Elastic strain constitutes a decisive factor in determining the recoverable deformability of thermoelectric materials.Plastic deformation for microstructure engineering has been demonstrated as a viable approach to en...Elastic strain constitutes a decisive factor in determining the recoverable deformability of thermoelectric materials.Plastic deformation for microstructure engineering has been demonstrated as a viable approach to enhance the elastic strain.However,this approach is highly dependent on the material's plasticity,which is rather limited by the rigidity for the majority of inorganic semiconducting thermoelectric materials.Thermocouple materials,as metallic thermoelectric materials,possess a favorable plasticity,motivating this work to focus on the elastic bendability of a metallic thermoelectric generator that is composed of K-type thermocouple components,namely p-type Ni_(90)Cr_(10) and n-type Ni_(95)Al_(2)Mn_(2)Si.The cold-rolling process enables a large elastic modulus and a high yield strength,thanks to the texturized direction along<111>,and dense dislocations and refined grains,respectively,eventually resulting in a 400%increase in the elastic strain.Such superior elasticity ensures the preservation of the initial transport properties for the rolled films even after being bent 100000 times within a radius of~8 mm.A power output of~414μW is achieved in a ten-leg flexible thermoelectric device,suggesting its substantial potential for powering wearable electronics.展开更多
In order to decrease the consumption of reagents and silicon during removal of surface contamination before silicon texturing in solar cell manufacturing industry, a new low-cost surface treatment approach of electroc...In order to decrease the consumption of reagents and silicon during removal of surface contamination before silicon texturing in solar cell manufacturing industry, a new low-cost surface treatment approach of electrochemical cleaning technique(ECT) is reported. In this technique, a powerful oxidizing electrolyte was obtained from the electrochemical reaction on Boron-doped Diamond(BDD) electrodes, and applied during removal of surface contaminations on silicon wafer surfaces. The slightly polished monocrystalline silicon surfaces after cleaning were compared with the ones of primal silicon wafers. The measurement results show that ECT is quite efficient in removing NaCl and organic contaminants. After cleaning, the contrast test was conducted for the textured silicon wafers with/without pre-treatment(polish) separately. The results show that the size of pyramids on the surface without traditional polishing process is homogeneous and smaller than 4μm, and the average surface reflectance is much lower in the wavelength range from 400nm to 800nm. Therefore, the new technique can save silicon material, and effectively avoid optical losses for improving photoconversion effect of solar cells.展开更多
Semi-transparent organic photovoltaics(ST-OPVs)have great potential for photovoltaic building integration and agricultural greenhouse energy.However,the mutually constraining relationship between average visible trans...Semi-transparent organic photovoltaics(ST-OPVs)have great potential for photovoltaic building integration and agricultural greenhouse energy.However,the mutually constraining relationship between average visible transmittance(AVT)and power conversion efficiency(PCE)remains a key issue of STOPVs.Herein,we innovatively applied a surface texturization strategy by integrating with a pseudo-planar heterojunction(PPHJ)structure to fabricate ST-OPVs,which possess outstanding photoelectric conversion and light management capability.The textured active layer performs significantly improved light capture capability and reduced optical loss due to that the micro-patterned arrays can deflect incident light multiple times.Moreover,the surface texturization strategy can enhance the crystallinity of the active layer and precisely control donor/acceptor inter-penetration,which magnifies exciton dissociation interface and forms ordered carrier dynamics.Consequently,the textured opaque device via blade-coating performs a record PCE of 19.17%(certified 19.02%)and the semi-transparent device achieves one of the highest light utilization efficiency(LUE)of 5.54%with prominent PCE(14.40%)and AVT(38.43%).Most importantly,the excellent thermal insulation performance and color rendering index of ST-OPVs are fitting for the agricultural greenhouses and insulation roofing,which shows that the surface texturization strategy can provide promising application prospects for ST-OPVs in economically sustainable agricultural development.展开更多
Etching was performed on （100） silicon wafers using silicon-dissolved tetramethylammonium hydroxide （TMAH） solutions without the addition of surfactant. Experiments were carried out in different TMAH concentration...Etching was performed on （100） silicon wafers using silicon-dissolved tetramethylammonium hydroxide （TMAH） solutions without the addition of surfactant. Experiments were carried out in different TMAH concentrations at different temperatures for different etching times. The surface phenomena, etching rates, surface morphology and surface reflectance were analyzed. Experimental results show that the resulting surface covered with uniform pyramids can be realized with a small change in etching rates during the etching process. The etching mechanism is explained based on the experimental results and the theoretical considerations. It is suggested that all the components in the TMAH solutions play important roles in the etching process. Moreover, TMA^＋ ions may increase the wettability of the textured surface. A good textured surface can be obtained in conditions where the absorption of OH-/H2O is in equilibrium with that of TMA＋/SiO2（OH）2^-.展开更多
Heterojunction with intrinsic thin-layer （HIT） solar cells are sensitive to interface state density. Tradi- tional texture process for silicon solar cells is not suitable for HIT one. Thus, sodium hydroxide （NaOH）...Heterojunction with intrinsic thin-layer （HIT） solar cells are sensitive to interface state density. Tradi- tional texture process for silicon solar cells is not suitable for HIT one. Thus, sodium hydroxide （NaOH）, isopropanol （IPA） and mixed additive were tentatively introduced for the texturization of HIT solar cells in this study. Then, a mixture including nitric acid （HNO3）, hydrofluoric acid （HF） and glacial acetic acid （CH3COOH） was employed to round pyramid structure. The morphology of textured surface and the influence of etching time on surface reflectance were studied, and the relationship between etching time and surface reflectance, vertex angle of pyramid structure was analyzed. It was found that the mixture consisting of 1.1 wt% NaOH, 3 vol% IPA and 0.3 vol% additives with etching time of 22.5 min is the best for H1T solar cells under the condition of 80℃. Uniform pyramid structure was observed and the base width of pyramid was about 2-4 μm. The average surface reflec- tance was 11.68%. Finally the effect of different processes on the performance of HIT solar cells was investigated. It was shown that these texturization and rounding techni- ques used in this study can increase short circuit current （Jsc）, but they have little influence on fill factor （FF） and open circuit voltage （Voo） of HIT solar cells.展开更多
