We demonstrate surface enhanced Raman scattering （SERS） detection of self-assembled nano silver film using a low-cost electrolysis strategy at a proper voltage and silver nitrate concentration in electrolyte. The co...We demonstrate surface enhanced Raman scattering （SERS） detection of self-assembled nano silver film using a low-cost electrolysis strategy at a proper voltage and silver nitrate concentration in electrolyte. The concentration dependence of SERS from crystal violet （CV） molecules adsorbed to silver film was systematically studied. Importantly, the SERS surface enhancement factor of such nano silver film was 603, which was measured by a portable Raman spectrometer. The minimum concentration of detectable CV molecules can be as low as 10^-11 mol/L. The nano silver film prepared by this electrolysis method is an active, stable, cost-effective, and reusable SERS substrate.展开更多
This paper examined how microstructure influences the homogenized thermal conductivity of cellular structures and revealed a surface-induced size-dependent effect.This effect is linked to the porous microstructural fe...This paper examined how microstructure influences the homogenized thermal conductivity of cellular structures and revealed a surface-induced size-dependent effect.This effect is linked to the porous microstructural features of cellular structures,which stems from the degree of porosity and the distri-bution of the pores.Unlike the phonon-driven surface effect at the nanoscale,the macro-scale surface mechanism in thermal cellular structures is found to be the microstructure-induced changes in the heat conduction path based on fully resolved 3D numerical simulations.The surface region is determined by the microstructure,characterized by the intrinsic length.With the coupling between extrinsic and intrinsic length scales under the surface mechanism,a surface-enriched multiscale method was devel-oped to accurately capture the complex size-dependent thermal conductivity.The principle of scale separation required by classical multiscale methods is not necessary to be satisfied by the proposed multiscale method.The significant potential of the surface-enriched multiscale method was demon-strated through simulations of the effective thermal conductivity of a thin-walled metamaterial struc-ture.The surface-enriched multiscale method offers higher accuracy compared with the classical multiscale method and superior efficiency over high-fidelity finite element methods.展开更多
In order to improve the quality of 3D printed raspberry preserves after post-processing,microwave ovens combining infrared and microwave methods were utilized.The effects of infrared heating temperature,infrared heati...In order to improve the quality of 3D printed raspberry preserves after post-processing,microwave ovens combining infrared and microwave methods were utilized.The effects of infrared heating temperature,infrared heating time,microwave power,microwave heating time on the center temperature,moisture content,the chroma(C*),the total color difference(ΔE*),shape fidelity,hardness,and the total anthocyanin content of 3D printed raspberry preserves were analyzed by response surface method(RSM).The results showed that under combining with the two methods,infrared heating improved the fidelity and quality degradation of printed products,while microwave heating enhanced the efficiency of infrared heating.Infrared-microwave combination cooking could maintain relatively stable color appearance and shape of 3D printed raspberry preserves.The AHP–CRITIC hybrid weighting method combined with the response surface test to determine the comprehensive weights of the evaluation indicators optimized the process parameters,and the optimal process parameters were obtained:infrared heating temperature of 190℃,infrared heating time of 10 min and 30 s,microwave power of 300 W,and microwave heating time of 2 min and 6 s.The 3D printed raspberry cooking methods obtained under the optimal conditions seldom had color variation,porous structure,uniform texture,and high shape fidelity,which retained the characteristics of personalized manufacturing by 3D printing.This study could provide a reference for the postprocessing and quality control of 3D cooking methods.展开更多
Anode-free lithium metal batteries are prone to capacity degradation and safety hazards due to the formation and growth of lithium dendrites.The interface between the current collector and deposited lithium plays a cr...Anode-free lithium metal batteries are prone to capacity degradation and safety hazards due to the formation and growth of lithium dendrites.The interface between the current collector and deposited lithium plays a critical role in preventing dendrite formation by regulating the thermodynamics and kinetics of lithium deposition.In this study,we develop a phase field model to investigate the influence of the current collector’s surface energy on lithium deposition morphology and its effect on the quality of the lithium metal film.It is demonstrated that a higher surface energy of the current collector promotes the growth of lithium metal along the surface of the current collector.Further,our simulation results show that a higher surface energy accelerates the formation of the lithium metal film while simultaneously reducing its surface roughness.By examining different contact angles and applied potentials,we construct a phase diagram of deposition morphology,illustrating that increased surface energy facilitates the dense and uniform deposition of lithium metal by preventing the formation of lithium filaments and voids.These findings provide new insights into the development and application of anode-free lithium metal batteries.展开更多
An advanced Actuator Surface Method(ASM)coupled with Computational Fluid Dynamics(CFD)is developed and applied to the complex unsteady aerodynamic simulation of helicopter.By introducing an improved three-dimensional ...An advanced Actuator Surface Method(ASM)coupled with Computational Fluid Dynamics(CFD)is developed and applied to the complex unsteady aerodynamic simulation of helicopter.By introducing an improved three-dimensional anisotropic Gaussian kernel,this method effectively addresses the severe aerodynamic load fluctuations commonly associated with traditional Virtual Blade Method(VBM)due to turbulent flow around blade elements.To manage the issues of regional shape and grid cell quantity variations caused by virtual blade sweeping,a universal hybrid grid generation strategy is established without body-fitted and disk interpolation grids,which enhances the computational stability at both blade elements and blade edges.Aerodynamic numerical simulations of helicopter are performed using this method,focusing on rotor/fuselage interaction dominated by rotor wake motion and fuselage blockage effects,Blade-Vortex Interaction(BVI)induced by tip vortices,and maneuvering flights involving collective pitch ramp increases.The results indicate that the advanced ASM demonstrates reliability and robustness in the simulation of complex unsteady flow fields around helicopter.Under similar computational accuracy,the advanced ASM improves computational efficiency by nearly 40 times compared to the oversetgrid-based full Blade-Resolved(B-R)method,and by 6 times compared to the VBM.It shows significant advantages when applied to complex full-aircraft interaction and maneuvering flight conditions that require substantial computational resources.展开更多
