquid electrolytes and solid catalysts,the focus of future research on reaction kinetics should gradually shift to three-phase reaction interfaces.In this review,we briefly introduce the formation and constraints of the three-phase interface and propose three criteria to judge its merit,namely,the active site,mass diffusion and electron mass transfer.Subsequently,a series of modulation methods and relevant works are discussed in detail from the three improvement directions of‘exposing more active sites,promoting mass diffusion and accelerating electron transfer’.Definitively,we provide farsighted insights into the understanding and research of three-phase interfaces in the future and point out the possible development direction of future regulatory methods,hoping that this review can broaden the future applications of the three-phase interface,including but not limited to gas-involved electrochemical reactions.展开更多
Half-wavelength AC transmission(HWACT) is an ultra-long distance AC transmission technology, whose electrical distance is close to half-wavelength at the system power frequency. It is very important for the constructi...Half-wavelength AC transmission(HWACT) is an ultra-long distance AC transmission technology, whose electrical distance is close to half-wavelength at the system power frequency. It is very important for the construction and operation of HWACT to analyze its fault features and corresponding protection technology. In this paper, the steady-state voltage and current characteristics of the bus bar and fault point and the steady-state overvoltage distribution along the line will be analyzed when a three-phase symmetrical short-circuit fault occurs on an HWACT line. On this basis, the threephase fault characteristics for longer transmission lines are also studied.展开更多
The present work is concerned with the solution of a problem on thermoelastic interactions in a functional graded material due to thermal shock in the context of the fractional order three-phase lag model. The governi...The present work is concerned with the solution of a problem on thermoelastic interactions in a functional graded material due to thermal shock in the context of the fractional order three-phase lag model. The governing equations of fractional order generalized thermoelasticity with three-phase lag model for functionally graded materials(FGM)(i.e., material with spatially varying material properties) are established. The analytical solution in the transform domain is obtained by using the eigenvalue approach.The inversion of Laplace transform is done numerically. The graphical results indicate that the fractional parameter has significant effects on all the physical quantities. Thus, we can consider the theory of fractional order generalized thermoelasticity an improvement on studying elastic materials.展开更多
A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether （DME） from syngas, considering both the influence of part inert c...A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether （DME） from syngas, considering both the influence of part inert carrier backmixing on transfer and the influence of catalyst grain sedimentation on reaction. On the basis of this model, the influences of the size and reaction conditions of a 100000 t/a DME reactor on capacity were investigated. The optimized size of the 10000 t/a DME synthesis reactor was proposed as follows： diameter 3.2 m, height 20 m, built-in 400 tube heat exchanger （Ф 38×2 mm）, and inert heat carrier paraffin oil 68 t and catalyst 34.46 t. Reaction temperature and pressure were important factors influencing the reaction conversion for different size reactors. Under the condition of uniform catalyst concentration distribution, higher pressure and temperature were proposed to achieve a higher production capacity of DME. The best ratio of fresh syngas for DME synthesis was 2.04.展开更多
The local gas-phase flow characteristics such as local gas holdup(εg), local bubble velocity (V_b) and local bubble mean diameter(d_b) at a specified point in a gas-liquid-solid three-phase reversedflow jet loop reac...The local gas-phase flow characteristics such as local gas holdup(εg), local bubble velocity (V_b) and local bubble mean diameter(d_b) at a specified point in a gas-liquid-solid three-phase reversedflow jet loop reactor was experimentally investigated by a five-pointconductivity probe. The effects of gas jet flow rate, liquid jet flowrate, solid loading, nozzle diameter and axial position on the localεg, V_b and d_b profiles were discussed. The presence of solids atlow solid concentrations not only increased the local εg and V_b,but also decreased the local d_b. The optimum solid loading for themaximum local εg and V_b together with the minimum local d_b was0.16×10^-3 m^3, corresponding to a solid volume fraction ε_S＝2.5/100.展开更多
