As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine properties.Fractal analysis has been used to characterize the shapes of metal...As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine properties.Fractal analysis has been used to characterize the shapes of metal materials at various scales and dimensions.Conventional methods make it difficult to quantitatively describe the relationship between the regular characteristics and properties of metal material surfaces and interfaces.However,fractal analysis can be used to quantitatively describe the shape characteristics of metal materials and to establish the quantitative relationships between the shape characteristics and various properties of metal materials.From the perspective of two-dimensional planes and three-dimensional curved surfaces,this paper reviews the current research status of the fractal analysis of metal precipitate interfaces,metal grain boundary interfaces,metal-deposited film surfaces,metal fracture surfaces,metal machined surfaces,and metal wear surfaces.The relationship between the fractal dimensions and properties of metal material surfaces and interfaces is summarized.Starting from three perspectives of fractal analysis,namely,research scope,image acquisition methods,and calculation methods,this paper identifies the direction of research on fractal analysis of metal material surfaces and interfaces that need to be developed.It is believed that revealing the deep influence mechanism between the fractal dimensions and properties of metal material surfaces and interfaces will be the key research direction of the fractal analysis of metal materials in the future.展开更多
According to surface morphology,microhardness,X-ray diffraction,and static contact angle experiments,the changes in the surface integrity and corrosion resistance of 6061-T6 aluminum alloy after ultrasonic shot peenin...According to surface morphology,microhardness,X-ray diffraction,and static contact angle experiments,the changes in the surface integrity and corrosion resistance of 6061-T6 aluminum alloy after ultrasonic shot peening(USP)were investigated.Results show that the grain size of the material surface is reduced by 43%,the residual compressive stress has an increasing trend,the roughness and hardness are increased by approximately 211.1%and 35%,respectively.And the static contact angle is increased at first,followed by a slight decrease.Weighing,scanning electron microscope,and energy dispersive spectrometer were used to study the samples after a cyclic corrosion test.Results show that USP reduces the corrosion rate by 41.2%.A model of surface corrosion mechanism of USP is developed,and the mechanism of USP to improve the corrosion resistance of materials is discussed.The introduction of compressive residual stresses,grain refinement,increased grain boundaries,increased hardness,and increased static contact angle are the main factors related to the improvement of corrosion resistance in most materials,while increased roughness tends to weaken surface corrosion resistance.展开更多
Fluid channeling caused by seal failure at the cement sheath-formation interface during fracturing is a severe problem in oil gas wells.In this study,a novel model was developed to evaluate interface sealing integrity...Fluid channeling caused by seal failure at the cement sheath-formation interface during fracturing is a severe problem in oil gas wells.In this study,a novel model was developed to evaluate interface sealing integrity.The model's accuracy was verified based on a self-developed interface seal evaluation device and an experiment.Subsequently,the interface seal under different formation conditions was investigated using this model.The theoretical calculation showed that for a cement sheath-carbonate formation interface,the channeling of acid-fracturing fluid caused interface seal failure and sustained casing pressure in the annulus space between the technical casing and formation.Mutual channeling between the fracturing sections occurred at the cement sheathshale formation interface during fracturing.For a sandstone formation,the interface seal failure caused the channeling between a water-bearing formation and a sandstone formation.Aiming at different formation conditions,the mechanical properties requirements of Young's modulus and Poisson's ratio of cement sheath were proposed respectively to ensure its seal integrity.The proposed model and method can be used to evaluate and optimize sealing integrity during fracturing.展开更多
Surface passivation with organic ammoniums improves perovskite solar cell performance by forming 2D/quasi-2D structures or adsorbing onto surfaces.However,complexity from mixed phases can trigger phase transitions,com...Surface passivation with organic ammoniums improves perovskite solar cell performance by forming 2D/quasi-2D structures or adsorbing onto surfaces.However,complexity from mixed phases can trigger phase transitions,compromising stability.The control of surface dimensionality after organic ammonium passivation presents significant importance to device stability.In this study,we developed a poly-fluorination strategy for surface treatment in perovskite solar cells,which enabled a high and durable interfacial phase purity after surface passivation.The locked surface dimensionality of perovskite was achieved through robust interaction between the poly-fluorinated ammoniums and the perovskite surface,along with the steric hindrance imparted by fluorine atoms,reducing its reactivity and penetration capabilities.The high hydrophobicity of the poly-fluorinated surface also aids in moisture resistance of the perovskite layer.The champion device achieved a power conversion efficiency(PCE)of 25.2% with certified 24.6%,with 90% of its initial PCE retained after approximately 1200 h under continuous 1-sun illumination,and over 14,400 h storage stability and superior stability under high-temperature operation.展开更多
To address problems in surface integrity and machining allowance distribution during combined electric arc-mechanical milling,this paper takes TC4 as the research object,examines the influence of electric arc milling(...To address problems in surface integrity and machining allowance distribution during combined electric arc-mechanical milling,this paper takes TC4 as the research object,examines the influence of electric arc milling(EAM)depth on recast layer thickness and surface roughness,alongside an analysis of the recast layer’s organization characteristics and sur-face morphology.A comparative evaluation of cutting forces,surface roughness,and surface hardening is conducted between combined milling and conventional mechanical milling.Key findings reveal that electric arc machining produces a recast layer with a hardness of 313.21 HV.As the EAM depth increases,the localized recast layer thickness and peak-to-valley(PV)differ-ences also rise.To ensure effective surface defect removal,the machining allowance for subsequent mechanical milling must exceed the combined thickness of the recast layer and the PV difference.Under identical parameters,combined milling yields higher surface roughness(0.584μm)and greater surface hardening(10.4%)compared to mechanical milling alone,alongside an 18.716 N increase in cutting force.Response surface methodology(RSM)analysis identifies feed per tooth as the most significant factor affecting surface roughness,followed by spindle speed,with milling depth having the least influence.展开更多
