In this paper, the phase diagram of the DyCl_3-NaCl system is optimized and calculated with CALPHAD (calculation of phase diagram) technology. A set of thermodynamic functions of compounds Na_3DyCl_6, NaDyCl_4, and Na...In this paper, the phase diagram of the DyCl_3-NaCl system is optimized and calculated with CALPHAD (calculation of phase diagram) technology. A set of thermodynamic functions of compounds Na_3DyCl_6, NaDyCl_4, and NaDy_2Cl_7 have been optimized and calculated based on an interactive computer-assisted analysis. The optimized thermodynamic parameters, calculated phase diagram and experimental phase diagram are thermodynamically self-consistent.展开更多
From the measured phase equilibria data and experimental thermochemical properties, the TmCl_3-ACl (A=Na, K, Rb, Cs) phase diagrams were optimized and calculated using the CALPHAD technique. For describing the Gibbs e...From the measured phase equilibria data and experimental thermochemical properties, the TmCl_3-ACl (A=Na, K, Rb, Cs) phase diagrams were optimized and calculated using the CALPHAD technique. For describing the Gibbs energies of the liquid phase in these systems, the new modified quasichemical model in the pair-approximation for short-range ordering was used. A set of thermodynamic functions was optimized and gotten based on an interactive computer-assisted analysis. The calculated phase diagrams and thermodynamic data are self-consistent.展开更多
From the measured phase diagram data and experimental thermochemical properties, the DyCl3-KCl and DyCl3-CaCl2 phase diagrams were optimized and calculated by the CALPHAD technique. The Gibbs energies of liquid phase ...From the measured phase diagram data and experimental thermochemical properties, the DyCl3-KCl and DyCl3-CaCl2 phase diagrams were optimized and calculated by the CALPHAD technique. The Gibbs energies of liquid phase in the two systems has been optimized and calculated by new modified quasi-chemical model in the pair-approximation for short-range ordering, and a series of thermodynamic functions has also been optimized based on an interactive computer-assisted analysis. The results showed that the calculated phase diagrams and thermodynamic data were serf-consistent.展开更多
Based on the phase diagram of the Fe-Pr system available,the thermodynamic optimization and calcula- tion of the system have been carried out by the least square method.The lattice stabilities of Fe and Pr are describ...Based on the phase diagram of the Fe-Pr system available,the thermodynamic optimization and calcula- tion of the system have been carried out by the least square method.The lattice stabilities of Fe and Pr are described by the expression recommended by SGTE organization.The liquid phase is described by the subregular solution model.The intermetallic compounds,Fe_(17)Pr_2 and Fe_2Pr,are treated as stoichiometric compounds.The optimized parameters describing phases in the system are presented.The comparision be- tween the calculated and experimentally determined phase diagram shows that the agreement is generally very good except for the liquid+δ-Fe equilibrium.It is suggested to measure this part of phase diagram again.展开更多
In this paper a critical assessment and optimization of the phase diagrams and thermodynamic properties of the PrCl_3-MCl(M=Li,Na)and PrCl_3-MCl_2(M=Mg,Ca,Sr,Ba) binary systems have been per- formed.The assessed and o...In this paper a critical assessment and optimization of the phase diagrams and thermodynamic properties of the PrCl_3-MCl(M=Li,Na)and PrCl_3-MCl_2(M=Mg,Ca,Sr,Ba) binary systems have been per- formed.The assessed and optimized binary phase diagrams and thermodynamic data with self consistency are a better basis for constructing multicomponent phase diagrams.展开更多
The relationship between engine mechanics and thermo-dynamics has been investigated by means of numerical simulation.The inherent mismatching between the mechanical behaviors and the thermodynamic process in internal ...The relationship between engine mechanics and thermo-dynamics has been investigated by means of numerical simulation.The inherent mismatching between the mechanical behaviors and the thermodynamic process in internal combustion engine is identified,which is believed to be one of the important limiting factors of energy efficiency for conventional engines available in the current market.An approach for engine efficiency improvement through optimal matching between mechanics and thermodynamics(OMBMT)is proposed.An ideal matching model is defined and the conflicts due to the constraints among the mapping strokes in a 4-stroke engine are analyzed.A novel mechanical model is built for approaching optimal matching among all 4 individual strokes in a 4-stroke spark-ignition engine,which is composed of non-circular gears(NCG)and integrated with conventional slider crank engine mechanism.By means of digital mechanical model and numerical simulation,the matching gains among all 4 strokes are defined and calculated for quantifying the NCG engine efficiency improvement by comparing with a baseline engine.The potentials with the OMBMT implemented and the enhancements made by NCG mechanism for engines in terms of overall engine efficiency are reported.Based on the results achieved,it is recommended that the feasibility studies and the experimental validations should be conducted to verify the engine matching concept and effectiveness of the NCG mechanism engine model proposed,and the engine performance and NCG design parameters should be further optimized.展开更多
The mass entransy and its dissipation extremum principle have opened up a new direction for the mass transfer optimization. Firstly, the emergence and development process of both the mass entransy and its dissipalion ...The mass entransy and its dissipation extremum principle have opened up a new direction for the mass transfer optimization. Firstly, the emergence and development process of both the mass entransy and its dissipalion extremum principle are reviewed. Secondly, the combination of the mass entransy dissipation extremum principle and the finite-time thermodynamics for opti- mizing the mass transfer processes of one-way isothermal mass transfer, two-way isothermal equimolar mass transfer, and iso- thermal throttling and isothermal crystallization are summarized. Thirdly, the combination of the mass entransy dissipation ex- tremum principle and the constructal theory for optimizing the mass transfer processes of disc-to-point and volume-to-point problems are summarized. The scientific features of the mass entransy dissipation extremam principle are emphasized.展开更多
