Thermal barrier coating(TBC)is crucial for the performance of turbine blades at high temperatures;however,it degrades the microstructure of single-crystal superalloy(SX),thereby reducing creep life.Despite this,the de...Thermal barrier coating(TBC)is crucial for the performance of turbine blades at high temperatures;however,it degrades the microstructure of single-crystal superalloy(SX),thereby reducing creep life.Despite this,the degradation mechanisms associated with the complex multi-layer damage and inter-layer diffusion behavior for TBC/SX systems have not yet been fully elucidated.In this study,using integrated experimental efforts and multiscale characterization techniques,the creep degradation mechanisms of TBC/SX systems at 900℃/500 MPa,980℃/300 MPa,and 1050℃/160 MPa are systematically investigated.Results demonstrate that the creep degradation from TBC intensifies with increasing temperature(T)and stress(σ)ratio(T/σ),exhibiting significant dependency on these two factors,and primarily reduces lifespan of the steady-state stage,with minimal effects on the accelerating stage.During creep deformation,the cracking behavior caused by thermally grown oxide(TGO)beneath the top coat(TC)layer,voids resulting from internal oxidation and interdiffusion in the bond coat(BC)layer,and the recrystallization growth driven by the sandblasting process in the secondary reaction zone(SRZ)are temperature-sensitive damages.In contrast,the initiation and propagation of cracks associated with the topologically close-packed(TCP)phases in the SRZ exhibit pronounced stress sensitivity.Furthermore,the formation of the substrate diffusion zone(SDZ)and the decomposition ofγ/γ′interfacial dislocation networks driven by the Cr-Ru diffusion,as well as the increased stacking fault energy in theγ′phase due to Co loss,are responsible for the acceleration of steady-state creep rate at 1050℃/160 MPa.This work provides a comprehensive and in-depth understanding of the degradation mechanisms under thermal-mechanical coupling in TBC/SX systems,offering new insights into targeted design optimization for multilayered coatings.展开更多
Distributions of nuclear magnetic resonance(NMR)relaxation times provide detailed information about the water in wood.This study documents the water dynamics analysis of T_(2)and T_(1)distributions for saturated delig...Distributions of nuclear magnetic resonance(NMR)relaxation times provide detailed information about the water in wood.This study documents the water dynamics analysis of T_(2)and T_(1)distributions for saturated delignified sapwood(DSW),delignified heartwood(DHW)and lignocellulose(LC)samples at different temperatures.Results indicate that below the freezing point of bulk water,free water freezes,causing its signal to disappear from the distribution.Then,the low temperature distributions of the unfrozen bound water contain more information about its components,with DSW,DHW and LC containing two distinct states of bound water(OH bound water(B-water)and more freely bound water(C-water)).Furthermore,it was observed that within the temperature range of−3°C to−60°C,B-water in DSW,DHW and LC maintained a higher unfrozen water content(UWC)value than C-water,and the T_(1)/T_(2)ratios for B-water were consistently higher than that for C-water,indicating that B-water has a greater antifreeze capacity.T_(2)and T_(1)distributions offer different kinds of information about water components,and all peaks within the distribution have been assigned.展开更多
This work is intended to further understand the controversial temperature dependencies of various slip modes in Mg alloys,and their effects on the mechanical properties at high temperature(HT).A systematical and stati...This work is intended to further understand the controversial temperature dependencies of various slip modes in Mg alloys,and their effects on the mechanical properties at high temperature(HT).A systematical and statistical investigation on the temperature-dependent macroscopic deformation behavior and the corresponding grain-scale slip activity was performed for both an extruded Mg-10Y(wt.%)sheet and a pure Mg sheet during tension at 25-300℃.The alloy’s strength increased by up to 44 MPa(14.0%)at HT compared to that at 25℃and this was accompanied by decreased pyramidal II(c+a)slip activity;both phenomena were opposite to that for pure Mg.The critical resolved shear stress(CRSS)ratios were estimated based on the~1700 sets of observed slip traces,and a positive temperature-dependent CRSS_(pyr II)/CRSS_(bas)was found in Mg-10Y.Compared to pure Mg,Mg-10Y exhibited pronounced strain hard-ening at HT due to enhanced slip-slip interactions,including multiple slip and cross slip,increased GND accumulation,and Y solute-dislocation interactions.The significant pyramidal II(c+a)slip activity(up to 30%frequency),its thermal hardening and pronounced strain hardening nature are proposed to be the key reasons for the observed anomalous strength increase in Mg-10Y.The grain-scale experimental evidence for(c+a)dislocation activity and its correlation to mechanical properties were revealed in this study and compared to recent atomic-scale simulations.展开更多
Due to their high dielectric constant,low melting point,and high boiling point,nitrile-based solvents exhibit significant potential in wide-temperature-range electrolytes.In this study,a wide-temperature electrolyte s...Due to their high dielectric constant,low melting point,and high boiling point,nitrile-based solvents exhibit significant potential in wide-temperature-range electrolytes.In this study,a wide-temperature electrolyte system composed of lithium bis(trifluoromethanesulfonyl)imide(LiTFSI),dimethyl carbonate(DMC),and butyronitrile(BN)in a molar ratio of 1:3:9 was designed.Using variable-temperature infrared(IR)spectroscopy with carbonyl(C=O)and cyano(C≡N)groups as IR probes,combined with molecular dynamics simulations and density functional theory calculations,the temperature-dependent evolution of the Li^(+)solvation structure and molecular dynamics were systematically investigated over the range of-45℃to 45℃.The results show that the introduction of BN not only significantly enhances the low-temperature ionic conductivity and high-temperature stability of the electrolyte,but also optimizes the solvation structure and interfacial characteristics of lithium ions through strong coordination interactions.This work provides both theoretical insights and experimental support for the design of wide-temperature electrolytes.展开更多
