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Temporary plugging agent transport behavior within visualized multi-fracture created during TPDF in a horizontal well: An experimental study
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作者 Yu-Shi Zou Dian-Yu Li +4 位作者 Can Yang Yan-Chao Li Shi-Cheng Zhang Long-Qing Zou Xin-Fang Ma 《Petroleum Science》 2025年第9期3671-3687,共17页
Temporary plugging and diversion fracturing(TPDF)is widely used to promote the uniform and complex distribution of multi-clustered hydraulic fractures(HFs)in a horizontal well of the unconventional formations.However,... Temporary plugging and diversion fracturing(TPDF)is widely used to promote the uniform and complex distribution of multi-clustered hydraulic fractures(HFs)in a horizontal well of the unconventional formations.However,the migration behavior of temporary plugging agent(TPA),as a function of the concentration and particle size of TPA and cluster-perforation numbers,etc.,determining the effectiveness of this technique,remains unclear.Therefore,this study conducted innovatively a series of TPDF simulation experiments on transparent polymethyl methacrylate(PMMA)specimens(cubic block of 30 cm×30 cm×30 cm)to explore visually the migration behavior of TPA in multi-clustered HFs in a horizontal well.A laboratory hydraulic sandblasting perforation completion technique was implemented to simulate the multi-cluster perforations.All the distributions of wellbore,perforations,HFs,and TPA can be seen clearly inside the PMMA specimen post the experiment.The results show that there are four characteristic plugging positions for the TPA:mouth of HF,middle of HF,tip of HF,and the intersection of HFs.Small particle size TPA tends to migrate to the fracture tip for plugging,while large particle size TPA tends to plug at the fracture mouth.The migration of the TPA is influenced obviously by the morphology of the fracture wall.A smooth fracture wall is conducive to the migration of the TPA to the far end of HFs,but not conducive to generating the plugging zone and HF diversion.In contrast,a"leaf vein"fracture of rough wall is conducive to generating the plugging layer and the diversion of HFs,but not conducive to the migration of the TPA to the far end of HFs.The migration ability of TPA in a"shell"pattern is intermediate between the two above cases.Increasing TPA concentration can encourage TPA to migrate more quickly to the characteristic plugging position,and thereby to promote the creation of effective plugging and subsequently the multi-stage diversion of the HFs.Nevertheless,excessive concentration may cause the TPA to settle prematurely,affecting the propagation of the HFs to the far end.Increasing the number of clusters to a certain extent can encourage TPA to migrate into the HFs and form plugging,and promote the diversion.An evaluation system for the migration ability of granular TPA has been established,and it was calculated that when there is no plugging expectation target,the comprehensive migration ability of small particle size TPA is stronger than that of large particle size TPA.This research provides theoretical foundation for the optimization of temporary plugging parameters. 展开更多