Machine Hammer Peening(MHP)is an emergent treatment that induces high compressive Residual Stresses(RS)which can enhance the in-service performance of components.This paper studies the use of small diameter MHP tools ...Machine Hammer Peening(MHP)is an emergent treatment that induces high compressive Residual Stresses(RS)which can enhance the in-service performance of components.This paper studies the use of small diameter MHP tools to improve the Surface Integrity(SI)of the nickel-based alloy Inconel 718 used in critical aero-engine components.Complementarily,the relaxation of RS is analyzed by in-situ annealing tests at in-service temperature combined with X-ray diffraction measurement.For this purpose,age hardened Inconel 718 discs were turned as reference condition,and then a pneumatic MHP tool was used under different conditions:two tool diameters(4 mm and 12 mm),feed rates(2.5 m/min and 5.0 m/min)and stepover distances(0.07 mm and 0.35 mm).Subsequently,surface topography characterization,RS measurements,nanoindentation tests,and microstructural observations were conducted.The in-situ annealing tests were done in the X-ray diffractometer at 550°C for exposure periods from 0 to 20 h.The results demonstrate that 4 mm diameter tools generate smooth surfaces and induce significant compressive RS within a0.5 mm thick layer.Residual stresses are relaxed,but they remain compressive even after a long thermal exposure.The microstructure of the surface layer(<10–15μm)was affected by the preceding turning operation,but importantly,MHP did not induce additional damage.展开更多
Understanding frictional anisotropy,which refers to the variation in frictional resistance based on the shear direction,is crucial for optimizing the friction angle between a bio-inspired structure and the surrounding...Understanding frictional anisotropy,which refers to the variation in frictional resistance based on the shear direction,is crucial for optimizing the friction angle between a bio-inspired structure and the surrounding soil.Previous studies focused on estimating the interface frictional anisotropy mobilized by snakeskin-inspired textured surfaces and sand under monotonic shear loading conditions.However,there is a need to estimate interface frictional anisotropy under repetitive shear loads.In this study,a series of repetitive direct shear(DS)tests are performed with snakeskin-inspired textured surfaces under a constant vertical stress and two shear directions(cranial first half→caudal second half or caudal first half→cranial second half).The results show that(1)mobilized shear stress increases with the number of shearing cycles,(2)cranial shearing(shearing against the scales)consistently produces a higher shear resistance and less contractive behavior than caudal shearing(shearing along the scales),and(3)a higher scale height or smaller scale length of the surface yields a higher interface friction angle across all shearing cycles.Further analysis reveals that the gap between the cranial and caudal shear zones of the interface friction angle as a function of L/H(i.e.the ratio of scale length L to scale height H)continues to decrease as the number of shearing cycles approaches asymptotic values.The directional frictional resistance(DFR)decreases as the number of shearing cycles increases.Furthermore,the discussion covers the impact of initial relative density,vertical stress,and the number of shearing cycles on interface frictional anisotropy.展开更多
For emerging renewable and sustainable energy technologies,single crystal materials have become key materials to enhance electrocatalytic performance because of their atomic-level ordered structures and tailorable sur...For emerging renewable and sustainable energy technologies,single crystal materials have become key materials to enhance electrocatalytic performance because of their atomic-level ordered structures and tailorable surface and interfacial properties.Various single crystal types,including metals,semiconductors,ceramics,organics,and nanocrystals,exhibit superior catalytic selectivity and stability in reactions such as water splitting and carbon/nitrogen cycles,benefiting from high electrical conductivity,tunable energy bands,and active sites with high surface energy.Through surface modification,interfacial atomic doping,and heterostructure construction,the distribution of active sites,electronic structure,and mass transport can be precisely regulated,significantly optimizing the catalytic kinetics of single crystal materials.In situ characterizations elucidate catalytic mechanisms at the atomic scale,while emerging methods like AI-assisted synthesis and bio-template directed growth offer pathways to overcome bottlenecks in the precision and cost of single crystal preparation.In addressing stability challenges in complex environments,strategies such as organic-inorganic hybridization and gradient interface design effectively mitigate interfacial instability.Future research should focus on cross-scale structural regulation and multidisciplinary integration to facilitate the transition of single crystal electrocatalysts from fundamental research to industrial applications,enabling efficient energy conversion.展开更多
Machined surface integrity of workpieces in harsh environments has a remarkable influence on their performance.However,the complexity of the new type of machining hinders a comprehensive understanding of machined surf...Machined surface integrity of workpieces in harsh environments has a remarkable influence on their performance.However,the complexity of the new type of machining hinders a comprehensive understanding of machined surface integrity and its formation mechanism,thereby limiting the study of component performance.With increasing demands for high-quality machined workpieces in aerospace industry applications,researchers from academia and industry are increasingly focusing on post-machining surface characterization.The profile grinding test was conducted on a novel single-crystal superalloy to simulate the formation of blade tenons,and the obtained tenons were characterized for surface integrity elements under various operating conditions.Results revealed that ultrasonic vibration-assisted grinding(UVAG)led to multiple superpositions of abrasive grain trajectories,causing reduced surface roughness(an average reduction of approximately29.6%)compared with conventional grinding.After examining the subsurface layer of UVAG using transmission electron microscopy,the results revealed that the single-crystal tenon grinding subsurface layer exhibited a gradient evolution from the near-surface to the substrate.This evolution was characterized by an equiaxed nanocrystalline layer measuring 0.34μm,followed by a submicrocrystalline grain-forming zone spanning 0.6μm and finally,a constituent phase-twisted dis-torted deformation zone over 0.62μm.Under normal grinding conditions,the tenon exhibited low surface hardening(not exceeding 15%),and residual compressive stresses were observed on its surface.In cases where grinding burns occurred,a white layer appeared on the tenon's surface,which demonstrated varying thicknesses along the teeth from top to root due to thermal-force-structural coupling effects.Additionally,these burns introduced residual tensile stresses on the tenon's surface,potentially substantially affecting its fatigue life.This paper enhances our understanding of UVAG processes and establishes a foundation for their application in manufacturing singlecrystal turbine blades for next-generation aero-turbine engines.展开更多
