The shot-range interaction and the atomic anharmonic vibration are both considered, and then the analytic functions of the Debye temperature, the specific capacity and the thermal conductivity of graphene with the tem...The shot-range interaction and the atomic anharmonic vibration are both considered, and then the analytic functions of the Debye temperature, the specific capacity and the thermal conductivity of graphene with the temperature are obtained. The influence of anharmonic vibration on these thermal physical properties is also investigated. Some theoretical results are given. If only the harmonic approximation is considered, the Debye temperature of the graphene is unrelated to the temperature. If the anharmonic terms are considered, it increases slowly with the increasing temperature. The molar heat capacity of the graphene increases nonlinearly with the increasing temperature. The mean free path of phonons and the thermal conductivity of the graphene decrease nonlinearly with the increasing temperature. The relative changes of the Debye temperature, the specific heat capacity and the thermal conductivity caused by the anharmonic terms increase with the increasing temperature. The anharmonic effect of atomic vibration becomes more significant under higher temperature.展开更多
Supercapacitors(SCs) are high-power energy storage devices with ultra-fast charge/discharge properties.SCs using concentrated aqueous-based electrolytes can work at low temperatures due to their intrinsic properties, ...Supercapacitors(SCs) are high-power energy storage devices with ultra-fast charge/discharge properties.SCs using concentrated aqueous-based electrolytes can work at low temperatures due to their intrinsic properties, such as higher freezing point depression(FPD) and robustness. Besides the traditional organic-and aqueous-based(salt-in-water) electrolytes used in SCs, water-in-salt(WISE) sodium perchlorate electrolytes offer high FPD, non-flammability, and low-toxicity conditions, allowing the fabrication of safer, environmentally friendly, and more robust devices. For the first time, this work reports a comprehensive study regarding WISE system’s charge-storage capabilities and physicochemical properties under low-temperature conditions(T < 0 ℃) using mesoporous carbon-based electrodes. The effect of temperature reduction on the electrolyte viscosity and electrical properties was investigated using different techniques and the in-situ(or operando) Raman spectroscopy under dynamic polarization conditions.The cell voltage, equivalent series resistance, and specific capacitance were investigated as a function of the temperature. The cell voltage(U) increased ~ 50%, while the specific capacitance decreased ~20%when the temperature was reduced from 25 ℃ to -10 ℃. As a result, the maximum specific energy(E = CU^(2)/2) increased ~ 100%. Therefore, low-temperature WISEs are promising candidates to improve the energy-storage characteristics in SCs.展开更多
Calorimetric measurements are performed to determine the specific heat of Si-xat.% Ge(where x = 0, 10, 30,50, 70, 90 and 100) alloys within a broad temperature range from 123 to 823 K. The measured specific heat incre...Calorimetric measurements are performed to determine the specific heat of Si-xat.% Ge(where x = 0, 10, 30,50, 70, 90 and 100) alloys within a broad temperature range from 123 to 823 K. The measured specific heat increases dramatically at low temperatures, and the composition dependence of specific heat is evaluated from the experimental results. Meanwhile, the specific heat at constant volume, the thermal expansion, and the bulk modulus of Si and Ge are investigated by the first principle calculations combined with the quasiharmonic approximation. The negative thermal expansion is observed for both Si and Ge. Furthermore, the isobaric specific heat of Si and Ge is calculated correspondingly from OK to their melting points, which is verified by the measured results and accounts for the temperature dependence in a still boarder range.展开更多
In this paper, the observational data from Marine and Meteorological Observation Platform （MMOP） at Bohe, Maoming and buoys located in Shanwei and Maoming are used to study the characteristics of air-sea temperature...In this paper, the observational data from Marine and Meteorological Observation Platform （MMOP） at Bohe, Maoming and buoys located in Shanwei and Maoming are used to study the characteristics of air-sea temperature and specific humidity difference and the relationship between wind and wave with the tropical cyclones over the South China Sea （SCS）. The heat and momentum fluxes from eddy covariance measurement （EC） are compared with these fluxes calculated by the COARE 3.0 algorithm for Typhoon Koppu. The results show that at the developing and weakening stages of Koppu, both these differences between the sea surface and the near-surface atmosphere from the MMOP are negative, and data from the buoys also indicate that the differences are negative between the sea surface and near-surface atmosphere on the right rear portion of tropical cyclones （TCs） Molave and Chanthu. However, the differences are positive on the left fi＇ont portion of Molave and Chanthu. These positive differences suggest that the heat flux is transferred