This paper considers the uniform parallel machine scheduling problem with unequal release dates and delivery times to minimize the maximum completion time.For this NP-hard problem,the largest sum of release date,proce...This paper considers the uniform parallel machine scheduling problem with unequal release dates and delivery times to minimize the maximum completion time.For this NP-hard problem,the largest sum of release date,processing time and delivery time first rule is designed to determine a certain machine for each job,and the largest difference between delivery time and release date first rule is designed to sequence the jobs scheduled on the same machine,and then a novel algorithm for the scheduling problem is built.To evaluate the performance of the proposed algorithm,a lower bound for the problem is proposed.The accuracy of the proposed algorithm is tested based on the data with problem size varying from 200 jobs to 600 jobs.The computational results indicate that the average relative error between the proposed algorithm and the lower bound is only 0.667%,therefore the solutions obtained by the proposed algorithm are very accurate.展开更多
The steady flow field of a canard missile on different angles of attack and Mach numbers were studied. Based on analysis, a method was proposed to reduce the calculation for the rolling characteristics of the canard m...The steady flow field of a canard missile on different angles of attack and Mach numbers were studied. Based on analysis, a method was proposed to reduce the calculation for the rolling characteristics of the canard missile with free-spinning tails, and was tested to obtain the relations between rolling moment coefficient, Mach number, and angle of attack. All the computed rolling moment coefficients obtained from the proposed method greatly agreed with the experimental results of FD-06 wind tunnel in CAAA, which proved that the method can not only reduce the calculation cost but also keep precision in calculating the rolling characteristics of canard missiles.展开更多
There is a pressing need for developing in vivo or ex vivo assays to screen the glucocorticoid（GC） signaling disruption of chemicals. Thus, we aimed to establish an ex vivo assay for screening GC signaling disruptio...There is a pressing need for developing in vivo or ex vivo assays to screen the glucocorticoid（GC） signaling disruption of chemicals. Thus, we aimed to establish an ex vivo assay for screening GC signaling disruption based on the GC-response gene transcription in Xenopus laevis tails cultured ex vivo. Firstly, we investigated effects of corticosterone（CORT, a main GC in frogs） on GC-response gene expression, and determined the six genes as molecular endpoints for assaying the GC signaling disruption. CORT in the range of 1.56–400 nmol/L was found to up-regulate transcription of the six GC-response genes, exhibiting comparable or higher sensitivity than previously reported assays. To validate this ex vivo assay, then, we examined effects of dexamethasone（a known GC signaling agonist） on GC-response gene expression. Dexamethasone displayed an agonistic action in a concentration-dependent manner, further demonstrating the efficiency of the established assay. Finally, we applied the ex vivo assay to evaluate the GC signaling disruption of bisphenol A（BPA）. In accordance with previous reports, we found a concentration-dependent agonistic activity of BPA,showing that the established assay is effective for detecting the GC signaling disrupting activity of environmental chemicals. Correspondingly, the GC signaling agonistic actions of CORT and BPA in ex vivo tails accorded with the observations in vivo, indicating that the ex vivo assay is able to detect the actions of chemicals in vivo. Overall, we established an ex vivo assay that can effectively screen GC signaling disruption of environmental chemicals.展开更多
The rare earth elements (REE) include the group of 15 lanthanides, scandium and yttrium and have diverse applications in technological and nuclear areas. The existence of REE in massive solid mining wastes generated i...The rare earth elements (REE) include the group of 15 lanthanides, scandium and yttrium and have diverse applications in technological and nuclear areas. The existence of REE in massive solid mining wastes generated in leaching processes of copper minerals in the Atacama region of Chile generates the possibility of creating added value to the treatment of this type of waste and supporting the development of a circular economy, generating a useful by-product in different industries. In order to know the behavior of these elements present in the solid carrier waste, a leaching process was carried out by using two agents separately, corresponding to hydrochloric and nitric acid. The technical feasibility to recover REE from carrier tail was demonstrated, the best leaching agent for these elements being a hydrochloric solution, obtaining a maximum recovery efficiency of 64.5%, for an acid concentration: 3M, temperature: 40<span style="white-space:nowrap;">°</span>C and (liquid/solid) ratio: 4. Lanthanum and cerium present the best individual recoveries compared to the other REE, with a maximum efficiency for a hydrochloric solution of 75.7% and 70.0%, respectively. The interaction of operational parameters that most influence the REE recovery corresponds to the temperature and the (liquid/solid) ratio. After 4 hours of leaching, REE recovery efficiencies remain practically constant. Acid consumptions correspond to 11 (kg HCl/ton mining tail) and 29 (kg HNO<sub>3</sub>/ton mining tail). The highest amount recovery ratios of these elements correspond to 0.355 and 0.224 (kg REE/ton mining tail), for hydrochloric and nitric solutions, respectively. These results influence the types of reagents and parameters to be studied in the following stages of the global process.展开更多
Approximately 3.44 billion tons of copper mine tailings(MT)were produced globally in 2018 with an increase of 45%from 2010.Significant efforts are being made to manage these tailings through storage facilities,recycli...Approximately 3.44 billion tons of copper mine tailings(MT)were produced globally in 2018 with an increase of 45%from 2010.Significant efforts are being made to manage these tailings through storage facilities,recycling,and reuse in different industries.Currently,a large portion of tailings are managed through the tailing storage facilities(TSF)where these tailings undergo hydro-thermal-mechanical stresses with seasonal cycles which are not comprehensively understood.This study presents an investigative study to evaluate the performance of control and cement-stabilized copper MT under the influence of seasonal cycles,freeze-thaw(F-T)and wet-dry(W-D)conditions,representing the seasonal variability in the cold and arid regions.The control and cement-stabilized MT samples were subjected to a maximum of 12 F-T and 12 W-D cycles and corresponding micro-and-macro behavior was investigated through scanning electron microscope(SEM),volumetric strain(εvT,wet density(r),moisture content loss,and unconfined compressive strength(UCS)tests.The results indicated the vulnerability of Copper MT to 67%and 75%strength loss reaching residual states with 12 F-T and 8 W-D cycles,respectively.Whereas the stabilized MT retained 39%-55%and 16%-34%strength with F-T and W-D cycles,demonstrating increased durability.This research highlights the impact of seasonal cycles and corresponding strength-deformation characteristics of control and stabilized Copper MT in cold and arid regions.展开更多