This study proposes an alternative calculation mode for stresses on the slip surface(SS).The calculation of the normal stress(NS)on the SS involves examining its composition and expanding its unknown using the Taylor ...This study proposes an alternative calculation mode for stresses on the slip surface(SS).The calculation of the normal stress(NS)on the SS involves examining its composition and expanding its unknown using the Taylor series.This expansion enables the reasonable construction of a function describing the NS on the SS.Additionally,by directly incorporating the nonlinear Generalized Hoke-Brown(GHB)strength criterion and utilizing the slope factor of safety(FOS)definition,a function of the shear stress on the SS is derived.This function considers the mutual feedback mechanism between the NS and strength parameters of the SS.The stress constraints conditions are then introduced at both ends of the SS based on the spatial stress relation of one point.Determining the slope FOS and stress solution for the SS involves considering the mechanical equilibrium conditions and the stress constraint conditions satisfied by the sliding body.The proposed approach successfully simulates the tension-shear stress zone near the slope top and provides an intuitive description of the concentration effect of compression-shear stress of the SS near the slope toe.Furthermore,compared to other methods,the present method demonstrates superior processing capabilities for the embedded nonlinear GHB strength criterion.展开更多
Mimicry of nature drives the development of bionic materials.Bionic superhydrophobic materials are a kind of high-efficiency materials to handle oil spills and water pollution.However,the stability of surface coatings...Mimicry of nature drives the development of bionic materials.Bionic superhydrophobic materials are a kind of high-efficiency materials to handle oil spills and water pollution.However,the stability of surface coatings of the superhydrophobic materials remains a challenge.Herein,a new category of self-assembly bionic superhydrophobic surface coating was prepared via one-step condensation/copolymerization of vinyltriethoxysilane(VTES)and divinylbenzene(DVB),which realized the close combination of covalent bonds between organic(e.g.DVB)and inorganic matter(e.g.VTES),and avoided the swelling of polydivinylbenzene(PDVB)in the process of collection of oil from water.This organic-inorganic hybrid polymer could self-assembly deposit on the surface of sponge even other substrates.For example,P(VTES-DVB)-Si0_(2)/MS obtained by assembling P(VTES-DVB)-Si0_(2)on the surface of Melamine Sponge(MS)exhibited superhydrophobicity with a Water Contact Angle(WCA)of 157.3,the optimal adsorption capacity of 77 g g 136 g g-1 for diverse oils,and an excellent separation efficiency of 99.3%.Besides,the excellent acid and alkali resistance of P(VTES-DVB)-Si0_(2)/MS suggested the potential value in practical oil-water separation.P(VTES-DVB)-Si0_(2)showed the outstanding hydrophobic performance by using as coating on different substrates.This work provided a new idea about the stable combination of organic and inorganic matter in the surface modification.展开更多
Photo-responsive azobenzene （ABZ） derivatives with different end groups （R） as photoswitchable molecules were employed to construct self-assembled monolayers （SAMs） on silicon substrate by using 3-glycidoxypropy...Photo-responsive azobenzene （ABZ） derivatives with different end groups （R） as photoswitchable molecules were employed to construct self-assembled monolayers （SAMs） on silicon substrate by using 3-glycidoxypropyltrimethoxysilane （GPTS） as the bridging molecules. The assembly process was optimized by changing various parameters, including the type and concentration of ABZ derivatives, reaction time, etc. The obtained SAMs were fully characterized and evaluated using UV spectroscopy, atomic force microscope （AFM）, elllipsometer, static contact angle and X-ray photoelectron spectroscopy （XPS）. It is found that the end group property of azobenzene derivatives is critical to the obtained SAMs＇ photoresponsive properties. Compared with hydrophobic compounds （4-（4＇-aminophenylazo） benzoic acid, ABZ-CF3）, the hydrophilic compounds （4-（4＇-aminophenylazo） benzoic acid, ABZ-COOH） show excellent reversible photoswitching performance with a large contact angle change of 35° under oDtimized process, and the SAMs are removable bv thermal treatment at 240 ℃ in air for onlv 5 min.展开更多
Recent advances in the study of magnetic atomic structures on noble metal surfaces are reviewed. These include one- dimensional strings, two-dimensional hexagonal superlattices, and novel structures stabilized by quan...Recent advances in the study of magnetic atomic structures on noble metal surfaces are reviewed. These include one- dimensional strings, two-dimensional hexagonal superlattices, and novel structures stabilized by quantum guiding. The combined techniques of low-temperature scanning tunneling microscopy, kinetic Monte Carlo simulations, and ab initio calculations reveal that surface-state-mediated adatom-step and adatom-adatom interactions are the driving forces for self- assembly of these structures. The formation conditions are further discussed by comparing various experimental systems and the kinetic Monte Carlo simulations. Using scanning tunneling spectroscopy and tight-binding calculations together, we reveal that the spectra of these well-ordered structures have characteristic peaks induced by electronic scattering processes of the atoms within the local environment. Moreover, it is demonstrated that quantum confinement by means of nano-size corrals has significant influence on adatom diffusion and self-assembly, leading to a quantum-guided self-assembly.展开更多
Polypiperazine-amide membranes were modified with poly(ethyleneimine)(PEI) by self-assembled method,through which PEI molecules were fixed on the membrane surface by ionic interaction. In the experiments,the PEI conce...Polypiperazine-amide membranes were modified with poly(ethyleneimine)(PEI) by self-assembled method,through which PEI molecules were fixed on the membrane surface by ionic interaction. In the experiments,the PEI concentration ranged from 50 to 2000 mg·L-1while the depositing time was fixed at 20 min. The results showed that low PEI concentration resulted in a slight increase of pure water flux, which was attributed to the enhanced membrane surface hydrophilicity. The PEI adsorption on membrane surface had less effect on the rejections to neutral PEG and sucrose, but improved the rejections to divalent cationic ions and methylene blue as the result of reversion of the membrane surface charge from negative to positive according to the XPS analysis and zeta potential measurements. The membrane modified at PEI = 1500 mg·L-1exhibited high rejection to methylene blue(MB) and is potential to be applied in the treatment of effluents containing positively charged dyes.展开更多
