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SUPER-ELASTIC CONSTITUTIVE MODEL CONSIDERING PLASTICITY AND ITS FINITE ELEMENT IMPLEMENTATION 被引量:7
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作者 Qianhua Kan Guozheng Kang 1 Linmao Qian(State Key Laboratory of Traction Power,Southwest Jiaotong University,Chengdu 610031,China) 《Acta Mechanica Solida Sinica》 SCIE EI 2010年第2期95-105,共11页
Based on the experimental results of super-elastic NiTi alloy, a three-dimensional super-elastic constitutive model including both of stress-induced martensite transformation and plasticity is constructed in a framewo... Based on the experimental results of super-elastic NiTi alloy, a three-dimensional super-elastic constitutive model including both of stress-induced martensite transformation and plasticity is constructed in a framework of general inelasticity. In the proposed model, transformation hardening, reverse transformation of stress-induced martensite, elastic mismatch between the austenite and martensite phases, and temperature-dependence of transformation stress and elastic modulus of each phase are considered. The plastic yielding of martensite occurred under high stress is addressed by a bilinear isotropic hardening rule. Drucker-Prager-typed transformation surfaces are employed to describe the asymmetric behavior of NiTi alloy in tension and compression. The prediction capability of the proposed model is verified by comparing the simulated results with the correspondent experimental ones. Based on backward Euler's integration, a new expression of consistent tangent modulus is derived. The proposed model is then implemented into a finite element package ABAQUS by user-subroutine UMAT. Finally, the validity of such implementation was verified by some numerical samples. 展开更多
关键词 NiTi alloy super-elasticity PLASTICITY finite element implementation
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COMPUTATION OF SUPER-CONVERGENT NODAL STRESSES OF TIMOSHENKO BEAM ELEMENTS BY EEP METHOD 被引量:1
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作者 王枚 袁驷 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2004年第11期1228-1240,共13页
The newly proposed element energy projection(EEP) method has been applied to the computation of super_convergent nodal stresses of Timoshenko beam elements.General formulas based on element projection theorem were der... The newly proposed element energy projection(EEP) method has been applied to the computation of super_convergent nodal stresses of Timoshenko beam elements.General formulas based on element projection theorem were derived and illustrative numerical examples using two typical elements were given.Both the analysis and examples show that EEP method also works very well for the problems with vector function solutions.The EEP method gives super_convergent nodal stresses,which are well comparable to the nodal displacements in terms of both convergence rate and error magnitude.And in addition,it can overcome the “shear locking” difficulty for stresses even when the displacements are badly affected.This research paves the way for application of the EEP method to general one_dimensional systems of ordinary differential equations. 展开更多
