Achieving high-level integration of composite micro-nano structures with different structural characteristics through a minimalist and universal process has long been the goal pursued by advanced manufacturing researc...Achieving high-level integration of composite micro-nano structures with different structural characteristics through a minimalist and universal process has long been the goal pursued by advanced manufacturing research but is rarely explored due to the absence of instructive mechanisms.Here,we revealed a controllable ultrafast laser-induced focal volume light field and experimentally succeeded in highly efficient one-step composite structuring in multiple transparent solids.A pair of spatially coupled twin periodic structures reflecting light distribution in the focal volume are simultaneously created and independently tuned by engineering ultrafast laser-matter interaction.We demonstrated that the generated composite micro-nano structures are applicable to multi-dimensional information integration,nonlinear diffractive elements,and multi-functional optical modulation.This work presents the experimental verification of highly universal all-optical fabrication of composite micro-nano structures with independent controllability in multiple degrees of freedom,expands the current cognition of ultrafast laser-based material modification in transparent solids,and establishes a new scientific aspect of strong-field optics,namely,focal volume optics for composite structuring transparent solids.展开更多
The implementation of ultrahigh-Ni cathodes in high-energy lithium-ion batteries(LIBs)is constrained by significant structural and interfacial degradation during cycling.In this study,doping-induced surface restructur...The implementation of ultrahigh-Ni cathodes in high-energy lithium-ion batteries(LIBs)is constrained by significant structural and interfacial degradation during cycling.In this study,doping-induced surface restructuring in ultrahigh-nickel cathode materials is rapidly facilitated through an ultrafast Joule heating method.Density functional theory(DFT)calculations,synchrotron X-ray absorption spectroscopy(XAS),and single-particle force test confirmed the establishment of a stable crystal framework and lattice oxygen,which mitigated H2-H3 phase transitions and improved structural reversibility.Additionally,the Sc doping process exhibits a pinning effect on the grain boundaries,as shown by scanning transmission electron microscopy(STEM),enhancing Li~+diffusion kinetics and decreasing mechanical strain during cycling.The in situ development of a cation-mixing layer at grain boundaries also creates a robust cathode/electrolyte interphase,effectively reducing interfacial parasitic reactions and transition metal dissolution,as validated by STEM and time-of-flight secondary ion mass spectrometry(TOF-SIMS).These synergistic modifications reduce particle cracking and surface/interface degradation,leading to enhanced rate capability,structural integrity,and thermal stability.Consequently,the optimized Sc-modified ultrahigh-Ni cathode(Sc-1)exhibits 93.99%capacity retention after 100 cycles at 1 C(25℃)and87.06%capacity retention after 100 cycles at 1 C(50℃),indicating excellent cycling and thermal stability.By presenting a one-step multifunctional modification approach,this research delivers an extensive analysis of the mechanisms governing the structure,microstructure,and interface properties of nickel-rich layered cathode materials(NCMs).These results underscore the potential of ultrahigh-Ni cathodes as viable candidates for advanced lithium-ion batteries(LIBs)in next-generation electric vehicles(EVs).展开更多
Metal additive manufacturing(MAM)enables near-net shape production of components with minimized waste and excellent mechanical performance based on multi-scale microstructural heterogeneity.Espe-cially,the dislocation...Metal additive manufacturing(MAM)enables near-net shape production of components with minimized waste and excellent mechanical performance based on multi-scale microstructural heterogeneity.Espe-cially,the dislocation cell network that often bears elemental segregation or precipitation of a secondary phase contributes to enhancing the strength of additively manufactured materials.The cell boundaries can also act as active nucleation sites for the formation of precipitates under post-MAM heat treatment,as the chemical heterogeneity and profuse dislocations generate a driving force for precipitation.In this work,we subjected a Co_(18)Cr_(15)Fe_(50)Ni_(10)Mo_(6.5)C_(0.5)(at%)medium-entropy alloy fabricated by laser powder bed fusion(LPBF)to post-LPBF annealing at 900℃for 10 min.Microstructural investigation revealed that the cell boundaries of the as-built sample,which were decorated by Mo segregation,are replaced byμphase andM_(6)C typecarbide precipitatesduringannealingwhile thegrainstructureand sizeremain unaffected,indicating that the post-LPBF annealing delivered the proper amount of heat input to alter only the cell structure.The yield strength slightly decreased with annealing due to a reduction in the strengthening effect by the cell boundaries despite an increased precipitation strengthening effect.How-ever,the post-LPBF annealing improved the strain hardenability and the ultimate tensile strength was enhanced from∼1.02 to∼1.15 GPa owing to reinforced back stress hardening by the increased disloca-tion pile-up at the precipitates.Our results suggest that the cell structure with chemical heterogeneity can be successfully controlled by careful post-MAM heat treatment to tailor the mechanical performance,while also providing insight into alloy design for additive manufacturing.展开更多
Advancing aqueous zinc-ion batteries(AZIBs)are significantly challenged by the need to find cathode materials that can provide both high capacity and fast reaction kinetics.Tellurium telluride,a topological insulator,...Advancing aqueous zinc-ion batteries(AZIBs)are significantly challenged by the need to find cathode materials that can provide both high capacity and fast reaction kinetics.Tellurium telluride,a topological insulator,has emerged as a promising cathode candidate for AZIBs,garnering increasing attention.However,the complete understanding of its electrochemical reaction mechanism and its unsatisfactory energy storage performance are major obstacles to the practical use.In this work,we synthesize a bimetallic bismuth-nickel telluride with Te vacancies,defined as Bi_(2)Te_(3-x)/NiTe_(2),which forms a topological insulator/topological Dirac semimetal heterostructure through a hydrothermal approach.The electrochemical reaction mechanism of Bi_(2)Te_(3-x)/NiTe_(2),along with its phase and structural changes are elucidated by using in-situ X-ray diffraction,various electrochemical techniques,and ex-situ characterizations.The influences of Bi_(2)Te_(3-x)/NiTe_(2)on the electronic structure,interracial electron transfer,migration barrier,and ion adsorption energy are investigated by using density functional theory calculations.Our findings reveal that Bi_(2)Te_(3-x)/NiTe_(2)exhibits excellent specific capacity,stable cycling,and superior rate capability as a cathode material for AZIBs.Moreover,further studies demonstrate that Bi_(2)Te_(3-x)/NiTe_(2)maintains exceptional performance at low temperatures of-15 and-5℃,and also retains stability and flexibility when integrated into flexible battery packs.展开更多