关键词 temporary plugging and diversion fracturing(TPDF) Polymethyl methacrylate(PMMA) Multi-cluster perforation temporary plugging agent migration Visualization plugging position
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Fracture propagation law of temporary plugging and diversion fracturing in shale reservoirs under completion experiments of horizontal well with multi-cluster sand jetting perforation 被引量:2
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作者 ZOU Yushi LI Yanchao +3 位作者 YANG Can ZHANG Shicheng MA Xinfang ZOU Longqing 《Petroleum Exploration and Development》 SCIE 2024年第3期715-726,共12页
This study conducted temporary plugging and diversion fracturing(TPDF)experiments using a true triaxial fracturing simulation system within a laboratory setting that replicated a lab-based horizontal well completion w... This study conducted temporary plugging and diversion fracturing(TPDF)experiments using a true triaxial fracturing simulation system within a laboratory setting that replicated a lab-based horizontal well completion with multi-cluster sand jetting perforation.The effects of temporary plugging agent(TPA)particle size,TPA concentration,single-cluster perforation number and cluster number on plugging pressure,multi-fracture diversion pattern and distribution of TPAs were investigated.A combination of TPAs with small particle sizes within the fracture and large particle sizes within the segment is conducive to increasing the plugging pressure and promoting the diversion of multi-fractures.The addition of fibers can quickly achieve ultra-high pressure,but it may lead to longitudinal fractures extending along the wellbore.The temporary plugging peak pressure increases with an increase in the concentration of the TPA,reaching a peak at a certain concentration,and further increases do not significantly improve the temporary plugging peak pressure.The breaking pressure and temporary plugging peak pressure show a decreasing trend with an increase in single-cluster perforation number.A lower number of single-cluster perforations is beneficial for increasing the breaking pressure and temporary plugging peak pressure,and it has a more significant control on the propagation of multi-cluster fractures.A lower number of clusters is not conducive to increasing the total number and complexity of artificial fractures,while a higher number of clusters makes it difficult to achieve effective plugging.The TPAs within the fracture is mainly concentrated in the complex fracture areas,especially at the intersections of fractures.Meanwhile,the TPAs within the segment are primarily distributed near the perforation cluster apertures which initiated complex fractures. 展开更多
关键词 shale temporary plugging and diversion fracturing multi-cluster sand jetting perforation distribution of temporary plugging agent fracture propagation law
