The phase equilibria and compositions at the Mg-rich corner of the Mg?Zn?Al ternary system at 335 °C were systemically investigated through the equilibrated alloy method by using X-ray diffraction (XRD) and scann...The phase equilibria and compositions at the Mg-rich corner of the Mg?Zn?Al ternary system at 335 °C were systemically investigated through the equilibrated alloy method by using X-ray diffraction (XRD) and scanning electron microscopy (SEM) assisted with energy dispersive spectroscopy of X-ray (EDS). It is experimentally testified that theα-Mg solid solution is not in equilibrium with the Mg32(Al, Zn)49 (τ) ternary intermetallic compound orq quasicrystalline phase, but only in equilibrium with one ternary intermetallic compound Al5Mg11Zn4 (φ). The whole composition range of theφ phase was also obtained at 335 °C, i.e., 52.5%?56.4% Mg, 13.6%?24.0% Al, 19.6%?33.9% Zn (mole fraction). The solubility of Al in the MgZn phase is remarkably more than that in the Mg7Zn3 phase, and the maximum is about 8.6% Al. Aluminum and zinc are simultaneously soluble in theα-Mg solid solution.展开更多
The isothermal sections of the Co-Nb-Ni ternary system at 1373 K and the Ni-Mo-Re ternary system at 1473 K were determined by means of diffusion triple and electron probe microanalysis（EPMA）.The results indicate tha...The isothermal sections of the Co-Nb-Ni ternary system at 1373 K and the Ni-Mo-Re ternary system at 1473 K were determined by means of diffusion triple and electron probe microanalysis（EPMA）.The results indicate that there are three three-phase regions found in the Co-Nb-Ni ternary system at 1373 K：（Ni,Co） ＋ NbCo3 ＋ Ni3Nb,NbCo3 ＋ NbCo2 ＋ Ni3Nb,and NbCo2 ＋ μ ＋ Ni3Nb;and four three-phase regions found in the Ni-Mo-Re ternary system at 1473 K：Re ＋ Ni ＋ χ,Ni ＋ NiMo ＋ σ,σ ＋ χ ＋ Ni,and σ ＋ Mo ＋ NiMo.No ternary compound is observed in the two isothermal sections.The isothermal sections are contrasted with the previous study.展开更多
Through alloy sampling combined with diffusion triple technique, phase equilibria in Al-Ti-Zr ternary system at 1073 Kwere experimentally determined with electron probe microanalysis （EPMA）. Experimental results sho...Through alloy sampling combined with diffusion triple technique, phase equilibria in Al-Ti-Zr ternary system at 1073 Kwere experimentally determined with electron probe microanalysis （EPMA）. Experimental results show that there is a solid solutionβ（Ti,Zr） which dissolves Al up to 16.3% （mole fraction）. Ti and Zr can substitute each other in most Ti-Al and Al-Zr binaryintermediate phases to a certain degree while the maximum solubility of Zr in Ti3Al and TiAl reaches up to 17.9% and 4.0% （molefraction）, respectively. The isothermal section consists of 16 single-phased regions, 27 two-phased regions and 14 three-phasedregions. No ternary phase was detected.展开更多
Three materials(agar,konjac glucomannan(KGM)andκ-carrageenan)were used to prepare ternary systems,i.e.,sol-gels and their dried composites conditioned at varied relative humidity(RH)(33%,54%and 75%).Combined methods,...Three materials(agar,konjac glucomannan(KGM)andκ-carrageenan)were used to prepare ternary systems,i.e.,sol-gels and their dried composites conditioned at varied relative humidity(RH)(33%,54%and 75%).Combined methods,e.g.,scanning electron microscopy,small-angle X-ray scattering,infrared spectroscopy(IR)and X-ray diffraction(XRD),were used to disclose howκ-carrageenan addition tailors the features of agar/KGM/κ-carrageenan ternary system.As affirmed by IR and XRD,the ternary systems withκ-carrageenan below 25%(agar/KGM/carrageenan,50:25:25,m/m)displayed proper component interactions,which increased the sol-gel transition temperature and the hardness of obtained gels.For instance,the ternary composites could show hardness about 3 to 4 times higher than that for binary counterpart.These gels were dehydrated to acquire ternary composites.Compared to agar/KGM composite,the ternary composites showed fewer crystallites and nanoscale orders,and newly-formed nanoscale structures from chain assembly.Such multi-scale structures,for composites withκ-carrageenan below 25%,showed weaker changes with RH,as revealed by especially morphologic and crystalline features.Consequently,the ternary composites with lessκ-carrageenan(below 25%)exhibited stabilized elongation at break and hydrophilicity at different RHs.This hints to us that agar/KGM/κ-carrageenan composite systems can display series applications with improved features,e.g.,increased sol-gel transition point.展开更多