The long-lasting expectation“the hotter the engine,the better”calls for the development of high-temperature metallic alloys.Although the high specific strengths of titanium alloys are compelling for such application...The long-lasting expectation“the hotter the engine,the better”calls for the development of high-temperature metallic alloys.Although the high specific strengths of titanium alloys are compelling for such applications,their deleterious softening beyond 600℃ imposes serious limitations.Much has been known for decades regarding the phase metallurgy for precipitation strengthening design in titanium alloys,however,the other facile strength promotion mechanism,dispersion strengthening,remains comparatively less-explored and unutilized.The present research concerns the multi-scale dispersion strengthening in titanium alloys,with mechanistic emphases on the critical plasticity micro-events that affect strength preservation.Due to the simultaneous introduction of intragranular dispersoids and intergranular reinforcers,the current titanium alloys present superior engineering tensile strength of 519 MPa at 700℃.Throughout the examined 25-800℃ temperature range,noticeable softening induced by the thermal activation occurs above 600℃,accompanied by evident strength loss.The temperature-dependence transition of dominated softening mechanisms from dynamic recovery to dynamic recrystallization has been clarified by theoretical calculations.Furthermore,the strengthening effect of multi-scale architectures is underpinned as the enhanced dislocation strengthening owing to the introduction of thermally-stable heterointerfaces,which could generically guide the design of similar heat-resistant titanium alloys.展开更多
Partial phase transformation in NiTi-based refrigerants usually enables efficient and durable elastocaloric cooling,but its thermomechanical behavior with varying temperatures remains unclear.Keeping this in view,the ...Partial phase transformation in NiTi-based refrigerants usually enables efficient and durable elastocaloric cooling,but its thermomechanical behavior with varying temperatures remains unclear.Keeping this in view,the elastocaloric effect of NiTi under incomplete transformation across 15-100℃ is investigated and a superelastic deformation window between 25 and 85℃ is identified.Synchronous infrared thermography and digital image correlation,and an innovative macro-micro phase-field model are employed to examine martensitic transformation and elastocaloric properties of NiTi within the superelastic window.Experimental and simulated results consistently reveal that the spatiotemporal thermal profiles correlate with Lüders strain band evolution.As superelastic deformation temperature increases,strain localization intensifies,with Lüders bands favoring an inward strain growth over an outward expansion,resulting in a smaller yet more deformed martensitic transformation zone.The aggravated strain inhomogeneity makes the local endothermic undercooling tested at 85℃ up to about twice(−30.05℃)that at 25℃(−15.32℃),boosting the global cooling capacity by 65%,despite constant strain.The seeming contradiction between the larger elastocaloric effect and the narrower apparent martensitic transformation zone is elucidated by recourse to the simulations.It is found that the martensitic transformation within the Lüders bands is incomplete,proceeding in a macroscopically uniform but microscopically heterogeneous manner.Elevated temperatures within the superelastic window increase the transformed volume fraction and enhance martensitic transformation,thereby strengthening the global caloric effect.The work sheds light on the interplay between partial martensitic transformation and thermal behavior in NiTi under varying superelastic deformation temperatures,providing insights for advanced elastocaloric cooling applications.展开更多
Based on the EAM potential, a molecular dynamics study on the tensile properties of ultrathin nickel nanowires in the （100〉 orientation with diameters of 3.94, 4.95 and 5.99 nm was presented at different temperature...Based on the EAM potential, a molecular dynamics study on the tensile properties of ultrathin nickel nanowires in the （100〉 orientation with diameters of 3.94, 4.95 and 5.99 nm was presented at different temperatures and strain rates. The temperature and strain rate dependences of tensile properties were investigated. The simulation results show that the elastic modulus and the yield strength are gradually decreasing with the increase of temperature, while with the increase of the strain rate, the stress--strain curves fluctuate more intensely and the ultrathin nickel nanowires rupture at one smaller and smaller strain. At an ideal temperature of 0.01 K, the yield strength of the nanowires drops rapidly with the increase of strain rate, and at other temperatures the strain rate has a little influence on the elastic modulus and the yield strength. Finally, the effects of size on the tensile properties of ultrathin nickel nanowires were briefly discussed.展开更多
Uniaxial compressive experiments of ultrafine-grained Al fabricated by equal channel angular pressing(ECAP) method were performed at wide temperature and strain rate range. The influence of temperature on flow stress,...Uniaxial compressive experiments of ultrafine-grained Al fabricated by equal channel angular pressing(ECAP) method were performed at wide temperature and strain rate range. The influence of temperature on flow stress, strain hardening rate and strain rate sensitivity was investigated experimentally. The results show that both the effect of temperature on flow stress and its strain rate sensitivity of ECAPed Al is much larger than those of the coarse-grained Al. The temperature sensitivity of ultrafine-grained Al is comparatively weaker than that of the coarse-grained Al. Based on the experimental results, the apparent activation volume was estimated at different temperatures and strain rates. The forest dislocation interactions is the dominant thermally activated mechanism for ECAPed Al compressed at quasi-static strain rates, while the viscous drag plays an important role at high strain rates.展开更多