The deformation behavior of GH4169 superalloy under room-temperature uniaxial tension was investigated through synchronized mesoscopic digital image correlation(DIC)and electron backscatter diffraction(EBSD)in-situ ch...The deformation behavior of GH4169 superalloy under room-temperature uniaxial tension was investigated through synchronized mesoscopic digital image correlation(DIC)and electron backscatter diffraction(EBSD)in-situ characterization techniques.Results show that in the field of grain deflection dynamics,through quantitative analysis using the independently developed M-DIC software,during uniaxial tension with significant bidirectional rotation along the tensile axis and the stress level of 1100 MPa,oscillatory rotation of±0.6°can be obtained,and microvoids are generated at the grain boundaries with 45°to the stress axis.EBSD crystallographic analysis demonstrates the load-dependent slip system evolution:in the initial stage,the soft-oriented systems with high Schmid factor(>0.4)is activated and then transformed into hard-oriented systems during cross-slip,generating parallel slip bands and dislocation pile-ups at grain boundaries.During the uniaxial tensile process,the characteristic of strain energy accumulation is observed,which follows a two-stage accumulation pattern:initial grain boundary localization(Stage I)and intragranular propagation(Stage II).Ultimately,the intergranular cracks are initiated at triple junctions,and the twin boundaries exhibit superior mechanical stability compared with the large-angle grain boundaries.Deformation texture characteristics indicate the copper-type components,including C{112}<111¯>,S{123}<634¯>,and B{110}<11¯0>.The complete deformation sequence is as follows:cross-slip of soft-oriented slip systems→initiation of dislocation slip→strain partitioning through grain rotation→intergranular stress concentration→damage dominated by boundary cracking.The cross-scale deformation mechanism revealed in this study provides critical guidance for the crystal boundary engineering to optimize nickel-based superalloys.展开更多
Texture and grain structure evolution during annealing and their effects on tensile strength and anisotropy were studied using XRD,DSC,SEM,EBSD and TEM.The results indicate that elevated rolling temperatures reduce th...Texture and grain structure evolution during annealing and their effects on tensile strength and anisotropy were studied using XRD,DSC,SEM,EBSD and TEM.The results indicate that elevated rolling temperatures reduce the f(g)_(max(Copper))/f(g)_(max(Brass))ratio,increase S-Brass fine bands,and promote S-dispersoid precipitation,leading to finer recrystallized grains.Dominant recrystallization textures transform from Goss+P to Goss and then to Goss+Cube with increasing rolling temperature.Annealing at 350℃shows four tensile strength response stages:fast softening I,rapid strengthening II,slow strengthening III,and slow softening IV.The transition from Stages I to II is driven by the formation of strong Goss and P textures,and Stage IV is linked to enhanced Cube texture.Plates with Goss+Cube textures and fine equiaxed grains exhibit the lowest YS/UTS ratio and minimal anisotropy.展开更多
[Objectives]This study was conducted to establish a quantitative assessment method for the textural quality of chieh-qua fruit.[Methods]Using two modes of a texture analyzer,namely TPA(texture profile analysis)and pun...[Objectives]This study was conducted to establish a quantitative assessment method for the textural quality of chieh-qua fruit.[Methods]Using two modes of a texture analyzer,namely TPA(texture profile analysis)and puncture,the index data of the fruit were obtained by setting different trigger forces,deformation levels,test speeds,as well as puncture speeds and puncture depths.The data included TPA hardness,adhesiveness,springiness,cohesiveness,gumminess,chewiness,resilience,as well as skin hardness,skin toughness,flesh hardness,fracturability,and compactness.[Results]Different deformation levels had a significant impact on all parameters.Hardness,adhesiveness,gumminess and chewiness showed a trend of first increasing and then decreasing with the deformation level increasing.When the deformation level was 30%,the adhesiveness,gumminess and chewiness reached their maximum values.When the deformation level was 50%,TPA hardness reached its maximum.When the compression speed was 3 mm/s,the measured values of TPA hardness,adhesiveness,chewiness,and resilience were at their maximums.The skin hardness varied significantly under different trigger forces.When the trigger force was 15 g,the skin hardness reached a maximum value of 944.63 g,and the skin toughness,flesh hardness,fracturability,and compactness also reach their maximum values respectively.When the puncture depth was 12 mm,the flesh hardness and skin toughness reached their maximums of 682.51 g and 1.82 mm,respectively.In the TPA mode,the flesh hardness of chieh-qua showed an extremely significant negative correlation with springiness,cohesiveness,and resilience(P<0.01).The fruit fracturability detected by puncture had an extremely significant positive correlation with compactness(P<0.01).[Conclusions]The evaluation method for measuring chieh-qua texture by combining TPA and the puncture mode could accurately and quantitatively reflect the differences in the flesh texture quality of chieh-qua.The optimal parameters for texture measurement of chieh-qua fruit were determined as a 15 g trigger force with 50%deformation and a 3 mm/s compression speed in TPA mode,and a 15 g trigger force with a 12 mm puncture depth in puncture mode.Puncture speed was found to have no significant effect on the texture indices of chieh-qua.展开更多
The original online version of this article was revised:Several errors occurred in the published version of the article.These have now been corrected as follows:Page 2,section"2.2 Laser Texturing Procedure of Sur...The original online version of this article was revised:Several errors occurred in the published version of the article.These have now been corrected as follows:Page 2,section"2.2 Laser Texturing Procedure of Surfaces",line 2:The device name was corrected from"YDFLP-E-50-M8"to"YDFLP-50-M8."Page 3,Section 2.4:The phrase"95%confidence interval"has been corrected to"95%confidence level."Page 3,Figure 1 caption:The phrase"fandg"has been corrected to"f and g."The order"C4 and C12"has been reversed to"C12 and C4,"in accordance with the display order in the figure.Page 4,Figure reference:The phrase"Figs.4c and d"has been corrected to"Figs.5b and c."Page 5,paragraph starting with"The ANOVA results are presented...":The phrase"95%confidence interval"has been corrected to"95%confidence level."展开更多
The performance of hematite(α-Fe_(2)O_(3))photoanodes for photoelectrochemical(PEC)water splitting has been limited to around 2-5 mA cm^(-2)under standard conditions due to their short hole diffusion length and slugg...The performance of hematite(α-Fe_(2)O_(3))photoanodes for photoelectrochemical(PEC)water splitting has been limited to around 2-5 mA cm^(-2)under standard conditions due to their short hole diffusion length and sluggish oxygen evolution reaction kinetics.This work overcomes those challenges through a synergistic strategy that co-designs the hematite architecture and the surface reaction pathway.We introduce a textured and hierarchically porous Ti-doped Fe_(2)O_(3)(tp-Fe_(2)O_(3))photoanode,synthesized via multi-cycle growth and flame annealing method.This unique architecture features a high texture(110),enlarged surface area,and hierarchically porous structure,which enable significantly enhanced bulk charge transport and interfacial charge transfer compared to typical nanorod Ti-doped Fe_(2)O_(3)(nr-Fe_(2)O_(3)).As a result,the tp-Fe_(2)O_(3)photoanode achieves a photocurrent density of 3.1 mA cm^(-2)at 1.23 V vs.RHE with exceptional stability over 105 h,notably without any co-catalyst.By replacing the OER with the hydrazine oxidation reaction,the photocurrent further reaches a record-high level of 7.1 mA cm^(-2)at 1.23 V_(RHE).Finally,when we integrate the tp-Fe_(2)O_(3)with a commercial Si solar cell,it achieves a solar-to-hydrogen efficiency of 8.7%-the highest reported value for any Fe_(2)O_(3)-based PVtandem system.This work provides critical insights into rational Fe_(2)O_(3)photoanode design and highlights the potential of hydrazine as an efficient alternative anodic reaction,enabling waste valorization.展开更多