Utilizing phosphorus tailings as the raw material for foam concrete is a key approach to achieving sustainable and efficient resource utilization.During the preparation of phosphorus tailings-based foam concrete,slurr...Utilizing phosphorus tailings as the raw material for foam concrete is a key approach to achieving sustainable and efficient resource utilization.During the preparation of phosphorus tailings-based foam concrete,slurry performance is critical to the successful production.Phosphorus tailings,cement and microsilica were used to prepare foam concrete slurry in this study.A rheometer was employed as a test tool to measure the variation of linear viscoelastic zone(LVR),viscosity,and yield stress of the slurries with different cement contents.The results indicate that the phosphorus tailings-cement-microsilica slurry exhibits shear-thinning properties,which aligns well with the Herschel-Bulkley model,showing a high degree of correlation.As the cement content increases,the energy storage modulus of the slurry rises,and the LVR length shows a nonlinear trend.The LVR reaches its maximum length of 0.04%when the cement content is 6 mass%or 8 mass%.The increment of the cement content leads to a more intricate internal network structure,which hinders the reconstruction rate of the flocculated structure after high-shear deformation.展开更多
Enhancing soil organic matter characteristics,ameliorating physical structure,mitigating heavy metal toxicity,and hastening mineral weathering processes are crucial approaches to accomplish the transition of tailings ...Enhancing soil organic matter characteristics,ameliorating physical structure,mitigating heavy metal toxicity,and hastening mineral weathering processes are crucial approaches to accomplish the transition of tailings substrate to a soil-like substrate.The incorporation of biomass co-pyrolysis and plant colonization has been established to be a significant factor in soil substrate formation and soil pollutant remediation.Despite this,there is presently an absence of research efforts aimed at synergistically utilizing these two technologies to expedite the process of mining tailings soil substrate formation.The current study aimed to investigate the underlying mechanism of geochemical changes and rapid mineral weathering during the process of transforming tailings substrate into a soil-like substrate,under the combined effects of biomass co-smoldering pyrolysis and plant colonization.The findings of this study suggest that the incorporation of smoldering pyrolysis and plant colonization induces a high-temperature effect and biological effects,which enhance the physical and chemical properties of tailings,while simultaneously accelerating the rate of mineral weathering.Notable improvements include the amelioration of extreme pH levels,nutrient enrichment,the formation of aggregates,and an increase in enzyme activity,all of which collectively demonstrate the successful attainment of tailings substrate reconstruction.Evidence of the acceleratedweathering was verified by phase and surfacemorphology analysis using X-ray diffraction and scanning electron microscopy.Discovered corrosion and fragmentation on the surface ofminerals.The weathering resulted in corrosion and fragmentation of the surface of the treated mineral.This study confirms that co-smoldering pyrolysis of biomass,combined with plant colonization,can effectively promote the transformation of tailings into soil-like substrates.This method has can effectively address the key challenges that have previously hindered sustainable development of the mining industry and provides a novel approach for ecological restoration of tailings deposits.展开更多
One of the major challenges in the application of microbially induced carbonate precipitation(MICP)is achieving"bacteria freedom",as it necessitates a substantial volume of bacterial solutions.Nevertheless,b...One of the major challenges in the application of microbially induced carbonate precipitation(MICP)is achieving"bacteria freedom",as it necessitates a substantial volume of bacterial solutions.Nevertheless,both insitu bacterial cultivation and transportation of bacterial solutions have proven to be inefficient.In this study,we suggested the utilization of bacteria in the form of dry powder,enabling easy on-site activation and achieving a relatively high urease activity.We conducted MICP curing experiments on gold mine tailings(GMT)using steel slag(SS)as an additive.The results showed that the average unconfined compressive strength(UCS)values of the tailings treated with MICP and MICP+SS reached 0.51 and 0.71 MPa,respectively.In addition,the average leaching reduction rates of Cu,Pb,Cr,Zn,and T-CN in GMT after MICP treatment reached 98.54%,100%,70.94%,59.25%,and 98.02%,respectively,and the average reduction rates after MICP+SS treatment reached 98.77%,100%,88.03%,72.59%,and 98.63%,respectively.SEM,XRD,FT-IR analyses,and ultra-deep field microscopy results confirmed that the MICP treatment produced calcite-based calcium carbonate that filled the inter-tailing pores and cemented them together,and the hydration mechanism was the main reason for the increased curing efficiency of SS.Our research findings demonstrate that bacterial powder can efficiently achieve the objectives of heavy metal removal and tailing solidification.This approach can substantially de-crease the expenses associated with bacterial cultivation and solution transportation,thereby playing a crucial role in advancing the practical implementation of MICP.展开更多
To recover the valuable elements in Bayan Obo tailings,Fe-Si bath smelting reduction was adopted to separate and enrich rare earth elements(REE),niobium and titanium from the REE-Nb-Ti-containing slag.The reduction re...To recover the valuable elements in Bayan Obo tailings,Fe-Si bath smelting reduction was adopted to separate and enrich rare earth elements(REE),niobium and titanium from the REE-Nb-Ti-containing slag.The reduction reaction process of the Fe-Si bath and the migration behavior of valuable elements in the solidification and crystallization process of silicothermic reduction tailings were investigated,and a treatment method for efficiently separating and enriching REE,Nb and Ti was explored.Thermodynamic analysis indicated that at 1600℃,with a 6 wt.%addition of Si as the reducing agent,the niobium oxide in the REE-Nb-Ti-containing slag could be selectively reduced to metallic Nb.In the Fe-Si bath reduction process,the Nb mass fraction in the metal phase increased with prolonged reaction time,peaking at 2.77%,while the Ti mass fraction consistently stayed below 0.12%.Lowering the w(CaO)/w(SiO_(2))enhanced the migration of Nb from slag to metal phase and reduced the Ti impurities.During solidification and crystallization,a significant quantity of perovskite precipitated from reduction tailings,with the REE dissolving into this perovskite.By adjusting the w(CaO)/w(SiO_(2))in tailings to 1.2-1.9 and maintaining a temperature of 1100℃for 4 h,the perovskite area fraction in the final slag could exceed 37%.Finally,a method was proposed to separate and enrich valuable elements in REE-Nb-Ti-containing slags via Fe-Si bath smelting reduction and crystallization control.展开更多
