The structure and thermal parameters of Ni20Pd80 alloy were studied by X-ray diffraction（XRD）. The diffraction experiments performed in the temperature range of 308-1100 K revealed that the alloy formed a face cente...The structure and thermal parameters of Ni20Pd80 alloy were studied by X-ray diffraction（XRD）. The diffraction experiments performed in the temperature range of 308-1100 K revealed that the alloy formed a face centered cubic （fcc） Al-type structure. The temperature dependence of the lattice parameters was investigated by using the Bragg line displacement method showing that the lattice parameter increases with the increase of temperature. The mean linear thermal expansion （MLTE（%））, coefficient of thermal expansion （CTE, α）, the characteristic Debye temperature （（θD） and mean square amplitudes of vibration were determined from XRD data. The value of Debye temperature was found to be 253 K. It was found that temperature factor was independent of the static displacements.展开更多
The hot spot temperature of a transformer is one of the critical indicators reflecting its operating status.Accurate and fast calculation of hot spot temperature is significant for the online monitoring of transformer...The hot spot temperature of a transformer is one of the critical indicators reflecting its operating status.Accurate and fast calculation of hot spot temperature is significant for the online monitoring of transformers.Considering the low computational efficiency of the transformer’s numerical full model(FM),this paper presents a model simplification method based on the equivalent thermal parameters of windings to expedite hot spot temperature computation.Initially,the representative volume element(RVE)reflecting the periodic structure of windings is selected to formulate a reduced model(RM)for the transformer.Subsequently,to achieve equivalence between the RM and the FM,the equivalent thermal parameters of the RVE are calculated,containing the equivalent thermal conductivity(ETC),the equivalent density(ED),and the equivalent specific heat capacity(ESHC).Finally,the validity of the RM is verified by the temperature rise test.The results show that,compared with the tested data,the maximum error of the hot spot temperature calculated by the RM is 2.56 K,demonstrating the accuracy of the hot spot temperature calculation by the RM.Compared with the FM,the computing time of the proposed RM is reduced to 1/189,which significantly improves the computational efficiency.展开更多
This study investigates the stratification of soil thermal properties induced by soil organic carbon (SOC) and its impacts on the parameterization of the thermal properties. Soil parameters were measured for alpine gr...This study investigates the stratification of soil thermal properties induced by soil organic carbon (SOC) and its impacts on the parameterization of the thermal properties. Soil parameters were measured for alpine grassland stations and North China flux stations, with a total of 34 stations and 77 soil profiles. Measured data indicate that the topsoils of alpine grasslands contain high SOC contents than underlying soil layers, which leads to higher soil porosity values and lower thermal conductivity and bulk density values in the topsoils. However, this stratification is not evident at the lowland stations due to low SOC contents. Evaluations against measured data show that three thermal conductivity schemes used in land surface models severely overestimate the values for soils with high SOC content (i.e. topsoils of alpine grassland), but they are better for soils with low SOC content. A new parameterization is then developed to take the impacts of SOC into account. The new one can well estimate the soil thermal conductivity values in both low and high SOC content cases, and therefore, it is a potential candidate of thermal conductivity scheme to be used in land surface models.展开更多
To satisfy performance and long life requirements for hot forging die,Ni60-Cr3C2 composite coatings were prepared on the high-speed steel W6Mo5Cr4V2 using laser cladding technology.Laser clad coatings with different r...To satisfy performance and long life requirements for hot forging die,Ni60-Cr3C2 composite coatings were prepared on the high-speed steel W6Mo5Cr4V2 using laser cladding technology.Laser clad coatings with different ratios of Ni60：Cr3C2 were investigated by scanning electron microscopy（SEM）,X-ray diffraction（XRD）,energy-dispersive X-ray analysis（EDX） and micro-hardness tester,respectively.Specific heat capacity and thermal conductivity were measured by Laser Thermal Constant Meter.Thermal expansion coefficient and elastic modulus were measured by Dynamic Mechanical Thermal Analyzer and Electro-Hydraulic Servocontrolled Testing System,respectively.The results indicated that Ni60＋50wt% Cr3C2 composite coating had dense and homogeneous structure,as well as a metallurgical bonding with the substrate.With the increase of Cr3C2 content,volume of chromium-containing compounds in the composite coating increased,microhardness increased and microstructure refined.The thermal physical parameters results showed that Ni60＋50wt% Cr3C2 composite coating was overall worse than W6Mo5Cr4V2,but had a higher hot yield strength to alleviate hot fatigue and surface hot wear of hot forging die during hot forging and thus improve the service life of hot forging die.展开更多