The constructal optimizations of T-shaped fin with two-dimensional heat transfer model are carried out by finite element method and taking the minimization of equivalent thermal resistance based on entransy dissipatio...The constructal optimizations of T-shaped fin with two-dimensional heat transfer model are carried out by finite element method and taking the minimization of equivalent thermal resistance based on entransy dissipation and the minimization of maximum thermal resistance as optimization objectives, respectively. The effects of the global parameter a (integrating the coefficient of convective heat transfer, the overall area occupied by fin and its thermal conductivity) and the volume fraction ? of fin on the minimums of equivalent thermal resistance and maximum thermal resistance as well as their corresponding optimal configurations are analyzed. The comparison of the results based on the above two optimization objectives is conducted. The results show that the optimal structures based on the two optimization objectives are obviously different from each other. Compared with the optimization result by taking the minimization of maximum thermal resistance as the objective, the optimization result by taking the equivalent thermal resistance minimization as the objective can reduce the average temperature difference in the fin obviously. The increases of a and ? can all improve the working status of local hot spot and the global heat transfer performance of the system. But the improvement effects of the increases of a and ? on the minimization of equivalent thermal resistance are different from those on the minimization of maximum thermal resistance. For either objective, the effect of a is different from that of ?. The T-shaped fin with minimum equivalent thermal resistance is much taller than that with minimum maximum thermal resistance; for either optimization objective, the stem of fin is thicker than the branches of fin, and the stem thickness is relatively close to branch thickness when the minimization of equivalent thermal resistance is taken as the optimization objective. The T-shaped fin with flat stem and slender branches can benefit the reduction of the maximum thermal resistance.展开更多
Based on constructal theory,the constructs of three "volume-point" heat conduction models with three-dimensional cylindrical element and rectangular and triangular elements on microscale and nanoscale are op...Based on constructal theory,the constructs of three "volume-point" heat conduction models with three-dimensional cylindrical element and rectangular and triangular elements on microscale and nanoscale are optimized by taking minimum entransy dissipation rate as optimization objective.The optimal constructs of the three "volume-point" heat conduction models with minimum dimensionless equivalent thermal resistance are obtained.The results show that the optimal constructs of the three-dimensional cylindrical assembly based on the minimizations of dimensionless equivalent thermal resistance and dimensionless maximum thermal resistance are different,which is obviously different from the comparison between those of the corresponding two-dimensional rectangular assembly based on the minimizations of these two objectives.The optimal constructs based on rectangular and triangular elements on microscale and nanoscale when the size effect takes effect are obviously different from those when the size effect does not take effect.Because the thermal current density in the high conductivity channel of the rectangular and triangular second order assemblies are not linear with the length,the optimal constructs of these assemblies based on the minimization of entransy dissipation rate are different from those based on the minimization of maximum temperature difference.The dimensionless equivalent thermal resistance defined based on entransy dissipation rate reflects the average heat transfer performance of the construct.The studies on "volume-point" heat conduction constructal problems at three-dimensional conditions and microscale and nanoscale by taking minimum entransy dissipation rate as optimization objective extend the application range of the entransy dissipation extremum principle.展开更多
Based on constructal theory and entransy theory,a generalized constructal optimization of a solidification heat transfer process of slab continuous casting for a specified total water flow rate in the secondary coolin...Based on constructal theory and entransy theory,a generalized constructal optimization of a solidification heat transfer process of slab continuous casting for a specified total water flow rate in the secondary cooling zone was carried out.A complex function was taken as the optimization objective to perform the casting.The complex function was composed of the functions of the entransy dissipation and surface temperature gradient of the slab.The optimal water distribution at the sections of the secondary cooling zone were obtained.The effects of the total water flow rate in the secondary cooling zone,casting speed,superheat and water distribution on the generalized constructal optimizations of the secondary cooling process were analyzed.The results show that on comparing the optimization results obtained based on the optimal water distributions of the 8 sections in the secondary cooling zone with those based on the initial ones,the complex function and the functions of the entransy dissipation and surface temperature gradient after optimization decreased by 43.25%,5.90%and 80.60%,respectively.The quality and energy storage of the slab had obviously improved in this case.The complex function,composed of the functions of the entransy dissipation and surface temperature gradient of the slab,was a compromise between the internal and surface temperature gradients of the slab.Essentially,it is also the compromise between energy storage and quality of the slab.The"generalized constructal optimization"based on the minimum complex function can provide an optimal alternative scheme from the point of view of improving energy storage and quality for the parameter design and dynamic operation of the solidification heat transfer process of slab continuous casting.展开更多