In recent years,train-tail swaying of 160 km/h electric multiple units(EMUs)inside single-line tunnels has been heavily researched,because the issue needs to be solved urgently.In this paper,a co-simulation model of v...In recent years,train-tail swaying of 160 km/h electric multiple units(EMUs)inside single-line tunnels has been heavily researched,because the issue needs to be solved urgently.In this paper,a co-simulation model of vortex-induced vibration(VIV)of the tail car body is established,and the aerodynamics of train-tail swaying is studied.The simulation results were confirmed through a field test of operating EMUs.Furthermore,the influence mechanism of train-tail swaying on the wake flow field is studied in detail through a wind-tunnel experiment and a simulation of a reduced-scaled train model.The results demonstrate that the aerodynamic force frequency(i.e.,vortex-induced frequency)of the train tail increases linearly with train speed.When the train runs at 130 km/h,with a small amplitude of train-tail swaying(within 10 mm),the vortex-induced frequency is 1.7 Hz,which primarily depends on the nose shape of the train tail.After the tail car body nose is extended,the vortex-induced frequency is decreased.As the swaying amplitude of the train tail increases(exceeding 25 mm),the separation point of the high-intensity vortex in the train wake shifts downstream to the nose tip,and the vortex-induced frequency shifts from 1.7 Hz to the nearby car body hunting(i.e.,the primary hunting)frequency of 1.3 Hz,which leads to the frequency-locking phenomenon of VIV,and the resonance intensifies train-tail swaying.For the motor vehicle of the train tail,optimization of the yaw damper to improve its primary hunting stability can effectively alleviate train-tail swaying inside single-line tunnels.Optimization of the tail car body nose shape reduces the amplitude of the vortex-induced force,thereby weakening the aerodynamic effect and solving the problem of train-tail swaying inside the single-line tunnels.展开更多
Non-aqueous emulsions have a wide range of applications in cosmetics,drug-controlled release,and the preparation of functional nanoparticles.However,due to the weaker polarity of non-aqueous solvents,these emulsions o...Non-aqueous emulsions have a wide range of applications in cosmetics,drug-controlled release,and the preparation of functional nanoparticles.However,due to the weaker polarity of non-aqueous solvents,these emulsions often exhibit inferior stability compared to their aqueous counterparts.In this experiment,the properties of quaternary ammonium surfactants in glycerol were investigated through surface tension measurements,to further enhance the stability of n-decane/glycerol emulsions,hydrophilic nanoparticles SiO_(2) were modified in situ using double tailed quaternary ammonium surfactants Di-C_(12)DAB and Di-C_(16)DAB.Stable n-decane/glycerol Pickering emulsions were successfully prepared.These emulsions were stable at 45℃for over six months,and no significant changes in droplet size occurred.The minimum droplet size of the emulsion was only 2-3μm.Contact angle measurements showed that the wettability of the silica surface was tremendously affected by the concentration and the alkyl chain length of the double-tailed surfactants.In the presence of Di-C_(12)DAB,the contact angle of glycerol on the silica surface increased monotonically with the surfactant concentration.This explains the phenomenon that the Pickering emulsions containing Di-C_(12)DAB and silica particles were stable within the contact angle range of 80°-120°.Comparatively,the contact angle of the glycerol on the silica surface in the presence of Di-C_(16)DAB first increased with surfactant concentrations and then decreased,reaching a maximum at 0.6 mmol/L.It can be concluded that Di-C_(12)DAB formed monolayers at the surface of silica particles within all investigated concentrations.On the contrary,Di-C_(16)DAB formed monolayers at concentrations below 0.6 mmol/L and formed double layers at concentrations above 0.6 mmol/L,leading to a non-monotonic change in the contact angle with respect to concentration.Using these stable non-aqueous Pickering emulsions as templates,polymer microspheres with a particle size of 2-3μm were successfully prepared with high yield.This work is helpful to expand the potential applications of non-aqueous emulsions in the encapsulation of drug,controlled release,material preparation,and cosmetic formulations.展开更多
A process for treating cyanide tailings was proposed.The process essentially implicates reduction smelting which involves volatilizing silver,lead,and zinc in the cyanide tailings at high temperatures.Meanwhile,gold a...A process for treating cyanide tailings was proposed.The process essentially implicates reduction smelting which involves volatilizing silver,lead,and zinc in the cyanide tailings at high temperatures.Meanwhile,gold and copper combine with the reduced iron to form a metal phase,allowing for the simultaneous recovery of polymetallic elements.The experimental results indicate that the process works optimally with a coke powder of 7.5 wt.%,an alkalinity of 1.0,a melting temperature of 1450℃,and a melting time of 60 min.Under these conditions,more than 99% of gold,77% of copper and 94% of iron are incorporated into pig iron.In the meantime,the volatilization rate of silver exceeds 90%,while lead and zinc are essentially completely volatilized.The primary component of the by-product smelting slag is akermanite,which exhibits lower leaching toxicity than the national standard and belongs to general solid waste.Additionally,taking the trapping process of iron to copper as a case study,the mechanism of iron trapping is methodically examined and divided into three processes:smelting reduction,migration capture,and condensation deposition.展开更多
This study used steel slag,fly ash,and metakaolin as raw materials(SFM materials)to create silica-alumina-based geopolymers that can solidify Hg^(2+)when activated with sodiumbased water glass.The experiments began wi...This study used steel slag,fly ash,and metakaolin as raw materials(SFM materials)to create silica-alumina-based geopolymers that can solidify Hg^(2+)when activated with sodiumbased water glass.The experiments began with a triangular lattice point mixing design experiment,and the results were fitted,analyzed,and predicted.The optimum SFM material mass ratio was found to be 70%steel slag,25%fly ash,and 5%metakaolin.The optimum modulus of the activator was identified by comparing the unconfined compressive strength and solidifying impact on Hg^(2+)of geosynthetics with different modulus.The SFM geopolymer was then applied in the form of potting to cure the granulated mercury tailings.The inclusion of 50%SFM material generated a geosynthetic that reduced mercury transport to the surface soil by roughly 90%.The mercury concentration of herbaceous plant samples was also reduced by 78%.It indicates that the SFM material can effectively attenuate the migration transformation of mercury.Finally,characterization methods such as XPS and FTIR were used to investigate the mechanism of Hg^(2+)solidification by geopolymers generated by SFM materials.The possible solidification mechanisms were proposed as alkaline environment-induced mercury precipitation,chemical bonding s,surface adsorption of Hg^(2+)and its precipitates by the geopolymer,and physical encapsulation.展开更多
