Employing decoupling index and industrial structure characteristic bias index methods, this study analyzed the spatial-temporal characteristics of industrial structure transformations and their resulting carbon emissi...Employing decoupling index and industrial structure characteristic bias index methods, this study analyzed the spatial-temporal characteristics of industrial structure transformations and their resulting carbon emissions in the Xuzhou Metropolitan Area from 2000 to 2014, with a focus on their relationships and driving factors. Our research indicates that carbon emission intensity from industrial structures in the Xuzhou Metropolitan Area at first showed an increasing trend, which then decreased. Furthermore, the relationship between emissions and industrial economic growth has been trending toward absolute decoupling. From the perspective of the center-periphery, the Xuzhou Metropolitan Area formed a concentric pattern, where both progress towards low emissions and the level of technological advancement gradually diminished from the center to the periphery. In terms of variation across provinces, the ISCB index in the eastern Henan has decreased the slowest, followed by the southern Shandong and the northern Anhui, with the northern Jiangsu ranking last. During this period, resource-and labor-intensive industries were the primary growth industries in the northern Anhui and the eastern Henan, while labor-intensive industries dominated the southern Shandong and capital-intensive industries dominated the northern Jiangsu. In terms of city types, the spatial pattern for industrial structure indicates that recession resource-based cities had higher carbon emission intensities than mature resource-based cities, followed by non-resource-based cities and regenerative resource-based cities. Generally, the industrial structure in the Xuzhou Metropolitan Area has transformed from being resource-intensive to capital-intensive, and has been trending toward technology-intensive as resource availability has been exploited to exhaustion and then been regenerated. Industrial structure has been the leading factor causing heterogeneity of carbon emission intensities between metropolitan cities. Therefore, the key to optimizing the industrial structure and layout of metropolitan areas is to promote industrial structure transformation and improve the system controlling collaborative industrial development between cities.展开更多
Land, as a key factor of production, is an appropriate indicator of national and regional economic structure transformation. Land use in the Changjiang （Yangtze） River Basin （CRB） since the 1950s has experienced t...Land, as a key factor of production, is an appropriate indicator of national and regional economic structure transformation. Land use in the Changjiang （Yangtze） River Basin （CRB） since the 1950s has experienced these changes. Industrialization has been the most powerful force of the change in the regional development of the CRB. Virtually all regional resources were put into this effort to modernize the industrial production and urban construction systems of the CRB whose industrialization and urbanization has been a success story, with impressive structural change in both production and land use. These changes are evident ih modem urban areas, but even more in traditionally rural areas. The regression analysis of regional development in the CRB over an extended period shows that the dominant factor in regional land use change is widespread industrialization in rural areas rather than the expansion of urban area. Thus, urbanization has had a limited influence on land use change in the CRB. A major task in realizing more sustainable land use in the future development of CRB is to relocate industrial activities from rural to urban areas.展开更多
Orthorhombic LiMnO2 cathode materials were synthesized successfully at lower temperature by sol-gel method. When LiMnO2 precursor prepared by sol-gel method was fired in air, the product was a mixture of spinel struct...Orthorhombic LiMnO2 cathode materials were synthesized successfully at lower temperature by sol-gel method. When LiMnO2 precursor prepared by sol-gel method was fired in air, the product was a mixture of spinel structure LiMn2O4 and rock-salt structure Li2MnO3, whereas in argon single-phase orthorhombic LiMnO2 could obtain at the range of 750℃ to 920℃. The substitution of Mn by Zn2+ or Co3+ in LiMnO2 led to the structure of LiMnO2 transiting to Qα-LiFeO2. The results of electrochemical cycles indicated that the discharged capacity of orthorhombic-LiMnO2 was smaller at the initial stages, then gradually increased with the increasing of cycle number, finally the capacity stabilized to certain value after about 10th cycles. This phenomenon reveals that there is an activation process for orthorhombic LiMnO2 cathode materials during electrochemical cycles, which is a phase transition process from orthorhombic LiMnO2 to tetragonal spinel Li2Mn2O4. The capacity of orthorhombic LiMnO2 synthesized at lower temperature is larger than that synthesized at high temperature.展开更多