The performance of supercritical fluid (SCF) as a solvent can be greatly affected by addition of anentrainer to the system. In this study, a constant volume visual method is used to measure the critical point ofCO2+n-...The performance of supercritical fluid (SCF) as a solvent can be greatly affected by addition of anentrainer to the system. In this study, a constant volume visual method is used to measure the critical point ofCO2+n-butyraldehyde, CO2+ i-butyraldehyde and CO2+alcohol binary systems and CO2+entrainer+trisodiumsalt of tri-(m-sulfonphenyl)phosphine (TPPTS) ternary systems, which provides us good theoretical basis for super-critical extraction and chemical reaction. The relationship between critical point and concentration of the entrainerare discussed. The phase behavior of binary system and that of ternary system are compared. The relationshipbetween the concentration of TPPTS and critical point of binary systems are also discussed.展开更多
The isothermal section of the Er-Mn-Nd ternary system at 773 K was investigated mainly by X-ray powder diffraction with the aid of differential thermal analysis. The 773 K isothermal section of the ternary system cons...The isothermal section of the Er-Mn-Nd ternary system at 773 K was investigated mainly by X-ray powder diffraction with the aid of differential thermal analysis. The 773 K isothermal section of the ternary system consists of 9 single-phase regions, 14 two-phase regions, and 6 three-phase regions. At 773 K, the maximum solid solubility of Er in Nd and Nd in Er is about 20%（atom fraction） Er and 26%（atom fraction） Nd, respectively. Er6Mn23 and Nd6Mn23 form a continuous solid solution. The homogeneity range of δ phase extends from about 38% （atom fraction） Er to 43% （atom fraction） Er. No ternary compounds were observed at 773 K in this system.展开更多
The phase constitutes and phase compositions in the eight alloys designed with dif-ferent compositions of Al--Zn--Cu system have been determined after the homogenous treatment and then equilibrium cooling to 20℃by us...The phase constitutes and phase compositions in the eight alloys designed with dif-ferent compositions of Al--Zn--Cu system have been determined after the homogenous treatment and then equilibrium cooling to 20℃by use of optical microscope,electron probe microanalysis and X--ray diffraction.It has been found that there existed the T'phase in the seven alloys.Consequently,it was testified that the T'phase was stable at room temperature.At the same time,the phase relationship was not locally right for the isothermal section of 20℃of Al--Zn--Cu system of the ASM published in 1997.展开更多
The phase relationships in the Zn-Al-Ti system at 450 and 600℃ were experimentally determined using equilibrated alloys method.The specimens were investigated by means of scanning electron microscopy coupled with ene...The phase relationships in the Zn-Al-Ti system at 450 and 600℃ were experimentally determined using equilibrated alloys method.The specimens were investigated by means of scanning electron microscopy coupled with energy dispersive spectroscopy and X-ray diffractometry.Eleven and eight three-phase regions are confirmed in the 450 and 600℃ isothermal sections,respectively.The Ti2Al5 which only exists at high temperature(990-1199.4℃)in Ti-Al binary system is confirmed in two isothermal sections due to the dissolution of zinc.The T phase is confirmed as a ternary compound rather than an extension phase of TiZn3 at 450℃.The T2 phase is a new ternary phase stable at 450 and 600℃ in Zn-Al-Ti ternary system.展开更多
1 Introduction The brines with high concentrations of magnesium and boron resources are widely distributed in the Qaidam Basin of the Qinghai-Tibet plateau,China(Zheng&Tang,1988).Although some works on the ternary...1 Introduction The brines with high concentrations of magnesium and boron resources are widely distributed in the Qaidam Basin of the Qinghai-Tibet plateau,China(Zheng&Tang,1988).Although some works on the ternary system展开更多
The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodyn...The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodynamic theory, a group of equations that determine the solid-liquid diagram of ternary system are derived, someisothermal sectional diagrams of the 2D ternary system are obtained. The results are quite similar to the behavior ofthree-dimensional substances.展开更多
