Deep-buried tunnels traversing complex hydrogeological zones with clay-sand-filled structures are highly susceptible to water inrush hazards.High ground temperature,high in-situ stress,and highwater pressure render th...Deep-buried tunnels traversing complex hydrogeological zones with clay-sand-filled structures are highly susceptible to water inrush hazards.High ground temperature,high in-situ stress,and highwater pressure render these events a complex thermohydro-mechanical coupling problem.However,current research on water inrush often insufficiently investigates the multi-field coupled instability mechanisms within highly permeable filling media and frequently neglects the influence of temperature.This study aims to investigate the evolutionary mechanism of seepage instability in filling structures that trigger water inrush hazards under the complex conditions of deep-buried tunnels.Laboratory tests were conducted using a large-scale triaxial thermo-hydro-mechanical system,and a DEM-CFD coupled model was established to numerically simulate the seepage process.The influences of temperature,particle size distribution,and confining pressure were analyzed on the seepage characteristics of the filling media.By examining the variations in water inflow rate,discharged clay-sand particle mass,porosity and permeability,we analyzed the entire process of seepage behavior and instability evolution under the thermohydro-mechanical coupling effect.The results show that:(1)Temperature significantly affects water inflow,discharged particle mass,porosity,and permeability.Higher temperatures remarkably increase porosity and permeability,with the maximum permeability coefficient of filling media at 90℃being 1.6 times that at 45℃.(2)The Talbol power index exhibits a positive correlation with water inflow rate and discharged particle mass,while confining pressure is negatively correlated with water inflow rate.(3)For filling materials dominated by clay-sand particles or with favorable gradation,the seepage instability process exhibits distinct phase characteristics,with different stages reflected in changes in water inflow,porosity,and permeability.The experimental results are consistent with the numerical simulation results.(4)In high ground temperature environments,temperature enhances convective heat transfer and energy exchange between water and filling media,thereby accelerating the process of water inrush caused by seepage instability.The findings provide scientific support for risk assessment,early warning,and prevention of water inrush hazards in deep-buried tunnels crossing clay-sand-filled structures.展开更多
The Taihang Mountains in North China are an important carbon-water ecosystem service supply area.Understanding the coupling effect and influencing mechanisms of mountain carbon sequestration as well as water conservat...The Taihang Mountains in North China are an important carbon-water ecosystem service supply area.Understanding the coupling effect and influencing mechanisms of mountain carbon sequestration as well as water conservation is essential for regional eco-logical restoration and sustainable development.In this study,we utilized models such as the coupled coordination degree model,the random forest and Geodetector to analyze the spa-tio-temporal changes as well as driving factors of carbon sequestration-water conservation coupling coordination in the Taihang Mountains.The results show that:(1)From 1990 to 2020,the carbon sequestration and water conservation capacity of the Taihang Mountains exhibited a spatial pattern with higher values in the southeast and central regions,while lower values in the northwest region.(2)The average coupling coordination degree from 1990 to 2020 was O.23,which was overall low,with a fluctuating decreasing-rising-decreasing trend over time.The coupling coordination degree exhibited a pattern that is high in the middle and low in the periphery,with a fluctuating distribution that initially decreases and then increases with the increasing altitude.The overall trend of coupling coordination is degradation,with concen-trated degradation in the northwest mountainous regions.(3)Precipitation and soil texture were identified as the main driving factors influencing coupling coordination,with the interac-tion between precipitation and soil sand content showing the strongest explanatory power,while that among topography,vegetation and human activities had relatively low explanatory power.Therefore,enhanced protection and the continuous monitoring of vegetation and soil environments in the Taihang Mountains are essential,with particular emphasis on ecological restoration in areas experiencing a persistent degradation of carbon-water coupling.This study can provide assistance in monitoring and managing carbon sink and water resources in the mountains,meanwhile mitigating potential adverse impacts on human well-being.展开更多
The coupling effect between ship motion and liquid sloshing in a beam sea is investigated,with a focus on the influence of liquid types,namely,water and liquefied natural gas(LNG),on the coupling dynamics.A hybrid num...The coupling effect between ship motion and liquid sloshing in a beam sea is investigated,with a focus on the influence of liquid types,namely,water and liquefied natural gas(LNG),on the coupling dynamics.A hybrid numerical model,combining a potential flow model and computational fluid dynamics methods,is employed to simulate these interactions.Numerical validation is performed using experimental data from water sloshing tests.Comparisons between water and LNG reveal that liquid type has minimal effects on the ship’s roll motion response in a beam sea,provided the total liquid masses are the same.Regarding sloshing impact pressure,although differences between LNG and water results are minor,substituting LNG with water in physical experiments is shown to yield reliable results.展开更多
Focusing on the conversion of pressure energy and internal energy under viscous dissipation,a heat-fluid-solid coupling method is established to study the flow and stress fields of 100 MPa submerged water jets.Results...Focusing on the conversion of pressure energy and internal energy under viscous dissipation,a heat-fluid-solid coupling method is established to study the flow and stress fields of 100 MPa submerged water jets.Results indicate that pressure energy to internal energy conversion primarily occurs at three locations:the nozzle wall,the potential core edge,and the impact wall,with the most intense conversion occurring at the impact wall.The impact temperature of the jet can reach 200℃,and the high-temperature region covers an area more than 4 times that of the high-pressure.Thermal stress can especially amplify erosion stress by more than 100%and expand the erosion area by more than 400%.Therefore,it serves as a dominant factor determining the optimal spray distance and jet angle in hard rock(E≥40 GPa).With increased spray distance or jet angle,impact pressure decreases,while the high-temperature zone moves toward the high-pressure region,thus increasing the overlap between the two regions.This extended overlap enhances the temperature-pressure coupling effect,consequently reducing the threshold pressure for jet-breaking rock.Therefore,the maximum erosion stress increases first and then decreases,and an optimal spray distance and jet angle exist.The optimal jet angle,defined by the maximum tensile stress,decreases with the dimensionless spray distance increase,ranging between 0°and 40°.This temperature-pressure coupling reduces rock-breaking threshold pressure by 15%-75%for elastic moduli of 40-80 GPa,with maximum erosion stress peaking at a dimensionless spray distance of 9 and jet angles of 15°-20°.When the overlap region decreases,the area affected by the temperature and pressure fields increases,leading to an increase in the rock-breaking area.It is important to note that reducing the rock-breaking threshold pressure and increasing the rock-breaking area are mutually exclusive objectives.It is necessary to optimize the design of the spray distance and jet angle according to the on-site rock-breaking requirements.展开更多