Analogizing with the heat conduction process, the entransy dissipation extremum principle for thermal insulation process can be described as: for a fixed boundary heat flux (heat loss) with certain constraints, the th...Analogizing with the heat conduction process, the entransy dissipation extremum principle for thermal insulation process can be described as: for a fixed boundary heat flux (heat loss) with certain constraints, the thermal insulation process is optimized when the entransy dissipation is maximized (maximum average temperature difference), while for a fixed boundary temperature, the thermal insulation process is optimized when the entransy dissipation is minimized (minimum average heat loss rate). Based on the constructal theory, the constructal optimizations of a single plane and cylindrical insulation layers as well as multi-layer insulation layers of the steel rolling reheating furnace walls are carried out for the fixed boundary temperatures and by taking the minimization of entransy dissipation rate as optimization objective. The optimal constructs of these three kinds of insulation structures with distributed thicknesses are obtained. The results show that compared with the insulation layers with uniform thicknesses and the optimal constructs of the insulation layers obtained by minimum heat loss rate, the optimal constructs of the insulation layers obtained by minimum entransy dissipation rate are obviously different from those of the former two insulation layers; the optimal constructs of the insulation layers obtained by minimum entransy dissipation rate can effectively reduce the average heat loss rates of the insulation layers, and can help to improve their global thermal insulation performances. The entransy dissipation extremum principle is applied to the constructal optimizations of insulation systems, which will help to extend the application range of the entransy dissipation extremum principle.展开更多
Based on constructal theory and entransy theory,the optimal designs of constant-and variable-cross-sectional cylindrical heat sources are carried out by taking dimensionless equivalent resistance minimization as optim...Based on constructal theory and entransy theory,the optimal designs of constant-and variable-cross-sectional cylindrical heat sources are carried out by taking dimensionless equivalent resistance minimization as optimization objective.The effects of the cylindrical height,the cylindrical shape and the ratio of thermal conductivity of the fin to that of the heat source are analyzed.The results show that when the volume of the heat source is fixed,there exists an optimal ratio of the center-to-centre distance of the fin and the heat source to the cylinder radius which leads to the minimum dimensionless equivalent thermal resistance.With the increase in the height of the cylindrical heat source and the ratio of thermal conductivity,the minimum dimensionless equivalent thermal resistance decreases gradually.For the heat source model with inverted variable-cross-sectional cylinder,there exist an optimal ratio of the center-to-centre distance of the fin and the heat source to the cylinder radius and an optimal radius ratio of the smaller and bigger circles of the cylindrical fin which lead to a double minimum dimensionless equivalent thermal resistance.Therefore,the heat transfer performance of the cylindrical heat source is improved by adopting the cylindrical model with variable-cross-section.The optimal constructs of the cylindrical heat source based on the minimizations of dimensionless maximum thermal resistance and dimensionless equivalent thermal resistance are different.When the thermal security is ensured,the optimal construct of the cylindrical heat source based on minimum equivalent thermal resistance can provide a new alternative scheme for the practical design of heat source.The results obtained herein enrich the work of constructal theory and entransy theory in the optimal design field of the heat sources,and they can provide some guidelines for the designs of practical heat source systems.展开更多
A strip laminar cooling process is investigated in this paper. Entransy theory and generalized constructal optimization are introduced into the optimization. Total water flow amount(WFA) in the laminar cooling zone(LC...A strip laminar cooling process is investigated in this paper. Entransy theory and generalized constructal optimization are introduced into the optimization. Total water flow amount(WFA) in the laminar cooling zone(LCZ) and complex function are taken as the constraint and optimization objective, respectively. The entransy dissipation(ED) and maximum temperature different(MTD) of the strip are simultaneously considered in the complex function. WFA distributions of the headers in the LCZ are optimized. The effects of the total WFA, strip thickness and cooling water temperature on the optimal results are analyzed.The optimal cooling scheme is the eleventh cooling mode for the considered total 257 cooling schemes, and the complex function,ED and MTD of the strip are decreased by 11.59%, 5.59% and 17.58% compared with the initial cooling scheme, respectively.The total WFA and strip thickness have the obvious influences on the optimal cooing scheme, but the cooling water temperature has no influence in the parameter analysis range of this paper. The "generalized optimal construct" derived by minimum complex function shows a compromise between the energy retention and quality of the strip.展开更多
Maisotsenko cycle(M-cycle)has been combined with some cooling and power cycles,and behaves important thermodynamic advantage.Finite-time thermodynamics(FTT)is applied to establish three endoreversible models of M-Atki...Maisotsenko cycle(M-cycle)has been combined with some cooling and power cycles,and behaves important thermodynamic advantage.Finite-time thermodynamics(FTT)is applied to establish three endoreversible models of M-Atkinson,M-Dual and M-Miller cycles.They are performed based on models of endoreversible Atkinson,Dual and Miller cycles by combing FTT model with M-cycle concept.Power output(POW)and thermal efficiency(TEF)of those M-cycles are studied and optimized by numerical calculations.The maximum power output(MPO)and the corresponding pressure ratio and TEF,the maximum TEF and the corresponding pressure ratio and POW,as well as optimal ranges of pressure ratio are obtained.Effects of mass flow rate of circulating water injection,initial cycle temperature and maximum cycle temperature on cycle POW,TEF and optimal pressure ratio range are analyzed.The optimal performances of the three M-cycles are compared with those of traditional Atkinson,Dual and Miller cycles under the same conditions.The results show that for the three M-cycles,end temperature of adiabatic expansion process of M-cycle is less than that of the corresponding traditional cycle,POW and TEF at arbitrary pressure ratio of M-cycle are much higher than those of the corresponding traditional cycle,and performance characteristics of M-cycles are superior to those of the corresponding traditional cycles.展开更多
Many F class gas turbine combined cycle （GTCC） power plants are built in China at present because of less emission and high efficiency. It is of great interest to investigate the efficiency improvement of GTCC plant...Many F class gas turbine combined cycle （GTCC） power plants are built in China at present because of less emission and high efficiency. It is of great interest to investigate the efficiency improvement of GTCC plant. A combined cycle with three-pressure reheat heat recovery steam generator （HRSG） is selected for study in this paper. In order to maximize the GTCC efficiency, the optimization of the HRSG operating parameters is performed. The operating parameters are determined by means of a thermodynamic analysis, i.e. the minimization of exergy losses. The influence of HRSG inlet gas temperature on the steam bottoming cycle efficiency is discussed. The result shows that increasing the HRSG inlet temperature has less improvement to steam cycle efficiency when it is over 590℃. Partial gas to gas recuperation in the topping cycle is studied. Joining HRSG optimization with the use of gas to gas heat recuperation, the combined plant efficiency can rise up to 59.05% at base load. In addition, the part load performance of the GTCC power plant gets much better. The efficiency is increased by 2.11% at 75% load and by 4.17% at 50% load.展开更多