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Development of degradable pre-formed particle gel(DPPG)as temporary plugging agent for petroleum drilling and production 被引量:8
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作者 Dao-Yi Zhu Xing-Yu Fang +3 位作者 Ren-Xian Sun Zeng-Hao Xu Yang Liu Ji-Yang Liu 《Petroleum Science》 SCIE CAS CSCD 2021年第2期479-494,共16页
Temporary plugging agent(TPA)is widely used in many fields of petroleum reservoir drilling and production,such as temporary plugging while drilling and petroleum well stimulation by diverting in acidizing or fracturin... Temporary plugging agent(TPA)is widely used in many fields of petroleum reservoir drilling and production,such as temporary plugging while drilling and petroleum well stimulation by diverting in acidizing or fracturing operations.The commonly used TPA mainly includes hard particles,fibers,gels,and composite systems.However,current particles have many limitations in applications,such as insufficient plugging strength and slow degradation rate.In this paper,a degradable pre-formed particle gel(DPPG)was developed.Experimental results show that the DPPG has an excellent static swelling effect and self-degradation performance.With a decrease in the concentration of total monomers or cross-linker,the swelling volume of the synthesized DPPG gradually increases.However,the entire self-degradation time gradually decreases.The increase in 2-acrylamide-2-methylpropanesulfonic acid(AMPS)in the DPPG composition can significantly increase its swelling ratio and shorten the self-degradation time.Moreover,DPPG has excellent high-temperature resistance(150°C)and high-salinity resistance(200,000 mg/L NaCl).Core displacement results show that the DPPG has a perfect plugging effect in the porous media(the plugging pressure gradient was as high as 21.12 MPa),and the damage to the formation after degradation is incredibly minor.Therefore,the DPPG can be used as an up-and-coming TPA in oil fields. 展开更多
关键词 temporary plugging agents Pre-formed particle gel(PPG) Degradable PPG Petroleum drilling Petroleum production
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Degradable preformed particle gel as temporary plugging agent for low-temperature unconventional petroleum reservoirs:Effect of molecular weight of the cross-linking agent 被引量:2
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作者 Hong-Jun Zhang Dao-Yi Zhu +8 位作者 Yong-Long Gong Jun-Hui Qin Xiao-Ning Liu Yuan-Hang Pi Qi Zhao Run-Tian Luo Wan-Sheng Wang Ke-Ke Zhi Zong-Jie Mu 《Petroleum Science》 SCIE CAS CSCD 2022年第6期3182-3193,共12页
