Disinfection of swimming pool water is critical to ensure the safety of the recreational activity for swimmers.However,swimming pools have a constant loading of organic matter from input water and anthropogenic contam...Disinfection of swimming pool water is critical to ensure the safety of the recreational activity for swimmers.However,swimming pools have a constant loading of organic matter from input water and anthropogenic contamination,leading to elevated levels of disinfection byproducts(DBPs).Epidemiological studies have associated increased risks of adverse health effects with frequent exposure to DBPs in swimming pools.Zhang et al.(2023b)investigated the occurrence of trihalomethanes(THMs),haloacetic acids(HAAs),haloacetonitriles(HANs),and haloacetaldehydes(HALs)in eight swimming pools and the corresponding input water in a city in Eastern China.The concentrations of THMs,HAAs,HANs,and HALs in swimming poolswere 1–2 orders of magnitude higher than those detected in the input water.The total lifetime cancer and non-cancer health risks of swimmers through oral,dermal,inhalation,buccal,and aural exposure pathways were assessed using the United States Environmental Protection Agency’s(USEPA)standard model and Swimmer Exposure Assessment Model(SWIMODEL).The results showed that dermal and inhalation pathways were the most significant for the associated cancer and non-cancer risks.This article provides an overview and perspectives of DBPs in swimming pools,the benefits of swimming,the need to improve the monitoring of DBPs,and the importance of swimmers’hygiene practices to keep swimming pools clean.The benefits of swimming outweigh the risks from DBP exposure for the promotion of public health.展开更多
The utilization of coalbed methane(CBM)cannot only alleviate the energy crisis,but also reduce greenhouse gas emissions.Gas injection is an effective method to enhance CBM recovery.Compared to single-gas injection,the...The utilization of coalbed methane(CBM)cannot only alleviate the energy crisis,but also reduce greenhouse gas emissions.Gas injection is an effective method to enhance CBM recovery.Compared to single-gas injection,the injection of CO_(2)/N_(2) mixtures can balance the sharp decline in permeability caused by pure CO_(2) and the premature breakthrough by pure N_(2).In this study,a more comprehensive thermo-hydro-mechanical(THM)coupled mathematical model was developed,incorporating processes such as ternary gas non-isothermal adsorption,gas dissolution in water,gas-water two-phase flow,energy exchange,and coal deformation.After experimental validation,the model was applied to simulate the entire process of gas mixtures for enhanced CBM recovery(GM-ECBM).Results indicate that the permeability near the production well(Pw)initially decreases due to increased effective stress,then increases as a result of CH_(4) desorption.Near the injection well(Iw),the permeability first increases due to reduced effective stress and later stabilizes under the combined effects of effective stress and CO_(2)/N_(2) adsorption.The initial CH_(4) pressure and coal seam permeability have the most significant impact on CH_(4) production,while the coal seam permeability and temperature significantly affect CO_(2)/N_(2) injection.As the coal seam permeability increases,the optimal CO_(2)/N_(2) ratio also increases accordingly.These findings provide important theoretical guidance for improving GM-ECBM efficiency in coal seams with varying permeabilities.展开更多
This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening aft...This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening after peak strength, anisotropy of stiffness and strength, as well as permeability variation due to damage. In addition, the mechanical properties are coupled with thermal phenomena and accumulated plastic strains. The adopted nonlocal and viscoplastic approaches enhance numerical efficiency and provide the possibility to simulate localization phenomena. The model is validated against experimental data from laboratory tests conducted on Callovo-Oxfordian (COx) claystone samples that are initially unsaturated and under suction. The tests include a thermal phase where the COx specimens are subjected to different temperature increases. A good agreement with experimental data is obtained. In addition, parametric analyses are carried out to investigate the influence of the hydraulic boundary conditions (B.C.) and post-failure behavior models on the THM behavior evolution. It is shown that different drainage conditions affect the thermally induced pore pressures that, in turn, influence the onset of softening. The constitutive model presented constitutes a promising approach for simulating the most important features of the THM behavior of clay rocks. It is a tool with a high potential for application to several relevant case studies, such as thermal fracturing analysis of nuclear waste disposal systems.展开更多
Understanding strain and fracture evolution in rock masses under climate change is crucial for slope stability.This study presents a fully coupled thermo-hydro-mechanical(THM)simulation of a rock slope at the Požá...Understanding strain and fracture evolution in rock masses under climate change is crucial for slope stability.This study presents a fully coupled thermo-hydro-mechanical(THM)simulation of a rock slope at the Požáry test site in the Czech Republic,integrating field tests and laboratory analyses.The simulations used the exactly measured slope geometry and incorporated a pre-existing upper slope fracture.Key constitutive models for fluid and vapor flow,heat conduction,and porosity-dependent permeability were coupled with a viscoplastic damage model to capture the THM behavior of the rock slope.Laboratory tests on three rock samples(A,B,and C)with varying elastic moduli and porosities informed the material