There are problems such as incomplete edges and poor noise suppression when a single fixed morphological structuring element is used to detect the edges in remote sensing images. For this reason, a morphological edge ...There are problems such as incomplete edges and poor noise suppression when a single fixed morphological structuring element is used to detect the edges in remote sensing images. For this reason, a morphological edge detection method for remote sensing image based on variable structuring element is proposed. Firstly, the structuring elements with different scales and multiple directions are constructed according to the diversity of remote sensing imagery targets. In order to suppress the noise of the target background and highlight the edge of the image target in the remote sensing image by adaptive Top hat and Bottom hat transform, the corresponding adaptive morphological operations are constructed based on variable structuring elements; Secondly, adaptive morphological edge detection is used to obtain multiple images with different scales and directional edge features; Finally, the image edges are obtained by weighted summation of each direction edge, and then the least square is used to fit the edges for accurate location of the edge contour of the target. The experimental results show that the proposed method not only can detect the complete edge of remote sensing image, but also has high edge detection accuracy and superior anti-noise performance. Compared with classical edge detection and the morphological edge detection with a fixed single structuring element, the proposed method performs better in edge detection effect, and the accuracy of detection can reach 95 %展开更多
In this study,we demonstrate a technique termed underwater persistent bubble assisted femtosecond laser ablation in liquids(UPB-fs-LAL)that can greatly expand the boundaries of surface micro/nanostructuring through la...In this study,we demonstrate a technique termed underwater persistent bubble assisted femtosecond laser ablation in liquids(UPB-fs-LAL)that can greatly expand the boundaries of surface micro/nanostructuring through laser ablation because of its capability to create concentric circular macrostructures with millimeter-scale tails on silicon substrates.Long-tailed macrostructures are composed of layered fan-shaped(central angles of 45°–141°)hierarchical micro/nanostructures,which are produced by fan-shaped beams refracted at the mobile bubble interface(.50°light tilt,referred to as the vertical incident direction)during UPB-fs-LAL line-by-line scanning.Marangoni flow generated during UPB-fs-LAL induces bubble movements.Fast scanning(e.g.1mms−1)allows a long bubble movement(as long as 2mm),while slow scanning(e.g.0.1mms−1)prevents bubble movements.When persistent bubbles grow considerably(e.g.hundreds of microns in diameter)due to incubation effects,they become sticky and can cause both gas-phase and liquidphase laser ablation in the central and peripheral regions of the persistent bubbles.This generates low/high/ultrahigh spatial frequency laser-induced periodic surface structures(LSFLs/HSFLs/UHSFLs)with periods of 550–900,100–200,40–100 nm,which produce complex hierarchical surface structures.A period of 40 nm,less than 1/25th of the laser wavelength(1030 nm),is the finest laser-induced periodic surface structures(LIPSS)ever created on silicon.The NIR-MIR reflectance/transmittance of fan-shaped hierarchical structures obtained by UPB-fs-LAL at a small line interval(5μm versus 10μm)is extremely low,due to both their extremely high light trapping capacity and absorbance characteristics,which are results of the structures’additional layers and much finer HSFLs.In the absence of persistent bubbles,only grooves covered with HSFLs with periods larger than 100 nm are produced,illustrating the unique attenuation abilities of laser properties(e.g.repetition rate,energy,incident angle,etc)by persistent bubbles with different curvatures.This research represents a straightforward and cost-effective approach to diversifying the achievable hierarchical micro/nanostructures for a multitude of applications.展开更多
Laser-structuring is an effective method to promote ion diffusion and improve the performance of lithium-ion battery(LIB)electrodes.In this work,the effects of laser structuring parameters(groove pitch and depth)on th...Laser-structuring is an effective method to promote ion diffusion and improve the performance of lithium-ion battery(LIB)electrodes.In this work,the effects of laser structuring parameters(groove pitch and depth)on the fundamental characteristics of LIB electrode,such as interfacial area,internal resistances,material loss and electrochemical performance,are investigated,LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathodes were structured by a femtosecond laser by varying groove depth and pitch,which resulted in a material loss of 5%-14%and an increase of 140%-260%in the in terfacial area between electrode surface and electrolyte.It is shown that the importance of groove depth and pitch on the electrochemical performance(specific capacity and areal discharge capacity)of laser-structured electrode varies with current rates.Groove pitch is more im porta nt at low current rate but groove depth is at high curre nt rate.From the mapping of lithium concentration within the electrodes of varying groove depth and pitch by laser-induced breakdown spectroscopy,it is verified that the groove functions as a diffusion path for lithium ions.The ionic,electronic,and charge transfer resistances measured with symmetric and half cells showed that these internal resistances are differently affected by laser structuring parameters and the changes in porosity,ionic diffusion and electronic pathways.It is demonstrated that the laser structuring parameters for maximum electrode performance and minimum capacity loss should be determined in consideration of the main operating conditions of LIBs.展开更多
The use of visible and infrared remote sensing images to calculate the water area is an effective means to grasp the basic situation of water resources,and water segmentation is the premise of statistics.Generally,the...The use of visible and infrared remote sensing images to calculate the water area is an effective means to grasp the basic situation of water resources,and water segmentation is the premise of statistics.Generally,the edge features of the water in the remote sensing images are complex.When the traditional morphology is used for image segmentation,it is easy to change the image edge and affect the accuracy of image segmentation because the fixed structuring elements are used to perform morphological operations on the image.To segment water in the remote sensing image accurately,a remote sensing image water segmentation method based on adaptive morphological elliptical structuring elements is proposed.Firstly,the eigenvalue and eigenvector of the image are estimated by linear structure tensor,and the elliptical structuring elements are constructed by the eigenvalue and eigenvector.Then adaptive morphological operations are defined,combining the close operation to eliminate the influence of dark detail noise on water without overstretching the water edge,so that the water edge can be maintained more accurately.Finally,on this basis,the water area can be segmented by gray slice.The experimental results show that the proposed method has higher segmentation accuracy and the average segmentation error is less than 1.43%.展开更多
Corporate restructuring was identified as a new industrial force that has great impact on economic values and that therefore has become central in daily financial decision making. This article investigates the optimal...Corporate restructuring was identified as a new industrial force that has great impact on economic values and that therefore has become central in daily financial decision making. This article investigates the optimal restructuring strategies under different dynamic factors and their numerous impacts on firm value. The concept of quasi-leverage is introduced and valuation models are built for corporate debt and equity under imperfect market conditions. The model’s input variables include the quasi-leverage and other firm-specific parameters, the output variables include multiple corporate security values. The restruc- turing cost is formulated in the form of exponential function, which allows us to observe the sensitivity of the variation in security values. The unified model and its analytical solution developed in this research allow us to examine the continuous changes of security values by dynamically changing the coupon rates, riskless interest rate, bankruptcy cost, quasi-leverage, personal tax rate, corporate taxes rate, transaction cost, firm risk, etc., so that the solutions provide useful guidance for financing and restructuring decisions.展开更多
