The core sampling experiments were conducted after hydraulic fracturing in the three-dimensional development zone of Fuling shale gas.Six coring wells of different well types were systematically designed.Based on the ...The core sampling experiments were conducted after hydraulic fracturing in the three-dimensional development zone of Fuling shale gas.Six coring wells of different well types were systematically designed.Based on the integrated engineering technology of post-fracturing drilling,coring and monitoring of shale and the analysis of fracture source tracing,the evaluation of the fracture network after fracturing in the three-dimensional development of shale gas was conducted.The data of core fractures after fracturing indicate that three major types of fractures are formed after fracturing:natural fractures,hydraulic fractures,and fractures induced by external mechanical force,which are further classified into six subcategories:natural structural fractures,natural bedding fractures,hydraulic fractures,hydraulically activated fractures,drilling induced fractures,and fractures induced by core transportation.The forms of the artificial fracture network after fracturing are complex.Hydraulic fractures and hydraulically activated fractures interweave with each other,presenting eight forms of artificial fracture networks,among which the“一”-shaped fracture is the most common,accounting for approximately 70%of the total fractures.When the distance to the fractured wellbore is less than 35 m,the density of the artificial fracture network is relatively high;when it is 35–100 m,the density is lower;and when it is beyond 100 m,the density gradually increases.The results of the fracture tracing in the core sampling area confirm that the current fracturing technology can essentially achieve the differential transformation of the reservoir in the main area of Jiaoshiba block in Fuling.The three-layer three-dimensional development model can efficiently utilize shale gas reserves,although there is still room for improvement in the complexity and propagation uniformity of fractures.It is necessary to further optimize technologies such as close-cutting combined with temporary blocking and deflection within fractures or at fracture mouths,as well as limited flow perforation techniques,to promote the balanced initiation and extension of fractures.展开更多
An integration processing system of three-dimensional laser scanning information visualization in goaf was developed. It is provided with multiple functions, such as laser scanning information management for goaf, clo...An integration processing system of three-dimensional laser scanning information visualization in goaf was developed. It is provided with multiple functions, such as laser scanning information management for goaf, cloud data de-noising optimization, construction, display and operation of three-dimensional model, model editing, profile generation, calculation of goaf volume and roof area, Boolean calculation among models and interaction with the third party soft ware. Concerning this system with a concise interface, plentiful data input/output interfaces, it is featured with high integration, simple and convenient operations of applications. According to practice, in addition to being well-adapted, this system is favorably reliable and stable.展开更多
In the Jiaoshiba block of the Fuling shale gas field,the employed reserves and recovery factor by primary well pattern are low,no obvious barrier is found in the development layer series,and layered development is dif...In the Jiaoshiba block of the Fuling shale gas field,the employed reserves and recovery factor by primary well pattern are low,no obvious barrier is found in the development layer series,and layered development is difficult.Based on the understanding of the main factors controlling shale gas enrichment and high production,the theory and technology of shale gas three-dimensional development,such as fine description and modeling of shale gas reservoir,optimization of three-dimensional development strategy,highly efficient drilling with dense well pattern,precision fracturing and real-time control,are discussed.Three-dimensional development refers to the application of optimal and fast drilling and volume fracturing technologies,depending upon the sedimentary characteristics,reservoir characteristics and sweet spot distribution of shale gas,to form"artificial gas reservoir"in a multidimensional space,so as to maximize the employed reserves,recovery factor and yield rate of shale gas development.In the research on shale gas three-dimensional development,the geological+engineering sweet spot description is fundamental,the collaborative optimization of natural fractures and artificial fractures is critical,and the improvement of speed and efficiency in drilling and fracturing engineering is the guarantee.Through the implementation of three-dimensional development,the overall recovery factor in the Jiaoshiba block has increased from 12.6%to 23.3%,providing an important support for the continuous and stable production of the Fuling shale gas field.展开更多
With the low-carbon coordinated development in Beijing-Tianjin-Hebei Region as the starting point, the necessity and realistic difficulties in achieving the lowcarbon coordination in Beijing-Tianjin-Hebei Region was a...With the low-carbon coordinated development in Beijing-Tianjin-Hebei Region as the starting point, the necessity and realistic difficulties in achieving the lowcarbon coordination in Beijing-Tianjin-Hebei Region was analyzed, based on which we constructed the systematic analytical framework for low-carbon coordination in Beijing-Tianjin-Hebei Region, and proposed the development path of regional lowcarbon coordinated development from the three levels of government, industry and consumer with the aim to provide specific references for the low-carbon coordinated development in Beijing-Tianjin-Hebei Region.展开更多
