Innovative S-scheme heterostructures face intrinsic limitations in charge separation due to insufficient interfacial driving forces.This work pioneers a dual-vacancy engineering strategy to break this bottleneck,const...Innovative S-scheme heterostructures face intrinsic limitations in charge separation due to insufficient interfacial driving forces.This work pioneers a dual-vacancy engineering strategy to break this bottleneck,constructing a plasmonic ZnIn_(2)S_(4-x)MoO_(3-x)(ZIS/MO)S-scheme heterojunction where oxygen and sulfur vacancies synergistically reconfigure charge transfer dynamics via dual-path modulation.Uniquely,sulfur vacancies amplify the built-in electric field(IEF)intensity by enlarging the Fermi level gap,while oxygen and sulfur dual-vacancies induce localized surface plasmon resonance(LSPR)via free-carrier concentration enhancement.Simultaneously,sulfur vacancies lower the H^(*)adsorption barrier,and dual vacancies amplify photothermal conversion by promoting nonradiative decay,accelerating temperature elevation and kinetics.Electron dynamics confirm that this dual-vacancy synergy prolongs charge carrier lifetime by a factor of 5.23.Consequently,the optimized sulfur vacancy-rich ZnIn_(2)S_(4-x)/MoO_(3-x)(R-ZIS/MO)exhibits remarkable photocatalytic hydrogen production rates of 3.60 mmol g^(-1) h^(-1)under visible light and 22.74 mmol g^(-1) h^(-1) under full-spectrum irradiation,representing 7.8-fold and17.2-fold enhancements,respectively.This study establishes a new paradigm.Targeted dual-vacancy coordination in plasmonic heterostructures enables unprecedented IEF-LSPR co-modulation,opening avenues for high-efficiency solar energy conversion.展开更多
The continuous extension of human life expectancy and the global trend of population aging have contributed to a marked increase in the incidence of musculoskeletal diseases,with fractures and osteoporosis being promi...The continuous extension of human life expectancy and the global trend of population aging have contributed to a marked increase in the incidence of musculoskeletal diseases,with fractures and osteoporosis being prominent examples.Consequently,promoting bone regeneration is a crucial medical challenge that demands immediate attention.As early as the mid-20th century,researchers revealed that electrical stimulation could effectively promote the healing and regeneration of bone tissue.This is achieved by mimicking the endogenous electric field within bone tissue,which influences cellular behavior and molecular mechanisms.In recent years,electroactive hydrogels responsive to electric field stimulation have been developed and applied to regulate cell functions at different stages of bone regeneration.This paper elaborates on the regulatory effects of electrical stimulation on MSCs,macrophages,and vascular endothelial cells during the process of bone regeneration.It also involves the activation of relevant ion channels and signaling pathways.Subsequently,it comprehensively reviews various electric-field-responsive hydrogels developed in recent years,covering aspects such as material selection,preparation methods,characteristics,and their applications in bone regeneration.Ultimately,it provides an objective summary of the existing deficiencies in hydrogel materials and research,and looks ahead to future development directions.展开更多
Peroxymonosulfate(PMS)-based advanced oxidation processes(AOPs)are an effective way to remove emerging contaminants(ECs)from water.The catalytic process involving PMS is hindered by the suboptimal electron trans-fer e...Peroxymonosulfate(PMS)-based advanced oxidation processes(AOPs)are an effective way to remove emerging contaminants(ECs)from water.The catalytic process involving PMS is hindered by the suboptimal electron trans-fer efficiency of current catalysts,the further application of AOPs technology is limited.Here,it is proposed that the interfacial electric field can be controlled by bor(B)-doped FeNC catalysts,which shows significant advantages in the efficient generation,release and participation of reactive oxygen species(ROS)in the reaction.The super exchange interaction between Fe sites and N and B sites is realized through the directional transfer of electrons in the interfacial electric field,which ensures the high efficiency and stability of the PMS catalytic process.B doping increases the d orbitals distribution at Fermi level,which facilitates enhanced electron transition activity,thereby promoting the effective generation of (1)^O_(2).At the same time,orbital hybridization causes the center of the d band to move to a lower energy level,which not only contributes to the desorption process of (1)^O_(2),but also accelerates its release.In addition,B-doping also improved the adsorption capacity of organic pollutants and shortened the migration distance of ROS,thereby significantly improving the degradation efficiency of ECs.The B-doping strategy outlined offers a novel approach to the development of FeNC catalysts,it lays a theoretical foundation and offers technical insights for the integration of PMS/AOPs technology in the ECs management.展开更多
Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is p...Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.展开更多
As a core functional refractory in the continuous casting process,the service reliability of the submerged entry nozzle(SEN)is directly related to the stability of continuous casting production,the quality of casting ...As a core functional refractory in the continuous casting process,the service reliability of the submerged entry nozzle(SEN)is directly related to the stability of continuous casting production,the quality of casting billets,and production efficiency.Al_(2)O_(3) inclusions clogging constitutes the predominant failure mode of SEN,particularly during continuous casting of high-grade steels.Although several studies in the literature have demonstrated that electric field application can mitigate SEN clogging to some extent,the underlying mechanism remains poorly understood,which hinders its widespread acceptance and practical implementation.The mechanism of preventing SEN clogging by applying a positive electric field was studied,and experimental verification was conducted on it in a certain steel plant.The results indicate that Al_(2)O_(3) inclusions exhibit a positive charge in molten steel under high-temperature(~1600℃)and low-oxygen-partial-pressure(≤20×10-6)conditions.In the continuous casting process at a Chinese steel plant,applying a positive electric field to the SEN effectively suppressed the migration of Al_(2)O_(3) inclusions toward the SEN wall,significantly enhancing its clogging resistance.展开更多
The traditional ground direct current method is not suitable for leakage detection of underground diaphragm walls in foundation pits because of its low accuracy and poor anti-noise ability.Here,we propose a joint surf...The traditional ground direct current method is not suitable for leakage detection of underground diaphragm walls in foundation pits because of its low accuracy and poor anti-noise ability.Here,we propose a joint surface-borehole observation device for leakage electric fi eld detection to achieve rapid measurement of the electric fi eld distribution characteristics at ground level in the foundation pit,thus enabling rapid localization of leakage points.We first establish the mechanism and basic equation of the leakage electric field response by combining the electric field formed by electrokinetic effect(EK)and the stable electric fi eld formed by conduction current in a combined leakage channel.Then,the fi nite–infi nite element coupling method is used to solve the electric fi eld equation to simulate the responses of a three-dimensional foundation pit leakage model.Furthermore,we conduct numerical simulations of diff erent pit models to investigate the infl uencing factors of the detection device and response characteristics of the change in the properties of the leakage channel.The results demonstrate that the proposed joint surface-borehole observation device can effi ciently reveal anomalous potential caused by leakage,and the amplitude of the electric fi eld generated by EK can eff ectively strengthen the leakage electric fi eld signal at the leakage,thus improving detection accuracy and effi ciency.展开更多