We study the influences of the temperature on the energy-band structure for the Holstein molecular-crystal model. We show that the energy-band width and the energy-gap width of a solid are relevant to both the interac...We study the influences of the temperature on the energy-band structure for the Holstein molecular-crystal model. We show that the energy-band width and the energy-gap width of a solid are relevant to both the interaction between an electron and thermal phonons and to thermal expansion. For a one-dimensional Li atom lattice chain, under the chosen parameters,the width of the ls and 2s energy bands narrows as the temperature increases and the energy-gap width between the two bands widens. These results agree qualitatively with those observed experimentally. Studying temperature dependence of the energy-band structure is of great importance for understanding optical and transporting characteristics of a solid.展开更多
The temperature dependence of some performance of 6H SiC unipolar power devices is analyzed theoretically.By employing the temperature dependent ionization coefficient and mobility of a silicon carbide,the analytica...The temperature dependence of some performance of 6H SiC unipolar power devices is analyzed theoretically.By employing the temperature dependent ionization coefficient and mobility of a silicon carbide,the analytical expressions of the temperature dependent performance,such as breakdown characteristics and on resistance of 6H SiC unipolar power devices are derived in a closed form.The analytical results are compared with the experimental results,with good accordance found in the breakdown characteristics.展开更多
The aim of this work is firstly to optimize T6 heat-treatment of low-pressure sand-cast Mg-10Gd-3Y-0.5Zr alloy,and then systematically investigate the mechanical behavior of the T6-treated alloy from room temperature ...The aim of this work is firstly to optimize T6 heat-treatment of low-pressure sand-cast Mg-10Gd-3Y-0.5Zr alloy,and then systematically investigate the mechanical behavior of the T6-treated alloy from room temperature to 300℃.It turned out that the optimum T6 heat-treatments for the tested alloy are 525℃×12 h+225℃×14 h and 525℃×12 h+250℃×12 h which integrated age-hardening and tensile properties into account,respectively.The strength of the T6-treated alloy indicates obvious anomalous temperature dependence from room temperature to 300℃,namely both ultimate tensile strength and yield strength of the tested alloy firstly increase with tensile temperature,and then decrease as temperature increases further.Elongation increased with temperature monotonously.The tensile fracture mode of the tested alloy changes from transgranular fracture to intergranular fracture with the increasing of test temperature.展开更多
The temperature dependences of forward voltage drop（VF） of the fast recovery diodes（FRDs） are remarkably influenced by different lifetime controlled treatments. In this paper the results of an experimental study a...The temperature dependences of forward voltage drop（VF） of the fast recovery diodes（FRDs） are remarkably influenced by different lifetime controlled treatments. In this paper the results of an experimental study are presented, which are the lifetime controls of platinum treatment, electron irradiation treatment, and the combined treatment of the above ones.Based on deep level transient spectroscopy（DLTS） measurements, a new level E6（EC-0.376 e V） is found in the combined lifetime treated（CLT） sample, which is different from the levels of the individual platinum and electron irradiation ones. Comparing the tested VFresults of CLT samples with the others, the level E6 is responsible for the degradation of temperature dependence of the forward voltage drop in the FRD.展开更多
In this work, temperature dependences of small-signal model parameters in the SiGe HBT HICUM model are presented. Electrical elements in the small-signal equivalent circuit are first extracted at each temperature, the...In this work, temperature dependences of small-signal model parameters in the SiGe HBT HICUM model are presented. Electrical elements in the small-signal equivalent circuit are first extracted at each temperature, then the temperature dependences are determined by the series of extracted temperature coefficients, based on the established temperature for- mulas for corresponding model parameters. The proposed method is validated by a 1x 0.2 x 16 μm2 SiGe HBT over a wide temperature range （from 218 K to 473 K）, and good matching is obtained between the extracted and modeled resuits. Therefore, we believe that the proposed extraction flow of model parameter temperature dependence is reliable for characterizing the transistor performance and guiding the circuit design over a wide temperature range.展开更多
Heterogeneous reactions of nitrogen dioxide （NO2） on soils collected from Dalian （S 1） and Changsha （S2） were investigated over the relative humidity （RH） range of 5%-80% and temperature range of 278-328 K usi...Heterogeneous reactions of nitrogen dioxide （NO2） on soils collected from Dalian （S 1） and Changsha （S2） were investigated over the relative humidity （RH） range of 5%-80% and temperature range of 278-328 K using a horizontal coated-wall flow tube. The initial uptake coefficients of NO2 on S2 exhibited a decreasing trend from （10 ± 1.3） × 10-8 to （3.1 ± 0.5） x 10-8 with the relative humidity increasing from 5% to 80%. In the temperature effect studies, the initial uptake coefficients of S1 and S2 decreased from （10± 1.2） × 10-8 to （3.8 ± 0.5） × 10-8 and from （16± 2.2） × 10-8 to （3.8 ±0.4） × 10-8 when temperature increased from 278 to 288 K for S1 and from 278 to 308 K for S2, respectively. As the temperature continued to increase, the initial uptake coefficients of S1 and S2 returned to （7.9 ± 1.1）× 10-8 and （20 ± 3.1） × 10-8 at 313 and 328 K, respectively. This study shows that relative humidity could influence the uptake kinetics of NO2 on soil and temperature would impact the heterogeneous chemistry of NO2.展开更多