Topological insulators with localized edge or interface states have been extensively studied,particularly in phononic crystals and related fields;however,their application in seismic metamaterials remains largely unex...Topological insulators with localized edge or interface states have been extensively studied,particularly in phononic crystals and related fields;however,their application in seismic metamaterials remains largely unexplored.To address this gap,we designed a topological seismic metamaterial,where the topological interface is formed by joining the ends of two distinct one-dimensional periodic lattices.The first full-scale field experiment confirms the existence of topological interface states,which exhibit pronounced localization characteristics and induce a resonant amplification effect of 7.2 dB on the total energy of seismic surface waves.This study provides the first experimental validation for the implementation of topological principles in the design of seismic metamaterials,enabling novel approaches to high-sensitivity seismic detection and efficient energy localization for wave control.展开更多
Organic-inorganic hybrid metal halide perovskite solar cells(PSCs)have attracted much attention due to their high photoelectric conversion efficiency(PCE)and low cost.The certificated PCE of small active area(below 0....Organic-inorganic hybrid metal halide perovskite solar cells(PSCs)have attracted much attention due to their high photoelectric conversion efficiency(PCE)and low cost.The certificated PCE of small active area(below 0.1 cm^(2))device has reached 26.7%[1].However,when considering the scaled-up commercialization of PSCs,an obvious efficiency drop exists for the translation to large-area perovskite submodules(PSMs)with areas more than 200 cm^(2),thus limiting the practical commercialization[2].The major PCE gap between small area cells and large area modules arises the drop of open-circuit voltage(VOC)and fill factor(FF).Formamidinium lead iodide(FAPbI_(3))is now the mostly widely used and highly efficient perovskite composition.However,the photo-active black α-FAPbI_(3) phase will spontaneously transform into photo-inactive yellowδ-FAPbI_(3) phase at room temperature[3].展开更多
The technique of creep feed grinding is most suitable for geometrical shaping, and therefore has been expected to improve effectively material removal rate and surface quality of components with complex profile. This ...The technique of creep feed grinding is most suitable for geometrical shaping, and therefore has been expected to improve effectively material removal rate and surface quality of components with complex profile. This article studies experimentally the effects of process parameters （i.e. wheel speed, workpiece speed and depth of cut） on the grindability and surface integrity of cast nickel-based superalloys, i.e. K424, during creep feed grinding with brazed cubic boron nitride （CBN） abrasive wheels. Some important factors, such as grinding force and temperature, specific grinding energy, size stability, surface topography, microhardhess and microstructure alteration of the sub-surface, residual stresses, are investigated in detail. The results show that during creep feed grinding with brazed CBN wheels, low grinding temperature at about 100 ℃ is obtained though the specific grinding energy of nickel-based superalloys is high up to 200-300 J/mm^3. A combination of wheel speed 22.5 m/s, workpiece speed 0.1 m/min, depth of cut 0.2 mm accomplishes the straight grooves with the expected dimensional accuracy. Moreover, the compressive residual stresses are formed in the bum-free and crack-free ground surface.展开更多
Titanium alloy tenon is creep feed ground with monolayer brazed cubic boron nitride （CBN） shaped wheels. The dimension accuracy of the tenon is assessed and the results indicate that it completely meets the requirem...Titanium alloy tenon is creep feed ground with monolayer brazed cubic boron nitride （CBN） shaped wheels. The dimension accuracy of the tenon is assessed and the results indicate that it completely meets the requirement of blade tenon of aero-engine. Residual stresses, surface roughness, microstructure and microhardness are measured on ground surfaces of the specimen, which are all compared with that ground with vitrified CBN wheels. Under all the circumstances, compressive residual stress is obtained and the depth of the machining affected zone is found to be less than 40 μm. No phase transformation is observed at depths of up to 100 lain below the surface, though plastic deformation is visible in the process of grain refinement. The residual stress and microhardness of specimens ground with brazed CBN wheels are observed to be lower than those ground with vitrified ones. The arithmetic mean roughness （Ra） values obtained are all below 0.8μm.展开更多
Surface integrity of a new damage-tolerant titanium alloy （TC21）, including surface roughness, microhardness and metallurgical structure is investigated when normal and high speed milling are used at different tool ...Surface integrity of a new damage-tolerant titanium alloy （TC21）, including surface roughness, microhardness and metallurgical structure is investigated when normal and high speed milling are used at different tool wear status. Results show that good surface integrity of TC21 can be obtained in high speed milling. In addition, even in acutely worn stages, there is no so-called serious hardening layer （or white layer） according to the studies on microhardness and metallurgical structure.展开更多
An important step for achieving the knowledge-based design freedom on nano-and interfacial materials is attained by elucidating the related surface and interface thermodynamics from the first principles so as to allow...An important step for achieving the knowledge-based design freedom on nano-and interfacial materials is attained by elucidating the related surface and interface thermodynamics from the first principles so as to allow engineering the microstructures for desired properties through smartly designing fabrication processing parameters.This is demonstrated for SnO2 nano-particle surfaces and also a technologically important Ag-SnO2 interface fabricated by in-situ internal oxidation.Based on defect thermodynamics,we first modeled and calculated the equilibrium surface and interface structures,and as well corresponding properties,as a function of the ambient temperature and oxygen partial pressure.A series of first principles energetics calculations were then performed to construct the equilibrium surface and interface phase diagrams,to describe the environment dependence of the microstructures and properties of the surfaces and interfaces during fabrication and service conditions.The use and potential application of these phase diagrams as a process design tool were suggested and discussed.展开更多
To evaluate the new designed cutting tools for high-efficiency milling of the hardened die steel SKD11,surface integrities of millers with different geometric structures are analyzed, considering the surface roughness...To evaluate the new designed cutting tools for high-efficiency milling of the hardened die steel SKD11,surface integrities of millers with different geometric structures are analyzed, considering the surface roughness, micrograph of chips, surface microhardness, residual stress and metallurgical texture of the surface layer. The in fluences of geometric characteristics of different cutting tools and their wear characteristics on the surface integrity are studied. Results show that the milling tool with rake angle; 5 of the hardened diesteel. The generation of saw-tooth chips is depressed when a reasonable positive rake angle is selected. And the compressive residual stress is induced on the machined surface in milling the hardened die steel. The occurrence of surface softening is postponed by increasing the clearance angle and reducing the tool flank wear.展开更多