An effective optimization method for the shape/sizing design of composite wing structures is presented with satisfying weight-cutting results. After decoupling, a kind of two-layer cycled optimization strategy suitabl...An effective optimization method for the shape/sizing design of composite wing structures is presented with satisfying weight-cutting results. After decoupling, a kind of two-layer cycled optimization strategy suitable for these integrated shape/sizing optimization is obtained. The uniform design method is used to provide sample points, and approximation models for shape design variables. And the results of sizing optimization are construct- ed with the quadratic response surface method （QRSM）. The complex method based on QRSM is used to opti- mize the shape design variables and the criteria method is adopted to optimize the sizing design variables. Compared with the conventional method, the proposed algorithm is more effective and feasible for solving complex composite optimization problems and has good efficiency in weight cutting.展开更多
The aim of the present study was to optimize the supercritical CO_2 extraction conditions of icariin from Herba Epimedii by response surface method(RSM) and central composite design(CCD).A 3-factor,5-level CCD was use...The aim of the present study was to optimize the supercritical CO_2 extraction conditions of icariin from Herba Epimedii by response surface method(RSM) and central composite design(CCD).A 3-factor,5-level CCD was used for the optimization.Independent variables were extraction temperature,extraction pressure and entrainer flow rate.Dependent variable was yield ratio of icariin from Herba Epimedii.A two-order polynomial equation was fitted to the data.The results showed that the optimum extraction conditions were as follows:extraction temperature 46.5℃,extraction pressure 30.6 MPa,entrainer flow rate 3.3 mL/min.CCD/ RSM is convenient and highly predictive for optimizing the extraction process of icariin from Herba Epimedii.展开更多
A surface edge element method is proposed and implemented in the study ofelectromagnetic scattering fields of general targets. The basis functions for surfaces of arbitraryshape are derived according to the geometrica...A surface edge element method is proposed and implemented in the study ofelectromagnetic scattering fields of general targets. The basis functions for surfaces of arbitraryshape are derived according to the geometrical properties of each triangular patch. The proposedbasis functions are 3-D linear functions and the tangential components of the vectors are continuousas the traditional edge element method. Combined field integral equations (CFIE) that include bothelectrical field and magnetic field integral equations are used to model the electromagneticscattering of general dielectric targets. Special treatment for singularity is presented to enhancethe quality of numerical solutions. The proposed method is used to compute the scattering fieldsfrom various targets. Numerical results obtained by the proposed method are validated by resultsfrom other numerical methods.展开更多
Surface notches lower the stiffness of laminated strips, so they lower the buckling loads of the laminated strips, too. In this paper a new method is proposed to predict the buckling loads of the laminated strips with...Surface notches lower the stiffness of laminated strips, so they lower the buckling loads of the laminated strips, too. In this paper a new method is proposed to predict the buckling loads of the laminated strips with a surface notch. The theoretical and experimental results show that the buckling loads decrease as the depth or width of the surface notches increase; when the stacking sequence of the laminated strips is [0°/0°/+ θ/-θ/0°/0°/+θ/-θ] s , the buckling load decrease as θ increases. It proves that the method is reliable and significant.展开更多
Studying and understanding of the surface topography variation are the basis for analyzing tribological problems,and characterization of worn surface is necessary.Fractal geometry offers a more accurate description fo...Studying and understanding of the surface topography variation are the basis for analyzing tribological problems,and characterization of worn surface is necessary.Fractal geometry offers a more accurate description for surface roughness that topographic surfaces are statistically self-similar and can be quantitatively evaluated by fractal parameters.The change regularity of worn surface topography is one of the most important aspects of running-in study.However,the existing research normally adopts only one friction matching pair to explore the surface topography change,which interrupts the running-in wear process and makes the experimental result lack authenticity and objectivity.In this paper,to investigate the change regularity of surface topography during the real running-in process,a series of running-in tests by changing friction pairs under the same operating conditions are conducted on UMT-II Universal Multifunction Tester.The surface profile data are acquired by MiaoXAM2.5X-50X Ultrahigh Precision Surface 3D Profiler and analyzed using fractal dimension D,scale coefficient C and characteristic roughness Ra ＊based on root mean square（RMS） method.The characterization effects of the three parameters are discussed and compared.The results obtained show that there exists remarkable fractal feature of surface topography during running-in process,both D and Ra ＊increase gradually,while C decreases slowly as the wear-in process goes on,and all parameters tend to be stable when the wear process steps into the normal wear process.Ra ＊illustrates higher sensitivity for rough surface characterization compared with the other two parameters.In addition,the running-in test carried with a set of identical surface properties is more scientific and reasonable than the traditional one.The proposed research further indicates that the fractal method can quantitatively measure the rough surface,which also provides an evidence for running-in process identification and tribology design.展开更多
Due to the size effects of rockfill materials, the settlement difference between numerical simulation and in situ monitoring of rockfill dams is a topic of general concern.The constitutive model parameters obtained fr...Due to the size effects of rockfill materials, the settlement difference between numerical simulation and in situ monitoring of rockfill dams is a topic of general concern.The constitutive model parameters obtained from laboratory triaxial tests often underestimate the deformation of high rockfill dams.Therefore, constitutive model parameters obtained by back analysis were used to calculate and predict the long-term deformation of rockfill dams.Instead of using artificial neural networks (ANNs), the response surface method (RSM) was employed to replace the finite element simulation used in the optimization iteration.Only 27 training samples were required for RSM, improving computational efficiency compared with ANN, which required 300 training samples.RSM can be used to describe the relationship between the constitutive model parameters and dam settlements.The inversion results of the Shuibuya concrete face rockfill dam (CFRD) show that the calculated settlements agree with the measured data, indicating the accuracy and efficiency of RSM.展开更多