We investigate the dynamic characteristics of oil-gas-water three-phase flow in terms of chaotic attractor comparison. In particular, we extract a statistic to characterize the dynamical difference in attractor probab...We investigate the dynamic characteristics of oil-gas-water three-phase flow in terms of chaotic attractor comparison. In particular, we extract a statistic to characterize the dynamical difference in attractor probability distribution. We first take time series from Logistic chaotic system with different parameters as examples to demonstrate the effectiveness of the method. Then we use this method to investigate the experimental signals from oil-gas-water three-phase flow. The results indicate that the extracted statistic is very sensitive to the change of flow parameters and can gain a quantitatively insight into the dynamic characteristics of different flow patterns.展开更多
Based on the conductance fluctuation signals measured from vertical upward oil-gas-water three-phase flow experiment, time frequency representation and surrogate data method were used to investigate dynamical characte...Based on the conductance fluctuation signals measured from vertical upward oil-gas-water three-phase flow experiment, time frequency representation and surrogate data method were used to investigate dynamical characteristics of oil-in-water type bubble and slug flows. The results indicate that oil-in-water type bubble flow will turn to deterministic motion with the increase of oil phase fraction f o and superficial gas velocity U sg under fixed flowrate of oil-water mixture Q mix . The dynamics of oil-in-water type slug flow becomes more complex with the increase of U sg under fixed flowrate of oil-water mixture. The change of f o leads to irregular influence on the dynamics of slug flow. These interesting findings suggest that the surrogate data method can be a faithful tool for characterizing dynamic characteristics of oil-in-water type bubble and slug flows.展开更多
文摘Sliding mode control(SMC) becomes a common tool in designing robust nonlinear control systems, due to its inherent characteristics such as insensitivity to system uncertainties and fast dynamic response.Two modes are involved in the SMC operation, namely reaching mode and sliding mode.In the reaching mode, the system state is forced to reach the sliding surface in a finite time.The major drawback of the SMC approach is the occurrence of chattering in the sliding mode, which is undesirable in most applications.Generally, the trade-off between chattering reduction and fast reaching time must be considered in the conventional SMC design.This paper proposes SMC design with a novel reaching law called the exponential rate reaching law(ERRL) to reduce chattering, and the control structure of the converter is designed based on the multiinput SMC that is applied to a three-phase AC/DC power converter.The simulation and experimental results show the effectiveness of the proposed technique.
基金National Natural Science Foundation of China(No.61741508)
文摘Due to the decrease in the number of switches for the four-switch three-phase alternating current-direct current(FSTP AC-DC)converter,it can easily lead to DC-link capacitor voltage imbalance and the system stability reduction.In order to solve these problems,a finite control set model predictive control(FCS-MPC)for FSTP AC-DC converters with DC-link capacitor voltage balancing is proposed.In this strategy,in order to facilitate calculation,theαβcoordinate system model is established and all voltage vectors are evaluated by establishing a cost function.During the whole process,phase locked loop(PLL)and complex modulation strategy are not required.In the new established cost function,the additional objective term of suppressing capacitor voltage fluctuation is to eliminate effectively the capacitor voltages oscillations and deviations and improve the system reliability.The simulation results show that the proposed strategy can keep the capacitor voltage balancing and has good dynamic and static performance.
文摘International standards impose several constraints concerning the electric power quality and require that the harmonic content of the line current of grid connected equipment is below assigned limits; for this reason, operating of AC-DC converters with high power factor and low line current distortion has become essential. In this paper, the prototypal realization of a three-phase AC-DC 48 V power electronic converter for telecom system supplying is described and experimental testing results are discussed. The main constraints in the power supply design are the required power density of about 900 W per dm3 as well as the absence of the neutral wire in the supply grid. The carried out investigation is focused on three-level power converter configurations which are considered in order to reduce voltage rating of power switches. As a result of the reduced voltage, low on-resistance metal-oxide-semiconductor field effect transistors can be used in the power stage, solution which allows to achieve improved efficiency as well as increased switching frequency with respect to the insulated gate bipolar transistors based two-level topologies.
基金supported by the key technology project of China Southern Power Grid Corporation(GZKJXM20220041)partly by the National Key Research and Development Plan(2022YFE0205300).