Phase equilibria in Ti?Ni?Pt ternary system have been experimentally determined through diffusion triple technique combined with alloy samples approach.Assisted with electron probe microanalysis(EPMA)and X-ray diffrac...Phase equilibria in Ti?Ni?Pt ternary system have been experimentally determined through diffusion triple technique combined with alloy samples approach.Assisted with electron probe microanalysis(EPMA)and X-ray diffraction(XRD)techniques,isothermal sections at 1073 and 1173 K of this system were constructed and existence of ternary phase Ti2(Ni,Pt)3 was confirmed.In addition,binary compounds Ti3Pt5 and TiPt3-were found to be stable at 1073 and 1173 K,and remarkable ternary solubility in some binary compounds was detected,e.g.,solubility of Pt in TiNi can be up to about 36%(molar fraction)at 1073 K and 40%(molar fraction)at 1173 K.Furthermore,a ternary invariant transition reaction TiNi3+Ti3Pt5→Ti2(Ni,Pt)3+TiPt3+at a temperature between 1073 and 1173 K was deduced.展开更多
Swelling capacity of vinyl chloride (VC) in chlorinated polyethylene (CPE) with 25—40 wt% Cl at temperature 30—57℃ was studied and their relationships were correlated with Langmuir and Freundlich adsorption equatio...Swelling capacity of vinyl chloride (VC) in chlorinated polyethylene (CPE) with 25—40 wt% Cl at temperature 30—57℃ was studied and their relationships were correlated with Langmuir and Freundlich adsorption equations. A ternary phase diagram for VC-CPE-PVC was also established. In-situ polymerization conditions of CPE-g-VC were proposed and CPE content control was analyzed for the manufacturing process of CPE-g-VC graft product based on results of phase equilibrium study.展开更多
The isothermal sections of Al-Fe-Sn ternary system at 973 and 593 K were determined experimentally by the equilibriated alloy method using scanning electron microscopy coupled with energy-dispersive spectrometry and X...The isothermal sections of Al-Fe-Sn ternary system at 973 and 593 K were determined experimentally by the equilibriated alloy method using scanning electron microscopy coupled with energy-dispersive spectrometry and X-ray diffractometry. Experimental results show that no ternary compound is found on these two sections. The maximum solubility of Fe in the liquid phase is 1.6%（mole fraction） at 973 K and those of Fe and Al in the liquid phase are 0.6% and 5.1%（mole fraction） at 593 K, respectively. The maximum solubility of Sn in the Fe-Al compounds is 4.2%（mole fraction） at 973 K and 2.3%（mole fraction） at 593 K. All the Fe-Al compounds can be in equilibrium with the liquid phase.展开更多
To experimentally determine the isothermal sections of Co-Mo-Zn ternary system at 600 and 450℃,the equilibrated alloy and diffusion couple methods were adopted by using scanning electron microscopy coupled with energ...To experimentally determine the isothermal sections of Co-Mo-Zn ternary system at 600 and 450℃,the equilibrated alloy and diffusion couple methods were adopted by using scanning electron microscopy coupled with energy-dispersive spectrometry,X-ray diffractometry and electron probe microanalysis.Experimental results show that there are six three-phase regions on the Co-Mo-Zn isothermal section at 600℃and nine three-phase regions on the Co-Mo-Zn isothermal section at 450℃.No ternary compound is found in these two isothermal sections.Both the maximum solubilities of Mo in the Co-Zn compounds(γ-Co5 Zn21,γ1-Co Zn7,γ2-Co Zn13 andβ1-Co Zn)and that of Zn inε-Co3 Mo are no more than 1.5 at.%.The maximum solubilities of Zn inμ-Co7 Mo6 are determined to be 2.1 at.%and 2.7 at.%at 600 and 450℃,respectively.In addition,the maximum solubilities of Co in MoZn7 and MoZn22 are 0.5 at.%and 4.7 at.%at 450℃,respectively.展开更多
The densities and viscosities of ternary systems(Poloxamer 188+ethanol/acetone+water)were meas- ured at 288.15,293.15,298.15,303.15,308.15 K and atmospheric pressure for different mass fractions of Poloxamer 188(0 to ...The densities and viscosities of ternary systems(Poloxamer 188+ethanol/acetone+water)were meas- ured at 288.15,293.15,298.15,303.15,308.15 K and atmospheric pressure for different mass fractions of Poloxamer 188(0 to 0.02)in aqueous solution and different solvent volume fractions of ethanol/acetone(0 to 0.3)in Poloxamer 188 aqueous solution.The densities were measured by a pycnometer,while the viscosities were measured using two Ubbelohde capillary viscometers.The correlations of density and viscosity of these ternary systems are obtained by fitting the experimental data at different temperatures,mass fractions and volume fractions.展开更多
Isothermal section at 25℃ of phase diagram and phase structure of Bi-Pb-Tl ternary system have been studied by means of room and high temperature X-ray diffraction and quenching.