This work is carried out to predict the special distribution of electric field induced by multi-circuit intersecting overhead high-voltage (HV) transmission lines (TLs) within a large range without any expensive and t...This work is carried out to predict the special distribution of electric field induced by multi-circuit intersecting overhead high-voltage (HV) transmission lines (TLs) within a large range without any expensive and time-consuming computation. The two main parts of the presented methodology are 1) setting up a three-dimensional (3D) model to calculate the electric field based on combining ca- tenary equations with charge simulation method and 2) calculating the hybrid electric field excited by multi-circuit intersecting TLs using coordinate transformation and superposition technique. Examples of different TLs configurations, including a 220 kV single-circuit hori- zontally configured TLs, a 500 kV single-circuit triangularly configured TLs and a combination of the 220 kV TLs and the 550 kV TLs, are illustrated to verify the validity of this methodology. A more complicatal configurations, including a 500 kV double-circuit TLs and two 220 kV single-circuit horizontally configured TLs, are also calculated. Conclusions were drawn from the simulation: 1) The presented 3D model outperforms 2D models in describing the electric field distribution generated by practical HV TLs with sag and span. 2) Coordinate trans- formation and superposition technique considerably simplify the electric field computation for multi-circuit TLs configurations, which makes it possible to deal with complex engineering problems. 3) The electric field in the area covered by multiple intersecting overhead TLs is distorted and the hybrid electric field strength in some partial region increases so sharply that it might exceed the admissible value. 4) The configuration parameters of the TLs and the spatial configuration of multi-circuit TLs, for instance, the height of TLs, the length of span and the intersection angle of multiple circuits, influence the strength and the distribution of hybrid electric field. The influence regularities sum- marized in this paper can be referred by future TL designs to meet the electromagnetic environmental protection regulations.展开更多
A three-dimensional approach to the effect of magnetic field incidence angle on electrical power and conversion efficiency is performed on a front-illuminated polycrystalline silicon bifacial solar cell. A solution of...A three-dimensional approach to the effect of magnetic field incidence angle on electrical power and conversion efficiency is performed on a front-illuminated polycrystalline silicon bifacial solar cell. A solution of the continuity equation allowed us to present the equations of photocurrent density, photovoltage and electric power. The influence of the angle of incidence of the magnetic field on the photocurrent density, the photovoltage and the electric power has been studied. The curves of electrical power versus dynamic junction velocity were used to extract the values of maximum electrical power and dynamic junction velocity and to calculate those of conversion efficiency. From this study, it is found that the conversion efficiency values increase with the angle of incidence of the magnetic field.展开更多
The rational configuration of built-in electric field(IEF)in heterogeneous materials can significantly optimize the band structure to accelerate the separation of photogenerated charge carriers.However,the strength mo...The rational configuration of built-in electric field(IEF)in heterogeneous materials can significantly optimize the band structure to accelerate the separation of photogenerated charge carriers.However,the strength modulation of IEF formed by various materials has an uncertain enhancing effect on the separation of photogenerated carriers.Herein,a mesoporous MIL-125(Ti)@BiOCl S-scheme heterojunction with controllable IEF is prepared by green photoreduction reaction to investigate the relationship between IEF,microstructure,and photocatalytic activity.Moreover,the corresponding results demonstrate the MIL-125(Ti)@BiOCl effectively regulates the IEF strength through controlling the concentration of ligand defects,thereby optimizing the band structure and improving the efficiency of photogenerated charge separation.The optimized IEF significantly enhances the photocatalytic degradation performance of mesoporous MIL-125(Ti)-3@BiOCl towards tetracycline,with a k value of 0.07 min^(–1),which are approximately 5.5 and 4.7 times greater than that of BiOCl(0.0127 min^(–1))and MIL-125(Ti)-3(0.015 min^(–1)).These findings provide a new pathway for regulating IEF within MOF-based heterojunctions,and offer new insights into the intrinsic correlations between defect structure,IEF,and photocatalytic activity.展开更多
Silicon(Si)anodes,with a theoretical specific capacity of 4200 mAh g^(-1),hold significant promise for the development of high-energy-density lithium-ion batteries(LIBs).However,practical applications are hindered by ...Silicon(Si)anodes,with a theoretical specific capacity of 4200 mAh g^(-1),hold significant promise for the development of high-energy-density lithium-ion batteries(LIBs).However,practical applications are hindered by sluggish charge transfer kinetics,substantial volume expansion,and an unstable solid elec-trolyte interphase during cycling.To address these challenges,we propose a centimeter-scale Si anode design featuring a three-dimensional continuous network structure of Si nanowires(SiNWs)decorated with high-density Ag nanoparticles(Ag-SiNWs-Net)on both the surface and internally.This architecture effectively mitigates mechanical stress from Si volume changes through the high-aspect-ratio wire network.Additionally,the distribution of Ag nanoparticles on the Si induces electronic structure redistribution,generating built-in electric fields that accelerate charge transfer within the Si,significantly enhancing rate performance and cycling stability.The Ag-SiNWs-Net anode achieves a high reversible capacity of 3780.9 mAh g^(-1)at 0.1 A g^(-1),with an initial coulombic efficiency of 85.1%.Moreover,the energy density of full cells assembled with Ag-SiNWs-Net anodes and LiFePO4 cathodes can be pushed further up to 395.8 Wh kg^(-1).This study offers valuable insights and methodologies for the development of high-capacity and practical Si anodes-.展开更多
In photocatalysis field,S-scheme heterojunctions show unique advantages and prospects.However,the carrier shielding effect of heterojunctions limits the separation and migration of interfacial charges.In this study,a ...In photocatalysis field,S-scheme heterojunctions show unique advantages and prospects.However,the carrier shielding effect of heterojunctions limits the separation and migration of interfacial charges.In this study,a strategy of“dynamic cascade electric fields to deplete unilaterally accumulated charges”was innovatively proposed to overcome this drawback.By modulating g-C_(3)N_(4)(CN)and Bi_(2)WO_(6)(BWO)using the polarized electric field(PEF)of spontaneously polarized ceramic(SPC),a BWO/SPC-CN composite with cascade internal electric field(IEF)and PEF was successfully constructed for efficient piezophotocatalytic degradation of recalcitrant pollutants.BWO/SPC-CN contributed to 96.8% degradation of carbamazepine,significantly surpassing BWO/CN(70.5%).BWO/SPC-CN performed excellent capacity of harvesting piezoelectric energy due to its unique three-dimensional porous nano-network structure.The PEF of SPC modulated the electronic band structure and thus strengthened the IEF of BWO/SPC-CN,providing a persistent driving force for interfacial charge migration.Moreover,SPC with a strong PEF unilaterally consumed the charges accumulated on CN under periodic piezoelectricity,weakening the shielding electric field to inhibit the recombination of electron-hole pairs.As a consequence,the dynamic cascade PEF-IEF ultimately broke the carrier shielding effect in heterojunction photocatalysis and enhanced interfacial electron transfer.This work provides reliable methods to enhance the interfacial charge transfer in heterojunction and new insights into piezo-photocatalytic mechanism.展开更多