Considering the size of an irreversible air heat pump （AHP）, heating load density （HLD） is taken as thermodynamic opt/mization objective by using finite-time thermodynamics. Based on an irreversible AHP with infin...Considering the size of an irreversible air heat pump （AHP）, heating load density （HLD） is taken as thermodynamic opt/mization objective by using finite-time thermodynamics. Based on an irreversible AHP with infinite reservoir thermal-capacitance rate model, the expression of HLD of AHP is put forward. The HLD opti-mization processes are studied analytically and numerically, which consist of two aspects： （1） to choose pressure ratio; （2） to distribute heat-exchanger inventory. Heat reservoir temperatures, heat transfer performance of heat exchangers as well as irreversibility during compression and expansion processes are important factors influenc-ing on the performance of an irreversible AHP, which are characterized with temperature ratio, heat exchanger inventory as well as isentropic efficiencies, respectively. Those impacts of parameters on the maximum HLD are thoroughly studied. The research results show that HLD optimization can make the size of the AHP system smaller and improve the compactness of system.展开更多
The mass entransy describes the mass-diffusion ability of the solution system, and the mass-diffusion process with the finite concentration difference always leads to the mass-entransy dissipation. This paper studies ...The mass entransy describes the mass-diffusion ability of the solution system, and the mass-diffusion process with the finite concentration difference always leads to the mass-entransy dissipation. This paper studies the equimolar reverse constant-temperature mass-diffusion process with Fick's law( g∝Δ(c)). The optimal concentration paths for the MED(Minimum Entransy Dissipation) are derived and compared with those for the MEG(Minimum Entropy Generation) and CCR(Constant Concentration Ratio) operations. It is indicated that the strategy of the MED is equivalent to that of the CCD(Constant Concentration Difference) of the same component; whether the MED or the MEG is selected as the optimization objective, the strategy of the CCD is much better than that of the CCR.展开更多
Constructal theory is introduced into the molten steel yield maximization of a converter in this paper. For the specific total cost of materials, generalized constructal optimization of a converter steel-making proces...Constructal theory is introduced into the molten steel yield maximization of a converter in this paper. For the specific total cost of materials, generalized constructal optimization of a converter steel-making process is performed. The optimal cost distribution of materials is obtained, and is also called as "generalized optimal construct". The effects of the hot metal composition contents, hot metal temperature, slag basicity and ratio of the waste steel price to the sinter ore price on the optimization results are analyzed.The results show that the molten steel yield after optimization is increased by 5.48% compared with that before optimization when sinter ore and waste steel are taken as the coolants, and the molten steel yield is increased by 6.84% when only the sinter ore is taken as the coolant. It means that taking sinter ore as coolant can improve the economic performance of the converter steelmaking process. Decreasing the contents of the silicon, phosphorus and manganese in the hot metal can increase the molten steel yield. The change of slag basicity affects the molten steel yield a little.展开更多
Atmospheric water harvesting(AWH)is a promising solution to the water shortage problem.Current sorption-based AWH(SAWH)systems seldom obtain both wide climatic adaptability and high energy efficiency due to the lack o...Atmospheric water harvesting(AWH)is a promising solution to the water shortage problem.Current sorption-based AWH(SAWH)systems seldom obtain both wide climatic adaptability and high energy efficiency due to the lack of thermodynamic optimization.To achieve the ideal harvesting circulation in SAWH systems,the“optimal harvesting window”(OHW)design based on thermodynamic analysis was first proposed and validated by our prototype.The“OHW”theory indicates the water production rate and energy efficiency could be improved by properly reducing the adsorption temperature.As the humidity increases,the optimal adsorption temperature should be closer to the dew point of the environment.Experimental results revealed that,loaded with 3 kg widely adopted silica gel,the daily water production could reach 5.76-17.64 L/d with ultrahigh energy efficiency of 0.46-1.5 L/kWh.This prototype could also achieve optimal performance in wide climatic conditions in terms of 13-35℃and 18%-72%RH.Lastly,the performance of photovoltaic(PV)-driven SAWH was evaluated.Results showed that a 1 m^(2)PV panel could generate 0.66-2 L water per day in Shanghai throughout the year,the highest in opening literature.Notably,this work introduces a promising concept that can help achieve large-scale,ultra-fast,energyefficient AWH worldwide.展开更多
The emergence and development of constructal theory,which has been a new discipline branch to research sorts of structures in nature and engineering,are reviewed.The core of the constructal theory is that various shap...The emergence and development of constructal theory,which has been a new discipline branch to research sorts of structures in nature and engineering,are reviewed.The core of the constructal theory is that various shapes and structures of the matters in nature are generated from the tendency to obtain optimal performance.Constructal theory and its application are summarized,from disciplines such as heat,mechanism,fluid flow,electricity,magnetism and chemistry,to life and non-life systems in nature.展开更多
文摘In this paper, the phase diagram of the DyCl_3-NaCl system is optimized and calculated with CALPHAD (calculation of phase diagram) technology. A set of thermodynamic functions of compounds Na_3DyCl_6, NaDyCl_4, and NaDy_2Cl_7 have been optimized and calculated based on an interactive computer-assisted analysis. The optimized thermodynamic parameters, calculated phase diagram and experimental phase diagram are thermodynamically self-consistent.