The phase boundary,of α_2 precipitation at 600℃ in Ti-AI-La ternary system has been de- termined by TEM examination,which shows three kinds of phase regions,namely the single α phase region,the transitional phase r...The phase boundary,of α_2 precipitation at 600℃ in Ti-AI-La ternary system has been de- termined by TEM examination,which shows three kinds of phase regions,namely the single α phase region,the transitional phase region where there is superlattice reflection but no α_2 precipitation,and the α+α_2 region.A point of maximum aluminium content was found to exist on the α/(α+α_2)boundary and the track of the boundary was explained in terms of the internal oxidation of lanthanum and the electron concentration rule for α_2 formation.展开更多
The microstructure and phase constitution in stoichiometric NbTiAl3 (γ1 phase) alloy treated at 1000℃ were examined by metallography and X-ray diffraction. The alloy microstructure is mainly γ1 phase containing η ...The microstructure and phase constitution in stoichiometric NbTiAl3 (γ1 phase) alloy treated at 1000℃ were examined by metallography and X-ray diffraction. The alloy microstructure is mainly γ1 phase containing η second phase [(Ti,Nb)Al3] less than 1%. DTA analysis shows no phase transformation from room temperature to 1200℃. In the diffusion couple of NbTiAl3 with 7-TiAl compound, clear phase boundary and composition jump exist between γ1 and γ phase.These results further confirm the existence of γ1 single phase at 1000℃ in Ti-Al-Nb ternary system.展开更多
A partial section of Ti-Ni-Si ternary system at 1100℃was constituted with Ni less than 50 at.pct. Twelve single phase areas were determined. The binary Ti3Si phase proposed to occur at 1100℃ was not found in our inv...A partial section of Ti-Ni-Si ternary system at 1100℃was constituted with Ni less than 50 at.pct. Twelve single phase areas were determined. The binary Ti3Si phase proposed to occur at 1100℃ was not found in our investigations. A phase with the composition of Ni2Ti9Si9 detected is possibly a new phase. No linear ternary compound was found. Some of these compounds show noticeable composition range展开更多
Based on the available experimental phase equilibrium relations and aging precipitation sequences,the Mg–Gd–Y ternary system has been thermodynamically re-assessed by means of CALPHAD technique.To simulate the exper...Based on the available experimental phase equilibrium relations and aging precipitation sequences,the Mg–Gd–Y ternary system has been thermodynamically re-assessed by means of CALPHAD technique.To simulate the experimentally reported aging precipitation sequence,α(Mg)_(SS)(supersaturated)→GP zones(D019-type,metastable)→β’-Mg_(7)Gd(c-bco,metastable)→β_(1)-Mg_(3)Gd(fcc,metastable)→β-Mg_(5)Gd(fcc,stable)near the Mg–Gd side,andα(Mg)SS(supersaturated)→β’-Mg_(7)Y(c-bco,metastable)→β-Mg_(24)Y_(5)(bcc,stable)near the Mg–Y side,the effective nucleation driving forces obtained by deducting the nucleation resistances from the thermodynamic driving forces are calculated and analyzed.Two metastable components,GP zones(D019-type)andβ’(c-bco)ordered fromα(Mg)_(SS),do not exist in the stable equilibrium phase diagram but appear in the annealing process of typical alloys.The Redlich–Kister equations are adopted to describe three solution phases,Liquid,HCP_A3 and BCC_A2.The intermediate compounds Mg_(2)Y,Mg_(24)Y_(5),Mg_(2)Gd,Mg_(3)Gd and Mg_(5)Gd are expressed by the formulas