Bifunctional Ir catalysts for proton exchange membrane(PEM)water electrolysis offer transformative potential by streamlining electrolyzer while achieving efficient performance remains challenging due to the distinct c...Bifunctional Ir catalysts for proton exchange membrane(PEM)water electrolysis offer transformative potential by streamlining electrolyzer while achieving efficient performance remains challenging due to the distinct conditions required for oxygen and hydrogen evolution reaction(OER and HER).Herein,we propose a theory-directed design of Ir-based bifunctional catalysts,Ir nanoparticles supported on mesoporous carbon spheres embedded with MoSe_(2)(Ir/MoSe_(2)@MCS),leveraging a work function(WF)-induced spontaneous built-in electric field to enhance catalytic performance.They demonstrate exceptional kinetics for both OER and HER,and potential application in the practical PEM electrolyzer,showcasing the effectiveness of this innovative approach.Low overpotentials of 252 mV for OER and 28 mV for HER to drive 10 mA cm^(-2)were observed,and the PEM electrolyzer showed the current density of 2 A cm^(-2)at 1.87 V and maintained stable activity at 1.65 V for over 30 h to deliver 1 A cm^(-2).Density functional theory calculations reveal that the WF difference at Ir/MoSe_(2)interface induces a spontaneous built-in electric field with asymmetric charge distributions,that modulate the electronic environment and d-band center of Ir promoting bifunctional active phase formation.This significantly lowers reaction barriers for water splitting by balancing intermediate adsorption,endowing the bifunctional activity.展开更多
The difficulty in fabricating a multifaceted composite heterojunction system based on Cd_(x) Zn_(1-x) S limits the enhancement of photocatalytic performance.In the present scrutiny,novel ZnO/Cd_(x) Zn_(1-x) S/CdS com-...The difficulty in fabricating a multifaceted composite heterojunction system based on Cd_(x) Zn_(1-x) S limits the enhancement of photocatalytic performance.In the present scrutiny,novel ZnO/Cd_(x) Zn_(1-x) S/CdS com-posite heterojunctions are successfully prepared by the alkaline dissolution etching method.The internal electric field at the interface of I-type and Z-scheme heterojunction improved the effective charge sepa-ration.The ZC 8 sample exhibits excellent photocatalytic performance and the H2 production efficiency is 15.67 mmol g^(−1) h^(−1) with good stability up to 82.9%in 24-hour cycles.The performance of CH_(4) and CO capacity in the CO_(2) RR process is 3.47μmol g^(−1) h^(−1) and 23.5μmol g^(−1) h^(−1),respectively.The photogener-ated accelerated charge transport is then examined in detail by in situ X-ray photoelectron spectroscopy(ISXPS)and density functional theory(DFT)calculations.This work presents a new idea for the synthe-sis of Cd_(x) Zn_(1-x) S solid-solution-based materials and provides a solid reference for the detailed mechanism regarding the electric field at the heterojunction interface.展开更多
Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field c...Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field coupled with chloride ions(Cl-)fixation strategy in dual single-atom catalysts(DSACs)was proposed,and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte,with a high half-wave potential(E_(1/2))of 0.868 V and a good maximum power density(Pmax)of 182 mW·cm^(−2)in the assembled SZABs,much higher than those of the Pt/C catalyst(E_(1/2):0.846 V;Pmax:150 mW·cm^(−2)).The in-situ characterization and theoretical calculations revealed that the Fe sites have a higher Cl^(−)adsorption affinity than the Co sites,and preferentially adsorbs Cl^(−)in a seawater electrolyte during the ORR process,and thus constructs a low-concentration Cl^(−)local microenvironment through the common-ion exclusion effect,which prevents Cl^(−)adsorption and corrosion in the Co active centers,achieving impressive catalytic stability.In addition,the directional charge movement between Fe and Co atomic pairs establishes a local electric field,optimizing the adsorption energy of Co sites for oxygen-containing intermediates,and further improving the ORR activity.展开更多
We investigate the energy bands,magnetism,and superconductivity of bilayer octagraphene with A-A stackingunder a perpendicular electric field.A tight-binding model is used to analyze the band structure of the system.T...We investigate the energy bands,magnetism,and superconductivity of bilayer octagraphene with A-A stackingunder a perpendicular electric field.A tight-binding model is used to analyze the band structure of the system.The doubling of the unit cell results in each band of the single layer splitting into two.We find that applyinga perpendicular electric field increases the band splitting.As the electric field strength increases,the nestingof the Fermi surface(FS)weakens,eventually disrupting the antiferromagnetic order,and bilayer octagrapheneexhibits superconductivity.Spin fluctuations can induce unconventional superconductivity with s±-wave pairing.Applying a perpendicular electric field to bilayer octagraphene parent weakens the nesting of the FS,ultimatelykilling the spin-density-wave(SDW)ordered state and transitioning it into the superconducting state,whichworks as a doping effect.We use the random-phase approximation approach to obtain the pairing eigenvaluesand pairing symmetries of the perpendicular electric field-tuned bilayer octagraphene in the weak coupling limit.By tuning the strength of the perpendicular electric field,the critical interaction strength for SDW order can bemodified,which in turn may promote the emergence of unconventional superconductivity.展开更多
Einstein aimed to find a unified theoretical model to explain various interactions in nature,and the relationship between gravitational and electric fields was particularly important.For the first time,this paper prov...Einstein aimed to find a unified theoretical model to explain various interactions in nature,and the relationship between gravitational and electric fields was particularly important.For the first time,this paper provides the internal relationship equations of the electric and magnetic fields.Further,the relationship between the magnetic and gravity fields is analyzed,and the relationship equations of the electric,magnetic,and gravity fields are established.On this basis,a general formula for calculating the radius of charged particles is derived.Simultaneously,we also discussed and made predictions on black holes,providing convenience for future research and experimental detection.展开更多