Tooth modification technique is widely used in gear industry to improve the meshing performance of gearings. However, few of the present studies on tooth modification considers the influence of inevitable random error...Tooth modification technique is widely used in gear industry to improve the meshing performance of gearings. However, few of the present studies on tooth modification considers the influence of inevitable random errors on gear modification effects. In order to investigate the uncertainties of tooth modification amount variations on system＇s dynamic behaviors of a helical planetary gears, an analytical dynamic model including tooth modification parameters is proposed to carry out a deterministic analysis on the dynamics of a helical planetary gear. The dynamic meshing forces as well as the dynamic transmission errors of the sun-planet 1 gear pair with and without tooth modifications are computed and compared to show the effectiveness of tooth modifications on gear dynamics enhancement. By using response surface method, a fitted regression model for the dynamic transmission error（DTE） fluctuations is established to quantify the relationship between modification amounts and DTE fluctuations. By shifting the inevitable random errors arousing from manufacturing and installing process to tooth modification amount variations, a statistical tooth modification model is developed and a methodology combining Monte Carlo simulation and response surface method is presented for uncertainty analysis of tooth modifications. The uncertainly analysis reveals that the system＇s dynamic behaviors do not obey the normal distribution rule even though the design variables are normally distributed. In addition, a deterministic modification amount will not definitely achieve an optimal result for both static and dynamic transmission error fluctuation reduction simultaneously.展开更多
Surface low/distortion is one of the most challenging surface deflections that have a great effect on the exterior appearance of automobiles.Most studies on surface distortion/deflection have focused on evaluation and...Surface low/distortion is one of the most challenging surface deflections that have a great effect on the exterior appearance of automobiles.Most studies on surface distortion/deflection have focused on evaluation and visualization techniques,the research work on correction or prevention of surface low/distortion is limited,and there is no perfect surface low/distortion corrective method that can satisfy the needs of the engineering.A B-spline based geometry morphing algorithm is proposed and then a new program based on UG-NX platform is developed to modify the die face in the surface low/distortion areas.To verify this developed system,the experimental dies that can replicate the surface low/distortion phenomenon successfully is put to use.Five geometric variables are introduced to describe the basic geometry of typical depression features of automotive outer panels.The experimental dies are then designed to reflect various combinations of these geometric parameters.The stamping experiments are conducted on cold rolled grade 5（CR5） sheet steel and various static measurements,such as oil-stoning,laser scanner,etc,are performed to measure and record the surface low/distortions.Three approaches including good bearing,holds in blank and die face morphing that aim to correct low/distortions are tried out and surface low/distortions are observed in the specimen with reverse draw depth of 10 mm.The measurement results show that die morphing is a practical and effective method to correct the surface low/distortion.The correction method proposed can be used to minimize the occurrence of surface low/distortion in die manufacturing,which has certain reference significance to the correction of surface low/distortion.展开更多
A current based hybrid method （HM） is proposed which combines the method of moment （MOM） with the Kirchhoff approximation （KA） for the analysis of scattering interaction between a two-dimensional （2D） infinite...A current based hybrid method （HM） is proposed which combines the method of moment （MOM） with the Kirchhoff approximation （KA） for the analysis of scattering interaction between a two-dimensional （2D） infinitely long conducting target with arbitrary cross section and a one-dimensional （1D） Gaussian rough surface. The electromagnetic scattering region in the HM is split into KA region and MOM region. The electric field integral equation （EFIE） in MOM region （target） is derived, the computational time of the HM depends mainly on the number of unknowns of the target. The bistatic scattering coefficient for the infinitely long cylinder above the rough surface with Gaussian roughness spectrum is calculated, and the numerical results are compared and verified with those obtained by the conventional MOM, which shows the high efficiency of the HM. Finally, the influence of the size, location of the target, the rms height and correlation length of the rough surface on the bistatic scattering coefficient with different polarizations is discussed in detail.展开更多
Because of the randomness of many impact factors influencing the dynamic assembly relationship of complex machinery, the reliability analysis of dynamic assembly relationship needs to be accomplished considering the r...Because of the randomness of many impact factors influencing the dynamic assembly relationship of complex machinery, the reliability analysis of dynamic assembly relationship needs to be accomplished considering the randomness from a probabilistic perspective. To improve the accuracy and efficiency of dynamic assembly relationship reliability analysis, the mechanical dynamic assembly reliability（MDAR） theory and a distributed collaborative response surface method（DCRSM） are proposed. The mathematic model of DCRSM is established based on the quadratic response surface function, and verified by the assembly relationship reliability analysis of aeroengine high pressure turbine（HPT） blade-tip radial running clearance（BTRRC）. Through the comparison of the DCRSM, traditional response surface method（RSM） and Monte Carlo Method（MCM）, the results show that the DCRSM is not able to accomplish the computational task which is impossible for the other methods when the number of simulation is more than 100 000 times, but also the computational precision for the DCRSM is basically consistent with the MCM and improved by 0.40-4.63% to the RSM, furthermore, the computational efficiency of DCRSM is up to about 188 times of the MCM and 55 times of the RSM under 10000 times simulations. The DCRSM is demonstrated to be a feasible and effective approach for markedly improving the computational efficiency and accuracy of MDAR analysis. Thus, the proposed research provides the promising theory and method for the MDAR design and optimization, and opens a novel research direction of probabilistic analysis for developing the high-performance and high-reliability of aeroengine.展开更多
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.10864001）, the Natural Science Foundation of Yunnan Province （No.2008ZC159M）, and No.8 Middle-Aged and Young Academic Talent Reserve Project of Yunnan Province （No.2005PY01-51）.