Scott proposes to use the term global city-regions to designate the phenomena that bear some resemblance to the "world cities" firstly identified by Hall and Friedmann and Wolff, and to the "global citi...Scott proposes to use the term global city-regions to designate the phenomena that bear some resemblance to the "world cities" firstly identified by Hall and Friedmann and Wolff, and to the "global cities" of Sassen but whose essential social logic and contextual characteristics have evolved considerably since these pioneering studies were published. In simple geographical terms, a global city-region can be refered to comprise any major metropolitan area or any contiguous set of metropolitan areas together with a surrounding hinterland of variable extent-itself a locus of scattered urban settlements-whose internal economic and political affairs are bound up in intricate ways in intensifying and far-flung extra-national relationships. Scott refers to these extra-national relationships as a symptom of "globalization". As economic motors and political actors, the global city regions have been regarded as crucial parts of development strategies in China. In the "Eleventh Five-year Plan" issued by the National Development and Reform Commission of P. R. China, the Beijing-Tianjin-Hebei Province (Jing-Jin-Ji) region, one of the typical megalopolises or global city regions in the East Coastal China is paid more attention. This paper first analyzes the regional structure of the Jing-Jin-Ji region based on data of the fifth national population census of China. And then through the changes of the population growth, the dynamic process and mechanisms of the regional restructuring in the Jing-Jin-Ji is explored and discussed.展开更多
Classical mathematical morphology operations use a fixed size and shape structuring element to process the whole image.Due to the diversity of image content and the complexity of target structure,for processed image,i...Classical mathematical morphology operations use a fixed size and shape structuring element to process the whole image.Due to the diversity of image content and the complexity of target structure,for processed image,its shape may be changed and part of the information may be lost.Therefore,we propose a method for constructing salience adaptive morphological structuring elements based on minimum spanning tree(MST).First,the gradient image of the input image is calculated,the edge image is obtained by non-maximum suppression(NMS)of the gradient image,and then chamfer distance transformation is performed on the edge image to obtain a salience map(SM).Second,the radius of structuring element is determined by calculating the maximum and minimum values of SM and then the minimum spanning tree is calculated on the SM.Finally,the radius is used to construct a structuring element whose shape and size adaptively change with the local features of the input image.In addition,the basic morphological operators such as erosion,dilation,opening and closing are redefined using the adaptive structuring elements and then compared with the classical morphological operators.The simulation results show that the proposed method can make full use of the local features of the image and has better processing results in image structure preservation and image filtering.展开更多
The paper deals with the dynamic response prediction of the composite structure,which consists of two linear components coupled by some nonlinear vibration isolators. Based on the measured impulse response functions o...The paper deals with the dynamic response prediction of the composite structure,which consists of two linear components coupled by some nonlinear vibration isolators. Based on the measured impulse response functions of the linear components, three kinds of dynamic equations of interfacial integration are proposed and a procedure to transform the dynamic equations of integral type into a set of ordinary differential equations is suggested. Computer simulations and a real test are given to verify the effectiveness of the theoretical results.展开更多
The results of observation of different structuring techniques of thin metal layers applied in micro system technologies are presented. The Ti V getter films formed by magnetron sputtering have been explored using sca...The results of observation of different structuring techniques of thin metal layers applied in micro system technologies are presented. The Ti V getter films formed by magnetron sputtering have been explored using scanning electron and atomic-force microscopy, Brunauer-Emmett-Teller method, thermogravimetric analysis and fractal geometry. The film sorption capacity for hydrogen given by thermogravimetry was of 7.7 m3·Pa·g-1. To estimate the effective surface area, the fractal geometry tools were used and the calculated value of the specific surface area was about 155 m2/m3. The second object under investigation was a structure composed of micro- and mesoporous silicon and copper layer deposited electrochemically on the pore walls. Porous silicon when coupled with a reactive metal or alloy is expected to be an effective getter for micro system techniques. The use of porous silicon and specific conditions of depositions allows to form the structure of complex fractal type with a specific surface area of 167 m2/cm3.展开更多
With the wide use of color in many areas, the interest on the color perception and processing has been growing rapidly. An important topic in color image processing is the development of efficient tools capable of fil...With the wide use of color in many areas, the interest on the color perception and processing has been growing rapidly. An important topic in color image processing is the development of efficient tools capable of filtering images without blurring them and without changing their original chromatic contents. In this paper, a new technique reducing noise of color image is developed. A class of color-scale morphological operations is introduced, which extend mathematical morphology to color image processing, representing a color image as a vector function. The correlation between color components is utilized to perform noise removal. Color-scale morphological niters with multiple structuring elements (CSMF-MSEs) are proposed. Their properties are discussed and proved. Experimental results show that CSMF-MSEs are suitable and powerful to eliminate noise and preserve edges in color image because of efficient utilization of inherent correlation between color components, and they perform better than vector展开更多