Sensitivity analysis of thermal equilibrium parameters in the reservoir module of MIKE 11 model was conducted for the Wuxikou Reservoir in Jiangxi Province of China in order to apply the module to the environmental im...Sensitivity analysis of thermal equilibrium parameters in the reservoir module of MIKE 11 model was conducted for the Wuxikou Reservoir in Jiangxi Province of China in order to apply the module to the environmental impact assessment to accurately predict water temperature of reservoirs.Results showed that radiation parameter A and evaporation-first parameter were much more sensitive than other parameters.The values of the radiation parameter A ranged from 0.10 to 0.34.The values of evaporation-first parameter varied from 0 to 10.The sensitivity of solar absorption parameters was less than that of evaporation parameter,of which light attenuation values ranged from 0.5 to 0.7,and this parameter would not impact model results if it was more than 2.Constants in Beer's law ranged from 0.2 to 0.7.Radiation parameter B was not more sensitive than evaporation parameter and its reasonable range was higher than 0.48.The fitting curves showed consistent changing tendency for these parameters within the reasonable ranges.Additionally,all the thermal equilibrium parameters had much more important effects on surface water temperature than deep water temperature.Moreover,if no observed data could be obtained,the local empirical value would be used to input to the MIKE 11 model to simulate the changes in the discharged outflow-water temperature qualitatively.展开更多
Simple parameterized models, either whole mantle convection or layered mantleconvection, cannot explain the tectonic characteristics of the Earth's evolution history, therefore a mixed mantle convection model has ...Simple parameterized models, either whole mantle convection or layered mantleconvection, cannot explain the tectonic characteristics of the Earth's evolution history, therefore a mixed mantle convection model has been carried out in this paper. We introduce a time-dependent parameter F, which denotes the ratio betWeen the mantle material involved in whole mantle convection and the material of the entire mantle, and introduce a local Rayleigh number Raloc as well as two critical numbers Ra1 and Ra2. These parameters are used to describe the stability of the phase boundary between the upper and lower mantle. The result shows that the mixed mantle convection model is able to simulate the episodic tectonic evolution of the Earth.展开更多
The high temperature gas occurs behind shock or near the wall surface of vehicle in the hypersonic flight. As the temperature exceeds 2 000 K, 4 000 K, respectively, O2 and N2 molecules are successively dissociated. B...The high temperature gas occurs behind shock or near the wall surface of vehicle in the hypersonic flight. As the temperature exceeds 2 000 K, 4 000 K, respectively, O2 and N2 molecules are successively dissociated. Because of variable components at dif- ferent temperatures and pressures, the dissociated air is no longer a perfect gas, In this paper, a new method is developed to calculate accurate thermal physical parameters with the dissociation degree providing the thermochemical equilibrium procedure. Based on the dissociation degree, it is concluded that few numbers of equations and the solutions are easily obtained. In addition, a set of formulas relating the parameter to the dissociation degree are set up four-species, O2 molecule The thermodynamic properties of dissociated air containing and N2 molecule, O atom and N atom, are studied with the new method, and the results are consistent with those with the traditional equilibrium constant method. It is shown that this method is reliable for solving thermal physical parameters easily and directly.展开更多
Through introducing the analytical problem of the plate with convection into the solution of the transient heat conduction thermal stress field model of the elastic plate, the stress reduction factor is presented expl...Through introducing the analytical problem of the plate with convection into the solution of the transient heat conduction thermal stress field model of the elastic plate, the stress reduction factor is presented explicitly in its dimensionless form. A new stress reduction factor is introduced for the purpose of comparison. The proper- ties and appropriate conditions of the stress reduction factor, the first and second ther- mal shock resistance （TSR） parameters for the high and low Biot numbers, respectively, and the approximation formulas for the intermediate Blot number-interval are discussed. To investigate the TSR of ceramics more accurately, it is recommended to combine the heat transfer theory with the theory of thermoelasticity or fracture mechanics or use a numerical method. The critical rupture temperature difference and the critical rup- ture dimensionless time can be used to characterize the TSR of ceramics intuitively and legibly.展开更多
An experiment was conducted to assess the impact of fused calcia-stabilized zirconia micro-powder on the thermal shock behavior of magnesia–spinel refractories.The effects of calcia-stabilized zirconia on the microst...An experiment was conducted to assess the impact of fused calcia-stabilized zirconia micro-powder on the thermal shock behavior of magnesia–spinel refractories.The effects of calcia-stabilized zirconia on the microstructure evolution and properties of magnesia–spinel refractories were characterized by the high-temperature elastic modulus,thermal shock damage resistance parameters,retainment of elastic modulus after thermal shock,and scanning electron microscopy.The results indicated that the incorporation of calcia-stabilized zirconia improved the thermomechanical properties and thermal shock behavior of magnesia–spinel specimens.The hot modulus of rupture of magnesia–spinel specimens increased by 2.5-fold due to the incorporation of calcia-stabilized zirconia micro-powder.The presence of a martensitic phase transformation in partially unstable ZrO2 and thermal mismatches among various phases contributed to a controlled formation of microcracks.And the pinning effect caused by the calcia-stabilized zirconia particles surrounding the grain boundaries played a crucial role in preventing the propagation of microcracks.This phenomenon significantly bolstered the thermal shock stability of magnesia–spinel refractories,consequently prolonging their service life.展开更多