Scarcity of land resources and transformation of industrial structure is a pair of contradictory elements.We derive the characteristics of land use structure and industrial structure transformation in Xining City usin...Scarcity of land resources and transformation of industrial structure is a pair of contradictory elements.We derive the characteristics of land use structure and industrial structure transformation in Xining City using Transformation Coefficient(TC):first,in the period 1999-2000,the land use structure coefficient(θ1) declined by 79.55%,but the overall evolution trend is gentle;second,the transformation coefficient of industrial structure(θ2) tended to decline ceaselessly on the whole,a decrease of 36.09%(overall,the transformation coefficient of industrial structure is slightly greater than the land use structure coefficient);third,the inter-annual variation of the two experienced ups and downs(in the period 1999-2007,the inter-annual variation was great and in the period 2008-2010,the inter-annual variation tended to be gentle).On the basis of autocorrelation and co-integration model,we draw the following conclusions through analysis:first,the land use structure in Xining City plays a role in promoting industrial structure transformation;second,there is a long-term equilibrium relationship between the two.Finally,relevant policy recommendations are put forward for the industrial development in Xining City.展开更多
Under the guidance of national policies,the“coal to gas”project has become one of the important measures to promote the transformation of energy structure in China.Foshan,an important industrial town in Guangdong pr...Under the guidance of national policies,the“coal to gas”project has become one of the important measures to promote the transformation of energy structure in China.Foshan,an important industrial town in Guangdong province,the implementation of the“coal to gas”policy has demonstrated significance for the optimization of the national energy structure.Through the analysis of the change in Foshan’s energy consumption structure and the implementation of the policy,this paper found that there were some challenges in the policy implementation process,such as high economic cost,lagging infrastructure,low social acceptance,and lack of technical personnel.To address this,suggestions are put forward,including increasing financial subsidies,improving laws and regulations,promoting technological innovation,and encouraging social inclusion policies.These recommendations aim to provide guidance and reference for the remaining“coal to gas”projects and the development of clean energy.展开更多
Occupational structural transformation is a common pattern during the steady growth of GDP per capita in major economies worldwide.In recent years,there has been a decline in the employment share of goods occupation a...Occupational structural transformation is a common pattern during the steady growth of GDP per capita in major economies worldwide.In recent years,there has been a decline in the employment share of goods occupation and an increase in service occupation within the Chinese manufacturing industry,presenting a trend of occupational structural transformation and rapid development of service-oriented manufacturing.It is an important driving force and typical performance of the high-end,intelligent,and green development of the manufacturing industry.As a strategic general technology which leads the new round of technological revolution and industrial transformation,artificial intelligence(AI)has become a new fundamental force to accelerate the occupational structural transformation and service-oriented manufacturing development in China.Thus,this paper establishes a dynamic general equilibrium model with AI technology and occupational heterogeneity,showing the endogenous mechanism of occupational structural transformation.We find that when AI technology is biased towards goods occupation,and the elasticity of substitution between goods occupation and service occupation is less than 1,then AI will drive the transformation of occupational structure from goods to service within the manufacturing sector,increase the proportion of service-oriented manufacturing,improve labor productivity of manufacturing relative to service and stabilize the real output share of manufacturing.Promoting deeper integration of different occupations,intensifying R&D in AI technology and reducing labor mobility barriers between occupations can effectively accelerate the occupational structural transformation and industrial structural upgrading.We use theoretical analysis and numerical simulation method to show the theoretical mechanism by which AI affects occupational structural transformation and industrial structural transformation from a macroeconomic perspective,and put forward policy implications on how to promote the service-oriented manufacturing development and accelerate the construction of modern industrial system through AI innovation.展开更多
Structure Data Layout Optimization （SDLO） is a prevailing compiler optimization technique to improve cache efficiency. Structure transformation is a critical step for SDLO. Diversity of transformation methods and ex...Structure Data Layout Optimization （SDLO） is a prevailing compiler optimization technique to improve cache efficiency. Structure transformation is a critical step for SDLO. Diversity of transformation methods and existence of complex data types are major challenges for structure transformation. We have designed and implemented STrans, a well-defined system which provides controllable and comprehensive functionality on structure transformation. Compared to known systems, it has less limitation on data types for transformation. In this paper we give formal definition of the approach STrans transforms data types. We have also designed Transformation Specification Language, a mini language to configure how to transform structures, which can be either manually tuned or generated by compiler. STrans supports three kinds of transformation methods, i.e., splitting, peeling, and pool-splitting, and works well on different combinations of compound data types. STrans is the transformation system used in ASLOP and is well tested for all benchmarks for ASLOR展开更多