The temperature dependence of carrier transport properties of Alx Gal-xN/InyGal-yN/CaN and AlzGal-xN/GaN heterostructures has been investigated. It is shown that the Hall mobility in Alo.25Gao.75N/Ino.03Gao.97N/GaN he...The temperature dependence of carrier transport properties of Alx Gal-xN/InyGal-yN/CaN and AlzGal-xN/GaN heterostructures has been investigated. It is shown that the Hall mobility in Alo.25Gao.75N/Ino.03Gao.97N/GaN heterostructures is higher than that in Alo.25Gao.75N/GaN heterostructures at temperatures above 500 K, even the mobility in the former is much lower than that in the latter at 300 K. More importantly, the electron sheet density in Alo.25Gao.75N/Ino.03Gao.97N/GaN heterostructures decreases slightly, whereas the electron sheet density in Al0.25Gao.75N/CaN heterostructures gradually increases with increasing temperature above 500 K. It is believed that an electron depletion layer is formed due to the negative polarization charges at the Iny Can-yN/GaN heterointerface induced by the compressive strain in the InyCal-yN channel, which effectively suppresses the parallel conductivity originating from the thermal excitation in the underlying GaN layer at high temperatures.展开更多
The current-voltage characteristics of 4H-SiC junction barrier Schottky （JBS） diodes terminated by an offset field plate have been measured in the temperature range of 25-300℃. An experimental barrier height value ...The current-voltage characteristics of 4H-SiC junction barrier Schottky （JBS） diodes terminated by an offset field plate have been measured in the temperature range of 25-300℃. An experimental barrier height value of about 0.5 eV is obtained for the Ti/4H-SiC JBS diodes at room temperature. A decrease in the experimental barrier height and an increase in the ideality factor with decreasing temperature are shown. Reverse recovery testing also shows the temperature dependence of the peak recovery current density and the reverse recovery time. Finally, a discussion of reducing the reverse recovery time is presented.展开更多
A comparison of the temperature dependence of the P-hit single event transient （SET） in a two-transistor （2T） inverter with that in a three-transistor （3T） inverter is carried out based on a three-dimensional nu...A comparison of the temperature dependence of the P-hit single event transient （SET） in a two-transistor （2T） inverter with that in a three-transistor （3T） inverter is carried out based on a three-dimensional numerical simulation. Due to the significantly distinct mechanisms of the single event change collection in the 2T and the 3T inverters, the temperature plays different roles in the SET production and propagation. The SET pulse will be significantly broadened in the 2T inverter chain while will be compressed in the 3T inverter chain as temperature increases. The investigation provides a new insight into the SET mitigation under the extreme environment, where both the high temperature and the single event effects should be considered. The 3T inverter layout structure （or similar layout structures） will be a better solution for spaceborne integrated circuit design for extreme environments.展开更多
It is challenging for aqueous Zn-ion batteries(ZIBs)to achieve comparable low-temperature(low-T)performance due to the easy-frozen electrolyte and severe Zn dendrites.Herein,an aqueous electrolyte with a low freezing ...It is challenging for aqueous Zn-ion batteries(ZIBs)to achieve comparable low-temperature(low-T)performance due to the easy-frozen electrolyte and severe Zn dendrites.Herein,an aqueous electrolyte with a low freezing point and high ionic conductivity is proposed.Combined with molecular dynamics simulation and multi-scale interface analysis(time of flight secondary ion mass spectrometry threedimensional mapping and in-situ electrochemical impedance spectroscopy method),the temperature independence of the V_(2)O_(5)cathode and Zn anode is observed to be opposite.Surprisingly,dominated by the solvent structure of the designed electrolyte at low temperatures,vanadium dissolution/shuttle is significantly inhibited,and the zinc dendrites caused by this electrochemical crosstalk are greatly relieved,thus showing an abnormal temperature inversion effect.Through the disclosure and improvement of the above phenomena,the designed Zn||V_(2)O_(5)full cell delivers superior low-T performance,maintaining almost 99%capacity retention after 9500 cycles(working more than 2500 h)at-20°C.This work proposes a kind of electrolyte suitable for low-T ZIBs and reveals the inverse temperature dependence of the Zn anode,which might offer a novel perspective for the investigation of low-T aqueous battery systems.展开更多
This paper deals with finite element study of the scanning induction heating of the magnetic steel sheets in transversal flux devices,taking into account the magnetic nonlinearity and the dependence on temperature of ...This paper deals with finite element study of the scanning induction heating of the magnetic steel sheets in transversal flux devices,taking into account the magnetic nonlinearity and the dependence on temperature of steel properties.The decrease of the non-uniformity of the transversal profile of sheet heating as effect of the magnetic or electromagnetic screening of the sheet lateral sides was proved.展开更多
基金supported by the National Science and Technology Major Project of China(No.J2019-Ⅲ-0008-0051)the National Natural Science Foundation of China(Nos.52201140,52375225,and 92360307)the Natural Science Foundation for Youths of Shaanxi Province(No.2023-JC-QN-0521).
