In this paper, a strategy for the reactive power compensation and harmonic suppression of the power supply system in HT-7U superconductive Tokamak is proposed. The optimized approach is given in the parameters design...In this paper, a strategy for the reactive power compensation and harmonic suppression of the power supply system in HT-7U superconductive Tokamak is proposed. The optimized approach is given in the parameters design for passive filter. Also a controlling method with fast response time and good accuracy is put forward for the compensator, which is more suitable for the dynamic load.展开更多
By laser heated pedestal growth method, Bi_2Sr_2CaCu_2O_(8+δ) as-grown fibers with different morphologies were solidified in non-equilibrium condition at the rates of 0.1～14mm/min.At low rates,a(Sr_(1-x)Ca_x)CuO_2 p...By laser heated pedestal growth method, Bi_2Sr_2CaCu_2O_(8+δ) as-grown fibers with different morphologies were solidified in non-equilibrium condition at the rates of 0.1～14mm/min.At low rates,a(Sr_(1-x)Ca_x)CuO_2 phase with long and straight strips in shape and a white Cu-rich phase having a morphology of globular shape were found. With the increase of solidification rates,the phase (Sr_(1-x)Ca_x)CuO_2 becomes thinner and the Cu-rich phase becomes smaller and dispersive.When the solidification rates were last.another unstable phase(Sr_(1-x)Ca_x)Cu_2O_3 occurred.In fact,the tran- sition of the semiconductive as-grown fiber to the superconductor is a peritectoid reaction influenced by the annealing temperature and time.展开更多
Large area YBCO superconductive films prepared by d.c. magnetron sputtering have reached: T c>89 K, J c>3.5×10 6 A/cm 2 (77 K, 0 T), R s=0.25 mΩ, at 77.5 K, 9894 MHz. The microstructure an...Large area YBCO superconductive films prepared by d.c. magnetron sputtering have reached: T c>89 K, J c>3.5×10 6 A/cm 2 (77 K, 0 T), R s=0.25 mΩ, at 77.5 K, 9894 MHz. The microstructure analysis of the film showed it has fine monocrystalline structure and the crystalline perfectness is satisfactory. The oscillator, filter and antenna made from these films are good in performance. Therefore, YBCO superconductive films have great prospect in application.展开更多
As one of the main materials in the practical application.of superconductor,lead(Pb)has been used to manufacture superconducting AC power cable,and some weak current fields.With the development of manufacturing,techno...As one of the main materials in the practical application.of superconductor,lead(Pb)has been used to manufacture superconducting AC power cable,and some weak current fields.With the development of manufacturing,technology,more and more researchers focus on exploring the physical and chemical properties of cryogenic superconducting materials,instead of blindly pursuing the improvement of the superconducting transition temperature(T_(c)).In this paper,the structural properties and superconducting transition temperature under high pressure of Pb have been studied by first-principles calculations.It has shown that Pb can withstand the compressive strain up to 10%while the lattice structure remains stable,indicated by the calculations of phonon band structures.From 0%to 10%compressive strain,there is neither a band-gap nor changing of the band structure.The.changing of electronic DOS.at the Fermi level leads to a decreasing of T_(c).Our calculations show that Pb is a stable elemental metallic superconductor even under high pressure,which explains the reason why it has been used in practical productions.展开更多
We investigate the controllable group velocity of a microwave probe field in a superconductive quantum circuit（SQC） pumped by microwave fields,and the use of such a SQC function as an artificial Λ-type three-level ...We investigate the controllable group velocity of a microwave probe field in a superconductive quantum circuit（SQC） pumped by microwave fields,and the use of such a SQC function as an artificial Λ-type three-level atom.The exchange between the subluminal and the superluminal states of the probe field can be realized simply by sweeping the pumping intensity,and the superluminal state is usually realized with a lower absorption.This work is one of the efforts to extend the study of electromagnetically induced transparency and its related properties from the lightwave band to the microwave band.展开更多
On the basis of the published literature and the interviews with some participants,this paper introduces the early history of the studies of superconductive materials and superconducting magnet during 1962～ 1966 in C...On the basis of the published literature and the interviews with some participants,this paper introduces the early history of the studies of superconductive materials and superconducting magnet during 1962～ 1966 in China,narrates the achievements of other relevant experimental and theoretical studies of superconductivity in that period briefly,and tries to give the authors' comments on that history.展开更多
The discovery of an extraordinarily superconductive large energy gap in SrTiO3 supported single-layer FeSe films has recently initiated a great deal of research interests in surface-enhanced superconductivity and supe...The discovery of an extraordinarily superconductive large energy gap in SrTiO3 supported single-layer FeSe films has recently initiated a great deal of research interests in surface-enhanced superconductivity and superconductive ultrathin films fabricated on crystal surfaces. On account of the instability of ultra-thin films in air, it is desirable to perform elec- trical transport measurement in ultra-high vaccum （UHV）. Here we review the experimental techniques of in situ electrical transport measurement and their applications on superconductive ultrathin films.展开更多