A CuPc/SiO2 sample is fabricated. Its morphology is characterized by atomic force microscopy, and the electron states are investigated by X-ray photoelectron spectroscopy. In order to investigate these spectra in deta...A CuPc/SiO2 sample is fabricated. Its morphology is characterized by atomic force microscopy, and the electron states are investigated by X-ray photoelectron spectroscopy. In order to investigate these spectra in detail, all of these spectra are normalized to the height of the most intense peak,and each component is fitted with a single Gaussian function. Analysis shows that the O element has great bearing on the electron states and that SiO2 layers produced by spurting technology are better than those produced by oxidation technology.展开更多
Titanium alloys are widely used in aeronautics that demand a good combination of high strength, good corrosion resistance and low mass. The mechanical properties lead to challenges in machining operations such as high...Titanium alloys are widely used in aeronautics that demand a good combination of high strength, good corrosion resistance and low mass. The mechanical properties lead to challenges in machining operations such as high process temperature as well as rapidly increasing tool wear. The conventional tool materials are not able to maintain their hardness and other mechanical prop- erties at higher cutting temperatures encountered in high speed machining. In this work, the new material tools, which are poly- crystalline diamond （PCD） and polycrystalline cubic boron nitride （PCBN） tools, are used in high-speed milling of Ti-6.5AI-2Zr-IMo-IV （TA15） alloy. The performance and wear mechanism of the tools are investigated. Compared to PCBN tool, PCD tool has a much longer tool life, especially at higher cutting speeds. Analyses based on the SEM and EDX suggest that attrition, adhesion and diffusion are the main wear mechanisms of PCD and PCBN tools in high-speed milling of TA 15. Oxida- tion wear is also observed at PCBN tool/workpiece interface. Roughness, defects, micro-hardness and microstructure of the ma- chined surface are investigated. The recorded surface roughness values with PCD/PCBN tools are bellow 0.3 μm at initial and steady cutting stage. Micro-hardness analysis shows that the machined surface hardening depth with PCD and PCBN tools is small. There is no evidence of sub-surface defects with PCD and PCBN tools. It is concluded that for TA15 alloy, high-speed milling can be carried out with PCD/PCBN tools.展开更多
Due to its superior nanoscale properties,cobalt(Co)is highly desirable for ultrahigh-density 3D integration into materials through metal/dielectric hybrid bonding.However,this process is very challenging through Co/Si...Due to its superior nanoscale properties,cobalt(Co)is highly desirable for ultrahigh-density 3D integration into materials through metal/dielectric hybrid bonding.However,this process is very challenging through Co/SiO_(2)hybrid bonding,as very hydrophilic SiO_(2)surfaces are needed for bonding during dehydration reactions and oxidation of the Co surfaces must be avoided.Additionally,the substantial coefficient of thermal expansion mismatch between the robust capping layers(Co and SiO_(2)layers)necessitates hybrid bonding with minimal thermal input and compression.In this study,we introduce a ternary plasma activation strategy employing an Ar/NH_(3)/H_(2)O gas mixture to facilitate Co/SiO_(2)hybrid bonding at temperatures as low as~200℃,which is markedly lower than the melting point of Co(~1500℃).Intriguingly,non-oxide metallization at the Co-Co interface can be realized without the hindrance of a bonding barrier,thereby reducing the electrical resistance by over 40%and compression force requirements.Moreover,the enhancement in the SiO_(2)surface energy through active group terminations fosters extensive interfacial hydration and strengthens the mechanical properties.This research paves the way for fine-tuning bonding surfaces using a material-selective strategy which should advance metal/dielectric hybrid bonding for future integration applications.展开更多
An experimental study was carried out to investigat e the influence of temperatures on workpiece surface integrity in surface grinding of a cast nickel-based superalloy with alumina abrasive wheels. Temperatur e respo...An experimental study was carried out to investigat e the influence of temperatures on workpiece surface integrity in surface grinding of a cast nickel-based superalloy with alumina abrasive wheels. Temperatur e response at the wheel-workpiece interface was measured using a grindable foil /workpiece thermocouple. Specimens with different grinding temperatures were obt ained through changing grinding conditions including depth of cut, workpiece fee d speed, and coolant supply. Changes in surface roughness, residual stress, meta llographies, ground surface morphology, and micro hardness on the specimens were then analyzed. Bending fatigue tests were separately conducted at room temperat ure and 950oC in an effort to evaluate the influence of temperatures on the serv ice life of the ground specimens. A different burning color was found on the gro und workpiece surfaces when grinding temperatures are over a critical value. Alo ng with the emergence of burning color, roughness of the ground workpiece surfac e increased greatly compared with the surfaces without burning color, which was attributed to the plastically deformed coatings on the workpiece surface with el evated temperatures. Excepting the surface roughness, other items concerning the surface integrity of the ground workpiece were not affected by temperatures pro vided that grinding temperatures are not high enough to cause grinding cracks. B ased on the findings in this study, the grinding of the nickel-based superalloy can be divided into two stages in order to increase production efficiency, in which case the first stage is to reach an high material removal rate without concerning of the presence of burning color, whereas the second stage is to remo ve the plastically deformed coatings in order to decrease surface roughness.展开更多
基金financially supported by the National Key R&D Program of China(No.2022YFE0121300)the National Natural Science Foundation of China(No.52374376)the Introduction Plan for High-end Foreign Experts(No.G2023105001L)。
文摘As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine properties.Fractal analysis has been used to characterize the shapes of metal materials at various scales and dimensions.Conventional methods make it difficult to quantitatively describe the relationship between the regular characteristics and properties of metal material surfaces and interfaces.However,fractal analysis can be used to quantitatively describe the shape characteristics of metal materials and to establish the quantitative relationships between the shape characteristics and various properties of metal materials.From the perspective of two-dimensional planes and three-dimensional curved surfaces,this paper reviews the current research status of the fractal analysis of metal precipitate interfaces,metal grain boundary interfaces,metal-deposited film surfaces,metal fracture surfaces,metal machined surfaces,and metal wear surfaces.The relationship between the fractal dimensions and properties of metal material surfaces and interfaces is summarized.Starting from three perspectives of fractal analysis,namely,research scope,image acquisition methods,and calculation methods,this paper identifies the direction of research on fractal analysis of metal material surfaces and interfaces that need to be developed.It is believed that revealing the deep influence mechanism between the fractal dimensions and properties of metal material surfaces and interfaces will be the key research direction of the fractal analysis of metal materials in the future.
