Selective oxidation of amines to imines through electrocatalysis is an attractive and efficient way for the chemical industry to produce nitrile compounds,but it is limited by the difficulty of designing efficient cat...Selective oxidation of amines to imines through electrocatalysis is an attractive and efficient way for the chemical industry to produce nitrile compounds,but it is limited by the difficulty of designing efficient catalysts and lack of understanding the mechanism of catalysis.Herein,we demonstrate a novel strategy by generation of oxyhydroxide layers on two-dimensional iron-doped layered nickel phosphorus trisulfides(Ni1-xFexPS_(3))during the oxidation of benzylamine(BA).In-depth structural and surface chemical characterizations during the electrocatalytic process combined with theoretical calculations reveal that Ni(1-x)FexPS_(3) undergoes surface reconstruction under alkaline conditions to form the metal oxyhydroxide/phosphorus trichalcogenide(NiFeOOH/Ni1-xFexPS_(3))heterostructure.Interestingly,the generated heterointerface facilitates BA oxidation with a low onset potential of 1.39 V and Faradaic efficiency of 53%for benzonitrile(BN)synthesis.Theoretical calculations further indicate that the as-formed NiFeOOH/Ni1-xFexPS_(3) heterostructure could offer optimum free energy for BA adsorption and BN desorption,resulting in promising BN synthesis.展开更多
A new method for recovering shape from cross-sectional contours with complexbranching structures is presented. First, each branching problem by providing an intermediatecontour using distance function and image proces...A new method for recovering shape from cross-sectional contours with complexbranching structures is presented. First, each branching problem by providing an intermediatecontour using distance function and image processing technology is solved. Then, all contours aredivided into several groups of simple contours. For each group, a NURBS curve is fitted to contourpoints in each section within a given accuracy on a common knot vector. Finally, the NURBS surfaceskinning of these contours is performed for providing a smooth geometric model. The method issuitable to reproduce the object by NC machining or rapid prototyping. Some results demonstrate itsusefulness and feasibility.展开更多
基金National Natural Science Foundation of China,Grant/Award Number:22179029Fundamental Research Funds for the Central Universities,Grant/Award Number:buctrc202324+2 种基金Young Elite Scientists Sponsorship Program by BAST,Grant/Award Number:BYESS2023093Ministero dell'Istruzione,dell'Universitàe della Ricerca,Grant/Award Number:2022FNL89YKempestiftelserna。
文摘Selective oxidation of amines to imines through electrocatalysis is an attractive and efficient way for the chemical industry to produce nitrile compounds,but it is limited by the difficulty of designing efficient catalysts and lack of understanding the mechanism of catalysis.Herein,we demonstrate a novel strategy by generation of oxyhydroxide layers on two-dimensional iron-doped layered nickel phosphorus trisulfides(Ni1-xFexPS_(3))during the oxidation of benzylamine(BA).In-depth structural and surface chemical characterizations during the electrocatalytic process combined with theoretical calculations reveal that Ni(1-x)FexPS_(3) undergoes surface reconstruction under alkaline conditions to form the metal oxyhydroxide/phosphorus trichalcogenide(NiFeOOH/Ni1-xFexPS_(3))heterostructure.Interestingly,the generated heterointerface facilitates BA oxidation with a low onset potential of 1.39 V and Faradaic efficiency of 53%for benzonitrile(BN)synthesis.Theoretical calculations further indicate that the as-formed NiFeOOH/Ni1-xFexPS_(3) heterostructure could offer optimum free energy for BA adsorption and BN desorption,resulting in promising BN synthesis.
基金Provincial Natural Science Foundation of Liaoning,China (No.20010102087)
文摘A new method for recovering shape from cross-sectional contours with complexbranching structures is presented. First, each branching problem by providing an intermediatecontour using distance function and image processing technology is solved. Then, all contours aredivided into several groups of simple contours. For each group, a NURBS curve is fitted to contourpoints in each section within a given accuracy on a common knot vector. Finally, the NURBS surfaceskinning of these contours is performed for providing a smooth geometric model. The method issuitable to reproduce the object by NC machining or rapid prototyping. Some results demonstrate itsusefulness and feasibility.