Bi3.15Nd0.85Ti3O12 （BNT） powder and thin film were prepared by metal organic decomposition （MOD） method. The heat flow curve of BNT powder was measured with a modulated temperature differential scanning calorimete...Bi3.15Nd0.85Ti3O12 （BNT） powder and thin film were prepared by metal organic decomposition （MOD） method. The heat flow curve of BNT powder was measured with a modulated temperature differential scanning calorimeter, and thermal physical parameters such as thermal conductivity coefficient and thermal diffusion coefficient were obtained from the heat flow curve. The phase identification, ferroelectric, and piezoelectric properties of BNT thin film annealed at 700℃ were investigated with X-ray diffractometer, ferroelectric analyzer, and scanning probe microscope. The results show that the thin films consisting of a single phase of bismuth-layered perovskite are polycrystalline, without a preferred orientation. Remnant polarization 2Pr is 63.2 μC/cm2 under 530 kV/cm applied field, and the effective piezoelectric coefficient d33 is 30 pm/V.展开更多
The large reserves ofoil are disposed in zones of permafrost in shelf and continental fields. In Europe the subarctic and arctic tundra are abundant only in Nenetsky autonomous area and in the north-east of the republ...The large reserves ofoil are disposed in zones of permafrost in shelf and continental fields. In Europe the subarctic and arctic tundra are abundant only in Nenetsky autonomous area and in the north-east of the republic of Komi. Oil and gas production activity has threatened richest biological resources and health of the population of the region. A singularity of petroliferous fields of the north of Russia is the existence of the thick strata of permafrost. On top of them different heat-insulating overlying layers （snow, biogenic covers） reside. State and dynamics of permafrost cause progressing dangerous exogenic geoecological processes, which are exhibited completely. State of permafrost is instituted by exchange of heat in near-surface strata of a geological section. During the development of oil fields there is a disturbance of a temperature schedule of permafrost. For estimation of technical attack the analytical computational method of influence of the different factors on value of annual heat exchange and prediction of geocryological conditions is proposed. It is shown, that such dangerous phenomena as degradation of permafrost and thermokarst would develop in the first place, which would cause the destruction of natural ecosystems.展开更多
Fifty samples from the source rocks in Member 3 and Member 4 of the Paleogene Shahejie Formation in the Bohai Bay Basin, East China, were analyzed to investigate the distribution, evolution of the molecular maturity r...Fifty samples from the source rocks in Member 3 and Member 4 of the Paleogene Shahejie Formation in the Bohai Bay Basin, East China, were analyzed to investigate the distribution, evolution of the molecular maturity ratios C29ββ/（ββ＋αα） and C2920S/（20S＋20R） and their control factors in the natural geological profile and sequence. The results showed that progressive changes in molecular maturity parameters are associated with major changes in thermal evolution of related biomarkers. Increases in the C29ββ/（ββ＋αα） and C2920S/（20S＋20R） ratios result from the difference in the relative rate between generation and thermal degradation of isomers involved. The samples from a hyper-saline environment below 3.5 km in which evaporitic rocks deposited shows high response of Sr/Ba, Sr/Ca, Fe/ Mn, Pr/n-C17, Ph/n-C18 and gammacerane and low response of Pr/Ph. There presents negative reversal of biomarker maturity C29ββ/（ββ＋αα, C29ββ/（ββ＋αα） and Ts/（Ts＋Ym） in the samples from hypersaline environment, reflecting that the gypsum- halite have negative effect on the isomerization of biomarker and thermal evolution of organic matter. The minerals in evaporites also retard the conventional thermal indicators including vitrinite reflectance （Ro） and pyrolysis peak temperature Tmax at the depth below 3.4 km （i.e. 〉3.4 km）, and these parameters also show the inhibition from overpressure in the range of 2.4-3.4 kin. This result will be helpful in the interpretation and application of molecular maturity parameters for similar saline lacustrine basins.展开更多
We investigated the influences of process parameters on the head curvature of pure titanium sheet in hot rolling process and proposed the controlling means. First, the thermal simulation experiments for pure titanium ...We investigated the influences of process parameters on the head curvature of pure titanium sheet in hot rolling process and proposed the controlling means. First, the thermal simulation experiments for pure titanium TA1 were carried out to investigate the hot deformation behaviors of pure titanium in the temperature range of 700-800 ℃ with strain rate range of 1-20 S-1, and the processing map was established to determine optimized deformation parameters. Then, the finite element model has been constructed and used to analyze the effect of process parameters on the direction and severity of head curvature of pure titanium sheet. The process parameters considered in the present study include workpiece temperature, work roll diameter, pass reduction, oxide scale thickness of workpiece surface, and interface friction coefficient. The simulation results show that the workpiece temperature and the interface friction coefficient are the two main factors. The proposed controlling means was carried out on a hot rolling production line and solved the head curvature problem effectively. The rolling practices indicate that the rolling yield is improved greatly.展开更多
