A universal thermodynamic model of calculating mass action concentrations for structural units or ion couples in ternary and binary strong electrolyte aqueous solution was developed based on the ion and molecule coexi...A universal thermodynamic model of calculating mass action concentrations for structural units or ion couples in ternary and binary strong electrolyte aqueous solution was developed based on the ion and molecule coexistence theory and verified in four kinds of binary aqueous solutions and two kinds of ternary aqueous solutions. The calculated mass action concentrations of structural units or ion couples in four binary aqueous solutions and two ternary solutions at 298.15 K have good agreement with the reported activity data from literatures after shifting the standard state and concentration unit. Therefore, the calculated mass action concentrations of structural units or ion couples from the developed universal thermodynamic model for ternary and binary aqueous solutions can be applied to predict reaction ability of components in ternary and binary strong electrolyte aqueous solutions. It is also proved that the assumptions applied in the developed thermodynamic model are correct and reasonable, i.e., strong electrolyte aqueous solution is composed of cations and anions as simple ions, H2O as simple molecule and other hydrous salt compounds as complex molecules. The calculated mass action concentrations of structural units or ion couples in ternary and binary strong electrolyte aqueous solutions strictly follow the mass action law.展开更多
The shear failure of intact rock under thermo-mechanical(TM)coupling conditions is common,such as in enhanced geothermal mining and deep mine construction.Under the effect of a continuous engineering disturbance,shear...The shear failure of intact rock under thermo-mechanical(TM)coupling conditions is common,such as in enhanced geothermal mining and deep mine construction.Under the effect of a continuous engineering disturbance,shear-formed fractures are prone to secondary instability,posing a severe threat to deep engineering.Although numerous studies regarding three-dimensional(3D)morphologies of fracture surfaces have been conducted,the understanding of shear-formed fractures under TM coupling conditions is limited.In this study,direct shear tests of intact granite under various TM coupling conditions were conducted,followed by 3D laser scanning tests of shear-formed fractures.Test results demonstrated that the peak shear strength of intact granite is positively correlated with the normal stress,whereas it is negatively correlated with the temperature.The internal friction angle and cohesion of intact granite significantly decrease with an increase in the temperature.The anisotropy,roughness value,and height of the asperities on the fracture surfaces are reduced as the normal stress increases,whereas their variation trends are the opposite as the temperature increases.The macroscopic failure mode of intact granite under TM coupling conditions is dominated by mixed tensileeshear and shear failures.As the normal stress increases,intragranular fractures are developed ranging from a local to a global distribution,and the macroscopic failure mode of intact granite changes from mixed tensileeshear to shear failure.Finally,3D morphological characteristics of the asperities on the shear-formed fracture surfaces were analyzed,and a quadrangular pyramid conceptual model representing these asperities was proposed and sufficiently verified.展开更多
We present an efficient three-dimensional coupled-mode model based on the Fourier synthesis technique. In principle, this model is a one-way model, and hence provides satisfactory accuracy for problems where the forwa...We present an efficient three-dimensional coupled-mode model based on the Fourier synthesis technique. In principle, this model is a one-way model, and hence provides satisfactory accuracy for problems where the forward scattering dominates. At the same time, this model provides an efficiency gain of an order of magnitude or more over two-way coupled-mode models. This model can be applied to three-dimensional range-dependent problems with a slowly varying bathymetry or internal waves. A numerical example of the latter is demonstrated in this work. Comparisons of both accuracy and efficiency between the present model and a benchmark model are also provided.展开更多