基金Project supported by the Foundation of Natural Science of Anhui Province (00046509) and Foundation of Natural Science of Anhui Education Committee (2000j1090)
文摘From the measured phase equilibria data and experimental thermochemical properties, the TmCl_3-ACl (A=Na, K, Rb, Cs) phase diagrams were optimized and calculated using the CALPHAD technique. For describing the Gibbs energies of the liquid phase in these systems, the new modified quasichemical model in the pair-approximation for short-range ordering was used. A set of thermodynamic functions was optimized and gotten based on an interactive computer-assisted analysis. The calculated phase diagrams and thermodynamic data are self-consistent.
基金Project supported by Key Item Faundation of Anhui MunicipalCommission of Education (Grant No .2005KJ016ZD)
文摘From the measured phase diagram data and experimental thermochemical properties, the DyCl3-KCl and DyCl3-CaCl2 phase diagrams were optimized and calculated by the CALPHAD technique. The Gibbs energies of liquid phase in the two systems has been optimized and calculated by new modified quasi-chemical model in the pair-approximation for short-range ordering, and a series of thermodynamic functions has also been optimized based on an interactive computer-assisted analysis. The results showed that the calculated phase diagrams and thermodynamic data were serf-consistent.
文摘Based on the phase diagram of the Fe-Pr system available,the thermodynamic optimization and calcula- tion of the system have been carried out by the least square method.The lattice stabilities of Fe and Pr are described by the expression recommended by SGTE organization.The liquid phase is described by the subregular solution model.The intermetallic compounds,Fe_(17)Pr_2 and Fe_2Pr,are treated as stoichiometric compounds.The optimized parameters describing phases in the system are presented.The comparision be- tween the calculated and experimentally determined phase diagram shows that the agreement is generally very good except for the liquid+δ-Fe equilibrium.It is suggested to measure this part of phase diagram again.
文摘In this paper a critical assessment and optimization of the phase diagrams and thermodynamic properties of the PrCl_3-MCl(M=Li,Na)and PrCl_3-MCl_2(M=Mg,Ca,Sr,Ba) binary systems have been per- formed.The assessed and optimized binary phase diagrams and thermodynamic data with self consistency are a better basis for constructing multicomponent phase diagrams.
文摘The relationship between engine mechanics and thermo-dynamics has been investigated by means of numerical simulation.The inherent mismatching between the mechanical behaviors and the thermodynamic process in internal combustion engine is identified,which is believed to be one of the important limiting factors of energy efficiency for conventional engines available in the current market.An approach for engine efficiency improvement through optimal matching between mechanics and thermodynamics(OMBMT)is proposed.An ideal matching model is defined and the conflicts due to the constraints among the mapping strokes in a 4-stroke engine are analyzed.A novel mechanical model is built for approaching optimal matching among all 4 individual strokes in a 4-stroke spark-ignition engine,which is composed of non-circular gears(NCG)and integrated with conventional slider crank engine mechanism.By means of digital mechanical model and numerical simulation,the matching gains among all 4 strokes are defined and calculated for quantifying the NCG engine efficiency improvement by comparing with a baseline engine.The potentials with the OMBMT implemented and the enhancements made by NCG mechanism for engines in terms of overall engine efficiency are reported.Based on the results achieved,it is recommended that the feasibility studies and the experimental validations should be conducted to verify the engine matching concept and effectiveness of the NCG mechanism engine model proposed,and the engine performance and NCG design parameters should be further optimized.
基金supported by the National Natural Science Foundation China(Grant Nos.51176203 and 10905093)
文摘The mass entransy and its dissipation extremum principle have opened up a new direction for the mass transfer optimization. Firstly, the emergence and development process of both the mass entransy and its dissipalion extremum principle are reviewed. Secondly, the combination of the mass entransy dissipation extremum principle and the finite-time thermodynamics for opti- mizing the mass transfer processes of one-way isothermal mass transfer, two-way isothermal equimolar mass transfer, and iso- thermal throttling and isothermal crystallization are summarized. Thirdly, the combination of the mass entransy dissipation ex- tremum principle and the constructal theory for optimizing the mass transfer processes of disc-to-point and volume-to-point problems are summarized. The scientific features of the mass entransy dissipation extremam principle are emphasized.