The development of unconventional petroleum resources has gradually become an important succession for increasing oil production.However,the related engineers and researchers are paying more and more attention to the ... The development of unconventional petroleum resources has gradually become an important succession for increasing oil production.However,the related engineers and researchers are paying more and more attention to the application of temporary plugging agents(TPAs)for their efficient development.TPAs can expand the stimulated reservoir volume(SRV)and facilitate the flow of oil and gas to the bottom of the well.Particle-gels used as temporary plugging agents have the characteristics of the simple injection process,good deformation,high plugging strength,and complete self-degradation performance,which have been widely applied in recent years.In this paper,five samples of DPPG polymerized by different molecular weights of cross-linking agents were prepared.In addition,infrared spectroscopy analysis,differential calorimetry scanning(DSC)analysis,static particle gel swelling and degradation performance evaluation experiments,and dynamic temporary plugging performance experiments in cores were conducted at 34°C.Results show that as the molecular weight of the cross-linking agent(at 0.01 g)in the DPPG molecule decreased from 1,000 to 200 Da,the fewer cross-linking sites of DPPG,the looser the microscopic three-dimensional mesh structure formed.The swelling ratio increased from 7 to 33 times.However,the complete degradation time increased from 40 to 210 min.Moreover,the DSC results confirmed that the higher the molecular weight of the cross-linking agent,the worse is chemical stability and the more prone it to self-degradation.DPPG samples had good temporary plugging performance in reservoir cores.DPPGs prepared by the cross-linking agent with smaller molecular weight has a stronger swelling ratio,higher gel strength,and greater plugging strength in the core permeabilities.Moreover,the degraded DPPG is less damaging to the cores.However,their slower degradation rates take a slightly longer times to reach complete degradation.The results of this paper can provide new ideas and a theoretical basis for the development of particle gel-type temporary plugging agents(TPA)with controllable degradation time in low-temperature reservoirs.It can help to expand the application range of existing DPPG reservoir conditions. 展开更多
关键词 temporary plugging agent Preformed particle gel Degradable cross-linking agent Molecular weight Low-temperature reservoir
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A bull-heading water control technique of thermo-sensitive temporary plugging agent 被引量:4
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作者 LIU Pingde WEI Falin +3 位作者 ZHANG Song ZHU Xiuyu WANG Longfei XIONG Chunming 《Petroleum Exploration and Development》 2018年第3期536-543,共8页
Aimed at the disadvantages of secondary damage to oil layers caused by the conventional bull-heading water control technique, a thermo-sensitive temporary plugging agent for water control was synthesized by water solu... Aimed at the disadvantages of secondary damage to oil layers caused by the conventional bull-heading water control technique, a thermo-sensitive temporary plugging agent for water control was synthesized by water solution polymerization and applied in the field with a new secondary temporary plugging