Famatinite(Cu_(3)SbS_(4),p-type)and chalcopyrite(CuFeS_(2),n-type)are well-recognized sustainable minerals with good intermediate-temperature thermoelectric performance.In this article,we utilize the inherent thermoel...Famatinite(Cu_(3)SbS_(4),p-type)and chalcopyrite(CuFeS_(2),n-type)are well-recognized sustainable minerals with good intermediate-temperature thermoelectric performance.In this article,we utilize the inherent thermoelectric properties of these compounds to demonstrate real-time operational performance as a coupled thermoelectric generator(TEG)for waste heat recovery applications.First,we synthesized the polycrystalline and nano-grained famatinite and chalcopyrite materials with high purity through a sustainable synthesis process of mechanical alloying followed by hot pressing.A maximum output power of~5 mW by the developed TEG was demonstrated while harvesting from a waste heat source of 723 K.Furthermore,the TEG performance via computational simulations for varied thermal gradients was validated.Our results highlight the sustainable development of thermoelectric power generator from earth-abundant minerals having strong stability and capacity to convert waste heat to electricity,which opens a new direction for fabricating a low-cost TEG for intermediate-temperature applications.展开更多
基金supported by the Research Grants Council of Hong Kong Special Administrative Region under the Faculty Development Scheme Project no:UGC/FDS16/E01/23.
文摘Famatinite(Cu_(3)SbS_(4),p-type)and chalcopyrite(CuFeS_(2),n-type)are well-recognized sustainable minerals with good intermediate-temperature thermoelectric performance.In this article,we utilize the inherent thermoelectric properties of these compounds to demonstrate real-time operational performance as a coupled thermoelectric generator(TEG)for waste heat recovery applications.First,we synthesized the polycrystalline and nano-grained famatinite and chalcopyrite materials with high purity through a sustainable synthesis process of mechanical alloying followed by hot pressing.A maximum output power of~5 mW by the developed TEG was demonstrated while harvesting from a waste heat source of 723 K.Furthermore,the TEG performance via computational simulations for varied thermal gradients was validated.Our results highlight the sustainable development of thermoelectric power generator from earth-abundant minerals having strong stability and capacity to convert waste heat to electricity,which opens a new direction for fabricating a low-cost TEG for intermediate-temperature applications.