Aiming at the fact that the energy and mass exchange phenomena exist between barrel and gas-operated device of the automatic weapon, for describing its interior ballistics and dynamic characteristics of the gas-operat...Aiming at the fact that the energy and mass exchange phenomena exist between barrel and gas-operated device of the automatic weapon, for describing its interior ballistics and dynamic characteristics of the gas-operated device accurately, a new variable-mass thermodynamics model is built. It is used to calculate the automatic mechanism velocity of a certain automatic weapon, the calculation results coincide with the experimental results better, and thus the model is validated. The influences of structure parameters on gas-operated device's dynamic characteristics are discussed. It shows that the model is valuable for design and accurate performance prediction of gas-operated automatic weapon.展开更多
A three-dimensional fluid model is developed to investigate the radio-frequency inductively coupled H2 plasma in a reactor with a rectangular expansion chamber and a cylindrical driver chamber,for neutral beam injecti...A three-dimensional fluid model is developed to investigate the radio-frequency inductively coupled H2 plasma in a reactor with a rectangular expansion chamber and a cylindrical driver chamber,for neutral beam injection system in CFETR.In this model,the electron effective collision frequency and the ion mobility at high E-fields are employed,for accurate simulation of discharges at low pressures(0.3 Pa-2 Pa)and high powers(40 kW-100 kW).The results indicate that when the high E-field ion mobility is taken into account,the electron density is about four times higher than the value in the low E-field case.In addition,the influences of the magnetic field,pressure and power on the electron density and electron temperature are demonstrated.It is found that the electron density and electron temperature in the xz-plane along permanent magnet side become much more asymmetric when magnetic field enhances.However,the plasma parameters in the yz-plane without permanent magnet side are symmetric no matter the magnetic field is applied or not.Besides,the maximum of the electron density first increases and then decreases with magnetic field,while the electron temperature at the bottom of the expansion region first decreases and then almost keeps constant.As the pressure increases from 0.3 Pa to 2 Pa,the electron density becomes higher,with the maximum moving upwards to the driver region,and the symmetry of the electron temperature in the xz-plane becomes much better.As power increases,the electron density rises,whereas the spatial distribution is similar.It can be summarized that the magnetic field and gas pressure have great influence on the symmetry of the plasma parameters,while the power only has little effect.展开更多
Improving plasma uniformity is a critical issue in the development of large-area radio-frequency(RF)inductively coupled plasma(ICP)sources.In this work,the effects of coil structure and electromagnetic shielding on th...Improving plasma uniformity is a critical issue in the development of large-area radio-frequency(RF)inductively coupled plasma(ICP)sources.In this work,the effects of coil structure and electromagnetic shielding on the spatial distribution and uniformity of the plasma are systematically investigated using a three-dimensional fluid model.The model integrates plasma and electromagnetic field modules to simulate the discharge characteristics of a large-area RF ICP source with dimensions of 100 cm×50 cm.The results reveal that the electron density distribution varies significantly with the coil structure.For the rotating and translating coil structures,the electron density is high at off-axis positions and low at the center.In contrast,the mirror coil structure exhibits a significantly higher electron density at the chamber center,resulting in a high-center and low-edge density distribution.Among the three configurations,the rotating coil structure provides the best plasma uniformity.The incorporation of electromagnetic shielding further improves plasma uniformity,particularly for the mirror coil structure.For the rotating and translating coil structures,the electron density exhibits a saddle-shaped distribution regardless of electromagnetic shielding.However,introducing electromagnetic shielding into the mirror coil structure reduces the electron density at the chamber center and decreases the non-uniformity degree by 18.4%.Overall,the mirror coil structure with electromagnetic shielding achieves the highest uniformity,with an exceptional plasma uniformity of 94%.This work offers valuable insights for the design of large-area ICP sources in advanced plasma processing systems.展开更多