Uneven frost heave deformation can shorten the operational lifespan of foundation engineering.Clarifying the mechanisms of uneven frost heave facilitates the targeted mitigation of frost damage.This study focused on a...Uneven frost heave deformation can shorten the operational lifespan of foundation engineering.Clarifying the mechanisms of uneven frost heave facilitates the targeted mitigation of frost damage.This study focused on a water conveyance channel in Jilin Province,northern China,and found after monitoring that the frost heave at the channel bottom lining exceeded that at the crest by 44.5 mm,with the freezing temperature at the bottom being over 2℃lower than that at the crest.Soil columns with an initial gravimetric moisture content of 12%,16%,18%,and 20%were then prepared.The effects of temperature and moisture content on frost heave were analyzed under two freezing conditions(-5℃and-10℃)through unidirectional freezing tests.A coupled thermo-hydro-mechanical(THM)frost heave model,validated by the test results,was further established.In the soil with an initial moisture content of 20%,the formation of ice lenses associated with substantial water migration contributed to a large temperature gradient,which can jointly induce frost heave.Under the-10℃condition,the temperature gradient in the soil column with a 20%initial moisture content reached 0.84℃/cm,the total water migration reached 10.72%,and the frost heave deformation was 1.86 mm.The THM coupling results indicated that,under the interaction of a large temperature gradient and moisture accumulation,the volumetric ice content remained high in the bottom soil during freezing and peaked at 0.36.The frost damage to the bottom soil was severe,and the maximum deformation reached 57 mm.展开更多
Electrochemical carbon dioxide reduction reaction(CO_(2)RR)produces valuable chemicals by consuming gaseous CO_(2)as well as protons from the electrolyte.Protons,produced by water dissociation in alkaline electrolyte,...Electrochemical carbon dioxide reduction reaction(CO_(2)RR)produces valuable chemicals by consuming gaseous CO_(2)as well as protons from the electrolyte.Protons,produced by water dissociation in alkaline electrolyte,are critical for the reaction kinetics which involves multiple proton coupled electron transfer steps.Herein,we demonstrate that the two key steps(CO_(2)-^(*)COOH and^(*)CO-^(*)COH)efficiency can be precisely tuned by introducing proper amount of water dissociation center,i.e.,Fe single atoms,locally surrounding the Cu catalysts.In alkaline electrolyte,the Faradaic efficiency(FE)of multi-carbon(C^(2+))products exhibited a volcano type plot depending on the density of water dissociation center.A maximum FE for C^(2+)products of 73.2%could be reached on Cu nanoparticles supported on N-doped Carbon nanofibers with moderate Fe single atom sites,at a current density of 300 mA cm^(–2).Experimental and theoretical calculation results reveal that the Fe sites facilitate water dissociation kinetics,and the locally generated protons contribute significantly to the CO_(2)activation and^(*)CO protonation process.On the one hand,in-situ attenuated total reflection surface-enhanced infrared absorption spectroscopy(in-situ ATR-SEIRAS)clearly shows that the^(*)COOH intermediate can be observed at a lower potential.This phenomenon fully demonstrates that the optimized local water dissociation kinetics has a unique advantage in guiding the hydrogenation reaction pathway of CO₂molecules and can effectively reduce the reaction energy barrier.On the other hand,abundant^(*)CO and^(*)COH intermediates create favorable conditions for the asymmetric^(*)CO-^(*)COH coupling,significantly increasing the selectivity of the reaction for C^(2+)products and providing strong support for the efficient conversion of related reactions to the target products.This work provides a promising strategy for the design of a dual sites catalyst to achieve high FE of C^(2+)products through the optimized local water dissociation kinetics.展开更多
[Objective] The aim was to study the coupling effect of water and phosphate on economic traits of sugarcane. [Method] Taking sugarcane variety ROC22 as tested material,coupling effects of different levels of water sup...[Objective] The aim was to study the coupling effect of water and phosphate on economic traits of sugarcane. [Method] Taking sugarcane variety ROC22 as tested material,coupling effects of different levels of water supply quantity and different levels of phosphorus fertilizer on the yield and quality of sugarcane were studied. Among them,water supply quantity had 3 levels,that was,the water supply quantity per 10 days from the early tillering stage of sugarcane to the end of elongation was 199.5 m3/hm2 (A1),400.5 m3/hm2 (A2) and 600.0 m3/hm2 (A3),respectively; Phosphorus fertilizer as basic fertilizer had 4 levels:P2O5 0 kg/hm2 (B1),120 kg/hm2 (B2),240 kg/hm2 (B3) and 360 kg/hm2 (B4). [Result] Treatment A3B2 in water-fertilizer coupling was more suitable to improve economic traits of sugarcane. [Conclusion] The research results provide theoretical basis for the efficient utilization of water and phosphorus fertilizer in production of Guangxi sugarcane and the cultivation of high-yield and high-glucose sugarcane.展开更多
At present, the shortage of agricuItural water resources is worsening. In order to reduce the rice irrigation water and improve the utiIization of fertiIizers so as to achieve the high and stabIe yielding of rice, thi...At present, the shortage of agricuItural water resources is worsening. In order to reduce the rice irrigation water and improve the utiIization of fertiIizers so as to achieve the high and stabIe yielding of rice, this report reviewed the research advances in water and fertiIizer coupIing, the conception of water and fertiIizer cou-pIing and its three kinds of effects （synergy, antagonism, superposition）, mechanism of water and fertiIizer coupIing, effects of water and fertiIizer coupIing on growth, deveIopment, yield and quality of rice and effects of water and fertiIizer coupIing on utiIization rate of nitrogen in rice. In addition, the deveIopment prospects of water and fertiIizer coupIing in China were described. It was proposed that the water and fertiIizer coupIing mode is an effective measure to achieve the high yield and quality of rice. According to actual demand, referring to the ideas of promoting fertiIizer with water and reguIating water with fertiIizer, reasonabIe water and fertiIizer cou-pIing mode can be estabIished, thereby improving the utiIization efficiencies of water and fertiIizer. In the premise of saving irrigation water and no increasing fertiIization amount, both high yielding and Iess poI ution can be achieved, providing theoretical and technical basis for water-saving agricuIture and cuItivation and management of rice in future.展开更多