Developing an efficient photocatalyst is the key to realize the practical application of photocatalysis.The S-scheme heterojunction has great potential in photocatalysis due to its unique charge-carrier migration path...Developing an efficient photocatalyst is the key to realize the practical application of photocatalysis.The S-scheme heterojunction has great potential in photocatalysis due to its unique charge-carrier migration pathway,effective light absorption and high redox capacity.However,further enhancing the built-in electric field of the S-scheme,accelerating carrier separation,and achieving higher photocatalytic performance remain unresolved challenges.Herein,based on the continuously adjustable band structure of continuous solid-solution,a novel 0D/2D all solid-solution S-scheme heterojunction with adjustable internal electric field was designed and fabricated by employing a solid-solution of ZnxCd_(1–x)S and Bi_(2)MoyW_(1–y)O_(6)respectively as reduction and oxidation semiconductors.The synergistic optimization of effective light absorption,fast photogenerated carrier separation,and high redox potential leads can be tuned to promote photocatalytic activity.Under visible light,the S-scheme system constructed by Zn_(0.4)Cd_(0.6)S quantum dot(QDs)and Bi_(2)Mo_(0.2)W_(0.8)O_(6)monolayer exhibits a high rate for photocatalytic degradation C_(2)H_(4)(150.6×10^(–3)min^(–1)),which is 16.5 times higher than that of pure Zn_(0.4)Cd_(0.6)S(9.1×10^(–3)min^(–1))and 53.8 times higher than pure Bi_(2)Mo_(0.2)W_(0.8)O_(6)(2.8×10^(–3)min^(–1)).Due to the unique charge-carrier migration pathway,photo-corrosion of Zn_(x)Cd_(1–x)S is further inhibited simultaneously.In-situ irradiation X-ray photoelectron spectroscopy,photoluminescence spectroscopy,time-resolved photoluminescence,transient absorption spectroscopy and electron paramagnetic resonance provide compelling evidence for interfacial charge transfer via S-scheme pathways,while in-situ diffuse reflectance infrared Fourier transform spectroscopy identifies the reaction pathway for C_(2)H_(4)degradation.This novel S-scheme photocatalysts demonstrates excellent performance and potential for the practical application of the fruits and vegetables preservation at room temperatures.展开更多
Efficient selective adsorption and separation using porous frameworks are critical in many industrial processes,where adsorption energy and dynamic diffusion rate are predominant factors governing selectivity.They are...Efficient selective adsorption and separation using porous frameworks are critical in many industrial processes,where adsorption energy and dynamic diffusion rate are predominant factors governing selectivity.They are highly susceptible to framework charge,which plays a significant role in selective adsorption.Currently,ionic porous frameworks can be divided into two types.One of them is composed of a charged backbone and counter ions.The framework with zwitterionic channels is another type.It is composed of regular and alternating arrangements of cationic and anionic building units.Herein,we report a hydrogen-bonded ionic framework(HIF)of{(CN_(3)H_(6))_(2)[Ti(μ_(2)-O)(SO_(4))_(2)]}_nwith 1D channel exhibits unique adsorption selectivity for Ar against N_(2)and CO_(2).Density functional theory(DFT)results suggest that CO_(2)cannot be adsorbed by HIF at the experimental temperature due to a positive adsorption free energy.In addition,due to a relatively large diffusion barrier at 77 K,N_(2)molecules hardly diffuse in HIF channels,while Ar has a negligible diffusion barrier.The unique net positively-charged space in the channel is the key to the unusual phenomena,based on DFT simulations and structural analysis.The findings in this work proposes the new adsorption mechanism and provides unique perspective for special separation applications,such as isotope and noble gasses separations.展开更多
Spiral waves,as a typical self-organized structure with chiral characteristics,are widely found in excitable media such as cardiac tissues,chemical reactions,and neural networks.Based on the Fitz Hugh–Nagumo model,we...Spiral waves,as a typical self-organized structure with chiral characteristics,are widely found in excitable media such as cardiac tissues,chemical reactions,and neural networks.Based on the Fitz Hugh–Nagumo model,we investigated the mechanisms underlying the effects of direct current electric fields(DCEF),alternating current electric fields(ACEF),and polarized electric fields(PEF)on the interaction and annihilation processes of counter-rotating spiral waves.We found that in a direct current electric field,the drift direction of the spiral wave is determined jointly by its chirality and the electric field direction,which allows selective attraction or repulsion.In an alternating current electric field,the annihilation behavior of spiral waves can be influenced by the phase and intensity of the electric field,where a specific range of parameters induces resonance drift and eventual annihilation.On the other hand,the polarized electric field exhibits a more complex modulation capability on spiral waves:the trajectory and annihilation efficiency of spiral waves can be regulated by both the intensity and phase of the polarized electric field.These results reveal the potential feasibility of regulating multichiral spiral waves through multiple electric fields,providing theoretical insight for the control of spiral waves in relevant systems.展开更多
A fatal issue of Zn-based electrochemical energy storage is uneven Zn^(2+)deposition on the Zn metal anode.Unfortunately,the modulation for the inherent electric field,the origin of driving force for ion diffusion,has...A fatal issue of Zn-based electrochemical energy storage is uneven Zn^(2+)deposition on the Zn metal anode.Unfortunately,the modulation for the inherent electric field,the origin of driving force for ion diffusion,has been given insufficient importance.Herein,the redistribution of the surrounding electric field is demonstrated to depend on the permittivity of the surface medium for the first time,where highpermittivity particles can simultaneously enhance vertical components and reduce horizontal components of the electric field through polarization.Consequently,a bacterial cellulose-based separator is proposed by incorporating a high-permittivity surface medium.Cellulose serves as a robust substrate with a rather low thickness to enable homogeneous dispersion of high-permittivity particles on the surface,which can regulate the localized electric field to guide even Zn deposition by inhibiting twodimensional(2D)Zn^(2+)diffusion and suppressing side reactions by repulsing anion migration toward the Zn anode.The separator achieves significantly enhanced Zn anode stability of 2880 h at 1 mA cm^(-2)and a cumulative capacity of 3.5 Ah cm^(-2)at 10 mA cm^(-2).It also enables a long-term lifespan of 50,000 cycles in Zn||AC capacitor and 1000 cycles at a limited negative/positive(N/P)ratio of 3:1.This work provides a new view to stabilize Zn anode by electric field modulation.展开更多
基金supported by the NSF of China(Nos.22579102 and 22405160)the Natural Science Foundation of Hubei Province(2024AFB288)+2 种基金the Natural Science Research Project of Yichang City(Grant A25-3-007)the 111 Project(D20015)the Key Project Foundation of Hubei Three Gorges Laboratory(SC250009)。
文摘Innovative S-scheme heterostructures face intrinsic limitations in charge separation due to insufficient interfacial driving forces.This work pioneers a dual-vacancy engineering strategy to break this bottleneck,constructing a plasmonic ZnIn_(2)S_(4-x)MoO_(3-x)(ZIS/MO)S-scheme heterojunction where oxygen and sulfur vacancies synergistically reconfigure charge transfer dynamics via dual-path modulation.Uniquely,sulfur vacancies amplify the built-in electric field(IEF)intensity by enlarging the Fermi level gap,while oxygen and sulfur dual-vacancies induce localized surface plasmon resonance(LSPR)via free-carrier concentration enhancement.Simultaneously,sulfur vacancies lower the H^(*)adsorption barrier,and dual vacancies amplify photothermal conversion by promoting nonradiative decay,accelerating temperature elevation and kinetics.Electron dynamics confirm that this dual-vacancy synergy prolongs charge carrier lifetime by a factor of 5.23.Consequently,the optimized sulfur vacancy-rich ZnIn_(2)S_(4-x)/MoO_(3-x)(R-ZIS/MO)exhibits remarkable photocatalytic hydrogen production rates of 3.60 mmol g^(-1) h^(-1)under visible light and 22.74 mmol g^(-1) h^(-1) under full-spectrum irradiation,representing 7.8-fold and17.2-fold enhancements,respectively.This study establishes a new paradigm.Targeted dual-vacancy coordination in plasmonic heterostructures enables unprecedented IEF-LSPR co-modulation,opening avenues for high-efficiency solar energy conversion.