With the increasing number of digital devices generating a vast amount of video data,the recognition of abnormal image patterns has become more important.Accordingly,it is necessary to develop a method that achieves t...With the increasing number of digital devices generating a vast amount of video data,the recognition of abnormal image patterns has become more important.Accordingly,it is necessary to develop a method that achieves this task using object and behavior information within video data.Existing methods for detecting abnormal behaviors only focus on simple motions,therefore they cannot determine the overall behavior occurring throughout a video.In this study,an abnormal behavior detection method that uses deep learning(DL)-based video-data structuring is proposed.Objects and motions are first extracted from continuous images by combining existing DL-based image analysis models.The weight of the continuous data pattern is then analyzed through data structuring to classify the overall video.The performance of the proposed method was evaluated using varying parameter settings,such as the size of the action clip and interval between action clips.The model achieved an accuracy of 0.9817,indicating excellent performance.Therefore,we conclude that the proposed data structuring method is useful in detecting and classifying abnormal behaviors.展开更多
A new concept of digital vector-layer structuring of landscape space at the local level (on a scale of 1:25,000) is considered on the example of Russian island and adjacent island systems of the Vladivostok urban dist...A new concept of digital vector-layer structuring of landscape space at the local level (on a scale of 1:25,000) is considered on the example of Russian island and adjacent island systems of the Vladivostok urban district. Synthesis, analysis and evaluation of the internal and external content of landscape systems are carried out and altitude complexes of tracts are identified, in each of which altitudes are distinguished. It is noted that one of the main criteria for identifying high-altitude complexes and levels is the high-altitude criterion and the quantitative and qualitative changes in their internal content, taking into account the state of erosion-denudation lowland and mountain landscape systems formed under the influence of the Earth’s real material-energy flows and first of all gravitational energy. According to these criteria, landscape areas are classified and vertex, saddle, upper slope, middle slope and other altitude complexes of tracts are distinguished in each of which altitude levels are distinguished. Structuring and classification proposed to the reader are presented for further study of structures as objects of industry-specific indication and possibilities of using high-landscape complexes as development areas. Noted, as well as the fact that the study was conducted for the first time and is aimed at the practical implementation of the landscape approach in the development of landscape systems, defines the relevance of the work performed.展开更多
For the first time, a new concept of digital structuring of landscape space of mountainous territories is considered. It is proposed to carry out structuring and classification of landscape systems, with the distribut...For the first time, a new concept of digital structuring of landscape space of mountainous territories is considered. It is proposed to carry out structuring and classification of landscape systems, with the distribution of high-altitude landscape complexes. When finding the boundaries of these complexes, the high-altitude selection criterion prevailed, as well as quantitative and qualitative changes in their internal content. According to these criteria, it is possible to distinguish between plain, low-slope, low-mountain, dissected-middle-mountain, massive-medium-mountain, altitude-landscape complexes. Structuring and classification are presented for further study of structures as objects of industry indications and possibilities of using high-growing complexes as development areas.展开更多
Astrocytes, the dominant glial cell type, modulate synaptic information transmission. Each astrocyte is organized in non-overlapping domains. Here, a formally based model of the possible significance of astrocyte doma...Astrocytes, the dominant glial cell type, modulate synaptic information transmission. Each astrocyte is organized in non-overlapping domains. Here, a formally based model of the possible significance of astrocyte domain organization is proposed. It is hypothesized that each astrocyte contacting n neurons with m synapses via its processes generates dynamic domains of synaptic interactions based on qualitative criteria so that it exerts a structuring of neuronal information processing. The formalism (morpho-grammatics) describes the combinatorics of the various astrocytic receptor types for occupancy with cognate neurotransmitters. Astrocytic processes are able both to contact synapses and retract from them. Rhythmic oscillations of the astrocyte may program the domain organization, where clock genes may play a role in rhythm generation. For the interpretation of a domain organization a player of a string instrument is used as a paradigm. Since astrocytes form networks (syncytia), the interactions between astrocyte domains may be comparable to the improvisations in a jazz ensemble. Given the fact of a high combinational complexity of an astrocyte domain organization, which is formally demonstrable, and an uncomputable complexity of a network of astrocyte domains, the model proposed may not be testable in biological brains, but robotics could be a real alternative.展开更多
Northern foot of the Qinling Mountains(Xi'an Section) is a transitional section between the Qinling Mountains and Xi'an City, so it has great ecological signifi cance. On the basis of sorting out landscape cit...Northern foot of the Qinling Mountains(Xi'an Section) is a transitional section between the Qinling Mountains and Xi'an City, so it has great ecological signifi cance. On the basis of sorting out landscape city, space structuring of the northern foot of the Qinling Mountains was studied within the theoretical framework of landscape city, it was disclosed that northern foot of the Qinling Mountains was a signifi cant ecological screen for the landscape city spatial pattern of Xi'an, and an important carrier for its "mountain, water and city" cultures. Then, fi ve infl uence factors for the space structuring of the study area were given, and basic contents of the space structuring analyzed from fi ve perspectives of spatial structure, spatial form, ecological environment, integration of regional spaces, historical and cultural context, so as to explore ecological conservation and moderate utilization of the northern foot of the Qinling Mountains from the perspective of space structuring.展开更多
基金financially supported by the National Key Research and Development Program of China(No.2021YFB2802001)the National Natural Science Foundation of China(Grant Nos.12304349,U20A20211,62275233)the Postdoctoral Fellowship Program of CPSF(GZB20230628,GZC20241465)。
文摘Achieving high-level integration of composite micro-nano structures with different structural characteristics through a minimalist and universal process has long been the goal pursued by advanced manufacturing research but is rarely explored due to the absence of instructive mechanisms.Here,we revealed a controllable ultrafast laser-induced focal volume light field and experimentally succeeded in highly efficient one-step composite structuring in multiple transparent solids.A pair of spatially coupled twin periodic structures reflecting light distribution in the focal volume are simultaneously created and independently tuned by engineering ultrafast laser-matter interaction.We demonstrated that the generated composite micro-nano structures are applicable to multi-dimensional information integration,nonlinear diffractive elements,and multi-functional optical modulation.This work presents the experimental verification of highly universal all-optical fabrication of composite micro-nano structures with independent controllability in multiple degrees of freedom,expands the current cognition of ultrafast laser-based material modification in transparent solids,and establishes a new scientific aspect of strong-field optics,namely,focal volume optics for composite structuring transparent solids.