关键词 Timoshenko beam element super-convergent stress element energy projection method shear locking
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Self-adaptive strategy for one-dimensional finite element method based on EEP method with optimal super-convergence order 被引量:4
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作者 袁驷 邢沁妍 +1 位作者 王旭 叶康生 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2008年第5期591-602,共12页
Based on the newly-developed element energy projection (EEP) method with optimal super-convergence order for computation of super-convergent results, an improved self-adaptive strategy for one-dimensional finite ele... Based on the newly-developed element energy projection (EEP) method with optimal super-convergence order for computation of super-convergent results, an improved self-adaptive strategy for one-dimensional finite element method (FEM) is proposed. In the strategy, a posteriori errors are estimated by comparing FEM solutions to EEP super-convergent solutions with optimal order of super-convergence, meshes are refined by using the error-averaging method. Quasi-FEM solutions are used to replace the true FEM solutions in the adaptive process. This strategy has been found to be simple, clear, efficient and reliable. For most problems, only one adaptive step is needed to produce the required FEM solutions which pointwise satisfy the user specified error tolerances in the max-norm. Taking the elliptical ordinary differential equation of the second order as the model problem, this paper describes the fundamental idea, implementation strategy and computational algorithm and representative numerical examples are given to show the effectiveness and reliability of the proposed approach. 展开更多
关键词 finite element method (FEM) self-adaptive solution super-convergence optimal convergence order element energy projection condensed shape functions
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Super-Enrichment of Dispersed Elements and Associated Ore Deposits
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作者 高振敏 姚林波 《Chinese Journal Of Geochemistry》 EI CAS 2004年第1期46-51,共6页
Dispersed elements do not always occur as associated elements in the ore deposits of other elements. Instead, they can constitute independent ore deposits. The focus of this paper is placed on the mechanism of super-e... Dispersed elements do not always occur as associated elements in the ore deposits of other elements. Instead, they can constitute independent ore deposits. The focus of this paper is placed on the mechanism of super-enrichment of the four dispersed elements Tl, Ge, Se, and Te under favorable geological conditions, where their enrichment coefficients are so high that their abundances can reach n×10+3-n×10+4, sometimes even up to n×10+6 times (e.g. Te) those of the crust. As a result, they can form their independent ore deposits. Studies have shown that such independent