Recent advancements in thermal conductivity modulating strategies have shown promising enhancements to the thermal management capabilities of two-dimensional materials.In this article,both the iterative Boltzmann tran...Recent advancements in thermal conductivity modulating strategies have shown promising enhancements to the thermal management capabilities of two-dimensional materials.In this article,both the iterative Boltzmann transport equation solution and the two-temperature model were employed to investigate the efficacy of targeted phonon excitation applied to hexagonal boron nitride(hBN).The results indicate significant modifications to hBN's thermal conductivity,achieving increases of up to 30.1%as well as decreases of up to 59.8%.These findings validate the reliability of the strategy,expand its scope of applicability,and establish it as a powerful tool for tailoring thermal properties across a wider range of fields.展开更多
To obtain the adjustable photonic crystals (PCs), we numerically investigate one-dimensional (1D) PCs with alternating VO2 and SiO2 layers through transfer matrix method. The dispersion relation agrees well with the t...To obtain the adjustable photonic crystals (PCs), we numerically investigate one-dimensional (1D) PCs with alternating VO2 and SiO2 layers through transfer matrix method. The dispersion relation agrees well with the transmittance obtained by the finite element calculation. Tunable band gaps are achieved with the thermal stimuli of VO2, which has two crystal structures. The monoclinic crystal structure VO2 (R) at low temperature exhibits insulating property, and the high temperature square rutile structure VO2 (M) presents metal state. Concretely, the bandwidth is getting narrower and red shift occurs with the higher temperature in VO2 (R)/SiO2 PCs structure. Based on the phase change characteristics of VO2, we can flexibly adjust the original structure as VO2 (R)/VO2 (M)/SiO2. By increasing the phase ratio of VO2 (R) to VO2 (M), the band gap width gradually becomes wider and blue shift occurs. The discrete layers of gradient composites on the dispersion of 1D PCs are also investigated, which enhances the feasibility in practical operation. Thus, our proposed thermal modulation PCs structure paves a new way to realize thermal tunable optical filters and sensors.展开更多
This paper proposed a new function of photovoltaic thermal(PVT)module to produce nocturnal cool water not just only generating electrical power and hot water during daytime.Experimental tests were carried out under Ch...This paper proposed a new function of photovoltaic thermal(PVT)module to produce nocturnal cool water not just only generating electrical power and hot water during daytime.Experimental tests were carried out under Chiang Mai tropical climate with a 200 Wp monocrystalline PVT module having dimensions of 1.601 m×0.828 m connected with two water tanks each of 60 L taken for hot and cool water storages.The module was facing south with 18o inclination.The electrical load was a 200 W halogen lamp.From experiments,by taking the module as a nocturnal radiative cooling surface,the cool water temperature in the cool storage tank could be reduced 2℃–3℃each night and the temperature could be reduced from 31.5℃to 22.1℃within 4 consecutive days.The cool water at approximately 23℃was also used to cool down the PVT module from noon when the PVT module temperature was rather high,and then the module temperature immediately dropped around 5℃and approximately 10%increase of electrical power could be achieved.A set of mathematical models was also developed to predict the PVT module temperature and the hot water temperature including the cool water temperature in the storage tanks during daytime and nighttime.The simulated results agreed well with the experimental data.展开更多
Resistive switching random access memory(RRAM) is considered as one of the potential candidates for next-generation memory. However, obtaining an RRAM device with comprehensively excellent performance, such as high re...Resistive switching random access memory(RRAM) is considered as one of the potential candidates for next-generation memory. However, obtaining an RRAM device with comprehensively excellent performance, such as high retention and endurance, low variations, as well as CMOS compatibility, etc., is still an open question. In this work, we introduce an insert TaO_(x) layer into HfO_(x)-based RRAM to optimize the device performance. Attributing to robust filament formed in the TaO_(x) layer by a forming operation, the local-field and thermal enhanced effect and interface modulation has been implemented simultaneously. Consequently, the RRAM device features large windows(> 10^(3)), fast switching speed(-10 ns), steady retention(> 72h), high endurance(> 10^(8) cycles), and excellent uniformity of both cycle-to-cycle and device-to-device. These results indicate that inserting the TaO_(x) layer can significantly improve HfO_(x)-based device performance, providing a constructive approach for the practical application of RRAM.展开更多