In this paper, the thermal field of double wire welding is simulated by using ANSYS software. Simulation results were shown that the total heat input (E) is the most significant parameters to change the value of t8/5;...In this paper, the thermal field of double wire welding is simulated by using ANSYS software. Simulation results were shown that the total heat input (E) is the most significant parameters to change the value of t8/5;By the mean of rationally controlling the proportion of the front arc heat input (E1) in the total heat input (E) and appropriately selecting double wire spacing (L), It is effective means to get the double wire welding thermal cycle. By the way of simulation, it is possible to manage the thermal input in the double welding wires and to control the temperature field and cooling rate that are fundamental for the final joint quality, it is great importance guidance to optimize the double wire welding process parameters.展开更多
A three-factor three-level orthogonal test project has been designed based on the numerical simulation of a Jominy quenching process.Then the data scattering effects of thermal conductivity and enthalpy of tested stee...A three-factor three-level orthogonal test project has been designed based on the numerical simulation of a Jominy quenching process.Then the data scattering effects of thermal conductivity and enthalpy of tested steel,as well as the heat exchange coefficients of the cooling media,on the results have been studied.The results can be used as a reference for choosing the input thermal parameter in finite element simulation of quenching,and for evaluating the simulation results.展开更多
The efficiency and precision of parameter calibration in discrete element method （DEM） are not satisfactory, and parameter calibration for granular heat transfer is rarely involved. Accordingly, parameter calibratio...The efficiency and precision of parameter calibration in discrete element method （DEM） are not satisfactory, and parameter calibration for granular heat transfer is rarely involved. Accordingly, parameter calibration for granular heat transfer with the DEM is studied. The heat transfer in granular assemblies is simulated with DEM, and the effective thermal conductivity （ETC） of these granular assemblies is measured with the transient method in simulations. The measurement testbed is designed to test the ETC of the granular assemblies under normal pressure and a vacuum based on the steady method. Central composite design （CCD） is used to simulate the impact of the DEM parameters on the ETC of granular assemblies, and the heat transfer parameters are calibrated and compared with experimental data. The results show that, within the scope of the considered parameters, the ETC of the granular assemblies increases with an increasing particle thermal conductivity and decreases with an increasing particle shear modulus and particle diameter. The particle thermal conductivity has the greatest impact on the ETC of granular assemblies followed by the particle shear modulus and then the particle diameter. The calibration results show good agreement with the experimental results. The error is less than 4%, which is within a reasonable range for the scope of the CCD parameters. The proposed research provides high efficiency and high accuracy parameter calibration for granular heat transfer in DEM.展开更多
The new organic-inorganic compound, [C_6H_7N_2O_2]_3TeCl_5·2Cl was synthesized and its structure was determined at room temperature in the triclinic system （P^-1） with the following parameters： a = 10.5330（11...The new organic-inorganic compound, [C_6H_7N_2O_2]_3TeCl_5·2Cl was synthesized and its structure was determined at room temperature in the triclinic system （P^-1） with the following parameters： a = 10.5330（11） ？, b = 10.6663（11） ？, c = 15.9751（16）？, α = 82.090（2）°, β = 71.193（2）°, γ = 68.284（2）°and Z = 2. The final cycle of refinement led to R = 0.057 and Rw = 0.149. The crystal structure was stabilized by an extensive network of N--H···Cl and non-classical C--H···Cl hydrogen bonds between the cation and the anionic group. Several thermal analysis techniques such as thermogravimetric analysis, differential scanning calorimetric analysis and evolved gas analysis were used. We used isoconversional kinetics methods to determine the kinetics parameters. We observe that the decomposition of [C_6H_7N_2O_2]_3TeCl_5·2Cl entails the formation hydrochloric acid of nitroaniline as volatiles. The infrared spectra were recorded in the4000–400 cm^（-1）frequency region. The Raman spectra were recorded in the external region of the anionic sublattice vibration 50–1500 cm^（-1）. The optical band gap was calculated from the UV-Vis absorbance spectra using classical Tauc relation which was found to be 3.12 and 3.67 eV.展开更多
文摘The structure and thermal parameters of Ni20Pd80 alloy were studied by X-ray diffraction（XRD）. The diffraction experiments performed in the temperature range of 308-1100 K revealed that the alloy formed a face centered cubic （fcc） Al-type structure. The temperature dependence of the lattice parameters was investigated by using the Bragg line displacement method showing that the lattice parameter increases with the increase of temperature. The mean linear thermal expansion （MLTE（%））, coefficient of thermal expansion （CTE, α）, the characteristic Debye temperature （（θD） and mean square amplitudes of vibration were determined from XRD data. The value of Debye temperature was found to be 253 K. It was found that temperature factor was independent of the static displacements.