文摘This paper presents an optimal operation method for embedded DC interconnections based on low-voltage AC/DC distribution areas(EDC-LVDA)under three-phase unbalanced compensation conditions.It can optimally determine the transmission power of the DC and AC paths to simultaneously improve voltage quality and reduce losses.First,considering the embedded interconnected,unbalanced power structure of the distribution area,a power flow calculation method for EDC-LVDA that accounts for three-phase unbalanced compensation is introduced.This method accurately describes the power flow distribution characteristics under both AC and DC power allocation scenarios.Second,an optimization scheduling model for EDC-LVDA under three-phase unbalanced conditions is developed,incorporating network losses,voltage quality,DC link losses,and unbalance levels.The proposed model employs an improved particle swarm optimization(IPSO)two-layer algorithm to autonomously select different power allocation coefficients for the DC link and AC section under various operating conditions.This enables embedded economic optimization scheduling while maintaining compensation for unbalanced conditions.Finally,a case study based on the IEEE 13-node system for EDC-LVDA is conducted and tested.The results show that the proposed optimal operation method achieves a 100%voltage compliance rate and reduces network losses by 13.8%,while ensuring three-phase power balance compensation.This provides a practical solution for the modernization and upgrading of low-voltage power grids.
基金supported by the National Natural Science Foundation of China(Nos.52422408 and 52171031)the Liaoning Xingliao Talents-Top-notch Young Talents Project(No.XLYC2203064)+1 种基金the Excellent Youth Fund of Liaoning Natural Science Foundation(No.2023JH3/10200001)the Fundamental Research Funds for the Central Universities(No.N2425004).
文摘The transient phenomena of re-oxidation and slag entrapment occurring in the tundish during the ladle change-over process have been proven detrimental to clean steel production.Therefore,an unsteady three-phase turbulence model,coupling velocity,temperature,and phase field was established to study the effect of the ladle shroud immersion depth on the slag eye formation,slag entrainment,slag dragging,air dragging,and flow characteristics during the ladle change-over process of a two-strand tundish.The results showed that reducing the immersion depth decreases the high-velocity region area under the slag layer in the quasi-steady process.During the emptying stage,as the molten bath level gradually decreases,the outlet temperature exhibits a trend of initially decreasing and subsequently increasing across all three shroud immersion depths.However,under a 210 mm shroud immersion depth,molten slag and air are dragged into the shroud,forming slag droplets and causing significant fluctuations,with a maximum scalar velocity of 0.0764 m/s at the monitoring point.In the filling stage,air and molten slag are dragged into the molten bath,forming bubbles and slag droplets at an immersion depth of 210 mm.Bubbles are observed within the molten slag layer,which can readily cause an emulsification phenomenon,making it easier to be dragged as slag droplets.Additionally,the slag eye area measured under 210 mm immersion depth at 45 s is 0.303 m^(2),while the maximum scalar velocity of 2.4259 m/s is detected at 12 s.At an immersion depth of 360 mm,the average area of the slag eye is minimized to 0.06268 m2,with corresponding variances of 0.006753,representing the optimal immersion depth.
基金This research was supported by the Science and Technology Plan Project of Sichuan Province(No.21YYJC3324)the Science and Technology Plan Project of Sichuan Province(No.2022YFQ0104).
文摘A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit.With the application of two-stage three-phase continuous power supply structure,the electrical characteristics exhibit new features differing from the existing traction system.In this work,the principle for voltage levels determining two-stage network is dissected in accordance with the requirements of traction network and electric locomotive.The equivalent model of three-phase traction system is built for deducing the formula of current distribution and voltage losses.Based on the chain network model of the traction network,a simulation model is established to analyze the electrical characteristics such as traction current distribution,voltage losses,system equivalent impedance,voltage distribution,voltage unbalance and regenerative energy utilization.In a few words,quite a lot traction current of about 99%is undertaken by long-section cable network.The proportion of system voltage losses is small attributed to the two-stage three-phase power supply structure,and the voltage unbal-ance caused by impedance asymmetry of traction network is less than 1‰.In addition,the utilization rate of regenerative energy for locomotive achieves a significant promotion of over 97%.