Siderite tailings is a potentially cost-free iron(Fe)source for arsenic(As)fixation in hazardous arsenic-calcium residues(ACR)as stable scorodite.In this study,a pure siderite reagent was employed to investigate the m...Siderite tailings is a potentially cost-free iron(Fe)source for arsenic(As)fixation in hazardous arsenic-calcium residues(ACR)as stable scorodite.In this study,a pure siderite reagent was employed to investigate the mechanism and optimal conditions for As fixation in ACR via scorodite formation,while the waste siderite tailings were used to further demonstrate the cotreatment method.The cotreatment method starts with an introduction of sulfuric acid to the ACR for As extraction and gypsum precipitation,and is followed by the addition of H_(2)O_(2) to oxidize As(Ⅲ)in the extraction solutions and finalized by adding siderite with continuous air injection for scorodite formation.The dissolution-oxidation of siderite can slowly produce Fe(Ⅲ)to control aqueous As(V)-Fe(Ⅲ)precipitation supersaturation for continuous scorodite crystallization.Chemical analyses show that the extraction efficiency of As from the ACR reaches 94.55%,while the precipitation yield of extracted As via scorodite formation arrives at 99.63% and 99.47%,leading to fixation efficiency of 94.20% and 94.04% in terms of the total As in the ACR by using siderite reagent and tailings,respectively.The final solid products show desirable TCLP stability and long-term stability,meeting the requirement for safe storage(GB 5085.3-2007).XRD,FTIR,and TEM results reveal that such high stability is attributable to the formation of scorodite and the surface adsorption of As on the raw siderite and secondary maghemite.This innovative and economical application of siderite tailings for the treatment of hazardous ACR can be extended to the management of hydrometallurgical wastes.展开更多
Gecko-inspired robots have significant potential applications;however,deviations in the yaw direction during locomotion are inevitable for legged robots that lack external sensing.These deviations cause the robot to s...Gecko-inspired robots have significant potential applications;however,deviations in the yaw direction during locomotion are inevitable for legged robots that lack external sensing.These deviations cause the robot to stray from its intended path.Therefore,a cost-effective and straightforward solution is essential for reducing this deviation.In nature,the tail is often used to maintain balance and stability.Similarly,it has been used in robots to improve manoeuvrability and stability.Our aim is to reduce this deviation using a morphological computation approach,specifically by adding a tail.To test this hypothesis,we investigated four different tails(rigid plate,rigid gecko-shaped,soft plate,and soft gecko-shaped)and assessed the deviation of the robot with these tails on different slopes.Additionally,to evaluate the influence of different tail parameters,such as material,shape,and linkage,we investigated the locomotion performance in terms of the robot's climbing speed on slopes,its ability to turn at narrow corners,and the resistance of the tails to external disturbances.A new auto-reset joint was designed to ensure that a disturbed tail could be quickly reset.Our results demonstrate that the yaw deviation of the robot can be reduced by applying a tail.Among the four tails,the soft gecko-shaped tail was the most effective for most tasks.In summary,our findings demonstrate the functional role of the tail in reducing yaw deviation,improving climbing ability and stability and provide a reference for selecting the most suitable tail for geckoinspired robots.展开更多
The rapid development of novel energy materials has led to a sustained surge in the global demand for fluorine.Fluorite is the primary source of fluorine globally and is increasingly being exploited.The estimated annu...The rapid development of novel energy materials has led to a sustained surge in the global demand for fluorine.Fluorite is the primary source of fluorine globally and is increasingly being exploited.The estimated annual production of fluorite worldwide is approximately 8 million tons,with an additional 5 million tons of fluorite tailings.This accumulation not only consumes land resources,but also contributes to dust generation and F-percolation,leading to water and air contamination.This paper comprehensively reviews the utilization methods of fluorite tailings,including the flotation recovery of quartz and fluorite,the preparation of cement mineralizing agents,and the preparation of concrete mineral additives,autoclaved lime sand brick,and glass-ceramics.Furthermore,potential future applications and research directions are proposed,including the comprehensive recovery of valuable minerals,auxiliary cementitious materials preparation,and the functionalization of glass-ceramics.This study can serve as a reference for expediting the utilization of fluorite tailings,promoting the development of tailing-free mines,and establishing sustainable development strategies.展开更多
The problems of tailings storage and high-stress conditions in deep mining have emerged as critical factors that limit the security,efficiency,and sustainability of such mines.This study explores the potential to util...The problems of tailings storage and high-stress conditions in deep mining have emerged as critical factors that limit the security,efficiency,and sustainability of such mines.This study explores the potential to utilize tungsten tailings to create cementitious backfill(CTB)materials and investigates the macroscopic strength features and microscopic damage evolution mechanisms of different-sized CTBs with varying dosages of hydroxypropyl methyl cellulose(HPMC).Specimens with bottom diameters of 50,75,and 100 mm are combined with HPMC dosages of 0,0.15wt%,0.25wt%,and 0.35wt%.A diameter/height ratio of 1:2 is maintained for all CTB specimens.The experimental results show that as the HPMC dosage is increased from 0 to 0.35wt%,the uniaxial compressive strength(UCS)of the CTBs decreases significantly in a linear manner.The 75 mm×150 mm CTB specimen exhibits relatively high plasticity and toughness,with good plastic deformation and energy absorption capabilities,indicating significant size effects.HPMC introduces connected bubbles during the CTB pouring process,but it exhibits anti-segregation and anti-bleeding characteristics,thus reducing tailing settling.The hydration reaction of the CTB doped with HPMC is more uniform,and the Ca/Si atomic ratio dispersion at different sites is smaller.The three CTB sizes all exhibit combined tensile and shear failure,with the 75 mm×150 mm specimen exhibiting macroscopic tensile cracks and relatively few shear cracks.At the micro-scale,excessive ettringite and hydrated calcium silicate are interwoven and fuse,and the tungsten tailings are tightly wrapped.These results provide valuable data and notional insights for optimizing the fluidity of the backfill,and elucidate the strength and damage evolution of solidified materials during filling and extraction.This study contributes to the advancement of green,economical,safe,and sustainable mining practices.展开更多
基金supported by the National Natural Science Foundation of China (7087103290924021+2 种基金70971035)the National High Technology Research and Development Program of China (863 Program) (2008AA042901)Anhui Provincial Natural Science Foundation (11040606Q27)
文摘This paper considers the uniform parallel machine scheduling problem with unequal release dates and delivery times to minimize the maximum completion time.For this NP-hard problem,the largest sum of release date,processing time and delivery time first rule is designed to determine a certain machine for each job,and the largest difference between delivery time and release date first rule is designed to sequence the jobs scheduled on the same machine,and then a novel algorithm for the scheduling problem is built.To evaluate the performance of the proposed algorithm,a lower bound for the problem is proposed.The accuracy of the proposed algorithm is tested based on the data with problem size varying from 200 jobs to 600 jobs.The computational results indicate that the average relative error between the proposed algorithm and the lower bound is only 0.667%,therefore the solutions obtained by the proposed algorithm are very accurate.