One kind of 3D coupled thermo-hydro-mechanical-migratory model for saturated-unsaturated dual-porosity medium was established,in which the stress field and the temperature field are single,but the seepage field and th...One kind of 3D coupled thermo-hydro-mechanical-migratory model for saturated-unsaturated dual-porosity medium was established,in which the stress field and the temperature field are single,but the seepage field and the concentration field are double,and the influences of sets,spaces,angles,continuity ratios,stiffness of fractures on the constitutive relationship of the medium can be considered.The relative three-dimensional program of finite element method was also developed.By comparing with the existing computation example,reliability of the model and the program were verified.Taking a hypothetical nuclear waste repository as a calculation example,the radioactive nuclide leak was simulated numerically with both the rock mass and the buffer being unsaturated media,and the temperatures,negative pore pressures,flow velocities,nuclide concentrations and normal stresses in the rock mass were investigated.The results showed that the temperatures,negative pore pressures and nuclide concentrations in the buffer all present nonlinear changes and distributions that even though the saturation degree in porosity is only about 1/9 of that in fracture,the flow velocity of underground water in fracture is about 6 times of that in porosity because the permeability coefficient of fracture is almost four orders higher than that of porosity,and that the regions of stress concentration occur at the vicinity of two sides of the boundary between buffer and disposal pit wall.展开更多
Microwave-assisted rock-breaking technology,as a novel hybrid approach,is anticipated to facilitate the efficient excavation of complex rock formations.It is therefore crucial to understand the damage and failure mech...Microwave-assisted rock-breaking technology,as a novel hybrid approach,is anticipated to facilitate the efficient excavation of complex rock formations.It is therefore crucial to understand the damage and failure mechanisms of rocks that have been subjected to irradiation.In this study,uniaxial compression experiments were conducted on granite specimens after 1.4 kW microwave irradiation for varying durations.Furthermore,a numerical method was proposed to solve electromagnetic-thermal-mechanical coupling problems by integrating finite and discrete elements.The results demonstrated a differential temperature distribution(high temperature in the middle and low-temperature areas at the ends)in the granite specimens under microwave irradiation,which resulted in a notable reduction in their physical and mechanical properties.As the duration of irradiation increased,the rate of heating and the extent of strength reduction both diminished,while the morphology and distribution of cracks at ultimate failure became increasingly complex.The numerical method effectively addresses the simulation challenges associated with the electromagnetic selective heating of granite containing multiple polar minerals under microwave irradiation.This approach accounted for the non-uniform thermal expansion of the minerals and provided a comprehensive model of damage progression under compression.展开更多
针对现有的研究大多集中在大型浮式液化天然气生产储卸装置(Floating Liquefied Natural Gas System,FLNG)船的运动性能,忽略其液舱超低温对结构强度的影响,参考实际工程船型与在位工况,使用有限元软件搭建液舱的热力耦合模型,采用顺序...针对现有的研究大多集中在大型浮式液化天然气生产储卸装置(Floating Liquefied Natural Gas System,FLNG)船的运动性能,忽略其液舱超低温对结构强度的影响,参考实际工程船型与在位工况,使用有限元软件搭建液舱的热力耦合模型,采用顺序热力耦合方法分析液舱的温度和应力分布。结合挪威船级社(DNV)的相关规定,进一步对液舱的结构强度进行校核。结果显示:超低温温度场会影响液舱的应力分布;考虑超低温及外载荷影响的应力结果满足DNV规范要求。展开更多
基金Project supported by Publication Foundation of National Science and Technology Academic Books of China
文摘A universal thermodynamic model of calculating mass action concentrations for structural units or ion couples in ternary and binary strong electrolyte aqueous solution was developed based on the ion and molecule coexistence theory and verified in four kinds of binary aqueous solutions and two kinds of ternary aqueous solutions. The calculated mass action concentrations of structural units or ion couples in four binary aqueous solutions and two ternary solutions at 298.15 K have good agreement with the reported activity data from literatures after shifting the standard state and concentration unit. Therefore, the calculated mass action concentrations of structural units or ion couples from the developed universal thermodynamic model for ternary and binary aqueous solutions can be applied to predict reaction ability of components in ternary and binary strong electrolyte aqueous solutions. It is also proved that the assumptions applied in the developed thermodynamic model are correct and reasonable, i.e., strong electrolyte aqueous solution is composed of cations and anions as simple ions, H2O as simple molecule and other hydrous salt compounds as complex molecules. The calculated mass action concentrations of structural units or ion couples in ternary and binary strong electrolyte aqueous solutions strictly follow the mass action law.
基金supported by the National Natural Science Foundation of China(Grant No.51974173)the Natural Science Foundation of Shandong Province,China(Grant No.ZR2020QD122).
