To improve the overall magnetic properties of Sm(CoFeCuZr)_(z)sintered magnets,a dual-alloy sintering process that involves mixing high-iron,low-copper powders with low-iron,high-copper powders was systematically inve...To improve the overall magnetic properties of Sm(CoFeCuZr)_(z)sintered magnets,a dual-alloy sintering process that involves mixing high-iron,low-copper powders with low-iron,high-copper powders was systematically investigated.The results demonstrate that this method significantly improves the Cu-lean phenomenon at the grain boundaries,achieves multiscale uniform microstructures,greatly enhances the pinning field strength,and ultimately produces a high-performance dual-alloy magnet with a maximum energy product((BH)_(max))exceeding 240 kJ/m^(3)and an intrinsic coercivity(H_(cj))exceeding 2400 kA/m.In particular,when 35 wt.%of low-iron,high-copper alloy powder is incorporated,the dual-alloy magnet achieves a remanence of 1.13 T,H_(cj)of 2691.2 kA/m and(BH)_(max)of 248 kJ/m^(3).To evaluate the overall magnetic performance,the sum of H_(cj)(in kA/m)and(BH)_(max)(in kJ/m^(3))is used as a combined parameter,yielding a value of 2939.2.Compared with single-alloy magnets of the same composition,the dual-alloy sintering process yields magnets with a more uniform elemental distribution and superior magnetic properties.展开更多
基金supported by the National Key Research and Development Program for Young Scientists,China(No.2023YFB3508400)the National Natural Science Foundation of China(Nos.51871005,51931007)+1 种基金the Key Program of Science and Technology Development Project of Beijing Municipal Education Commission of China(No.KZ202010005009)the Program of Top Disciplines Construction in Beijing,China(No.PXM2019_014204_500031)。
文摘To improve the overall magnetic properties of Sm(CoFeCuZr)_(z)sintered magnets,a dual-alloy sintering process that involves mixing high-iron,low-copper powders with low-iron,high-copper powders was systematically investigated.The results demonstrate that this method significantly improves the Cu-lean phenomenon at the grain boundaries,achieves multiscale uniform microstructures,greatly enhances the pinning field strength,and ultimately produces a high-performance dual-alloy magnet with a maximum energy product((BH)_(max))exceeding 240 kJ/m^(3)and an intrinsic coercivity(H_(cj))exceeding 2400 kA/m.In particular,when 35 wt.%of low-iron,high-copper alloy powder is incorporated,the dual-alloy magnet achieves a remanence of 1.13 T,H_(cj)of 2691.2 kA/m and(BH)_(max)of 248 kJ/m^(3).To evaluate the overall magnetic performance,the sum of H_(cj)(in kA/m)and(BH)_(max)(in kJ/m^(3))is used as a combined parameter,yielding a value of 2939.2.Compared with single-alloy magnets of the same composition,the dual-alloy sintering process yields magnets with a more uniform elemental distribution and superior magnetic properties.