The process of air—sea fresh water exchange is included successfully in the Global— Ocean—Atmosphere Land—System model developed at the State Key Laboratory of Atmospheric Sciences and Geophysical Fluid Dynamics (...The process of air—sea fresh water exchange is included successfully in the Global— Ocean—Atmosphere Land—System model developed at the State Key Laboratory of Atmospheric Sciences and Geophysical Fluid Dynamics (LASG). The results of the coupled integration show that the climate drift has been controlled successfully. Analyses on the responses of ocean circulation to the changes of surface fresh water or salinity forcing show that the ocean spin-up stage under flux condition for salinity is the key to the implementation of air-sea fresh water flux coupling. This study also demonstrates that the Modified—Monthly—Flux—Anomaly coupling scheme (MMFA) brought forward by Yu and Zhang (1998) is suitable not only for daily air—sea heat flux coupling but also for daily fresh water flux coupling. Key words Fresh water flux - Air-sea coupling - Thermohaline circulation This work was co-supported by the National Key Project (Grant No.96-908-02-03), the Excellent National Key Laboratory Research Project (Grant No.49823002) and Chinese Academy of Sciences (CAS) under grant “ Bai Ren Ji Hua? for “Validation of Coupled Climate Models”.展开更多
Wheat is an important agricultural crop in the Loess region of China, where there is drought stress and low availability of soil nitrogen and phosphorus. Using a pulse modulation fluorometer, we studied the effects of...Wheat is an important agricultural crop in the Loess region of China, where there is drought stress and low availability of soil nitrogen and phosphorus. Using a pulse modulation fluorometer, we studied the effects of water, nitrogen, and phosphorus on the kinetic parameters of chlorophyll fluorescence in winter wheat. The wheat was grown in layered columns of Eum-Orthic Anthrosol （Cinnamon soil）, with the water content and nutrient composition of each layer controlled. The results showed that the kinetic parameters of chlorophyll fluorescence were sensitive to water stress. The basic fluorescence （F0） of leaves was higher in the dry treatment （0-30 cm layer at 40-45% of field capacity, 30-90 cm at 75-80% of field capacity） compared to the wet treatment （entire soil column at 75-80% of field capacity）. The maximal fluorescence （Fm）, the variable fluorescence （Fv）, the photochemical efficiency （Fv/Fm） and potential activites （Fv/F0） of photosystem 2 （PS2） were significantly lower in the dry treatment. Although drought stress impaired PS2 function, this effect was significantly ameliorated by applying P or NP fertilizer, but not N alone. P application increased FJFm, both in well-watered and water stressed plants, especially when fertilizer was applied throughout the column or within the top 30 em of soil. A combined fertilizer improved photosynthesis in well watered plants, with Fm and F,fFm being the highest when fertilizer was applied throughout the columns. For drought stressed, plants FJFm was significantly greater when combined fertilizer was added within the top 30 cm of soil. We concluded that, when growing winter wheat in both arid and semi-arid parts of the Loess region of China, it is important to guarantee the nutrient supply in the top 30 cm of the soil.展开更多
Soybean cultivar Bei 92-28 was tested in this experiment in 2000 to study the coupling effect of water and ferilizer on soybean yield.The results showed that the effect of irrigation varied among the levels of fertili...Soybean cultivar Bei 92-28 was tested in this experiment in 2000 to study the coupling effect of water and ferilizer on soybean yield.The results showed that the effect of irrigation varied among the levels of fertilizer application,and vice versa;pods per plant,seeds per pod.and 100-seed weight had positive correlations with soybean yield,but the degrees of correlations of different treatments were various;LAI and dry matter accumulation could be significantly increased when watered and applied fertilizer with different levels,but high fertilizer application treatment didn't obtain the highest yield;watering could increase the absolute absorption amount of N,P,K in seeds,but the accumulation rates were various.展开更多
The coupling relation exists in water and soil conser-vation and economic-social development. The article analyses the relation of soil and water conservation and economic-social development stages as well as the coup...The coupling relation exists in water and soil conser-vation and economic-social development. The article analyses the relation of soil and water conservation and economic-social development stages as well as the coupling analytical method. Then calculates the expecting income by dispersing Markov decision and calculates the correlation coefficient and the re-lationship degree. The article obtains the relationship of soil and water conservation investments and all kinds of incomes. Finally, it analyzes the important meaning in socio-economic development of water and soil conservation.展开更多
This study investigates the impact of different water coupling coefficients on the blasting effect of red sandstone.The analysis is based on the theories of detonation wave and elastic wave,focusing on the variation i...This study investigates the impact of different water coupling coefficients on the blasting effect of red sandstone.The analysis is based on the theories of detonation wave and elastic wave,focusing on the variation in wall pressure of the blasting holes.Using DDNP explosive as the explosive load,blasting tests were conducted on red sandstone specimens with four different water coupling coefficients:1.20,1.33,1.50,and 2.00.The study examines the morphologies of the rock specimens after blasting under these different water coupling coefficients.Additionally,the fractal dimensions of the surface cracks resulting from the blasting were calculated to provide a quantitative evaluation of the extent of rock damage.CT scanning and 3D reconstruction were performed on the post-blasting specimens to visually depict the extent of damage and fractures within the rock.Additionally,the volume fractal dimension and damage degree of the post-blasting specimens are calculated.The findings are then combined with numerical simulation to facilitate auxiliary analysis.The results demonstrate that an increase in the water coupling coefficient leads to a reduction in the peak pressure on the hole wall and the crushing zone,enabling more of the explosion energy to be utilized for crack propagation following the explosion.The specimens exhibited distinct failure patterns,resulting in corresponding changes in fractal dimensions.The simulated pore wall pressure–time curve validated the derived theoretical results,whereas the stress cloud map and explosion energy-time curve demonstrated the buffering effect of the water medium.As the water coupling coefficient increases,the buffering effect of the water medium becomes increasingly prominent.展开更多