基金supported by the National Natural Science Foundation of China (Grant No. 10905093)the Program for New Century Excellent Talents in University of China (Grant No. NCET-04-1006)+1 种基金the Foundation for the Author of National Excellent Doctoral Dissertation of China (Grant No. 200136)the Natural Science Foundation for Youngsters of Naval University of Engineering (Grant No. HGDQNJJ10017)
文摘The constructal optimizations of T-shaped fin with two-dimensional heat transfer model are carried out by finite element method and taking the minimization of equivalent thermal resistance based on entransy dissipation and the minimization of maximum thermal resistance as optimization objectives, respectively. The effects of the global parameter a (integrating the coefficient of convective heat transfer, the overall area occupied by fin and its thermal conductivity) and the volume fraction ? of fin on the minimums of equivalent thermal resistance and maximum thermal resistance as well as their corresponding optimal configurations are analyzed. The comparison of the results based on the above two optimization objectives is conducted. The results show that the optimal structures based on the two optimization objectives are obviously different from each other. Compared with the optimization result by taking the minimization of maximum thermal resistance as the objective, the optimization result by taking the equivalent thermal resistance minimization as the objective can reduce the average temperature difference in the fin obviously. The increases of a and ? can all improve the working status of local hot spot and the global heat transfer performance of the system. But the improvement effects of the increases of a and ? on the minimization of equivalent thermal resistance are different from those on the minimization of maximum thermal resistance. For either objective, the effect of a is different from that of ?. The T-shaped fin with minimum equivalent thermal resistance is much taller than that with minimum maximum thermal resistance; for either optimization objective, the stem of fin is thicker than the branches of fin, and the stem thickness is relatively close to branch thickness when the minimization of equivalent thermal resistance is taken as the optimization objective. The T-shaped fin with flat stem and slender branches can benefit the reduction of the maximum thermal resistance.
基金supported by the National Natural Science Foundation of China (Grant No. 51176203)the Natural Science Foundation of Naval University of Engineering (Grant No. HGDYDJJ10011)the Natural Science Foundation for Youngsters of Naval University of Engineering (Grant No. HGDQNJJ10017)
文摘Based on constructal theory,the constructs of three "volume-point" heat conduction models with three-dimensional cylindrical element and rectangular and triangular elements on microscale and nanoscale are optimized by taking minimum entransy dissipation rate as optimization objective.The optimal constructs of the three "volume-point" heat conduction models with minimum dimensionless equivalent thermal resistance are obtained.The results show that the optimal constructs of the three-dimensional cylindrical assembly based on the minimizations of dimensionless equivalent thermal resistance and dimensionless maximum thermal resistance are different,which is obviously different from the comparison between those of the corresponding two-dimensional rectangular assembly based on the minimizations of these two objectives.The optimal constructs based on rectangular and triangular elements on microscale and nanoscale when the size effect takes effect are obviously different from those when the size effect does not take effect.Because the thermal current density in the high conductivity channel of the rectangular and triangular second order assemblies are not linear with the length,the optimal constructs of these assemblies based on the minimization of entransy dissipation rate are different from those based on the minimization of maximum temperature difference.The dimensionless equivalent thermal resistance defined based on entransy dissipation rate reflects the average heat transfer performance of the construct.The studies on "volume-point" heat conduction constructal problems at three-dimensional conditions and microscale and nanoscale by taking minimum entransy dissipation rate as optimization objective extend the application range of the entransy dissipation extremum principle.
基金supported by the National Key Basic Research and Devel-opment Program of China("973"Project)(Grant No.2012CB720405)the National Natural Science Foundation of China(Grant Nos.51176203 and 51206184)the Natural Science Foundation of Hubei Province(Grant No.2012FFB06905)
文摘Based on constructal theory and entransy theory,a generalized constructal optimization of a solidification heat transfer process of slab continuous casting for a specified total water flow rate in the secondary cooling zone was carried out.A complex function was taken as the optimization objective to perform the casting.The complex function was composed of the functions of the entransy dissipation and surface temperature gradient of the slab.The optimal water distribution at the sections of the secondary cooling zone were obtained.The effects of the total water flow rate in the secondary cooling zone,casting speed,superheat and water distribution on the generalized constructal optimizations of the secondary cooling process were analyzed.The results show that on comparing the optimization results obtained based on the optimal water distributions of the 8 sections in the secondary cooling zone with those based on the initial ones,the complex function and the functions of the entransy dissipation and surface temperature gradient after optimization decreased by 43.25%,5.90%and 80.60%,respectively.The quality and energy storage of the slab had obviously improved in this case.The complex function,composed of the functions of the entransy dissipation and surface temperature gradient of the slab,was a compromise between the internal and surface temperature gradients of the slab.Essentially,it is also the compromise between energy storage and quality of the slab.The"generalized constructal optimization"based on the minimum complex function can provide an optimal alternative scheme from the point of view of improving energy storage and quality for the parameter design and dynamic operation of the solidification heat transfer process of slab continuous casting.