The 2030 Agenda for Sustainable Development provides a new global policy to guide the way countries collectively manage and transform the social,economic,and environmental dimensions of people and the planet over the ...The 2030 Agenda for Sustainable Development provides a new global policy to guide the way countries collectively manage and transform the social,economic,and environmental dimensions of people and the planet over the next 15 years.Achieving sustainable development presents all countries and the global policy community with a set of significant development challenges that are almost entirely geographic in nature.Many of the issues impacting sustainable development can be analyzed,modeled,and mapped within a geographic context,which in turn can provide the integrative framework necessary for global collaboration,consensus and evidence-based decision-making.However,and despite significant advances in geospatial information technologies,there is a lack of awareness,understanding and uptake,particular at the policy and decision-making level,of the vital and integrative role of geospatial information and related enabling architectures such as National Spatial Data Infrastructures.This paper reasons that the role of geospatial information in contributing to sustainable development has not adequately been described by either the sustainable development policy practice or by the geospatial professional community.This lack of policy and guidance,with commensurate critical gaps and connection points with national geospatial frameworks,is a visible impediment to developing countries and those most affected by the challenges and need to achieve sustainable development.The global geospatial community now has a unique opportunity to integrate and connect geospatial information into the global development agenda in a more holistic and sustainable manner,specifically in contributing their data resources toward measuring and monitoring the 17 Sustainable Development Goals,and their 169 associated targets,through the global indicator framework that anchors the 2030 Agenda for Sustainable Development.This paper introduces and discusses a new strategic framework for linking a global policy to national geospatial capabilities.展开更多
Two reported three-dimensional covalent organic frameworks(3D-COFs),COF-300 and COF-301,which have hierarchical porous structures and large pore volumes,were synthesized and employed as host materials for lithium-sulf...Two reported three-dimensional covalent organic frameworks(3D-COFs),COF-300 and COF-301,which have hierarchical porous structures and large pore volumes,were synthesized and employed as host materials for lithium-sulfur batteries.Owing to possessing excellent porosities as well as abundant hydroxyl groups in the pore walls,COF-301 can not only trap lithium polysulfides(PSs)via physical adsorption inside the pores,but also capture PSs by chemical interactions to relieve the shuttle effect.Interestingly,it is the first time that 3D-COFs were utilized as host materials for lithium-sulfur batteries as well as hydroxyl groups were introduced into COFs for improving the battery performance.As a result,COF-301@S as cathode material could reserve the capacity of 411.6 mA·h·g^-1 after 500 cycles with only 0.081%fading per cycle at 0.5 C,exhibiting better battery performance compared with COF-300@S.This study not only expands the applications of 3D-COFs but also provides a new route for designing lithium-sulfur batteries.展开更多
The bis(tributyltin) ester of succinic acid was synthesized by the reaction of disodium salt of succinic acid with tributyltin chloride in a molar ratio of 1:2. The crystal structure was determined by X-ray single-cry...The bis(tributyltin) ester of succinic acid was synthesized by the reaction of disodium salt of succinic acid with tributyltin chloride in a molar ratio of 1:2. The crystal structure was determined by X-ray single-crystal diffraction. It belongs to orthorhombic with space group Pccn, a = 20.949(3), b = 17.470(3), c = 20.345(3) Angstrom, V = 7446(2) Angstrom(3), Z = 8, D-c = 1.242 g/cm(3), mu = 1.365 mm(-1), F(000) = 2864, R = 0.0544 and wR = 0.1417. The tin atom is of five-coordination in a trigonal bipyramidal structure by bridging two carboxylate groups in different directions and the resulting structure which contains straight twist large ring channels along the axes of a, b and c is a three-dimensional framework polymer containing two different tin atoms.展开更多
The strategic delineation of the urban development boundary(UDB)is an effective initiative for efficient land resource allocation and for facilitating planned urban development.To align with sustainable development ob...The strategic delineation of the urban development boundary(UDB)is an effective initiative for efficient land resource allocation and for facilitating planned urban development.To align with sustainable development objectives,UDB definitions have evolved to reconcile urban development with ecological preservation.This study presents a UDB delineation framework from an integrated perspective that incorporates both demand-oriented and comprehensive constraints.Specifically,the urban construction land demand area was estimated based on population projections,meanwhile,the ecological red line(ERL)was delineated and integrated into the evaluation of the construction land suitability.Subsequently,with the demand area as the simulation target and unsuitable areas as comprehensive constraints,the UDB was delineated by simulating future land use patterns.The proposed framework was applied to Wuhan,a rapidly urbanizing city in central China,where the delineation of the UDB serves the dual purpose of managing the rapid expansion of built-up land and achieving a harmonious balance between urban development imperatives and ecological protection goals.Moreover,based on the results and analysis,policy implications for the rational spatial planning of Wuhan were proposed,encompassing the spatial patterns and scientific decision-making in ecological conservation and urban development.The results demonstrate that the efficacy of adopting a comprehensive perspective in delineating UDB effectively reconciles the competing needs of urban development and conservation.The framework and the policy insights derived in this study could inform spatial planning efforts not only in Wuhan but also in other cities facing the dilemma of urban development and ecological protection.展开更多