基金Sponsored by the Fundamental Research Funds for the Central Universities(Grant No.HEUCFG201815)
文摘The steady flow field of a canard missile on different angles of attack and Mach numbers were studied. Based on analysis, a method was proposed to reduce the calculation for the rolling characteristics of the canard missile with free-spinning tails, and was tested to obtain the relations between rolling moment coefficient, Mach number, and angle of attack. All the computed rolling moment coefficients obtained from the proposed method greatly agreed with the experimental results of FD-06 wind tunnel in CAAA, which proved that the method can not only reduce the calculation cost but also keep precision in calculating the rolling characteristics of canard missiles.
基金supported by the National Natural Science Foundation of China (No. 21377153)the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB14040102)
文摘There is a pressing need for developing in vivo or ex vivo assays to screen the glucocorticoid（GC） signaling disruption of chemicals. Thus, we aimed to establish an ex vivo assay for screening GC signaling disruption based on the GC-response gene transcription in Xenopus laevis tails cultured ex vivo. Firstly, we investigated effects of corticosterone（CORT, a main GC in frogs） on GC-response gene expression, and determined the six genes as molecular endpoints for assaying the GC signaling disruption. CORT in the range of 1.56–400 nmol/L was found to up-regulate transcription of the six GC-response genes, exhibiting comparable or higher sensitivity than previously reported assays. To validate this ex vivo assay, then, we examined effects of dexamethasone（a known GC signaling agonist） on GC-response gene expression. Dexamethasone displayed an agonistic action in a concentration-dependent manner, further demonstrating the efficiency of the established assay. Finally, we applied the ex vivo assay to evaluate the GC signaling disruption of bisphenol A（BPA）. In accordance with previous reports, we found a concentration-dependent agonistic activity of BPA,showing that the established assay is effective for detecting the GC signaling disrupting activity of environmental chemicals. Correspondingly, the GC signaling agonistic actions of CORT and BPA in ex vivo tails accorded with the observations in vivo, indicating that the ex vivo assay is able to detect the actions of chemicals in vivo. Overall, we established an ex vivo assay that can effectively screen GC signaling disruption of environmental chemicals.
文摘The rare earth elements (REE) include the group of 15 lanthanides, scandium and yttrium and have diverse applications in technological and nuclear areas. The existence of REE in massive solid mining wastes generated in leaching processes of copper minerals in the Atacama region of Chile generates the possibility of creating added value to the treatment of this type of waste and supporting the development of a circular economy, generating a useful by-product in different industries. In order to know the behavior of these elements present in the solid carrier waste, a leaching process was carried out by using two agents separately, corresponding to hydrochloric and nitric acid. The technical feasibility to recover REE from carrier tail was demonstrated, the best leaching agent for these elements being a hydrochloric solution, obtaining a maximum recovery efficiency of 64.5%, for an acid concentration: 3M, temperature: 40<span style="white-space:nowrap;">°</span>C and (liquid/solid) ratio: 4. Lanthanum and cerium present the best individual recoveries compared to the other REE, with a maximum efficiency for a hydrochloric solution of 75.7% and 70.0%, respectively. The interaction of operational parameters that most influence the REE recovery corresponds to the temperature and the (liquid/solid) ratio. After 4 hours of leaching, REE recovery efficiencies remain practically constant. Acid consumptions correspond to 11 (kg HCl/ton mining tail) and 29 (kg HNO<sub>3</sub>/ton mining tail). The highest amount recovery ratios of these elements correspond to 0.355 and 0.224 (kg REE/ton mining tail), for hydrochloric and nitric solutions, respectively. These results influence the types of reagents and parameters to be studied in the following stages of the global process.
基金the W.M.Keck Center for Nano-Scale Imaging in the Department of Chemistry and Biochemistry at the University of Arizona(Grant No.RRID:SCR_022884),with funding from the W.M.Keck Foundation Grant.
文摘Approximately 3.44 billion tons of copper mine tailings(MT)were produced globally in 2018 with an increase of 45%from 2010.Significant efforts are being made to manage these tailings through storage facilities,recycling,and reuse in different industries.Currently,a large portion of tailings are managed through the tailing storage facilities(TSF)where these tailings undergo hydro-thermal-mechanical stresses with seasonal cycles which are not comprehensively understood.This study presents an investigative study to evaluate the performance of control and cement-stabilized copper MT under the influence of seasonal cycles,freeze-thaw(F-T)and wet-dry(W-D)conditions,representing the seasonal variability in the cold and arid regions.The control and cement-stabilized MT samples were subjected to a maximum of 12 F-T and 12 W-D cycles and corresponding micro-and-macro behavior was investigated through scanning electron microscope(SEM),volumetric strain(εvT,wet density(r),moisture content loss,and unconfined compressive strength(UCS)tests.The results indicated the vulnerability of Copper MT to 67%and 75%strength loss reaching residual states with 12 F-T and 8 W-D cycles,respectively.Whereas the stabilized MT retained 39%-55%and 16%-34%strength with F-T and W-D cycles,demonstrating increased durability.This research highlights the impact of seasonal cycles and corresponding strength-deformation characteristics of control and stabilized Copper MT in cold and arid regions.
基金Hubei Provincial Key Research Program Project(2023BCB099).