基金supported by the National Key R&D Program of China(2022YFB3803501)the National Natural Science Foundation of China(22179008,22209156)+5 种基金support from the Beijing Nova Program(20230484241)support from the China Postdoctoral Science Foundation(2024M754084)the Postdoctoral Fellowship Program of CPSF(GZB20230931)support from beamline BL08U1A of Shanghai Synchrotron Radiation Facility(2024-SSRF-PT-506950)beamline 1W1B of the Beijing Synchrotron Radiation Facility(2021-BEPC-PT-006276)support from Initial Energy Science&Technology Co.,Ltd(IEST)。
文摘The implementation of ultrahigh-Ni cathodes in high-energy lithium-ion batteries(LIBs)is constrained by significant structural and interfacial degradation during cycling.In this study,doping-induced surface restructuring in ultrahigh-nickel cathode materials is rapidly facilitated through an ultrafast Joule heating method.Density functional theory(DFT)calculations,synchrotron X-ray absorption spectroscopy(XAS),and single-particle force test confirmed the establishment of a stable crystal framework and lattice oxygen,which mitigated H2-H3 phase transitions and improved structural reversibility.Additionally,the Sc doping process exhibits a pinning effect on the grain boundaries,as shown by scanning transmission electron microscopy(STEM),enhancing Li~+diffusion kinetics and decreasing mechanical strain during cycling.The in situ development of a cation-mixing layer at grain boundaries also creates a robust cathode/electrolyte interphase,effectively reducing interfacial parasitic reactions and transition metal dissolution,as validated by STEM and time-of-flight secondary ion mass spectrometry(TOF-SIMS).These synergistic modifications reduce particle cracking and surface/interface degradation,leading to enhanced rate capability,structural integrity,and thermal stability.Consequently,the optimized Sc-modified ultrahigh-Ni cathode(Sc-1)exhibits 93.99%capacity retention after 100 cycles at 1 C(25℃)and87.06%capacity retention after 100 cycles at 1 C(50℃),indicating excellent cycling and thermal stability.By presenting a one-step multifunctional modification approach,this research delivers an extensive analysis of the mechanisms governing the structure,microstructure,and interface properties of nickel-rich layered cathode materials(NCMs).These results underscore the potential of ultrahigh-Ni cathodes as viable candidates for advanced lithium-ion batteries(LIBs)in next-generation electric vehicles(EVs).
基金supported by the National Research Founda-tion of Korea(NRF)grant funded by the Korean government(MSIT)(Nos.2021R1A2C3006662 and RS-2023-00281246)supported by the Principal R&D project(contract no.PNK9950)of the Korean Institute of Materials Science(KIMS).
文摘Metal additive manufacturing(MAM)enables near-net shape production of components with minimized waste and excellent mechanical performance based on multi-scale microstructural heterogeneity.Espe-cially,the dislocation cell network that often bears elemental segregation or precipitation of a secondary phase contributes to enhancing the strength of additively manufactured materials.The cell boundaries can also act as active nucleation sites for the formation of precipitates under post-MAM heat treatment,as the chemical heterogeneity and profuse dislocations generate a driving force for precipitation.In this work,we subjected a Co_(18)Cr_(15)Fe_(50)Ni_(10)Mo_(6.5)C_(0.5)(at%)medium-entropy alloy fabricated by laser powder bed fusion(LPBF)to post-LPBF annealing at 900℃for 10 min.Microstructural investigation revealed that the cell boundaries of the as-built sample,which were decorated by Mo segregation,are replaced byμphase andM_(6)C typecarbide precipitatesduringannealingwhile thegrainstructureand sizeremain unaffected,indicating that the post-LPBF annealing delivered the proper amount of heat input to alter only the cell structure.The yield strength slightly decreased with annealing due to a reduction in the strengthening effect by the cell boundaries despite an increased precipitation strengthening effect.How-ever,the post-LPBF annealing improved the strain hardenability and the ultimate tensile strength was enhanced from∼1.02 to∼1.15 GPa owing to reinforced back stress hardening by the increased disloca-tion pile-up at the precipitates.Our results suggest that the cell structure with chemical heterogeneity can be successfully controlled by careful post-MAM heat treatment to tailor the mechanical performance,while also providing insight into alloy design for additive manufacturing.