ore deposits are mostly distributed in the southwestern part of China, most of which belong to low-temperature ore deposits, ranging in age from Yanshanian to Himalayan (Cretaceous to Cenozoic), with a significant time gap with the host strata. Moreover, this paper also deals with the existing forms (as independent minerals, occurring isomorphously and being adsorbed) of the dispersed elements in those independent ore deposits. The discovery of independent ore deposits of dispersed elements is a great breakthrough in the study of dispersed element metallogenesis. 展开更多
关键词 沉积物 地质条件 元素富集 地壳 喜马拉雅山
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Self-adaptive one-dimensional nonlinear finite element method based on element energy projection method 被引量:17
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作者 袁驷 杜炎 +1 位作者 邢沁妍 叶康生 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2014年第10期1223-1232,共10页
The element energy projection (EEP) method for computation of super- convergent resulting in a one-dimensional finite element method (FEM) is successfully used to self-adaptive FEM analysis of various linear probl... The element energy projection (EEP) method for computation of super- convergent resulting in a one-dimensional finite element method (FEM) is successfully used to self-adaptive FEM analysis of various linear problems, based on which this paper presents a substantial extension of the whole set of technology to nonlinear problems. The main idea behind the technology transfer from linear analysis to nonlinear analysis is to use Newton's method to linearize nonlinear problems into a series of linear problems so that the EEP formulation and the corresponding adaptive strategy can be directly used without the need for specific super-convergence formulation for nonlinear FEM. As a re- sult, a unified and general self-adaptive algorithm for nonlinear FEM analysis is formed. The proposed algorithm is found to be able to produce satisfactory finite element results with accuracy satisfying the user-preset error tolerances by maximum norm anywhere on the mesh. Taking the nonlinear ordinary differential equation (ODE) of second-order as the model problem, this paper describes the related fundamental idea, the imple- mentation strategy, and the computational algorithm. Representative numerical exam- ples are given to show the efficiency, stability, versatility, and reliability of the proposed approach. 展开更多
关键词 NONLINEARITY finite element method (FEM) self-adaptive analysis super-convergence element energy projection (EEP)~ ordinary differential equation(ODE)
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SELF-ADAPTIVE STRATEGY FOR ONE-DIMENSIONAL FINITE ELEMENT METHOD BASED ON ELEMENT ENERGY PROJECTION METHOD 被引量:4
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作者 袁驷 和雪峰 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2006年第11期1461-1474,共14页