文摘The shear failure of intact rock under thermo-mechanical(TM)coupling conditions is common,such as in enhanced geothermal mining and deep mine construction.Under the effect of a continuous engineering disturbance,shear-formed fractures are prone to secondary instability,posing a severe threat to deep engineering.Although numerous studies regarding three-dimensional(3D)morphologies of fracture surfaces have been conducted,the understanding of shear-formed fractures under TM coupling conditions is limited.In this study,direct shear tests of intact granite under various TM coupling conditions were conducted,followed by 3D laser scanning tests of shear-formed fractures.Test results demonstrated that the peak shear strength of intact granite is positively correlated with the normal stress,whereas it is negatively correlated with the temperature.The internal friction angle and cohesion of intact granite significantly decrease with an increase in the temperature.The anisotropy,roughness value,and height of the asperities on the fracture surfaces are reduced as the normal stress increases,whereas their variation trends are the opposite as the temperature increases.The macroscopic failure mode of intact granite under TM coupling conditions is dominated by mixed tensileeshear and shear failures.As the normal stress increases,intragranular fractures are developed ranging from a local to a global distribution,and the macroscopic failure mode of intact granite changes from mixed tensileeshear to shear failure.Finally,3D morphological characteristics of the asperities on the shear-formed fracture surfaces were analyzed,and a quadrangular pyramid conceptual model representing these asperities was proposed and sufficiently verified.
基金Supported by the National Natural Science Foundation of China under Grant No 11774374the Natural Science Foundation of Shandong Province of China under Grant No ZR2016AL10
文摘We present an efficient three-dimensional coupled-mode model based on the Fourier synthesis technique. In principle, this model is a one-way model, and hence provides satisfactory accuracy for problems where the forward scattering dominates. At the same time, this model provides an efficiency gain of an order of magnitude or more over two-way coupled-mode models. This model can be applied to three-dimensional range-dependent problems with a slowly varying bathymetry or internal waves. A numerical example of the latter is demonstrated in this work. Comparisons of both accuracy and efficiency between the present model and a benchmark model are also provided.
文摘Aiming at the fact that the energy and mass exchange phenomena exist between barrel and gas-operated device of the automatic weapon, for describing its interior ballistics and dynamic characteristics of the gas-operated device accurately, a new variable-mass thermodynamics model is built. It is used to calculate the automatic mechanism velocity of a certain automatic weapon, the calculation results coincide with the experimental results better, and thus the model is validated. The influences of structure parameters on gas-operated device's dynamic characteristics are discussed. It shows that the model is valuable for design and accurate performance prediction of gas-operated automatic weapon.
基金Project supported by the National Key Research and Development Program of China(Grant No.2017YFE0300106)the National Natural Science Foundation of China(Grant No.12075049)the Fundamental Research Funds for the Central Universities,China(Grant Nos.DUT20LAB201 and DUT21LAB110).
文摘A three-dimensional fluid model is developed to investigate the radio-frequency inductively coupled H2 plasma in a reactor with a rectangular expansion chamber and a cylindrical driver chamber,for neutral beam injection system in CFETR.In this model,the electron effective collision frequency and the ion mobility at high E-fields are employed,for accurate simulation of discharges at low pressures(0.3 Pa-2 Pa)and high powers(40 kW-100 kW).The results indicate that when the high E-field ion mobility is taken into account,the electron density is about four times higher than the value in the low E-field case.In addition,the influences of the magnetic field,pressure and power on the electron density and electron temperature are demonstrated.It is found that the electron density and electron temperature in the xz-plane along permanent magnet side become much more asymmetric when magnetic field enhances.However,the plasma parameters in the yz-plane without permanent magnet side are symmetric no matter the magnetic field is applied or not.Besides,the maximum of the electron density first increases and then decreases with magnetic field,while the electron temperature at the bottom of the expansion region first decreases and then almost keeps constant.As the pressure increases from 0.3 Pa to 2 Pa,the electron density becomes higher,with the maximum moving upwards to the driver region,and the symmetry of the electron temperature in the xz-plane becomes much better.As power increases,the electron density rises,whereas the spatial distribution is similar.It can be summarized that the magnetic field and gas pressure have great influence on the symmetry of the plasma parameters,while the power only has little effect.