基金supported by the National Natural Science Foundation of China(No.52372223)the Science Foundation of Shaanxi Province(No.2023-JC-ZD-03 and 2022GD-TSLD-15)Shaanxi Fundamental Science Research Project for Mathematics and Physics(No.23JSQ005)。
文摘Advancing aqueous zinc-ion batteries(AZIBs)are significantly challenged by the need to find cathode materials that can provide both high capacity and fast reaction kinetics.Tellurium telluride,a topological insulator,has emerged as a promising cathode candidate for AZIBs,garnering increasing attention.However,the complete understanding of its electrochemical reaction mechanism and its unsatisfactory energy storage performance are major obstacles to the practical use.In this work,we synthesize a bimetallic bismuth-nickel telluride with Te vacancies,defined as Bi_(2)Te_(3-x)/NiTe_(2),which forms a topological insulator/topological Dirac semimetal heterostructure through a hydrothermal approach.The electrochemical reaction mechanism of Bi_(2)Te_(3-x)/NiTe_(2),along with its phase and structural changes are elucidated by using in-situ X-ray diffraction,various electrochemical techniques,and ex-situ characterizations.The influences of Bi_(2)Te_(3-x)/NiTe_(2)on the electronic structure,interracial electron transfer,migration barrier,and ion adsorption energy are investigated by using density functional theory calculations.Our findings reveal that Bi_(2)Te_(3-x)/NiTe_(2)exhibits excellent specific capacity,stable cycling,and superior rate capability as a cathode material for AZIBs.Moreover,further studies demonstrate that Bi_(2)Te_(3-x)/NiTe_(2)maintains exceptional performance at low temperatures of-15 and-5℃,and also retains stability and flexibility when integrated into flexible battery packs.
基金National Natural Science Foundation of China(No.61761027)Postgraduate Education Reform Project of Lanzhou Jiaotong University(No.1600120101)
文摘There are problems such as incomplete edges and poor noise suppression when a single fixed morphological structuring element is used to detect the edges in remote sensing images. For this reason, a morphological edge detection method for remote sensing image based on variable structuring element is proposed. Firstly, the structuring elements with different scales and multiple directions are constructed according to the diversity of remote sensing imagery targets. In order to suppress the noise of the target background and highlight the edge of the image target in the remote sensing image by adaptive Top hat and Bottom hat transform, the corresponding adaptive morphological operations are constructed based on variable structuring elements; Secondly, adaptive morphological edge detection is used to obtain multiple images with different scales and directional edge features; Finally, the image edges are obtained by weighted summation of each direction edge, and then the least square is used to fit the edges for accurate location of the edge contour of the target. The experimental results show that the proposed method not only can detect the complete edge of remote sensing image, but also has high edge detection accuracy and superior anti-noise performance. Compared with classical edge detection and the morphological edge detection with a fixed single structuring element, the proposed method performs better in edge detection effect, and the accuracy of detection can reach 95 %
文摘In this study,we demonstrate a technique termed underwater persistent bubble assisted femtosecond laser ablation in liquids(UPB-fs-LAL)that can greatly expand the boundaries of surface micro/nanostructuring through laser ablation because of its capability to create concentric circular macrostructures with millimeter-scale tails on silicon substrates.Long-tailed macrostructures are composed of layered fan-shaped(central angles of 45°–141°)hierarchical micro/nanostructures,which are produced by fan-shaped beams refracted at the mobile bubble interface(.50°light tilt,referred to as the vertical incident direction)during UPB-fs-LAL line-by-line scanning.Marangoni flow generated during UPB-fs-LAL induces bubble movements.Fast scanning(e.g.1mms−1)allows a long bubble movement(as long as 2mm),while slow scanning(e.g.0.1mms−1)prevents bubble movements.When persistent bubbles grow considerably(e.g.hundreds of microns in diameter)due to incubation effects,they become sticky and can cause both gas-phase and liquidphase laser ablation in the central and peripheral regions of the persistent bubbles.This generates low/high/ultrahigh spatial frequency laser-induced periodic surface structures(LSFLs/HSFLs/UHSFLs)with periods of 550–900,100–200,40–100 nm,which produce complex hierarchical surface structures.A period of 40 nm,less than 1/25th of the laser wavelength(1030 nm),is the finest laser-induced periodic surface structures(LIPSS)ever created on silicon.The NIR-MIR reflectance/transmittance of fan-shaped hierarchical structures obtained by UPB-fs-LAL at a small line interval(5μm versus 10μm)is extremely low,due to both their extremely high light trapping capacity and absorbance characteristics,which are results of the structures’additional layers and much finer HSFLs.In the absence of persistent bubbles,only grooves covered with HSFLs with periods larger than 100 nm are produced,illustrating the unique attenuation abilities of laser properties(e.g.repetition rate,energy,incident angle,etc)by persistent bubbles with different curvatures.This research represents a straightforward and cost-effective approach to diversifying the achievable hierarchical micro/nanostructures for a multitude of applications.
基金supported by a GIST Research Institute(GRI)grant funded by the GIST in 2021supported by the Korea In stitute for Advancement of Tech no logy(KIAT)grant funded by the Korea Government(MOTIE).(P0008763,The Competency Development Program for Industry Specialist.)。
文摘Laser-structuring is an effective method to promote ion diffusion and improve the performance of lithium-ion battery(LIB)electrodes.In this work,the effects of laser structuring parameters(groove pitch and depth)on the fundamental characteristics of LIB electrode,such as interfacial area,internal resistances,material loss and electrochemical performance,are investigated,LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathodes were structured by a femtosecond laser by varying groove depth and pitch,which resulted in a material loss of 5%-14%and an increase of 140%-260%in the in terfacial area between electrode surface and electrolyte.It is shown that the importance of groove depth and pitch on the electrochemical performance(specific capacity and areal discharge capacity)of laser-structured electrode varies with current rates.Groove pitch is more im porta nt at low current rate but groove depth is at high curre nt rate.From the mapping of lithium concentration within the electrodes of varying groove depth and pitch by laser-induced breakdown spectroscopy,it is verified that the groove functions as a diffusion path for lithium ions.The ionic,electronic,and charge transfer resistances measured with symmetric and half cells showed that these internal resistances are differently affected by laser structuring parameters and the changes in porosity,ionic diffusion and electronic pathways.It is demonstrated that the laser structuring parameters for maximum electrode performance and minimum capacity loss should be determined in consideration of the main operating conditions of LIBs.