文摘We demonstrate surface enhanced Raman scattering （SERS） detection of self-assembled nano silver film using a low-cost electrolysis strategy at a proper voltage and silver nitrate concentration in electrolyte. The concentration dependence of SERS from crystal violet （CV） molecules adsorbed to silver film was systematically studied. Importantly, the SERS surface enhancement factor of such nano silver film was 603, which was measured by a portable Raman spectrometer. The minimum concentration of detectable CV molecules can be as low as 10^-11 mol/L. The nano silver film prepared by this electrolysis method is an active, stable, cost-effective, and reusable SERS substrate.
基金supported by the National Key Research and Development Program of China(Grant No.2021YFB1714600)the National Natural Science Foundation of China(Grant No.52175095)the Young Top-Notch Talent Cultivation Program of Hubei Province of China.
文摘This paper examined how microstructure influences the homogenized thermal conductivity of cellular structures and revealed a surface-induced size-dependent effect.This effect is linked to the porous microstructural features of cellular structures,which stems from the degree of porosity and the distri-bution of the pores.Unlike the phonon-driven surface effect at the nanoscale,the macro-scale surface mechanism in thermal cellular structures is found to be the microstructure-induced changes in the heat conduction path based on fully resolved 3D numerical simulations.The surface region is determined by the microstructure,characterized by the intrinsic length.With the coupling between extrinsic and intrinsic length scales under the surface mechanism,a surface-enriched multiscale method was devel-oped to accurately capture the complex size-dependent thermal conductivity.The principle of scale separation required by classical multiscale methods is not necessary to be satisfied by the proposed multiscale method.The significant potential of the surface-enriched multiscale method was demon-strated through simulations of the effective thermal conductivity of a thin-walled metamaterial struc-ture.The surface-enriched multiscale method offers higher accuracy compared with the classical multiscale method and superior efficiency over high-fidelity finite element methods.
基金Supported by the National Natural Science Foundation of China(32072352)。
文摘In order to improve the quality of 3D printed raspberry preserves after post-processing,microwave ovens combining infrared and microwave methods were utilized.The effects of infrared heating temperature,infrared heating time,microwave power,microwave heating time on the center temperature,moisture content,the chroma(C*),the total color difference(ΔE*),shape fidelity,hardness,and the total anthocyanin content of 3D printed raspberry preserves were analyzed by response surface method(RSM).The results showed that under combining with the two methods,infrared heating improved the fidelity and quality degradation of printed products,while microwave heating enhanced the efficiency of infrared heating.Infrared-microwave combination cooking could maintain relatively stable color appearance and shape of 3D printed raspberry preserves.The AHP–CRITIC hybrid weighting method combined with the response surface test to determine the comprehensive weights of the evaluation indicators optimized the process parameters,and the optimal process parameters were obtained:infrared heating temperature of 190℃,infrared heating time of 10 min and 30 s,microwave power of 300 W,and microwave heating time of 2 min and 6 s.The 3D printed raspberry cooking methods obtained under the optimal conditions seldom had color variation,porous structure,uniform texture,and high shape fidelity,which retained the characteristics of personalized manufacturing by 3D printing.This study could provide a reference for the postprocessing and quality control of 3D cooking methods.
基金supported by the National Key Research and Development Program of China(2022YFA1203602)the National Natural Science Foundation of China(Grant No.12025206)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB0620101)the National Natural Science Foundations of China(Grant No.12202366).
文摘Anode-free lithium metal batteries are prone to capacity degradation and safety hazards due to the formation and growth of lithium dendrites.The interface between the current collector and deposited lithium plays a critical role in preventing dendrite formation by regulating the thermodynamics and kinetics of lithium deposition.In this study,we develop a phase field model to investigate the influence of the current collector’s surface energy on lithium deposition morphology and its effect on the quality of the lithium metal film.It is demonstrated that a higher surface energy of the current collector promotes the growth of lithium metal along the surface of the current collector.Further,our simulation results show that a higher surface energy accelerates the formation of the lithium metal film while simultaneously reducing its surface roughness.By examining different contact angles and applied potentials,we construct a phase diagram of deposition morphology,illustrating that increased surface energy facilitates the dense and uniform deposition of lithium metal by preventing the formation of lithium filaments and voids.These findings provide new insights into the development and application of anode-free lithium metal batteries.
基金co-supported by the Foundation of the State Key Laboratory of Aerodynamics(No.RAL202203)the National Key Laboratory Foundation(No.6142202202)the China Postdoctoral Science Foundation(No.2024M754133)。
文摘An advanced Actuator Surface Method(ASM)coupled with Computational Fluid Dynamics(CFD)is developed and applied to the complex unsteady aerodynamic simulation of helicopter.By introducing an improved three-dimensional anisotropic Gaussian kernel,this method effectively addresses the severe aerodynamic load fluctuations commonly associated with traditional Virtual Blade Method(VBM)due to turbulent flow around blade elements.To manage the issues of regional shape and grid cell quantity variations caused by virtual blade sweeping,a universal hybrid grid generation strategy is established without body-fitted and disk interpolation grids,which enhances the computational stability at both blade elements and blade edges.Aerodynamic numerical simulations of helicopter are performed using this method,focusing on rotor/fuselage interaction dominated by rotor wake motion and fuselage blockage effects,Blade-Vortex Interaction(BVI)induced by tip vortices,and maneuvering flights involving collective pitch ramp increases.The results indicate that the advanced ASM demonstrates reliability and robustness in the simulation of complex unsteady flow fields around helicopter.Under similar computational accuracy,the advanced ASM improves computational efficiency by nearly 40 times compared to the oversetgrid-based full Blade-Resolved(B-R)method,and by 6 times compared to the VBM.It shows significant advantages when applied to complex full-aircraft interaction and maneuvering flight conditions that require substantial computational resources.