Industry interaction is becoming an important approach to promoting highquality economic development.In this paper,the multi-sector general equilibrium model is developed to clarify the theoretical mechanism among ind...Industry interaction is becoming an important approach to promoting highquality economic development.In this paper,the multi-sector general equilibrium model is developed to clarify the theoretical mechanism among industry interaction,structure transformation,and high-quality economic development;the empirical tests are carried out based on the provincial panel data from 2000 to 2017;and the empowerment paths for digital technologies are explored to drive high-quality economic development.The findings are as follows.(1)The industry interaction can promote high-qualityy economic development in China on the whole,but it shows a significant imbalance and a healthy two-way promotion mode have not been formed.(2)The impact of industry interaction on high-quality economic development is significantly heterogeneous at the sector and regional levels.(3)The current unhealthy industry interaction may widen the productivity gap between manufacturing and service sectors,and transform China's economic into service-oriented structure,thus leading the economic development to a vicious circle of“low efficiency to low-end servitization and further to lower efficiency”and hindering the sustainability of high-quality economic development:.(4)Digitaltlechnologies can break the development dilemma and achieve high-quality economic development by alleviating structural contradictions,boosting healthy industry interaction,and narrowing the productivity gap among sectors.The conclusions provide empirical evidence for the government to promote the integration of advanced manufacturing and modern service sectors and achieve highquality economic development.展开更多
After the end of the cold war, the Asia-Pacific security structure has experienced great changes, especially on the occasion of the current "power-sharing" and "power-shifting" between China and th...After the end of the cold war, the Asia-Pacific security structure has experienced great changes, especially on the occasion of the current "power-sharing" and "power-shifting" between China and the United States in the Asia-Pacific region, the Asia-Pacific security structure adjustment is especially significant. On the one hand, the Alliance structure with the United States as the pivot has experienced transformation from a hub-spokes system to a network, has formed the hierarchical layout of new alliance, quasi-alliance and potential alliance, On the other hand, emerging economies represented by China and Russia, while reinforcing the existing coordinate security framework, reshape the Asia-Pacific and even the whole Eurasia geopolitical posture through strategic initiatives such as the Belt and Road Initiative, the Eurasian Economic Union. As the third force in the Asia-Pacific security architecture, the Association of South-East Asian Nations(ASEAN) with the construction of a series of multilateral security mechanisms provides dialogue platform for the two security architectures led by major countries, and has also become one of the feasible paths to realize the future holistic security architecture in the Asia-Pacific region. Meanwhile, the major countries strategic competitions have intensified, which has gradually eroded the ASEAN ‘s cohesion, neutrality and even the central position in a holistic security architecture. The future's reconstruction of the Asia-Pacific security architecture needs to find new strategic consensus and reconfirm the ASEAN central position.展开更多
Tumor-targeted delivery of nanomedicine is of great importance to improve therapeutic efficacy of cancer and minimize systemic side effects.Unfortunately,nowadays the targeting efficiency of nanomedicine toward tumor ...Tumor-targeted delivery of nanomedicine is of great importance to improve therapeutic efficacy of cancer and minimize systemic side effects.Unfortunately,nowadays the targeting efficiency of nanomedicine toward tumor is still quite limited and far from clinical requirements.In this work,we develop an innovative peptide-based nanoparticle to realize light-triggered nitric oxide(NO)release and structural transformation for enhanced intratumoral retention and simultaneously sensitizing photodynamic therapy(PDT).The designed nanoparticle is self-assembled from a chimeric peptide monomer,TPP-RRRKLVFFK-Ce6,which contains a photosensitive moiety(chlorin e6,Ce6),aβ-sheet-forming peptide domain(Lys-Leu-Val-Phe-Phe,KLVFF),an oligoarginine domain(RRR)as NO donor and a triphenylphosphonium(TPP)moiety for targeting mitochondria.When irradiated by light,the constructed nanoparticles undergo rapid structural transformation from nanosphere to nanorod,enabling to achieve a significantly higher intratumoral accumulation by 3.26 times compared to that without light irradiation.More importantly,the conversion of generated NO and reactive oxygen species(ROS)in a light-responsive way to peroxynitrite anions(ONOO)with higher cytotoxicity enables NO to sensitize PDT in cancer treatment.Both in vitro and in vivo studies demonstrate that NO sensitized PDT based on the well-designed transformable nanoparticles enables to eradicate tumors efficiently.The light-triggered transformable nanoplatform developed in this work provides a new strategy for enhanced intratumoral retention and improved therapeutic outcome.展开更多