We present a systematical study on comparison between water and dry coupling in photoacoustic tomography of the humanfinger joints.Compared to the direct water immersion of thefinger for water coupling,the dry couplin...We present a systematical study on comparison between water and dry coupling in photoacoustic tomography of the humanfinger joints.Compared to the direct water immersion of thefinger for water coupling,the dry coupling is realized through a transparent PDMSfilm-based water bag,which ensures water-free contact with the skin.The results obtained suggest that the dry cou-pling provides image quality comparable to that by water coupling while eliminating the wrin-kling of thefinger joint caused by the water immersion.In addition,the dry coupling offers more stable hemodynamic images than the water coupling as the water immersion of thefinger joint causes reduction in blood vessel size.展开更多
An efficient, practical, highly selective and environmentally benign method is reported for the synthesis of aryl thioethers via the coupling of thiols with aryl boronic acids in the presence of NaOH and a catalytic a...An efficient, practical, highly selective and environmentally benign method is reported for the synthesis of aryl thioethers via the coupling of thiols with aryl boronic acids in the presence of NaOH and a catalytic amount of CuSO4 at 130 ℃ using water as a green solvent. The products were obtained in moderate to excellent yields;more importantly, the use of toxic ligands and solvents was avoided. A broad range of aryl boronic acids and scalable processes make this methodology valuable and versatile for the synthesis of a broad range of aryl sulfides.展开更多
About 75% water-inrush accidents in China are caused by geological structure such as faults, therefore, it is necessary to investigate the water-inrush mechanism of faults to provide references for the mining activity...About 75% water-inrush accidents in China are caused by geological structure such as faults, therefore, it is necessary to investigate the water-inrush mechanism of faults to provide references for the mining activity above confined water. In this paper, based on the fluid-solid coupling theory, we built the stress-seepage coupling model for rock, then we combined with an example of water-inrush caused by fault, studied the water-inrush mechanism by using the numerical software COMSOL Mutiphysics, analyzed the change rule of shear stress, vertical stress, plastic area and water pressure for stope with a fault, and estimated the water-inrush risk at the different distances between working faces and the fault. The numerical simula- tion results indicate that： （1） the water-inrush risk will grow as the decrease of the distance between working face and the fault; （2） the failure mode of the rock in floor with fault is shear failure; （3） the rock between water-containing fault and working face failure is the reason for water-inrush.展开更多
Quantitatively assessing the carrying capacity of water and land resources systems in arid and semi-arid areas is crucial for achieving the 2030 Sustainable Development Goals.In this work,taking Yulin City in China as...Quantitatively assessing the carrying capacity of water and land resources systems in arid and semi-arid areas is crucial for achieving the 2030 Sustainable Development Goals.In this work,taking Yulin City in China as a case study and employing the Criteria Importance Through Intercriteria Correlation(CRITIC)method,a modified model of coupling degree was developed to evaluate the car-rying capacity of water and land resources systems endowment and utilization,as well as their coupling coordination degree from 2013 to 2020.Our findings indicate that the water and land resources of Yulin are diminishing due to declines in agriculture,higher industrial water use,and wetland shrinkage.However,reallocating domestic water for ecological sustainability and reducing sloping farmland can mitigate this trend of decline.Temporally,as the coupling coordination between water and land resources system endowment in Yulin continuously improved,the coupling coordination between water and land resources system utilization first decreased and then in-creased with 2016 as the turning point.Spatially,the carrying capacity of water and land resources systems,the coupling coordination degree between water and land resources system endowment,and the coupling coordination degree between water and land resources system utilization in Yulin exhibited the same pattern of being higher in the six northern counties than in the six southern counties.Improving the water resources endowment is vital for the highly efficient use of water and land resources.展开更多
This paper presents the heave responses and the moonpool water motions of a truss Spar platform with semi-closed moonpool in random waves. A 2-DOF（degree of freedom） coupling dynamical equations of the platform heav...This paper presents the heave responses and the moonpool water motions of a truss Spar platform with semi-closed moonpool in random waves. A 2-DOF（degree of freedom） coupling dynamical equations of the platform heave and vertical motions of the moonpool water are derived. The linear wave theory is used to simulate the random waves. The response statistical values and the power spectrums are calculated to analyze the mutual influences between the platform heave and the moonpool water motions for different opening ratios of the moonpool. The effect of coupling parameters on the platform heave and the moonpool water motions are analyzed. The results show that motions of the moonpool water significantly affected the platform heave when the characteristic wave period is far away from the natural period of the platform heave, and different moonpool opening ratios lead to different heave amplitudes of the platform. In the actual design, an optimized moonpool opening ratio can be designed to reduce heave motions of the platform.展开更多
Under the water resources perspective,coupling coordination of economy-ecology-society system in Xinjiang was taken as the research object. By building the coupling evaluation index system of the water resources-econo...Under the water resources perspective,coupling coordination of economy-ecology-society system in Xinjiang was taken as the research object. By building the coupling evaluation index system of the water resources-economy-ecology-society system,quantitative evaluation and analysis of the coupling coordination of the water resources-economy-ecology-society system from 2001 to 2014 were conducted. The results showed that benefit indexes of economic system and social system grew rapidly,while benefit indexes of water resources system and ecosystem fluctuated smoothly from 2001 to 2014; coupling state of the whole system was at rival stage,and coupling coordination was reluctant coordination type,and the coupling index was slightly higher than the coupling coordination index. Moreover,it showed that the more the coupling systems,the lower indices of coupling and the coupling coordination.展开更多
