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A review of the surface activation and modification of biochars
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作者 Zhang Yihan Chen Longyi 《新型炭材料(中英文)》 北大核心 2026年第1期67-90,共24页
Biomass-derived carbon materials are favored for their abundance and sustainability,and ease of preparation and modification.By surface activation and modification they can have a good electrical conductivity,excellen... Biomass-derived carbon materials are favored for their abundance and sustainability,and ease of preparation and modification.By surface activation and modification they can have a good electrical conductivity,excellent catalytic activity,a remarkable adsorption capacity,and different interfacial physicochemical functionalities.Surface-modified biochars have found wide applications in energy storage,environmental remediation,and catalysis.However,achieving precise and controllable modification of their active sites remains a challenge.Recent advances and future prospects for controlling their surface morphology,defect engineering,and surface coating strategies,with particular attention to their means of fabrication,are reviewed. 展开更多
关键词 Activation and modification Carbon material interface surface functionalization Metal nanoparticle deposition surface defect
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Thermodynamic Correlation Between Surface Carboxyl Configuration and Wettability
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作者 GUO Zhuohuan WANG Dayang 《高等学校化学学报》 北大核心 2026年第1期255-266,共12页
In this study,polyacrylic acid(PAA)films were employed as a model system,and a series of PAA films with tunable water wettability was systematically prepared by varying molecular weight and curing temperature.Using at... In this study,polyacrylic acid(PAA)films were employed as a model system,and a series of PAA films with tunable water wettability was systematically prepared by varying molecular weight and curing temperature.Using attenuated total reflectance Fourier-transform infrared spectroscopy(ATR-FTIR),the molecular configurations of surface carboxyl groups(COOH),free carboxyl(COOH_(f))and hydrogen-bonded carboxyl(COOH_(HB),were directly correlated with the polar component of surface energy(γ^(s,p)).By decomposing theγ^(s,p)values of the PAA thin films as a sum of the contributions of COOH_(f)and COOH_(H B),the intrinsic polar component of surface energy of COOH_(H B)(γ_(H B)^(s,p*))was quantified for the first time as 8.34 mN/m,significantly lower than that of COOH_(f)(γ_(f)^(s,p*)=34 mN/m).This result highlights that hydrogen bonding markedly reduces theγ^(s,p),providing a rational explanation for the relatively large water contact angle observed on PAA thin films.Furthermore,it establishes a thermodynamic basis for estimating the fraction of surface COOH_(H B)groups(f H B)from wettability measurements.Further extension of the model to carboxyl-terminated self-assembled monolayers(COOH-SAMs)revealed that surface COOH density(ΣCOOH)critically regulates wetting behavior:whenΣCOOH ranges from 4.30 to 5.25 nm^(-2),COOH groups predominantly exist in a free state and facilitate effective hydration layers,thereby promoting superhydrophilicity.Overall,this study not only establishes a unified thermodynamic framework linking surface COOH configurations to macroscopic wettability,but also validates its universality by extending it to COOH-SAMs systems,thereby providing a unified theoretical framework for the controllable design of hydrophilicity in various COOH-functionalized surfaces. 展开更多
关键词 Polyacrylic acid film Hydrogen bonding Attenuated total reflectance Fourier-transform infrared spectroscopy Quantitative carboxyl configuration Polar component of surface energy
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Theoretical insights into the hydrogen peroxide oxidation and reduction reactions on low-index Pt surfaces
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作者 WANG Qi CHEN Lifang +1 位作者 DING Ruimin YIN Xi 《燃料化学学报(中英文)》 北大核心 2026年第1期35-45,共11页
Hydrogen peroxide(H_(2)O_(2))oxidation and reduction reactions(HPOR/HPRR)are pivotal in various innovative electrochemical energy conversion devices.A comprehensive understanding of these mechanisms is critical for ca... Hydrogen peroxide(H_(2)O_(2))oxidation and reduction reactions(HPOR/HPRR)are pivotal in various innovative electrochemical energy conversion devices.A comprehensive understanding of these mechanisms is critical for catalyst design and performance improvement in these applications.In this work,we systematically investigate the HPOR/HPRR mechanisms on low-index Pt surfaces,specifically Pt(111),Pt(100)and Pt(110),through density functional theory(DFT)calculations combined with the computational hydrogen electrode(CHE)model.For HPOR,all the low-index Pt surfaces exhibit a unified potential-determining step(PDS)involving the electrochemical oxidation of