文摘Thermal barrier coating(TBC)is crucial for the performance of turbine blades at high temperatures;however,it degrades the microstructure of single-crystal superalloy(SX),thereby reducing creep life.Despite this,the degradation mechanisms associated with the complex multi-layer damage and inter-layer diffusion behavior for TBC/SX systems have not yet been fully elucidated.In this study,using integrated experimental efforts and multiscale characterization techniques,the creep degradation mechanisms of TBC/SX systems at 900℃/500 MPa,980℃/300 MPa,and 1050℃/160 MPa are systematically investigated.Results demonstrate that the creep degradation from TBC intensifies with increasing temperature(T)and stress(σ)ratio(T/σ),exhibiting significant dependency on these two factors,and primarily reduces lifespan of the steady-state stage,with minimal effects on the accelerating stage.During creep deformation,the cracking behavior caused by thermally grown oxide(TGO)beneath the top coat(TC)layer,voids resulting from internal oxidation and interdiffusion in the bond coat(BC)layer,and the recrystallization growth driven by the sandblasting process in the secondary reaction zone(SRZ)are temperature-sensitive damages.In contrast,the initiation and propagation of cracks associated with the topologically close-packed(TCP)phases in the SRZ exhibit pronounced stress sensitivity.Furthermore,the formation of the substrate diffusion zone(SDZ)and the decomposition ofγ/γ′interfacial dislocation networks driven by the Cr-Ru diffusion,as well as the increased stacking fault energy in theγ′phase due to Co loss,are responsible for the acceleration of steady-state creep rate at 1050℃/160 MPa.This work provides a comprehensive and in-depth understanding of the degradation mechanisms under thermal-mechanical coupling in TBC/SX systems,offering new insights into targeted design optimization for multilayered coatings.
基金supported by Natural Science Foundation of Inner Mongolia Autonomous Region of China (2023MS03027)the National Natural Science Foundation of China (31860185 and 31160141)
文摘Distributions of nuclear magnetic resonance(NMR)relaxation times provide detailed information about the water in wood.This study documents the water dynamics analysis of T_(2)and T_(1)distributions for saturated delignified sapwood(DSW),delignified heartwood(DHW)and lignocellulose(LC)samples at different temperatures.Results indicate that below the freezing point of bulk water,free water freezes,causing its signal to disappear from the distribution.Then,the low temperature distributions of the unfrozen bound water contain more information about its components,with DSW,DHW and LC containing two distinct states of bound water(OH bound water(B-water)and more freely bound water(C-water)).Furthermore,it was observed that within the temperature range of−3°C to−60°C,B-water in DSW,DHW and LC maintained a higher unfrozen water content(UWC)value than C-water,and the T_(1)/T_(2)ratios for B-water were consistently higher than that for C-water,indicating that B-water has a greater antifreeze capacity.T_(2)and T_(1)distributions offer different kinds of information about water components,and all peaks within the distribution have been assigned.
基金supported by the National Natural Science Foundation of China(No.52171125)the Sichuan Science and Technology Program(No.2024NSFSC0193)。
文摘This work is intended to further understand the controversial temperature dependencies of various slip modes in Mg alloys,and their effects on the mechanical properties at high temperature(HT).A systematical and statistical investigation on the temperature-dependent macroscopic deformation behavior and the corresponding grain-scale slip activity was performed for both an extruded Mg-10Y(wt.%)sheet and a pure Mg sheet during tension at 25-300℃.The alloy’s strength increased by up to 44 MPa(14.0%)at HT compared to that at 25℃and this was accompanied by decreased pyramidal II(c+a)slip activity;both phenomena were opposite to that for pure Mg.The critical resolved shear stress(CRSS)ratios were estimated based on the~1700 sets of observed slip traces,and a positive temperature-dependent CRSS_(pyr II)/CRSS_(bas)was found in Mg-10Y.Compared to pure Mg,Mg-10Y exhibited pronounced strain hard-ening at HT due to enhanced slip-slip interactions,including multiple slip and cross slip,increased GND accumulation,and Y solute-dislocation interactions.The significant pyramidal II(c+a)slip activity(up to 30%frequency),its thermal hardening and pronounced strain hardening nature are proposed to be the key reasons for the observed anomalous strength increase in Mg-10Y.The grain-scale experimental evidence for(c+a)dislocation activity and its correlation to mechanical properties were revealed in this study and compared to recent atomic-scale simulations.
基金supported by the National Natural Science Foundation of China(No.21603238 to Juan Zhao,Nos.21573243 and 21327802 to Jianping Wang).
