By surface mechanical attrition treatment（SMAT）,a gradient nano structure（GNS） from the surface to center was generated in the AZ31 alloy sheet.The tribological behavior of AZ31 alloy with GNS was systematically i...By surface mechanical attrition treatment（SMAT）,a gradient nano structure（GNS） from the surface to center was generated in the AZ31 alloy sheet.The tribological behavior of AZ31 alloy with GNS was systematically investigated by using dry sliding tests,a 3D surface profile-meter and a scanning electron microscope equipped with an energy-dispersive spectrometer.The experimental results indicate that the Mg alloy with GNS exhibits better wear resistance comparing to the as-received sample,which is associated to the alteration of wear mechanism at different sliding speeds.The Mg alloy with GNS presents the wear mechanism of the abrasive wear at 0.05 m/s and the oxidative wear at 0.5 m/s,respectively.Moreover,the GNS can effectively promote the reaction between the oxygen and worn surface,which leads to a compact oxidation layer at 0.5 m/s.The effect of oxidation layer on the wear resistance of the Mg alloy was also discussed.展开更多
A systematic investigation of oxidation on a superconductive Fe Te_（0.5）Se_（0.5）thin film,which was grown on Nb-doped SrTiO_3（001） by pulsed laser deposition,has been carried out.The sample was exposed to ambien...A systematic investigation of oxidation on a superconductive Fe Te_（0.5）Se_（0.5）thin film,which was grown on Nb-doped SrTiO_3（001） by pulsed laser deposition,has been carried out.The sample was exposed to ambient air for one month for oxidation.Macroscopically,the exposed specimen lost its superconductivity due to oxidation.The specimen was subjected to in situ synchrotron radiation photoelectron spectroscopy（PES） and x-ray absorption spectroscopy（XAS） measurements following cycles of annealing and argon ion etching treatments to unravel what happened in the electronic structure and composition after exposure to air.By the spectroscopic measurements,we found that the as-grown FeTe_（0.5）Se_（0.5）superconductive thin film experienced an element selective substitution reaction.The oxidation preferentially proceeds through pumping out the Te and forming Fe–O bonds by O substitution of Te.In addition,our results certify that in situ vacuum annealing and low-energy argon ion etching methods combined with spectroscopy are suitable for depth element and valence analysis of layered structure superconductor materials.展开更多
基金National Key Research and Development Program(No.2016YFB0701201)National Natural Science Foundation of China(Nos.51671101,51464034)+3 种基金Natural Science foundation of Jiangxi Province(No.20161ACB21003)the Scientific Research Foundation of the Education Department of Jiangxi Province(No.GJJ150010)the financial support provided by the Croucher Foundation(No.9500006)Hong Kong Collaborative Research Fund(CRF)Scheme(No.C4028-14G)
文摘By surface mechanical attrition treatment（SMAT）,a gradient nano structure（GNS） from the surface to center was generated in the AZ31 alloy sheet.The tribological behavior of AZ31 alloy with GNS was systematically investigated by using dry sliding tests,a 3D surface profile-meter and a scanning electron microscope equipped with an energy-dispersive spectrometer.The experimental results indicate that the Mg alloy with GNS exhibits better wear resistance comparing to the as-received sample,which is associated to the alteration of wear mechanism at different sliding speeds.The Mg alloy with GNS presents the wear mechanism of the abrasive wear at 0.05 m/s and the oxidative wear at 0.5 m/s,respectively.Moreover,the GNS can effectively promote the reaction between the oxygen and worn surface,which leads to a compact oxidation layer at 0.5 m/s.The effect of oxidation layer on the wear resistance of the Mg alloy was also discussed.
基金Project supported by the Chinese Academy of Sciences(Grant No.1G2009312311750101)the National Natural Science Foundation of China(Grant Nos.11375228,11204303,and U1332105)
文摘A systematic investigation of oxidation on a superconductive Fe Te_（0.5）Se_（0.5）thin film,which was grown on Nb-doped SrTiO_3（001） by pulsed laser deposition,has been carried out.The sample was exposed to ambient air for one month for oxidation.Macroscopically,the exposed specimen lost its superconductivity due to oxidation.The specimen was subjected to in situ synchrotron radiation photoelectron spectroscopy（PES） and x-ray absorption spectroscopy（XAS） measurements following cycles of annealing and argon ion etching treatments to unravel what happened in the electronic structure and composition after exposure to air.By the spectroscopic measurements,we found that the as-grown FeTe_（0.5）Se_（0.5）superconductive thin film experienced an element selective substitution reaction.The oxidation preferentially proceeds through pumping out the Te and forming Fe–O bonds by O substitution of Te.In addition,our results certify that in situ vacuum annealing and low-energy argon ion etching methods combined with spectroscopy are suitable for depth element and valence analysis of layered structure superconductor materials.