Based on the newly-developed element energy projection (EEP) method for computation of super-convergent results in one-dimensional finite element method (FEM), the task of self-adaptive FEM analysis was converted ... Based on the newly-developed element energy projection (EEP) method for computation of super-convergent results in one-dimensional finite element method (FEM), the task of self-adaptive FEM analysis was converted into the task of adaptive piecewise polynomial interpolation. As a result, a satisfactory FEM mesh can be obtained, and further FEM analysis on this mesh would immediately produce an FEM solution which usually satisfies the user specified error tolerance. Even though the error tolerance was not completely satisfied, one or two steps of further local refinements would be sufficient. This strategy was found to be very simple, rapid, cheap and efficient. Taking the elliptical ordinary differential equation of second order as the model problem, the fundamental idea, implementation strategy and detailed algorithm are described. Representative numerical examples are given to show the effectiveness and reliability of the proposed approach. 展开更多
关键词 finite element method (FEM) self-adaptive solution super-convergence element energy projection ordinary differential equation (ODE)
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Distribution of calcium, nickel, iron, and manganese in super-heavy oil from Liaohe Oilfield, China 被引量:4
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作者 Wu Bencheng Zhu Jianhua Li Xiaohui 《Petroleum Science》 SCIE CAS CSCD 2014年第4期590-595,共6页
Liaohe super-heavy crude oil was separated into its components, namely saturates, aromatics, resins, and asphaltenes (SARA), by the group separation method. Several solvents were used to extract different forms of m... Liaohe super-heavy crude oil was separated into its components, namely saturates, aromatics, resins, and asphaltenes (SARA), by the group separation method. Several solvents were used to extract different forms of metallic elements from crude oil. The metallic elements, such as calcium, nickel, iron and manganese, in crude oil, SARA and extract samples were analyzed by inductively coupled plasma atomic emission spectroscopy (ICP-AES). The results demonstrate that the contents of calcium, nickel, iron, and manganese gradually increase in saturates, aromatics, resins, and asphaltenes, suggesting that the abundance of the four metallic elements in asphaltenes is much higher than that in the other groups. For example, the content of calcium in asphaltenes reaches a maximum of 7,920 pg/g. Among the SARA components of Liaohe super-heavy crude oil, resins account for more than 50 wt%, suggesting that the total amount of the four metallic elements are higher in the resin component than in other components. The four metallic elements mainly exist in the form of organic metallic compounds in crude oil. Further analysis shows that calcium and manganese elements exist mainly as metal salts of petroleum acids, and the majority of the iron and all the nickel exist mainly as metalloporphyrin and non-metalloporphyrin compounds. 展开更多
关键词 super-heavy oil metallic element DISTRIBUTION group separation solvent extraction