Laser heated pedestal growth technique (LHPG) has been used to fabricate BSCCO (BiSrCaCuO) superconductive wires.The critical current density of the wires has surpassed 5000A/cm^2 (78K, OT;cross area=1.04 mm^2).The fi...Laser heated pedestal growth technique (LHPG) has been used to fabricate BSCCO (BiSrCaCuO) superconductive wires.The critical current density of the wires has surpassed 5000A/cm^2 (78K, OT;cross area=1.04 mm^2).The fiber rods obtained directly from LHPG method are semiconductive and after heat treatment at temperature range from 780 to 870℃,they transformed into superconductive wires.Triple junctions and sharp grain boundary exist in the sample.HREM studies showed the intergrowth of (010) and (110),the occasional missing of CaCuO_2 layer in the 2212 phase.展开更多
High quality YBa2Cu3O6+x (YBCO) superconductive thin films have been fabricated on the SrTiO3(100) substrate using laser molecular beam epitaxy (laser-MBE).The active oxygen source was used,which made the necessary am...High quality YBa2Cu3O6+x (YBCO) superconductive thin films have been fabricated on the SrTiO3(100) substrate using laser molecular beam epitaxy (laser-MBE).The active oxygen source was used,which made the necessary ambient oxygen pressure be 2-3 orders lower than that in pulsed laser deposition (PLD).Tc0 is 85-87 K,and Jc～1.0×106 A/cm2.Atomic force microscopy (AFM) measurements show that no obvious particulates can be observed and the root mean square roughness is 7.8 nm.High stability DC superconducting quantum interference devices (DC-SQUID) was fabricated using this YBCO thin film.展开更多
Superconducting diodes,which enable dissipationless supercurrent flow in one direction while blocking it in the reverse direction,are emerging as pivotal components for superconducting electronics.The development of e...Superconducting diodes,which enable dissipationless supercurrent flow in one direction while blocking it in the reverse direction,are emerging as pivotal components for superconducting electronics.The development of editable superconducting diodes could unlock transformative applications,including dynamically reconfigurable quantum circuits that adapt to operational requirements.Here,we report the first observation of the superconducting diode effect(SDE)in LaAlO_(3)/KTaO_(3) heterostructures—a two-dimensional oxide interface superconductor with exceptional tunability.We observe a strong SDE in Hall-bar(or strip-shaped)devices under perpendicular magnetic fields(<15 Oe),with efficiencies above 40%and rectification signals exceeding 10 mV.Through conductive atomic force microscope lithography,we demonstrate reversible nanoscale editing of the SDE’s polarity and efficiency by locally modifying the superconducting channel edges.This approach enables multiple nonvolatile configurations within a single device,realizing an editable superconducting diode.Our work establishes LaAlO_(3)/KTaO_(3) as a platform for vortex-based nonreciprocal transport and provides a pathway toward designer quantum circuits with on-demand functionalities.展开更多
Background In superconductive linear accelerator,the performance and stability can be impacted by gas adsorbed on cryogenic surfaces adversely.The cryogenic devices usually work at 4.2 K or 1.9 K and are refrigerated ...Background In superconductive linear accelerator,the performance and stability can be impacted by gas adsorbed on cryogenic surfaces adversely.The cryogenic devices usually work at 4.2 K or 1.9 K and are refrigerated by normal or super fluid liquid helium,respectively.Purpose The purpose of this paper is to study the character of gas migration in cryogenic tubes.Method Adsorption coefficient for hydrogen at 4.2 K is measured by experimental study.Then,a gas migration model is established based on the experimental results to depict the hydrogen migration process in cryogenic tubes.Results The experimental results and model analysis indicated that at cryogenic temperature(4.2 K),adsorption coefficient for hydrogen is very close to 1,which is several orders higher than the adsorption coefficient at room temperature,resulting in a unique pressure distribution pattern in cryogenic tubes when compared with the pressure distribution in room temperature tubes.Conclusions At 4.2 K or 1.9 K,the gas migration process is obviously different from the process at room temperature and is significantly affected by the gas adsorption on the cryogenic surfaces.The model established in this article can be applied not only to hydrogen migration in cryogenic tubes but also to other gas migration in tubes with high adsorption coefficient.展开更多