technique. The optimization and performance evaluation of thermo-sensitive temporary plugging agent were carried out through laboratory experiments. The optimized formula is as follows:(6%-8%) acrylamide +(0.08%-0.12%) ammonium persulfate +(1.5%-2.0%) sepiolite +(0.5%-0.8%) polyethylene glycol diacrylate. The thermo-sensitive temporary plugging agent is suitable for formation temperatures of 70-90 ?C, it has high temporary plugging strength(5-40 k Pa), controllable degradation time(1-15 d), the apparent viscosity after degradation of less than 100 m Pa?S and the permeability recovery value of simulated cores of more than 95%. Based on the research results, secondary temporary plugging technique was used in a horizontal well in the Jidong Oilfield. After treatment, the well saw a drop of water cut to 27%, and now it has a water cut of 67%, its daily increased oil production was 4.8 t, and the cumulative oil increment was 750 t, demonstrating that the technique worked well in controlling water production and increasing oil production. 展开更多
关键词 bull-heading water control TECHNIQUE THERMO-SENSITIVE temporary plugging agent secondary temporary plugging TECHNIQUE thermal degradation property RESERVOIR protection
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Application of Temporary Plugging Technology in Liaohe Oilfield
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作者 ZHAOChunliang 《外文科技期刊数据库(文摘版)工程技术》 2022年第2期039-044,共6页
At present, the oil and water wells in Liaohe Oilfield have entered the middle and later stages of development. The pressure of the oil and water wells has decreased year by year and the contradiction between injectio... At present, the oil and water wells in Liaohe Oilfield have entered the middle and later stages of development. The pressure of the oil and water wells has decreased year by year and the contradiction between injection and production has become increasingly prominent. In order to maximize its recovery, various new processes and technologies have been widely applied in different oilfields. The loss of workover fluid during workover operation not only increases the dosage of workover fluid, but also causes more serious pollution to the oil layer (formation). Affect oil production after workover operation. 展开更多
关键词 temporary plugging process APPLICATION plugging agent
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深层油气层水力压裂化学暂堵剂研究进展及展望 被引量:1
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作者 戴彩丽 王子昭 +5 位作者 李琳 蒋田宇 刘津铭 董云博 赵明伟 吴一宁 《天然气工业》 北大核心 2025年第4期19-32,共14页
深层油气储层普遍具有埋藏深、温度高、压力大、非均质性强、地层流体特征复杂、自然产能低,岩石塑性强等特征,油气层暂堵压裂技术一般通过化学暂堵剂来实现压力转向开启新裂缝,从而有效提高储层的增产改造体积。暂堵剂性能对于深层油... 深层油气储层普遍具有埋藏深、温度高、压力大、非均质性强、地层流体特征复杂、自然产能低,岩石塑性强等特征,油气层暂堵压裂技术一般通过化学暂堵剂来实现压力转向开启新裂缝,从而有效提高储层的增产改造体积。暂堵剂性能对于深层油气水力压裂形成复杂缝网至关重要。为此,通过对现有深层油气化学暂堵压裂技术进行梳理和总结,结合各储层应用条件、施工工况提出了深层油气暂堵剂关键应用材料的使用要求,然后通过对各类深层油气储层暂堵材料的作用机理及现场应用调研,明晰了深层油气层水力压裂暂堵材料研发面临的挑战并对其技术发展方向进行了展望。研究结果表明:①现有深层油气层暂堵压裂技术针对不同储层特征已经形成了较为完善的施工工艺,缝口/缝内暂堵材料的性能要求主要集中在高温(>160℃)适应性、封堵后高承压能力(有效暂堵压力10~20 MPa)以及降解后低残渣率(降解率>99%);②现有缝口/缝内暂堵材料分别以金属合金及有机高分子类、树脂及凝胶类或复合类为主,室内岩心暂堵实验评价能够实现最高耐温160℃、缝口/缝内承压最高30 MPa/24.6 MPa;③针对耐温超160℃储层,暂堵材料研发主要面临高温封堵结构提前失效、混合致密承压材料降解后残渣率较高和暂堵压裂支撑裂缝导流能力差等问题,后续暂堵材料应从提升封堵结构致密性、优化暂堵剂结构、合理调整可降解材料中混合耐温材料占比等方面进行研发。结论认为,现有深层油气层暂堵转向压裂储层改造能力主要受关键暂堵材料影响,将来暂堵材料研发应向多功能、复合化方向发展,该成果可以为研发适用于超160℃油气层暂堵压裂关键材料提供理论指导。 展开更多