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Repressor elements provide insights into tissue development and phenotypes in pigs
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作者 Yue-Dong Zhang Chao Guo +9 位作者 Hang Liu Yun Gao Yongjun Tan Longjian Niu Ligang Wang Lixian Wang David MIrwin Chunhui Hou Zhong-Yin Zhou Ya-Ping Zhang 《Zoological Research》 SCIE CSCD 2024年第6期1313-1326,共14页
Repressor elements significantly influence economically relevant phenotypes in pigs;however,their precise roles and characteristics are inadequately understood.In the present study,we employed H3K27me3 profiling,assay... Repressor elements significantly influence economically relevant phenotypes in pigs;however,their precise roles and characteristics are inadequately understood.In the present study,we employed H3K27me3 profiling,assay for transposase-accessible chromatin with highthroughput sequencing(ATAC-seq),and RNA sequencing(RNA-seq)data across six tissues derived from three embryonic layers to identify and map 2034 super repressor elements(SREs) and 22223 typical repressor elements(TREs) in the pig genome.Notably,many repressor elements were conserved across mesodermal and ectodermal tissues.SREs exhibited tight regulation of their target genes,affecting a limited number of genes within a specific genomic region with pronounced effects,while TREs exerted broader but weaker regulation over a wider range of target genes.Furthermore,in neuronal tissues,genes regulated by repressor elements started to be repressed during the differentiation of stem cells into progenitor cells.Notably,analysis showed that many repressor elements exhibited cooperative and additive effects on the modulation of KLF4 expression.This research provides the first comprehensive map of pig repressor elements,serving as an essential reference for future studies on repressor elements. 展开更多
关键词 Repressor elements super repressor elements SILENCER Regulatory model Tissue development KLF4 Pig
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Difficulties and measures of driving super long piles in Bohai Gulf
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作者 Shuwang Yan Jia Li +1 位作者 Liqiang Sun Guomin Sun 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2015年第2期69-73,共5页
Long piles of the ocean oil platform are usually manufactured as the integration of several segments, which have to be assembled one by one during installation. During pile driving, excessive pore pressure will build ... Long piles of the ocean oil platform are usually manufactured as the integration of several segments, which have to be assembled one by one during installation. During pile driving, excessive pore pressure will build up in such a high level that hydraulic fracturing in the soil round the pile may take place, which will cause the soil to consolidate much faster during pile extension period. Consequently, after pile extension, the soil strength will recover to some extent and the driving resistance will increase considerably, which makes restarting driving the pile very difficult and even causes refusal. A finite element (FE) analysis procedure is presented for judging the risk of refusal by estimating the blow counts after pile extension, in which the regain of soil strength is considered. A case analysis in Bohai Gulf is performed using the proposed orocedure to exolain the nile refusal phenomenon. 展开更多