基金Introduction of Talent Research Start-up Fund of Anhui University of Science and Technology(2022yjrc35)Colleges and Universities Excellent Young Talents Domestic Visit Research Project of Anhui Province(gxgnfx2022006)。
文摘According to surface morphology,microhardness,X-ray diffraction,and static contact angle experiments,the changes in the surface integrity and corrosion resistance of 6061-T6 aluminum alloy after ultrasonic shot peening(USP)were investigated.Results show that the grain size of the material surface is reduced by 43%,the residual compressive stress has an increasing trend,the roughness and hardness are increased by approximately 211.1%and 35%,respectively.And the static contact angle is increased at first,followed by a slight decrease.Weighing,scanning electron microscope,and energy dispersive spectrometer were used to study the samples after a cyclic corrosion test.Results show that USP reduces the corrosion rate by 41.2%.A model of surface corrosion mechanism of USP is developed,and the mechanism of USP to improve the corrosion resistance of materials is discussed.The introduction of compressive residual stresses,grain refinement,increased grain boundaries,increased hardness,and increased static contact angle are the main factors related to the improvement of corrosion resistance in most materials,while increased roughness tends to weaken surface corrosion resistance.
基金the financial support provide by the National Natural Science Foundation of China(No.52304009)the Natural Science Foundation of Sichuan(No.2023NSFSC0927)the Sichuan Province Innovative Talent Funding Project for Postdoctoral Fellows(No.BX202305)。
文摘Fluid channeling caused by seal failure at the cement sheath-formation interface during fracturing is a severe problem in oil gas wells.In this study,a novel model was developed to evaluate interface sealing integrity.The model's accuracy was verified based on a self-developed interface seal evaluation device and an experiment.Subsequently,the interface seal under different formation conditions was investigated using this model.The theoretical calculation showed that for a cement sheath-carbonate formation interface,the channeling of acid-fracturing fluid caused interface seal failure and sustained casing pressure in the annulus space between the technical casing and formation.Mutual channeling between the fracturing sections occurred at the cement sheathshale formation interface during fracturing.For a sandstone formation,the interface seal failure caused the channeling between a water-bearing formation and a sandstone formation.Aiming at different formation conditions,the mechanical properties requirements of Young's modulus and Poisson's ratio of cement sheath were proposed respectively to ensure its seal integrity.The proposed model and method can be used to evaluate and optimize sealing integrity during fracturing.
基金grants(grant numbers LR24F040001,LD24E020001 and LD22E020002)from the Natural Science Foundation of Zhejiang Province of Chinathe National Natural Science Foundation of China(grant number 62274146)+1 种基金the support of Key R&D Program of Zhejiang(2024SSYS0061)supported by the Fundamental Research Funds for the Central Universities(226-2022-00200).
文摘Surface passivation with organic ammoniums improves perovskite solar cell performance by forming 2D/quasi-2D structures or adsorbing onto surfaces.However,complexity from mixed phases can trigger phase transitions,compromising stability.The control of surface dimensionality after organic ammonium passivation presents significant importance to device stability.In this study,we developed a poly-fluorination strategy for surface treatment in perovskite solar cells,which enabled a high and durable interfacial phase purity after surface passivation.The locked surface dimensionality of perovskite was achieved through robust interaction between the poly-fluorinated ammoniums and the perovskite surface,along with the steric hindrance imparted by fluorine atoms,reducing its reactivity and penetration capabilities.The high hydrophobicity of the poly-fluorinated surface also aids in moisture resistance of the perovskite layer.The champion device achieved a power conversion efficiency(PCE)of 25.2% with certified 24.6%,with 90% of its initial PCE retained after approximately 1200 h under continuous 1-sun illumination,and over 14,400 h storage stability and superior stability under high-temperature operation.
基金supported by the National Natural Science Foundation of China“Study on the evolution law of discharge channel and deformation suppression method for low-pressure micro-arc milling machining of aerospace thin-walled parts”(52265061)The Tianshan Innovation Team“Robotics and intelligent equipment technology science and technology innovation team”(2022D14002).
文摘To address problems in surface integrity and machining allowance distribution during combined electric arc-mechanical milling,this paper takes TC4 as the research object,examines the influence of electric arc milling(EAM)depth on recast layer thickness and surface roughness,alongside an analysis of the recast layer’s organization characteristics and sur-face morphology.A comparative evaluation of cutting forces,surface roughness,and surface hardening is conducted between combined milling and conventional mechanical milling.Key findings reveal that electric arc machining produces a recast layer with a hardness of 313.21 HV.As the EAM depth increases,the localized recast layer thickness and peak-to-valley(PV)differ-ences also rise.To ensure effective surface defect removal,the machining allowance for subsequent mechanical milling must exceed the combined thickness of the recast layer and the PV difference.Under identical parameters,combined milling yields higher surface roughness(0.584μm)and greater surface hardening(10.4%)compared to mechanical milling alone,alongside an 18.716 N increase in cutting force.Response surface methodology(RSM)analysis identifies feed per tooth as the most significant factor affecting surface roughness,followed by spindle speed,with milling depth having the least influence.