of(Mg,Y)_(2/3)(Gd,Mg,Y)_(1/3),Mg_(24/29)(Gd,Mg,Y)_(4/29)Y1/29,(Gd,Mg)_(2/3)(Gd,Mg,Y)_(1/3),(Gd,Mg)_(3/4)(Gd,Mg,Y)_(1/4)and Mg_(5/6)(Gd,Mg,Y)_(1/6),respectively.In particular,the two-sublattice models(Gd,Mg,Y)_(1/2)(Gd,Mg,Y)_(1/2),(Gd,Mg,Y)_(3/4)(Gd,Mg,Y)_(1/4)and(Gd,Mg,Y)_(7/8)(Gd,Mg,Y)_(1/8)have been respectively used to describe the stable Mg(Gd,Y)(BCC_B2)alloy compound as well as the metastable GP zones(D019-type)andβ’(c-bco)phase,in order to cope with the order-disorder transitions.A set of self-consistent thermodynamic parameters has been obtained to ensure the thermodynamic calculations well consistent with the reported experimental data,containing not only the stable equilibrium phase diagram but also the aging precipitation sequence.展开更多
基金Projects(50901017,51171043,51271053)supported by the National Natural Science Foundation of ChinaProject(20090042120008)supported by the Doctoral Program Foundation of Institutions of Higher Education of ChinaProject(2011BAE22B04-2)supported by National Key Technology R&D Program of China during the Twelfth Five-Year Plan Period
文摘The phase equilibria and compositions at the Mg-rich corner of the Mg?Zn?Al ternary system at 335 °C were systemically investigated through the equilibrated alloy method by using X-ray diffraction (XRD) and scanning electron microscopy (SEM) assisted with energy dispersive spectroscopy of X-ray (EDS). It is experimentally testified that theα-Mg solid solution is not in equilibrium with the Mg32(Al, Zn)49 (τ) ternary intermetallic compound orq quasicrystalline phase, but only in equilibrium with one ternary intermetallic compound Al5Mg11Zn4 (φ). The whole composition range of theφ phase was also obtained at 335 °C, i.e., 52.5%?56.4% Mg, 13.6%?24.0% Al, 19.6%?33.9% Zn (mole fraction). The solubility of Al in the MgZn phase is remarkably more than that in the Mg7Zn3 phase, and the maximum is about 8.6% Al. Aluminum and zinc are simultaneously soluble in theα-Mg solid solution.
文摘The isothermal sections of the Co-Nb-Ni ternary system at 1373 K and the Ni-Mo-Re ternary system at 1473 K were determined by means of diffusion triple and electron probe microanalysis（EPMA）.The results indicate that there are three three-phase regions found in the Co-Nb-Ni ternary system at 1373 K：（Ni,Co） ＋ NbCo3 ＋ Ni3Nb,NbCo3 ＋ NbCo2 ＋ Ni3Nb,and NbCo2 ＋ μ ＋ Ni3Nb;and four three-phase regions found in the Ni-Mo-Re ternary system at 1473 K：Re ＋ Ni ＋ χ,Ni ＋ NiMo ＋ σ,σ ＋ χ ＋ Ni,and σ ＋ Mo ＋ NiMo.No ternary compound is observed in the two isothermal sections.The isothermal sections are contrasted with the previous study.
基金Project(51171210)supported by the National Natural Science Foundation of ChinaProject(2014CB6644002)supported by the Major State Basic Research Development Program of China
文摘Through alloy sampling combined with diffusion triple technique, phase equilibria in Al-Ti-Zr ternary system at 1073 Kwere experimentally determined with electron probe microanalysis （EPMA）. Experimental results show that there is a solid solutionβ（Ti,Zr） which dissolves Al up to 16.3% （mole fraction）. Ti and Zr can substitute each other in most Ti-Al and Al-Zr binaryintermediate phases to a certain degree while the maximum solubility of Zr in Ti3Al and TiAl reaches up to 17.9% and 4.0% （molefraction）, respectively. The isothermal section consists of 16 single-phased regions, 27 two-phased regions and 14 three-phasedregions. No ternary phase was detected.