基金National Natural Science Foundation of China(No.61761027)Graduate Education Reform Project of Lanzhou Jiaotong University(No.1600120101)。
文摘The use of visible and infrared remote sensing images to calculate the water area is an effective means to grasp the basic situation of water resources,and water segmentation is the premise of statistics.Generally,the edge features of the water in the remote sensing images are complex.When the traditional morphology is used for image segmentation,it is easy to change the image edge and affect the accuracy of image segmentation because the fixed structuring elements are used to perform morphological operations on the image.To segment water in the remote sensing image accurately,a remote sensing image water segmentation method based on adaptive morphological elliptical structuring elements is proposed.Firstly,the eigenvalue and eigenvector of the image are estimated by linear structure tensor,and the elliptical structuring elements are constructed by the eigenvalue and eigenvector.Then adaptive morphological operations are defined,combining the close operation to eliminate the influence of dark detail noise on water without overstretching the water edge,so that the water edge can be maintained more accurately.Finally,on this basis,the water area can be segmented by gray slice.The experimental results show that the proposed method has higher segmentation accuracy and the average segmentation error is less than 1.43%.
文摘Corporate restructuring was identified as a new industrial force that has great impact on economic values and that therefore has become central in daily financial decision making. This article investigates the optimal restructuring strategies under different dynamic factors and their numerous impacts on firm value. The concept of quasi-leverage is introduced and valuation models are built for corporate debt and equity under imperfect market conditions. The model’s input variables include the quasi-leverage and other firm-specific parameters, the output variables include multiple corporate security values. The restruc- turing cost is formulated in the form of exponential function, which allows us to observe the sensitivity of the variation in security values. The unified model and its analytical solution developed in this research allow us to examine the continuous changes of security values by dynamically changing the coupon rates, riskless interest rate, bankruptcy cost, quasi-leverage, personal tax rate, corporate taxes rate, transaction cost, firm risk, etc., so that the solutions provide useful guidance for financing and restructuring decisions.
基金Under the auspices of the National Natural Science Foundation of China (No. 40435013)
文摘Scott proposes to use the term global city-regions to designate the phenomena that bear some resemblance to the "world cities" firstly identified by Hall and Friedmann and Wolff, and to the "global cities" of Sassen but whose essential social logic and contextual characteristics have evolved considerably since these pioneering studies were published. In simple geographical terms, a global city-region can be refered to comprise any major metropolitan area or any contiguous set of metropolitan areas together with a surrounding hinterland of variable extent-itself a locus of scattered urban settlements-whose internal economic and political affairs are bound up in intricate ways in intensifying and far-flung extra-national relationships. Scott refers to these extra-national relationships as a symptom of "globalization". As economic motors and political actors, the global city regions have been regarded as crucial parts of development strategies in China. In the "Eleventh Five-year Plan" issued by the National Development and Reform Commission of P. R. China, the Beijing-Tianjin-Hebei Province (Jing-Jin-Ji) region, one of the typical megalopolises or global city regions in the East Coastal China is paid more attention. This paper first analyzes the regional structure of the Jing-Jin-Ji region based on data of the fifth national population census of China. And then through the changes of the population growth, the dynamic process and mechanisms of the regional restructuring in the Jing-Jin-Ji is explored and discussed.
基金National Natural Science Foundation of China(No.61761027)。
文摘Classical mathematical morphology operations use a fixed size and shape structuring element to process the whole image.Due to the diversity of image content and the complexity of target structure,for processed image,its shape may be changed and part of the information may be lost.Therefore,we propose a method for constructing salience adaptive morphological structuring elements based on minimum spanning tree(MST).First,the gradient image of the input image is calculated,the edge image is obtained by non-maximum suppression(NMS)of the gradient image,and then chamfer distance transformation is performed on the edge image to obtain a salience map(SM).Second,the radius of structuring element is determined by calculating the maximum and minimum values of SM and then the minimum spanning tree is calculated on the SM.Finally,the radius is used to construct a structuring element whose shape and size adaptively change with the local features of the input image.In addition,the basic morphological operators such as erosion,dilation,opening and closing are redefined using the adaptive structuring elements and then compared with the classical morphological operators.The simulation results show that the proposed method can make full use of the local features of the image and has better processing results in image structure preservation and image filtering.
文摘The paper deals with the dynamic response prediction of the composite structure,which consists of two linear components coupled by some nonlinear vibration isolators. Based on the measured impulse response functions of the linear components, three kinds of dynamic equations of interfacial integration are proposed and a procedure to transform the dynamic equations of integral type into a set of ordinary differential equations is suggested. Computer simulations and a real test are given to verify the effectiveness of the theoretical results.
文摘The results of observation of different structuring techniques of thin metal layers applied in micro system technologies are presented. The Ti V getter films formed by magnetron sputtering have been explored using scanning electron and atomic-force microscopy, Brunauer-Emmett-Teller method, thermogravimetric analysis and fractal geometry. The film sorption capacity for hydrogen given by thermogravimetry was of 7.7 m3·Pa·g-1. To estimate the effective surface area, the fractal geometry tools were used and the calculated value of the specific surface area was about 155 m2/m3. The second object under investigation was a structure composed of micro- and mesoporous silicon and copper layer deposited electrochemically on the pore walls. Porous silicon when coupled with a reactive metal or alloy is expected to be an effective getter for micro system techniques. The use of porous silicon and specific conditions of depositions allows to form the structure of complex fractal type with a specific surface area of 167 m2/cm3.