To study the behavior of overlying strata and the likelihood of water inrush and quicksand with different mining sequences under an unconsolidated alluvium aquifer, a numerical model based on the fluid-solid coupling ...To study the behavior of overlying strata and the likelihood of water inrush and quicksand with different mining sequences under an unconsolidated alluvium aquifer, a numerical model based on the fluid-solid coupling theory was con- structed by FLAC3D. Simulation results revealed that the mining sequences had a significant influence on the seepage, dis- placement and failure characteristics of the overlying strata. In this kind of geological and hydrogeological conditions, the workface close to the outcrop of coal seam easily suffers from water inrush and quicksand during mining. In the simulation re- sults, the plastic zone, vertical displacement and pore water pressure in the overlying strata of the workface decrease more or less using the upward mining sequence than using the downward mining sequence. Therefore, the application of the upward mining sequence in the process of mining is preferential to prevent water inrush and quicksand.展开更多
基金funded by National Natural Science Foundation of China(Grant No.52278404)Taishan Young Scholar Program of Shandong Province(Grant No.tsqn202103002),which collectively funded this project。
文摘Deep-buried tunnels traversing complex hydrogeological zones with clay-sand-filled structures are highly susceptible to water inrush hazards.High ground temperature,high in-situ stress,and highwater pressure render these events a complex thermohydro-mechanical coupling problem.However,current research on water inrush often insufficiently investigates the multi-field coupled instability mechanisms within highly permeable filling media and frequently neglects the influence of temperature.This study aims to investigate the evolutionary mechanism of seepage instability in filling structures that trigger water inrush hazards under the complex conditions of deep-buried tunnels.Laboratory tests were conducted using a large-scale triaxial thermo-hydro-mechanical system,and a DEM-CFD coupled model was established to numerically simulate the seepage process.The influences of temperature,particle size distribution,and confining pressure were analyzed on the seepage characteristics of the filling media.By examining the variations in water inflow rate,discharged clay-sand particle mass,porosity and permeability,we analyzed the entire process of seepage behavior and instability evolution under the thermohydro-mechanical coupling effect.The results show that:(1)Temperature significantly affects water inflow,discharged particle mass,porosity,and permeability.Higher temperatures remarkably increase porosity and permeability,with the maximum permeability coefficient of filling media at 90℃being 1.6 times that at 45℃.(2)The Talbol power index exhibits a positive correlation with water inflow rate and discharged particle mass,while confining pressure is negatively correlated with water inflow rate.(3)For filling materials dominated by clay-sand particles or with favorable gradation,the seepage instability process exhibits distinct phase characteristics,with different stages reflected in changes in water inflow,porosity,and permeability.The experimental results are consistent with the numerical simulation results.(4)In high ground temperature environments,temperature enhances convective heat transfer and energy exchange between water and filling media,thereby accelerating the process of water inrush caused by seepage instability.The findings provide scientific support for risk assessment,early warning,and prevention of water inrush hazards in deep-buried tunnels crossing clay-sand-filled structures.
基金Special Program for Survey of National Basic Scientific and Technological Resources,No.2021FY00802。
文摘The Taihang Mountains in North China are an important carbon-water ecosystem service supply area.Understanding the coupling effect and influencing mechanisms of mountain carbon sequestration as well as water conservation is essential for regional eco-logical restoration and sustainable development.In this study,we utilized models such as the coupled coordination degree model,the random forest and Geodetector to analyze the spa-tio-temporal changes as well as driving factors of carbon sequestration-water conservation coupling coordination in the Taihang Mountains.The results show that:(1)From 1990 to 2020,the carbon sequestration and water conservation capacity of the Taihang Mountains exhibited a spatial pattern with higher values in the southeast and central regions,while lower values in the northwest region.(2)The average coupling coordination degree from 1990 to 2020 was O.23,which was overall low,with a fluctuating decreasing-rising-decreasing trend over time.The coupling coordination degree exhibited a pattern that is high in the middle and low in the periphery,with a fluctuating distribution that initially decreases and then increases with the increasing altitude.The overall trend of coupling coordination is degradation,with concen-trated degradation in the northwest mountainous regions.(3)Precipitation and soil texture were identified as the main driving factors influencing coupling coordination,with the interac-tion between precipitation and soil sand content showing the strongest explanatory power,while that among topography,vegetation and human activities had relatively low explanatory power.Therefore,enhanced protection and the continuous monitoring of vegetation and soil environments in the Taihang Mountains are essential,with particular emphasis on ecological restoration in areas experiencing a persistent degradation of carbon-water coupling.This study can provide assistance in monitoring and managing carbon sink and water resources in the mountains,meanwhile mitigating potential adverse impacts on human well-being.
基金supported by the Natural Science Foundation of China with Grant Nos.52371267 and 52171250。
文摘The coupling effect between ship motion and liquid sloshing in a beam sea is investigated,with a focus on the influence of liquid types,namely,water and liquefied natural gas(LNG),on the coupling dynamics.A hybrid numerical model,combining a potential flow model and computational fluid dynamics methods,is employed to simulate these interactions.Numerical validation is performed using experimental data from water sloshing tests.Comparisons between water and LNG reveal that liquid type has minimal effects on the ship’s roll motion response in a beam sea,provided the total liquid masses are the same.Regarding sloshing impact pressure,although differences between LNG and water results are minor,substituting LNG with water in physical experiments is shown to yield reliable results.
基金supported by the National Natural Science Foundation of China(No.52204126)the Shandong Provincial Natural Science Foundation(Nos.ZR2022ME077,ZR2022QE060,and ZR2023ME119).