基金the National Natural Science Foundation of China(32172240)BL19U2 beamline of National Facility for Protein Science in Shanghai(NFPS)at Shanghai Synchrotron Radiation Facility,for their assistance during data collection。
文摘Three materials(agar,konjac glucomannan(KGM)andκ-carrageenan)were used to prepare ternary systems,i.e.,sol-gels and their dried composites conditioned at varied relative humidity(RH)(33%,54%and 75%).Combined methods,e.g.,scanning electron microscopy,small-angle X-ray scattering,infrared spectroscopy(IR)and X-ray diffraction(XRD),were used to disclose howκ-carrageenan addition tailors the features of agar/KGM/κ-carrageenan ternary system.As affirmed by IR and XRD,the ternary systems withκ-carrageenan below 25%(agar/KGM/carrageenan,50:25:25,m/m)displayed proper component interactions,which increased the sol-gel transition temperature and the hardness of obtained gels.For instance,the ternary composites could show hardness about 3 to 4 times higher than that for binary counterpart.These gels were dehydrated to acquire ternary composites.Compared to agar/KGM composite,the ternary composites showed fewer crystallites and nanoscale orders,and newly-formed nanoscale structures from chain assembly.Such multi-scale structures,for composites withκ-carrageenan below 25%,showed weaker changes with RH,as revealed by especially morphologic and crystalline features.Consequently,the ternary composites with lessκ-carrageenan(below 25%)exhibited stabilized elongation at break and hydrophilicity at different RHs.This hints to us that agar/KGM/κ-carrageenan composite systems can display series applications with improved features,e.g.,increased sol-gel transition point.
基金Supported by the National Natural Science Foundation of China (No. 20076004) and the Doctoral Program Foundation of the Institution of Higher Education of China (No. 2000001005).
文摘The performance of supercritical fluid (SCF) as a solvent can be greatly affected by addition of anentrainer to the system. In this study, a constant volume visual method is used to measure the critical point ofCO2+n-butyraldehyde, CO2+ i-butyraldehyde and CO2+alcohol binary systems and CO2+entrainer+trisodiumsalt of tri-(m-sulfonphenyl)phosphine (TPPTS) ternary systems, which provides us good theoretical basis for super-critical extraction and chemical reaction. The relationship between critical point and concentration of the entrainerare discussed. The phase behavior of binary system and that of ternary system are compared. The relationshipbetween the concentration of TPPTS and critical point of binary systems are also discussed.
基金Project supported bythe National Natural Science Foundation of China (50471108)
文摘The isothermal section of the Er-Mn-Nd ternary system at 773 K was investigated mainly by X-ray powder diffraction with the aid of differential thermal analysis. The 773 K isothermal section of the ternary system consists of 9 single-phase regions, 14 two-phase regions, and 6 three-phase regions. At 773 K, the maximum solid solubility of Er in Nd and Nd in Er is about 20%（atom fraction） Er and 26%（atom fraction） Nd, respectively. Er6Mn23 and Nd6Mn23 form a continuous solid solution. The homogeneity range of δ phase extends from about 38% （atom fraction） Er to 43% （atom fraction） Er. No ternary compounds were observed at 773 K in this system.
基金This work was supported by National Natural Science Foundation of China(No.50171019)
文摘The phase constitutes and phase compositions in the eight alloys designed with dif-ferent compositions of Al--Zn--Cu system have been determined after the homogenous treatment and then equilibrium cooling to 20℃by use of optical microscope,electron probe microanalysis and X--ray diffraction.It has been found that there existed the T'phase in the seven alloys.Consequently,it was testified that the T'phase was stable at room temperature.At the same time,the phase relationship was not locally right for the isothermal section of 20℃of Al--Zn--Cu system of the ASM published in 1997.
基金Project(51971189)supported by the National Natural Science Foundation of ChinaProject(2019JJ60011)supported by Zhuzhou Joint Fund of Hunan Natural Science Foundation,ChinaProject(KFBM20180001)supported by Jiangsu Key Laboratory of Materials Surface Science and Technology(Changzhou University),China。
文摘The phase relationships in the Zn-Al-Ti system at 450 and 600℃ were experimentally determined using equilibrated alloys method.The specimens were investigated by means of scanning electron microscopy coupled with energy dispersive spectroscopy and X-ray diffractometry.Eleven and eight three-phase regions are confirmed in the 450 and 600℃ isothermal sections,respectively.The Ti2Al5 which only exists at high temperature(990-1199.4℃)in Ti-Al binary system is confirmed in two isothermal sections due to the dissolution of zinc.The T phase is confirmed as a ternary compound rather than an extension phase of TiZn3 at 450℃.The T2 phase is a new ternary phase stable at 450 and 600℃ in Zn-Al-Ti ternary system.
基金Financial supports from the National Natural Science Foundation of China (21276194 and 21306136)Key Laboratory of Salt Lake Resources and Chemistry at Chinese Academy Sciences (KLSLRC-KF-13-HX-2)Tianjin Key Laboratory of Marine Resources and Chemistry (201206)
文摘1 Introduction The brines with high concentrations of magnesium and boron resources are widely distributed in the Qaidam Basin of the Qinghai-Tibet plateau,China(Zheng&Tang,1988).Although some works on the ternary system
基金The project supported by National Natural Science Foundation of China
文摘The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodynamic theory, a group of equations that determine the solid-liquid diagram of ternary system are derived, someisothermal sectional diagrams of the 2D ternary system are obtained. The results are quite similar to the behavior ofthree-dimensional substances.
