A new sodium borate-formate,Na_(3)B_(6)O_(10)(HCOO)(1),has been successfully synthesized in a surfactantthermal system.Compound 1 crystallizes in the orthorhombic system,with the polar P2_(1)2_(1)2_(1) space group and...A new sodium borate-formate,Na_(3)B_(6)O_(10)(HCOO)(1),has been successfully synthesized in a surfactantthermal system.Compound 1 crystallizes in the orthorhombic system,with the polar P2_(1)2_(1)2_(1) space group and the parameters a=7.6375(8)Å,b=9.9345(9)Å,c=12.7231(13)Å,V=965.36(17)Å^(3),and Z=4.Compound 1 contains basic building units of(B_(6)O_(13))^(8-),and each(B_(6)O_(13))^(8-)unit connects with six other neighboring units and forms a novel 3D open-framework with 9R channels.展开更多
基金supported by the National Natural Science Foundation of China(Grant 21975224).
文摘A new sodium borate-formate,Na_(3)B_(6)O_(10)(HCOO)(1),has been successfully synthesized in a surfactantthermal system.Compound 1 crystallizes in the orthorhombic system,with the polar P2_(1)2_(1)2_(1) space group and the parameters a=7.6375(8)Å,b=9.9345(9)Å,c=12.7231(13)Å,V=965.36(17)Å^(3),and Z=4.Compound 1 contains basic building units of(B_(6)O_(13))^(8-),and each(B_(6)O_(13))^(8-)unit connects with six other neighboring units and forms a novel 3D open-framework with 9R channels.