基金the financial support given by EPSRC to the Grant LOFAMO(No.EP/X023281/1)the Basque Government for the financial support given from Elkartek Program to the Project FRONTIERS 2022—Superficies Multifuncionales en la Frontera del Conocimiento(No.KK2022/00109)。
文摘Machine Hammer Peening(MHP)is an emergent treatment that induces high compressive Residual Stresses(RS)which can enhance the in-service performance of components.This paper studies the use of small diameter MHP tools to improve the Surface Integrity(SI)of the nickel-based alloy Inconel 718 used in critical aero-engine components.Complementarily,the relaxation of RS is analyzed by in-situ annealing tests at in-service temperature combined with X-ray diffraction measurement.For this purpose,age hardened Inconel 718 discs were turned as reference condition,and then a pneumatic MHP tool was used under different conditions:two tool diameters(4 mm and 12 mm),feed rates(2.5 m/min and 5.0 m/min)and stepover distances(0.07 mm and 0.35 mm).Subsequently,surface topography characterization,RS measurements,nanoindentation tests,and microstructural observations were conducted.The in-situ annealing tests were done in the X-ray diffractometer at 550°C for exposure periods from 0 to 20 h.The results demonstrate that 4 mm diameter tools generate smooth surfaces and induce significant compressive RS within a0.5 mm thick layer.Residual stresses are relaxed,but they remain compressive even after a long thermal exposure.The microstructure of the surface layer(<10–15μm)was affected by the preceding turning operation,but importantly,MHP did not induce additional damage.
基金the funding supported from the National Research Foundation of Korea(NRF)grant funded by the Korea Government MSIT(No.2021R1C1C1006003).
文摘Understanding frictional anisotropy,which refers to the variation in frictional resistance based on the shear direction,is crucial for optimizing the friction angle between a bio-inspired structure and the surrounding soil.Previous studies focused on estimating the interface frictional anisotropy mobilized by snakeskin-inspired textured surfaces and sand under monotonic shear loading conditions.However,there is a need to estimate interface frictional anisotropy under repetitive shear loads.In this study,a series of repetitive direct shear(DS)tests are performed with snakeskin-inspired textured surfaces under a constant vertical stress and two shear directions(cranial first half→caudal second half or caudal first half→cranial second half).The results show that(1)mobilized shear stress increases with the number of shearing cycles,(2)cranial shearing(shearing against the scales)consistently produces a higher shear resistance and less contractive behavior than caudal shearing(shearing along the scales),and(3)a higher scale height or smaller scale length of the surface yields a higher interface friction angle across all shearing cycles.Further analysis reveals that the gap between the cranial and caudal shear zones of the interface friction angle as a function of L/H(i.e.the ratio of scale length L to scale height H)continues to decrease as the number of shearing cycles approaches asymptotic values.The directional frictional resistance(DFR)decreases as the number of shearing cycles increases.Furthermore,the discussion covers the impact of initial relative density,vertical stress,and the number of shearing cycles on interface frictional anisotropy.
基金supported by National Natural Science Foundation of China(No.52202366)Taishan Scholar Project of Shandong Province(tstp20240515,tsqn202312217)+1 种基金Natural Science Foundation of Shandong Province(China,No.2025HWYQ-050,ZR2021QE011,ZR2022QH072,ZR2021QE284)the King Abdullah University of Science and Technology,the Center of Excellence for Renewable Energy and Storage Technologies.
文摘For emerging renewable and sustainable energy technologies,single crystal materials have become key materials to enhance electrocatalytic performance because of their atomic-level ordered structures and tailorable surface and interfacial properties.Various single crystal types,including metals,semiconductors,ceramics,organics,and nanocrystals,exhibit superior catalytic selectivity and stability in reactions such as water splitting and carbon/nitrogen cycles,benefiting from high electrical conductivity,tunable energy bands,and active sites with high surface energy.Through surface modification,interfacial atomic doping,and heterostructure construction,the distribution of active sites,electronic structure,and mass transport can be precisely regulated,significantly optimizing the catalytic kinetics of single crystal materials.In situ characterizations elucidate catalytic mechanisms at the atomic scale,while emerging methods like AI-assisted synthesis and bio-template directed growth offer pathways to overcome bottlenecks in the precision and cost of single crystal preparation.In addressing stability challenges in complex environments,strategies such as organic-inorganic hybridization and gradient interface design effectively mitigate interfacial instability.Future research should focus on cross-scale structural regulation and multidisciplinary integration to facilitate the transition of single crystal electrocatalysts from fundamental research to industrial applications,enabling efficient energy conversion.
基金supported by the National Natural Science Foundation of China(Nos.92160301,92060203,52175415,52205475,and 52322510)the Science Center for Gas Turbine Project(No.P2023-B-IV-003-001)+1 种基金the Huaqiao University Engineering Research Center of Brittle Materials Machining(No.2023IME-001)the Natural Science Foundation of Jiangsu Province(No.BK20210295).
文摘Machined surface integrity of workpieces in harsh environments has a remarkable influence on their performance.However,the complexity of the new type of machining hinders a comprehensive understanding of machined surface integrity and its formation mechanism,thereby limiting the study of component performance.With increasing demands for high-quality machined workpieces in aerospace industry applications,researchers from academia and industry are increasingly focusing on post-machining surface characterization.The profile grinding test was conducted on a novel single-crystal superalloy to simulate the formation of blade tenons,and the obtained tenons were characterized for surface integrity elements under various operating conditions.Results revealed that ultrasonic vibration-assisted grinding(UVAG)led to multiple superpositions of abrasive grain trajectories,causing reduced surface roughness(an average reduction of approximately29.6%)compared with conventional grinding.After examining the subsurface layer of UVAG using transmission electron microscopy,the results revealed that the single-crystal tenon grinding subsurface layer exhibited a gradient evolution from the near-surface to the substrate.This evolution was characterized by an equiaxed nanocrystalline layer measuring 0.34μm,followed by a submicrocrystalline grain-forming zone spanning 0.6μm and finally,a constituent phase-twisted dis-torted deformation zone over 0.62μm.Under normal grinding conditions,the tenon exhibited low surface hardening(not exceeding 15%),and residual compressive stresses were observed on its surface.In cases where grinding burns occurred,a white layer appeared on the tenon's surface,which demonstrated varying thicknesses along the teeth from top to root due to thermal-force-structural coupling effects.Additionally,these burns introduced residual tensile stresses on the tenon's surface,potentially substantially affecting its fatigue life.This paper enhances our understanding of UVAG processes and establishes a foundation for their application in manufacturing singlecrystal turbine blades for next-generation aero-turbine engines.