基金Project(2016YFB0701404)supported by the National Key Research and Development Program of ChinaProject(51171210)supported by the National Natural Science Foundation of China
文摘Phase equilibria in Ti?Ni?Pt ternary system have been experimentally determined through diffusion triple technique combined with alloy samples approach.Assisted with electron probe microanalysis(EPMA)and X-ray diffraction(XRD)techniques,isothermal sections at 1073 and 1173 K of this system were constructed and existence of ternary phase Ti2(Ni,Pt)3 was confirmed.In addition,binary compounds Ti3Pt5 and TiPt3-were found to be stable at 1073 and 1173 K,and remarkable ternary solubility in some binary compounds was detected,e.g.,solubility of Pt in TiNi can be up to about 36%(molar fraction)at 1073 K and 40%(molar fraction)at 1173 K.Furthermore,a ternary invariant transition reaction TiNi3+Ti3Pt5→Ti2(Ni,Pt)3+TiPt3+at a temperature between 1073 and 1173 K was deduced.
基金This project is supported by National Natural Science Foundation of China
文摘Swelling capacity of vinyl chloride (VC) in chlorinated polyethylene (CPE) with 25—40 wt% Cl at temperature 30—57℃ was studied and their relationships were correlated with Langmuir and Freundlich adsorption equations. A ternary phase diagram for VC-CPE-PVC was also established. In-situ polymerization conditions of CPE-g-VC were proposed and CPE content control was analyzed for the manufacturing process of CPE-g-VC graft product based on results of phase equilibrium study.
基金Projects(51471141,51471140)supported by the National Natural Science Foundation of ChinaProject(2016JC2005)supported by the Scientific Research Fund of Hunan Provincial Science and Technology Department,China
文摘The isothermal sections of Al-Fe-Sn ternary system at 973 and 593 K were determined experimentally by the equilibriated alloy method using scanning electron microscopy coupled with energy-dispersive spectrometry and X-ray diffractometry. Experimental results show that no ternary compound is found on these two sections. The maximum solubility of Fe in the liquid phase is 1.6%（mole fraction） at 973 K and those of Fe and Al in the liquid phase are 0.6% and 5.1%（mole fraction） at 593 K, respectively. The maximum solubility of Sn in the Fe-Al compounds is 4.2%（mole fraction） at 973 K and 2.3%（mole fraction） at 593 K. All the Fe-Al compounds can be in equilibrium with the liquid phase.
基金Project(51771160)supported by the National Natural Science Foundation of ChinaProject(2018JJ4057)supported by the Scientific Research Fund of Hunan Provincial Science and Technology Department,China
文摘To experimentally determine the isothermal sections of Co-Mo-Zn ternary system at 600 and 450℃,the equilibrated alloy and diffusion couple methods were adopted by using scanning electron microscopy coupled with energy-dispersive spectrometry,X-ray diffractometry and electron probe microanalysis.Experimental results show that there are six three-phase regions on the Co-Mo-Zn isothermal section at 600℃and nine three-phase regions on the Co-Mo-Zn isothermal section at 450℃.No ternary compound is found in these two isothermal sections.Both the maximum solubilities of Mo in the Co-Zn compounds(γ-Co5 Zn21,γ1-Co Zn7,γ2-Co Zn13 andβ1-Co Zn)and that of Zn inε-Co3 Mo are no more than 1.5 at.%.The maximum solubilities of Zn inμ-Co7 Mo6 are determined to be 2.1 at.%and 2.7 at.%at 600 and 450℃,respectively.In addition,the maximum solubilities of Co in MoZn7 and MoZn22 are 0.5 at.%and 4.7 at.%at 450℃,respectively.
基金Supported by the National Natural Science Foundation of China(20606031)
文摘The densities and viscosities of ternary systems(Poloxamer 188+ethanol/acetone+water)were meas- ured at 288.15,293.15,298.15,303.15,308.15 K and atmospheric pressure for different mass fractions of Poloxamer 188(0 to 0.02)in aqueous solution and different solvent volume fractions of ethanol/acetone(0 to 0.3)in Poloxamer 188 aqueous solution.The densities were measured by a pycnometer,while the viscosities were measured using two Ubbelohde capillary viscometers.The correlations of density and viscosity of these ternary systems are obtained by fitting the experimental data at different temperatures,mass fractions and volume fractions.