Architectural heritage comprises one o the most important elements of mountain settlements in Greece. It holds high cultural value, represents the tangible continuation of the past and forms the unique character and i...Architectural heritage comprises one o the most important elements of mountain settlements in Greece. It holds high cultural value, represents the tangible continuation of the past and forms the unique character and identity of each mountain region. Yet, controversy regarding funding for its preservation often arises. In this paper, we used two Contingent Valuation surveys to estimate the socia benefit deriving from protecting the traditiona architecture in the mountainous village of Sirako and through it, to examine perceptions and attitudes o local residents and visitors. Research findings revealed a strong social will in favor of the good＇s protection followed by high percentages of positive willingness to pay（WTP）. However, WTP is significantly higher among residents. Cultura heritage value, of the good, appears to prevail, along with the environmental one. However, both residents and visitors pointed out that local heritage, if wellpreserved, will boost tourism development. Residents appeared to better recognize the true level o architectural decay, expressed higher apprehension for its protection and were willing to pay higher amount of money. Tourists, on the other side expressed high satisfaction for their visit, appreciated the beauty and serenity emerging from local built and natural environment and spent several days visiting the surrounding area. The longer they stayed and gotfamiliar with the village, the more willing they were to contribute to local heritage＇s protection. Percentages reflecting indifference for protecting architecture were extremely low. Yet, they were higher among tourists. Traditional architecture is considered as public good; an opinion resulting in an important percentage of visitors stating that national government should provide the necessary funding. In addition, the architecture appears to hold a high level of topicality. Those descending from Sirako or emotionally connected to it, of both social groups,turned out to be more concerned about the good and with a stronger sense of responsibility for it. Usevalue of the good holds high economic value, as well,while higher percentages of zero WTP appeared among non-users. Research findings revealed social attitudes and perceptions on what constitutes architectural heritage, in its cultural and economic frame. If taken under consideration, they may form useful drivers for local, heritage-based, sustainable展开更多
Quantifying material use in infrastructure development and analyzing its relationship with economic growth is essential for enhancing resource efficiency and steering regional resource management toward sustainable de...Quantifying material use in infrastructure development and analyzing its relationship with economic growth is essential for enhancing resource efficiency and steering regional resource management toward sustainable development.This study systematically assessed infrastructure related material use in 30 provinces,autonomous regions,and municipalities in China during 1978-2022.The result indicated that material stock has experienced significant growth,increasing from 16.91×10^(9)t in 1978 to 103.60×10^(9)t in 2022,with an average annual growth rate of 4.20%.However,from 1978 to 2015,material input followed a strong upward trend but saturated after 2015.At the national level,material input peaked in 2015,after which it began to decline.The central region reached its peak earlier in 2013,while the eastern and western regions peaked in 2015.Using a decoupling analysis framework,this study revealed that nationally,the elasticity value between material stock and gross domestic product(GDP)remained near or above 1.0,reflecting continued reliance on stock accumulation.Regionally,the elasticity value between material stock and GDP has increased in the central and western regions during 1978-2022,whereas elasticity value between material stock and GDP in the eastern region showed a slower growth rate but still struggled to achieve absolute decoupling.Moreover,the elasticity value between material input and GDP has declined at the national level,presenting a relative decoupling,with some regions already achieving absolute decoupling.The eastern region was closer to absolute decoupling,while the central and western regions,though still intensive in material input,exhibited faster declines in elasticity.Accelerating the transition from linear to circular economy is an essential step for China to achieve absolute decoupling and long-term sustainability.Finally,this research recommends promoting the adoption of renewable energy,driving industrial upgrading,implementing compact urban design,and extending the lifespan of infrastructure to reduce material dependency and achieve sustainable infrastructure transformation at the national level.展开更多
The extensive application of artificial intelligence(AI)technology is profoundly affecting the ecology of education.To analyze the advantages and disadvantages of AI for the professional growth of students,this study ...The extensive application of artificial intelligence(AI)technology is profoundly affecting the ecology of education.To analyze the advantages and disadvantages of AI for the professional growth of students,this study systematically analyzed the potential dual impacts of AI in higher education from two dimensions,namely academic ability and thinking patterns.Results indicated AI facilitated the development of students by improving learning efficiency and optimizing the integration of resources.However,it simultaneously aggravated the crisis of academic integrity and the inertia of thinking.In responding to these issues,this study proposed an integrated framework that included management,guidance,and standardization.This framework would facilitate the positive interaction between AI and education,contributing to the professional development of students.展开更多
In October 2024,at the 27th ChinaASEAN Leaders'Meeting,the leaders of China and ten ASEAN nations announced the substantial conclusion of the China-ASEAN FTA 3.0 Upgrade Negotiations,and proposed that the two side...In October 2024,at the 27th ChinaASEAN Leaders'Meeting,the leaders of China and ten ASEAN nations announced the substantial conclusion of the China-ASEAN FTA 3.0 Upgrade Negotiations,and proposed that the two sides would strive to formally sign in 2025 the Protocol on Further Upgrading the China-ASEAN Comprehensive Economic Cooperation Framework Agreement and pertinent agreements under the Agreement.展开更多
Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully construct...Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully constructed by coordinatively assembling the semi-rigid multidentate ligand 5-(1-carboxyethoxy)isophthalic acid(H₃CIA)with the Nheterocyclic ligands 1,4-di(4H-1,2,4-triazol-4-yl)benzene(1,4-dtb)and 1,4-di(1H-imidazol-1-yl)benzene(1,4-dib),respectively,around Co^(2+)ions.Single-crystal X-ray diffraction analysis revealed that in both complexes HU23 and HU24,the CIA^(3-)anions adopt aκ^(7)-coordination mode,bridging six Co^(2+)ions via their five carboxylate oxygen atoms and one ether oxygen atom.This linkage forms tetranuclear[Co4(μ3-OH)2]^(6+)units.These Co-oxo cluster units were interconnected by CIA^(3-)anions to assemble into 2D kgd-type structures featuring a 3,6-connected topology.The 2D layers were further connected by 1,4-dtb and 1,4-dib,resulting in 3D pillar-layered frameworks for HU23 and HU24.Notably,despite the similar configurations of 1,4-dtb and 1,4-dib,differences in their coordination spatial orientations lead to topological divergence in the 3D frameworks of HU23 and HU24.Topological analysis indicates that the frameworks of HU23 and HU24 can be simplified into a 3,10-connected net(point symbol:(4^(10).6^(3).8^(2))(4^(3))_(2))and a 3,8-connected tfz-d net(point symbol:(4^(3))_(2)((4^(6).6^(18).8^(4)))),respectively.This structural differentiation confirms the precise regulatory role of ligands on the topology of metal-organic frameworks.Moreover,the ultraviolet-visible absorption spectra confirmed that HU23 and HU24 have strong absorption capabilities for ultraviolet and visible light.According to the Kubelka-Munk method,their bandwidths were 2.15 and 2.08 eV,respectively,which are consistent with those of typical semiconductor materials.Variable-temperature magnetic susceptibility measurements(2-300 K)revealed significant antiferromagnetic coupling in both complexes,with their effective magnetic moments decreasing markedly as the temperature lowered.CCDC:2457554,HU23;2457553,HU24.展开更多
Covalent organic frameworks(COFs) are a class of crystalline porous organic materials with variable structures and fascinating properties. The intrinsic low conductivity impedes their widely application in optoelectro...Covalent organic frameworks(COFs) are a class of crystalline porous organic materials with variable structures and fascinating properties. The intrinsic low conductivity impedes their widely application in optoelectronic. Iodine doping is an effective way to enhance the electrical conductivity of COFs. Here, a novel 3D imine COF with lvt topology is synthesized from two different pentacene derivatives with the same core in the form of structural complementarity. DDHP-COF is a highly crystalline material featuring high surface area of 1679 m^(2)/g and excellent thermal stability up to 490 ℃. Upon doping with iodine, the electrical conductivity can reach as high as 1.5×10^(-2)S/m which is significantly enhanced over 6 orders of magnitude compared with the pristine COF.展开更多
A new heteropolyoxotungstate [（C2H4N2）4（P4Co3W4O28H6）（H2C2O4）]n with a three-dimensional framework was hydrothermally synthesized.The compound crystallizes in a tetragonal system,space group I41/a with a = 17.1...A new heteropolyoxotungstate [（C2H4N2）4（P4Co3W4O28H6）（H2C2O4）]n with a three-dimensional framework was hydrothermally synthesized.The compound crystallizes in a tetragonal system,space group I41/a with a = 17.1006（17）,b = 17.1006（7）,c = 10.7525（5）,V = 3144.2（2）3,Z = 4,Dc = 3.795 g·cm-3,F（000） = 3300,MoKα（λ = 0.71073 ）,μ = 16.460 mm-1,the final R = 0.0335 and wR = 0.0776.In the heteropolyoxotungstate,tungsten-oxygen octahedra are linked by sharing two cis-vertexes into an infinite helical chain extending along the c axis.Cobalt atoms in the octahedral geometry act as the linkers of these chains,forming a three-dimensional framework.The cobalt and phosphorus atoms in the tetrahedral geometry play a role in stabilizing the three-dimensional framework.Ethylenediamine molecules are polymerized into organic chains which locate in the interspaces of the framework in the way of interwinding with the W-O chains.展开更多
The increasing use of digital video everyday in a multitude of electronic devices, including mobile phones, tablets and laptops, poses the need for quick development of cross-platform video software. However current a...The increasing use of digital video everyday in a multitude of electronic devices, including mobile phones, tablets and laptops, poses the need for quick development of cross-platform video software. However current approaches to this direction usually require a long learning curve, and their development lacks standardization. This results in software components that are difficult to reuse, and hard to maintain or extend. In order to overcome such issues, we propose a novel object-oriented framework for efficient development of software systems for video analysis. It consists of a set of four abstract components, suitable for the implementation of independent plug-in modules for video acquisition, preprocessing, analysis and output handling. The extensibility of each module can be facilitated by sub-modules specifying additional functionalities. This architecture enables quick responses to changes and re-configurability;thus conforming to the requirements of agile software development practices. Considering the need for platform independency, the proposed Java Video Analysis (JVA) framework is implemented in Java. It is publicly available through the web as open-access software, supported by a growing collection of implemented modules. Its efficiency is empirically validated for the development of a representative video analysis system.展开更多
Along with the history of the development of financial regulation, we can see that the theory of evolution has experienced from financial liberalization to financial supervision, financial regulation, then to the stag...Along with the history of the development of financial regulation, we can see that the theory of evolution has experienced from financial liberalization to financial supervision, financial regulation, then to the stage both with the safety and efficiency of financial supervision ; development of the theory of financial regulation experienced the theory of financial supervision represented by classical economics and neo- classical economic theory, to the Keynesian theory and financial repression theory, financial fragility hypothesis, the progressive liberalization of the financial road, then to the financial regulatory theory, regulatory function theory concept, regulatory incentives theory under the framework of economics of information in the 1990s. You can see the way scholars will not have feared in the study of financial regulation, and each theory proposed has its special significance in the special economic and financial environment at the time, and we can not necessarily say what kind of theory is advanced in other theory.展开更多