基金supported by Science and Engineering Research Board,India under SERB POWER FELLOWSHIP Grant (No.SPF/2021/000071)project Grant (No.EEQ/2021/000057)extended by SERB,India。
文摘In this paper,a wind energy conversion system(WECS)is presented for the electrification of rural areas with wind energy availability.A three-phase AC-DC converter based on a bridgeless Cuk converter is used for power extraction from the permanent magnet synchronous generator(PMSG).The bridgeless topology enables the elimination of the front-end diode bridge rectifier(DBR).Moreover,the converter has fewer components,simple control,and high efficiency,making it suitable for a small-scale WECS.A squirrel cage induction motor(SCIM)is used to emulate a MOD-2 wind turbine to implement the PMSG-based WECS.A direct-drive eight-pole PMSG is used in this study;thus,a low-input-voltage system is designed.The converter is designed to operate in the discontinuous inductor current mode(DICM)for inherent power factor correction(PFC)and the maximum power point tracking(MPPT)is achieved through the tip-speed ratio(TSR)following.The performance of the developed system is analyzed through simulation,and a 500 W hardware prototype is developed and tested in different wind speed conditions.
文摘For three phase four-wire active power filters （APFs）, several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor （UPF） and instantaneous active current （IAC） methods are analyzed and compared with each other. The interpretation of active and reactive currents in non-sinusoidal and unbalanced three-phase four-wire systems is given based on the generalized instantaneous reactive power theory. The performance and the characteristic are evaluated, and the application conditions of current reference generation strategies are concluded. Simulation results under different source voltages and loads verify the evaluation result.
文摘The paper proposes a novel three-phase voltage-fed quasi-Z-source ac-ac converter topology to overcome the shortcomings of the traditional three-phase AC-AC chopper.The quantitative relationship between the output voltage and duty-ratio is deduced by investigating the topology and operating principle.It can provide buck-boost function,and the output voltage of the circuit can keep stable in the case of voltage sagging.Simulation is performed using the MATLAB software,and the experimental circuit is built based on the simulation results,the simulation and experimental results verify the correctness and feasibility of the proposed ac-ac converter topology.
基金supported by the National Natural Science Foundation of China(U21A20332,52103226,52202275,52203314,and 12204253)the Distinguished Young Scholars Fund of Jiangsu Province(BK20220061)the Fellowship of China Postdoctoral Science Foundation(2021 M702382)。
文摘As an alternative to conventional energy conversion and storage reactions,gas-involved electrochemical reactions,including the carbon dioxide reduction reaction(CO_(2)RR),nitrogen reduction reaction(NRR)and hydrogen evolution reaction(HER),have become an emerging research direction and have gained increasing attention due to their advantages of environmental friendliness and sustainability.Various studies have been designed to accelerate sluggish kinetics but with limited results.Most of them promote the reaction by modulating the intrinsic properties of the catalyst,ignoring the synergistic effect of the reaction as a whole.Due to the introduction of gas,traditional liquid-solid two-phase reactions are no longer applicable to future research.Since gas-involved electrochemical reactions mostly occur at the junctions of gaseous reactants,liquid electrolytes and solid catalysts,the focus of future research on reaction kinetics should gradually shift to three-phase reaction interfaces.In this review,we briefly introduce the formation and constraints of the three-phase interface and propose three criteria to judge its merit,namely,the active site,mass diffusion and electron mass transfer.Subsequently,a series of modulation methods and relevant works are discussed in detail from the three improvement directions of‘exposing more active sites,promoting mass diffusion and accelerating electron transfer’.Definitively,we provide farsighted insights into the understanding and research of three-phase interfaces in the future and point out the possible development direction of future regulatory methods,hoping that this review can broaden the future applications of the three-phase interface,including but not limited to gas-involved electrochemical reactions.
基金supported by National Key Research and Development Program of China(2016YFB0900100)
文摘Half-wavelength AC transmission(HWACT) is an ultra-long distance AC transmission technology, whose electrical distance is close to half-wavelength at the system power frequency. It is very important for the construction and operation of HWACT to analyze its fault features and corresponding protection technology. In this paper, the steady-state voltage and current characteristics of the bus bar and fault point and the steady-state overvoltage distribution along the line will be analyzed when a three-phase symmetrical short-circuit fault occurs on an HWACT line. On this basis, the threephase fault characteristics for longer transmission lines are also studied.