hydroperoxyl intermediates(HOO*).The binding free energy of HOO*(Δ_(GHOO*))emerges as an activity descriptor,with Pt(110)exhibiting the highest HPOR activity.The HPRR mechanism follows a chem-electrochemical(C-EC)pathway.The rate-determining step(RDS)of HPRR is either the cleavage of the HO-OH bond(chemical)or the reduction of HO(electrochemical),depending on their respective activation energies.These activation energies are functions of the HO*binding free energy,Δ_(GHO*),establishingΔ_(GHO*)as the descriptor for HPRR activity prediction.Pt(111)and Pt(100)are identified as the most active HPRR catalysts among the studied metal surfaces,although they still experience a significant overpotential.The scaling relationship betweenΔ_(GHOO*)andΔ_(GHO*)reveals a thermodynamic coupling of HPOR and HPRR,explaining their occurrence on Pt surfaces.These findings provide important insights and activity descriptors for both HPOR and HPRR,providing valuable guidance for the design of electrocatalysts in H_(2)O_(2)-related energy applications and fuel cells. 展开更多
关键词 HPOR HPRR Pt low-index surfaces density functional theory
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Marine Shell-Inspired Laser Surface Texturing:Characterizing the Surface Properties of Co-Based Alloy
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作者 Şefika Kasman Sertan Ozan 《Journal of Bionic Engineering》 2026年第1期341-353,共13页
This study investigated surface roughness,the wettability behavior,and surface energy of Co-based alloy specimens textured using the biomimetic Laser Surface Texturing(LST)method.The surface texture was inspired by th... This study investigated surface roughness,the wettability behavior,and surface energy of Co-based alloy specimens textured using the biomimetic Laser Surface Texturing(LST)method.The surface texture was inspired by the patterns found on marine shells.The impacts of the parameters on wettability,Surface Free Energy(SFE),surface topography,and texture roughness generated by the laser beam tracking a spiral path were investigated.Reducing spiral pitch produces more complicated and chaotic surface patterns.Most surfaces are hydrophobic,and surface roughness and topography influence the Contact Angle(CA).Topography and roughness were affected by frequency and scanning speed;a decrease in scanning speed and frequency generated more chaotic and irregular surface textures.With general factorial analysis and Analysis of Variance(ANOVA),our statistical study reveals that accounting for 88%of the influence,the scanning speed is the primary factor influencing surface roughness.On the other hand,the spiral pitch is essential for defining the struc-tural features of the surface,even if it less influences roughness.The SFE of laser-textured CoCr28Mo alloy specimens was optimizable within the range of 14-32 mN/m.The relevant findings offer valuable insights into optimizing LST for the specific surface properties of the Co-based alloy. 展开更多
关键词 Bio-inspired surface CoCr28Mo alloy WETTABILITY surface roughness surface free energy
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Effect of surface area and pore size on long-term bone regeneration:dynamic changes in geometric characteristics,mass transport,and mechanobiology
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作者 Xing Peng Guoxian Zhang +5 位作者 Jian Pu Shu Yang Wen Cui Xue Zhou Shuxin Qu Zhongmin Jin 《Bio-Design and Manufacturing》 2026年第1期137-152,I0021,共17页
The specific surface area(S S)and pore size(D)exhibit an inherent trade-off in the microscale design of bone implants:larger pores typically correlate with reduced surface area and vice versa.This relationship has att... The specific surface area(S S)and pore size(D)exhibit an inherent trade-off in the microscale design of bone implants:larger pores typically correlate with reduced surface area and vice versa.This relationship has attracted notable attention because of its critical role in the regulation of cell adhesion and osteogenesis.However,it remains largely unclear how S S and D affect the generated bone tissue and dynamically change during long-term osteogenesis.Herein,by applying rigorous geometric mapping to minimal surfaces,we constructed precisely partitioned and layer-by-layer thickened tissue models to simulate osteogenesis across different temporal scales and thereby track the dynamic evolution of geometric characteristics,permeability,and mechanobiological tissue differentiation.The high-S S samples were found to facilitate the rapid formation of new bone tissue in the early stages.However,their smaller pores tended to cause occlusions,hindering further tissue development.In contrast,low-S S samples showed slower bone regeneration,but their larger pores provided adequate physical space for tissue regeneration and mass transport,ultimately promoting bone formation in the long term.Mechanobiological regulation suggests that fibrous tissue formation inhibits additional bone formation,establishing a dynamic equilibrium between osteogenesis and pore space to sustain nutrient/waste exchange throughout the regenerative process.Overall,smaller pores are preferable in implants for minimally loaded osteoplasty procedures focused on early-stage bone consolidation,whereas larger pores are preferable in dynamically loaded implants requiring prolonged mechanical stability. 展开更多