文摘Focusing on the conversion of pressure energy and internal energy under viscous dissipation,a heat-fluid-solid coupling method is established to study the flow and stress fields of 100 MPa submerged water jets.Results indicate that pressure energy to internal energy conversion primarily occurs at three locations:the nozzle wall,the potential core edge,and the impact wall,with the most intense conversion occurring at the impact wall.The impact temperature of the jet can reach 200℃,and the high-temperature region covers an area more than 4 times that of the high-pressure.Thermal stress can especially amplify erosion stress by more than 100%and expand the erosion area by more than 400%.Therefore,it serves as a dominant factor determining the optimal spray distance and jet angle in hard rock(E≥40 GPa).With increased spray distance or jet angle,impact pressure decreases,while the high-temperature zone moves toward the high-pressure region,thus increasing the overlap between the two regions.This extended overlap enhances the temperature-pressure coupling effect,consequently reducing the threshold pressure for jet-breaking rock.Therefore,the maximum erosion stress increases first and then decreases,and an optimal spray distance and jet angle exist.The optimal jet angle,defined by the maximum tensile stress,decreases with the dimensionless spray distance increase,ranging between 0°and 40°.This temperature-pressure coupling reduces rock-breaking threshold pressure by 15%-75%for elastic moduli of 40-80 GPa,with maximum erosion stress peaking at a dimensionless spray distance of 9 and jet angles of 15°-20°.When the overlap region decreases,the area affected by the temperature and pressure fields increases,leading to an increase in the rock-breaking area.It is important to note that reducing the rock-breaking threshold pressure and increasing the rock-breaking area are mutually exclusive objectives.It is necessary to optimize the design of the spray distance and jet angle according to the on-site rock-breaking requirements.
基金funding support from the National Natural Science Foundation of China(Grants Nos.42330708 and 42302329)the Graduate Innovation Research Program of Jilin University(Grant No.2024CX118).
文摘Uneven frost heave deformation can shorten the operational lifespan of foundation engineering.Clarifying the mechanisms of uneven frost heave facilitates the targeted mitigation of frost damage.This study focused on a water conveyance channel in Jilin Province,northern China,and found after monitoring that the frost heave at the channel bottom lining exceeded that at the crest by 44.5 mm,with the freezing temperature at the bottom being over 2℃lower than that at the crest.Soil columns with an initial gravimetric moisture content of 12%,16%,18%,and 20%were then prepared.The effects of temperature and moisture content on frost heave were analyzed under two freezing conditions(-5℃and-10℃)through unidirectional freezing tests.A coupled thermo-hydro-mechanical(THM)frost heave model,validated by the test results,was further established.In the soil with an initial moisture content of 20%,the formation of ice lenses associated with substantial water migration contributed to a large temperature gradient,which can jointly induce frost heave.Under the-10℃condition,the temperature gradient in the soil column with a 20%initial moisture content reached 0.84℃/cm,the total water migration reached 10.72%,and the frost heave deformation was 1.86 mm.The THM coupling results indicated that,under the interaction of a large temperature gradient and moisture accumulation,the volumetric ice content remained high in the bottom soil during freezing and peaked at 0.36.The frost damage to the bottom soil was severe,and the maximum deformation reached 57 mm.
文摘Electrochemical carbon dioxide reduction reaction(CO_(2)RR)produces valuable chemicals by consuming gaseous CO_(2)as well as protons from the electrolyte.Protons,produced by water dissociation in alkaline electrolyte,are critical for the reaction kinetics which involves multiple proton coupled electron transfer steps.Herein,we demonstrate that the two key steps(CO_(2)-^(*)COOH and^(*)CO-^(*)COH)efficiency can be precisely tuned by introducing proper amount of water dissociation center,i.e.,Fe single atoms,locally surrounding the Cu catalysts.In alkaline electrolyte,the Faradaic efficiency(FE)of multi-carbon(C^(2+))products exhibited a volcano type plot depending on the density of water dissociation center.A maximum FE for C^(2+)products of 73.2%could be reached on Cu nanoparticles supported on N-doped Carbon nanofibers with moderate Fe single atom sites,at a current density of 300 mA cm^(–2).Experimental and theoretical calculation results reveal that the Fe sites facilitate water dissociation kinetics,and the locally generated protons contribute significantly to the CO_(2)activation and^(*)CO protonation process.On the one hand,in-situ attenuated total reflection surface-enhanced infrared absorption spectroscopy(in-situ ATR-SEIRAS)clearly shows that the^(*)COOH intermediate can be observed at a lower potential.This phenomenon fully demonstrates that the optimized local water dissociation kinetics has a unique advantage in guiding the hydrogenation reaction pathway of CO₂molecules and can effectively reduce the reaction energy barrier.On the other hand,abundant^(*)CO and^(*)COH intermediates create favorable conditions for the asymmetric^(*)CO-^(*)COH coupling,significantly increasing the selectivity of the reaction for C^(2+)products and providing strong support for the efficient conversion of related reactions to the target products.This work provides a promising strategy for the design of a dual sites catalyst to achieve high FE of C^(2+)products through the optimized local water dissociation kinetics.
基金Supported by National Science and Technology Project of China(2007BAD30B04)~~
文摘[Objective] The aim was to study the coupling effect of water and phosphate on economic traits of sugarcane. [Method] Taking sugarcane variety ROC22 as tested material,coupling effects of different levels of water supply quantity and different levels of phosphorus fertilizer on the yield and quality of sugarcane were studied. Among them,water supply quantity had 3 levels,that was,the water supply quantity per 10 days from the early tillering stage of sugarcane to the end of elongation was 199.5 m3/hm2 (A1),400.5 m3/hm2 (A2) and 600.0 m3/hm2 (A3),respectively; Phosphorus fertilizer as basic fertilizer had 4 levels:P2O5 0 kg/hm2 (B1),120 kg/hm2 (B2),240 kg/hm2 (B3) and 360 kg/hm2 (B4). [Result] Treatment A3B2 in water-fertilizer coupling was more suitable to improve economic traits of sugarcane. [Conclusion] The research results provide theoretical basis for the efficient utilization of water and phosphorus fertilizer in production of Guangxi sugarcane and the cultivation of high-yield and high-glucose sugarcane.