基金supported by the National Natural Science Foundation of China(Grant No.11974044)。
文摘Topological insulators with localized edge or interface states have been extensively studied,particularly in phononic crystals and related fields;however,their application in seismic metamaterials remains largely unexplored.To address this gap,we designed a topological seismic metamaterial,where the topological interface is formed by joining the ends of two distinct one-dimensional periodic lattices.The first full-scale field experiment confirms the existence of topological interface states,which exhibit pronounced localization characteristics and induce a resonant amplification effect of 7.2 dB on the total energy of seismic surface waves.This study provides the first experimental validation for the implementation of topological principles in the design of seismic metamaterials,enabling novel approaches to high-sensitivity seismic detection and efficient energy localization for wave control.
基金support from open fund of Fujian Provincial Key Laboratory of Functional Materials and Applications(Xiamen University of Technology,fma2024003)the National Key R&D Program of China(No.2021YFB3500400)the National Natural Science Foundation of China(Nos.52073286 and 22275185).
文摘Organic-inorganic hybrid metal halide perovskite solar cells(PSCs)have attracted much attention due to their high photoelectric conversion efficiency(PCE)and low cost.The certificated PCE of small active area(below 0.1 cm^(2))device has reached 26.7%[1].However,when considering the scaled-up commercialization of PSCs,an obvious efficiency drop exists for the translation to large-area perovskite submodules(PSMs)with areas more than 200 cm^(2),thus limiting the practical commercialization[2].The major PCE gap between small area cells and large area modules arises the drop of open-circuit voltage(VOC)and fill factor(FF).Formamidinium lead iodide(FAPbI_(3))is now the mostly widely used and highly efficient perovskite composition.However,the photo-active black α-FAPbI_(3) phase will spontaneously transform into photo-inactive yellowδ-FAPbI_(3) phase at room temperature[3].
基金National Basic Research Program of China (2009CB724403)Program for Changjiang Scholars and Innovative Research Team in University (IRT0837)Program for New Century Excellent Talents in University from Ministry of Education of China (NCET-07-0435)
文摘The technique of creep feed grinding is most suitable for geometrical shaping, and therefore has been expected to improve effectively material removal rate and surface quality of components with complex profile. This article studies experimentally the effects of process parameters （i.e. wheel speed, workpiece speed and depth of cut） on the grindability and surface integrity of cast nickel-based superalloys, i.e. K424, during creep feed grinding with brazed cubic boron nitride （CBN） abrasive wheels. Some important factors, such as grinding force and temperature, specific grinding energy, size stability, surface topography, microhardhess and microstructure alteration of the sub-surface, residual stresses, are investigated in detail. The results show that during creep feed grinding with brazed CBN wheels, low grinding temperature at about 100 ℃ is obtained though the specific grinding energy of nickel-based superalloys is high up to 200-300 J/mm^3. A combination of wheel speed 22.5 m/s, workpiece speed 0.1 m/min, depth of cut 0.2 mm accomplishes the straight grooves with the expected dimensional accuracy. Moreover, the compressive residual stresses are formed in the bum-free and crack-free ground surface.
基金National Fundamental Research Program of China (2009CB724403)Program for New Century Excellent Talents in University from Ministry of Education of China (NCET-07-0435)
文摘Titanium alloy tenon is creep feed ground with monolayer brazed cubic boron nitride （CBN） shaped wheels. The dimension accuracy of the tenon is assessed and the results indicate that it completely meets the requirement of blade tenon of aero-engine. Residual stresses, surface roughness, microstructure and microhardness are measured on ground surfaces of the specimen, which are all compared with that ground with vitrified CBN wheels. Under all the circumstances, compressive residual stress is obtained and the depth of the machining affected zone is found to be less than 40 μm. No phase transformation is observed at depths of up to 100 lain below the surface, though plastic deformation is visible in the process of grain refinement. The residual stress and microhardness of specimens ground with brazed CBN wheels are observed to be lower than those ground with vitrified ones. The arithmetic mean roughness （Ra） values obtained are all below 0.8μm.
基金Supported by the National Natural Science Foundation of China(50975141)the National Scienceand Technology Major Project(2010ZX04012-042)the Aeronautical Science Foundation(2010352005)~~
文摘Surface integrity of a new damage-tolerant titanium alloy （TC21）, including surface roughness, microhardness and metallurgical structure is investigated when normal and high speed milling are used at different tool wear status. Results show that good surface integrity of TC21 can be obtained in high speed milling. In addition, even in acutely worn stages, there is no so-called serious hardening layer （or white layer） according to the studies on microhardness and metallurgical structure.
基金Project(51171211) supported by the National Natural Science Foundation of ChinaProject(NCET-10-0837) supported by the Chinese Ministry of Education's Supportive Program for New Century Excellent Talents in UniversitiesProject(2006BAE03B03) supported by the Chinese National Science and Technology Supportive Program
文摘An important step for achieving the knowledge-based design freedom on nano-and interfacial materials is attained by elucidating the related surface and interface thermodynamics from the first principles so as to allow engineering the microstructures for desired properties through smartly designing fabrication processing parameters.This is demonstrated for SnO2 nano-particle surfaces and also a technologically important Ag-SnO2 interface fabricated by in-situ internal oxidation.Based on defect thermodynamics,we first modeled and calculated the equilibrium surface and interface structures,and as well corresponding properties,as a function of the ambient temperature and oxygen partial pressure.A series of first principles energetics calculations were then performed to construct the equilibrium surface and interface phase diagrams,to describe the environment dependence of the microstructures and properties of the surfaces and interfaces during fabrication and service conditions.The use and potential application of these phase diagrams as a process design tool were suggested and discussed.