基金supported by the National Science Foundation of China(No.82272491)。
文摘The continuous extension of human life expectancy and the global trend of population aging have contributed to a marked increase in the incidence of musculoskeletal diseases,with fractures and osteoporosis being prominent examples.Consequently,promoting bone regeneration is a crucial medical challenge that demands immediate attention.As early as the mid-20th century,researchers revealed that electrical stimulation could effectively promote the healing and regeneration of bone tissue.This is achieved by mimicking the endogenous electric field within bone tissue,which influences cellular behavior and molecular mechanisms.In recent years,electroactive hydrogels responsive to electric field stimulation have been developed and applied to regulate cell functions at different stages of bone regeneration.This paper elaborates on the regulatory effects of electrical stimulation on MSCs,macrophages,and vascular endothelial cells during the process of bone regeneration.It also involves the activation of relevant ion channels and signaling pathways.Subsequently,it comprehensively reviews various electric-field-responsive hydrogels developed in recent years,covering aspects such as material selection,preparation methods,characteristics,and their applications in bone regeneration.Ultimately,it provides an objective summary of the existing deficiencies in hydrogel materials and research,and looks ahead to future development directions.
基金supported by the National Natural Science Foundation of China(No.22278156)the Guangdong Special Support Program Project(No.2021JC060580)+1 种基金the Young Elite Scientists Sponsorship Program by CAST-Doctoral Student Special Plan,the China Scholarship Council Program(No.202406150148)the Natural Science Foundation of Guangdong Province(No.2023A1515011186).
文摘Peroxymonosulfate(PMS)-based advanced oxidation processes(AOPs)are an effective way to remove emerging contaminants(ECs)from water.The catalytic process involving PMS is hindered by the suboptimal electron trans-fer efficiency of current catalysts,the further application of AOPs technology is limited.Here,it is proposed that the interfacial electric field can be controlled by bor(B)-doped FeNC catalysts,which shows significant advantages in the efficient generation,release and participation of reactive oxygen species(ROS)in the reaction.The super exchange interaction between Fe sites and N and B sites is realized through the directional transfer of electrons in the interfacial electric field,which ensures the high efficiency and stability of the PMS catalytic process.B doping increases the d orbitals distribution at Fermi level,which facilitates enhanced electron transition activity,thereby promoting the effective generation of (1)^O_(2).At the same time,orbital hybridization causes the center of the d band to move to a lower energy level,which not only contributes to the desorption process of (1)^O_(2),but also accelerates its release.In addition,B-doping also improved the adsorption capacity of organic pollutants and shortened the migration distance of ROS,thereby significantly improving the degradation efficiency of ECs.The B-doping strategy outlined offers a novel approach to the development of FeNC catalysts,it lays a theoretical foundation and offers technical insights for the integration of PMS/AOPs technology in the ECs management.
基金supported by National Natural Science Foundation of China(No.52025055 and 52275571)Basic Research Operation Fund of China(No.xzy012024024).
文摘Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.
基金supported by the National Outstanding Youth Science Fund Project of National Natural Science Foundation of China(No.52302031)National Natural Science Foundation of China(No.51932008).
文摘As a core functional refractory in the continuous casting process,the service reliability of the submerged entry nozzle(SEN)is directly related to the stability of continuous casting production,the quality of casting billets,and production efficiency.Al_(2)O_(3) inclusions clogging constitutes the predominant failure mode of SEN,particularly during continuous casting of high-grade steels.Although several studies in the literature have demonstrated that electric field application can mitigate SEN clogging to some extent,the underlying mechanism remains poorly understood,which hinders its widespread acceptance and practical implementation.The mechanism of preventing SEN clogging by applying a positive electric field was studied,and experimental verification was conducted on it in a certain steel plant.The results indicate that Al_(2)O_(3) inclusions exhibit a positive charge in molten steel under high-temperature(~1600℃)and low-oxygen-partial-pressure(≤20×10-6)conditions.In the continuous casting process at a Chinese steel plant,applying a positive electric field to the SEN effectively suppressed the migration of Al_(2)O_(3) inclusions toward the SEN wall,significantly enhancing its clogging resistance.
基金partially supported by the National Natural Science Foundation of China (Nos. 41864004 and 41674077)Jiangxi Provincial Academic Leaders (Youth) Training Program (No. 20204BCJL23058)Open Fund from Engineering Research Center for Seismic Disaster Prevention and Engineering Geological Disaster Detection of Jiangxi Province (SDGD202102)。
文摘The traditional ground direct current method is not suitable for leakage detection of underground diaphragm walls in foundation pits because of its low accuracy and poor anti-noise ability.Here,we propose a joint surface-borehole observation device for leakage electric fi eld detection to achieve rapid measurement of the electric fi eld distribution characteristics at ground level in the foundation pit,thus enabling rapid localization of leakage points.We first establish the mechanism and basic equation of the leakage electric field response by combining the electric field formed by electrokinetic effect(EK)and the stable electric fi eld formed by conduction current in a combined leakage channel.Then,the fi nite–infi nite element coupling method is used to solve the electric fi eld equation to simulate the responses of a three-dimensional foundation pit leakage model.Furthermore,we conduct numerical simulations of diff erent pit models to investigate the infl uencing factors of the detection device and response characteristics of the change in the properties of the leakage channel.The results demonstrate that the proposed joint surface-borehole observation device can effi ciently reveal anomalous potential caused by leakage,and the amplitude of the electric fi eld generated by EK can eff ectively strengthen the leakage electric fi eld signal at the leakage,thus improving detection accuracy and effi ciency.