基金Project(52278380)supported by the National Natural Science Foundation of ChinaProject(2023JJ30670)supported by the National Science Foundation of and Technology Major Project of Hunan Province,China。
文摘This study proposes an alternative calculation mode for stresses on the slip surface(SS).The calculation of the normal stress(NS)on the SS involves examining its composition and expanding its unknown using the Taylor series.This expansion enables the reasonable construction of a function describing the NS on the SS.Additionally,by directly incorporating the nonlinear Generalized Hoke-Brown(GHB)strength criterion and utilizing the slope factor of safety(FOS)definition,a function of the shear stress on the SS is derived.This function considers the mutual feedback mechanism between the NS and strength parameters of the SS.The stress constraints conditions are then introduced at both ends of the SS based on the spatial stress relation of one point.Determining the slope FOS and stress solution for the SS involves considering the mechanical equilibrium conditions and the stress constraint conditions satisfied by the sliding body.The proposed approach successfully simulates the tension-shear stress zone near the slope top and provides an intuitive description of the concentration effect of compression-shear stress of the SS near the slope toe.Furthermore,compared to other methods,the present method demonstrates superior processing capabilities for the embedded nonlinear GHB strength criterion.
基金This work was financially supported by the National Natural Science Foundation of China(Nos.22008092,21822807 and 51803080)Postgraduate Research&Practice Innovation Program of Jiangsu Prov ince(KYCX19_1592)Science and Technology Planning Social Development Project of Zhenjiang City(SH2020003).
文摘Mimicry of nature drives the development of bionic materials.Bionic superhydrophobic materials are a kind of high-efficiency materials to handle oil spills and water pollution.However,the stability of surface coatings of the superhydrophobic materials remains a challenge.Herein,a new category of self-assembly bionic superhydrophobic surface coating was prepared via one-step condensation/copolymerization of vinyltriethoxysilane(VTES)and divinylbenzene(DVB),which realized the close combination of covalent bonds between organic(e.g.DVB)and inorganic matter(e.g.VTES),and avoided the swelling of polydivinylbenzene(PDVB)in the process of collection of oil from water.This organic-inorganic hybrid polymer could self-assembly deposit on the surface of sponge even other substrates.For example,P(VTES-DVB)-Si0_(2)/MS obtained by assembling P(VTES-DVB)-Si0_(2)on the surface of Melamine Sponge(MS)exhibited superhydrophobicity with a Water Contact Angle(WCA)of 157.3,the optimal adsorption capacity of 77 g g 136 g g-1 for diverse oils,and an excellent separation efficiency of 99.3%.Besides,the excellent acid and alkali resistance of P(VTES-DVB)-Si0_(2)/MS suggested the potential value in practical oil-water separation.P(VTES-DVB)-Si0_(2)showed the outstanding hydrophobic performance by using as coating on different substrates.This work provided a new idea about the stable combination of organic and inorganic matter in the surface modification.
基金financially supported by The Dow Chemical Company
文摘Photo-responsive azobenzene （ABZ） derivatives with different end groups （R） as photoswitchable molecules were employed to construct self-assembled monolayers （SAMs） on silicon substrate by using 3-glycidoxypropyltrimethoxysilane （GPTS） as the bridging molecules. The assembly process was optimized by changing various parameters, including the type and concentration of ABZ derivatives, reaction time, etc. The obtained SAMs were fully characterized and evaluated using UV spectroscopy, atomic force microscope （AFM）, elllipsometer, static contact angle and X-ray photoelectron spectroscopy （XPS）. It is found that the end group property of azobenzene derivatives is critical to the obtained SAMs＇ photoresponsive properties. Compared with hydrophobic compounds （4-（4＇-aminophenylazo） benzoic acid, ABZ-CF3）, the hydrophilic compounds （4-（4＇-aminophenylazo） benzoic acid, ABZ-COOH） show excellent reversible photoswitching performance with a large contact angle change of 35° under oDtimized process, and the SAMs are removable bv thermal treatment at 240 ℃ in air for onlv 5 min.
基金Project supported by the National Basic Research Program of China(Grant No.2010CB923401)the National Natural Science Foundation of China(Grant Nos.10974087,11374145,11304150,and 11023002)
文摘Recent advances in the study of magnetic atomic structures on noble metal surfaces are reviewed. These include one- dimensional strings, two-dimensional hexagonal superlattices, and novel structures stabilized by quantum guiding. The combined techniques of low-temperature scanning tunneling microscopy, kinetic Monte Carlo simulations, and ab initio calculations reveal that surface-state-mediated adatom-step and adatom-adatom interactions are the driving forces for self- assembly of these structures. The formation conditions are further discussed by comparing various experimental systems and the kinetic Monte Carlo simulations. Using scanning tunneling spectroscopy and tight-binding calculations together, we reveal that the spectra of these well-ordered structures have characteristic peaks induced by electronic scattering processes of the atoms within the local environment. Moreover, it is demonstrated that quantum confinement by means of nano-size corrals has significant influence on adatom diffusion and self-assembly, leading to a quantum-guided self-assembly.