The evolution of the society and economy has stimulated the development of Knowledge Service(KS), making it an indispensable solution to address future challenges facing libraries and information institutions. However...The evolution of the society and economy has stimulated the development of Knowledge Service(KS), making it an indispensable solution to address future challenges facing libraries and information institutions. However at present, academic research on knowledge service is falling short and its definition is far from clear and complete. As such,this article proposes the Three-dimensional Framework Knowledge Service(TdFKS) for libraries and information institutions based on the knowledge value chain model. By making reliability analysis and mean value analysis of a questionnaire survey result, the article clarifies the structure of the three-dimensional framework and verifies the rationality of the TdFKS.展开更多
文摘The core sampling experiments were conducted after hydraulic fracturing in the three-dimensional development zone of Fuling shale gas.Six coring wells of different well types were systematically designed.Based on the integrated engineering technology of post-fracturing drilling,coring and monitoring of shale and the analysis of fracture source tracing,the evaluation of the fracture network after fracturing in the three-dimensional development of shale gas was conducted.The data of core fractures after fracturing indicate that three major types of fractures are formed after fracturing:natural fractures,hydraulic fractures,and fractures induced by external mechanical force,which are further classified into six subcategories:natural structural fractures,natural bedding fractures,hydraulic fractures,hydraulically activated fractures,drilling induced fractures,and fractures induced by core transportation.The forms of the artificial fracture network after fracturing are complex.Hydraulic fractures and hydraulically activated fractures interweave with each other,presenting eight forms of artificial fracture networks,among which the“一”-shaped fracture is the most common,accounting for approximately 70%of the total fractures.When the distance to the fractured wellbore is less than 35 m,the density of the artificial fracture network is relatively high;when it is 35–100 m,the density is lower;and when it is beyond 100 m,the density gradually increases.The results of the fracture tracing in the core sampling area confirm that the current fracturing technology can essentially achieve the differential transformation of the reservoir in the main area of Jiaoshiba block in Fuling.The three-layer three-dimensional development model can efficiently utilize shale gas reserves,although there is still room for improvement in the complexity and propagation uniformity of fractures.It is necessary to further optimize technologies such as close-cutting combined with temporary blocking and deflection within fractures or at fracture mouths,as well as limited flow perforation techniques,to promote the balanced initiation and extension of fractures.
基金Project(51274250)supported by the National Natural Science Foundation of ChinaProject(2012BAK09B02-05)supported by the National Key Technology R&D Program during the 12th Five-year Plan of China
文摘An integration processing system of three-dimensional laser scanning information visualization in goaf was developed. It is provided with multiple functions, such as laser scanning information management for goaf, cloud data de-noising optimization, construction, display and operation of three-dimensional model, model editing, profile generation, calculation of goaf volume and roof area, Boolean calculation among models and interaction with the third party soft ware. Concerning this system with a concise interface, plentiful data input/output interfaces, it is featured with high integration, simple and convenient operations of applications. According to practice, in addition to being well-adapted, this system is favorably reliable and stable.
基金Supported by the Sinopec Science and Technology Project(P22183).
文摘In the Jiaoshiba block of the Fuling shale gas field,the employed reserves and recovery factor by primary well pattern are low,no obvious barrier is found in the development layer series,and layered development is difficult.Based on the understanding of the main factors controlling shale gas enrichment and high production,the theory and technology of shale gas three-dimensional development,such as fine description and modeling of shale gas reservoir,optimization of three-dimensional development strategy,highly efficient drilling with dense well pattern,precision fracturing and real-time control,are discussed.Three-dimensional development refers to the application of optimal and fast drilling and volume fracturing technologies,depending upon the sedimentary characteristics,reservoir characteristics and sweet spot distribution of shale gas,to form"artificial gas reservoir"in a multidimensional space,so as to maximize the employed reserves,recovery factor and yield rate of shale gas development.In the research on shale gas three-dimensional development,the geological+engineering sweet spot description is fundamental,the collaborative optimization of natural fractures and artificial fractures is critical,and the improvement of speed and efficiency in drilling and fracturing engineering is the guarantee.Through the implementation of three-dimensional development,the overall recovery factor in the Jiaoshiba block has increased from 12.6%to 23.3%,providing an important support for the continuous and stable production of the Fuling shale gas field.
基金Study on the Coordinated Innovation of Agricultural Knowledge Under the Perspective of Industrial Chain,One of the Periodical Achievements of Strategic Research Program for the Science and Technology Development of Tianjin City(15ZLZLZF00210)Study on the Evolution Path and Scientific and Technological Supporting System of Agriculture of Appropriate Scale Based on Heterogeneous Farmers,One of the Periodical Achievements of Strategic Research Program for the Science and Technology Development of Tianjin City(15ZLZLZF00390)~~
文摘With the low-carbon coordinated development in Beijing-Tianjin-Hebei Region as the starting point, the necessity and realistic difficulties in achieving the lowcarbon coordination in Beijing-Tianjin-Hebei Region was analyzed, based on which we constructed the systematic analytical framework for low-carbon coordination in Beijing-Tianjin-Hebei Region, and proposed the development path of regional lowcarbon coordinated development from the three levels of government, industry and consumer with the aim to provide specific references for the low-carbon coordinated development in Beijing-Tianjin-Hebei Region.