from the ocean to the atmosphere, thus intensifying and maintaining the two TCs. The negative differences indicate that the ocean removes heat fluxes from the atmosphere, thus weakening the TCs. The wind-wave curves of TCs Molave and Chanthu show that significant wave height increases linearly with 2-min wind speed at 10-m height when the wind speed is less than 25 m/s, but when the wind speed is greater than 25 m/s, the significant wave height increases slightly with the wind speed. By comparing the observed sensible heat, latent heat, and friction velocity from EC with these variables from COARE 3.0 algorithm, a great bias between the observed and calculated sensible heat and latent heat fluxes is revealed, and the observed friction velocity is found to be almost the same as the calculated friction velocity.展开更多
Numerical solution of the parabolic partial differential equations with an unknown parameter play a very important role in engineering applications. In this study we present a high order scheme for determining unknown...Numerical solution of the parabolic partial differential equations with an unknown parameter play a very important role in engineering applications. In this study we present a high order scheme for determining unknown control parameter and unknown solution of two-dimensional parabolic inverse problem with overspe- cialization at a point in the spatial domain. In this approach, a compact fourth-order scheme is used to discretize spatial derivatives of equation and reduces the problem to a system of ordinary differential equations （ODEs）. Then we apply a fourth order boundary value method to the solution of resulting system of ODEs. So the proposed method has fourth order of accuracy in both space and time components and is unconditionally stable due to the favorable stability property of boundary value methods. The results of numerical experiments are presented and some comparisons are made with several well-known finite difference schemes in the literature. Also we will investigate the effect of noise in data on the approximate solutions.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 11574253the Scientific and Technological Research Program of Chongqing Municipal Education Commission under Grant Nos KJ1601111 and KJ1601118the Basic and Frontier Research Projects of Chongqing under Grant No cstc2015jcyjA40054
文摘The shot-range interaction and the atomic anharmonic vibration are both considered, and then the analytic functions of the Debye temperature, the specific capacity and the thermal conductivity of graphene with the temperature are obtained. The influence of anharmonic vibration on these thermal physical properties is also investigated. Some theoretical results are given. If only the harmonic approximation is considered, the Debye temperature of the graphene is unrelated to the temperature. If the anharmonic terms are considered, it increases slowly with the increasing temperature. The molar heat capacity of the graphene increases nonlinearly with the increasing temperature. The mean free path of phonons and the thermal conductivity of the graphene decrease nonlinearly with the increasing temperature. The relative changes of the Debye temperature, the specific heat capacity and the thermal conductivity caused by the anharmonic terms increase with the increasing temperature. The anharmonic effect of atomic vibration becomes more significant under higher temperature.
基金the financial support from the Brazilian funding agencies CNPq(310544/2019-0),FAPESP(2014/02163-7&2017/11958-1)FAPEMIG(Financial support for the LMMA/UFVJM Laboratory)and CNPq(PQ-2 grant:Process 301095/2018-3)the support from Shell and the strategic importance of the support given by ANP(Brazil’s National Oil,Natural Gas,and Biofuels Agency)through the R&D levy regulation。
文摘Supercapacitors(SCs) are high-power energy storage devices with ultra-fast charge/discharge properties.SCs using concentrated aqueous-based electrolytes can work at low temperatures due to their intrinsic properties, such as higher freezing point depression(FPD) and robustness. Besides the traditional organic-and aqueous-based(salt-in-water) electrolytes used in SCs, water-in-salt(WISE) sodium perchlorate electrolytes offer high FPD, non-flammability, and low-toxicity conditions, allowing the fabrication of safer, environmentally friendly, and more robust devices. For the first time, this work reports a comprehensive study regarding WISE system’s charge-storage capabilities and physicochemical properties under low-temperature conditions(T < 0 ℃) using mesoporous carbon-based electrodes. The effect of temperature reduction on the electrolyte viscosity and electrical properties was investigated using different techniques and the in-situ(or operando) Raman spectroscopy under dynamic polarization conditions.The cell voltage, equivalent series resistance, and specific capacitance were investigated as a function of the temperature. The cell voltage(U) increased ~ 50%, while the specific capacitance decreased ~20%when the temperature was reduced from 25 ℃ to -10 ℃. As a result, the maximum specific energy(E = CU^(2)/2) increased ~ 100%. Therefore, low-temperature WISEs are promising candidates to improve the energy-storage characteristics in SCs.