文摘Utilizing phosphorus tailings as the raw material for foam concrete is a key approach to achieving sustainable and efficient resource utilization.During the preparation of phosphorus tailings-based foam concrete,slurry performance is critical to the successful production.Phosphorus tailings,cement and microsilica were used to prepare foam concrete slurry in this study.A rheometer was employed as a test tool to measure the variation of linear viscoelastic zone(LVR),viscosity,and yield stress of the slurries with different cement contents.The results indicate that the phosphorus tailings-cement-microsilica slurry exhibits shear-thinning properties,which aligns well with the Herschel-Bulkley model,showing a high degree of correlation.As the cement content increases,the energy storage modulus of the slurry rises,and the LVR length shows a nonlinear trend.The LVR reaches its maximum length of 0.04%when the cement content is 6 mass%or 8 mass%.The increment of the cement content leads to a more intricate internal network structure,which hinders the reconstruction rate of the flocculated structure after high-shear deformation.
基金supported by the National Natural Science Foundation of China(No.52060011).
文摘Enhancing soil organic matter characteristics,ameliorating physical structure,mitigating heavy metal toxicity,and hastening mineral weathering processes are crucial approaches to accomplish the transition of tailings substrate to a soil-like substrate.The incorporation of biomass co-pyrolysis and plant colonization has been established to be a significant factor in soil substrate formation and soil pollutant remediation.Despite this,there is presently an absence of research efforts aimed at synergistically utilizing these two technologies to expedite the process of mining tailings soil substrate formation.The current study aimed to investigate the underlying mechanism of geochemical changes and rapid mineral weathering during the process of transforming tailings substrate into a soil-like substrate,under the combined effects of biomass co-smoldering pyrolysis and plant colonization.The findings of this study suggest that the incorporation of smoldering pyrolysis and plant colonization induces a high-temperature effect and biological effects,which enhance the physical and chemical properties of tailings,while simultaneously accelerating the rate of mineral weathering.Notable improvements include the amelioration of extreme pH levels,nutrient enrichment,the formation of aggregates,and an increase in enzyme activity,all of which collectively demonstrate the successful attainment of tailings substrate reconstruction.Evidence of the acceleratedweathering was verified by phase and surfacemorphology analysis using X-ray diffraction and scanning electron microscopy.Discovered corrosion and fragmentation on the surface ofminerals.The weathering resulted in corrosion and fragmentation of the surface of the treated mineral.This study confirms that co-smoldering pyrolysis of biomass,combined with plant colonization,can effectively promote the transformation of tailings into soil-like substrates.This method has can effectively address the key challenges that have previously hindered sustainable development of the mining industry and provides a novel approach for ecological restoration of tailings deposits.
基金supported by the Ordos City Science and Technology Major Project(2021ZD14-16)the National Key Research and Development Program(2018YFC1802904)the Discipline Signature Achievements of the Shanghai Polytechnic University(A10GY23G004-14).
文摘One of the major challenges in the application of microbially induced carbonate precipitation(MICP)is achieving"bacteria freedom",as it necessitates a substantial volume of bacterial solutions.Nevertheless,both insitu bacterial cultivation and transportation of bacterial solutions have proven to be inefficient.In this study,we suggested the utilization of bacteria in the form of dry powder,enabling easy on-site activation and achieving a relatively high urease activity.We conducted MICP curing experiments on gold mine tailings(GMT)using steel slag(SS)as an additive.The results showed that the average unconfined compressive strength(UCS)values of the tailings treated with MICP and MICP+SS reached 0.51 and 0.71 MPa,respectively.In addition,the average leaching reduction rates of Cu,Pb,Cr,Zn,and T-CN in GMT after MICP treatment reached 98.54%,100%,70.94%,59.25%,and 98.02%,respectively,and the average reduction rates after MICP+SS treatment reached 98.77%,100%,88.03%,72.59%,and 98.63%,respectively.SEM,XRD,FT-IR analyses,and ultra-deep field microscopy results confirmed that the MICP treatment produced calcite-based calcium carbonate that filled the inter-tailing pores and cemented them together,and the hydration mechanism was the main reason for the increased curing efficiency of SS.Our research findings demonstrate that bacterial powder can efficiently achieve the objectives of heavy metal removal and tailing solidification.This approach can substantially de-crease the expenses associated with bacterial cultivation and solution transportation,thereby playing a crucial role in advancing the practical implementation of MICP.
基金supported by the National Key R&D Program of China(No.2021YFC2901200)National Natural Science Foundation of China(Nos.52174383 and 52374412)Liaoning Provincial Natural Science Foundation of China(No.2022-YQ-09).
文摘To recover the valuable elements in Bayan Obo tailings,Fe-Si bath smelting reduction was adopted to separate and enrich rare earth elements(REE),niobium and titanium from the REE-Nb-Ti-containing slag.The reduction reaction process of the Fe-Si bath and the migration behavior of valuable elements in the solidification and crystallization process of silicothermic reduction tailings were investigated,and a treatment method for efficiently separating and enriching REE,Nb and Ti was explored.Thermodynamic analysis indicated that at 1600℃,with a 6 wt.%addition of Si as the reducing agent,the niobium oxide in the REE-Nb-Ti-containing slag could be selectively reduced to metallic Nb.In the Fe-Si bath reduction process,the Nb mass fraction in the metal phase increased with prolonged reaction time,peaking at 2.77%,while the Ti mass fraction consistently stayed below 0.12%.Lowering the w(CaO)/w(SiO_(2))enhanced the migration of Nb from slag to metal phase and reduced the Ti impurities.During solidification and crystallization,a significant quantity of perovskite precipitated from reduction tailings,with the REE dissolving into this perovskite.By adjusting the w(CaO)/w(SiO_(2))in tailings to 1.2-1.9 and maintaining a temperature of 1100℃for 4 h,the perovskite area fraction in the final slag could exceed 37%.Finally,a method was proposed to separate and enrich valuable elements in REE-Nb-Ti-containing slags via Fe-Si bath smelting reduction and crystallization control.
基金supported by the National Natural Science Foundation of China(Nos.52372403 and U2268211)the Natural Science Foundation of Sichuan Province(No.2022NSFSC0034),China+1 种基金the National Railway Group Science and Technology Program(No.2023J071)the Traction Power State Key Laboratory of the Independent Research and Development Projects(No.2022TPL-T02),China.