关键词 深层油气藏 水力压裂 暂堵转向 化学暂堵剂 非均质性 展望
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绳结式暂堵剂高压暂堵矿场尺度试验
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作者 许江文 王明星 +3 位作者 吴宝成 谢勃勃 谭林 王博 《石油钻探技术》 北大核心 2025年第4期117-122,共6页
针对现有暂堵试验难以满足高温高压大尺度条件、试验结果对孔眼暂堵施工指导有限的问题,设计了大尺度高承压孔眼暂堵试验装置,综合考虑绳结式暂堵剂球结直径、储层温度及流体压力等因素,通过孔眼封堵试验揭示了暂堵规律,明确了球结直径... 针对现有暂堵试验难以满足高温高压大尺度条件、试验结果对孔眼暂堵施工指导有限的问题,设计了大尺度高承压孔眼暂堵试验装置,综合考虑绳结式暂堵剂球结直径、储层温度及流体压力等因素,通过孔眼封堵试验揭示了暂堵规律,明确了球结直径与孔眼直径的匹配关系及温度和压力对封堵效果的影响。研究结果表明:封堵直径12 mm的孔眼需球结直径15~22 mm的绳结式暂堵剂,封堵直径10 mm的孔眼需球结直径13~14 mm的绳结式暂堵剂,且绳结球结直径应比孔眼大3~5 mm;绳结式暂堵剂可有效封堵破裂盘及滑套孔眼,并在25 MPa压力下保持稳定封堵;当设定封堵压力20 MPa、温度40~95℃时,绳结式暂堵剂可维持5~7 d有效封堵。基于试验结果,建议采用适配尺寸的绳结式暂堵剂封堵优势进液射孔孔眼,促进段内多簇裂缝均衡起裂与扩展。研究结果为矿场暂堵施工优化设计提供了依据。 展开更多
关键词 绳结式暂堵剂 高承压 暂堵规律 矿场试验
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钻井液用油溶性暂堵剂的设计合成及其储层保护应用研究
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作者 王京光 尹利杰 +3 位作者 贺会锋 雷江 曲波 孙亚平 《应用化工》 北大核心 2025年第10期2648-2656,共9页
针对钻井液用油溶性暂堵剂存在的软化点集中、油溶率低、颗粒粒径与储层不匹配、岩芯渗透率恢复率较低等问题,选择与油具有相似分子结构的油溶性材料(柔性树脂+刚性树脂),并辅以表面活性剂、成核剂研发了油溶性暂堵剂Poly-ZD-Ⅰ和Poly-... 针对钻井液用油溶性暂堵剂存在的软化点集中、油溶率低、颗粒粒径与储层不匹配、岩芯渗透率恢复率较低等问题,选择与油具有相似分子结构的油溶性材料(柔性树脂+刚性树脂),并辅以表面活性剂、成核剂研发了油溶性暂堵剂Poly-ZD-Ⅰ和Poly-ZD-Ⅱ,其软化点、粒度均可根据不同油藏条件调整,封堵强度高,解堵性能好,能够显著降低钻井液对油井储层损害。研究结果显示油溶性暂堵剂软化点为100~130℃,可调,粒径为31.11~2 000μm,可控。油溶性暂堵剂Poly-ZD-Ⅰ和Poly-ZD-Ⅱ在不同试验温度下的油溶率均大于90%,岩心模拟实验显示其暂堵率大于90%,且渗透率恢复率大于90%。油溶性暂堵剂Poly-ZD-Ⅰ和Poly-ZD-Ⅱ粒度大小及软化点均可根据不同的油藏条件调节,且封堵强度及解堵性能优良,应用潜力较大。 展开更多
关键词 油气储层保护 钻井液体系 油溶性暂堵剂 渗透率恢复率 岩心模拟实验
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基于CFD-DEM的压裂水平井暂堵剂运移与封堵有效性研究
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作者 朱炬辉 郑衣珍 +4 位作者 何乐 宋佳忆 龚蔚 黄义涛 隋微波 《石油科学通报》 2025年第3期511-526,共16页
暂堵剂被广泛用于水平井压裂过程中的裂缝暂堵与转向,对提高压裂改造效果具有重要作用。目前国内外关于暂堵剂运移规律的研究多局限于室内实验,对暂堵剂在井筒中的运移、在缝中封堵过程的宏观模拟研究还不充分。本文基于计算流体力学(C... 暂堵剂被广泛用于水平井压裂过程中的裂缝暂堵与转向,对提高压裂改造效果具有重要作用。目前国内外关于暂堵剂运移规律的研究多局限于室内实验,对暂堵剂在井筒中的运移、在缝中封堵过程的宏观模拟研究还不充分。本文基于计算流体力学(CFD)与离散元(DEM)耦合的数值模拟方法,模拟了水平井压裂暂堵过程中暂堵剂颗粒井下运移与封堵过程。模拟时,将暂堵剂颗粒视作离散相,将压裂液视作连续相,对离散相与连续相单独建立数学模型,同时耦合离散相与连续相之间的相互作用,从而实现暂堵剂—压裂液多相体系的流固耦合。针对暂堵剂从井口到封堵井段的运移过程,建立了井筒模型、井筒—炮眼—单一裂缝和井筒—炮眼—多条裂缝模型。揭示了暂堵剂浓度、暂堵剂粒径、压裂液黏度和泵注排量对暂堵剂运移完整性的影响规律,探究了不同裂缝形态下工艺参数与施工参数对暂堵剂封堵效果的影响。研究表明,暂堵剂体系颗粒浓度、压裂液黏度与泵注排量是影响暂堵剂体系运移完整性的重要因素,暂堵剂粒径与浓度是决定暂堵剂体系能否有效封堵裂缝的关键因素。暂堵剂粒径大于20目时,暂堵剂质量浓度的改变只会影响缝内封堵段长度,而不会影响缝内暂堵有效性;当裂缝末端缝宽达到4 mm时,选用20~70目粒径的暂堵剂难以在缝高方向完全封堵裂缝。本研究为水平井暂堵压裂施工过程中工艺参数与施工参数的选取提供了理论依据。 展开更多
关键词 缝内暂堵 暂堵剂运移 暂堵机理 水平井 CFD-DEM
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聚乙醇酸的制备及其在油田领域应用研究进展 被引量:1
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作者 王雨康 赵方园 +2 位作者 伊卓 李晶 杨捷 《塑料科技》 北大核心 2025年第3期187-192,共6页