基金Support by the National High Technology Research and Development Program of China(863 Program)(2012AA03A608)the Open Foundation of Zhejiang Provincial Top Key Academic Discipline of Applied Chemistry and Eco-Dyeing&Finishing Engineering(YR2012012)
文摘Polypiperazine-amide membranes were modified with poly(ethyleneimine)(PEI) by self-assembled method,through which PEI molecules were fixed on the membrane surface by ionic interaction. In the experiments,the PEI concentration ranged from 50 to 2000 mg·L-1while the depositing time was fixed at 20 min. The results showed that low PEI concentration resulted in a slight increase of pure water flux, which was attributed to the enhanced membrane surface hydrophilicity. The PEI adsorption on membrane surface had less effect on the rejections to neutral PEG and sucrose, but improved the rejections to divalent cationic ions and methylene blue as the result of reversion of the membrane surface charge from negative to positive according to the XPS analysis and zeta potential measurements. The membrane modified at PEI = 1500 mg·L-1exhibited high rejection to methylene blue(MB) and is potential to be applied in the treatment of effluents containing positively charged dyes.
文摘An effective optimization method for the shape/sizing design of composite wing structures is presented with satisfying weight-cutting results. After decoupling, a kind of two-layer cycled optimization strategy suitable for these integrated shape/sizing optimization is obtained. The uniform design method is used to provide sample points, and approximation models for shape design variables. And the results of sizing optimization are construct- ed with the quadratic response surface method （QRSM）. The complex method based on QRSM is used to opti- mize the shape design variables and the criteria method is adopted to optimize the sizing design variables. Compared with the conventional method, the proposed algorithm is more effective and feasible for solving complex composite optimization problems and has good efficiency in weight cutting.
文摘The aim of the present study was to optimize the supercritical CO_2 extraction conditions of icariin from Herba Epimedii by response surface method(RSM) and central composite design(CCD).A 3-factor,5-level CCD was used for the optimization.Independent variables were extraction temperature,extraction pressure and entrainer flow rate.Dependent variable was yield ratio of icariin from Herba Epimedii.A two-order polynomial equation was fitted to the data.The results showed that the optimum extraction conditions were as follows:extraction temperature 46.5℃,extraction pressure 30.6 MPa,entrainer flow rate 3.3 mL/min.CCD/ RSM is convenient and highly predictive for optimizing the extraction process of icariin from Herba Epimedii.
文摘A surface edge element method is proposed and implemented in the study ofelectromagnetic scattering fields of general targets. The basis functions for surfaces of arbitraryshape are derived according to the geometrical properties of each triangular patch. The proposedbasis functions are 3-D linear functions and the tangential components of the vectors are continuousas the traditional edge element method. Combined field integral equations (CFIE) that include bothelectrical field and magnetic field integral equations are used to model the electromagneticscattering of general dielectric targets. Special treatment for singularity is presented to enhancethe quality of numerical solutions. The proposed method is used to compute the scattering fieldsfrom various targets. Numerical results obtained by the proposed method are validated by resultsfrom other numerical methods.
文摘Surface notches lower the stiffness of laminated strips, so they lower the buckling loads of the laminated strips, too. In this paper a new method is proposed to predict the buckling loads of the laminated strips with a surface notch. The theoretical and experimental results show that the buckling loads decrease as the depth or width of the surface notches increase; when the stacking sequence of the laminated strips is [0°/0°/+ θ/-θ/0°/0°/+θ/-θ] s , the buckling load decrease as θ increases. It proves that the method is reliable and significant.
基金supported by National Natural Science Foundation of China (Grant No.50975276,Grant No.50475164)National Basic Research Program of China (973 Program,Grant No.2007CB607605)Doctoral Programs Foundation of Ministry of Education of China (Grant No.200802900513)
文摘Studying and understanding of the surface topography variation are the basis for analyzing tribological problems,and characterization of worn surface is necessary.Fractal geometry offers a more accurate description for surface roughness that topographic surfaces are statistically self-similar and can be quantitatively evaluated by fractal parameters.The change regularity of worn surface topography is one of the most important aspects of running-in study.However,the existing research normally adopts only one friction matching pair to explore the surface topography change,which interrupts the running-in wear process and makes the experimental result lack authenticity and objectivity.In this paper,to investigate the change regularity of surface topography during the real running-in process,a series of running-in tests by changing friction pairs under the same operating conditions are conducted on UMT-II Universal Multifunction Tester.The surface profile data are acquired by MiaoXAM2.5X-50X Ultrahigh Precision Surface 3D Profiler and analyzed using fractal dimension D,scale coefficient C and characteristic roughness Ra ＊based on root mean square（RMS） method.The characterization effects of the three parameters are discussed and compared.The results obtained show that there exists remarkable fractal feature of surface topography during running-in process,both D and Ra ＊increase gradually,while C decreases slowly as the wear-in process goes on,and all parameters tend to be stable when the wear process steps into the normal wear process.Ra ＊illustrates higher sensitivity for rough surface characterization compared with the other two parameters.In addition,the running-in test carried with a set of identical surface properties is more scientific and reasonable than the traditional one.The proposed research further indicates that the fractal method can quantitatively measure the rough surface,which also provides an evidence for running-in process identification and tribology design.
基金supported by the National Natural Science Foundation of China(Grant No.51579193)the Science and Technology Planning Project of Guizhou Province(Grant No.[2016]1154)
文摘Due to the size effects of rockfill materials, the settlement difference between numerical simulation and in situ monitoring of rockfill dams is a topic of general concern.The constitutive model parameters obtained from laboratory triaxial tests often underestimate the deformation of high rockfill dams.Therefore, constitutive model parameters obtained by back analysis were used to calculate and predict the long-term deformation of rockfill dams.Instead of using artificial neural networks (ANNs), the response surface method (RSM) was employed to replace the finite element simulation used in the optimization iteration.Only 27 training samples were required for RSM, improving computational efficiency compared with ANN, which required 300 training samples.RSM can be used to describe the relationship between the constitutive model parameters and dam settlements.The inversion results of the Shuibuya concrete face rockfill dam (CFRD) show that the calculated settlements agree with the measured data, indicating the accuracy and efficiency of RSM.