The 6D pose estimation of objects is of great significance for the intelligent assembly and sorting of industrial parts.In the industrial robot production scenarios,the 6D pose estimation of industrial parts mainly fa...The 6D pose estimation of objects is of great significance for the intelligent assembly and sorting of industrial parts.In the industrial robot production scenarios,the 6D pose estimation of industrial parts mainly faces two challenges:one is the loss of information and interference caused by occlusion and stacking in the sorting scenario,the other is the difficulty of feature extraction due to the weak texture of industrial parts.To address the above problems,this paper proposes an attention-based pixel-level voting network for 6D pose estimation of weakly textured industrial parts,namely CB-PVNet.On the one hand,the voting scheme can predict the keypoints of affected pixels,which improves the accuracy of keypoint localization even in scenarios such as weak texture and partial occlusion.On the other hand,the attention mechanism can extract interesting features of the object while suppressing useless features of surroundings.Extensive comparative experiments were conducted on both public datasets(including LINEMOD,Occlusion LINEMOD and T-LESS datasets)and self-made datasets.The experimental results indicate that the proposed network CB-PVNet can achieve accuracy of ADD(-s)comparable to state-of-the-art using only RGB images while ensuring real-time performance.Additionally,we also conducted robot grasping experiments in the real world.The balance between accuracy and computational efficiency makes the method well-suited for applications in industrial automation.展开更多
A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The resu...A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The results show that cold-pressing produces intense plastic deformation near the corrugated surface of the Al plate,which promotes dynamic recrystallization of the Al substrate near the interface during the subsequent hot-pressing.In addition,the initial corrugation on the surface of the Al plate also changes the local stress state near the interface during hot pressing,which has a large effect on the texture components of the substrates near the corrugated interface.The construction of the corrugated interface can greatly enhance the shear strength by 2−4 times due to the increased contact area and the strong“mechanical gearing”effect.Moreover,the mechanical properties are largely depended on the orientation relationship between corrugated direction and loading direction.展开更多
The microstructure and mechanical properties of ZK60 extruded alloy by rapid solidification(RS)and as-cast ingot processes were investigated using optical microscope,scanning electron microscope,X-ray diffraction,elec...The microstructure and mechanical properties of ZK60 extruded alloy by rapid solidification(RS)and as-cast ingot processes were investigated using optical microscope,scanning electron microscope,X-ray diffraction,electron back-scatter diffraction,and mechanical tests.The results show that the RS ZK60 extruded alloy exhibits relatively high tensile yield strength(TYS),compressive yield strength(CYS)and elongation of 300.8 MPa,303.6 MPa and 18.6%,respectively.The RS ZK60 extruded alloy with an ultra-fine grain size of 1.28μm not only has a weak texture with a maximum polar density of 3.3 but also addresses the tension-compression asymmetry with a CYS/TYS ratio of approximately 1.0.The calculation of the strengthening mechanism indicates that the improvement in the mechanical properties of the RS ZK60 extruded alloy is primarily attributed to grain refinement.展开更多
Floating ring bearings are widely used in high-speed turbomachinery such as turbochargers and turbogenerators.Research-ers have recently explored various surface texturing strategies on the inner surface of floating r...Floating ring bearings are widely used in high-speed turbomachinery such as turbochargers and turbogenerators.Research-ers have recently explored various surface texturing strategies on the inner surface of floating rings to enhance bearing performance.In this study,the herring patterns are textured on the inner surface of the floating ring.This pattern is inspired by the secondary flight feathers of the Indian pigeon,which aid the bird in reducing viscous drag during flight.The result-ing Herringbone Textured Floating Ring Bearing(HTFRB)is investigated for its potential application in locomotive turbo-chargers.The HTFRB is numerically modeled using the Reynolds equation to evaluate the bearing's pressure distribution and static characteristics,including load-carrying capacity,power loss,and side leakage.Dynamic characteristics are determined by solving the zeroth-and first-order perturbed Reynolds equation.A Sobol sensitivity analysis is conducted to quantify the influence of groove parameters-helix angle,groove depth,groove width ratio,and number of grooves-on bearing performance metrics.An artificial intelligence-based optimization framework,integrating artificial neural networks and adaptive neuro-fuzzy inference systems,is developed to maximize load carrying capacity while minimiz-ing power loss,side leakage,and friction coefficient.The optimized texture parameters obtained from this framework are employed to validate the ANN model and evaluate the static and dynamic characteristics of the HTFRB.The dynamic coefficients of the HTFRB are further employed to evaluate the stability and robustness of the turbocharger rotor-HTFRB system.This study underscores the potential of combining bio-inspired texture design with numerical modeling and AI-based optimization to develop high-performance HTFRB.展开更多
Phosphorus(P)leaching in alkaline soils,exacerbated by excessive fertilizer application,represents a significant pathway for P loss.While soil pore structure and texture critically regulate P transport,mechanisms gove...Phosphorus(P)leaching in alkaline soils,exacerbated by excessive fertilizer application,represents a significant pathway for P loss.While soil pore structure and texture critically regulate P transport,mechanisms governing P loss in texturally diverse alkaline soils remain unclear.This study investigated P leaching dynamics and transport parameters across four alkaline soil textures(silty clay,clay loam,loam,sandy loam)using a one-dimensional convective-diffusion equation(CDE)based on column experiments.Results indicated that phosphorus leaching kinetics were predominantly governed by diffusion transport,evidenced by low Peclet numbers(P_(e))(ranged from 0.02 to 0.31)across varying textures and initial P concentrations(C_(0)).Comparative analysis of transport parameters revealed significant textural effects on dispersion coefficient(D),retardation factor(R),pore water velocity(V),P_(e),and diffusion coefficient(λ)(F>523.42,p<0.001).Among these,only D,P_(e) andλexhibited substantial differences in response to variations in C_(0)(F>89.47,p<0.001).Saturated hydraulic conductivity(K_(s))(R^(2)=62.9%,p<0.01)and total pore area(A)(R^(2)=12.4%,p<0.01)emerged as primary regulators of P leaching.Enhanced clay content increased total pore area while reducing average pore diameter,concurrently decreasing pore water velocity and saturated infiltration rates.These textural modifications amplified diffusive P transport within soil matrices.The findings provide mechanistic insights into texturedependent P mobility in alkaline environments,informing targeted strategies for agricultural phosphorus management.展开更多