The Indian Test Blanket Module（TBM） program in ITER is one of the major steps in its fusion reactor program towards DEMO and the future fusion power reactor vision. Research and development（RD） is focused on two t...The Indian Test Blanket Module（TBM） program in ITER is one of the major steps in its fusion reactor program towards DEMO and the future fusion power reactor vision. Research and development（RD） is focused on two types of breeding blanket concepts： lead–lithium ceramic breeder（LLCB） and helium-cooled ceramic breeder（HCCB） blanket systems for the DEMO reactor. As part of the ITER-TBM program, the LLCB concept will be tested in one-half of ITER port no. 2, whose materials and technologies will be tested during ITER operation. The HCCB concept is a variant of the solid breeder blanket, which is presently part of our domestic RD program for DEMO relevant technology development. In the HCCB concept Li_2TiO_3 and beryllium are used as the tritium breeder and neutron multiplier, respectively, in the form of a packed bed having edge-on configuration with reduced activation ferritic martensitic steel as the structural material. In this paper two design schemes, mainly two different orientations of pebble beds, are discussed. In the current concept（case-1）, the ceramic breeder beds are kept horizontal in the toroidal–radial direction. Due to gravity, the pebbles may settle down at the bottom and create a finite gap between the pebbles and the top cooling plate, which will affect the heat transfer between them. In the alternate design concept（case-2）, the pebble bed is vertically（poloidal–radial） orientated where the side plates act as cooling plates instead of top and bottom plates. These two design variants are analyzed analytically and 2 D thermal-hydraulic simulation studies are carried out with ANSYS, using the heat loads obtained from neutronic calculations.Based on the analysis the performance is compared and details of the thermal and radiative heat transfer studies are also discussed in this paper.展开更多
The quest for materials and devices that are capable of controlling heat flux continues to fuel research on thermal controlling devices. In this letter, using molecular dynamics simulations, we demonstrate that a part...The quest for materials and devices that are capable of controlling heat flux continues to fuel research on thermal controlling devices. In this letter, using molecular dynamics simulations, we demonstrate that a partially clamped singlelayer graphene can serve as a thermal modulator. The mismatch in phonon dispersion between the unclamped and clamped graphene sections results in phonon interface scattering, and the strength of interface scattering is tunable by controlling the clamp-graphene distance via applying the external pressure. Owing to the ultra-thin structure of graphene and its highly sensitive phonon dispersion to external physical interaction, the modulation efficiency--which is defined as the ratio of the highest to lowest heat flux-can reach as high as 150% at a moderate pressure of 50 GPa. This modulation efficiency can be further enhanced by arranging a number of clamps in series along the direction of the heat flux.展开更多
Thermal properties are essentially decided by atomic geometry and thus stress is the most direct way for manipulating. In this paper, we investigate stress modulation of thermal conductivity of graphene by molecular d...Thermal properties are essentially decided by atomic geometry and thus stress is the most direct way for manipulating. In this paper, we investigate stress modulation of thermal conductivity of graphene by molecular dynamics simulations and discuss the underlying microscopic mechanism. It is found that thermal conductivity of ftexural-free graphene increases with compression and decreases with strain, while thermal conductivity of flexural-included graphene decreases with both compression and strain. Such difference in thermal behavior originates from the changes in the anharmonicity of the interatomic potential, where the wrinkle scattering is responsible for the thermal conductivity diminishment in flexural-included graphene under strain. By comparing the results obtained from the Tersoff and AIREBO potentials, it is revealed that the degree of the symmetry of interatomic potential determines the thermal conductivity variation of graphene. Our results indicate that the symmetry of interatomic potential should be taken into careful consideration in constructing the lattice model of graphene.展开更多
Electrothermal metasurfaces have garneredconsiderable attention owing to their ability to dynamicallycontrol thermal infrared radiation. Although previousstudies were mainly focused on metasurfaces with infiniteunit c...Electrothermal metasurfaces have garneredconsiderable attention owing to their ability to dynamicallycontrol thermal infrared radiation. Although previousstudies were mainly focused on metasurfaces with infiniteunit cells, in practice, the finite-size effect can be a criticaldesign factor for developing thermal metasurfaces withfast response and broad temperature uniformity. Here, westudy the thermal metasurfaces consisting of goldnanorods with a finite array size, which can achieve aresonance close to that of the infinite case with onlyseveral periods. More importantly, such a small footprintdue to the finite array size yields response time down to ananosecond level. Furthermore, the number of the unitcells in the direction perpendicular to the axis of nanorodsis found to be insensitive to the resonance and responsetime;thus, providing a tunable aspect ratio that can boostthe temperature uniformity in the sub-Kelvin level.展开更多
基金supported by the National Key Research and Development Project of China(Grant No.2018YFE0127800)。
文摘Recent advancements in thermal conductivity modulating strategies have shown promising enhancements to the thermal management capabilities of two-dimensional materials.In this article,both the iterative Boltzmann transport equation solution and the two-temperature model were employed to investigate the efficacy of targeted phonon excitation applied to hexagonal boron nitride(hBN).The results indicate significant modifications to hBN's thermal conductivity,achieving increases of up to 30.1%as well as decreases of up to 59.8%.These findings validate the reliability of the strategy,expand its scope of applicability,and establish it as a powerful tool for tailoring thermal properties across a wider range of fields.