基金Supported by the Natural Science Foundation of China,No.69775004
文摘With the wide use of color in many areas, the interest on the color perception and processing has been growing rapidly. An important topic in color image processing is the development of efficient tools capable of filtering images without blurring them and without changing their original chromatic contents. In this paper, a new technique reducing noise of color image is developed. A class of color-scale morphological operations is introduced, which extend mathematical morphology to color image processing, representing a color image as a vector function. The correlation between color components is utilized to perform noise removal. Color-scale morphological niters with multiple structuring elements (CSMF-MSEs) are proposed. Their properties are discussed and proved. Experimental results show that CSMF-MSEs are suitable and powerful to eliminate noise and preserve edges in color image because of efficient utilization of inherent correlation between color components, and they perform better than vector
基金supported by Basic Science Research Program through the NationalResearch Foundation of Korea (NRF)funded by the Ministry of Education (2020R1A6A1A03040583).
文摘With the increasing number of digital devices generating a vast amount of video data,the recognition of abnormal image patterns has become more important.Accordingly,it is necessary to develop a method that achieves this task using object and behavior information within video data.Existing methods for detecting abnormal behaviors only focus on simple motions,therefore they cannot determine the overall behavior occurring throughout a video.In this study,an abnormal behavior detection method that uses deep learning(DL)-based video-data structuring is proposed.Objects and motions are first extracted from continuous images by combining existing DL-based image analysis models.The weight of the continuous data pattern is then analyzed through data structuring to classify the overall video.The performance of the proposed method was evaluated using varying parameter settings,such as the size of the action clip and interval between action clips.The model achieved an accuracy of 0.9817,indicating excellent performance.Therefore,we conclude that the proposed data structuring method is useful in detecting and classifying abnormal behaviors.
文摘A new concept of digital vector-layer structuring of landscape space at the local level (on a scale of 1:25,000) is considered on the example of Russian island and adjacent island systems of the Vladivostok urban district. Synthesis, analysis and evaluation of the internal and external content of landscape systems are carried out and altitude complexes of tracts are identified, in each of which altitudes are distinguished. It is noted that one of the main criteria for identifying high-altitude complexes and levels is the high-altitude criterion and the quantitative and qualitative changes in their internal content, taking into account the state of erosion-denudation lowland and mountain landscape systems formed under the influence of the Earth’s real material-energy flows and first of all gravitational energy. According to these criteria, landscape areas are classified and vertex, saddle, upper slope, middle slope and other altitude complexes of tracts are distinguished in each of which altitude levels are distinguished. Structuring and classification proposed to the reader are presented for further study of structures as objects of industry-specific indication and possibilities of using high-landscape complexes as development areas. Noted, as well as the fact that the study was conducted for the first time and is aimed at the practical implementation of the landscape approach in the development of landscape systems, defines the relevance of the work performed.
文摘For the first time, a new concept of digital structuring of landscape space of mountainous territories is considered. It is proposed to carry out structuring and classification of landscape systems, with the distribution of high-altitude landscape complexes. When finding the boundaries of these complexes, the high-altitude selection criterion prevailed, as well as quantitative and qualitative changes in their internal content. According to these criteria, it is possible to distinguish between plain, low-slope, low-mountain, dissected-middle-mountain, massive-medium-mountain, altitude-landscape complexes. Structuring and classification are presented for further study of structures as objects of industry indications and possibilities of using high-growing complexes as development areas.
文摘Astrocytes, the dominant glial cell type, modulate synaptic information transmission. Each astrocyte is organized in non-overlapping domains. Here, a formally based model of the possible significance of astrocyte domain organization is proposed. It is hypothesized that each astrocyte contacting n neurons with m synapses via its processes generates dynamic domains of synaptic interactions based on qualitative criteria so that it exerts a structuring of neuronal information processing. The formalism (morpho-grammatics) describes the combinatorics of the various astrocytic receptor types for occupancy with cognate neurotransmitters. Astrocytic processes are able both to contact synapses and retract from them. Rhythmic oscillations of the astrocyte may program the domain organization, where clock genes may play a role in rhythm generation. For the interpretation of a domain organization a player of a string instrument is used as a paradigm. Since astrocytes form networks (syncytia), the interactions between astrocyte domains may be comparable to the improvisations in a jazz ensemble. Given the fact of a high combinational complexity of an astrocyte domain organization, which is formally demonstrable, and an uncomputable complexity of a network of astrocyte domains, the model proposed may not be testable in biological brains, but robotics could be a real alternative.
基金Sponsored by Humanities and Social Science Research Program of Henan Provincial Department of Education(2013GH-141,2014-GH-208)
文摘Northern foot of the Qinling Mountains(Xi'an Section) is a transitional section between the Qinling Mountains and Xi'an City, so it has great ecological signifi cance. On the basis of sorting out landscape city, space structuring of the northern foot of the Qinling Mountains was studied within the theoretical framework of landscape city, it was disclosed that northern foot of the Qinling Mountains was a signifi cant ecological screen for the landscape city spatial pattern of Xi'an, and an important carrier for its "mountain, water and city" cultures. Then, fi ve infl uence factors for the space structuring of the study area were given, and basic contents of the space structuring analyzed from fi ve perspectives of spatial structure, spatial form, ecological environment, integration of regional spaces, historical and cultural context, so as to explore ecological conservation and moderate utilization of the northern foot of the Qinling Mountains from the perspective of space structuring.