关键词 super long pile driving Refusal Excessive pore pressure Hydraulic fracture Finite element analysis Prevent measures
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一维Galerkin有限元EEP超收敛计算的加强格式
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作者 袁驷 杨帅 《工程力学》 北大核心 2025年第5期1-8,共8页
基于对单元能量投影(element energy projection,EEP)法误差项的直接推导及分析,用EEP简约格式的解计算出略掉的误差项,反补后得到比简约格式高一阶精度的EEP超收敛计算的加强格式。该文以一维Galerkin有限元为例,给出EEP加强格式的算... 基于对单元能量投影(element energy projection,EEP)法误差项的直接推导及分析,用EEP简约格式的解计算出略掉的误差项,反补后得到比简约格式高一阶精度的EEP超收敛计算的加强格式。该文以一维Galerkin有限元为例,给出EEP加强格式的算法公式和数学证明。理论分析和算例验证表明:对于m (≥1)次单元,采用EEP加强格式计算的内点位移和内点导数都具有h^(min(m+3,2m))阶的收敛精度,对系数特例问题二者甚至可以分别达到h^(min(m+5,2m))和h^(min(m+4,2m))阶的收敛精度。并对该法的进一步拓展作了讨论。 展开更多
关键词 GALERKIN有限元 一维问题 超收敛 单元能量投影(EEP) 加强格式
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动车组车体复合材料承载部件结构强度优化
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作者 谢素明 张乾 +1 位作者 王彦翔 薛宁鑫 《大连交通大学学报》 2025年第3期54-61,共8页
利用超单元和结构优化相结合的技术,对动车组复合材料车体承载部件进行强度优化。首先,根据复合材料承载特点和力学特征,建立某动车组复合材料车体强度分析有限元模型。其次,在EN 12663-2014标准静态载荷工况下,车体碳纤维侧墙的最大蔡... 利用超单元和结构优化相结合的技术,对动车组复合材料车体承载部件进行强度优化。首先,根据复合材料承载特点和力学特征,建立某动车组复合材料车体强度分析有限元模型。其次,在EN 12663-2014标准静态载荷工况下,车体碳纤维侧墙的最大蔡-吴失效因子仅为0.120,表明结构强度存在较大冗余。最后,通过超单元建模技术,以侧墙柔度、质量和铺层顺序为目标函数,以质量分数、蔡-吴失效因子和应变值为约束条件,对侧墙铺层方案进行优化设计,得到最佳的铺层顺序为[45°/-45°/45°/-45°/0°/45°/-45°/90°/90°/0°/90°/0°/45°/-45°]_(s)。优化结果显示,侧墙质量减少24.2%,最大蔡-吴失效因子提升至0.278,在满足车体静强度要求的同时,有效减少强度冗余。 展开更多
关键词 动车组 复合材料 超单元 铺层优化设计
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Light weight analysis of a skeleton vehicle frame using BS960 super-high-strength steel 被引量:1
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作者 HAO Xin WANG Yong CAI Zheng 《Baosteel Technical Research》 CAS 2016年第2期40-44,共5页
Static strength finite element analysis was conducted to decrease the weight of a skeleton vehicle's frame. Results indicated that the maximum stress occurs on the front beam 's variable section area. Dynamic sensit... Static strength finite element analysis was conducted to decrease the weight of a skeleton vehicle's frame. Results indicated that the maximum stress occurs on the front beam 's variable section area. Dynamic sensitivity analysis elucidated the relationship between the maximum stress and the thickness of a particular beam,e. g.,top,middle,and bottom beam. Displacement was analyzed by the key part that influenced the maximum stress. Finally,the new plan using BS960 super-high-strength beam steel and the preferred beam thickness was compared with the original plan. New combinations of beam thickness were introduced on the basis of different purposes; the maximum responding light w eight ratio was 21%. 展开更多
关键词 skeleton vehicle frame finite element analysis dynamic sensitivity analysis BS960 super-high-strength beam steel light weight