基金Supported by National Natural Science Foundation of China(Grant No.51375013)Anhui Provincial Natural Science Foundation of China(Grant No.1208085ME64)
文摘Tooth modification technique is widely used in gear industry to improve the meshing performance of gearings. However, few of the present studies on tooth modification considers the influence of inevitable random errors on gear modification effects. In order to investigate the uncertainties of tooth modification amount variations on system＇s dynamic behaviors of a helical planetary gears, an analytical dynamic model including tooth modification parameters is proposed to carry out a deterministic analysis on the dynamics of a helical planetary gear. The dynamic meshing forces as well as the dynamic transmission errors of the sun-planet 1 gear pair with and without tooth modifications are computed and compared to show the effectiveness of tooth modifications on gear dynamics enhancement. By using response surface method, a fitted regression model for the dynamic transmission error（DTE） fluctuations is established to quantify the relationship between modification amounts and DTE fluctuations. By shifting the inevitable random errors arousing from manufacturing and installing process to tooth modification amount variations, a statistical tooth modification model is developed and a methodology combining Monte Carlo simulation and response surface method is presented for uncertainty analysis of tooth modifications. The uncertainly analysis reveals that the system＇s dynamic behaviors do not obey the normal distribution rule even though the design variables are normally distributed. In addition, a deterministic modification amount will not definitely achieve an optimal result for both static and dynamic transmission error fluctuation reduction simultaneously.
基金supported by Key Project of National Natural Science Foundation of China (Grant No. 10932003)National Hi-tech Research and Development Program of China (863 Program,Grant No.2009AA04Z101)National Basic Research Program of China (973Program,Grant No. 2010CB832700)
文摘Surface low/distortion is one of the most challenging surface deflections that have a great effect on the exterior appearance of automobiles.Most studies on surface distortion/deflection have focused on evaluation and visualization techniques,the research work on correction or prevention of surface low/distortion is limited,and there is no perfect surface low/distortion corrective method that can satisfy the needs of the engineering.A B-spline based geometry morphing algorithm is proposed and then a new program based on UG-NX platform is developed to modify the die face in the surface low/distortion areas.To verify this developed system,the experimental dies that can replicate the surface low/distortion phenomenon successfully is put to use.Five geometric variables are introduced to describe the basic geometry of typical depression features of automotive outer panels.The experimental dies are then designed to reflect various combinations of these geometric parameters.The stamping experiments are conducted on cold rolled grade 5（CR5） sheet steel and various static measurements,such as oil-stoning,laser scanner,etc,are performed to measure and record the surface low/distortions.Three approaches including good bearing,holds in blank and die face morphing that aim to correct low/distortions are tried out and surface low/distortions are observed in the specimen with reverse draw depth of 10 mm.The measurement results show that die morphing is a practical and effective method to correct the surface low/distortion.The correction method proposed can be used to minimize the occurrence of surface low/distortion in die manufacturing,which has certain reference significance to the correction of surface low/distortion.
基金Project supported by the National Natural Science Foundation of China (Grant No 60571058)the Specialized Research Fund for the Doctoral Program of Higher Education, China
文摘A current based hybrid method （HM） is proposed which combines the method of moment （MOM） with the Kirchhoff approximation （KA） for the analysis of scattering interaction between a two-dimensional （2D） infinitely long conducting target with arbitrary cross section and a one-dimensional （1D） Gaussian rough surface. The electromagnetic scattering region in the HM is split into KA region and MOM region. The electric field integral equation （EFIE） in MOM region （target） is derived, the computational time of the HM depends mainly on the number of unknowns of the target. The bistatic scattering coefficient for the infinitely long cylinder above the rough surface with Gaussian roughness spectrum is calculated, and the numerical results are compared and verified with those obtained by the conventional MOM, which shows the high efficiency of the HM. Finally, the influence of the size, location of the target, the rms height and correlation length of the rough surface on the bistatic scattering coefficient with different polarizations is discussed in detail.
基金supported by National Natural Science Foundation of China(Grant Nos.51175017,51245027)Innovation Foundation of Beihang University for PhD Graduates,China(Grant No.YWF-12-RBYJ008)Research Fund for the Doctoral Program of Higher Education of China(Grant No.20111102110011)
文摘Because of the randomness of many impact factors influencing the dynamic assembly relationship of complex machinery, the reliability analysis of dynamic assembly relationship needs to be accomplished considering the randomness from a probabilistic perspective. To improve the accuracy and efficiency of dynamic assembly relationship reliability analysis, the mechanical dynamic assembly reliability（MDAR） theory and a distributed collaborative response surface method（DCRSM） are proposed. The mathematic model of DCRSM is established based on the quadratic response surface function, and verified by the assembly relationship reliability analysis of aeroengine high pressure turbine（HPT） blade-tip radial running clearance（BTRRC）. Through the comparison of the DCRSM, traditional response surface method（RSM） and Monte Carlo Method（MCM）, the results show that the DCRSM is not able to accomplish the computational task which is impossible for the other methods when the number of simulation is more than 100 000 times, but also the computational precision for the DCRSM is basically consistent with the MCM and improved by 0.40-4.63% to the RSM, furthermore, the computational efficiency of DCRSM is up to about 188 times of the MCM and 55 times of the RSM under 10000 times simulations. The DCRSM is demonstrated to be a feasible and effective approach for markedly improving the computational efficiency and accuracy of MDAR analysis. Thus, the proposed research provides the promising theory and method for the MDAR design and optimization, and opens a novel research direction of probabilistic analysis for developing the high-performance and high-reliability of aeroengine.