基金Project supported by Scientific Research Foundation of State Key Laboratory of Power Transmission Equipment ＆ System Security and New Technology （2007DA1051271 2204）, Natural Science Foundation of Chongqing Municipality （cstc201 ljjA20009）.
文摘This work is carried out to predict the special distribution of electric field induced by multi-circuit intersecting overhead high-voltage (HV) transmission lines (TLs) within a large range without any expensive and time-consuming computation. The two main parts of the presented methodology are 1) setting up a three-dimensional (3D) model to calculate the electric field based on combining ca- tenary equations with charge simulation method and 2) calculating the hybrid electric field excited by multi-circuit intersecting TLs using coordinate transformation and superposition technique. Examples of different TLs configurations, including a 220 kV single-circuit hori- zontally configured TLs, a 500 kV single-circuit triangularly configured TLs and a combination of the 220 kV TLs and the 550 kV TLs, are illustrated to verify the validity of this methodology. A more complicatal configurations, including a 500 kV double-circuit TLs and two 220 kV single-circuit horizontally configured TLs, are also calculated. Conclusions were drawn from the simulation: 1) The presented 3D model outperforms 2D models in describing the electric field distribution generated by practical HV TLs with sag and span. 2) Coordinate trans- formation and superposition technique considerably simplify the electric field computation for multi-circuit TLs configurations, which makes it possible to deal with complex engineering problems. 3) The electric field in the area covered by multiple intersecting overhead TLs is distorted and the hybrid electric field strength in some partial region increases so sharply that it might exceed the admissible value. 4) The configuration parameters of the TLs and the spatial configuration of multi-circuit TLs, for instance, the height of TLs, the length of span and the intersection angle of multiple circuits, influence the strength and the distribution of hybrid electric field. The influence regularities sum- marized in this paper can be referred by future TL designs to meet the electromagnetic environmental protection regulations.
文摘A three-dimensional approach to the effect of magnetic field incidence angle on electrical power and conversion efficiency is performed on a front-illuminated polycrystalline silicon bifacial solar cell. A solution of the continuity equation allowed us to present the equations of photocurrent density, photovoltage and electric power. The influence of the angle of incidence of the magnetic field on the photocurrent density, the photovoltage and the electric power has been studied. The curves of electrical power versus dynamic junction velocity were used to extract the values of maximum electrical power and dynamic junction velocity and to calculate those of conversion efficiency. From this study, it is found that the conversion efficiency values increase with the angle of incidence of the magnetic field.
文摘The rational configuration of built-in electric field(IEF)in heterogeneous materials can significantly optimize the band structure to accelerate the separation of photogenerated charge carriers.However,the strength modulation of IEF formed by various materials has an uncertain enhancing effect on the separation of photogenerated carriers.Herein,a mesoporous MIL-125(Ti)@BiOCl S-scheme heterojunction with controllable IEF is prepared by green photoreduction reaction to investigate the relationship between IEF,microstructure,and photocatalytic activity.Moreover,the corresponding results demonstrate the MIL-125(Ti)@BiOCl effectively regulates the IEF strength through controlling the concentration of ligand defects,thereby optimizing the band structure and improving the efficiency of photogenerated charge separation.The optimized IEF significantly enhances the photocatalytic degradation performance of mesoporous MIL-125(Ti)-3@BiOCl towards tetracycline,with a k value of 0.07 min^(–1),which are approximately 5.5 and 4.7 times greater than that of BiOCl(0.0127 min^(–1))and MIL-125(Ti)-3(0.015 min^(–1)).These findings provide a new pathway for regulating IEF within MOF-based heterojunctions,and offer new insights into the intrinsic correlations between defect structure,IEF,and photocatalytic activity.
基金supported by the National Natural Science Foundation of China(No.61904130)the Key Research and Development Program of Hubei Province(Nos.2023BAB122,2021BAA063,and 2020BAB084)the Key Laboratory of Coal Conversion and New Carbon Materials in Hubei Province(No.WKDM201907)for their invaluable support.
文摘Silicon(Si)anodes,with a theoretical specific capacity of 4200 mAh g^(-1),hold significant promise for the development of high-energy-density lithium-ion batteries(LIBs).However,practical applications are hindered by sluggish charge transfer kinetics,substantial volume expansion,and an unstable solid elec-trolyte interphase during cycling.To address these challenges,we propose a centimeter-scale Si anode design featuring a three-dimensional continuous network structure of Si nanowires(SiNWs)decorated with high-density Ag nanoparticles(Ag-SiNWs-Net)on both the surface and internally.This architecture effectively mitigates mechanical stress from Si volume changes through the high-aspect-ratio wire network.Additionally,the distribution of Ag nanoparticles on the Si induces electronic structure redistribution,generating built-in electric fields that accelerate charge transfer within the Si,significantly enhancing rate performance and cycling stability.The Ag-SiNWs-Net anode achieves a high reversible capacity of 3780.9 mAh g^(-1)at 0.1 A g^(-1),with an initial coulombic efficiency of 85.1%.Moreover,the energy density of full cells assembled with Ag-SiNWs-Net anodes and LiFePO4 cathodes can be pushed further up to 395.8 Wh kg^(-1).This study offers valuable insights and methodologies for the development of high-capacity and practical Si anodes-.
基金financially supported by the National Natural Science Foundation of China(No.22068007).
文摘In photocatalysis field,S-scheme heterojunctions show unique advantages and prospects.However,the carrier shielding effect of heterojunctions limits the separation and migration of interfacial charges.In this study,a strategy of“dynamic cascade electric fields to deplete unilaterally accumulated charges”was innovatively proposed to overcome this drawback.By modulating g-C_(3)N_(4)(CN)and Bi_(2)WO_(6)(BWO)using the polarized electric field(PEF)of spontaneously polarized ceramic(SPC),a BWO/SPC-CN composite with cascade internal electric field(IEF)and PEF was successfully constructed for efficient piezophotocatalytic degradation of recalcitrant pollutants.BWO/SPC-CN contributed to 96.8% degradation of carbamazepine,significantly surpassing BWO/CN(70.5%).BWO/SPC-CN performed excellent capacity of harvesting piezoelectric energy due to its unique three-dimensional porous nano-network structure.The PEF of SPC modulated the electronic band structure and thus strengthened the IEF of BWO/SPC-CN,providing a persistent driving force for interfacial charge migration.Moreover,SPC with a strong PEF unilaterally consumed the charges accumulated on CN under periodic piezoelectricity,weakening the shielding electric field to inhibit the recombination of electron-hole pairs.As a consequence,the dynamic cascade PEF-IEF ultimately broke the carrier shielding effect in heterojunction photocatalysis and enhanced interfacial electron transfer.This work provides reliable methods to enhance the interfacial charge transfer in heterojunction and new insights into piezo-photocatalytic mechanism.