基金supported by the National Key Basic Research and Development Program of China (‘973’ Program) (Grant No. 2012CB720405)the National Natural Science Foundation of China (Grant No. 51176203)the Natural Science Foundation for Youngsters of Naval University of Engineering (Grant No. HGDQNJJ11008)
文摘Analogizing with the heat conduction process, the entransy dissipation extremum principle for thermal insulation process can be described as: for a fixed boundary heat flux (heat loss) with certain constraints, the thermal insulation process is optimized when the entransy dissipation is maximized (maximum average temperature difference), while for a fixed boundary temperature, the thermal insulation process is optimized when the entransy dissipation is minimized (minimum average heat loss rate). Based on the constructal theory, the constructal optimizations of a single plane and cylindrical insulation layers as well as multi-layer insulation layers of the steel rolling reheating furnace walls are carried out for the fixed boundary temperatures and by taking the minimization of entransy dissipation rate as optimization objective. The optimal constructs of these three kinds of insulation structures with distributed thicknesses are obtained. The results show that compared with the insulation layers with uniform thicknesses and the optimal constructs of the insulation layers obtained by minimum heat loss rate, the optimal constructs of the insulation layers obtained by minimum entransy dissipation rate are obviously different from those of the former two insulation layers; the optimal constructs of the insulation layers obtained by minimum entransy dissipation rate can effectively reduce the average heat loss rates of the insulation layers, and can help to improve their global thermal insulation performances. The entransy dissipation extremum principle is applied to the constructal optimizations of insulation systems, which will help to extend the application range of the entransy dissipation extremum principle.
基金supported by the National Natural Science Foundation of China(Grant Nos.5120618451176203&51356001)
文摘Based on constructal theory and entransy theory,the optimal designs of constant-and variable-cross-sectional cylindrical heat sources are carried out by taking dimensionless equivalent resistance minimization as optimization objective.The effects of the cylindrical height,the cylindrical shape and the ratio of thermal conductivity of the fin to that of the heat source are analyzed.The results show that when the volume of the heat source is fixed,there exists an optimal ratio of the center-to-centre distance of the fin and the heat source to the cylinder radius which leads to the minimum dimensionless equivalent thermal resistance.With the increase in the height of the cylindrical heat source and the ratio of thermal conductivity,the minimum dimensionless equivalent thermal resistance decreases gradually.For the heat source model with inverted variable-cross-sectional cylinder,there exist an optimal ratio of the center-to-centre distance of the fin and the heat source to the cylinder radius and an optimal radius ratio of the smaller and bigger circles of the cylindrical fin which lead to a double minimum dimensionless equivalent thermal resistance.Therefore,the heat transfer performance of the cylindrical heat source is improved by adopting the cylindrical model with variable-cross-section.The optimal constructs of the cylindrical heat source based on the minimizations of dimensionless maximum thermal resistance and dimensionless equivalent thermal resistance are different.When the thermal security is ensured,the optimal construct of the cylindrical heat source based on minimum equivalent thermal resistance can provide a new alternative scheme for the practical design of heat source.The results obtained herein enrich the work of constructal theory and entransy theory in the optimal design field of the heat sources,and they can provide some guidelines for the designs of practical heat source systems.
基金supported by the National Basic Research Program of China ("973" Project) (Grant No. 2012CB720405)the National Natural Science Foundation of China (Grant Nos. 51506220 & 51356001)
文摘A strip laminar cooling process is investigated in this paper. Entransy theory and generalized constructal optimization are introduced into the optimization. Total water flow amount(WFA) in the laminar cooling zone(LCZ) and complex function are taken as the constraint and optimization objective, respectively. The entransy dissipation(ED) and maximum temperature different(MTD) of the strip are simultaneously considered in the complex function. WFA distributions of the headers in the LCZ are optimized. The effects of the total WFA, strip thickness and cooling water temperature on the optimal results are analyzed.The optimal cooling scheme is the eleventh cooling mode for the considered total 257 cooling schemes, and the complex function,ED and MTD of the strip are decreased by 11.59%, 5.59% and 17.58% compared with the initial cooling scheme, respectively.The total WFA and strip thickness have the obvious influences on the optimal cooing scheme, but the cooling water temperature has no influence in the parameter analysis range of this paper. The "generalized optimal construct" derived by minimum complex function shows a compromise between the energy retention and quality of the strip.
基金supported by the National Natural Science Foundation of China (Grant Nos.52171317 and 51779262)。
文摘Maisotsenko cycle(M-cycle)has been combined with some cooling and power cycles,and behaves important thermodynamic advantage.Finite-time thermodynamics(FTT)is applied to establish three endoreversible models of M-Atkinson,M-Dual and M-Miller cycles.They are performed based on models of endoreversible Atkinson,Dual and Miller cycles by combing FTT model with M-cycle concept.Power output(POW)and thermal efficiency(TEF)of those M-cycles are studied and optimized by numerical calculations.The maximum power output(MPO)and the corresponding pressure ratio and TEF,the maximum TEF and the corresponding pressure ratio and POW,as well as optimal ranges of pressure ratio are obtained.Effects of mass flow rate of circulating water injection,initial cycle temperature and maximum cycle temperature on cycle POW,TEF and optimal pressure ratio range are analyzed.The optimal performances of the three M-cycles are compared with those of traditional Atkinson,Dual and Miller cycles under the same conditions.The results show that for the three M-cycles,end temperature of adiabatic expansion process of M-cycle is less than that of the corresponding traditional cycle,POW and TEF at arbitrary pressure ratio of M-cycle are much higher than those of the corresponding traditional cycle,and performance characteristics of M-cycles are superior to those of the corresponding traditional cycles.
