A new model of a triple-terminal quantum ring with three arms is proposed.We develop an equivalent method for reducing the triple-terminal quantum ring to the double-terminal quantum ring and calculate the persistent ...A new model of a triple-terminal quantum ring with three arms is proposed.We develop an equivalent method for reducing the triple-terminal quantum ring to the double-terminal quantum ring and calculate the persistent spin currents in this model.The results indicate that the persistent spin currents show behavior of nonperiodic and unequal amplitude oscillation with increasing semiconductor ring size when the total magnetic flux is zero. However,when the total magnetic flux is non-zero,the persistent spin currents make periodic equal amplitude oscillations with increasing AB magnetic flux intensity.At the same time,the two kinds of spin state persistent spin currents have the same frequency and amplitude but the inverse phase.In addition,the Rashba spin-orbit interaction affects the phase and the phase difference of the persistent spin currents.The average persistent spin currents relate to the arm length and the terminal position as well as the distribution of the magnetic flux in each arm.Furthermore, our results indicate that the AB magnetic flux has different influences on the two kinds of spin state electrons.展开更多
A versatile and effective method for incorporating functional groups on the pore wall of three-dimensionally ordered macroporous cross-linked polystyrene（3DOM CLPS） by hydrophilic spacer arm has been investigated.Th...A versatile and effective method for incorporating functional groups on the pore wall of three-dimensionally ordered macroporous cross-linked polystyrene（3DOM CLPS） by hydrophilic spacer arm has been investigated.The 3DOM CLPS with pore size 865 nm was prepared by sacrifice template method.The hydrophilic spacer arm（polyethylene glycol,molecular weight is 600） was grafted to the 3DOM CLPS via nucleophilic substitution reaction.The other side of active hydroxyl can be further converted into a lot of other functional groups.In this report,the chelating ligand 2-mercaptobenzothiazole（MBZ） group was introduced on the end of the PGE chain to evidence the versatile functionalization approach.The functionalized ordered macroporous materials were characterized by FT-IR,element analyzer,SEM.The results reveal that the pores were successfully bonded with 2-mercaptobenzothiazole groups via hydrophilic spacer arms and the original morphology of ordered macroporous materials were remained after functionalization.The MBZ group density is 0.052 mmol/m^2.The functionalized 3DOM CLPS are expected to application as heavy metal ions adsorbent.展开更多
基金Project supported by the Natural Foundation of the Bureau of Education of Hebei Province,China(NoZ2008103)
文摘A new model of a triple-terminal quantum ring with three arms is proposed.We develop an equivalent method for reducing the triple-terminal quantum ring to the double-terminal quantum ring and calculate the persistent spin currents in this model.The results indicate that the persistent spin currents show behavior of nonperiodic and unequal amplitude oscillation with increasing semiconductor ring size when the total magnetic flux is zero. However,when the total magnetic flux is non-zero,the persistent spin currents make periodic equal amplitude oscillations with increasing AB magnetic flux intensity.At the same time,the two kinds of spin state persistent spin currents have the same frequency and amplitude but the inverse phase.In addition,the Rashba spin-orbit interaction affects the phase and the phase difference of the persistent spin currents.The average persistent spin currents relate to the arm length and the terminal position as well as the distribution of the magnetic flux in each arm.Furthermore, our results indicate that the AB magnetic flux has different influences on the two kinds of spin state electrons.
基金supported by National Natural Science Funds for Young Scholar(No.50903027)the Natural Science Foundation of Hebei Province(No.E2010000058)Education Department Science Research Plan of Hebei Province(No.2007307).
文摘A versatile and effective method for incorporating functional groups on the pore wall of three-dimensionally ordered macroporous cross-linked polystyrene（3DOM CLPS） by hydrophilic spacer arm has been investigated.The 3DOM CLPS with pore size 865 nm was prepared by sacrifice template method.The hydrophilic spacer arm（polyethylene glycol,molecular weight is 600） was grafted to the 3DOM CLPS via nucleophilic substitution reaction.The other side of active hydroxyl can be further converted into a lot of other functional groups.In this report,the chelating ligand 2-mercaptobenzothiazole（MBZ） group was introduced on the end of the PGE chain to evidence the versatile functionalization approach.The functionalized ordered macroporous materials were characterized by FT-IR,element analyzer,SEM.The results reveal that the pores were successfully bonded with 2-mercaptobenzothiazole groups via hydrophilic spacer arms and the original morphology of ordered macroporous materials were remained after functionalization.The MBZ group density is 0.052 mmol/m^2.The functionalized 3DOM CLPS are expected to application as heavy metal ions adsorbent.