文摘Bifunctional Ir catalysts for proton exchange membrane(PEM)water electrolysis offer transformative potential by streamlining electrolyzer while achieving efficient performance remains challenging due to the distinct conditions required for oxygen and hydrogen evolution reaction(OER and HER).Herein,we propose a theory-directed design of Ir-based bifunctional catalysts,Ir nanoparticles supported on mesoporous carbon spheres embedded with MoSe_(2)(Ir/MoSe_(2)@MCS),leveraging a work function(WF)-induced spontaneous built-in electric field to enhance catalytic performance.They demonstrate exceptional kinetics for both OER and HER,and potential application in the practical PEM electrolyzer,showcasing the effectiveness of this innovative approach.Low overpotentials of 252 mV for OER and 28 mV for HER to drive 10 mA cm^(-2)were observed,and the PEM electrolyzer showed the current density of 2 A cm^(-2)at 1.87 V and maintained stable activity at 1.65 V for over 30 h to deliver 1 A cm^(-2).Density functional theory calculations reveal that the WF difference at Ir/MoSe_(2)interface induces a spontaneous built-in electric field with asymmetric charge distributions,that modulate the electronic environment and d-band center of Ir promoting bifunctional active phase formation.This significantly lowers reaction barriers for water splitting by balancing intermediate adsorption,endowing the bifunctional activity.
基金financially supported by the National Key Re-search and Development Program of China[No.2022YFF1202500,2022YFF1202502]the National Natural Science Foundation of China[62071459]+1 种基金the Subject arrangement Foundation of Shen-zhen[No.JCYJ20180507182057026]the International Science and Technology Cooperation Project of Bingtuan[No.2022BC008]。
文摘The difficulty in fabricating a multifaceted composite heterojunction system based on Cd_(x) Zn_(1-x) S limits the enhancement of photocatalytic performance.In the present scrutiny,novel ZnO/Cd_(x) Zn_(1-x) S/CdS com-posite heterojunctions are successfully prepared by the alkaline dissolution etching method.The internal electric field at the interface of I-type and Z-scheme heterojunction improved the effective charge sepa-ration.The ZC 8 sample exhibits excellent photocatalytic performance and the H2 production efficiency is 15.67 mmol g^(−1) h^(−1) with good stability up to 82.9%in 24-hour cycles.The performance of CH_(4) and CO capacity in the CO_(2) RR process is 3.47μmol g^(−1) h^(−1) and 23.5μmol g^(−1) h^(−1),respectively.The photogener-ated accelerated charge transport is then examined in detail by in situ X-ray photoelectron spectroscopy(ISXPS)and density functional theory(DFT)calculations.This work presents a new idea for the synthe-sis of Cd_(x) Zn_(1-x) S solid-solution-based materials and provides a solid reference for the detailed mechanism regarding the electric field at the heterojunction interface.
基金supported by the National Natural Science Foundation of China(52164028,52274297)the Start-up Research Foundation of Hainan University(KYQD(ZR)20008,KYQD(ZR)21125,KYQD(ZR)23169))+1 种基金Collaborative Innovation Center of Marine Science and Technology of Hainan University(XTCX2022HYC14)Innovative Research Project for Postgraduate Students in Hainan Province(Qhyb2024-95).
文摘Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field coupled with chloride ions(Cl-)fixation strategy in dual single-atom catalysts(DSACs)was proposed,and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte,with a high half-wave potential(E_(1/2))of 0.868 V and a good maximum power density(Pmax)of 182 mW·cm^(−2)in the assembled SZABs,much higher than those of the Pt/C catalyst(E_(1/2):0.846 V;Pmax:150 mW·cm^(−2)).The in-situ characterization and theoretical calculations revealed that the Fe sites have a higher Cl^(−)adsorption affinity than the Co sites,and preferentially adsorbs Cl^(−)in a seawater electrolyte during the ORR process,and thus constructs a low-concentration Cl^(−)local microenvironment through the common-ion exclusion effect,which prevents Cl^(−)adsorption and corrosion in the Co active centers,achieving impressive catalytic stability.In addition,the directional charge movement between Fe and Co atomic pairs establishes a local electric field,optimizing the adsorption energy of Co sites for oxygen-containing intermediates,and further improving the ORR activity.
基金supported by the National Key R&D Program of China(Grant No.2022YFA1402802)the National Natural Science Foundation of China(Grant Nos.12494591 and 92165204)+4 种基金the Leading Talent Program of Guangdong Special Projects(Grant No.201626003)the Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices(Grant No.2022B1212010008)the Research Center for Magnetoelectric Physics of Guangdong Province(Grant No.2024B0303390001)the Guangdong Provincial Quantum Science Strategic Initiative(Grant No.GDZX2401010)supported by the National Natural Science Foundation of China(Grant Nos.12234016 and 12074031)。
文摘We investigate the energy bands,magnetism,and superconductivity of bilayer octagraphene with A-A stackingunder a perpendicular electric field.A tight-binding model is used to analyze the band structure of the system.The doubling of the unit cell results in each band of the single layer splitting into two.We find that applyinga perpendicular electric field increases the band splitting.As the electric field strength increases,the nestingof the Fermi surface(FS)weakens,eventually disrupting the antiferromagnetic order,and bilayer octagrapheneexhibits superconductivity.Spin fluctuations can induce unconventional superconductivity with s±-wave pairing.Applying a perpendicular electric field to bilayer octagraphene parent weakens the nesting of the FS,ultimatelykilling the spin-density-wave(SDW)ordered state and transitioning it into the superconducting state,whichworks as a doping effect.We use the random-phase approximation approach to obtain the pairing eigenvaluesand pairing symmetries of the perpendicular electric field-tuned bilayer octagraphene in the weak coupling limit.By tuning the strength of the perpendicular electric field,the critical interaction strength for SDW order can bemodified,which in turn may promote the emergence of unconventional superconductivity.
基金supported by the Hunan Provincial Natural Science Foundation(No.2016JJ3034).
文摘Einstein aimed to find a unified theoretical model to explain various interactions in nature,and the relationship between gravitational and electric fields was particularly important.For the first time,this paper provides the internal relationship equations of the electric and magnetic fields.Further,the relationship between the magnetic and gravity fields is analyzed,and the relationship equations of the electric,magnetic,and gravity fields are established.On this basis,a general formula for calculating the radius of charged particles is derived.Simultaneously,we also discussed and made predictions on black holes,providing convenience for future research and experimental detection.