文摘Many F class gas turbine combined cycle （GTCC） power plants are built in China at present because of less emission and high efficiency. It is of great interest to investigate the efficiency improvement of GTCC plant. A combined cycle with three-pressure reheat heat recovery steam generator （HRSG） is selected for study in this paper. In order to maximize the GTCC efficiency, the optimization of the HRSG operating parameters is performed. The operating parameters are determined by means of a thermodynamic analysis, i.e. the minimization of exergy losses. The influence of HRSG inlet gas temperature on the steam bottoming cycle efficiency is discussed. The result shows that increasing the HRSG inlet temperature has less improvement to steam cycle efficiency when it is over 590℃. Partial gas to gas recuperation in the topping cycle is studied. Joining HRSG optimization with the use of gas to gas heat recuperation, the combined plant efficiency can rise up to 59.05% at base load. In addition, the part load performance of the GTCC power plant gets much better. The efficiency is increased by 2.11% at 75% load and by 4.17% at 50% load.
基金supported by National Natural Science Foundation of China(NSFC)under the contracts No.51776008 and No.51376012
文摘Considering the size of an irreversible air heat pump （AHP）, heating load density （HLD） is taken as thermodynamic opt/mization objective by using finite-time thermodynamics. Based on an irreversible AHP with infinite reservoir thermal-capacitance rate model, the expression of HLD of AHP is put forward. The HLD opti-mization processes are studied analytically and numerically, which consist of two aspects： （1） to choose pressure ratio; （2） to distribute heat-exchanger inventory. Heat reservoir temperatures, heat transfer performance of heat exchangers as well as irreversibility during compression and expansion processes are important factors influenc-ing on the performance of an irreversible AHP, which are characterized with temperature ratio, heat exchanger inventory as well as isentropic efficiencies, respectively. Those impacts of parameters on the maximum HLD are thoroughly studied. The research results show that HLD optimization can make the size of the AHP system smaller and improve the compactness of system.
基金supported by the National Natural Science Foundation of China (Grant Nos. 51576207 & 51356001)
文摘The mass entransy describes the mass-diffusion ability of the solution system, and the mass-diffusion process with the finite concentration difference always leads to the mass-entransy dissipation. This paper studies the equimolar reverse constant-temperature mass-diffusion process with Fick's law( g∝Δ(c)). The optimal concentration paths for the MED(Minimum Entransy Dissipation) are derived and compared with those for the MEG(Minimum Entropy Generation) and CCR(Constant Concentration Ratio) operations. It is indicated that the strategy of the MED is equivalent to that of the CCD(Constant Concentration Difference) of the same component; whether the MED or the MEG is selected as the optimization objective, the strategy of the CCD is much better than that of the CCR.
基金supported by the National Natural Science Foundation of China(Grant Nos.51506220&51579244)the National Key Basic Research and Development Program of China(Grant No.2012CB720405)
文摘Constructal theory is introduced into the molten steel yield maximization of a converter in this paper. For the specific total cost of materials, generalized constructal optimization of a converter steel-making process is performed. The optimal cost distribution of materials is obtained, and is also called as "generalized optimal construct". The effects of the hot metal composition contents, hot metal temperature, slag basicity and ratio of the waste steel price to the sinter ore price on the optimization results are analyzed.The results show that the molten steel yield after optimization is increased by 5.48% compared with that before optimization when sinter ore and waste steel are taken as the coolants, and the molten steel yield is increased by 6.84% when only the sinter ore is taken as the coolant. It means that taking sinter ore as coolant can improve the economic performance of the converter steelmaking process. Decreasing the contents of the silicon, phosphorus and manganese in the hot metal can increase the molten steel yield. The change of slag basicity affects the molten steel yield a little.
基金supported by the National Natural Science Foundation of China(51922070).
文摘Atmospheric water harvesting(AWH)is a promising solution to the water shortage problem.Current sorption-based AWH(SAWH)systems seldom obtain both wide climatic adaptability and high energy efficiency due to the lack of thermodynamic optimization.To achieve the ideal harvesting circulation in SAWH systems,the“optimal harvesting window”(OHW)design based on thermodynamic analysis was first proposed and validated by our prototype.The“OHW”theory indicates the water production rate and energy efficiency could be improved by properly reducing the adsorption temperature.As the humidity increases,the optimal adsorption temperature should be closer to the dew point of the environment.Experimental results revealed that,loaded with 3 kg widely adopted silica gel,the daily water production could reach 5.76-17.64 L/d with ultrahigh energy efficiency of 0.46-1.5 L/kWh.This prototype could also achieve optimal performance in wide climatic conditions in terms of 13-35℃and 18%-72%RH.Lastly,the performance of photovoltaic(PV)-driven SAWH was evaluated.Results showed that a 1 m^(2)PV panel could generate 0.66-2 L water per day in Shanghai throughout the year,the highest in opening literature.Notably,this work introduces a promising concept that can help achieve large-scale,ultra-fast,energyefficient AWH worldwide.
基金supported by the National Natural Science Foundation of China (Grant No. 51176203)the Natural Science Foundation of Naval University of Engineering (Grant No. HGDYDJJ10011)
文摘The emergence and development of constructal theory,which has been a new discipline branch to research sorts of structures in nature and engineering,are reviewed.The core of the constructal theory is that various shapes and structures of the matters in nature are generated from the tendency to obtain optimal performance.Constructal theory and its application are summarized,from disciplines such as heat,mechanism,fluid flow,electricity,magnetism and chemistry,to life and non-life systems in nature.