基金Project supported by the Key Science and Technology Research Project of Henan Province, China (Grant No. 1721023100107).
文摘To obtain the adjustable photonic crystals (PCs), we numerically investigate one-dimensional (1D) PCs with alternating VO2 and SiO2 layers through transfer matrix method. The dispersion relation agrees well with the transmittance obtained by the finite element calculation. Tunable band gaps are achieved with the thermal stimuli of VO2, which has two crystal structures. The monoclinic crystal structure VO2 (R) at low temperature exhibits insulating property, and the high temperature square rutile structure VO2 (M) presents metal state. Concretely, the bandwidth is getting narrower and red shift occurs with the higher temperature in VO2 (R)/SiO2 PCs structure. Based on the phase change characteristics of VO2, we can flexibly adjust the original structure as VO2 (R)/VO2 (M)/SiO2. By increasing the phase ratio of VO2 (R) to VO2 (M), the band gap width gradually becomes wider and blue shift occurs. The discrete layers of gradient composites on the dispersion of 1D PCs are also investigated, which enhances the feasibility in practical operation. Thus, our proposed thermal modulation PCs structure paves a new way to realize thermal tunable optical filters and sensors.
文摘This paper proposed a new function of photovoltaic thermal(PVT)module to produce nocturnal cool water not just only generating electrical power and hot water during daytime.Experimental tests were carried out under Chiang Mai tropical climate with a 200 Wp monocrystalline PVT module having dimensions of 1.601 m×0.828 m connected with two water tanks each of 60 L taken for hot and cool water storages.The module was facing south with 18o inclination.The electrical load was a 200 W halogen lamp.From experiments,by taking the module as a nocturnal radiative cooling surface,the cool water temperature in the cool storage tank could be reduced 2℃–3℃each night and the temperature could be reduced from 31.5℃to 22.1℃within 4 consecutive days.The cool water at approximately 23℃was also used to cool down the PVT module from noon when the PVT module temperature was rather high,and then the module temperature immediately dropped around 5℃and approximately 10%increase of electrical power could be achieved.A set of mathematical models was also developed to predict the PVT module temperature and the hot water temperature including the cool water temperature in the storage tanks during daytime and nighttime.The simulated results agreed well with the experimental data.
基金supported by the National Key R&D Program of China under Grant No.2018YFA0701500the National Natural Science Foundation of China under Grant Nos.61825404,U20A20220,61732020,and 61851402+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences under Grant No.XDB44000000the China Postdoctoral Science Foundation under Grant No.2020M681167。
文摘Resistive switching random access memory(RRAM) is considered as one of the potential candidates for next-generation memory. However, obtaining an RRAM device with comprehensively excellent performance, such as high retention and endurance, low variations, as well as CMOS compatibility, etc., is still an open question. In this work, we introduce an insert TaO_(x) layer into HfO_(x)-based RRAM to optimize the device performance. Attributing to robust filament formed in the TaO_(x) layer by a forming operation, the local-field and thermal enhanced effect and interface modulation has been implemented simultaneously. Consequently, the RRAM device features large windows(> 10^(3)), fast switching speed(-10 ns), steady retention(> 72h), high endurance(> 10^(8) cycles), and excellent uniformity of both cycle-to-cycle and device-to-device. These results indicate that inserting the TaO_(x) layer can significantly improve HfO_(x)-based device performance, providing a constructive approach for the practical application of RRAM.