基金Supported by the National Natural Science Foundation of China under Grant Nos 51522102,51734008,51327901 and 51474175
文摘Calorimetric measurements are performed to determine the specific heat of Si-xat.% Ge(where x = 0, 10, 30,50, 70, 90 and 100) alloys within a broad temperature range from 123 to 823 K. The measured specific heat increases dramatically at low temperatures, and the composition dependence of specific heat is evaluated from the experimental results. Meanwhile, the specific heat at constant volume, the thermal expansion, and the bulk modulus of Si and Ge are investigated by the first principle calculations combined with the quasiharmonic approximation. The negative thermal expansion is observed for both Si and Ge. Furthermore, the isobaric specific heat of Si and Ge is calculated correspondingly from OK to their melting points, which is verified by the measured results and accounts for the temperature dependence in a still boarder range.
基金Key Project of Natural Science Foundation of China(40730948)National Basic Research Program of China(2009CB421501)National Natural Science Foundation of China(41075051)
文摘In this paper, the observational data from Marine and Meteorological Observation Platform （MMOP） at Bohe, Maoming and buoys located in Shanwei and Maoming are used to study the characteristics of air-sea temperature and specific humidity difference and the relationship between wind and wave with the tropical cyclones over the South China Sea （SCS）. The heat and momentum fluxes from eddy covariance measurement （EC） are compared with these fluxes calculated by the COARE 3.0 algorithm for Typhoon Koppu. The results show that at the developing and weakening stages of Koppu, both these differences between the sea surface and the near-surface atmosphere from the MMOP are negative, and data from the buoys also indicate that the differences are negative between the sea surface and near-surface atmosphere on the right rear portion of tropical cyclones （TCs） Molave and Chanthu. However, the differences are positive on the left fi＇ont portion of Molave and Chanthu. These positive differences suggest that the heat flux is transferred from the ocean to the atmosphere, thus intensifying and maintaining the two TCs. The negative differences indicate that the ocean removes heat fluxes from the atmosphere, thus weakening the TCs. The wind-wave curves of TCs Molave and Chanthu show that significant wave height increases linearly with 2-min wind speed at 10-m height when the wind speed is less than 25 m/s, but when the wind speed is greater than 25 m/s, the significant wave height increases slightly with the wind speed. By comparing the observed sensible heat, latent heat, and friction velocity from EC with these variables from COARE 3.0 algorithm, a great bias between the observed and calculated sensible heat and latent heat fluxes is revealed, and the observed friction velocity is found to be almost the same as the calculated friction velocity.
基金Supported by the Foundation of University of Kashn(Grant No.258499/5)
文摘Numerical solution of the parabolic partial differential equations with an unknown parameter play a very important role in engineering applications. In this study we present a high order scheme for determining unknown control parameter and unknown solution of two-dimensional parabolic inverse problem with overspe- cialization at a point in the spatial domain. In this approach, a compact fourth-order scheme is used to discretize spatial derivatives of equation and reduces the problem to a system of ordinary differential equations （ODEs）. Then we apply a fourth order boundary value method to the solution of resulting system of ODEs. So the proposed method has fourth order of accuracy in both space and time components and is unconditionally stable due to the favorable stability property of boundary value methods. The results of numerical experiments are presented and some comparisons are made with several well-known finite difference schemes in the literature. Also we will investigate the effect of noise in data on the approximate solutions.