关键词 Minimal surface Specific surface area Pore size Bone ingrowth MECHANOBIOLOGY Finite element simulation
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Erratum:Marine Shell-Inspired Laser Surface Texturing:Characterizing the Surface Properties of Co-Based Alloy
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作者 Sefika Kasman Sertan Ozan 《Journal of Bionic Engineering》 2026年第1期551-551,共1页
The original online version of this article was revised:Several errors occurred in the published version of the article.These have now been corrected as follows:Page 2,section"2.2 Laser Texturing Procedure of Sur... The original online version of this article was revised:Several errors occurred in the published version of the article.These have now been corrected as follows:Page 2,section"2.2 Laser Texturing Procedure of Surfaces",line 2:The device name was corrected from"YDFLP-E-50-M8"to"YDFLP-50-M8."Page 3,Section 2.4:The phrase"95%confidence interval"has been corrected to"95%confidence level."Page 3,Figure 1 caption:The phrase"fandg"has been corrected to"f and g."The order"C4 and C12"has been reversed to"C12 and C4,"in accordance with the display order in the figure.Page 4,Figure reference:The phrase"Figs.4c and d"has been corrected to"Figs.5b and c."Page 5,paragraph starting with"The ANOVA results are presented...":The phrase"95%confidence interval"has been corrected to"95%confidence level." 展开更多
关键词 laser surface texturing surface properties marine shell inspired co based alloy laser texturing procedure confidence level ANOVA results
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The surface binding and energy issues in the rational design of separators for Li||S batteries
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作者 Hongfang Du Lijing Wang +8 位作者 Shuyu Cheng Chao Wu Sheng Yang Yang Liu Yi Zhao Dandan Cui Shaowei Zhang Shixue Dou Liangxu Lin 《Journal of Energy Chemistry》 2026年第1期987-1013,I0021,共28页
Lithium-sulfur batteries(LSBs)represent a next-generation energy storage technology,but widespread applications are restricted by the shuttle of lithium polysulfides(LiPSs).The rational design of separators has been d... Lithium-sulfur batteries(LSBs)represent a next-generation energy storage technology,but widespread applications are restricted by the shuttle of lithium polysulfides(LiPSs).The rational design of separators has been demonstrated to be one of the most efficient and cost-effective strategies to curb the shuttle effect,and tremendous research progress has been achieved.The efficiency of a separator depends on its interaction with LiPSs,which is governed by the surface energy and binding strength.Despite several review works that have been reported to advance the separators,most of them primarily focus on active material innovation and construction.The most crucial issues of surface binding energy have not been systematically reviewed,limiting the precise design of efficient separators.In this review,fundamentals related to surface energy and binding interactions with LiPSs are comprehensively analyzed and discussed.With surface binding and energy main lines,the advancements in separator engineering strategies are elaborately summarized and discussed.Moreover,techniques for evaluating affinity to LiPSs are thoroughly analyzed to avoid any ambiguities in measurement.Based on the research context,valuable research directions are suggested to construct efficient separators.This work provides guidelines to regulate the surface binding and energy of separators for high-performance LSBs. 展开更多
关键词 Lithium-sulfur batteries SEPARATOR surface binding affinity surface energy Rational design
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Experimental Study on the Frosting Characteristics of Corrugated Surfaces under the Influence of Different Surface Properties
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作者 Kai Song Lishan Feng +2 位作者 Shugang Duan Weilong Zhao Haikun Zheng 《Frontiers in Heat and Mass Transfer》 2026年第1期210-227,共18页