Superconducting elect rides have attracted growing attention for their potential to achieve high superconducting transition temperatures(T_(C))under pressure.However,many known elect rides are chemically reactive and ...Superconducting elect rides have attracted growing attention for their potential to achieve high superconducting transition temperatures(T_(C))under pressure.However,many known elect rides are chemically reactive and unstable,making high-quality single-crystal growth,characterization,and measurements difficult,and most do not exhibit superconductivity at ambient pressure.In contrast,La_(3) In stands out for its ambient-pressure superconductivity(T_(C)∼9.4 K)and the availability of high-quality single crystals.Here,we investigate its low-energy electronic structure using angle-resolved photoemission spectroscopy and first-principles calculations.The bands near the Fermi energy(E_(F))are mainly derived from La 5d and In 5p orbitals.A saddle point is directly observed at the Brillouin zone(BZ)boundary,while a three-dimensional Van Hove singularity crosses E_(F) at the BZ corner.First-principles calculations further reveal topological Dirac surface states within the bulk energy gap above E_(F).The coexistence of a high density of states and in-gap topological surface states near𝐸F suggests that La3In offers a promising platform for tuning superconductivity and exploring possible topological superconducting phases through doping or external pressure.展开更多
We report a comprehensive investigation of the superconducting properties of the mineral superconductor covellite(Cu S)using high-quality single crystals.First,we establish that Cu S is an intrinsic type-Ⅱsuperconduc...We report a comprehensive investigation of the superconducting properties of the mineral superconductor covellite(Cu S)using high-quality single crystals.First,we establish that Cu S is an intrinsic type-Ⅱsuperconductor,correcting its long-standing classification as type-Ⅰ.Second,a complete set of anisotropic superconducting parameters is determined,including the critical fields,penetration depth and coherence length,which yield a Ginzburg–Landau parameterκ~1.5 and a moderate anisotropy ofγ~2.Our results indicate that this type-Ⅱsuperconductivity can be well-described by a conventional,weak-coupling,single-band s-wave pairing mechanism.This work fills a long-standing gap in the understanding of this archetypal superconductor.展开更多
A solenoid is typically used in normally conducting and superconducting radio frequency(SRF)photoinjectors to compensate for the projected transverse beam emittance.In the ELBE SRF Gun-Ⅱ,a superconducting solenoid is...A solenoid is typically used in normally conducting and superconducting radio frequency(SRF)photoinjectors to compensate for the projected transverse beam emittance.In the ELBE SRF Gun-Ⅱ,a superconducting solenoid is positioned inside the gun cryomodule approximately 0.7 m from the end of the gun cavity.The spherical aberration and multipole field effects caused by offset and tilt limit the reduction in beam emittance for high bunch charges.We designed a novel superconducting(SC)solenoid with a lower spherical aberration coefficient.In the simulation,the beam emittance from the spherical aberration decreased by 47%.Both the longitudinal and transverse fields were measured and analyzed using the formalism fitting method to assess the performance of the SC solenoid within the cryomodule and its influence on the beam transverse emittance.展开更多
We present a systematic investigation of the superconductivity in high-quality CsTi_(3)Bi_(5) single crystals by combining bulk property characterization and local-probe spectroscopy.Two successive superconducting tra...We present a systematic investigation of the superconductivity in high-quality CsTi_(3)Bi_(5) single crystals by combining bulk property characterization and local-probe spectroscopy.Two successive superconducting transitions are observed in this newly discovered kagome material.In the first stage,the diamagnetic response strengthens significantly from T_(c)~4.9 K to 4.6 K,followed by a broad transition below 4.6 K in the second stage.Moreover,different magnetic field dependences are observed for the two stages,where the first stage is field-insensitive while the second stage exhibits strong field dependence.The ultra-low magnetic field measurements indicate that the lower critical field H_(c1)(T)exhibits small anisotropy.Based on a comparative study of the superconducting state in CsBi2 and microscopic verification via scanning tunneling microscopy(STM),our results suggest the emergence of exotic and intrinsic superconductivity in this new titanium-based kagome superconductor,establishing it as a promising platform for further exploring the complexity of electronic states in the kagome lattice.展开更多
This study investigates the effect of BaHfO_(3)(BHO)addition on the optical properties of YBa_2Cu_(3)O_(7-δ)(YBCO)superconducting thin films using spectroscopic ellipsometry.Through Raman spectroscopy and SEM analysi...This study investigates the effect of BaHfO_(3)(BHO)addition on the optical properties of YBa_2Cu_(3)O_(7-δ)(YBCO)superconducting thin films using spectroscopic ellipsometry.Through Raman spectroscopy and SEM analysis,optimal 10-min Ar ion etching effectively removes surface a-axis-oriented grains and Ba–Cu–O impurities,enhancing surface quality.Optical conductivity analysis reveals a doping-dependent evolution:10%BHO doping maximizes free carrier density and interband transition efficiency,attributed to optimized Cu–O bond contraction and reduced lattice distortions.Higher doping induces defect clustering,carrier scattering,and redshifted transitions due to lattice expansion.Dielectric function and loss function analyses confirm enhanced plasmonic behavior and flux pinning at 10%doping,while excessive doping degrades electronic transitions.These results highlight the critical role of controlled BHO addition and surface treatment in tailoring the optical and superconducting properties of YBCO,offering insights into the interplay among doping,carrier dynamics,and electronic structure in high-temperature superconductors(HTS).展开更多