properties for three corresponding models.Simulation results showed greater thermal changes in the upper sections of the slope due to increased exposure to thermal effects.Model A,with the highest elastic modulus,exhibited lower initial strain changes,while Model C showed significant early strain variations.After 30 d,Model A experienced a sudden strain decrease due to thermal contraction-induced damage.The critical fractured zone(CFZ)analysis revealed that rock contraction under cooling led to an increase in pore water pressure,exacerbating the damage.Model B highlighted the impact of geometrical asymmetry on the propagation of the damaged zone.Over time,the thermal effects increased plastic deformation in Model A,while Model C remained elastic and exhibited no damage.These findings have significant implications for assessing rock slope stability,particularly in predicting failure zones due to permeability reduction and pore water pressure generation.展开更多
The freeze-thaw(FT)behavior of porous materials(PMs)involves the coupling of the thermo-hydromechanical(THM)processes and is significantly influenced by the microstructure.However,modeling FT in unsaturated PMs remain...The freeze-thaw(FT)behavior of porous materials(PMs)involves the coupling of the thermo-hydromechanical(THM)processes and is significantly influenced by the microstructure.However,modeling FT in unsaturated PMs remains an open issue,and the influence of microstructure is not yet fully understood.To address these challenges,we propose a THM model for FT in PMs that considers microstructure and variable air content.In this work,a non-equilibrium thermodynamic approach is proposed to capture ice formation/melting,the microstructure is accounted for utilizing micromechanics,and the FT processes in air-entrained PMs are formulated within the proposed THM model.This model incorporates variable air void characteristics,e.g.air content,spacing factor,specific surface area,and supercooled water-filled regimes,and distinguishes the roles of air voids between freezing and thawing.The FT behaviors,including deformation,ice formation/melting,spacing factor,and pore water pressure evolutions,are focused.Comparisons with experimental results,confirm the capability of the present model.The results demonstrate the effects of variable air voids on the FT behavior of air-entrained PMs.The findings reveal that assuming fixed air void characteristics can lead to underestimation of pore pressure and deformation,particularly at low air content.Additionally,air voids act as cryo-pumps during freezing and when the cooling temperature stabilizes.During thawing,air voids supply gas to the melting sites(i.e.“gas escape”),preventing further significant deformation reduction.These results can provide novel insights for understanding the frost damage of PMs.展开更多
In this study,a powerful thermo-hydro-mechanical(THM)coupling solution scheme for saturated poroelastic media involving brittle fracturing is developed.Under the local thermal non-equilibrium(LTNE)assumption,this sche...In this study,a powerful thermo-hydro-mechanical(THM)coupling solution scheme for saturated poroelastic media involving brittle fracturing is developed.Under the local thermal non-equilibrium(LTNE)assumption,this scheme seamlessly combines the material point method(MPM)for accurately tracking solid-phase deformation and heat transport,and the Eulerian finite element method(FEM)for effectively capturing fluid flow and heat advection-diffusion behavior.The proposed approach circumvents the substantial challenges posed by large nonlinear equation systems with the monolithic solution scheme.The staggered solution process strategically separates each physical field through explicit or implicit integration.The characteristic-based method is used to stabilize advection-dominated heat flows for efficient numerical implementation.Furthermore,a fractional step approach is employed to decompose fluid velocity and pressure,thereby suppressing pore pressure oscillation on the linear background grid.The fracturing initiation and propagation are simulated by a rate-dependent phase field model.Through a series of quasi-static and transient simulations,the exceptional performance and promising potential of the proposed model in addressing THM fracturing problems in poro-elastic media is demonstrated.展开更多
文摘Disinfection of swimming pool water is critical to ensure the safety of the recreational activity for swimmers.However,swimming pools have a constant loading of organic matter from input water and anthropogenic contamination,leading to elevated levels of disinfection byproducts(DBPs).Epidemiological studies have associated increased risks of adverse health effects with frequent exposure to DBPs in swimming pools.Zhang et al.(2023b)investigated the occurrence of trihalomethanes(THMs),haloacetic acids(HAAs),haloacetonitriles(HANs),and haloacetaldehydes(HALs)in eight swimming pools and the corresponding input water in a city in Eastern China.The concentrations of THMs,HAAs,HANs,and HALs in swimming poolswere 1–2 orders of magnitude higher than those detected in the input water.The total lifetime cancer and non-cancer health risks of swimmers through oral,dermal,inhalation,buccal,and aural exposure pathways were assessed using the United States Environmental Protection Agency’s(USEPA)standard model and Swimmer Exposure Assessment Model(SWIMODEL).The results showed that dermal and inhalation pathways were the most significant for the associated cancer and non-cancer risks.This article provides an overview and perspectives of DBPs in swimming pools,the benefits of swimming,the need to improve the monitoring of DBPs,and the importance of swimmers’hygiene practices to keep swimming pools clean.The benefits of swimming outweigh the risks from DBP exposure for the promotion of public health.