This study experimentally investigates the influence of surfacewettability on the frosting characteristics of three types of corrugated structures(Types A,B,and C)under controlled low-temperature conditions.The experi... This study experimentally investigates the influence of surfacewettability on the frosting characteristics of three types of corrugated structures(Types A,B,and C)under controlled low-temperature conditions.The experiments were conducted in a constant-temperature bath at a cold surface temperature of–5℃,relative humidity of 90%,and ambient air temperature of 10℃.The results reveal that the variation trends of frost morphology,frost mass,and frost layer thickness are generally consistent across surfaces with different wettability.Among the tested surfaces,frost crystal formation and complete surface coverage occurred latest on the superhydrophobic surface(CA=153.9–165.8℃),next on the bare aluminumsurface(75.3–83.2℃),and earliest on the hydrophilic surface(5.3–7.5℃).At the same frosting duration,the superhydrophobic surface exhibited a sparse and fluffy frost layer,the bare aluminum surface formed a rough and dense frost,while the hydrophilic surface developed a fine and compact frost layer.The amount of frost formation decreased in the order of hydrophilic>bare aluminum>superhydrophobic,indicating that the superhydrophobic surface provides the most significant anti-frosting effect during the initial stages of frost formation.For instance,on the Type A corrugated structure,after 15 min of frosting,the frost mass on the superhydrophobic surface was 38.78%and 68.45%lower than those on the bare aluminum and hydrophilic surfaces,respectively.After 30 min,these differences were 4.99%and 25.26%,respectively.Overall,the superhydrophobic surface exhibited the smallest frost mass and frost layer thickness,demonstrating superior anti-frosting performance compared with the other surface types. 展开更多
关键词 FROSTING corrugated surface frosting amount superhydrophobic surface
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Depression induces ocular surface inflammation and dry eye-like changes in mice
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作者 Xiang Lin Yu-Wen Liu +7 位作者 Jia-Ni Li Wei-Jie Ouyang Li-Ying Tang Jie-Li Wu Zhao-Lin Liu Shi-Nan Wu Jiao-Yue Hu Zu-Guo Liu 《International Journal of Ophthalmology(English edition)》 2026年第3期434-442,共9页
AIM:To investigate the impact of depression-like behavior on ocular surface homeostasis in a mouse model,with a focus on dry eye-like alterations.METHODS:Male C57BL/6J mice(10-12 weeks old)were randomly assigned to co... AIM:To investigate the impact of depression-like behavior on ocular surface homeostasis in a mouse model,with a focus on dry eye-like alterations.METHODS:Male C57BL/6J mice(10-12 weeks old)were randomly assigned to control or restraint stress(RS)groups.The RS group underwent three intermittent 24-hour restraint sessions to induce depressive-like behavior.Behavioral testing,tear secretion measurement,and corneal Oregon Green Dextran(OGD)staining were performed.Postmortem analyses included histological evaluation of lacrimal glands,goblet cell quantification using periodic acid-Schiff staining,and assessment of key inflammatory and apoptotic markers:interleukin(IL)-17,matrix metalloproteinases(MMP)-3,MMP-9,IL-13,interferon(IFN)-γ,and cleaved caspase-3 and-8.RESULTS:Repeated RS induced depression-like behavior and significant ocular surface changes.RStreated mice showed increased corneal OGD uptake and upregulation of gene/protein expression of IL-17,MMP-3,and MMP-9(P<0.05).Goblet cell density and IL-13 protein expression were reduced,while IFN-γprotein expression was elevated(P<0.05).Cleaved caspase-3 and-8 levels were significantly increased in both cornea and conjunctiva.Tear volume and lacrimal gland size were unchanged;however,mild inflammatory infiltration was observed in lacrimal glands.CONCLUSION:Repeated RS leads to ocular surface inflammation and dry eye-like pathology,including corneal barrier disruption,goblet cell loss,and epithelial apoptosis.These findings suggest that depression contributes to the pathogenesis of dry eye disease via immune-mediated mechanisms. 展开更多
关键词 DEPRESSION restraint stress dry eye ocular surface damage INFLAMMATION MICE
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Transmission Characteristics of Biological Pollutant on Cold Surface Through Surface Contact During Cold Storage
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作者 Zhiqiang Wang Lixin Chen +3 位作者 Saiwei Ge Wei Xiao Zhuohao Xuan Pengcheng Zhang 《Journal of Harbin Institute of Technology(New Series)》 2026年第1期20-32,共13页
The cold chain environment is an important route for the long⁃distance transmission of pathogenic micro⁃organisms.In this study,we explored the mechanisms of secondary propagation through surface contact on cold surfa... The cold chain environment is an important route for the long⁃distance transmission of pathogenic micro⁃organisms.In this study,we explored the mechanisms of secondary propagation through surface contact on cold surfaces.A quantitative statistical experimental method was adopted to study the surface⁃contact transmission of micro⁃organisms,wherein the transfer rate of surface contact was the dependent variable and Escherichia coli was used as the indicator bacterium.The effects of contact pressure(0.44,0.86,1.55,2.25,and 2.94 N/cm^(2)),contact time(0,15,30,45,and 60 