The effects of Y,Ce and La on the sulfidation of alloy Fe-25Cr-40Ni have been investigated. The sulfidation rate of the alloys with RE more than 0.1 wt-% is lower than that of the base alloy.The addition of Y is more ...The effects of Y,Ce and La on the sulfidation of alloy Fe-25Cr-40Ni have been investigated. The sulfidation rate of the alloys with RE more than 0.1 wt-% is lower than that of the base alloy.The addition of Y is more effective than La and Ce in lowering the sulfidation rate. Based on the analyses of the structure and composition of the sulfide seales,the sulfidation mechanism of the alloys with RE has been proposed.展开更多
The effect of Al on the morphology of MnS in medium-carbon non-quenched and tempered steel was investigated at three different cooling rates of 0.24, 0.43, and 200°C·s^-1. The formation mechanisms of three t...The effect of Al on the morphology of MnS in medium-carbon non-quenched and tempered steel was investigated at three different cooling rates of 0.24, 0.43, and 200°C·s^-1. The formation mechanisms of three types of MnS were elucidated based on phase diagram information combined with crystal growth models. The morphology of MnS is governed by the precipitation mode and the growth conditions. A monotectic reaction and subsequent fast solidification lead to globular Type I MnS. Type II MnS inclusions with different morphological characteristics form as a result of a eutectic reaction followed by the growth in the Fe matrix. Type III MnS presents a divorced eutectic morphology. At the cooling rate of 0.24°C·s^-1, the precipitation of dispersed Type III MnS is significantly enhanced by the addition of 0.044wt% acid-soluble Al（Als）, while Type II MnS clusters prefer to form in steels with either 0.034wt% or 0.052wt% Als. At the relatively higher cooling rates of 200°C·s^-1 and 0.43°C·s^-1, the formation of Type I and Type II MnS inclusions is promoted, and the influence of Al is negligible. The results of this work are expected to be employed in practice to improve the mechanical properties of non-quenched and tempered steels.展开更多
文摘The effects of Y,Ce and La on the sulfidation of alloy Fe-25Cr-40Ni have been investigated. The sulfidation rate of the alloys with RE more than 0.1 wt-% is lower than that of the base alloy.The addition of Y is more effective than La and Ce in lowering the sulfidation rate. Based on the analyses of the structure and composition of the sulfide seales,the sulfidation mechanism of the alloys with RE has been proposed.
基金financially supported by the National Natural Science Foundation of China (Nos. 51174020 and 51374018)the National High-Tech Research and Development Program of China (No. 2013AA031601)
文摘The effect of Al on the morphology of MnS in medium-carbon non-quenched and tempered steel was investigated at three different cooling rates of 0.24, 0.43, and 200°C·s^-1. The formation mechanisms of three types of MnS were elucidated based on phase diagram information combined with crystal growth models. The morphology of MnS is governed by the precipitation mode and the growth conditions. A monotectic reaction and subsequent fast solidification lead to globular Type I MnS. Type II MnS inclusions with different morphological characteristics form as a result of a eutectic reaction followed by the growth in the Fe matrix. Type III MnS presents a divorced eutectic morphology. At the cooling rate of 0.24°C·s^-1, the precipitation of dispersed Type III MnS is significantly enhanced by the addition of 0.044wt% acid-soluble Al（Als）, while Type II MnS clusters prefer to form in steels with either 0.034wt% or 0.052wt% Als. At the relatively higher cooling rates of 200°C·s^-1 and 0.43°C·s^-1, the formation of Type I and Type II MnS inclusions is promoted, and the influence of Al is negligible. The results of this work are expected to be employed in practice to improve the mechanical properties of non-quenched and tempered steels.