基金supported by the National Natural Science Foundation of China(Grant Nos.12075049 and 11935005)。
文摘Improving plasma uniformity is a critical issue in the development of large-area radio-frequency(RF)inductively coupled plasma(ICP)sources.In this work,the effects of coil structure and electromagnetic shielding on the spatial distribution and uniformity of the plasma are systematically investigated using a three-dimensional fluid model.The model integrates plasma and electromagnetic field modules to simulate the discharge characteristics of a large-area RF ICP source with dimensions of 100 cm×50 cm.The results reveal that the electron density distribution varies significantly with the coil structure.For the rotating and translating coil structures,the electron density is high at off-axis positions and low at the center.In contrast,the mirror coil structure exhibits a significantly higher electron density at the chamber center,resulting in a high-center and low-edge density distribution.Among the three configurations,the rotating coil structure provides the best plasma uniformity.The incorporation of electromagnetic shielding further improves plasma uniformity,particularly for the mirror coil structure.For the rotating and translating coil structures,the electron density exhibits a saddle-shaped distribution regardless of electromagnetic shielding.However,introducing electromagnetic shielding into the mirror coil structure reduces the electron density at the chamber center and decreases the non-uniformity degree by 18.4%.Overall,the mirror coil structure with electromagnetic shielding achieves the highest uniformity,with an exceptional plasma uniformity of 94%.This work offers valuable insights for the design of large-area ICP sources in advanced plasma processing systems.
基金supported by the National Key Basic Research and Development Program of China("973"Project)(Grant No.2010CB732101)the Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering(Grant No.SKLQ008)
文摘One kind of 3D coupled thermo-hydro-mechanical-migratory model for saturated-unsaturated dual-porosity medium was established,in which the stress field and the temperature field are single,but the seepage field and the concentration field are double,and the influences of sets,spaces,angles,continuity ratios,stiffness of fractures on the constitutive relationship of the medium can be considered.The relative three-dimensional program of finite element method was also developed.By comparing with the existing computation example,reliability of the model and the program were verified.Taking a hypothetical nuclear waste repository as a calculation example,the radioactive nuclide leak was simulated numerically with both the rock mass and the buffer being unsaturated media,and the temperatures,negative pore pressures,flow velocities,nuclide concentrations and normal stresses in the rock mass were investigated.The results showed that the temperatures,negative pore pressures and nuclide concentrations in the buffer all present nonlinear changes and distributions that even though the saturation degree in porosity is only about 1/9 of that in fracture,the flow velocity of underground water in fracture is about 6 times of that in porosity because the permeability coefficient of fracture is almost four orders higher than that of porosity,and that the regions of stress concentration occur at the vicinity of two sides of the boundary between buffer and disposal pit wall.
基金funded by the Postgraduate Research and Practice Innovation Program of Jiangsu Province(Grant No.KYCX23_2744)the Fundamental Research Funds for the Central Universities(Grant No.2023XSCX051)the Graduate Innovation Program of China University of Mining and Technology(Grant No.2023WLKXJ182).
文摘Microwave-assisted rock-breaking technology,as a novel hybrid approach,is anticipated to facilitate the efficient excavation of complex rock formations.It is therefore crucial to understand the damage and failure mechanisms of rocks that have been subjected to irradiation.In this study,uniaxial compression experiments were conducted on granite specimens after 1.4 kW microwave irradiation for varying durations.Furthermore,a numerical method was proposed to solve electromagnetic-thermal-mechanical coupling problems by integrating finite and discrete elements.The results demonstrated a differential temperature distribution(high temperature in the middle and low-temperature areas at the ends)in the granite specimens under microwave irradiation,which resulted in a notable reduction in their physical and mechanical properties.As the duration of irradiation increased,the rate of heating and the extent of strength reduction both diminished,while the morphology and distribution of cracks at ultimate failure became increasingly complex.The numerical method effectively addresses the simulation challenges associated with the electromagnetic selective heating of granite containing multiple polar minerals under microwave irradiation.This approach accounted for the non-uniform thermal expansion of the minerals and provided a comprehensive model of damage progression under compression.
文摘针对现有的研究大多集中在大型浮式液化天然气生产储卸装置(Floating Liquefied Natural Gas System,FLNG)船的运动性能,忽略其液舱超低温对结构强度的影响,参考实际工程船型与在位工况,使用有限元软件搭建液舱的热力耦合模型,采用顺序热力耦合方法分析液舱的温度和应力分布。结合挪威船级社(DNV)的相关规定,进一步对液舱的结构强度进行校核。结果显示:超低温温度场会影响液舱的应力分布;考虑超低温及外载荷影响的应力结果满足DNV规范要求。