In recent years,the research on superconductivity in one-dimensional(1D)materials has been attracting increasing attention due to its potential applications in low-dimensional nanodevices.However,the critical temperat...In recent years,the research on superconductivity in one-dimensional(1D)materials has been attracting increasing attention due to its potential applications in low-dimensional nanodevices.However,the critical temperature(T_(c))of 1D superconductors is low.In this work,we theoretically investigate the possible high T_(c) superconductivity of(5,5)carbon nanotube(CNT).The pristine(5,5)CNT is a Dirac semimetal and can be modulated into a semiconductor by full hydrogenation.Interestingly,by further hole doping,it can be regulated into a metallic state with the sp^(3)-hybridized σ electrons metalized,and a giant Kohn anomaly appears in the optical phonons.The two factors together enhance the electron–phonon coupling,and lead to high-T_(c) superconductivity.When the hole doping concentration of hydrogenated-(5,5)CNT is 2.5 hole/cell,the calculated T_(c) is 82.3 K,exceeding the boiling point of liquid nitrogen.Therefore,the predicted hole-doped hydrogenated-(5,5)CNT provides a new platform for 1D high-T_(c) superconductivity and may have potential applications in 1D nanodevices.展开更多
Interfacial superconductivity(IS)has been a topic of intense interest in condensed matter physics,due to its unique properties and exotic photoelectrical performance.However,there are few reports about IS systems cons...Interfacial superconductivity(IS)has been a topic of intense interest in condensed matter physics,due to its unique properties and exotic photoelectrical performance.However,there are few reports about IS systems consisting of two insulators.Here,motivated by the emergence of an insulator-metal transition in type-Ⅲ heterostructures and the superconductivity in some“special”two-dimensional(2D)semiconductors via electron doping,we predict that the 2D heterostructure SnSe_(2)/PtTe_(2) is a model system for realizing IS by using firstprinciples calculations.Our results show that due to slight but crucial interlayer charge transfer,SnSe_(2)/PtTe_(2) turns to be a type-Ⅲ heterostructure with metallic properties and shows a superconducting transition with the critical temperature(T_(c))of 3.73 K.Similar to the enhanced electron–phonon coupling(EPC)in the electrondoped SnSe_(2) monolayer,the IS in the SnSe_(2)/PtTe_(2) heterostructure mainly originates from the metallized SnSe_(2) layer.Furthermore,we find that its superconductivity is sensitive to tensile lattice strain,forming a domeshaped superconducting phase diagram.Remarkably,at 7%biaxial tensile strain,the superconducting T_(c) can increase more than twofold(8.80 K),resulting from softened acoustic phonons at the𝑀point and enhanced EPC strength.Our study provides a concrete example for realizing IS in type-Ⅲ heterostructures,which waits for future experimental verification.展开更多
High-pressure electrides,characterized by the presence of interstitial quasi-atoms(ISQs),possess unique electronic structures and physical properties,such as diverse dimensions of electride states exhibiting different...High-pressure electrides,characterized by the presence of interstitial quasi-atoms(ISQs),possess unique electronic structures and physical properties,such as diverse dimensions of electride states exhibiting different superconductivity,which has attracted significant attention.Here,we report a new electron-deficient type of electride Li_(4)Al and identify its phase transition progress with pressurization,where the internal driving force behind phase transitions,bonding characteristics,and superconducting behaviors have been revealed based on first-principles density functional theory.Through analysis of the bonding properties of electride Li_(4)Al,we demonstrate that the ISQs exhibiting increasingly covalent characteristics between Al ions play a critical role in driving the phase transition.Our electron–phonon coupling calculations indicate that all phases exhibit superconducting behaviors.Importantly,we prove that the ISQs behave as free electrons and demonstrate that the factor governing T_(c) is primarily derived from Li-p-hybridized electronic states with ISQ compositions.These electronic states are scattered by low-frequency phonons arising from mixed vibrations of Li and Al affected by ISQs to enhance electron–phonon coupling.Our study largely expands the research scope of electrides,provides new insight for understanding phase transitions,and elucidates the effects of ISQs on superconducting behavior.展开更多
文摘In this paper, a strategy for the reactive power compensation and harmonic suppression of the power supply system in HT-7U superconductive Tokamak is proposed. The optimized approach is given in the parameters design for passive filter. Also a controlling method with fast response time and good accuracy is put forward for the compensator, which is more suitable for the dynamic load.