基金Supported by National Key Technology Research and Development Program(2011BAD16B01,2012BAD04B10,2013BAD07B11)~~
文摘At present, the shortage of agricuItural water resources is worsening. In order to reduce the rice irrigation water and improve the utiIization of fertiIizers so as to achieve the high and stabIe yielding of rice, this report reviewed the research advances in water and fertiIizer coupIing, the conception of water and fertiIizer cou-pIing and its three kinds of effects （synergy, antagonism, superposition）, mechanism of water and fertiIizer coupIing, effects of water and fertiIizer coupIing on growth, deveIopment, yield and quality of rice and effects of water and fertiIizer coupIing on utiIization rate of nitrogen in rice. In addition, the deveIopment prospects of water and fertiIizer coupIing in China were described. It was proposed that the water and fertiIizer coupIing mode is an effective measure to achieve the high yield and quality of rice. According to actual demand, referring to the ideas of promoting fertiIizer with water and reguIating water with fertiIizer, reasonabIe water and fertiIizer cou-pIing mode can be estabIished, thereby improving the utiIization efficiencies of water and fertiIizer. In the premise of saving irrigation water and no increasing fertiIization amount, both high yielding and Iess poI ution can be achieved, providing theoretical and technical basis for water-saving agricuIture and cuItivation and management of rice in future.
文摘The process of air—sea fresh water exchange is included successfully in the Global— Ocean—Atmosphere Land—System model developed at the State Key Laboratory of Atmospheric Sciences and Geophysical Fluid Dynamics (LASG). The results of the coupled integration show that the climate drift has been controlled successfully. Analyses on the responses of ocean circulation to the changes of surface fresh water or salinity forcing show that the ocean spin-up stage under flux condition for salinity is the key to the implementation of air-sea fresh water flux coupling. This study also demonstrates that the Modified—Monthly—Flux—Anomaly coupling scheme (MMFA) brought forward by Yu and Zhang (1998) is suitable not only for daily air—sea heat flux coupling but also for daily fresh water flux coupling. Key words Fresh water flux - Air-sea coupling - Thermohaline circulation This work was co-supported by the National Key Project (Grant No.96-908-02-03), the Excellent National Key Laboratory Research Project (Grant No.49823002) and Chinese Academy of Sciences (CAS) under grant “ Bai Ren Ji Hua? for “Validation of Coupled Climate Models”.
基金supported by the National Natural Science Foundation of China (NSFC 50809068)the foundation of the State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau,China (10502)+1 种基金the China Postdoctoral Science Foundation (20080441196)the West Light Foundation of the Chinese Academy of Science
文摘Wheat is an important agricultural crop in the Loess region of China, where there is drought stress and low availability of soil nitrogen and phosphorus. Using a pulse modulation fluorometer, we studied the effects of water, nitrogen, and phosphorus on the kinetic parameters of chlorophyll fluorescence in winter wheat. The wheat was grown in layered columns of Eum-Orthic Anthrosol （Cinnamon soil）, with the water content and nutrient composition of each layer controlled. The results showed that the kinetic parameters of chlorophyll fluorescence were sensitive to water stress. The basic fluorescence （F0） of leaves was higher in the dry treatment （0-30 cm layer at 40-45% of field capacity, 30-90 cm at 75-80% of field capacity） compared to the wet treatment （entire soil column at 75-80% of field capacity）. The maximal fluorescence （Fm）, the variable fluorescence （Fv）, the photochemical efficiency （Fv/Fm） and potential activites （Fv/F0） of photosystem 2 （PS2） were significantly lower in the dry treatment. Although drought stress impaired PS2 function, this effect was significantly ameliorated by applying P or NP fertilizer, but not N alone. P application increased FJFm, both in well-watered and water stressed plants, especially when fertilizer was applied throughout the column or within the top 30 em of soil. A combined fertilizer improved photosynthesis in well watered plants, with Fm and F,fFm being the highest when fertilizer was applied throughout the columns. For drought stressed, plants FJFm was significantly greater when combined fertilizer was added within the top 30 cm of soil. We concluded that, when growing winter wheat in both arid and semi-arid parts of the Loess region of China, it is important to guarantee the nutrient supply in the top 30 cm of the soil.
文摘Soybean cultivar Bei 92-28 was tested in this experiment in 2000 to study the coupling effect of water and ferilizer on soybean yield.The results showed that the effect of irrigation varied among the levels of fertilizer application,and vice versa;pods per plant,seeds per pod.and 100-seed weight had positive correlations with soybean yield,but the degrees of correlations of different treatments were various;LAI and dry matter accumulation could be significantly increased when watered and applied fertilizer with different levels,but high fertilizer application treatment didn't obtain the highest yield;watering could increase the absolute absorption amount of N,P,K in seeds,but the accumulation rates were various.
文摘The coupling relation exists in water and soil conser-vation and economic-social development. The article analyses the relation of soil and water conservation and economic-social development stages as well as the coupling analytical method. Then calculates the expecting income by dispersing Markov decision and calculates the correlation coefficient and the re-lationship degree. The article obtains the relationship of soil and water conservation investments and all kinds of incomes. Finally, it analyzes the important meaning in socio-economic development of water and soil conservation.
基金National Key Research and Development Program of China(2021YFC2902103)National Natural Science Foundation of China(51934001)Fundamental Research Funds for the Central Universities(2023JCCXLJ02).
文摘This study investigates the impact of different water coupling coefficients on the blasting effect of red sandstone.The analysis is based on the theories of detonation wave and elastic wave,focusing on the variation in wall pressure of the blasting holes.Using DDNP explosive as the explosive load,blasting tests were conducted on red sandstone specimens with four different water coupling coefficients:1.20,1.33,1.50,and 2.00.The study examines the morphologies of the rock specimens after blasting under these different water coupling coefficients.Additionally,the fractal dimensions of the surface cracks resulting from the blasting were calculated to provide a quantitative evaluation of the extent of rock damage.CT scanning and 3D reconstruction were performed on the post-blasting specimens to visually depict the extent of damage and fractures within the rock.Additionally,the volume fractal dimension and damage degree of the post-blasting specimens are calculated.The findings are then combined with numerical simulation to facilitate auxiliary analysis.The results demonstrate that an increase in the water coupling coefficient leads to a reduction in the peak pressure on the hole wall and the crushing zone,enabling more of the explosion energy to be utilized for crack propagation following the explosion.The specimens exhibited distinct failure patterns,resulting in corresponding changes in fractal dimensions.The simulated pore wall pressure–time curve validated the derived theoretical results,whereas the stress cloud map and explosion energy-time curve demonstrated the buffering effect of the water medium.As the water coupling coefficient increases,the buffering effect of the water medium becomes increasingly prominent.