文摘The 2030 Agenda for Sustainable Development provides a new global policy to guide the way countries collectively manage and transform the social,economic,and environmental dimensions of people and the planet over the next 15 years.Achieving sustainable development presents all countries and the global policy community with a set of significant development challenges that are almost entirely geographic in nature.Many of the issues impacting sustainable development can be analyzed,modeled,and mapped within a geographic context,which in turn can provide the integrative framework necessary for global collaboration,consensus and evidence-based decision-making.However,and despite significant advances in geospatial information technologies,there is a lack of awareness,understanding and uptake,particular at the policy and decision-making level,of the vital and integrative role of geospatial information and related enabling architectures such as National Spatial Data Infrastructures.This paper reasons that the role of geospatial information in contributing to sustainable development has not adequately been described by either the sustainable development policy practice or by the geospatial professional community.This lack of policy and guidance,with commensurate critical gaps and connection points with national geospatial frameworks,is a visible impediment to developing countries and those most affected by the challenges and need to achieve sustainable development.The global geospatial community now has a unique opportunity to integrate and connect geospatial information into the global development agenda in a more holistic and sustainable manner,specifically in contributing their data resources toward measuring and monitoring the 17 Sustainable Development Goals,and their 169 associated targets,through the global indicator framework that anchors the 2030 Agenda for Sustainable Development.This paper introduces and discusses a new strategic framework for linking a global policy to national geospatial capabilities.
基金supported by the National Natural Science Foundation of China(Nos.21674026,21574032,51573125,51573147,51803149,51973155,and 51633007(the State Key Program))the Sino-German Center for Research Promotion(No.GZ1286)the Chinese Academy of Sciences(No.121D11KYSB20170031).
文摘Two reported three-dimensional covalent organic frameworks(3D-COFs),COF-300 and COF-301,which have hierarchical porous structures and large pore volumes,were synthesized and employed as host materials for lithium-sulfur batteries.Owing to possessing excellent porosities as well as abundant hydroxyl groups in the pore walls,COF-301 can not only trap lithium polysulfides(PSs)via physical adsorption inside the pores,but also capture PSs by chemical interactions to relieve the shuttle effect.Interestingly,it is the first time that 3D-COFs were utilized as host materials for lithium-sulfur batteries as well as hydroxyl groups were introduced into COFs for improving the battery performance.As a result,COF-301@S as cathode material could reserve the capacity of 411.6 mA·h·g^-1 after 500 cycles with only 0.081%fading per cycle at 0.5 C,exhibiting better battery performance compared with COF-300@S.This study not only expands the applications of 3D-COFs but also provides a new route for designing lithium-sulfur batteries.
基金the National Natural Science Foundation of China (No. 20271025)the Natural Science Foundation of Shandong province (No. Z2001B02)the State Key Laboratory of Crystal Materials,Shandong University
文摘The bis(tributyltin) ester of succinic acid was synthesized by the reaction of disodium salt of succinic acid with tributyltin chloride in a molar ratio of 1:2. The crystal structure was determined by X-ray single-crystal diffraction. It belongs to orthorhombic with space group Pccn, a = 20.949(3), b = 17.470(3), c = 20.345(3) Angstrom, V = 7446(2) Angstrom(3), Z = 8, D-c = 1.242 g/cm(3), mu = 1.365 mm(-1), F(000) = 2864, R = 0.0544 and wR = 0.1417. The tin atom is of five-coordination in a trigonal bipyramidal structure by bridging two carboxylate groups in different directions and the resulting structure which contains straight twist large ring channels along the axes of a, b and c is a three-dimensional framework polymer containing two different tin atoms.
基金National Natural Science Foundation of China,No.72174071。
文摘The strategic delineation of the urban development boundary(UDB)is an effective initiative for efficient land resource allocation and for facilitating planned urban development.To align with sustainable development objectives,UDB definitions have evolved to reconcile urban development with ecological preservation.This study presents a UDB delineation framework from an integrated perspective that incorporates both demand-oriented and comprehensive constraints.Specifically,the urban construction land demand area was estimated based on population projections,meanwhile,the ecological red line(ERL)was delineated and integrated into the evaluation of the construction land suitability.Subsequently,with the demand area as the simulation target and unsuitable areas as comprehensive constraints,the UDB was delineated by simulating future land use patterns.The proposed framework was applied to Wuhan,a rapidly urbanizing city in central China,where the delineation of the UDB serves the dual purpose of managing the rapid expansion of built-up land and achieving a harmonious balance between urban development imperatives and ecological protection goals.Moreover,based on the results and analysis,policy implications for the rational spatial planning of Wuhan were proposed,encompassing the spatial patterns and scientific decision-making in ecological conservation and urban development.The results demonstrate that the efficacy of adopting a comprehensive perspective in delineating UDB effectively reconciles the competing needs of urban development and conservation.The framework and the policy insights derived in this study could inform spatial planning efforts not only in Wuhan but also in other cities facing the dilemma of urban development and ecological protection.