To investigate the evolution of grain orientation and slip modes in magnesium alloys with multiple texture components,an AZ31 gradient-structured magnesium alloy sheet was fabricated using hard plate rolling(HPR).The ...To investigate the evolution of grain orientation and slip modes in magnesium alloys with multiple texture components,an AZ31 gradient-structured magnesium alloy sheet was fabricated using hard plate rolling(HPR).The changes in texture and slip modes under different reductions were examined.The results demonstrate that the AZ31 magnesium alloy sheets display a self-epitaxial gradient structure,with the best mechanical properties observed at rolling temperature of 673 K and reduction of 50%.Significant changes in texture type and strength are observed along the normal direction(ND)of the sheet.The coarse-grain region exhibits a bimodal texture aligned with the rolling direction.These texture variations enhance the stress distribution at the fine grain-coarse grain interface,influencing the grain orientation and the activation of different slip modes,thus improving the mechanical properties of gradient-structured magnesium alloy sheets.This approach offers a new strategy for the fabrication of high-performance magnesium alloy sheets.展开更多
Aqueous zinc-ion batteries(AZIBs)are currently confronted with the challenge of achieving long-term cyclic stability under high current densities.This issue is primarily attributed to the excessive growth of dendrites...Aqueous zinc-ion batteries(AZIBs)are currently confronted with the challenge of achieving long-term cyclic stability under high current densities.This issue is primarily attributed to the excessive growth of dendrites and the occurrence of significant side reactions.Herein,sucralose(SCL),as an electrolyte additive,has been used to promote the exposure of the Zn(002)texture.The introduction of SCL can adjust the Zn~(2+)nucleation and diffusion along different crystal facets,promoting the exposure of the Zn(002)texture.By substituting water molecules in the[Zn(H_(2)O)_(6)]~(2+),SCL reconfigures the hydrogen bond network in the electrolyte,reconstructing the solvation structure and suppressing the hydrogen evolution reaction.Consequently,the Zn//Zn symmetric battery exhibits long-term cycling stability of over 4900 h at 1 mA cm^(-2)-1 mAh cm^(-2).Even at a harsh condition of 30 mA cm^(-2)-30 mAh cm^(-2)(DOD=73.3%),it can stably cycle for 171 h.The CE of the Zn//Cu half battery reaches 99.61% at 0.2 mA cm^(-2)with 0.2 mAh cm^(-2).Employing the optimized electrolyte,after 500 cycles,a high specific capacity of 420 mAh g^(-1)can be retained for the NH_4V_4O_(10)//Zn full battery at 500 mA g^(-1),corresponding to a capacity retention of 90.7%.展开更多
Efficient tool condition monitoring techniques help to realize intelligent management of tool life and reduce tool usage costs.In this paper,the influence of different wear degrees of ball-end milling cutters on the t...Efficient tool condition monitoring techniques help to realize intelligent management of tool life and reduce tool usage costs.In this paper,the influence of different wear degrees of ball-end milling cutters on the texture shape of machining tool marks is investigated,and a method is proposed for predicting the wear state(including the position and degree of tool wear)of ball-end milling cutters based on entropy measurement of tool mark texture images.Firstly,data samples are prepared through wear experiments,and the change law of the tool mark texture shape with the tool wear state is analyzed.Then,a two-dimensional sample entropy algorithm is developed to quantify the texture morphology.Finally,the processing parameters and tool attitude are integrated into the prediction process to predict the wear value and wear position of the ball end milling cutter.After testing,the correlation between the predicted value and the standard value of the proposed tool condition monitoring method reaches 95.32%,and the accuracy reaches 82.73%,indicating that the proposed method meets the requirement of tool condition monitoring.展开更多
Rolled Mg-Al-Sn series alloys generally possess limited formability due to the formation of strong basal texture.Texture weakening is an effective way to enhance formability,but usually accompanied with decreasing str...Rolled Mg-Al-Sn series alloys generally possess limited formability due to the formation of strong basal texture.Texture weakening is an effective way to enhance formability,but usually accompanied with decreasing strength.In this work,synergistic enhancement of strength and formability is achieved in a Mg-3Al-1Sn-0.5Ca-0.1Sm(ATXS3110)alloy by 0.2 wt.%Mn addition combined with high temperature rolling,exhibiting a high index Erichsen(I.E.)value of~8.1 mm and near-isotropic mechanical properties.On one hand,after Mn addition,the grain refinement from~7.6μm to~4.1μm results in suppression of extension twinning,thereby preventing the development of strong basal texture upon stretch forming.On the other hand,trace Mn addition narrows the grain size distribution and promotes the formation of uniform fine grains,which induces homogeneous deformation during stretch forming.Moreover,grain refinement and high-density nano-sized precipitates caused by trace Mn addition increase the strength.This work may provide insights into designing low-cost Mg-Al-Sn series alloys with superior comprehensive mechanical properties for further structural applications.展开更多
An internal state variable(ISV)model was established according to the experimental results of hot plane strain compression(PSC)to predict the microstructure evolution during hot spinning of ZK61 alloy.The effects of t...An internal state variable(ISV)model was established according to the experimental results of hot plane strain compression(PSC)to predict the microstructure evolution during hot spinning of ZK61 alloy.The effects of the internal variables were considered in this ISV model,and the parameters were optimized by genetic algorithm.After validation,the ISV model was used to simulate the evolution of grain size(GS)and dynamic recrystallization(DRX)fraction during hot spinning via Abaqus and its subroutine Vumat.By comparing the simulated results with the experimental results,the application of the ISV model was proven to be reliable.Meanwhile,the strength of the thin-walled spun ZK61 tube increased from 303 to 334 MPa due to grain refinement by DRX and texture strengthening.Besides,some ultrafine grains(0.5μm)that played an important role in mechanical properties were formed due to the proliferation,movement,and entanglement of dislocations during the spinning process.展开更多
基金supported by the National Key Research and Development Program of China(2023YFB3809400)the National Natural Science Foundation of China(Grant nos.T2125008,92163203,and 52371234)+1 种基金the Hong Kong,Macao,and Taiwan Science and Technology Cooperation Project for Science and Technology Innovation Plan of Shanghai(23520760600)the Fundamental Research Funds for the Central Universities.