基金This work was supported by the National Natural Science Foundation of Chinathe National Laboratory of Rapidly Solidified Non-equilibrium Alloys,Institute of Metal Research,Academia Sinica
文摘By laser heated pedestal growth method, Bi_2Sr_2CaCu_2O_(8+δ) as-grown fibers with different morphologies were solidified in non-equilibrium condition at the rates of 0.1～14mm/min.At low rates,a(Sr_(1-x)Ca_x)CuO_2 phase with long and straight strips in shape and a white Cu-rich phase having a morphology of globular shape were found. With the increase of solidification rates,the phase (Sr_(1-x)Ca_x)CuO_2 becomes thinner and the Cu-rich phase becomes smaller and dispersive.When the solidification rates were last.another unstable phase(Sr_(1-x)Ca_x)Cu_2O_3 occurred.In fact,the tran- sition of the semiconductive as-grown fiber to the superconductor is a peritectoid reaction influenced by the annealing temperature and time.
文摘Large area YBCO superconductive films prepared by d.c. magnetron sputtering have reached: T c>89 K, J c>3.5×10 6 A/cm 2 (77 K, 0 T), R s=0.25 mΩ, at 77.5 K, 9894 MHz. The microstructure analysis of the film showed it has fine monocrystalline structure and the crystalline perfectness is satisfactory. The oscillator, filter and antenna made from these films are good in performance. Therefore, YBCO superconductive films have great prospect in application.
文摘As one of the main materials in the practical application.of superconductor,lead(Pb)has been used to manufacture superconducting AC power cable,and some weak current fields.With the development of manufacturing,technology,more and more researchers focus on exploring the physical and chemical properties of cryogenic superconducting materials,instead of blindly pursuing the improvement of the superconducting transition temperature(T_(c)).In this paper,the structural properties and superconducting transition temperature under high pressure of Pb have been studied by first-principles calculations.It has shown that Pb can withstand the compressive strain up to 10%while the lattice structure remains stable,indicated by the calculations of phonon band structures.From 0%to 10%compressive strain,there is neither a band-gap nor changing of the band structure.The.changing of electronic DOS.at the Fermi level leads to a decreasing of T_(c).Our calculations show that Pb is a stable elemental metallic superconductor even under high pressure,which explains the reason why it has been used in practical productions.
基金Project supported by the National Natural Science Foundation of China (Grant No. 111174040)the Fundamental Research Funds for the Central Universities
文摘We investigate the controllable group velocity of a microwave probe field in a superconductive quantum circuit（SQC） pumped by microwave fields,and the use of such a SQC function as an artificial Λ-type three-level atom.The exchange between the subluminal and the superluminal states of the probe field can be realized simply by sweeping the pumping intensity,and the superluminal state is usually realized with a lower absorption.This work is one of the efforts to extend the study of electromagnetically induced transparency and its related properties from the lightwave band to the microwave band.
文摘On the basis of the published literature and the interviews with some participants,this paper introduces the early history of the studies of superconductive materials and superconducting magnet during 1962～ 1966 in China,narrates the achievements of other relevant experimental and theoretical studies of superconductivity in that period briefly,and tries to give the authors' comments on that history.
基金supported by the National Basic Research Program of China(Grant Nos.2013CB921902 and 2011CB922200)the National Natural Science Foundation of China(Grant Nos.11227404,11274228,11521404,11174199,and 11134008)
文摘The discovery of an extraordinarily superconductive large energy gap in SrTiO3 supported single-layer FeSe films has recently initiated a great deal of research interests in surface-enhanced superconductivity and superconductive ultrathin films fabricated on crystal surfaces. On account of the instability of ultra-thin films in air, it is desirable to perform elec- trical transport measurement in ultra-high vaccum （UHV）. Here we review the experimental techniques of in situ electrical transport measurement and their applications on superconductive ultrathin films.
文摘Laser heated pedestal growth technique (LHPG) has been used to fabricate BSCCO (BiSrCaCuO) superconductive wires.The critical current density of the wires has surpassed 5000A/cm^2 (78K, OT;cross area=1.04 mm^2).The fiber rods obtained directly from LHPG method are semiconductive and after heat treatment at temperature range from 780 to 870℃,they transformed into superconductive wires.Triple junctions and sharp grain boundary exist in the sample.HREM studies showed the intergrowth of (010) and (110),the occasional missing of CaCuO_2 layer in the 2212 phase.