s),contact angle(15°and 25°),and surface materials(rubber and cotton gloves)were measured at two storage temperatures:cold storage(5℃)and freezing(-18℃).The results showed that as temperature decreases,the transfer of micro⁃organisms through surface contact becomes less probable.The contact time did not significantly influence the transfer rate of micro⁃organisms when items were handled at cold⁃storage temperatures.Based on these results,we recommend placing items as flat as possible to minimize the tilt angle when handling them at cold⁃storage temperatures.Additionally,if the tilt angle cannot be avoided,rubber gloves should be used when handling items stored at large tilt angles,whereas cotton gloves may be used for items placed at smaller angles. 展开更多
关键词 cold chain biological pollutant surface contact transfer rate transmission characteristics
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Correlation of ocular surface function with sleep quality,anxiety,and depression in patients with dry eye disease
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作者 Yi-Long Lin Hai-Hua Liu +2 位作者 Shu-Jin Chen Qi-Hua Wan Kai-Ping Zhang 《World Journal of Psychiatry》 2026年第1期256-266,共11页
BACKGROUND Dry eye disease(DED)is a multifactorial ocular surface disorder with rising prevalence.It is closely related to systemic health and psychological factors,such as sleep and mood disorders,which significantly... BACKGROUND Dry eye disease(DED)is a multifactorial ocular surface disorder with rising prevalence.It is closely related to systemic health and psychological factors,such as sleep and mood disorders,which significantly impact the quality of life of patients.AIM To explore the correlations between ocular surface function,sleep quality,and anxiety/depression in patients with DED.METHODS This was a cross-sectional investigative study that included 358 patients with DED between January 2022 and January 2025.Ocular surface was assessed using the ocular surface disease index(OSDI),tear film break-up time,fluorescein staining score,and Schirmer I test.The Pittsburgh Sleep Quality Index(PSQI),Self-Rating Anxiety Scale(SAS),and Self-Rating Depression Scale(SDS)were used to evaluate sleep quality and anxiety/depression levels.Correlation and linear regression analyses were used to explore the relationships.RESULTS The mean PSQI score of the patients was 9.94±2.18;the mean SAS score was 47.30±4.90,and the mean SDS score was 50.08±5.52.These suggested a prevalence of sleep and psychological abnormalities.There was a significant correlation between the indicators of ocular surface function(OSDI,tear film break-up time,fluorescein staining,and Schirmer I test)and PSQI,SAS,and SDS scores(P<0.05).Moreover,multiple regression revealed that age≥50 years(β=1.55,P=0.029),PSQI scores(β=0.58,P<0.001),SAS scores(β=0.17,P=0.017),and SDS scores(β=0.15,P=0.019)were independent predictors of the OSDI scores.CONCLUSION Ocular surface function in patients with DED is closely related to sleep quality and anxiety/depression,emphasizing the need for holistic clinical management. 展开更多
关键词 Dry eye disease Ocular surface function Sleep quality ANXIETY DEPRESSION
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A surface emphasized multi-task learning framework for surface property predictions:A case study of magnesium intermetallics
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作者 Gaoning Shi Yaowei Wang +3 位作者 Kun Yang Yuan Qiu Hong Zhu Xiaoqin Zeng 《Journal of Magnesium and Alloys》 2026年第1期216-227,共12页
Surface properties of crystals are critical in many fields,including electrochemistry and photoelectronics,the efficient prediction of which can expedite the design and optimization of catalysts,batteries,alloys etc.H... Surface properties of crystals are critical in many fields,including electrochemistry and photoelectronics,the efficient prediction of which can expedite the design and optimization of catalysts,batteries,alloys etc.However,we are still far from realizing this vision due to the rarity of surface property-related databases,especially for multicomponent compounds,due to the large sample spaces and limited computing resources.In this work,we present a surface emphasized multi-task crystal graph convolutional neural network(SEM-CGCNN)to predict multiple surface properties simultaneously from crystal structures.The model is evaluated on a dataset of 3526 surface energies and work functions of binary magnesium intermetallics obtained through first-principles calculations,and obvious improvements are observed both in efficiency and accuracy over the original CGCNN model.By transferring the pre-trained model to the datasets of pure metals and other intermetallics,the fine-tuned SEM-CGCNN outperforms learning from scratch and can be further applied to other surface properties and materials systems.This study could be a paradigm for the end-to-end mapping of atomic structures to anisotropic surface properties of crystals,which provides an efficient framework to understand and screen materials with desired surface characteristics. 展开更多