文摘In recent years,train-tail swaying of 160 km/h electric multiple units(EMUs)inside single-line tunnels has been heavily researched,because the issue needs to be solved urgently.In this paper,a co-simulation model of vortex-induced vibration(VIV)of the tail car body is established,and the aerodynamics of train-tail swaying is studied.The simulation results were confirmed through a field test of operating EMUs.Furthermore,the influence mechanism of train-tail swaying on the wake flow field is studied in detail through a wind-tunnel experiment and a simulation of a reduced-scaled train model.The results demonstrate that the aerodynamic force frequency(i.e.,vortex-induced frequency)of the train tail increases linearly with train speed.When the train runs at 130 km/h,with a small amplitude of train-tail swaying(within 10 mm),the vortex-induced frequency is 1.7 Hz,which primarily depends on the nose shape of the train tail.After the tail car body nose is extended,the vortex-induced frequency is decreased.As the swaying amplitude of the train tail increases(exceeding 25 mm),the separation point of the high-intensity vortex in the train wake shifts downstream to the nose tip,and the vortex-induced frequency shifts from 1.7 Hz to the nearby car body hunting(i.e.,the primary hunting)frequency of 1.3 Hz,which leads to the frequency-locking phenomenon of VIV,and the resonance intensifies train-tail swaying.For the motor vehicle of the train tail,optimization of the yaw damper to improve its primary hunting stability can effectively alleviate train-tail swaying inside single-line tunnels.Optimization of the tail car body nose shape reduces the amplitude of the vortex-induced force,thereby weakening the aerodynamic effect and solving the problem of train-tail swaying inside the single-line tunnels.
文摘Non-aqueous emulsions have a wide range of applications in cosmetics,drug-controlled release,and the preparation of functional nanoparticles.However,due to the weaker polarity of non-aqueous solvents,these emulsions often exhibit inferior stability compared to their aqueous counterparts.In this experiment,the properties of quaternary ammonium surfactants in glycerol were investigated through surface tension measurements,to further enhance the stability of n-decane/glycerol emulsions,hydrophilic nanoparticles SiO_(2) were modified in situ using double tailed quaternary ammonium surfactants Di-C_(12)DAB and Di-C_(16)DAB.Stable n-decane/glycerol Pickering emulsions were successfully prepared.These emulsions were stable at 45℃for over six months,and no significant changes in droplet size occurred.The minimum droplet size of the emulsion was only 2-3μm.Contact angle measurements showed that the wettability of the silica surface was tremendously affected by the concentration and the alkyl chain length of the double-tailed surfactants.In the presence of Di-C_(12)DAB,the contact angle of glycerol on the silica surface increased monotonically with the surfactant concentration.This explains the phenomenon that the Pickering emulsions containing Di-C_(12)DAB and silica particles were stable within the contact angle range of 80°-120°.Comparatively,the contact angle of the glycerol on the silica surface in the presence of Di-C_(16)DAB first increased with surfactant concentrations and then decreased,reaching a maximum at 0.6 mmol/L.It can be concluded that Di-C_(12)DAB formed monolayers at the surface of silica particles within all investigated concentrations.On the contrary,Di-C_(16)DAB formed monolayers at concentrations below 0.6 mmol/L and formed double layers at concentrations above 0.6 mmol/L,leading to a non-monotonic change in the contact angle with respect to concentration.Using these stable non-aqueous Pickering emulsions as templates,polymer microspheres with a particle size of 2-3μm were successfully prepared with high yield.This work is helpful to expand the potential applications of non-aqueous emulsions in the encapsulation of drug,controlled release,material preparation,and cosmetic formulations.
基金supported by the National Key R&D Program of China(No.2020YFC1909203)the Hunan Provincial Innovation Project,China(No.CX20230213)。
文摘A process for treating cyanide tailings was proposed.The process essentially implicates reduction smelting which involves volatilizing silver,lead,and zinc in the cyanide tailings at high temperatures.Meanwhile,gold and copper combine with the reduced iron to form a metal phase,allowing for the simultaneous recovery of polymetallic elements.The experimental results indicate that the process works optimally with a coke powder of 7.5 wt.%,an alkalinity of 1.0,a melting temperature of 1450℃,and a melting time of 60 min.Under these conditions,more than 99% of gold,77% of copper and 94% of iron are incorporated into pig iron.In the meantime,the volatilization rate of silver exceeds 90%,while lead and zinc are essentially completely volatilized.The primary component of the by-product smelting slag is akermanite,which exhibits lower leaching toxicity than the national standard and belongs to general solid waste.Additionally,taking the trapping process of iron to copper as a case study,the mechanism of iron trapping is methodically examined and divided into three processes:smelting reduction,migration capture,and condensation deposition.
基金supported by the National Key R&D Projects of China(No.2018YFC1801706-01)the National Natural Science Foundation of China(No.22162007)+2 种基金the Science and Technology Supporting Project of Guizhou Province(No.[2021]480,[2023]379)the Wengfu(Group)Co.,Ltd.Technology Development Project(No.WH-220787(YF))the Project from Guizhou Institute of Innovation and Development of Dual-carbon and New Energy Technologies(No.DCRE-2023-05)。
文摘This study used steel slag,fly ash,and metakaolin as raw materials(SFM materials)to create silica-alumina-based geopolymers that can solidify Hg^(2+)when activated with sodiumbased water glass.The experiments began with a triangular lattice point mixing design experiment,and the results were fitted,analyzed,and predicted.The optimum SFM material mass ratio was found to be 70%steel slag,25%fly ash,and 5%metakaolin.The optimum modulus of the activator was identified by comparing the unconfined compressive strength and solidifying impact on Hg^(2+)of geosynthetics with different modulus.The SFM geopolymer was then applied in the form of potting to cure the granulated mercury tailings.The inclusion of 50%SFM material generated a geosynthetic that reduced mercury transport to the surface soil by roughly 90%.The mercury concentration of herbaceous plant samples was also reduced by 78%.It indicates that the SFM material can effectively attenuate the migration transformation of mercury.Finally,characterization methods such as XPS and FTIR were used to investigate the mechanism of Hg^(2+)solidification by geopolymers generated by SFM materials.The possible solidification mechanisms were proposed as alkaline environment-induced mercury precipitation,chemical bonding s,surface adsorption of Hg^(2+)and its precipitates by the geopolymer,and physical encapsulation.