基金This work was supported by the State Key Program of China (Grant No. G1998061412) the National 863 Project (Grant No. 863-CD070103) .
文摘High quality YBa2Cu3O6+x (YBCO) superconductive thin films have been fabricated on the SrTiO3(100) substrate using laser molecular beam epitaxy (laser-MBE).The active oxygen source was used,which made the necessary ambient oxygen pressure be 2-3 orders lower than that in pulsed laser deposition (PLD).Tc0 is 85-87 K,and Jc～1.0×106 A/cm2.Atomic force microscopy (AFM) measurements show that no obvious particulates can be observed and the root mean square roughness is 7.8 nm.High stability DC superconducting quantum interference devices (DC-SQUID) was fabricated using this YBCO thin film.
基金supported by the National Key R&D Program of China (Grant No.2023YFA1406400)the National Natural Science Foundation of China (Grant Nos.12534005 and 12325402)。
文摘Superconducting diodes,which enable dissipationless supercurrent flow in one direction while blocking it in the reverse direction,are emerging as pivotal components for superconducting electronics.The development of editable superconducting diodes could unlock transformative applications,including dynamically reconfigurable quantum circuits that adapt to operational requirements.Here,we report the first observation of the superconducting diode effect(SDE)in LaAlO_(3)/KTaO_(3) heterostructures—a two-dimensional oxide interface superconductor with exceptional tunability.We observe a strong SDE in Hall-bar(or strip-shaped)devices under perpendicular magnetic fields(<15 Oe),with efficiencies above 40%and rectification signals exceeding 10 mV.Through conductive atomic force microscope lithography,we demonstrate reversible nanoscale editing of the SDE’s polarity and efficiency by locally modifying the superconducting channel edges.This approach enables multiple nonvolatile configurations within a single device,realizing an editable superconducting diode.Our work establishes LaAlO_(3)/KTaO_(3) as a platform for vortex-based nonreciprocal transport and provides a pathway toward designer quantum circuits with on-demand functionalities.
文摘Background In superconductive linear accelerator,the performance and stability can be impacted by gas adsorbed on cryogenic surfaces adversely.The cryogenic devices usually work at 4.2 K or 1.9 K and are refrigerated by normal or super fluid liquid helium,respectively.Purpose The purpose of this paper is to study the character of gas migration in cryogenic tubes.Method Adsorption coefficient for hydrogen at 4.2 K is measured by experimental study.Then,a gas migration model is established based on the experimental results to depict the hydrogen migration process in cryogenic tubes.Results The experimental results and model analysis indicated that at cryogenic temperature(4.2 K),adsorption coefficient for hydrogen is very close to 1,which is several orders higher than the adsorption coefficient at room temperature,resulting in a unique pressure distribution pattern in cryogenic tubes when compared with the pressure distribution in room temperature tubes.Conclusions At 4.2 K or 1.9 K,the gas migration process is obviously different from the process at room temperature and is significantly affected by the gas adsorption on the cryogenic surfaces.The model established in this article can be applied not only to hydrogen migration in cryogenic tubes but also to other gas migration in tubes with high adsorption coefficient.
基金supported by the National Natural Science Foundation of China(Grant Nos.12222413,12174443,12274459,and 12404266)the National Key R&D Program of China(Grant Nos.2023YFA1406500,2022YFA1403800,and 2022YFA1403103)+3 种基金the Natural Science Foundation of Shanghai (Grant No.23ZR1482200)the Natural Science Foundation of Ningbo (Grant No.2024J019)the Science Research Project of Hebei Education Department (Grant No.BJ2025060)the funding of Ningbo Yongjiang Talent Program。
文摘Superconducting elect rides have attracted growing attention for their potential to achieve high superconducting transition temperatures(T_(C))under pressure.However,many known elect rides are chemically reactive and unstable,making high-quality single-crystal growth,characterization,and measurements difficult,and most do not exhibit superconductivity at ambient pressure.In contrast,La_(3) In stands out for its ambient-pressure superconductivity(T_(C)∼9.4 K)and the availability of high-quality single crystals.Here,we investigate its low-energy electronic structure using angle-resolved photoemission spectroscopy and first-principles calculations.The bands near the Fermi energy(E_(F))are mainly derived from La 5d and In 5p orbitals.A saddle point is directly observed at the Brillouin zone(BZ)boundary,while a three-dimensional Van Hove singularity crosses E_(F) at the BZ corner.First-principles calculations further reveal topological Dirac surface states within the bulk energy gap above E_(F).The coexistence of a high density of states and in-gap topological surface states near𝐸F suggests that La3In offers a promising platform for tuning superconductivity and exploring possible topological superconducting phases through doping or external pressure.