文摘Due to their high dielectric constant,low melting point,and high boiling point,nitrile-based solvents exhibit significant potential in wide-temperature-range electrolytes.In this study,a wide-temperature electrolyte system composed of lithium bis(trifluoromethanesulfonyl)imide(LiTFSI),dimethyl carbonate(DMC),and butyronitrile(BN)in a molar ratio of 1:3:9 was designed.Using variable-temperature infrared(IR)spectroscopy with carbonyl(C=O)and cyano(C≡N)groups as IR probes,combined with molecular dynamics simulations and density functional theory calculations,the temperature-dependent evolution of the Li^(+)solvation structure and molecular dynamics were systematically investigated over the range of-45℃to 45℃.The results show that the introduction of BN not only significantly enhances the low-temperature ionic conductivity and high-temperature stability of the electrolyte,but also optimizes the solvation structure and interfacial characteristics of lithium ions through strong coordination interactions.This work provides both theoretical insights and experimental support for the design of wide-temperature electrolytes.
基金financially supported by the National Key R&D Program of China(No.2021YFB3701203)the National Natural Science Foundation of China(Nos.U22A20113,52261135543,52171137 and 52071116)the Heilongjiang Touyan Team Program,Heilongjiang Provincial Natural Science Foundation of China(No.TD2020E001).
文摘The long-lasting expectation“the hotter the engine,the better”calls for the development of high-temperature metallic alloys.Although the high specific strengths of titanium alloys are compelling for such applications,their deleterious softening beyond 600℃ imposes serious limitations.Much has been known for decades regarding the phase metallurgy for precipitation strengthening design in titanium alloys,however,the other facile strength promotion mechanism,dispersion strengthening,remains comparatively less-explored and unutilized.The present research concerns the multi-scale dispersion strengthening in titanium alloys,with mechanistic emphases on the critical plasticity micro-events that affect strength preservation.Due to the simultaneous introduction of intragranular dispersoids and intergranular reinforcers,the current titanium alloys present superior engineering tensile strength of 519 MPa at 700℃.Throughout the examined 25-800℃ temperature range,noticeable softening induced by the thermal activation occurs above 600℃,accompanied by evident strength loss.The temperature-dependence transition of dominated softening mechanisms from dynamic recovery to dynamic recrystallization has been clarified by theoretical calculations.Furthermore,the strengthening effect of multi-scale architectures is underpinned as the enhanced dislocation strengthening owing to the introduction of thermally-stable heterointerfaces,which could generically guide the design of similar heat-resistant titanium alloys.
基金financially supported by the National Key Re-search and Development Program of China(No.2017YFB0701801)。
文摘Partial phase transformation in NiTi-based refrigerants usually enables efficient and durable elastocaloric cooling,but its thermomechanical behavior with varying temperatures remains unclear.Keeping this in view,the elastocaloric effect of NiTi under incomplete transformation across 15-100℃ is investigated and a superelastic deformation window between 25 and 85℃ is identified.Synchronous infrared thermography and digital image correlation,and an innovative macro-micro phase-field model are employed to examine martensitic transformation and elastocaloric properties of NiTi within the superelastic window.Experimental and simulated results consistently reveal that the spatiotemporal thermal profiles correlate with Lüders strain band evolution.As superelastic deformation temperature increases,strain localization intensifies,with Lüders bands favoring an inward strain growth over an outward expansion,resulting in a smaller yet more deformed martensitic transformation zone.The aggravated strain inhomogeneity makes the local endothermic undercooling tested at 85℃ up to about twice(−30.05℃)that at 25℃(−15.32℃),boosting the global cooling capacity by 65%,despite constant strain.The seeming contradiction between the larger elastocaloric effect and the narrower apparent martensitic transformation zone is elucidated by recourse to the simulations.It is found that the martensitic transformation within the Lüders bands is incomplete,proceeding in a macroscopically uniform but microscopically heterogeneous manner.Elevated temperatures within the superelastic window increase the transformed volume fraction and enhance martensitic transformation,thereby strengthening the global caloric effect.The work sheds light on the interplay between partial martensitic transformation and thermal behavior in NiTi under varying superelastic deformation temperatures,providing insights for advanced elastocaloric cooling applications.
基金Project(51205302)supported by the National Natural Science Foundation of ChinaProject(2013JM7017)supported by the Natural Science Basic Research Plan in Shanxi Province of ChinaProject(K5051304006)supported by the Fundamental Research Funds for the Central Universities,China
文摘Based on the EAM potential, a molecular dynamics study on the tensile properties of ultrathin nickel nanowires in the （100〉 orientation with diameters of 3.94, 4.95 and 5.99 nm was presented at different temperatures and strain rates. The temperature and strain rate dependences of tensile properties were investigated. The simulation results show that the elastic modulus and the yield strength are gradually decreasing with the increase of temperature, while with the increase of the strain rate, the stress--strain curves fluctuate more intensely and the ultrathin nickel nanowires rupture at one smaller and smaller strain. At an ideal temperature of 0.01 K, the yield strength of the nanowires drops rapidly with the increase of strain rate, and at other temperatures the strain rate has a little influence on the elastic modulus and the yield strength. Finally, the effects of size on the tensile properties of ultrathin nickel nanowires were briefly discussed.