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温度作用下高精电子厂房开洞华夫板的力学性能分析 被引量:1
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作者 杨超祺 陈连健 +2 位作者 方四宝 向勇 李海锋 《华侨大学学报(自然科学版)》 2025年第3期272-282,共11页
为分析不设置伸缩缝的开洞华夫板受温度影响下楼板的应力及裂缝响应,采用ABAQUS有限元分析软件对开洞华夫板进行仿真模拟,对比工程实际,得到该类楼板在不同尺寸及温度变化下的应力、变形情况。结果表明:在日常温度变化下,核心区楼板均... 为分析不设置伸缩缝的开洞华夫板受温度影响下楼板的应力及裂缝响应,采用ABAQUS有限元分析软件对开洞华夫板进行仿真模拟,对比工程实际,得到该类楼板在不同尺寸及温度变化下的应力、变形情况。结果表明:在日常温度变化下,核心区楼板均不超过计算应力限值,位移最大与应力集中主要出现在板柱节点处;随着混凝土强度上升,同温差下整体应力无明显变化,增量不大于2%,但楼板厚度的增加会导致应力突变及变形趋势的改变;考虑对跨度较大的钢筋混凝土楼板进行分块施工,合理控制板块间的温差为15~30℃,有利于整体浇筑后楼板的应力均匀分布。 展开更多
关键词 温度作用 开洞华夫板 有限元模拟 超长混凝土
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超级微波消解-电感耦合等离子体发射光谱法测定食糖中8种营养元素 被引量:1
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作者 余健斌 钟艺维 +3 位作者 钟宏星 辜秋如 郭汶彬 陆剑华 《甘蔗糖业》 2025年第3期102-109,共8页
构建了基于超级微波消解与电感耦合等离子体发射光谱检测技术,测定食糖中钙、铁、钾、镁、锰、钠、磷、锌8种营养元素含量的方法。通过优化消解体系与最高消解温度,保证了食糖样品的消解完全。通过观测方式优化及分析谱线优选提高了电... 构建了基于超级微波消解与电感耦合等离子体发射光谱检测技术,测定食糖中钙、铁、钾、镁、锰、钠、磷、锌8种营养元素含量的方法。通过优化消解体系与最高消解温度,保证了食糖样品的消解完全。通过观测方式优化及分析谱线优选提高了电感耦合等离子体发射光谱法测定8种目标元素的灵敏度与抗干扰能力。为了考察方法的精密度和准确性,进行3种食糖加标回收实验及重复性实验。方法验证表明,各元素标准曲线相关系数均超过0.9997,方法检出限在0.0059~2.5384 mg/kg之间,3类食糖样品8种目标元素的加标回收率在90.84%~103.61%之间,白砂糖加标样品的8种营养元素的重复测定RSD值控制在1.1%~2.5%之间。该方法简便、快捷、准确、高效、稳定,可以满足日常中所有种类食糖8种营养元素的检测需求。 展开更多
关键词 食糖 营养元素 超级微波消解 电感耦合等离子体发射光谱法
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超级增强子与肥胖相关代谢性疾病的研究进展
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作者 王同帅 郭锡熔 《中国儿童保健杂志》 北大核心 2025年第10期1079-1081,共3页
超级增强子(SE)是基因组中重要的大片段顺式调控元件,通过显著增强基因转录效率发挥基因调控作用。细胞内数百个SE协同调控大量关键基因,其异常活化与糖尿病、炎症和肿瘤等多种疾病的发生密切相关。然而,SE在代谢性疾病中的调控机制研... 超级增强子(SE)是基因组中重要的大片段顺式调控元件,通过显著增强基因转录效率发挥基因调控作用。细胞内数百个SE协同调控大量关键基因,其异常活化与糖尿病、炎症和肿瘤等多种疾病的发生密切相关。然而,SE在代谢性疾病中的调控机制研究仍相对滞后。代谢性疾病不仅是多种慢性病的早期诱因,也是肿瘤发生的关键风险因素,被视为疾病发生的“共同土壤”。深入研究SE在代谢性疾病中的作用机制,可为完善疾病防治策略提供科学依据。本文就SE在代谢性疾病中的作用与机制进行综述,以期为开展相关基础研究和开拓临床应用提供依据。 展开更多
关键词 超级增强子 肥胖 转录调控 调节元件 代谢性疾病
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钢-UHPC组合梁与钢箱梁结合段有限元分析
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作者 刘沐宇 邢恒 +2 位作者 邓晓光 冯鹏程 刘新华 《武汉理工大学学报(交通科学与工程版)》 2025年第2期374-379,386,共7页
针对某主跨1 160 m的混合式组合梁斜拉桥主梁结合段设计方案的受力性能分析问题,采用ABAQUS软件建立实桥的钢箱梁-组合梁结合段的精细化有限元模型,计算得到实桥模型在最大轴力工况、最大弯矩工况下的应力特征.结果如下:钢箱梁-组合梁... 针对某主跨1 160 m的混合式组合梁斜拉桥主梁结合段设计方案的受力性能分析问题,采用ABAQUS软件建立实桥的钢箱梁-组合梁结合段的精细化有限元模型,计算得到实桥模型在最大轴力工况、最大弯矩工况下的应力特征.结果如下:钢箱梁-组合梁结合段在最大弯矩工况下,钢结构最大Mises应力为158.5 MPa, UHPC桥面板最大轴向压应力为16.9 MPa,最大主压应力为17.1 MPa,最大拉应力为2.4 MPa;承压板分担了5.87×10^(4) kN的轴力,占总轴力的36%,钢箱梁承担总轴力的64%,传力均匀明确,传力路径清晰,结合段受力满足规范要求. 展开更多
关键词 超千米主跨斜拉桥 钢箱梁-组合梁结合段 有限元模拟 应力分析 传力机理
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超大型舰船浮箱下水技术及计算方法
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作者 李啸峰 李小灵 +2 位作者 陈明高 于瑶 奚喆华 《船舶与海洋工程》 2025年第5期76-81,共6页
以某超大型舰船为例,针对其空船重量超过载船浮箱最大载重量和下水过程中“船-箱系统”局部受力过大的问题,开展下水重量控制、支撑系统优化、浮箱装载优化和安全起浮控制技术研究;采用弹簧单元、刚性连接和大刚度弹簧单元模拟横梁与船... 以某超大型舰船为例,针对其空船重量超过载船浮箱最大载重量和下水过程中“船-箱系统”局部受力过大的问题,开展下水重量控制、支撑系统优化、浮箱装载优化和安全起浮控制技术研究;采用弹簧单元、刚性连接和大刚度弹簧单元模拟横梁与船体和支墩之间的连接形式,并根据弹簧单元支反力大小采用不同的浮箱载船分析模型方案,建立一种新的“船-箱”有限元分析简化力学模型,准确模拟船体、支撑系统和浮箱之间的变形耦合效应和主要构件的刚度特征,开展浮箱载船下水结构强度分析。研究表明,提出的船舶浮箱下水技术和浮箱载船下水结构强度分析方法合理有效,能保障超大型舰船浮箱载船下水的安全性。研究成果可供类似规模舰船灵活开展浮箱载船下水作业参考。 展开更多