文摘Elastic strain constitutes a decisive factor in determining the recoverable deformability of thermoelectric materials.Plastic deformation for microstructure engineering has been demonstrated as a viable approach to enhance the elastic strain.However,this approach is highly dependent on the material's plasticity,which is rather limited by the rigidity for the majority of inorganic semiconducting thermoelectric materials.Thermocouple materials,as metallic thermoelectric materials,possess a favorable plasticity,motivating this work to focus on the elastic bendability of a metallic thermoelectric generator that is composed of K-type thermocouple components,namely p-type Ni_(90)Cr_(10) and n-type Ni_(95)Al_(2)Mn_(2)Si.The cold-rolling process enables a large elastic modulus and a high yield strength,thanks to the texturized direction along<111>,and dense dislocations and refined grains,respectively,eventually resulting in a 400%increase in the elastic strain.Such superior elasticity ensures the preservation of the initial transport properties for the rolled films even after being bent 100000 times within a radius of~8 mm.A power output of~414μW is achieved in a ten-leg flexible thermoelectric device,suggesting its substantial potential for powering wearable electronics.
基金National Natural Science Foundation of China(10676008)Specialized Research Fund for the Doctoral Program of Higher Education of China(20050080007)
文摘In order to decrease the consumption of reagents and silicon during removal of surface contamination before silicon texturing in solar cell manufacturing industry, a new low-cost surface treatment approach of electrochemical cleaning technique(ECT) is reported. In this technique, a powerful oxidizing electrolyte was obtained from the electrochemical reaction on Boron-doped Diamond(BDD) electrodes, and applied during removal of surface contaminations on silicon wafer surfaces. The slightly polished monocrystalline silicon surfaces after cleaning were compared with the ones of primal silicon wafers. The measurement results show that ECT is quite efficient in removing NaCl and organic contaminants. After cleaning, the contrast test was conducted for the textured silicon wafers with/without pre-treatment(polish) separately. The results show that the size of pyramids on the surface without traditional polishing process is homogeneous and smaller than 4μm, and the average surface reflectance is much lower in the wavelength range from 400nm to 800nm. Therefore, the new technique can save silicon material, and effectively avoid optical losses for improving photoconversion effect of solar cells.
基金the support from the National Natural Science Foundation of China (52333006)the support from the National Natural Science Foundation of China (52303232)+2 种基金the Natural Science Foundation of Jiangxi Province (20242BAB20184)the support from National Natural Science Foundation of China (52373186)the “Double Thousand Plan” Science and Technology Innovation High-end Talent Project of Jiangxi Province (jxsq2019201107).
文摘Semi-transparent organic photovoltaics(ST-OPVs)have great potential for photovoltaic building integration and agricultural greenhouse energy.However,the mutually constraining relationship between average visible transmittance(AVT)and power conversion efficiency(PCE)remains a key issue of STOPVs.Herein,we innovatively applied a surface texturization strategy by integrating with a pseudo-planar heterojunction(PPHJ)structure to fabricate ST-OPVs,which possess outstanding photoelectric conversion and light management capability.The textured active layer performs significantly improved light capture capability and reduced optical loss due to that the micro-patterned arrays can deflect incident light multiple times.Moreover,the surface texturization strategy can enhance the crystallinity of the active layer and precisely control donor/acceptor inter-penetration,which magnifies exciton dissociation interface and forms ordered carrier dynamics.Consequently,the textured opaque device via blade-coating performs a record PCE of 19.17%(certified 19.02%)and the semi-transparent device achieves one of the highest light utilization efficiency(LUE)of 5.54%with prominent PCE(14.40%)and AVT(38.43%).Most importantly,the excellent thermal insulation performance and color rendering index of ST-OPVs are fitting for the agricultural greenhouses and insulation roofing,which shows that the surface texturization strategy can provide promising application prospects for ST-OPVs in economically sustainable agricultural development.
基金Project supported by the National High Technology Research and Development Program of China(No.2007AA05Z437)
文摘Etching was performed on （100） silicon wafers using silicon-dissolved tetramethylammonium hydroxide （TMAH） solutions without the addition of surfactant. Experiments were carried out in different TMAH concentrations at different temperatures for different etching times. The surface phenomena, etching rates, surface morphology and surface reflectance were analyzed. Experimental results show that the resulting surface covered with uniform pyramids can be realized with a small change in etching rates during the etching process. The etching mechanism is explained based on the experimental results and the theoretical considerations. It is suggested that all the components in the TMAH solutions play important roles in the etching process. Moreover, TMA^＋ ions may increase the wettability of the textured surface. A good textured surface can be obtained in conditions where the absorption of OH-/H2O is in equilibrium with that of TMA＋/SiO2（OH）2^-.
文摘Heterojunction with intrinsic thin-layer （HIT） solar cells are sensitive to interface state density. Tradi- tional texture process for silicon solar cells is not suitable for HIT one. Thus, sodium hydroxide （NaOH）, isopropanol （IPA） and mixed additive were tentatively introduced for the texturization of HIT solar cells in this study. Then, a mixture including nitric acid （HNO3）, hydrofluoric acid （HF） and glacial acetic acid （CH3COOH） was employed to round pyramid structure. The morphology of textured surface and the influence of etching time on surface reflectance were studied, and the relationship between etching time and surface reflectance, vertex angle of pyramid structure was analyzed. It was found that the mixture consisting of 1.1 wt% NaOH, 3 vol% IPA and 0.3 vol% additives with etching time of 22.5 min is the best for H1T solar cells under the condition of 80℃. Uniform pyramid structure was observed and the base width of pyramid was about 2-4 μm. The average surface reflec- tance was 11.68%. Finally the effect of different processes on the performance of HIT solar cells was investigated. It was shown that these texturization and rounding techni- ques used in this study can increase short circuit current （Jsc）, but they have little influence on fill factor （FF） and open circuit voltage （Voo） of HIT solar cells.