文摘To evaluate the new designed cutting tools for high-efficiency milling of the hardened die steel SKD11,surface integrities of millers with different geometric structures are analyzed, considering the surface roughness, micrograph of chips, surface microhardness, residual stress and metallurgical texture of the surface layer. The in fluences of geometric characteristics of different cutting tools and their wear characteristics on the surface integrity are studied. Results show that the milling tool with rake angle; 5 of the hardened diesteel. The generation of saw-tooth chips is depressed when a reasonable positive rake angle is selected. And the compressive residual stress is induced on the machined surface in milling the hardened die steel. The occurrence of surface softening is postponed by increasing the clearance angle and reducing the tool flank wear.
文摘A CuPc/SiO2 sample is fabricated. Its morphology is characterized by atomic force microscopy, and the electron states are investigated by X-ray photoelectron spectroscopy. In order to investigate these spectra in detail, all of these spectra are normalized to the height of the most intense peak,and each component is fitted with a single Gaussian function. Analysis shows that the O element has great bearing on the electron states and that SiO2 layers produced by spurting technology are better than those produced by oxidation technology.
基金National High-tech Research and Development Program of China (2009AA04Z116)Program for Changjiang Scholars and Innovative Research Team in University ( IRT0837)
文摘Titanium alloys are widely used in aeronautics that demand a good combination of high strength, good corrosion resistance and low mass. The mechanical properties lead to challenges in machining operations such as high process temperature as well as rapidly increasing tool wear. The conventional tool materials are not able to maintain their hardness and other mechanical prop- erties at higher cutting temperatures encountered in high speed machining. In this work, the new material tools, which are poly- crystalline diamond （PCD） and polycrystalline cubic boron nitride （PCBN） tools, are used in high-speed milling of Ti-6.5AI-2Zr-IMo-IV （TA15） alloy. The performance and wear mechanism of the tools are investigated. Compared to PCBN tool, PCD tool has a much longer tool life, especially at higher cutting speeds. Analyses based on the SEM and EDX suggest that attrition, adhesion and diffusion are the main wear mechanisms of PCD and PCBN tools in high-speed milling of TA 15. Oxida- tion wear is also observed at PCBN tool/workpiece interface. Roughness, defects, micro-hardness and microstructure of the ma- chined surface are investigated. The recorded surface roughness values with PCD/PCBN tools are bellow 0.3 μm at initial and steady cutting stage. Micro-hardness analysis shows that the machined surface hardening depth with PCD and PCBN tools is small. There is no evidence of sub-surface defects with PCD and PCBN tools. It is concluded that for TA15 alloy, high-speed milling can be carried out with PCD/PCBN tools.
基金supported by the National Natural Science Foundation of China(Grant Nos.92164105 and 51975151)the Heilongjiang Provincial Natural Science Foundation of China under grant LH2019E041+1 种基金the Heilongjiang Touyan Innovation Team Program(HITTY-20190013)State Key Laboratory of Precision Welding&Joining of Materials and Structures(No.24-T-04)。
文摘Due to its superior nanoscale properties,cobalt(Co)is highly desirable for ultrahigh-density 3D integration into materials through metal/dielectric hybrid bonding.However,this process is very challenging through Co/SiO_(2)hybrid bonding,as very hydrophilic SiO_(2)surfaces are needed for bonding during dehydration reactions and oxidation of the Co surfaces must be avoided.Additionally,the substantial coefficient of thermal expansion mismatch between the robust capping layers(Co and SiO_(2)layers)necessitates hybrid bonding with minimal thermal input and compression.In this study,we introduce a ternary plasma activation strategy employing an Ar/NH_(3)/H_(2)O gas mixture to facilitate Co/SiO_(2)hybrid bonding at temperatures as low as~200℃,which is markedly lower than the melting point of Co(~1500℃).Intriguingly,non-oxide metallization at the Co-Co interface can be realized without the hindrance of a bonding barrier,thereby reducing the electrical resistance by over 40%and compression force requirements.Moreover,the enhancement in the SiO_(2)surface energy through active group terminations fosters extensive interfacial hydration and strengthens the mechanical properties.This research paves the way for fine-tuning bonding surfaces using a material-selective strategy which should advance metal/dielectric hybrid bonding for future integration applications.
文摘An experimental study was carried out to investigat e the influence of temperatures on workpiece surface integrity in surface grinding of a cast nickel-based superalloy with alumina abrasive wheels. Temperatur e response at the wheel-workpiece interface was measured using a grindable foil /workpiece thermocouple. Specimens with different grinding temperatures were obt ained through changing grinding conditions including depth of cut, workpiece fee d speed, and coolant supply. Changes in surface roughness, residual stress, meta llographies, ground surface morphology, and micro hardness on the specimens were then analyzed. Bending fatigue tests were separately conducted at room temperat ure and 950oC in an effort to evaluate the influence of temperatures on the serv ice life of the ground specimens. A different burning color was found on the gro und workpiece surfaces when grinding temperatures are over a critical value. Alo ng with the emergence of burning color, roughness of the ground workpiece surfac e increased greatly compared with the surfaces without burning color, which was attributed to the plastically deformed coatings on the workpiece surface with el evated temperatures. Excepting the surface roughness, other items concerning the surface integrity of the ground workpiece were not affected by temperatures pro vided that grinding temperatures are not high enough to cause grinding cracks. B ased on the findings in this study, the grinding of the nickel-based superalloy can be divided into two stages in order to increase production efficiency, in which case the first stage is to reach an high material removal rate without concerning of the presence of burning color, whereas the second stage is to remo ve the plastically deformed coatings in order to decrease surface roughness.