基金supported by the National Natural Science Foundation of China(Nos.42207258 and 52270150)the Liaoning Provincial Natural Science Foundation Program Project(No.2022-BS-312)+1 种基金the Liaoning University of Technology Doctoral Research Start-up Fund Project(No.XB2021013)the Shenyang Youth Science and Technology Project(No.RC210166).
文摘Siderite tailings is a potentially cost-free iron(Fe)source for arsenic(As)fixation in hazardous arsenic-calcium residues(ACR)as stable scorodite.In this study,a pure siderite reagent was employed to investigate the mechanism and optimal conditions for As fixation in ACR via scorodite formation,while the waste siderite tailings were used to further demonstrate the cotreatment method.The cotreatment method starts with an introduction of sulfuric acid to the ACR for As extraction and gypsum precipitation,and is followed by the addition of H_(2)O_(2) to oxidize As(Ⅲ)in the extraction solutions and finalized by adding siderite with continuous air injection for scorodite formation.The dissolution-oxidation of siderite can slowly produce Fe(Ⅲ)to control aqueous As(V)-Fe(Ⅲ)precipitation supersaturation for continuous scorodite crystallization.Chemical analyses show that the extraction efficiency of As from the ACR reaches 94.55%,while the precipitation yield of extracted As via scorodite formation arrives at 99.63% and 99.47%,leading to fixation efficiency of 94.20% and 94.04% in terms of the total As in the ACR by using siderite reagent and tailings,respectively.The final solid products show desirable TCLP stability and long-term stability,meeting the requirement for safe storage(GB 5085.3-2007).XRD,FTIR,and TEM results reveal that such high stability is attributable to the formation of scorodite and the surface adsorption of As on the raw siderite and secondary maghemite.This innovative and economical application of siderite tailings for the treatment of hazardous ACR can be extended to the management of hydrometallurgical wastes.
基金supported by the National Key Research&Development Program of China(Grant No.2020YFB1313504)the State Key Laboratory of Mechanics and Control for Aerospace Structures of Nanjing University of Aeronautics and Astronautics.
文摘Gecko-inspired robots have significant potential applications;however,deviations in the yaw direction during locomotion are inevitable for legged robots that lack external sensing.These deviations cause the robot to stray from its intended path.Therefore,a cost-effective and straightforward solution is essential for reducing this deviation.In nature,the tail is often used to maintain balance and stability.Similarly,it has been used in robots to improve manoeuvrability and stability.Our aim is to reduce this deviation using a morphological computation approach,specifically by adding a tail.To test this hypothesis,we investigated four different tails(rigid plate,rigid gecko-shaped,soft plate,and soft gecko-shaped)and assessed the deviation of the robot with these tails on different slopes.Additionally,to evaluate the influence of different tail parameters,such as material,shape,and linkage,we investigated the locomotion performance in terms of the robot's climbing speed on slopes,its ability to turn at narrow corners,and the resistance of the tails to external disturbances.A new auto-reset joint was designed to ensure that a disturbed tail could be quickly reset.Our results demonstrate that the yaw deviation of the robot can be reduced by applying a tail.Among the four tails,the soft gecko-shaped tail was the most effective for most tasks.In summary,our findings demonstrate the functional role of the tail in reducing yaw deviation,improving climbing ability and stability and provide a reference for selecting the most suitable tail for geckoinspired robots.
基金supported by the National Key Research and Development Program of China(No.2023YFC3903901)the Key Research and Development Program of Hubei Province,CHina(No.2022BAA029)the Science and Technology Project of Shaanxi Yanchang Petroleum(Group)Co.,Ltd.,China(No.yc-whlg-2023ky-03).
文摘The rapid development of novel energy materials has led to a sustained surge in the global demand for fluorine.Fluorite is the primary source of fluorine globally and is increasingly being exploited.The estimated annual production of fluorite worldwide is approximately 8 million tons,with an additional 5 million tons of fluorite tailings.This accumulation not only consumes land resources,but also contributes to dust generation and F-percolation,leading to water and air contamination.This paper comprehensively reviews the utilization methods of fluorite tailings,including the flotation recovery of quartz and fluorite,the preparation of cement mineralizing agents,and the preparation of concrete mineral additives,autoclaved lime sand brick,and glass-ceramics.Furthermore,potential future applications and research directions are proposed,including the comprehensive recovery of valuable minerals,auxiliary cementitious materials preparation,and the functionalization of glass-ceramics.This study can serve as a reference for expediting the utilization of fluorite tailings,promoting the development of tailing-free mines,and establishing sustainable development strategies.
基金National Key Research and Development Program of China(No.2022YFC2905004).
文摘The problems of tailings storage and high-stress conditions in deep mining have emerged as critical factors that limit the security,efficiency,and sustainability of such mines.This study explores the potential to utilize tungsten tailings to create cementitious backfill(CTB)materials and investigates the macroscopic strength features and microscopic damage evolution mechanisms of different-sized CTBs with varying dosages of hydroxypropyl methyl cellulose(HPMC).Specimens with bottom diameters of 50,75,and 100 mm are combined with HPMC dosages of 0,0.15wt%,0.25wt%,and 0.35wt%.A diameter/height ratio of 1:2 is maintained for all CTB specimens.The experimental results show that as the HPMC dosage is increased from 0 to 0.35wt%,the uniaxial compressive strength(UCS)of the CTBs decreases significantly in a linear manner.The 75 mm×150 mm CTB specimen exhibits relatively high plasticity and toughness,with good plastic deformation and energy absorption capabilities,indicating significant size effects.HPMC introduces connected bubbles during the CTB pouring process,but it exhibits anti-segregation and anti-bleeding characteristics,thus reducing tailing settling.The hydration reaction of the CTB doped with HPMC is more uniform,and the Ca/Si atomic ratio dispersion at different sites is smaller.The three CTB sizes all exhibit combined tensile and shear failure,with the 75 mm×150 mm specimen exhibiting macroscopic tensile cracks and relatively few shear cracks.At the micro-scale,excessive ettringite and hydrated calcium silicate are interwoven and fuse,and the tungsten tailings are tightly wrapped.These results provide valuable data and notional insights for optimizing the fluidity of the backfill,and elucidate the strength and damage evolution of solidified materials during filling and extraction.This study contributes to the advancement of green,economical,safe,and sustainable mining practices.