基金supported by the National Key Research and Development Program of China(Grant Nos.2024YFA1611102,2022YFA1403903,2022YFA1602802,and 2023YFA1406101)the National Natural Science Foundation of China(Grant No.12304075)CAS Project for Young Scientists in Basic Research(Grant No.2022YSBR-048)。
文摘We report a comprehensive investigation of the superconducting properties of the mineral superconductor covellite(Cu S)using high-quality single crystals.First,we establish that Cu S is an intrinsic type-Ⅱsuperconductor,correcting its long-standing classification as type-Ⅰ.Second,a complete set of anisotropic superconducting parameters is determined,including the critical fields,penetration depth and coherence length,which yield a Ginzburg–Landau parameterκ~1.5 and a moderate anisotropy ofγ~2.Our results indicate that this type-Ⅱsuperconductivity can be well-described by a conventional,weak-coupling,single-band s-wave pairing mechanism.This work fills a long-standing gap in the understanding of this archetypal superconductor.
基金Open Access funding enabled and organized by Projekt DEAL.
文摘A solenoid is typically used in normally conducting and superconducting radio frequency(SRF)photoinjectors to compensate for the projected transverse beam emittance.In the ELBE SRF Gun-Ⅱ,a superconducting solenoid is positioned inside the gun cryomodule approximately 0.7 m from the end of the gun cavity.The spherical aberration and multipole field effects caused by offset and tilt limit the reduction in beam emittance for high bunch charges.We designed a novel superconducting(SC)solenoid with a lower spherical aberration coefficient.In the simulation,the beam emittance from the spherical aberration decreased by 47%.Both the longitudinal and transverse fields were measured and analyzed using the formalism fitting method to assess the performance of the SC solenoid within the cryomodule and its influence on the beam transverse emittance.
基金supported by the National Key Research and Development Program of China(Grant Nos.2024YFA1611102,2022YFA1403903,2023YFA1406101,and 2022YFA1204100)the National Natural Science Foundation of China(Grant Nos.12304075 and 62488201)+1 种基金CAS Project for Young Scientists in Basic Research(Grant Nos.2022YSBR-048 and YSBR-003)the Innovation Program of Quantum Science and Technology(Grant No.2021ZD0302700)。
文摘We present a systematic investigation of the superconductivity in high-quality CsTi_(3)Bi_(5) single crystals by combining bulk property characterization and local-probe spectroscopy.Two successive superconducting transitions are observed in this newly discovered kagome material.In the first stage,the diamagnetic response strengthens significantly from T_(c)~4.9 K to 4.6 K,followed by a broad transition below 4.6 K in the second stage.Moreover,different magnetic field dependences are observed for the two stages,where the first stage is field-insensitive while the second stage exhibits strong field dependence.The ultra-low magnetic field measurements indicate that the lower critical field H_(c1)(T)exhibits small anisotropy.Based on a comparative study of the superconducting state in CsBi2 and microscopic verification via scanning tunneling microscopy(STM),our results suggest the emergence of exotic and intrinsic superconductivity in this new titanium-based kagome superconductor,establishing it as a promising platform for further exploring the complexity of electronic states in the kagome lattice.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52172271,12374378,52307026,and 52477022)the National Key Research and Development Program of China(Grant No.2022YFE03150200)Shanghai Science and Technology Innovation Program(Grant No.23511101600)。
文摘This study investigates the effect of BaHfO_(3)(BHO)addition on the optical properties of YBa_2Cu_(3)O_(7-δ)(YBCO)superconducting thin films using spectroscopic ellipsometry.Through Raman spectroscopy and SEM analysis,optimal 10-min Ar ion etching effectively removes surface a-axis-oriented grains and Ba–Cu–O impurities,enhancing surface quality.Optical conductivity analysis reveals a doping-dependent evolution:10%BHO doping maximizes free carrier density and interband transition efficiency,attributed to optimized Cu–O bond contraction and reduced lattice distortions.Higher doping induces defect clustering,carrier scattering,and redshifted transitions due to lattice expansion.Dielectric function and loss function analyses confirm enhanced plasmonic behavior and flux pinning at 10%doping,while excessive doping degrades electronic transitions.These results highlight the critical role of controlled BHO addition and surface treatment in tailoring the optical and superconducting properties of YBCO,offering insights into the interplay among doping,carrier dynamics,and electronic structure in high-temperature superconductors(HTS).