基金supported by Scientific Research Foundation for Youth Scholars, IGSNRR, CAS, entitled “Evaluation on the conservation and development of agricultural heritage systems in China”
文摘Architectural heritage comprises one o the most important elements of mountain settlements in Greece. It holds high cultural value, represents the tangible continuation of the past and forms the unique character and identity of each mountain region. Yet, controversy regarding funding for its preservation often arises. In this paper, we used two Contingent Valuation surveys to estimate the socia benefit deriving from protecting the traditiona architecture in the mountainous village of Sirako and through it, to examine perceptions and attitudes o local residents and visitors. Research findings revealed a strong social will in favor of the good＇s protection followed by high percentages of positive willingness to pay（WTP）. However, WTP is significantly higher among residents. Cultura heritage value, of the good, appears to prevail, along with the environmental one. However, both residents and visitors pointed out that local heritage, if wellpreserved, will boost tourism development. Residents appeared to better recognize the true level o architectural decay, expressed higher apprehension for its protection and were willing to pay higher amount of money. Tourists, on the other side expressed high satisfaction for their visit, appreciated the beauty and serenity emerging from local built and natural environment and spent several days visiting the surrounding area. The longer they stayed and gotfamiliar with the village, the more willing they were to contribute to local heritage＇s protection. Percentages reflecting indifference for protecting architecture were extremely low. Yet, they were higher among tourists. Traditional architecture is considered as public good; an opinion resulting in an important percentage of visitors stating that national government should provide the necessary funding. In addition, the architecture appears to hold a high level of topicality. Those descending from Sirako or emotionally connected to it, of both social groups,turned out to be more concerned about the good and with a stronger sense of responsibility for it. Usevalue of the good holds high economic value, as well,while higher percentages of zero WTP appeared among non-users. Research findings revealed social attitudes and perceptions on what constitutes architectural heritage, in its cultural and economic frame. If taken under consideration, they may form useful drivers for local, heritage-based, sustainable
基金supported by the Shanghai Committee of Science and Technology Fund(22ZR1419300)the Academic Year 2025 Ritsumeikan Asia Pacific University Academic Research Subsidy(Grants-in-Aid Reapplication Type).
文摘Quantifying material use in infrastructure development and analyzing its relationship with economic growth is essential for enhancing resource efficiency and steering regional resource management toward sustainable development.This study systematically assessed infrastructure related material use in 30 provinces,autonomous regions,and municipalities in China during 1978-2022.The result indicated that material stock has experienced significant growth,increasing from 16.91×10^(9)t in 1978 to 103.60×10^(9)t in 2022,with an average annual growth rate of 4.20%.However,from 1978 to 2015,material input followed a strong upward trend but saturated after 2015.At the national level,material input peaked in 2015,after which it began to decline.The central region reached its peak earlier in 2013,while the eastern and western regions peaked in 2015.Using a decoupling analysis framework,this study revealed that nationally,the elasticity value between material stock and gross domestic product(GDP)remained near or above 1.0,reflecting continued reliance on stock accumulation.Regionally,the elasticity value between material stock and GDP has increased in the central and western regions during 1978-2022,whereas elasticity value between material stock and GDP in the eastern region showed a slower growth rate but still struggled to achieve absolute decoupling.Moreover,the elasticity value between material input and GDP has declined at the national level,presenting a relative decoupling,with some regions already achieving absolute decoupling.The eastern region was closer to absolute decoupling,while the central and western regions,though still intensive in material input,exhibited faster declines in elasticity.Accelerating the transition from linear to circular economy is an essential step for China to achieve absolute decoupling and long-term sustainability.Finally,this research recommends promoting the adoption of renewable energy,driving industrial upgrading,implementing compact urban design,and extending the lifespan of infrastructure to reduce material dependency and achieve sustainable infrastructure transformation at the national level.
文摘The extensive application of artificial intelligence(AI)technology is profoundly affecting the ecology of education.To analyze the advantages and disadvantages of AI for the professional growth of students,this study systematically analyzed the potential dual impacts of AI in higher education from two dimensions,namely academic ability and thinking patterns.Results indicated AI facilitated the development of students by improving learning efficiency and optimizing the integration of resources.However,it simultaneously aggravated the crisis of academic integrity and the inertia of thinking.In responding to these issues,this study proposed an integrated framework that included management,guidance,and standardization.This framework would facilitate the positive interaction between AI and education,contributing to the professional development of students.
文摘In October 2024,at the 27th ChinaASEAN Leaders'Meeting,the leaders of China and ten ASEAN nations announced the substantial conclusion of the China-ASEAN FTA 3.0 Upgrade Negotiations,and proposed that the two sides would strive to formally sign in 2025 the Protocol on Further Upgrading the China-ASEAN Comprehensive Economic Cooperation Framework Agreement and pertinent agreements under the Agreement.