作为一种生物可降解材料,聚乙醇酸(PGA)凭借高强度、耐高温和可控降解性成为解决传统油田材料污染与地层堵塞问题的绿色替代品。然而,PGA仍面临高温高盐环境稳定性不足、降解速率调控不精准及成本较高等挑战。文章系统综述聚乙醇酸PGA... 作为一种生物可降解材料,聚乙醇酸(PGA)凭借高强度、耐高温和可控降解性成为解决传统油田材料污染与地层堵塞问题的绿色替代品。然而,PGA仍面临高温高盐环境稳定性不足、降解速率调控不精准及成本较高等挑战。文章系统综述聚乙醇酸PGA的制备技术,涵盖直接缩聚法、开环聚合法及煤化工合成路径;系统分析PGA的物理特性、力学性能、热稳定性及降解行为,着重探讨其在油田高温高压环境中表现出的高强度、耐压特性及可控降解优势。在此基础上,重点梳理近年来PGA材料改性研究进展,包括共聚改性中的分子结构优化策略以及共混改性中的界面相容性强化技术。最后,深入探讨当前面临的热稳定性控制、降解速率精准调控等关键技术瓶颈,并展望PGA在智能暂堵、储层保护等油田工程领域的应用潜力。 展开更多
关键词 聚乙醇酸 性能 改性 暂堵剂
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致密页岩气藏热致相变压裂暂堵剂研制
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作者 汪小宇 陈倩 +7 位作者 张汉信 王军闯 李勇 陈平 徐洋 王忍峰 张承武 唐雷 《钻采工艺》 北大核心 2025年第4期141-147,共7页
针对目前致密页岩气的压裂暂堵剂研究较少,富集在致密页岩气储层的页岩气难以被高效开采的问题,根据超分子研究理论基础,以β-环糊精为主体分子,通过筛选出与之适配的客体、助剂以及温度调节剂分子研制出一种新型的热致相变压裂暂堵剂体... 针对目前致密页岩气的压裂暂堵剂研究较少,富集在致密页岩气储层的页岩气难以被高效开采的问题,根据超分子研究理论基础,以β-环糊精为主体分子,通过筛选出与之适配的客体、助剂以及温度调节剂分子研制出一种新型的热致相变压裂暂堵剂体系CDP400。对该暂堵剂体系进行系列表征及室内适配性考察,研究其成胶及破胶过程,并进行了现场应用效果分析。室内及现场应用结果表明,CDP400在室内呈流动液体状态,升温后可形成高强度的凝胶体系,室内最大封堵压力可达15.97 MPa,现场应用最大暂堵压力为73.9 MPa,封堵强度大,可满足现场暂堵剂的应用要求,是一种应用前景广阔的热致相变压裂暂堵剂体系。 展开更多
关键词 热致相变 压裂暂堵剂 页岩储层 封堵压力
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油气田用自适应绳结式暂堵剂的研究进展
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作者 汪小宇 许朝阳 +5 位作者 杨江宇 卢履盛 佀小翠 徐洋 孙雨维 武月荣 《应用化工》 北大核心 2025年第3期770-775,共6页
综述了国内外油气田增产用绳结式暂堵剂的研究进展,阐述了绳结暂堵剂的作用机理,并对绳结暂堵剂外壳、绳结主体和改性工艺等进行了归纳,列举了其在工程实际中的应用。对绳结式暂堵材料的发展趋势及前景进行了展望,为提升非常规油气田压... 综述了国内外油气田增产用绳结式暂堵剂的研究进展,阐述了绳结暂堵剂的作用机理,并对绳结暂堵剂外壳、绳结主体和改性工艺等进行了归纳,列举了其在工程实际中的应用。对绳结式暂堵材料的发展趋势及前景进行了展望,为提升非常规油气田压裂效果提供参考。 展开更多
关键词 绳结暂堵剂 储层改造 射孔封堵
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钻井液用可降解聚合物暂堵剂的研制
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作者 田智元 齐舵 +3 位作者 王海波 张馨鹏 郭宝华 徐军 《钻井液与完井液》 北大核心 2025年第1期74-81,共8页
生物可降解聚酯类暂堵剂的降解性较好,对储层伤害较小,但是具有耐温性不足、封堵强度较小、生产成本较高等问题,导致其目前难以广泛应用。为了满足更高温度条件下暂堵剂的需求,采用水解速率更慢的聚对苯二甲酸丁二酯(PBT)和聚酰胺6(PA6... 生物可降解聚酯类暂堵剂的降解性较好,对储层伤害较小,但是具有耐温性不足、封堵强度较小、生产成本较高等问题,导致其目前难以广泛应用。为了满足更高温度条件下暂堵剂的需求,采用水解速率更慢的聚对苯二甲酸丁二酯(PBT)和聚酰胺6(PA6)熔融共混,并加入环氧扩链剂ADR提高共混物的相容性,制备出耐温性能较好、封堵强度较高,并且降解速率可调控的可降解暂堵剂。实验结果表明,制备出的暂堵剂具有较好的降解性能,暂堵剂在120~150℃钻井液条件下(pH=10的NaOH水溶液)降解20~60 d后的失重率均大于80%;当共混比例为70%PBT/30%PA6,并加入1.5%ADR时,暂堵剂的抗压强度可达91 MPa、150℃降解16 h后仍大于70 MPa;与钻井液的配伍性较好,并且封堵性能优良,120℃降解14 d后仍然具有2 MPa的封堵强度。 展开更多
关键词 聚对苯二甲酸丁二酯(PBT) 聚酰胺6(PA6) 暂堵剂 可控降解
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压裂用有机硅暂堵转向剂的制备及性能评价
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作者 刘彝 余成林 +4 位作者 李云子 姜喜梅 于洋洋 吴均 刘京 《钻井液与完井液》 北大核心 2025年第2期275-282,共8页
压裂现用颗粒暂堵剂多以刚性颗粒为主,现场实施过程中存在压力升高不明显,稳压时间短,应力不能有效转移的难题。通过引入一种有机硅疏水单体,以丙烯酰胺、N,N-亚甲基双丙烯酰胺为主要原料,胶束聚合了一种有机硅水凝胶。考察了不同聚合... 压裂现用颗粒暂堵剂多以刚性颗粒为主,现场实施过程中存在压力升高不明显,稳压时间短,应力不能有效转移的难题。通过引入一种有机硅疏水单体,以丙烯酰胺、N,N-亚甲基双丙烯酰胺为主要原料,胶束聚合了一种有机硅水凝胶。考察了不同聚合单体浓度、疏水单体、聚合方法、聚合条件等对LYB聚合物水凝胶的影响,并采用FTIR和元素分析仪对LYB聚合物进行表征。结果显示,LYB聚合物水凝胶的最佳合成工艺:水溶性单体浓度8~10%,有机硅浓度2%,交联剂浓度0.02%,引发剂加量0.2%,反应温度为50~60℃,反应时间为6~8 h。评价了暂堵剂的吸水膨胀、耐盐性、抗剪切、变形性和热降解性。与常规刚性颗粒相比,具有更强抗剪切性、耐盐性和弹性的优势。基于压裂施工曲线和微震监测结果:LYB暂堵剂到位后,现场起压7~8 MPa,暂堵后,相同施工压力下,施工排量下降1.5 m^(3)/min,并通过井下微地震,进一步验证了LYB裂缝转向的有效性。 展开更多
关键词 暂堵剂 水平井多段多簇压裂 有机硅凝胶 有机硅疏水单体
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多级暂堵重复压裂技术在致密油水平井的应用
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作者 樊庆军 常润钊 曾志林 《中外能源》 CAS 2025年第1期71-77,共7页