关键词 超大型舰船 浮箱下水 有限元分析 弹簧单元 刚性连接
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超级微波消解-碰撞反应池电感耦合等离子体质谱法测定蔬菜中21种元素含量
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作者 曾云夏 曾晓龙 +5 位作者 薛丰 冷文杰 刘淼 胡雪郢 徐增伟 游飞凤 《食品安全质量检测学报》 2025年第19期18-25,共8页
目的建立超级微波消解-碰撞反应池电感耦合等离子体质谱法同时测定蔬菜中铅、砷、镉、铬等21种元素的方法。方法选择超级微波消解法进行样品预处理,以硝酸为消解液,运用具有八极杆反应池系统的电感耦合等离子体质谱仪,以铂锥作为采样锥... 目的建立超级微波消解-碰撞反应池电感耦合等离子体质谱法同时测定蔬菜中铅、砷、镉、铬等21种元素的方法。方法选择超级微波消解法进行样品预处理,以硝酸为消解液,运用具有八极杆反应池系统的电感耦合等离子体质谱仪,以铂锥作为采样锥,使用He气碰撞模式(5 m L/min),通过动能歧视和碰撞诱导解离进行干扰的消除。此外,选择包括低、中、高质量范围的^(6)Li、^(45)Sc、^(72)Ge、^(103)Rh、^(115)In、^(159)Tb、^(175)Lu、^(209)Bi元素作为内标,使用在线添加内标的方式进行干扰消除,并在数据分析时采用虚拟内标校正模式。结果在优化后的实验条件下,21种元素在一定的质量浓度区间内,其对应的信号强度与质量浓度呈线性关系。标准曲线线性良好,相关系数在0.999~1.000之间。方法的检出限在0.005~1.200 mg/kg,定量限在0.015~3.600 mg/kg。方法通过加标回收测定回收率,加标回收率在85.2%~119.9%之间。对处理后的蔬菜样品加入低、中、高3种不同浓度的标准,每份平行测定7次,测定值的相对标准偏差在1.03%~4.60%之间。结论通过本研究方法对蔬菜样品中21种元素进行测定,满足国家标准对各项技术指标参数的要求。该方法检出限低,选择性好,结果准确可靠,为蔬菜样品中多种元素分析测定提供了新的参考方法。 展开更多
关键词 超级微波消解 电感耦合等离子质谱法 蔬菜 元素
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超级微波消解-电感耦合等离子体串联质谱法测定滨海白首乌制品中23种元素及其质量评价
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作者 陈小云 陈炳灿 +2 位作者 刘慧珍 陈国清 王坤 《理化检验(化学分册)》 北大核心 2025年第2期165-175,共11页
通过优化消解体系、消解温度、消解时间,采用题示方法测定滨海白首乌制品中Li、Be、V、Cr、Ni、As、Se、Cd、Sn、Sb、Tl、Co、Mo、Al、Mn、Cu、Ba、Zn、K、Ca、Mg、Fe、Na等23种元素的含量。取粉碎后的样品约0.3 g置于石英消解管中,加入... 通过优化消解体系、消解温度、消解时间,采用题示方法测定滨海白首乌制品中Li、Be、V、Cr、Ni、As、Se、Cd、Sn、Sb、Tl、Co、Mo、Al、Mn、Cu、Ba、Zn、K、Ca、Mg、Fe、Na等23种元素的含量。取粉碎后的样品约0.3 g置于石英消解管中,加入1 mL水和2 mL硝酸,混匀后加盖升温至200℃并消解10 min,冷却后,用水将消解液稀释至25 mL,采用电感耦合等离子体串联质谱法(ICP-MS/MS)在氦气碰撞模式下测定30份样品中23种元素的含量,并采用SPSS18.0软件对30份样品中均有检出的16种元素进行相关性分析和主成分分析。结果表明,23种元素的质量浓度均在一定范围内和对应的响应强度与内标响应强度之比呈线性关系,检出限(3s)为0.0003~0.900 mg·kg^(−1),利用内标法和气体稀释降低基质效应引起的信号漂移;按照标准加入法进行回收试验,回收率为81.2%~115%,测定值的相对标准偏差(n=6)为0.53%~5.0%。样品分析结果表明,滨海白首乌制品中不同元素的含量差异明显,K、Ca、Mg、Na等常量元素含量较高,Mn、Al、Fe、Zn、Ba、Cu含量次之,Li、Be、V、Cr、Ni、As、Se、Cd、Sn、Sb、Tl、Co、Mo含量较低或未检出。相关性分析结果表明,30份滨海白首乌制品中均含有的16种元素之间存在着协同或拮抗的作用。主成分分析结果表明,Ni、Co、Mo、Mn、Cu、Zn、K、Ca、Mg、V、Al、Cr为滨海白首乌制品中的特征元素。 展开更多
关键词 超级微波消解 电感耦合等离子体串联质谱法 元素 相关性分析 主成分分析
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ICP-MS/MS法测定儿童彩妆类化妆品中的7种元素
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作者 吴莉 庞庆林 +2 位作者 张妤琳 耿悦 陈民辉 《日用化学工业(中英文)》 北大核心 2025年第1期98-103,共6页
建立了电感耦合等离子体串联质谱法(ICP-MS/MS)测定儿童彩妆类化妆品中7种元素的含量测定方法。样品经硝酸-氢氟酸的消解酸体系破坏、超级微波消解法进行消解,采用ICP-MS/MS法同时测定儿童彩妆类化妆品中硼(B)、钛(Ti)、锗(Ge)、钼(Mo)... 建立了电感耦合等离子体串联质谱法(ICP-MS/MS)测定儿童彩妆类化妆品中7种元素的含量测定方法。样品经硝酸-氢氟酸的消解酸体系破坏、超级微波消解法进行消解,采用ICP-MS/MS法同时测定儿童彩妆类化妆品中硼(B)、钛(Ti)、锗(Ge)、钼(Mo)、锡(Sn)、锑(Sb)、碲(Te)7种元素的含量,选用铑(Rh)作为内标。分别以霜类、粉类、口红类为基质进行方法学考察,结果表明,所测元素在各自质量浓度范围内线性关系良好,相关系数均大于0.9967。在2个加标水平下,三种基质的平均回收率范围分别为81.1%~104.6%、84.0%~116.0%、80.8%~113.1%,RSD分别为2.2%~7.5%、0.5%~7.1%、0.8%~7.3%。该方法采用硝酸-氢氟酸体系、超级微波消解法进行样品前处理,应用ICPMS/MS技术对儿童彩妆类化妆品中元素进行含量测定,解决了不同类型样品尤其是组成复杂、基质干扰大的彩妆类样品在元素检测中的难题,为各类化妆品的样品前处理和元素分析提供了新思路,填补了现有法定标准中尚未建立的7种元素检测方法的空白。 展开更多
关键词 电感耦合等离子体串联质谱法(ICP-MS/MS) 超级微波消解 氢氟酸 儿童彩妆 元素分析
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