文摘Isothermal section at 25℃ of phase diagram and phase structure of Bi-Pb-Tl ternary system have been studied by means of room and high temperature X-ray diffraction and quenching.
文摘The phase boundary,of α_2 precipitation at 600℃ in Ti-AI-La ternary system has been de- termined by TEM examination,which shows three kinds of phase regions,namely the single α phase region,the transitional phase region where there is superlattice reflection but no α_2 precipitation,and the α+α_2 region.A point of maximum aluminium content was found to exist on the α/(α+α_2)boundary and the track of the boundary was explained in terms of the internal oxidation of lanthanum and the electron concentration rule for α_2 formation.
文摘The microstructure and phase constitution in stoichiometric NbTiAl3 (γ1 phase) alloy treated at 1000℃ were examined by metallography and X-ray diffraction. The alloy microstructure is mainly γ1 phase containing η second phase [(Ti,Nb)Al3] less than 1%. DTA analysis shows no phase transformation from room temperature to 1200℃. In the diffusion couple of NbTiAl3 with 7-TiAl compound, clear phase boundary and composition jump exist between γ1 and γ phase.These results further confirm the existence of γ1 single phase at 1000℃ in Ti-Al-Nb ternary system.
文摘A partial section of Ti-Ni-Si ternary system at 1100℃was constituted with Ni less than 50 at.pct. Twelve single phase areas were determined. The binary Ti3Si phase proposed to occur at 1100℃ was not found in our investigations. A phase with the composition of Ni2Ti9Si9 detected is possibly a new phase. No linear ternary compound was found. Some of these compounds show noticeable composition range
基金the National Key Research and Development Program of China(No.2016YFB0701201)the National Natural Science Foundation of China(No.52071011)for the financial supports.
文摘Based on the available experimental phase equilibrium relations and aging precipitation sequences,the Mg–Gd–Y ternary system has been thermodynamically re-assessed by means of CALPHAD technique.To simulate the experimentally reported aging precipitation sequence,α(Mg)_(SS)(supersaturated)→GP zones(D019-type,metastable)→β’-Mg_(7)Gd(c-bco,metastable)→β_(1)-Mg_(3)Gd(fcc,metastable)→β-Mg_(5)Gd(fcc,stable)near the Mg–Gd side,andα(Mg)SS(supersaturated)→β’-Mg_(7)Y(c-bco,metastable)→β-Mg_(24)Y_(5)(bcc,stable)near the Mg–Y side,the effective nucleation driving forces obtained by deducting the nucleation resistances from the thermodynamic driving forces are calculated and analyzed.Two metastable components,GP zones(D019-type)andβ’(c-bco)ordered fromα(Mg)_(SS),do not exist in the stable equilibrium phase diagram but appear in the annealing process of typical alloys.The Redlich–Kister equations are adopted to describe three solution phases,Liquid,HCP_A3 and BCC_A2.The intermediate compounds Mg_(2)Y,Mg_(24)Y_(5),Mg_(2)Gd,Mg_(3)Gd and Mg_(5)Gd are expressed by the formulas of(Mg,Y)_(2/3)(Gd,Mg,Y)_(1/3),Mg_(24/29)(Gd,Mg,Y)_(4/29)Y1/29,(Gd,Mg)_(2/3)(Gd,Mg,Y)_(1/3),(Gd,Mg)_(3/4)(Gd,Mg,Y)_(1/4)and Mg_(5/6)(Gd,Mg,Y)_(1/6),respectively.In particular,the two-sublattice models(Gd,Mg,Y)_(1/2)(Gd,Mg,Y)_(1/2),(Gd,Mg,Y)_(3/4)(Gd,Mg,Y)_(1/4)and(Gd,Mg,Y)_(7/8)(Gd,Mg,Y)_(1/8)have been respectively used to describe the stable Mg(Gd,Y)(BCC_B2)alloy compound as well as the metastable GP zones(D019-type)andβ’(c-bco)phase,in order to cope with the order-disorder transitions.A set of self-consistent thermodynamic parameters has been obtained to ensure the thermodynamic calculations well consistent with the reported experimental data,containing not only the stable equilibrium phase diagram but also the aging precipitation sequence.