关键词 Graph neural networks Multi-task learning surface energy Work function Intermetallic compounds Mg alloy
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Improved method for modeling discrete segment surfaces in myopia control lens design
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作者 Dewen Cheng Yesheng Wang +4 位作者 Tong Yang Wenbin Wei Yabin Hu Weizhong Lan Yongtian Wang 《Advanced Photonics Nexus》 2026年第1期88-100,共13页
With increasing awareness of myopia control,various preventive methods have been developed.In recent decades,a range of specialized spectacle lenses utilizing optical interventions has been manufactured and widely ado... With increasing awareness of myopia control,various preventive methods have been developed.In recent decades,a range of specialized spectacle lenses utilizing optical interventions has been manufactured and widely adopted for myopia management.However,the underlying optical mechanisms of these lenses remain unclear,and there is a lack of simulation methods for pre-manufacturing analysis.Meanwhile,the structures of these lenses are becoming increasingly complex,even incorporating an aspheric segment array on a curved base.To address these challenges,we have developed an efficient,accurate,and flexible modeling method for simulating such lenses,along with an experimental setup for validation.We provide deeper insights into the optical mechanisms of these lenses and establish a convenient design framework that facilitates the development of optimized lens structures. 展开更多
关键词 optics modeling complex surface description optical design optical property myopia management optical measurement
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A high-energy powder with excellent combustion reaction performance:Surface modification strategy of boron powder based on non-thermal plasma
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作者 Kangkang Li Jianyong Xu +9 位作者 Xiaoting Lei Mengzhe Yang Jing Liu Luqi Guo Pengfei Cui Dihua Ouyang Chunpei Yu He Cheng Jiahai Ye Wenchao Zhang 《Defence Technology(防务技术)》 2026年第1期289-300,共12页
The presence of a surface oxide film(B_(2)O_(3))on boron(B)particles significantly compromises their combustion efficiency and kinetic performance in fuel-rich solid propellants.This study proposes an innovative conti... The presence of a surface oxide film(B_(2)O_(3))on boron(B)particles significantly compromises their combustion efficiency and kinetic performance in fuel-rich solid propellants.This study proposes an innovative continuous modification strategy combining non-thermal plasma(NTP)etching with fluorocarbon passivation.Characterization and kinetic analysis revealed that reactive plasma species—including atomic hydrogen(H),electronically excited molecular hydrogen(H_(2)^(*)),vibrationally excited molecular hydrogen(H_(2)v),and hydrogen ions(H^(+))—dominate the reduction of B_(2)O_(3)through lowering the transition energy barrier and shifting the reaction spontaneity.Subsequent argon plasma fragmentation of C_(8)F_(18)generates fluorocarbon radicals that form conformal passivation coatings(thickness:7 nm)on purified boron surfaces.The modified boron particles exhibit 37.5℃lower exothermic peak temperature and 27.2%higher heat release(14.8 kJ/g vs.11.6 kJ/g)compared to untreated counterparts.Combustion diagnostics reveal 194%increase in maximum flame height(135.10 mm vs.46.03 mm)and 134%enhancement in flame propagation rate(4.44 cm/s vs.1.90 cm/s).This NTP-based surface engineering approach establishes a scalable pathway for developing highperformance boron-based energetic composites. 展开更多
关键词 Oxide film materials surface modification Boron powder Non-thermal plasma Combustion performance
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Surface/Interface Engineering for High‑Resolution Micro‑/Nano‑Photodetectors
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作者 Jinlin Chang Ting Liu +7 位作者 Xiao Geng Genting Dai Liangliang Yang Mingjun Cheng Linpan Jiang Zhenyuan Sun Jianshe Liu Wei Chen 《Nano-Micro Letters》 2026年第3期499-553,共55页