文摘The Indian Test Blanket Module（TBM） program in ITER is one of the major steps in its fusion reactor program towards DEMO and the future fusion power reactor vision. Research and development（RD） is focused on two types of breeding blanket concepts： lead–lithium ceramic breeder（LLCB） and helium-cooled ceramic breeder（HCCB） blanket systems for the DEMO reactor. As part of the ITER-TBM program, the LLCB concept will be tested in one-half of ITER port no. 2, whose materials and technologies will be tested during ITER operation. The HCCB concept is a variant of the solid breeder blanket, which is presently part of our domestic RD program for DEMO relevant technology development. In the HCCB concept Li_2TiO_3 and beryllium are used as the tritium breeder and neutron multiplier, respectively, in the form of a packed bed having edge-on configuration with reduced activation ferritic martensitic steel as the structural material. In this paper two design schemes, mainly two different orientations of pebble beds, are discussed. In the current concept（case-1）, the ceramic breeder beds are kept horizontal in the toroidal–radial direction. Due to gravity, the pebbles may settle down at the bottom and create a finite gap between the pebbles and the top cooling plate, which will affect the heat transfer between them. In the alternate design concept（case-2）, the pebble bed is vertically（poloidal–radial） orientated where the side plates act as cooling plates instead of top and bottom plates. These two design variants are analyzed analytically and 2 D thermal-hydraulic simulation studies are carried out with ANSYS, using the heat loads obtained from neutronic calculations.Based on the analysis the performance is compared and details of the thermal and radiative heat transfer studies are also discussed in this paper.
文摘The quest for materials and devices that are capable of controlling heat flux continues to fuel research on thermal controlling devices. In this letter, using molecular dynamics simulations, we demonstrate that a partially clamped singlelayer graphene can serve as a thermal modulator. The mismatch in phonon dispersion between the unclamped and clamped graphene sections results in phonon interface scattering, and the strength of interface scattering is tunable by controlling the clamp-graphene distance via applying the external pressure. Owing to the ultra-thin structure of graphene and its highly sensitive phonon dispersion to external physical interaction, the modulation efficiency--which is defined as the ratio of the highest to lowest heat flux-can reach as high as 150% at a moderate pressure of 50 GPa. This modulation efficiency can be further enhanced by arranging a number of clamps in series along the direction of the heat flux.
基金supported by the National Natural Science Foundation of China(Grant Nos.11335006,and 11405245)
文摘Thermal properties are essentially decided by atomic geometry and thus stress is the most direct way for manipulating. In this paper, we investigate stress modulation of thermal conductivity of graphene by molecular dynamics simulations and discuss the underlying microscopic mechanism. It is found that thermal conductivity of ftexural-free graphene increases with compression and decreases with strain, while thermal conductivity of flexural-included graphene decreases with both compression and strain. Such difference in thermal behavior originates from the changes in the anharmonicity of the interatomic potential, where the wrinkle scattering is responsible for the thermal conductivity diminishment in flexural-included graphene under strain. By comparing the results obtained from the Tersoff and AIREBO potentials, it is revealed that the degree of the symmetry of interatomic potential determines the thermal conductivity variation of graphene. Our results indicate that the symmetry of interatomic potential should be taken into careful consideration in constructing the lattice model of graphene.
文摘Electrothermal metasurfaces have garneredconsiderable attention owing to their ability to dynamicallycontrol thermal infrared radiation. Although previousstudies were mainly focused on metasurfaces with infiniteunit cells, in practice, the finite-size effect can be a criticaldesign factor for developing thermal metasurfaces withfast response and broad temperature uniformity. Here, westudy the thermal metasurfaces consisting of goldnanorods with a finite array size, which can achieve aresonance close to that of the infinite case with onlyseveral periods. More importantly, such a small footprintdue to the finite array size yields response time down to ananosecond level. Furthermore, the number of the unitcells in the direction perpendicular to the axis of nanorodsis found to be insensitive to the resonance and responsetime;thus, providing a tunable aspect ratio that can boostthe temperature uniformity in the sub-Kelvin level.
