Anionic dopants,such as O-atom vacancies,alter the thermochemical and kinetic parameters of proton coupled electron transfer(PCET)at metal oxide surfaces;understanding their impact(s)is essential for informed material...Anionic dopants,such as O-atom vacancies,alter the thermochemical and kinetic parameters of proton coupled electron transfer(PCET)at metal oxide surfaces;understanding their impact(s)is essential for informed material design for efficient energy conversion processes.To circumvent challenges associated with studying extended solids,we employ polyoxovanadate-alkoxide clusters as atomically precise models of reducible metal oxide surfaces.展开更多
基金funded by the National Science Foundation(CHE-2154727).
文摘Anionic dopants,such as O-atom vacancies,alter the thermochemical and kinetic parameters of proton coupled electron transfer(PCET)at metal oxide surfaces;understanding their impact(s)is essential for informed material design for efficient energy conversion processes.To circumvent challenges associated with studying extended solids,we employ polyoxovanadate-alkoxide clusters as atomically precise models of reducible metal oxide surfaces.