基金National Natural Science Foundation of China(2022YFF0609300)。
文摘The deformation behavior of GH4169 superalloy under room-temperature uniaxial tension was investigated through synchronized mesoscopic digital image correlation(DIC)and electron backscatter diffraction(EBSD)in-situ characterization techniques.Results show that in the field of grain deflection dynamics,through quantitative analysis using the independently developed M-DIC software,during uniaxial tension with significant bidirectional rotation along the tensile axis and the stress level of 1100 MPa,oscillatory rotation of±0.6°can be obtained,and microvoids are generated at the grain boundaries with 45°to the stress axis.EBSD crystallographic analysis demonstrates the load-dependent slip system evolution:in the initial stage,the soft-oriented systems with high Schmid factor(>0.4)is activated and then transformed into hard-oriented systems during cross-slip,generating parallel slip bands and dislocation pile-ups at grain boundaries.During the uniaxial tensile process,the characteristic of strain energy accumulation is observed,which follows a two-stage accumulation pattern:initial grain boundary localization(Stage I)and intragranular propagation(Stage II).Ultimately,the intergranular cracks are initiated at triple junctions,and the twin boundaries exhibit superior mechanical stability compared with the large-angle grain boundaries.Deformation texture characteristics indicate the copper-type components,including C{112}<111¯>,S{123}<634¯>,and B{110}<11¯0>.The complete deformation sequence is as follows:cross-slip of soft-oriented slip systems→initiation of dislocation slip→strain partitioning through grain rotation→intergranular stress concentration→damage dominated by boundary cracking.The cross-scale deformation mechanism revealed in this study provides critical guidance for the crystal boundary engineering to optimize nickel-based superalloys.
基金financial support from the National Key Research and Development Program of China(No.2016YFB0300900)the National Key Fundamental Research Project of China(No.2012CB619506-3)the National Natural Science Foundation of China(No.51171209)。
文摘Texture and grain structure evolution during annealing and their effects on tensile strength and anisotropy were studied using XRD,DSC,SEM,EBSD and TEM.The results indicate that elevated rolling temperatures reduce the f(g)_(max(Copper))/f(g)_(max(Brass))ratio,increase S-Brass fine bands,and promote S-dispersoid precipitation,leading to finer recrystallized grains.Dominant recrystallization textures transform from Goss+P to Goss and then to Goss+Cube with increasing rolling temperature.Annealing at 350℃shows four tensile strength response stages:fast softening I,rapid strengthening II,slow strengthening III,and slow softening IV.The transition from Stages I to II is driven by the formation of strong Goss and P textures,and Stage IV is linked to enhanced Cube texture.Plates with Goss+Cube textures and fine equiaxed grains exhibit the lowest YS/UTS ratio and minimal anisotropy.
基金Supported by Shanghai Agriculture Applied Technology Development Program (Grant No.T20220120).
文摘[Objectives]This study was conducted to establish a quantitative assessment method for the textural quality of chieh-qua fruit.[Methods]Using two modes of a texture analyzer,namely TPA(texture profile analysis)and puncture,the index data of the fruit were obtained by setting different trigger forces,deformation levels,test speeds,as well as puncture speeds and puncture depths.The data included TPA hardness,adhesiveness,springiness,cohesiveness,gumminess,chewiness,resilience,as well as skin hardness,skin toughness,flesh hardness,fracturability,and compactness.[Results]Different deformation levels had a significant impact on all parameters.Hardness,adhesiveness,gumminess and chewiness showed a trend of first increasing and then decreasing with the deformation level increasing.When the deformation level was 30%,the adhesiveness,gumminess and chewiness reached their maximum values.When the deformation level was 50%,TPA hardness reached its maximum.When the compression speed was 3 mm/s,the measured values of TPA hardness,adhesiveness,chewiness,and resilience were at their maximums.The skin hardness varied significantly under different trigger forces.When the trigger force was 15 g,the skin hardness reached a maximum value of 944.63 g,and the skin toughness,flesh hardness,fracturability,and compactness also reach their maximum values respectively.When the puncture depth was 12 mm,the flesh hardness and skin toughness reached their maximums of 682.51 g and 1.82 mm,respectively.In the TPA mode,the flesh hardness of chieh-qua showed an extremely significant negative correlation with springiness,cohesiveness,and resilience(P<0.01).The fruit fracturability detected by puncture had an extremely significant positive correlation with compactness(P<0.01).[Conclusions]The evaluation method for measuring chieh-qua texture by combining TPA and the puncture mode could accurately and quantitatively reflect the differences in the flesh texture quality of chieh-qua.The optimal parameters for texture measurement of chieh-qua fruit were determined as a 15 g trigger force with 50%deformation and a 3 mm/s compression speed in TPA mode,and a 15 g trigger force with a 12 mm puncture depth in puncture mode.Puncture speed was found to have no significant effect on the texture indices of chieh-qua.
文摘The original online version of this article was revised:Several errors occurred in the published version of the article.These have now been corrected as follows:Page 2,section"2.2 Laser Texturing Procedure of Surfaces",line 2:The device name was corrected from"YDFLP-E-50-M8"to"YDFLP-50-M8."Page 3,Section 2.4:The phrase"95%confidence interval"has been corrected to"95%confidence level."Page 3,Figure 1 caption:The phrase"fandg"has been corrected to"f and g."The order"C4 and C12"has been reversed to"C12 and C4,"in accordance with the display order in the figure.Page 4,Figure reference:The phrase"Figs.4c and d"has been corrected to"Figs.5b and c."Page 5,paragraph starting with"The ANOVA results are presented...":The phrase"95%confidence interval"has been corrected to"95%confidence level."
基金supported by a National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(No.RS-2024-00335976)。
文摘The performance of hematite(α-Fe_(2)O_(3))photoanodes for photoelectrochemical(PEC)water splitting has been limited to around 2-5 mA cm^(-2)under standard conditions due to their short hole diffusion length and sluggish oxygen evolution reaction kinetics.This work overcomes those challenges through a synergistic strategy that co-designs the hematite architecture and the surface reaction pathway.We introduce a textured and hierarchically porous Ti-doped Fe_(2)O_(3)(tp-Fe_(2)O_(3))photoanode,synthesized via multi-cycle growth and flame annealing method.This unique architecture features a high texture(110),enlarged surface area,and hierarchically porous structure,which enable significantly enhanced bulk charge transport and interfacial charge transfer compared to typical nanorod Ti-doped Fe_(2)O_(3)(nr-Fe_(2)O_(3)).As a result,the tp-Fe_(2)O_(3)photoanode achieves a photocurrent density of 3.1 mA cm^(-2)at 1.23 V vs.RHE with exceptional stability over 105 h,notably without any co-catalyst.By replacing the OER with the hydrazine oxidation reaction,the photocurrent further reaches a record-high level of 7.1 mA cm^(-2)at 1.23 V_(RHE).Finally,when we integrate the tp-Fe_(2)O_(3)with a commercial Si solar cell,it achieves a solar-to-hydrogen efficiency of 8.7%-the highest reported value for any Fe_(2)O_(3)-based PVtandem system.This work provides critical insights into rational Fe_(2)O_(3)photoanode design and highlights the potential of hydrazine as an efficient alternative anodic reaction,enabling waste valorization.