基金Projects(11272267,11102168,10932008)supported by the National Natural Science Foundation of ChinaProject(B07050)supported by Northwestern Polytechnical University
文摘Uniaxial compressive experiments of ultrafine-grained Al fabricated by equal channel angular pressing(ECAP) method were performed at wide temperature and strain rate range. The influence of temperature on flow stress, strain hardening rate and strain rate sensitivity was investigated experimentally. The results show that both the effect of temperature on flow stress and its strain rate sensitivity of ECAPed Al is much larger than those of the coarse-grained Al. The temperature sensitivity of ultrafine-grained Al is comparatively weaker than that of the coarse-grained Al. Based on the experimental results, the apparent activation volume was estimated at different temperatures and strain rates. The forest dislocation interactions is the dominant thermally activated mechanism for ECAPed Al compressed at quasi-static strain rates, while the viscous drag plays an important role at high strain rates.
文摘We study the influences of the temperature on the energy-band structure for the Holstein molecular-crystal model. We show that the energy-band width and the energy-gap width of a solid are relevant to both the interaction between an electron and thermal phonons and to thermal expansion. For a one-dimensional Li atom lattice chain, under the chosen parameters,the width of the ls and 2s energy bands narrows as the temperature increases and the energy-gap width between the two bands widens. These results agree qualitatively with those observed experimentally. Studying temperature dependence of the energy-band structure is of great importance for understanding optical and transporting characteristics of a solid.
文摘The temperature dependence of some performance of 6H SiC unipolar power devices is analyzed theoretically.By employing the temperature dependent ionization coefficient and mobility of a silicon carbide,the analytical expressions of the temperature dependent performance,such as breakdown characteristics and on resistance of 6H SiC unipolar power devices are derived in a closed form.The analytical results are compared with the experimental results,with good accordance found in the breakdown characteristics.
基金This work is supported by National Natural Science Foundation of China(Nos.51771115 and 51775334)National Science and Technology Major Project(2017ZX04006001)+1 种基金Joint Fund for Space Science and Technology(6141B06300401 and 6141B06310106)Science Innovation Foundation of Shanghai Academy of Spaceflight Technology(No.SAST2016048).
文摘The aim of this work is firstly to optimize T6 heat-treatment of low-pressure sand-cast Mg-10Gd-3Y-0.5Zr alloy,and then systematically investigate the mechanical behavior of the T6-treated alloy from room temperature to 300℃.It turned out that the optimum T6 heat-treatments for the tested alloy are 525℃×12 h+225℃×14 h and 525℃×12 h+250℃×12 h which integrated age-hardening and tensile properties into account,respectively.The strength of the T6-treated alloy indicates obvious anomalous temperature dependence from room temperature to 300℃,namely both ultimate tensile strength and yield strength of the tested alloy firstly increase with tensile temperature,and then decrease as temperature increases further.Elongation increased with temperature monotonously.The tensile fracture mode of the tested alloy changes from transgranular fracture to intergranular fracture with the increasing of test temperature.
基金Project supported by the Doctoral Fund of Ministry of Education of China(Grant No.20111103120016)the State Grid Corporation of China Program of Science and Technology,China(Grant No.5455DW140003)
文摘The temperature dependences of forward voltage drop（VF） of the fast recovery diodes（FRDs） are remarkably influenced by different lifetime controlled treatments. In this paper the results of an experimental study are presented, which are the lifetime controls of platinum treatment, electron irradiation treatment, and the combined treatment of the above ones.Based on deep level transient spectroscopy（DLTS） measurements, a new level E6（EC-0.376 e V） is found in the combined lifetime treated（CLT） sample, which is different from the levels of the individual platinum and electron irradiation ones. Comparing the tested VFresults of CLT samples with the others, the level E6 is responsible for the degradation of temperature dependence of the forward voltage drop in the FRD.
基金supported partially by the Important National Science&Technology Specific Projects,China(Grant No.2013ZX02503003)
文摘In this work, temperature dependences of small-signal model parameters in the SiGe HBT HICUM model are presented. Electrical elements in the small-signal equivalent circuit are first extracted at each temperature, then the temperature dependences are determined by the series of extracted temperature coefficients, based on the established temperature for- mulas for corresponding model parameters. The proposed method is validated by a 1x 0.2 x 16 μm2 SiGe HBT over a wide temperature range （from 218 K to 473 K）, and good matching is obtained between the extracted and modeled resuits. Therefore, we believe that the proposed extraction flow of model parameter temperature dependence is reliable for characterizing the transistor performance and guiding the circuit design over a wide temperature range.