Photodetectors can convert light energy into electrical signals,so are widely used in photovoltaics,photon counting,monitoring,and imaging.Photodetectors are easy to prepare high-resolution photochips because of their... Photodetectors can convert light energy into electrical signals,so are widely used in photovoltaics,photon counting,monitoring,and imaging.Photodetectors are easy to prepare high-resolution photochips because of their small size unit integration.However,these photodetector units often exhibit poor photoelectric performance due to material defects and inadequate structures,which greatly limit the functions of devices.Designing modification strategies and micro-/nanostructures can compensate for defects,adjust the bandgap,and develop novel quantum structures,which consequently optimize photovoltaic units and revolutionize optoelectronic devices.Here,this paper aims to comprehensively elaborate on the surface/interface engineering scheme of micro-/nano-photodetectors.It starts from the fundamentals of photodetectors,such as principles,types,and parameters,and describes the influence of material selection,manufacturing techniques,and post-processing.Then,we analyse in detail the great influence of surface/interface engineering on the performance of photovoltaic devices,including surface/interface modification and micro-/nanostructural design.Finally,the applications and prospects of optoelectronic devices in various fields such as miniaturization of electronic devices,robotics,and human–computer interaction are shown. 展开更多
关键词 PHOTODETECTORS surface modification HIGH-RESOLUTION Micro-/nanostructures
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Lithospheric magnetic variations on the Tibetan Plateau based on a 3D surface spline model,compared with strong earthquake occurrences
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作者 PengTao Zhang Jun Yang +3 位作者 LiLi Feng Xia Li YuHong Zhao YingFeng Ji 《Earth and Planetary Physics》 2026年第1期30-43,共14页
The National Geophysical Data Center(NGDC)of the United States has collected aeromagnetic data for input into a series of geomagnetic models to improve model resolution;however,in the Tibetan Plateau region,ground-bas... The National Geophysical Data Center(NGDC)of the United States has collected aeromagnetic data for input into a series of geomagnetic models to improve model resolution;however,in the Tibetan Plateau region,ground-based observations remain insufficient to clearly reflect the characteristics of the region’s lithospheric magnetism.In this study,we evaluate the lithospheric magnetism of the Tibetan Plateau by using a 3D surface spline model based on observations from>200 newly constructed repeat stations(portable stations)to determine the spatial distribution of plateau geomagnetism,as well as its correlation with the tectonic features of the region.We analyze the relationships between M≥5 earthquakes and lithospheric magnetic field variations on the Tibetan Plateau and identify regions susceptible to strong earthquakes.We compare the geomagnetic results with those from an enhanced magnetic model(EMM2015)developed by the NGDC and provide insights into improving lithospheric magnetic field calculations in the Tibetan Plateau region.Further research reveals that these magnetic anomalies exhibit distinct differences from the magnetic-seismic correlation mechanisms observed in other tectonic settings;here,they are governed primarily by the combined effects of compressional magnetism,thermal magnetism,and deep thermal stress.This study provides new evidence of geomagnetic anomalies on the Tibetan Plateau,interprets them physically,and demonstrates their potential for identifying seismic hazard zones on the Plateau. 展开更多
关键词 Tibetan Plateau magnetic variation SEISMICITY surface spline model enhanced magnetic model
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Construction of Bionic Non-Smooth Surface of Cu-Based Friction Materials Based on Finite Element Method
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作者 Lekai Li Juxiang Zhu +3 位作者 Zhaohua Yao Mengting Xing Yitong Tian Ma Yunhai 《Journal of Bionic Engineering》 2026年第1期326-340,共15页
To solve the problem of abnormal abrasion of Cu-Based Friction Materials(CBFMs),Bionic Non-Smooth Surface(BNS)on friction surface of CBFMs was constructed based on bionic principles,and the optimal bionic prototype wa... To solve the problem of abnormal abrasion of Cu-Based Friction Materials(CBFMs),Bionic Non-Smooth Surface(BNS)on friction surface of CBFMs was constructed based on bionic principles,and the optimal bionic prototype was selected by Finite Element Method(FEM).In addition,the bionic parameters were optimized by Response Surface Method(RSM).Samples holding BNS were prepared by Laser Processing,tribological properties were tested by a Friction and Wear Tester and worn surface morphology was characterized by a Scanning Electron Microscope(SEM).The results showed that BNS on friction surface could regulate the stress distribution and alleviate the peak stress.Among all samples,the coupled texture of pit-hexagonal got the minimum peak stress.During braking,bionic texture could also collect wear debris or change the motion forms from sliding to rotation,which can reduce abnormal abrasion.The wear rate was reduced by 19.31%.The results in this paper can provide a new idea for enhancing the tribological properties of CBFMs,and can also lay the foundation for further research of bionic tribology. 展开更多
关键词 Bionic non-smooth surface Friction materials FEM Wear mechanism
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Nitrogen and oxygen isotopes in nitrate and nitrite in the polluted surface waters from the Arno River Basin(Central Italy)