基金supported by the Knowledge Innovation Program of Wuhan-Shuguang Project(Grant No.2023010201020443)the School-Level Scientific Research Project Funding Program of Jianghan University(Grant No.2022XKZX33)the Natural Science Foundation of Hubei Province(Grant No.2024AFB466).
文摘The 6D pose estimation of objects is of great significance for the intelligent assembly and sorting of industrial parts.In the industrial robot production scenarios,the 6D pose estimation of industrial parts mainly faces two challenges:one is the loss of information and interference caused by occlusion and stacking in the sorting scenario,the other is the difficulty of feature extraction due to the weak texture of industrial parts.To address the above problems,this paper proposes an attention-based pixel-level voting network for 6D pose estimation of weakly textured industrial parts,namely CB-PVNet.On the one hand,the voting scheme can predict the keypoints of affected pixels,which improves the accuracy of keypoint localization even in scenarios such as weak texture and partial occlusion.On the other hand,the attention mechanism can extract interesting features of the object while suppressing useless features of surroundings.Extensive comparative experiments were conducted on both public datasets(including LINEMOD,Occlusion LINEMOD and T-LESS datasets)and self-made datasets.The experimental results indicate that the proposed network CB-PVNet can achieve accuracy of ADD(-s)comparable to state-of-the-art using only RGB images while ensuring real-time performance.Additionally,we also conducted robot grasping experiments in the real world.The balance between accuracy and computational efficiency makes the method well-suited for applications in industrial automation.
基金supported by Guangdong Major Project of Basic and Applied Basic Research, China (No. 2020B0301030006)Fundamental Research Funds for the Central Universities, China (No. SWU-XDJH202313)+1 种基金Chongqing Postdoctoral Science Foundation Funded Project, China (No. 2112012728014435)the Chongqing Postgraduate Research and Innovation Project, China (No. CYS23197)。
文摘A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The results show that cold-pressing produces intense plastic deformation near the corrugated surface of the Al plate,which promotes dynamic recrystallization of the Al substrate near the interface during the subsequent hot-pressing.In addition,the initial corrugation on the surface of the Al plate also changes the local stress state near the interface during hot pressing,which has a large effect on the texture components of the substrates near the corrugated interface.The construction of the corrugated interface can greatly enhance the shear strength by 2−4 times due to the increased contact area and the strong“mechanical gearing”effect.Moreover,the mechanical properties are largely depended on the orientation relationship between corrugated direction and loading direction.
基金supported by Sichuan LTWT Metal Materials Co.,Ltd.,Sichuan Province,China(No.21H1367)。
文摘The microstructure and mechanical properties of ZK60 extruded alloy by rapid solidification(RS)and as-cast ingot processes were investigated using optical microscope,scanning electron microscope,X-ray diffraction,electron back-scatter diffraction,and mechanical tests.The results show that the RS ZK60 extruded alloy exhibits relatively high tensile yield strength(TYS),compressive yield strength(CYS)and elongation of 300.8 MPa,303.6 MPa and 18.6%,respectively.The RS ZK60 extruded alloy with an ultra-fine grain size of 1.28μm not only has a weak texture with a maximum polar density of 3.3 but also addresses the tension-compression asymmetry with a CYS/TYS ratio of approximately 1.0.The calculation of the strengthening mechanism indicates that the improvement in the mechanical properties of the RS ZK60 extruded alloy is primarily attributed to grain refinement.
文摘Floating ring bearings are widely used in high-speed turbomachinery such as turbochargers and turbogenerators.Research-ers have recently explored various surface texturing strategies on the inner surface of floating rings to enhance bearing performance.In this study,the herring patterns are textured on the inner surface of the floating ring.This pattern is inspired by the secondary flight feathers of the Indian pigeon,which aid the bird in reducing viscous drag during flight.The result-ing Herringbone Textured Floating Ring Bearing(HTFRB)is investigated for its potential application in locomotive turbo-chargers.The HTFRB is numerically modeled using the Reynolds equation to evaluate the bearing's pressure distribution and static characteristics,including load-carrying capacity,power loss,and side leakage.Dynamic characteristics are determined by solving the zeroth-and first-order perturbed Reynolds equation.A Sobol sensitivity analysis is conducted to quantify the influence of groove parameters-helix angle,groove depth,groove width ratio,and number of grooves-on bearing performance metrics.An artificial intelligence-based optimization framework,integrating artificial neural networks and adaptive neuro-fuzzy inference systems,is developed to maximize load carrying capacity while minimiz-ing power loss,side leakage,and friction coefficient.The optimized texture parameters obtained from this framework are employed to validate the ANN model and evaluate the static and dynamic characteristics of the HTFRB.The dynamic coefficients of the HTFRB are further employed to evaluate the stability and robustness of the turbocharger rotor-HTFRB system.This study underscores the potential of combining bio-inspired texture design with numerical modeling and AI-based optimization to develop high-performance HTFRB.
基金supported by the National Natural Science Foundation of China(Nos.42077067,42277329)the Projects of Talents Recruitment of GDUPT(No.XJ2005000301)。
文摘Phosphorus(P)leaching in alkaline soils,exacerbated by excessive fertilizer application,represents a significant pathway for P loss.While soil pore structure and texture critically regulate P transport,mechanisms governing P loss in texturally diverse alkaline soils remain unclear.This study investigated P leaching dynamics and transport parameters across four alkaline soil textures(silty clay,clay loam,loam,sandy loam)using a one-dimensional convective-diffusion equation(CDE)based on column experiments.Results indicated that phosphorus leaching kinetics were predominantly governed by diffusion transport,evidenced by low Peclet numbers(P_(e))(ranged from 0.02 to 0.31)across varying textures and initial P concentrations(C_(0)).Comparative analysis of transport parameters revealed significant textural effects on dispersion coefficient(D),retardation factor(R),pore water velocity(V),P_(e),and diffusion coefficient(λ)(F>523.42,p<0.001).Among these,only D,P_(e) andλexhibited substantial differences in response to variations in C_(0)(F>89.47,p<0.001).Saturated hydraulic conductivity(K_(s))(R^(2)=62.9%,p<0.01)and total pore area(A)(R^(2)=12.4%,p<0.01)emerged as primary regulators of P leaching.Enhanced clay content increased total pore area while reducing average pore diameter,concurrently decreasing pore water velocity and saturated infiltration rates.These textural modifications amplified diffusive P transport within soil matrices.The findings provide mechanistic insights into texturedependent P mobility in alkaline environments,informing targeted strategies for agricultural phosphorus management.