基金supported by Hubei Technology Innovation Center for Smart Hydropower(SDCXZX-JJ-2023-03).
文摘The hot spot temperature of a transformer is one of the critical indicators reflecting its operating status.Accurate and fast calculation of hot spot temperature is significant for the online monitoring of transformers.Considering the low computational efficiency of the transformer’s numerical full model(FM),this paper presents a model simplification method based on the equivalent thermal parameters of windings to expedite hot spot temperature computation.Initially,the representative volume element(RVE)reflecting the periodic structure of windings is selected to formulate a reduced model(RM)for the transformer.Subsequently,to achieve equivalence between the RM and the FM,the equivalent thermal parameters of the RVE are calculated,containing the equivalent thermal conductivity(ETC),the equivalent density(ED),and the equivalent specific heat capacity(ESHC).Finally,the validity of the RM is verified by the temperature rise test.The results show that,compared with the tested data,the maximum error of the hot spot temperature calculated by the RM is 2.56 K,demonstrating the accuracy of the hot spot temperature calculation by the RM.Compared with the FM,the computing time of the proposed RM is reduced to 1/189,which significantly improves the computational efficiency.
基金supported by National Natural Science Foundation of China (Grant No. 41105003)Key Project of Chinese Academy of Sciences (Grant No.KZCX2-YW-Q10-2)+1 种基金National Natural Science Foundation of China (Grant No. 91025004)Open Fund from the State Key Laboratory of Remote Sensing Science (Grant No. OFSLRSS201108) that is cosponsored by the Institute of Remote Sensing Applications of Chinese Academy of Sciences and Beijing Normal University
文摘This study investigates the stratification of soil thermal properties induced by soil organic carbon (SOC) and its impacts on the parameterization of the thermal properties. Soil parameters were measured for alpine grassland stations and North China flux stations, with a total of 34 stations and 77 soil profiles. Measured data indicate that the topsoils of alpine grasslands contain high SOC contents than underlying soil layers, which leads to higher soil porosity values and lower thermal conductivity and bulk density values in the topsoils. However, this stratification is not evident at the lowland stations due to low SOC contents. Evaluations against measured data show that three thermal conductivity schemes used in land surface models severely overestimate the values for soils with high SOC content (i.e. topsoils of alpine grassland), but they are better for soils with low SOC content. A new parameterization is then developed to take the impacts of SOC into account. The new one can well estimate the soil thermal conductivity values in both low and high SOC content cases, and therefore, it is a potential candidate of thermal conductivity scheme to be used in land surface models.
基金Funded by the National Natural Science Foundation of China (No.50675165)the Fundamental Research Funds for the Central Universities (No.2010-II-025)
文摘To satisfy performance and long life requirements for hot forging die,Ni60-Cr3C2 composite coatings were prepared on the high-speed steel W6Mo5Cr4V2 using laser cladding technology.Laser clad coatings with different ratios of Ni60：Cr3C2 were investigated by scanning electron microscopy（SEM）,X-ray diffraction（XRD）,energy-dispersive X-ray analysis（EDX） and micro-hardness tester,respectively.Specific heat capacity and thermal conductivity were measured by Laser Thermal Constant Meter.Thermal expansion coefficient and elastic modulus were measured by Dynamic Mechanical Thermal Analyzer and Electro-Hydraulic Servocontrolled Testing System,respectively.The results indicated that Ni60＋50wt% Cr3C2 composite coating had dense and homogeneous structure,as well as a metallurgical bonding with the substrate.With the increase of Cr3C2 content,volume of chromium-containing compounds in the composite coating increased,microhardness increased and microstructure refined.The thermal physical parameters results showed that Ni60＋50wt% Cr3C2 composite coating was overall worse than W6Mo5Cr4V2,but had a higher hot yield strength to alleviate hot fatigue and surface hot wear of hot forging die during hot forging and thus improve the service life of hot forging die.