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (No.KJCX2-EW-H01)the National Basic Research Program(973) of China (No. 2011CB403401)the National Natural Science Foundation of China (No. 21077109,41005070)
文摘Heterogeneous reactions of nitrogen dioxide （NO2） on soils collected from Dalian （S 1） and Changsha （S2） were investigated over the relative humidity （RH） range of 5%-80% and temperature range of 278-328 K using a horizontal coated-wall flow tube. The initial uptake coefficients of NO2 on S2 exhibited a decreasing trend from （10 ± 1.3） × 10-8 to （3.1 ± 0.5） x 10-8 with the relative humidity increasing from 5% to 80%. In the temperature effect studies, the initial uptake coefficients of S1 and S2 decreased from （10± 1.2） × 10-8 to （3.8 ± 0.5） × 10-8 and from （16± 2.2） × 10-8 to （3.8 ±0.4） × 10-8 when temperature increased from 278 to 288 K for S1 and from 278 to 308 K for S2, respectively. As the temperature continued to increase, the initial uptake coefficients of S1 and S2 returned to （7.9 ± 1.1）× 10-8 and （20 ± 3.1） × 10-8 at 313 and 328 K, respectively. This study shows that relative humidity could influence the uptake kinetics of NO2 on soil and temperature would impact the heterogeneous chemistry of NO2.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.60906041,60736033,60890193,and 10774001)
文摘The temperature dependence of carrier transport properties of Alx Gal-xN/InyGal-yN/CaN and AlzGal-xN/GaN heterostructures has been investigated. It is shown that the Hall mobility in Alo.25Gao.75N/Ino.03Gao.97N/GaN heterostructures is higher than that in Alo.25Gao.75N/GaN heterostructures at temperatures above 500 K, even the mobility in the former is much lower than that in the latter at 300 K. More importantly, the electron sheet density in Alo.25Gao.75N/Ino.03Gao.97N/GaN heterostructures decreases slightly, whereas the electron sheet density in Al0.25Gao.75N/CaN heterostructures gradually increases with increasing temperature above 500 K. It is believed that an electron depletion layer is formed due to the negative polarization charges at the Iny Can-yN/GaN heterointerface induced by the compressive strain in the InyCal-yN channel, which effectively suppresses the parallel conductivity originating from the thermal excitation in the underlying GaN layer at high temperatures.
基金Project supported by the National Natural Science Foundation of China (Grant No. 61006060)the 13115 Innovation Engineering of Shaanxi, China (Grant No. 2008ZDKG-30)the Key Laboratory Fund of Ministry of Education, China (Grant No. JY0100112501)
文摘The current-voltage characteristics of 4H-SiC junction barrier Schottky （JBS） diodes terminated by an offset field plate have been measured in the temperature range of 25-300℃. An experimental barrier height value of about 0.5 eV is obtained for the Ti/4H-SiC JBS diodes at room temperature. A decrease in the experimental barrier height and an increase in the ideality factor with decreasing temperature are shown. Reverse recovery testing also shows the temperature dependence of the peak recovery current density and the reverse recovery time. Finally, a discussion of reducing the reverse recovery time is presented.
基金Project supported by the Key Program of the National Natural Science Foundation of China(Grant No.60836004)
文摘A comparison of the temperature dependence of the P-hit single event transient （SET） in a two-transistor （2T） inverter with that in a three-transistor （3T） inverter is carried out based on a three-dimensional numerical simulation. Due to the significantly distinct mechanisms of the single event change collection in the 2T and the 3T inverters, the temperature plays different roles in the SET production and propagation. The SET pulse will be significantly broadened in the 2T inverter chain while will be compressed in the 3T inverter chain as temperature increases. The investigation provides a new insight into the SET mitigation under the extreme environment, where both the high temperature and the single event effects should be considered. The 3T inverter layout structure （or similar layout structures） will be a better solution for spaceborne integrated circuit design for extreme environments.
基金financially supported by the National Natural Science Foundation of China(52372191)the Natural Science Foundation of Xiamen,China(3502Z202372036)+1 种基金the China Postdoctoral Science Foundation(2022TQ0282)the support of the High-Performance Computing Center(HPCC)at Harbin Institute of Technology on first-principles calculations。
文摘It is challenging for aqueous Zn-ion batteries(ZIBs)to achieve comparable low-temperature(low-T)performance due to the easy-frozen electrolyte and severe Zn dendrites.Herein,an aqueous electrolyte with a low freezing point and high ionic conductivity is proposed.Combined with molecular dynamics simulation and multi-scale interface analysis(time of flight secondary ion mass spectrometry threedimensional mapping and in-situ electrochemical impedance spectroscopy method),the temperature independence of the V_(2)O_(5)cathode and Zn anode is observed to be opposite.Surprisingly,dominated by the solvent structure of the designed electrolyte at low temperatures,vanadium dissolution/shuttle is significantly inhibited,and the zinc dendrites caused by this electrochemical crosstalk are greatly relieved,thus showing an abnormal temperature inversion effect.Through the disclosure and improvement of the above phenomena,the designed Zn||V_(2)O_(5)full cell delivers superior low-T performance,maintaining almost 99%capacity retention after 9500 cycles(working more than 2500 h)at-20°C.This work proposes a kind of electrolyte suitable for low-T ZIBs and reveals the inverse temperature dependence of the Zn anode,which might offer a novel perspective for the investigation of low-T aqueous battery systems.
文摘This paper deals with finite element study of the scanning induction heating of the magnetic steel sheets in transversal flux devices,taking into account the magnetic nonlinearity and the dependence on temperature of steel properties.The decrease of the non-uniformity of the transversal profile of sheet heating as effect of the magnetic or electromagnetic screening of the sheet lateral sides was proved.