基金supported by the Natural Science Foundation of Heilongjiang Province,China(No.JQ2022E004)。
文摘To investigate the evolution of grain orientation and slip modes in magnesium alloys with multiple texture components,an AZ31 gradient-structured magnesium alloy sheet was fabricated using hard plate rolling(HPR).The changes in texture and slip modes under different reductions were examined.The results demonstrate that the AZ31 magnesium alloy sheets display a self-epitaxial gradient structure,with the best mechanical properties observed at rolling temperature of 673 K and reduction of 50%.Significant changes in texture type and strength are observed along the normal direction(ND)of the sheet.The coarse-grain region exhibits a bimodal texture aligned with the rolling direction.These texture variations enhance the stress distribution at the fine grain-coarse grain interface,influencing the grain orientation and the activation of different slip modes,thus improving the mechanical properties of gradient-structured magnesium alloy sheets.This approach offers a new strategy for the fabrication of high-performance magnesium alloy sheets.
基金supported by the Anhui Provincial Science and Technology Innovation Initiative(202423i08050051)the Anhui Provincial Natural Science Foundation(2408085MB029)+1 种基金the HFIPS Director’s Fund(YZJJGGZX202201)the Natural Science Foundation of Hebei Province of China(B2024402018)。
文摘Aqueous zinc-ion batteries(AZIBs)are currently confronted with the challenge of achieving long-term cyclic stability under high current densities.This issue is primarily attributed to the excessive growth of dendrites and the occurrence of significant side reactions.Herein,sucralose(SCL),as an electrolyte additive,has been used to promote the exposure of the Zn(002)texture.The introduction of SCL can adjust the Zn~(2+)nucleation and diffusion along different crystal facets,promoting the exposure of the Zn(002)texture.By substituting water molecules in the[Zn(H_(2)O)_(6)]~(2+),SCL reconfigures the hydrogen bond network in the electrolyte,reconstructing the solvation structure and suppressing the hydrogen evolution reaction.Consequently,the Zn//Zn symmetric battery exhibits long-term cycling stability of over 4900 h at 1 mA cm^(-2)-1 mAh cm^(-2).Even at a harsh condition of 30 mA cm^(-2)-30 mAh cm^(-2)(DOD=73.3%),it can stably cycle for 171 h.The CE of the Zn//Cu half battery reaches 99.61% at 0.2 mA cm^(-2)with 0.2 mAh cm^(-2).Employing the optimized electrolyte,after 500 cycles,a high specific capacity of 420 mAh g^(-1)can be retained for the NH_4V_4O_(10)//Zn full battery at 500 mA g^(-1),corresponding to a capacity retention of 90.7%.
基金Project(51975169)supported by the National Natural Science Foundation of ChinaProject(LH2022E085)supported by the Natural Science Foundation of Heilongjiang Province,China。
文摘Efficient tool condition monitoring techniques help to realize intelligent management of tool life and reduce tool usage costs.In this paper,the influence of different wear degrees of ball-end milling cutters on the texture shape of machining tool marks is investigated,and a method is proposed for predicting the wear state(including the position and degree of tool wear)of ball-end milling cutters based on entropy measurement of tool mark texture images.Firstly,data samples are prepared through wear experiments,and the change law of the tool mark texture shape with the tool wear state is analyzed.Then,a two-dimensional sample entropy algorithm is developed to quantify the texture morphology.Finally,the processing parameters and tool attitude are integrated into the prediction process to predict the wear value and wear position of the ball end milling cutter.After testing,the correlation between the predicted value and the standard value of the proposed tool condition monitoring method reaches 95.32%,and the accuracy reaches 82.73%,indicating that the proposed method meets the requirement of tool condition monitoring.
基金supported by The National Natural Science Foundation of China(under Nos.52234009,U19A2084,52171116,U22A20109,52201113)Partial financial support came from Program for the Central University Youth Innovation Team(419021423505)+2 种基金the Fundamental Research Funds for the Central Universities(No.2412022QD037)the Excellent Youth Program of Jilin Provincial Department of Education(JJKH20241425KJ)the Fundamental Research Funds for the Central Universities,JLU.
文摘Rolled Mg-Al-Sn series alloys generally possess limited formability due to the formation of strong basal texture.Texture weakening is an effective way to enhance formability,but usually accompanied with decreasing strength.In this work,synergistic enhancement of strength and formability is achieved in a Mg-3Al-1Sn-0.5Ca-0.1Sm(ATXS3110)alloy by 0.2 wt.%Mn addition combined with high temperature rolling,exhibiting a high index Erichsen(I.E.)value of~8.1 mm and near-isotropic mechanical properties.On one hand,after Mn addition,the grain refinement from~7.6μm to~4.1μm results in suppression of extension twinning,thereby preventing the development of strong basal texture upon stretch forming.On the other hand,trace Mn addition narrows the grain size distribution and promotes the formation of uniform fine grains,which induces homogeneous deformation during stretch forming.Moreover,grain refinement and high-density nano-sized precipitates caused by trace Mn addition increase the strength.This work may provide insights into designing low-cost Mg-Al-Sn series alloys with superior comprehensive mechanical properties for further structural applications.
基金supported by the National Natural Science Foundation of China(No.51905123)Major Scientific and Technological Innovation Program of Shandong Province,China(Nos.2020CXGC010303,2022ZLGX04)Key R&D Programme of Shandong Province,China(No.2022JMRH0308).
文摘An internal state variable(ISV)model was established according to the experimental results of hot plane strain compression(PSC)to predict the microstructure evolution during hot spinning of ZK61 alloy.The effects of the internal variables were considered in this ISV model,and the parameters were optimized by genetic algorithm.After validation,the ISV model was used to simulate the evolution of grain size(GS)and dynamic recrystallization(DRX)fraction during hot spinning via Abaqus and its subroutine Vumat.By comparing the simulated results with the experimental results,the application of the ISV model was proven to be reliable.Meanwhile,the strength of the thin-walled spun ZK61 tube increased from 303 to 334 MPa due to grain refinement by DRX and texture strengthening.Besides,some ultrafine grains(0.5μm)that played an important role in mechanical properties were formed due to the proliferation,movement,and entanglement of dislocations during the spinning process.