基金Under the auspices of Research&Development Special Fund for Public Welfare Industry of Ministry of Environmental Protection(No.201309062201309003)
文摘Sensitivity analysis of thermal equilibrium parameters in the reservoir module of MIKE 11 model was conducted for the Wuxikou Reservoir in Jiangxi Province of China in order to apply the module to the environmental impact assessment to accurately predict water temperature of reservoirs.Results showed that radiation parameter A and evaporation-first parameter were much more sensitive than other parameters.The values of the radiation parameter A ranged from 0.10 to 0.34.The values of evaporation-first parameter varied from 0 to 10.The sensitivity of solar absorption parameters was less than that of evaporation parameter,of which light attenuation values ranged from 0.5 to 0.7,and this parameter would not impact model results if it was more than 2.Constants in Beer's law ranged from 0.2 to 0.7.Radiation parameter B was not more sensitive than evaporation parameter and its reasonable range was higher than 0.48.The fitting curves showed consistent changing tendency for these parameters within the reasonable ranges.Additionally,all the thermal equilibrium parameters had much more important effects on surface water temperature than deep water temperature.Moreover,if no observed data could be obtained,the local empirical value would be used to input to the MIKE 11 model to simulate the changes in the discharged outflow-water temperature qualitatively.
文摘Simple parameterized models, either whole mantle convection or layered mantleconvection, cannot explain the tectonic characteristics of the Earth's evolution history, therefore a mixed mantle convection model has been carried out in this paper. We introduce a time-dependent parameter F, which denotes the ratio betWeen the mantle material involved in whole mantle convection and the material of the entire mantle, and introduce a local Rayleigh number Raloc as well as two critical numbers Ra1 and Ra2. These parameters are used to describe the stability of the phase boundary between the upper and lower mantle. The result shows that the mixed mantle convection model is able to simulate the episodic tectonic evolution of the Earth.
基金supported by the National Natural Science Foundation of China(Nos.11732011,11672205,and 11332007)the National Key Research and Development Program of China(No.2016YFA0401200)
文摘The high temperature gas occurs behind shock or near the wall surface of vehicle in the hypersonic flight. As the temperature exceeds 2 000 K, 4 000 K, respectively, O2 and N2 molecules are successively dissociated. Because of variable components at dif- ferent temperatures and pressures, the dissociated air is no longer a perfect gas, In this paper, a new method is developed to calculate accurate thermal physical parameters with the dissociation degree providing the thermochemical equilibrium procedure. Based on the dissociation degree, it is concluded that few numbers of equations and the solutions are easily obtained. In addition, a set of formulas relating the parameter to the dissociation degree are set up four-species, O2 molecule The thermodynamic properties of dissociated air containing and N2 molecule, O atom and N atom, are studied with the new method, and the results are consistent with those with the traditional equilibrium constant method. It is shown that this method is reliable for solving thermal physical parameters easily and directly.
基金Project supported by the National Natural Science Foundation of China (Nos. 90916009 and11172336)
文摘Through introducing the analytical problem of the plate with convection into the solution of the transient heat conduction thermal stress field model of the elastic plate, the stress reduction factor is presented explicitly in its dimensionless form. A new stress reduction factor is introduced for the purpose of comparison. The proper- ties and appropriate conditions of the stress reduction factor, the first and second ther- mal shock resistance （TSR） parameters for the high and low Biot numbers, respectively, and the approximation formulas for the intermediate Blot number-interval are discussed. To investigate the TSR of ceramics more accurately, it is recommended to combine the heat transfer theory with the theory of thermoelasticity or fracture mechanics or use a numerical method. The critical rupture temperature difference and the critical rup- ture dimensionless time can be used to characterize the TSR of ceramics intuitively and legibly.
基金supported by the Key Project of the National Natural Science Foundation of China(Grant No.U21A2058)the Hebei Guoliang New Materials Co.,Ltd.(Grant No.22150239J).
文摘An experiment was conducted to assess the impact of fused calcia-stabilized zirconia micro-powder on the thermal shock behavior of magnesia–spinel refractories.The effects of calcia-stabilized zirconia on the microstructure evolution and properties of magnesia–spinel refractories were characterized by the high-temperature elastic modulus,thermal shock damage resistance parameters,retainment of elastic modulus after thermal shock,and scanning electron microscopy.The results indicated that the incorporation of calcia-stabilized zirconia improved the thermomechanical properties and thermal shock behavior of magnesia–spinel specimens.The hot modulus of rupture of magnesia–spinel specimens increased by 2.5-fold due to the incorporation of calcia-stabilized zirconia micro-powder.The presence of a martensitic phase transformation in partially unstable ZrO2 and thermal mismatches among various phases contributed to a controlled formation of microcracks.And the pinning effect caused by the calcia-stabilized zirconia particles surrounding the grain boundaries played a crucial role in preventing the propagation of microcracks.This phenomenon significantly bolstered the thermal shock stability of magnesia–spinel refractories,consequently prolonging their service life.