文摘Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully constructed by coordinatively assembling the semi-rigid multidentate ligand 5-(1-carboxyethoxy)isophthalic acid(H₃CIA)with the Nheterocyclic ligands 1,4-di(4H-1,2,4-triazol-4-yl)benzene(1,4-dtb)and 1,4-di(1H-imidazol-1-yl)benzene(1,4-dib),respectively,around Co^(2+)ions.Single-crystal X-ray diffraction analysis revealed that in both complexes HU23 and HU24,the CIA^(3-)anions adopt aκ^(7)-coordination mode,bridging six Co^(2+)ions via their five carboxylate oxygen atoms and one ether oxygen atom.This linkage forms tetranuclear[Co4(μ3-OH)2]^(6+)units.These Co-oxo cluster units were interconnected by CIA^(3-)anions to assemble into 2D kgd-type structures featuring a 3,6-connected topology.The 2D layers were further connected by 1,4-dtb and 1,4-dib,resulting in 3D pillar-layered frameworks for HU23 and HU24.Notably,despite the similar configurations of 1,4-dtb and 1,4-dib,differences in their coordination spatial orientations lead to topological divergence in the 3D frameworks of HU23 and HU24.Topological analysis indicates that the frameworks of HU23 and HU24 can be simplified into a 3,10-connected net(point symbol:(4^(10).6^(3).8^(2))(4^(3))_(2))and a 3,8-connected tfz-d net(point symbol:(4^(3))_(2)((4^(6).6^(18).8^(4)))),respectively.This structural differentiation confirms the precise regulatory role of ligands on the topology of metal-organic frameworks.Moreover,the ultraviolet-visible absorption spectra confirmed that HU23 and HU24 have strong absorption capabilities for ultraviolet and visible light.According to the Kubelka-Munk method,their bandwidths were 2.15 and 2.08 eV,respectively,which are consistent with those of typical semiconductor materials.Variable-temperature magnetic susceptibility measurements(2-300 K)revealed significant antiferromagnetic coupling in both complexes,with their effective magnetic moments decreasing markedly as the temperature lowered.CCDC:2457554,HU23;2457553,HU24.
基金financially supported by the National Natural Science Foundation of China (Nos. 51973153, 22001191)。
文摘Covalent organic frameworks(COFs) are a class of crystalline porous organic materials with variable structures and fascinating properties. The intrinsic low conductivity impedes their widely application in optoelectronic. Iodine doping is an effective way to enhance the electrical conductivity of COFs. Here, a novel 3D imine COF with lvt topology is synthesized from two different pentacene derivatives with the same core in the form of structural complementarity. DDHP-COF is a highly crystalline material featuring high surface area of 1679 m^(2)/g and excellent thermal stability up to 490 ℃. Upon doping with iodine, the electrical conductivity can reach as high as 1.5×10^(-2)S/m which is significantly enhanced over 6 orders of magnitude compared with the pristine COF.
基金supported by the Analysis and Testing Foundation of Northeast Normal University
文摘A new heteropolyoxotungstate [（C2H4N2）4（P4Co3W4O28H6）（H2C2O4）]n with a three-dimensional framework was hydrothermally synthesized.The compound crystallizes in a tetragonal system,space group I41/a with a = 17.1006（17）,b = 17.1006（7）,c = 10.7525（5）,V = 3144.2（2）3,Z = 4,Dc = 3.795 g·cm-3,F（000） = 3300,MoKα（λ = 0.71073 ）,μ = 16.460 mm-1,the final R = 0.0335 and wR = 0.0776.In the heteropolyoxotungstate,tungsten-oxygen octahedra are linked by sharing two cis-vertexes into an infinite helical chain extending along the c axis.Cobalt atoms in the octahedral geometry act as the linkers of these chains,forming a three-dimensional framework.The cobalt and phosphorus atoms in the tetrahedral geometry play a role in stabilizing the three-dimensional framework.Ethylenediamine molecules are polymerized into organic chains which locate in the interspaces of the framework in the way of interwinding with the W-O chains.
文摘The increasing use of digital video everyday in a multitude of electronic devices, including mobile phones, tablets and laptops, poses the need for quick development of cross-platform video software. However current approaches to this direction usually require a long learning curve, and their development lacks standardization. This results in software components that are difficult to reuse, and hard to maintain or extend. In order to overcome such issues, we propose a novel object-oriented framework for efficient development of software systems for video analysis. It consists of a set of four abstract components, suitable for the implementation of independent plug-in modules for video acquisition, preprocessing, analysis and output handling. The extensibility of each module can be facilitated by sub-modules specifying additional functionalities. This architecture enables quick responses to changes and re-configurability;thus conforming to the requirements of agile software development practices. Considering the need for platform independency, the proposed Java Video Analysis (JVA) framework is implemented in Java. It is publicly available through the web as open-access software, supported by a growing collection of implemented modules. Its efficiency is empirically validated for the development of a representative video analysis system.
文摘Along with the history of the development of financial regulation, we can see that the theory of evolution has experienced from financial liberalization to financial supervision, financial regulation, then to the stage both with the safety and efficiency of financial supervision ; development of the theory of financial regulation experienced the theory of financial supervision represented by classical economics and neo- classical economic theory, to the Keynesian theory and financial repression theory, financial fragility hypothesis, the progressive liberalization of the financial road, then to the financial regulatory theory, regulatory function theory concept, regulatory incentives theory under the framework of economics of information in the 1990s. You can see the way scholars will not have feared in the study of financial regulation, and each theory proposed has its special significance in the special economic and financial environment at the time, and we can not necessarily say what kind of theory is advanced in other theory.
基金supported by the National Planning Office of Philosophy and Social Science(Grant No.06BTQ027)
文摘The evolution of the society and economy has stimulated the development of Knowledge Service(KS), making it an indispensable solution to address future challenges facing libraries and information institutions. However at present, academic research on knowledge service is falling short and its definition is far from clear and complete. As such,this article proposes the Three-dimensional Framework Knowledge Service(TdFKS) for libraries and information institutions based on the knowledge value chain model. By making reliability analysis and mean value analysis of a questionnaire survey result, the article clarifies the structure of the three-dimensional framework and verifies the rationality of the TdFKS.