文摘The present work is concerned with the solution of a problem on thermoelastic interactions in a functional graded material due to thermal shock in the context of the fractional order three-phase lag model. The governing equations of fractional order generalized thermoelasticity with three-phase lag model for functionally graded materials(FGM)(i.e., material with spatially varying material properties) are established. The analytical solution in the transform domain is obtained by using the eigenvalue approach.The inversion of Laplace transform is done numerically. The graphical results indicate that the fractional parameter has significant effects on all the physical quantities. Thus, we can consider the theory of fractional order generalized thermoelasticity an improvement on studying elastic materials.
基金This work was supported by the National Basic Research Program of China (2005CB221205)
文摘A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether （DME） from syngas, considering both the influence of part inert carrier backmixing on transfer and the influence of catalyst grain sedimentation on reaction. On the basis of this model, the influences of the size and reaction conditions of a 100000 t/a DME reactor on capacity were investigated. The optimized size of the 10000 t/a DME synthesis reactor was proposed as follows： diameter 3.2 m, height 20 m, built-in 400 tube heat exchanger （Ф 38×2 mm）, and inert heat carrier paraffin oil 68 t and catalyst 34.46 t. Reaction temperature and pressure were important factors influencing the reaction conversion for different size reactors. Under the condition of uniform catalyst concentration distribution, higher pressure and temperature were proposed to achieve a higher production capacity of DME. The best ratio of fresh syngas for DME synthesis was 2.04.
基金Supported by the National Natural Science Foundation of China (No. 29706006) and the General Corporation of Petrochemical Engineering of China (No.X598021).
文摘The local gas-phase flow characteristics such as local gas holdup(εg), local bubble velocity (V_b) and local bubble mean diameter(d_b) at a specified point in a gas-liquid-solid three-phase reversedflow jet loop reactor was experimentally investigated by a five-pointconductivity probe. The effects of gas jet flow rate, liquid jet flowrate, solid loading, nozzle diameter and axial position on the localεg, V_b and d_b profiles were discussed. The presence of solids atlow solid concentrations not only increased the local εg and V_b,but also decreased the local d_b. The optimum solid loading for themaximum local εg and V_b together with the minimum local d_b was0.16×10^-3 m^3, corresponding to a solid volume fraction ε_S＝2.5/100.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.41174109 and 61104148)the National Science and Technology Major Project of the Ministry of Science and Technology of China(Grant No.2011ZX05020-006)the Tianjin City High School Science and Technology Fund Planning Project,China(Grant No.20130718)
文摘We investigate the dynamic characteristics of oil-gas-water three-phase flow in terms of chaotic attractor comparison. In particular, we extract a statistic to characterize the dynamical difference in attractor probability distribution. We first take time series from Logistic chaotic system with different parameters as examples to demonstrate the effectiveness of the method. Then we use this method to investigate the experimental signals from oil-gas-water three-phase flow. The results indicate that the extracted statistic is very sensitive to the change of flow parameters and can gain a quantitatively insight into the dynamic characteristics of different flow patterns.
基金Supported by the National Natural Science Foundation of China (50974095, 41174109)Gao Zhongke (高忠科) was also supported by the National Natural Science Foundation of China (61104148)+2 种基金the National Science and Technology Major Projects (2011ZX05020-006)Specialized Research Fund for the Doctoral Program of Higher Education of China(20110032120088)the Independent Innovation Foundation of Tianjin University
文摘Based on the conductance fluctuation signals measured from vertical upward oil-gas-water three-phase flow experiment, time frequency representation and surrogate data method were used to investigate dynamical characteristics of oil-in-water type bubble and slug flows. The results indicate that oil-in-water type bubble flow will turn to deterministic motion with the increase of oil phase fraction f o and superficial gas velocity U sg under fixed flowrate of oil-water mixture Q mix . The dynamics of oil-in-water type slug flow becomes more complex with the increase of U sg under fixed flowrate of oil-water mixture. The change of f o leads to irregular influence on the dynamics of slug flow. These interesting findings suggest that the surrogate data method can be a faithful tool for characterizing dynamic characteristics of oil-in-water type bubble and slug flows.