基金Projects(10825209,50872117) supported by the National Natural Science Foundation of ChinaProject([2009]17) supported by Changjiang Scholar Incentive Program,China+2 种基金Project([2007]362) supported by Hunan’s Prestigious Furong Scholar Award,ChinaProject supported by Aid Program for Science and Technology Innovative Research Team in Higher Educational Instituions of Hunan Province,ChinaProject(09JJ7004) supported by the Natural Science Foundation of Hunan Province for Innovation Group,China
文摘Bi3.15Nd0.85Ti3O12 （BNT） powder and thin film were prepared by metal organic decomposition （MOD） method. The heat flow curve of BNT powder was measured with a modulated temperature differential scanning calorimeter, and thermal physical parameters such as thermal conductivity coefficient and thermal diffusion coefficient were obtained from the heat flow curve. The phase identification, ferroelectric, and piezoelectric properties of BNT thin film annealed at 700℃ were investigated with X-ray diffractometer, ferroelectric analyzer, and scanning probe microscope. The results show that the thin films consisting of a single phase of bismuth-layered perovskite are polycrystalline, without a preferred orientation. Remnant polarization 2Pr is 63.2 μC/cm2 under 530 kV/cm applied field, and the effective piezoelectric coefficient d33 is 30 pm/V.
文摘The large reserves ofoil are disposed in zones of permafrost in shelf and continental fields. In Europe the subarctic and arctic tundra are abundant only in Nenetsky autonomous area and in the north-east of the republic of Komi. Oil and gas production activity has threatened richest biological resources and health of the population of the region. A singularity of petroliferous fields of the north of Russia is the existence of the thick strata of permafrost. On top of them different heat-insulating overlying layers （snow, biogenic covers） reside. State and dynamics of permafrost cause progressing dangerous exogenic geoecological processes, which are exhibited completely. State of permafrost is instituted by exchange of heat in near-surface strata of a geological section. During the development of oil fields there is a disturbance of a temperature schedule of permafrost. For estimation of technical attack the analytical computational method of influence of the different factors on value of annual heat exchange and prediction of geocryological conditions is proposed. It is shown, that such dangerous phenomena as degradation of permafrost and thermokarst would develop in the first place, which would cause the destruction of natural ecosystems.
基金supported by the National Natural Science Foundation of China(40802026)"the Fundamental Research Funds for the Central Universities"
文摘Fifty samples from the source rocks in Member 3 and Member 4 of the Paleogene Shahejie Formation in the Bohai Bay Basin, East China, were analyzed to investigate the distribution, evolution of the molecular maturity ratios C29ββ/（ββ＋αα） and C2920S/（20S＋20R） and their control factors in the natural geological profile and sequence. The results showed that progressive changes in molecular maturity parameters are associated with major changes in thermal evolution of related biomarkers. Increases in the C29ββ/（ββ＋αα） and C2920S/（20S＋20R） ratios result from the difference in the relative rate between generation and thermal degradation of isomers involved. The samples from a hyper-saline environment below 3.5 km in which evaporitic rocks deposited shows high response of Sr/Ba, Sr/Ca, Fe/ Mn, Pr/n-C17, Ph/n-C18 and gammacerane and low response of Pr/Ph. There presents negative reversal of biomarker maturity C29ββ/（ββ＋αα, C29ββ/（ββ＋αα） and Ts/（Ts＋Ym） in the samples from hypersaline environment, reflecting that the gypsum- halite have negative effect on the isomerization of biomarker and thermal evolution of organic matter. The minerals in evaporites also retard the conventional thermal indicators including vitrinite reflectance （Ro） and pyrolysis peak temperature Tmax at the depth below 3.4 km （i.e. 〉3.4 km）, and these parameters also show the inhibition from overpressure in the range of 2.4-3.4 kin. This result will be helpful in the interpretation and application of molecular maturity parameters for similar saline lacustrine basins.