基金supported by the National Natural Science Foundation of China(Grant No.52174117)the Universitylocal Government Scientific and Technical Cooperation Cultivation Project of Ordos Institute-LNTU(Grant No.YJY-XD-2024-A-009)+2 种基金the Basic Scientific Research Project of Liaoning Provincial Department of Education(Grant No.JYTZD2023073)the Liaoning Revitalization Talents Program(XLYC2203139)the Liaoning Provincial Natural Science Foundation Program(Excellent Youth Fund)(Grant No.2024JH3/10200043).
文摘The utilization of coalbed methane(CBM)cannot only alleviate the energy crisis,but also reduce greenhouse gas emissions.Gas injection is an effective method to enhance CBM recovery.Compared to single-gas injection,the injection of CO_(2)/N_(2) mixtures can balance the sharp decline in permeability caused by pure CO_(2) and the premature breakthrough by pure N_(2).In this study,a more comprehensive thermo-hydro-mechanical(THM)coupled mathematical model was developed,incorporating processes such as ternary gas non-isothermal adsorption,gas dissolution in water,gas-water two-phase flow,energy exchange,and coal deformation.After experimental validation,the model was applied to simulate the entire process of gas mixtures for enhanced CBM recovery(GM-ECBM).Results indicate that the permeability near the production well(Pw)initially decreases due to increased effective stress,then increases as a result of CH_(4) desorption.Near the injection well(Iw),the permeability first increases due to reduced effective stress and later stabilizes under the combined effects of effective stress and CO_(2)/N_(2) adsorption.The initial CH_(4) pressure and coal seam permeability have the most significant impact on CH_(4) production,while the coal seam permeability and temperature significantly affect CO_(2)/N_(2) injection.As the coal seam permeability increases,the optimal CO_(2)/N_(2) ratio also increases accordingly.These findings provide important theoretical guidance for improving GM-ECBM efficiency in coal seams with varying permeabilities.
基金funded by the European Union's Horizon 2020 research and innovation programme under a grant agreement (Grant No.847593)partially supported by the Fundamental Research Funds for the Central Universities (Grant No.22120240029).
文摘This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening after peak strength, anisotropy of stiffness and strength, as well as permeability variation due to damage. In addition, the mechanical properties are coupled with thermal phenomena and accumulated plastic strains. The adopted nonlocal and viscoplastic approaches enhance numerical efficiency and provide the possibility to simulate localization phenomena. The model is validated against experimental data from laboratory tests conducted on Callovo-Oxfordian (COx) claystone samples that are initially unsaturated and under suction. The tests include a thermal phase where the COx specimens are subjected to different temperature increases. A good agreement with experimental data is obtained. In addition, parametric analyses are carried out to investigate the influence of the hydraulic boundary conditions (B.C.) and post-failure behavior models on the THM behavior evolution. It is shown that different drainage conditions affect the thermally induced pore pressures that, in turn, influence the onset of softening. The constitutive model presented constitutes a promising approach for simulating the most important features of the THM behavior of clay rocks. It is a tool with a high potential for application to several relevant case studies, such as thermal fracturing analysis of nuclear waste disposal systems.