文摘Developing an efficient photocatalyst is the key to realize the practical application of photocatalysis.The S-scheme heterojunction has great potential in photocatalysis due to its unique charge-carrier migration pathway,effective light absorption and high redox capacity.However,further enhancing the built-in electric field of the S-scheme,accelerating carrier separation,and achieving higher photocatalytic performance remain unresolved challenges.Herein,based on the continuously adjustable band structure of continuous solid-solution,a novel 0D/2D all solid-solution S-scheme heterojunction with adjustable internal electric field was designed and fabricated by employing a solid-solution of ZnxCd_(1–x)S and Bi_(2)MoyW_(1–y)O_(6)respectively as reduction and oxidation semiconductors.The synergistic optimization of effective light absorption,fast photogenerated carrier separation,and high redox potential leads can be tuned to promote photocatalytic activity.Under visible light,the S-scheme system constructed by Zn_(0.4)Cd_(0.6)S quantum dot(QDs)and Bi_(2)Mo_(0.2)W_(0.8)O_(6)monolayer exhibits a high rate for photocatalytic degradation C_(2)H_(4)(150.6×10^(–3)min^(–1)),which is 16.5 times higher than that of pure Zn_(0.4)Cd_(0.6)S(9.1×10^(–3)min^(–1))and 53.8 times higher than pure Bi_(2)Mo_(0.2)W_(0.8)O_(6)(2.8×10^(–3)min^(–1)).Due to the unique charge-carrier migration pathway,photo-corrosion of Zn_(x)Cd_(1–x)S is further inhibited simultaneously.In-situ irradiation X-ray photoelectron spectroscopy,photoluminescence spectroscopy,time-resolved photoluminescence,transient absorption spectroscopy and electron paramagnetic resonance provide compelling evidence for interfacial charge transfer via S-scheme pathways,while in-situ diffuse reflectance infrared Fourier transform spectroscopy identifies the reaction pathway for C_(2)H_(4)degradation.This novel S-scheme photocatalysts demonstrates excellent performance and potential for the practical application of the fruits and vegetables preservation at room temperatures.
基金support from the Chinese Academy of Sciences and University of Science and Technology of China,National Key Research and Development Program of China(No.2021YFA1500402)National Natural Science Foundation of China(Nos.21571167,51502282 and 22075266)Fundamental Research Funds for the Central Universities(Nos.WK2060190053 and WK2060190100)。
文摘Efficient selective adsorption and separation using porous frameworks are critical in many industrial processes,where adsorption energy and dynamic diffusion rate are predominant factors governing selectivity.They are highly susceptible to framework charge,which plays a significant role in selective adsorption.Currently,ionic porous frameworks can be divided into two types.One of them is composed of a charged backbone and counter ions.The framework with zwitterionic channels is another type.It is composed of regular and alternating arrangements of cationic and anionic building units.Herein,we report a hydrogen-bonded ionic framework(HIF)of{(CN_(3)H_(6))_(2)[Ti(μ_(2)-O)(SO_(4))_(2)]}_nwith 1D channel exhibits unique adsorption selectivity for Ar against N_(2)and CO_(2).Density functional theory(DFT)results suggest that CO_(2)cannot be adsorbed by HIF at the experimental temperature due to a positive adsorption free energy.In addition,due to a relatively large diffusion barrier at 77 K,N_(2)molecules hardly diffuse in HIF channels,while Ar has a negligible diffusion barrier.The unique net positively-charged space in the channel is the key to the unusual phenomena,based on DFT simulations and structural analysis.The findings in this work proposes the new adsorption mechanism and provides unique perspective for special separation applications,such as isotope and noble gasses separations.
基金supported by the National Natural Science Foundation of China(Grant No.12175080)by Self-Determined Research Funds of Central China Normal University from the Colleges’Basic Research and Operation of MOE(Grant No.CCNU25JC012)。
文摘Spiral waves,as a typical self-organized structure with chiral characteristics,are widely found in excitable media such as cardiac tissues,chemical reactions,and neural networks.Based on the Fitz Hugh–Nagumo model,we investigated the mechanisms underlying the effects of direct current electric fields(DCEF),alternating current electric fields(ACEF),and polarized electric fields(PEF)on the interaction and annihilation processes of counter-rotating spiral waves.We found that in a direct current electric field,the drift direction of the spiral wave is determined jointly by its chirality and the electric field direction,which allows selective attraction or repulsion.In an alternating current electric field,the annihilation behavior of spiral waves can be influenced by the phase and intensity of the electric field,where a specific range of parameters induces resonance drift and eventual annihilation.On the other hand,the polarized electric field exhibits a more complex modulation capability on spiral waves:the trajectory and annihilation efficiency of spiral waves can be regulated by both the intensity and phase of the polarized electric field.These results reveal the potential feasibility of regulating multichiral spiral waves through multiple electric fields,providing theoretical insight for the control of spiral waves in relevant systems.
基金financial support from the National Natural Science Foundation of China(NSFC No.52202253,ter for Microscopy and Analysis at the Nanjing University of Aero52372193,52472211,22293041)the Natural Science Foundation of Jiangsu Province(No.BK20220914)the Large Instrument and Equipment Sharing Fund of NUAA。
文摘A fatal issue of Zn-based electrochemical energy storage is uneven Zn^(2+)deposition on the Zn metal anode.Unfortunately,the modulation for the inherent electric field,the origin of driving force for ion diffusion,has been given insufficient importance.Herein,the redistribution of the surrounding electric field is demonstrated to depend on the permittivity of the surface medium for the first time,where highpermittivity particles can simultaneously enhance vertical components and reduce horizontal components of the electric field through polarization.Consequently,a bacterial cellulose-based separator is proposed by incorporating a high-permittivity surface medium.Cellulose serves as a robust substrate with a rather low thickness to enable homogeneous dispersion of high-permittivity particles on the surface,which can regulate the localized electric field to guide even Zn deposition by inhibiting twodimensional(2D)Zn^(2+)diffusion and suppressing side reactions by repulsing anion migration toward the Zn anode.The separator achieves significantly enhanced Zn anode stability of 2880 h at 1 mA cm^(-2)and a cumulative capacity of 3.5 Ah cm^(-2)at 10 mA cm^(-2).It also enables a long-term lifespan of 50,000 cycles in Zn||AC capacitor and 1000 cycles at a limited negative/positive(N/P)ratio of 3:1.This work provides a new view to stabilize Zn anode by electric field modulation.