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作者 Lorenzo Chemeri Barbara Nisi +5 位作者 Andrea Pierozzi Jacopo Cabassi Marco Taussi Stefania Venturi Antonio Delgado Huertas Orlando Vaselli 《Journal of Environmental Sciences》 2026年第1期250-262,共13页
The Arno River Basin(Central Italy)is affected by a considerable anthropogenic pressure due to the presence of large cities and widespread industrial and agricultural practices.In this work,26 water samples from the A... The Arno River Basin(Central Italy)is affected by a considerable anthropogenic pressure due to the presence of large cities and widespread industrial and agricultural practices.In this work,26 water samples from the Arno River and its main tributaries were analyzed to assess the water pollution status.The geochemical composition of the Arno River changes from the source(dominated by a Ca-HCO_(3) facies)to the mouth(where a Na-Cl(SO4)chemistry prevails)with an increasing quality deterioration,as suggested by the Chemical Water Quality Index,due to anthropogenic contributions and seawater intrusion before flowing into the Ligurian Sea.The Ombrone and Usciana tributaries introduce anthropogenic pollutants into the Arno River,whilst Elsa tributary supplies significant contents of geogenic sulfate.The concentrations of dissolved nitrate and nitrite(up to 63 and 9 mg/L,respectively)and the respective isotopic values of𝛿15N and𝛿18O were also determined to understand origin and fate of the N-species in the Arno River Basin surface waters.The combined application of𝛿15N-NO_(3) and𝛿18O-NO_(3) and N-source apportionment modelling allowed the identification of soil organic nitrogen and sewage and domestic wastes as primary sources for dissolved NO_(3)-.The𝛿15N-NO_(2) and𝛿18O-NO_(2) values suggest that the nitrification process affects the ARB waters,thus controlling the abundances and proportion of the N-species.Our work indicates that additional efforts are needed to improve management strategies to reduce the release of nitrogenated species to the surface waters of the Arno River Basin,since little progress has been made from the early 2000s. 展开更多
关键词 River geochemistry Water pollution Nitrogen stable isotopes surface water management Water quality Anthropogenic pollution
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Erratum to"Amine-reactive Polymer Platform for Engineering Surface Modification of Next-generation Sequencing Chips"
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作者 Wei Tian Xin-Yuan Wang +4 位作者 Die-Wen Feng Xiang-Qian Li Yue-Kang Jin Hui Li Hao Liu 《Chinese Journal of Polymer Science》 2026年第1期314-314,I0019,共2页
We are sorry for the mistakes of Affiliation,"a State Key Laboratory of Advanced Fiber Materials,Center for Advanced Low-Dimension Materials,Donghua University,Shanghai 201620,China"should be replaced by&quo... We are sorry for the mistakes of Affiliation,"a State Key Laboratory of Advanced Fiber Materials,Center for Advanced Low-Dimension Materials,Donghua University,Shanghai 201620,China"should be replaced by"a State Key Laboratory of Advanced Fiber Materials,Center for Advanced Low-Dimension Materials,College of Materials Science and Engineering,Donghua University,Shanghai 201620,China".We apologized for the inconvenience caused by this error. 展开更多
关键词 erratum surface modification affiliation next generation sequencing chips reactive polymer platform advanced fiber materialscenter
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Experimental study of overall roughness surface effect on hypersonic boundary layer transition of yawed cone
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作者 Guoliang XU Chang ZHU +1 位作者 Jiaquan ZHAO Jie WU 《Chinese Journal of Aeronautics》 2026年第2期29-43,共15页
Crossflow instability will be present when the vehicle has an angle of attack in hypersonic flow,and it might play a dominant role in hypersonic boundary layer transition.By far the mechanism of crossflow instability-... Crossflow instability will be present when the vehicle has an angle of attack in hypersonic flow,and it might play a dominant role in hypersonic boundary layer transition.By far the mechanism of crossflow instability-induced hypersonic boundary layer transition is still out of understanding,although the large effort has been devoted.Upon this work,the overall roughness effect on instabilities in hypersonic flow was researched experimentally.Surface flush-mounted pressure sensors and infrared camera were employed to investigate the instability waves when different rough surfaces were deployed.The results reveal that the moderate surface roughness level on cone model can suppress the growth of crossflow instabilities at certain azimuthal angles in hypersonic flow. 展开更多
关键词 Crossflow instability Roughness surface Boundary layer transition Yawed cone Hypersonic flow
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