基金Funded by the National Natural Science Foundation of China(51275445)
文摘We investigated the influences of process parameters on the head curvature of pure titanium sheet in hot rolling process and proposed the controlling means. First, the thermal simulation experiments for pure titanium TA1 were carried out to investigate the hot deformation behaviors of pure titanium in the temperature range of 700-800 ℃ with strain rate range of 1-20 S-1, and the processing map was established to determine optimized deformation parameters. Then, the finite element model has been constructed and used to analyze the effect of process parameters on the direction and severity of head curvature of pure titanium sheet. The process parameters considered in the present study include workpiece temperature, work roll diameter, pass reduction, oxide scale thickness of workpiece surface, and interface friction coefficient. The simulation results show that the workpiece temperature and the interface friction coefficient are the two main factors. The proposed controlling means was carried out on a hot rolling production line and solved the head curvature problem effectively. The rolling practices indicate that the rolling yield is improved greatly.
文摘In this paper, the thermal field of double wire welding is simulated by using ANSYS software. Simulation results were shown that the total heat input (E) is the most significant parameters to change the value of t8/5;By the mean of rationally controlling the proportion of the front arc heat input (E1) in the total heat input (E) and appropriately selecting double wire spacing (L), It is effective means to get the double wire welding thermal cycle. By the way of simulation, it is possible to manage the thermal input in the double welding wires and to control the temperature field and cooling rate that are fundamental for the final joint quality, it is great importance guidance to optimize the double wire welding process parameters.
基金the Major Scientific Research Project of Shanghai Science & Technology Commission (No.08DZ1100302)the National Basic Research Program (973) of China (No.2011CB706600)
文摘A three-factor three-level orthogonal test project has been designed based on the numerical simulation of a Jominy quenching process.Then the data scattering effects of thermal conductivity and enthalpy of tested steel,as well as the heat exchange coefficients of the cooling media,on the results have been studied.The results can be used as a reference for choosing the input thermal parameter in finite element simulation of quenching,and for evaluating the simulation results.
基金Supported by National Natural Science Foundation of China(Grant Nos.51105092,61403106)International Science and Technology Cooperation Program of China(Grant No.2014DFR50250)the 111 Project,China(Grant No.B07018)
文摘The efficiency and precision of parameter calibration in discrete element method （DEM） are not satisfactory, and parameter calibration for granular heat transfer is rarely involved. Accordingly, parameter calibration for granular heat transfer with the DEM is studied. The heat transfer in granular assemblies is simulated with DEM, and the effective thermal conductivity （ETC） of these granular assemblies is measured with the transient method in simulations. The measurement testbed is designed to test the ETC of the granular assemblies under normal pressure and a vacuum based on the steady method. Central composite design （CCD） is used to simulate the impact of the DEM parameters on the ETC of granular assemblies, and the heat transfer parameters are calibrated and compared with experimental data. The results show that, within the scope of the considered parameters, the ETC of the granular assemblies increases with an increasing particle thermal conductivity and decreases with an increasing particle shear modulus and particle diameter. The particle thermal conductivity has the greatest impact on the ETC of granular assemblies followed by the particle shear modulus and then the particle diameter. The calibration results show good agreement with the experimental results. The error is less than 4%, which is within a reasonable range for the scope of the CCD parameters. The proposed research provides high efficiency and high accuracy parameter calibration for granular heat transfer in DEM.
基金partially funded by the Tunisian Ministry of Higher Education and Scientific Research,the Spanish Programa Nacional de Materiales through project MAT2014-51778-C2-2-Rby the Universitat de Girona contract No.MPCUd G2016/059.Dfinancial support of the Tunisian Ministry of Higher Education and Scientific Research
文摘The new organic-inorganic compound, [C_6H_7N_2O_2]_3TeCl_5·2Cl was synthesized and its structure was determined at room temperature in the triclinic system （P^-1） with the following parameters： a = 10.5330（11） ？, b = 10.6663（11） ？, c = 15.9751（16）？, α = 82.090（2）°, β = 71.193（2）°, γ = 68.284（2）°and Z = 2. The final cycle of refinement led to R = 0.057 and Rw = 0.149. The crystal structure was stabilized by an extensive network of N--H···Cl and non-classical C--H···Cl hydrogen bonds between the cation and the anionic group. Several thermal analysis techniques such as thermogravimetric analysis, differential scanning calorimetric analysis and evolved gas analysis were used. We used isoconversional kinetics methods to determine the kinetics parameters. We observe that the decomposition of [C_6H_7N_2O_2]_3TeCl_5·2Cl entails the formation hydrochloric acid of nitroaniline as volatiles. The infrared spectra were recorded in the4000–400 cm^（-1）frequency region. The Raman spectra were recorded in the external region of the anionic sublattice vibration 50–1500 cm^（-1）. The optical band gap was calculated from the UV-Vis absorbance spectra using classical Tauc relation which was found to be 3.12 and 3.67 eV.