基金support from the European Commission via a Marie Curie Fellowship(Grant No.101033084)awarded to Dr.Saeed Tourchi(corresponding author)the Research Grant Office at Sharif University of Technology for grants G4010902 and QB020105funding from the TACR project SS02030023,Rock Environment and Resources,under the“Environment for Life”program and the Institutional Research Plan RVO67985891 of the Institute of Rock Structure and Mechanics of the Czech Academy of Sciences.
文摘Understanding strain and fracture evolution in rock masses under climate change is crucial for slope stability.This study presents a fully coupled thermo-hydro-mechanical(THM)simulation of a rock slope at the Požáry test site in the Czech Republic,integrating field tests and laboratory analyses.The simulations used the exactly measured slope geometry and incorporated a pre-existing upper slope fracture.Key constitutive models for fluid and vapor flow,heat conduction,and porosity-dependent permeability were coupled with a viscoplastic damage model to capture the THM behavior of the rock slope.Laboratory tests on three rock samples(A,B,and C)with varying elastic moduli and porosities informed the material properties for three corresponding models.Simulation results showed greater thermal changes in the upper sections of the slope due to increased exposure to thermal effects.Model A,with the highest elastic modulus,exhibited lower initial strain changes,while Model C showed significant early strain variations.After 30 d,Model A experienced a sudden strain decrease due to thermal contraction-induced damage.The critical fractured zone(CFZ)analysis revealed that rock contraction under cooling led to an increase in pore water pressure,exacerbating the damage.Model B highlighted the impact of geometrical asymmetry on the propagation of the damaged zone.Over time,the thermal effects increased plastic deformation in Model A,while Model C remained elastic and exhibited no damage.These findings have significant implications for assessing rock slope stability,particularly in predicting failure zones due to permeability reduction and pore water pressure generation.
基金the funding support from the National Natural Science Foundation of China(Grant Nos.52350004 and 51925903).
文摘The freeze-thaw(FT)behavior of porous materials(PMs)involves the coupling of the thermo-hydromechanical(THM)processes and is significantly influenced by the microstructure.However,modeling FT in unsaturated PMs remains an open issue,and the influence of microstructure is not yet fully understood.To address these challenges,we propose a THM model for FT in PMs that considers microstructure and variable air content.In this work,a non-equilibrium thermodynamic approach is proposed to capture ice formation/melting,the microstructure is accounted for utilizing micromechanics,and the FT processes in air-entrained PMs are formulated within the proposed THM model.This model incorporates variable air void characteristics,e.g.air content,spacing factor,specific surface area,and supercooled water-filled regimes,and distinguishes the roles of air voids between freezing and thawing.The FT behaviors,including deformation,ice formation/melting,spacing factor,and pore water pressure evolutions,are focused.Comparisons with experimental results,confirm the capability of the present model.The results demonstrate the effects of variable air voids on the FT behavior of air-entrained PMs.The findings reveal that assuming fixed air void characteristics can lead to underestimation of pore pressure and deformation,particularly at low air content.Additionally,air voids act as cryo-pumps during freezing and when the cooling temperature stabilizes.During thawing,air voids supply gas to the melting sites(i.e.“gas escape”),preventing further significant deformation reduction.These results can provide novel insights for understanding the frost damage of PMs.
基金supported by National Natural Science Foundation of China(Grant No.42377149)the Research Grants Council of Hong Kong(General Research Fund Project No.17202423).
文摘In this study,a powerful thermo-hydro-mechanical(THM)coupling solution scheme for saturated poroelastic media involving brittle fracturing is developed.Under the local thermal non-equilibrium(LTNE)assumption,this scheme seamlessly combines the material point method(MPM)for accurately tracking solid-phase deformation and heat transport,and the Eulerian finite element method(FEM)for effectively capturing fluid flow and heat advection-diffusion behavior.The proposed approach circumvents the substantial challenges posed by large nonlinear equation systems with the monolithic solution scheme.The staggered solution process strategically separates each physical field through explicit or implicit integration.The characteristic-based method is used to stabilize advection-dominated heat flows for efficient numerical implementation.Furthermore,a fractional step approach is employed to decompose fluid velocity and pressure,thereby suppressing pore pressure oscillation on the linear background grid.The fracturing initiation and propagation are simulated by a rate-dependent phase field model.Through a series of quasi-static and transient simulations,the exceptional performance and promising potential of the proposed model in addressing THM fracturing problems in poro-elastic media is demonstrated.