基金supported by the Natural National Science Foundation of China(NSFC)(61701076)
文摘We present a systematical study on comparison between water and dry coupling in photoacoustic tomography of the humanfinger joints.Compared to the direct water immersion of thefinger for water coupling,the dry coupling is realized through a transparent PDMSfilm-based water bag,which ensures water-free contact with the skin.The results obtained suggest that the dry cou-pling provides image quality comparable to that by water coupling while eliminating the wrin-kling of thefinger joint caused by the water immersion.In addition,the dry coupling offers more stable hemodynamic images than the water coupling as the water immersion of thefinger joint causes reduction in blood vessel size.
基金Funded by the National Natural Science Foundation of China(No.21571144)
文摘An efficient, practical, highly selective and environmentally benign method is reported for the synthesis of aryl thioethers via the coupling of thiols with aryl boronic acids in the presence of NaOH and a catalytic amount of CuSO4 at 130 ℃ using water as a green solvent. The products were obtained in moderate to excellent yields;more importantly, the use of toxic ligands and solvents was avoided. A broad range of aryl boronic acids and scalable processes make this methodology valuable and versatile for the synthesis of a broad range of aryl sulfides.
基金Supported by the National Basic Research Program of China （2010CB226800） the National Natural Science Foundation of China （50904065） the Program for New Century Excellent Talents in University （NCET-09-0728）
文摘About 75% water-inrush accidents in China are caused by geological structure such as faults, therefore, it is necessary to investigate the water-inrush mechanism of faults to provide references for the mining activity above confined water. In this paper, based on the fluid-solid coupling theory, we built the stress-seepage coupling model for rock, then we combined with an example of water-inrush caused by fault, studied the water-inrush mechanism by using the numerical software COMSOL Mutiphysics, analyzed the change rule of shear stress, vertical stress, plastic area and water pressure for stope with a fault, and estimated the water-inrush risk at the different distances between working faces and the fault. The numerical simula- tion results indicate that： （1） the water-inrush risk will grow as the decrease of the distance between working face and the fault; （2） the failure mode of the rock in floor with fault is shear failure; （3） the rock between water-containing fault and working face failure is the reason for water-inrush.
基金Under the auspices of the National Natural Science Foundation of China(No.42271279,41931293,41801175)。
文摘Quantitatively assessing the carrying capacity of water and land resources systems in arid and semi-arid areas is crucial for achieving the 2030 Sustainable Development Goals.In this work,taking Yulin City in China as a case study and employing the Criteria Importance Through Intercriteria Correlation(CRITIC)method,a modified model of coupling degree was developed to evaluate the car-rying capacity of water and land resources systems endowment and utilization,as well as their coupling coordination degree from 2013 to 2020.Our findings indicate that the water and land resources of Yulin are diminishing due to declines in agriculture,higher industrial water use,and wetland shrinkage.However,reallocating domestic water for ecological sustainability and reducing sloping farmland can mitigate this trend of decline.Temporally,as the coupling coordination between water and land resources system endowment in Yulin continuously improved,the coupling coordination between water and land resources system utilization first decreased and then in-creased with 2016 as the turning point.Spatially,the carrying capacity of water and land resources systems,the coupling coordination degree between water and land resources system endowment,and the coupling coordination degree between water and land resources system utilization in Yulin exhibited the same pattern of being higher in the six northern counties than in the six southern counties.Improving the water resources endowment is vital for the highly efficient use of water and land resources.
基金financially supported by the National Natural Science Foundation of China(Grant No.51179125)the Innovation Foundation of Tianjin University(Grant No.1301)
文摘This paper presents the heave responses and the moonpool water motions of a truss Spar platform with semi-closed moonpool in random waves. A 2-DOF（degree of freedom） coupling dynamical equations of the platform heave and vertical motions of the moonpool water are derived. The linear wave theory is used to simulate the random waves. The response statistical values and the power spectrums are calculated to analyze the mutual influences between the platform heave and the moonpool water motions for different opening ratios of the moonpool. The effect of coupling parameters on the platform heave and the moonpool water motions are analyzed. The results show that motions of the moonpool water significantly affected the platform heave when the characteristic wave period is far away from the natural period of the platform heave, and different moonpool opening ratios lead to different heave amplitudes of the platform. In the actual design, an optimized moonpool opening ratio can be designed to reduce heave motions of the platform.
基金Supported by"Effect Evaluation of Xinjiang Implementing the First Round of Subsidy Reward Mechanism Policy of Grassland Eco-protection" from Special Item of Xinjiang Animal Husbandry DepartmentPublic Welfare Scientific Research Project of Xinjiang Uygur Autonomous Region(XK201516)
文摘Under the water resources perspective,coupling coordination of economy-ecology-society system in Xinjiang was taken as the research object. By building the coupling evaluation index system of the water resources-economy-ecology-society system,quantitative evaluation and analysis of the coupling coordination of the water resources-economy-ecology-society system from 2001 to 2014 were conducted. The results showed that benefit indexes of economic system and social system grew rapidly,while benefit indexes of water resources system and ecosystem fluctuated smoothly from 2001 to 2014; coupling state of the whole system was at rival stage,and coupling coordination was reluctant coordination type,and the coupling index was slightly higher than the coupling coordination index. Moreover,it showed that the more the coupling systems,the lower indices of coupling and the coupling coordination.
文摘To study the behavior of overlying strata and the likelihood of water inrush and quicksand with different mining sequences under an unconsolidated alluvium aquifer, a numerical model based on the fluid-solid coupling theory was con- structed by FLAC3D. Simulation results revealed that the mining sequences had a significant influence on the seepage, dis- placement and failure characteristics of the overlying strata. In this kind of geological and hydrogeological conditions, the workface close to the outcrop of coal seam easily suffers from water inrush and quicksand during mining. In the simulation re- sults, the plastic zone, vertical displacement and pore water pressure in the overlying strata of the workface decrease more or less using the upward mining sequence than using the downward mining sequence. Therefore, the application of the upward mining sequence in the process of mining is preferential to prevent water inrush and quicksand.