致密油水平井均采用大规模压裂+弹性开采方式进行开发,开发初期由于经验不足,裂缝布署间距大、改造规模小、渗流距离远、产量递减快、有效动用程度低,部分早期投产的致密油水平井已无法正常起抽生产。为了进一步挖掘老水平井潜能,总结B... 致密油水平井均采用大规模压裂+弹性开采方式进行开发,开发初期由于经验不足,裂缝布署间距大、改造规模小、渗流距离远、产量递减快、有效动用程度低,部分早期投产的致密油水平井已无法正常起抽生产。为了进一步挖掘老水平井潜能,总结B井缩小缝间距双封单卡重复压裂试验的经验,在致密油老水平井中选取A井开展多级暂堵重复压裂试验。通过优化缝间距及实施加密布缝,将水平段分为55簇(老缝22簇、新缝33簇)进行改造,平均缝间距10m。结合A井区油层岩心属性、测井综合解释成果及软件模拟结果等,对补孔方式、缝长、施工排量、施工规模、暂堵剂用量及暂堵次数等参数进行优化,实现产能重新动用,保证老井储层新、旧缝彻底改造。从投产效果来看,试验井重复压裂初期产量是初次压裂的1.7倍,投产1年的累产油与初次压后投产4年的累产油相当。 展开更多
关键词 致密油水平井 多级暂堵 重复压裂 缝间距 施工排量 暂堵剂
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一种抗高温强封堵水基暂堵剂体系室内实验研究 被引量:1
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作者 刘垒 陈智 +4 位作者 刘丙晓 古志斌 文冉 陈超 梁谷 《当代化工》 2025年第2期275-278,283,共5页
基于淀粉的可降解性及碳酸钙的热稳定性,将其接枝复配为吸水树脂,合成了一种抗高温强封堵性水基暂堵剂HWT-1体系,结合微观手段测试了其基本结构及性能,岩心实验评价了其吸水性、流变/滤失性、封堵性及抗温抗盐性等,并对其在不同渗透率... 基于淀粉的可降解性及碳酸钙的热稳定性,将其接枝复配为吸水树脂,合成了一种抗高温强封堵性水基暂堵剂HWT-1体系,结合微观手段测试了其基本结构及性能,岩心实验评价了其吸水性、流变/滤失性、封堵性及抗温抗盐性等,并对其在不同渗透率储藏中的适应性进行了分析。结果表明:优化的HWT-1体系合成条件为单体与淀粉质量比为3∶1,AA、AM与抗盐单体质量比为1∶1∶1。HWT-1体系降解率良好,且与时间和温度关联较为密切。HWT-1体系对于200μm的裂缝会形成暂堵带且封堵效果良好。HWT-1体系抗温能力为140℃,抗NaCl及CaCl_(2)质量分数分别为8.0%及0.9%。HWT-1体系在不同渗透率岩心中均具备良好的封堵性,且渗透率恢复率较高。 展开更多
关键词 暂堵剂 封堵性能 耐温 可降解性
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页岩气压裂暂堵剂技术发展与应用挑战 被引量:1
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作者 蒋大富 《当代化工研究》 2025年第8期118-120,共3页
暂堵剂技术作为页岩气压裂作业中的关键材料,通过动态封堵机制实现裂缝的转向和储层改造体积的提升,有效克服了传统压裂技术在高渗透层优先改造的局限性。暂堵剂的发展历程可划分为四个阶段:初期以刚性颗粒为主;随后进入可降解材料阶段... 暂堵剂技术作为页岩气压裂作业中的关键材料,通过动态封堵机制实现裂缝的转向和储层改造体积的提升,有效克服了传统压裂技术在高渗透层优先改造的局限性。暂堵剂的发展历程可划分为四个阶段:初期以刚性颗粒为主;随后进入可降解材料阶段;进而迈入复合功能化阶段;当前智能响应阶段则实现了环境响应型精准控制。其作用机理涉及封堵动力学、压力响应和降解动力学等多个方面。目前,暂堵剂技术仍面临高温高压耦合及地层非均质性适配的挑战。未来研究应聚焦于“高强度-智能化-低成本”的发展方向,重点开发智能响应材料、绿色制备工艺及人工智能决策系统,通过跨学科的融合推动技术的普适化,为深层页岩气的开发提供环保且高效的解决方案。 展开更多
关键词 暂堵剂 发展机理 发展方向
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准东油田北83井区蓄能压裂技术研究与应用
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作者 王小江 《石油工业技术监督》 2025年第11期62-66,共5页
北83井区梧桐沟组油藏具备一定开发潜力,但其储层低渗、水敏等特点给开发带来了挑战。针对油藏存在的问题开展了蓄能压裂工艺优化,以井组为单位,采用蓄能压裂工艺补充地层能量,提高压裂初期产量和有效期。采用地层压力恢复法,根据油井... 北83井区梧桐沟组油藏具备一定开发潜力,但其储层低渗、水敏等特点给开发带来了挑战。针对油藏存在的问题开展了蓄能压裂工艺优化,以井组为单位,采用蓄能压裂工艺补充地层能量,提高压裂初期产量和有效期。采用地层压力恢复法,根据油井测试资料和压裂裂缝模拟结果进行蓄能液用量精准计算;加入驱油剂、引入焖井压降模型提高蓄能液的油水置换效率;采用新型绳结暂堵剂改善转向效果。蓄能压裂技术在现场试验中得到有效验证,改变了低效油藏的开发模式,推动了北83井区及同类油藏的开发和扩边。 展开更多
关键词 蓄能 焖井 驱油剂 暂堵压裂
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页岩气储层用高温相变压裂暂堵剂研究
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作者 黄梦蝶 郑学成 徐宏伟 《四川化工》 2025年第3期6-11,共6页
针对川渝地区的高温页岩气储层,基于超分子化学理论,设计适用温度范围在120~130℃,可实现高温相变的压裂暂堵剂(CD-THN)。CD-THN体系以二甲基乙酰胺(DMAc)为溶剂,β-环糊精(β-CD)作为主体,四氢萘(THN)为客体,氯化锂作为助剂。通过探究... 针对川渝地区的高温页岩气储层,基于超分子化学理论,设计适用温度范围在120~130℃,可实现高温相变的压裂暂堵剂(CD-THN)。CD-THN体系以二甲基乙酰胺(DMAc)为溶剂,β-环糊精(β-CD)作为主体,四氢萘(THN)为客体,氯化锂作为助剂。通过探究搅拌时长、主体浓度、客体浓度和助剂浓度等对成胶温度的影响,进行暂堵剂配方优化。结果表明:形成的暂堵剂CD-THN升温至128℃时,最高黏度可达1 379 mPa·s,能够在成胶温度范围内稳定6 h以上,CD-THN具有低温低黏、高温高黏的特性,能通过升高温度使体系实现溶液-凝胶相转变,继续升高一定温度后,暂堵剂能实现自动破胶,是一种在油田暂堵领域有较好应用前景的新型暂堵材料。 展开更多
关键词 页岩气储层 暂堵材料 高温相变 水凝胶 压裂
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