基金supported by the National Natural Science Foundation of China (Grant Nos.12074213 and 11574108)the Major Basic Program of Natural Science Foundation of Shandong Province (Grant No.ZR2021ZD01)the Natural Science Foundation of Shandong Province (Grant No.ZR2023MA082)。
文摘In recent years,the research on superconductivity in one-dimensional(1D)materials has been attracting increasing attention due to its potential applications in low-dimensional nanodevices.However,the critical temperature(T_(c))of 1D superconductors is low.In this work,we theoretically investigate the possible high T_(c) superconductivity of(5,5)carbon nanotube(CNT).The pristine(5,5)CNT is a Dirac semimetal and can be modulated into a semiconductor by full hydrogenation.Interestingly,by further hole doping,it can be regulated into a metallic state with the sp^(3)-hybridized σ electrons metalized,and a giant Kohn anomaly appears in the optical phonons.The two factors together enhance the electron–phonon coupling,and lead to high-T_(c) superconductivity.When the hole doping concentration of hydrogenated-(5,5)CNT is 2.5 hole/cell,the calculated T_(c) is 82.3 K,exceeding the boiling point of liquid nitrogen.Therefore,the predicted hole-doped hydrogenated-(5,5)CNT provides a new platform for 1D high-T_(c) superconductivity and may have potential applications in 1D nanodevices.
基金supported by the National Key R&D Program of China (Grant Nos.2022YFA1403103 and 2019YFA0308603)the National Natural Science Foundation of China (Grant No.12304167)the Shandong Provincial Natural Science Foundation of China (Grant No.ZR2023QA020)。
文摘Interfacial superconductivity(IS)has been a topic of intense interest in condensed matter physics,due to its unique properties and exotic photoelectrical performance.However,there are few reports about IS systems consisting of two insulators.Here,motivated by the emergence of an insulator-metal transition in type-Ⅲ heterostructures and the superconductivity in some“special”two-dimensional(2D)semiconductors via electron doping,we predict that the 2D heterostructure SnSe_(2)/PtTe_(2) is a model system for realizing IS by using firstprinciples calculations.Our results show that due to slight but crucial interlayer charge transfer,SnSe_(2)/PtTe_(2) turns to be a type-Ⅲ heterostructure with metallic properties and shows a superconducting transition with the critical temperature(T_(c))of 3.73 K.Similar to the enhanced electron–phonon coupling(EPC)in the electrondoped SnSe_(2) monolayer,the IS in the SnSe_(2)/PtTe_(2) heterostructure mainly originates from the metallized SnSe_(2) layer.Furthermore,we find that its superconductivity is sensitive to tensile lattice strain,forming a domeshaped superconducting phase diagram.Remarkably,at 7%biaxial tensile strain,the superconducting T_(c) can increase more than twofold(8.80 K),resulting from softened acoustic phonons at the𝑀point and enhanced EPC strength.Our study provides a concrete example for realizing IS in type-Ⅲ heterostructures,which waits for future experimental verification.
基金supported by the National Key Research and Development Program of China (Grant Nos.2023YFA1406200 and 2022YFA-1405500)the National Natural Science Foundation of China (Grant Nos.12304021 and 52072188)+3 种基金Zhejiang Provincial Natural Science Foundation of China (Grant Nos.LQ23A040004 and MS26A040028)Natural Science Foundation of Ningbo (Grant Nos.2022J091 and ZX2025001430)the Program for Science and Technology Innovation Team in Zhejiang (Grant No.2021R01004)the Program for Changjiang Scholars and Innovative Research Team in University (Grant No.IRT_15R23)。
文摘High-pressure electrides,characterized by the presence of interstitial quasi-atoms(ISQs),possess unique electronic structures and physical properties,such as diverse dimensions of electride states exhibiting different superconductivity,which has attracted significant attention.Here,we report a new electron-deficient type of electride Li_(4)Al and identify its phase transition progress with pressurization,where the internal driving force behind phase transitions,bonding characteristics,and superconducting behaviors have been revealed based on first-principles density functional theory.Through analysis of the bonding properties of electride Li_(4)Al,we demonstrate that the ISQs exhibiting increasingly covalent characteristics between Al ions play a critical role in driving the phase transition.Our electron–phonon coupling calculations indicate that all phases exhibit superconducting behaviors.Importantly,we prove that the ISQs behave as free electrons and demonstrate that the factor governing T_(c) is primarily derived from Li-p-hybridized electronic states with ISQ compositions.These electronic states are scattered by low-frequency phonons arising from mixed vibrations of Li and Al affected by ISQs to enhance electron–phonon coupling.Our study largely expands the research scope of electrides,provides new insight for understanding phase transitions,and elucidates the effects of ISQs on superconducting behavior.