304 austenitic stainless steel was cold rolled in the range of 20%-80%reductions and then annealed at 700-900°C for 60 sto obtain nano/ultrafine-grained（NG/UFG）structure.Transmission electron microscopy,electro...304 austenitic stainless steel was cold rolled in the range of 20%-80%reductions and then annealed at 700-900°C for 60 sto obtain nano/ultrafine-grained（NG/UFG）structure.Transmission electron microscopy,electron backscatter diffraction and X-ray diffraction were used to characterize the resulting microstructures.The results showed that with the increase of cold reduction,the content of martensite was increased.The steel performed work hardening during cold-working owing to the occurrence of strain induced martensite which nucleated in single shear bands.Further rolling broke up the lath-type martensite into dislocation-cell type martensite because of the formation of slip bands.Samples annealed at 800-960°C for 60 swere of NG/UFG structure with different percentage of nanocrystalline（60-100 nm）and ultrafine（100-500 nm）grains,submicron size（500-1000 nm）grains and micron size（〉1000 nm）grains.The value of the Gibbs free energy exhibited that the reversion mechanism of the reversion process was shear controlled by the annealing temperature.For a certain annealing time during the reversion process,austenite nucleated first on dislocation-cell type martensite and the grains grew up subsequently and eventually to be micrometer/submicrometer grains,while the nucleation of austenite on lath-type martensite occurred later resulting in nanocrystalline/ultrafine grains.The existence of the NG/UFG structure led to a higher strength and toughness during tensile test.展开更多
The microstructure of CdI2 thin film grown during vapor-phase deposition was investigated by scanning electron microscopy (SEM). The thin film deposited on Si crystal consists of numerous sunflower-like aggregates. Th...The microstructure of CdI2 thin film grown during vapor-phase deposition was investigated by scanning electron microscopy (SEM). The thin film deposited on Si crystal consists of numerous sunflower-like aggregates. These aggregates display well self-assembly characteristics. The size of Sunflower-like aggregates is between 12 and 44 μm. Each sunflower-like aggregate is surrounded with many adjacent wings-'petals'. The structure of central region of the 'sunflower' is obviously difFerent from that of the 'petal'. Electron spectroscopy for chemical analysis (ESCA) was employed in determining the chemical valence of the thin film. Self-organization efFect is used to explain the coring growth process of CdI2 thin film展开更多
The intimate host-anion interactions will regulate thermodynamics and kinetics in the self-assembly of cationic cages mimicking biological counterparts.Herein,we report construction and transformation of three Pd(Ⅱ)-...The intimate host-anion interactions will regulate thermodynamics and kinetics in the self-assembly of cationic cages mimicking biological counterparts.Herein,we report construction and transformation of three Pd(Ⅱ)-based metal-organic cages(MOCs)depending on different anions.Stoichiometric conversions of the lantern-shaped MOC-34 into either octahedral MOC-35 or tricapped trigonal prism MOC-36 are induced by BF_(4)^(–)or NO_(3)^(–),respectively.MOC-36 is kinetically favored and can undergo quantitative conversion to the thermodynamically preferred MOC-35 upon heating,accelerated by excess BF_(4)^(–)to motivate dissociative dynamics of Pd-vertices and lower activation barrier of cage transformation.The vip encapsulation behaviors of MOC-35 and MOC-36 have also been tested.These results manifest a significance of host-anion dynamics beyond complementary anion template,shedding light on the understanding of intricate anion recognition in nature.展开更多
Based on Joseph Schumpeter’s theory of“creative destruction,”we constructed a multi-sectoral endogenous growth model that integrates the agriculture,manufacturing,and service sectors.Employing numerical simulation,...Based on Joseph Schumpeter’s theory of“creative destruction,”we constructed a multi-sectoral endogenous growth model that integrates the agriculture,manufacturing,and service sectors.Employing numerical simulation,we investigated the dynamic influence of technological innovation on the industrial structural transformation in two key aspects:the level of innovation and the research and development(R&D)efficiency within industries.Our findings indicate that technological innovation plays a pivotal role in advancing industrial structural transformation.Enhancements in both the level of innovation and R&D efficiency within industries are instrumental in fostering industrial structural transformation.Specifically,the enhancements in the level of innovation or R&D efficiency within the agricultural sector hasten its transition toward the manufacturing sector,while such enhancement within the manufacturing sector expedites its transition toward the service sector.However,such enhancements within the service sector tend to decelerate the transition from manufacturing to service.In light of this,it is essential to harness technological innovation to enhance the level of innovation and R&D efficiency in industries to facilitate the transition of traditional industries into high-value-added and emerging ones.Meanwhile,tailored technological innovation strategies should be implemented to boost a balanced industrial structural transformation within industries.展开更多
A simple model of the closely packed structure for system of hard-sphere particles interacting via the long-range Newtonian type attraction is suggested. Based on density functional theory, the exact equation of ...A simple model of the closely packed structure for system of hard-sphere particles interacting via the long-range Newtonian type attraction is suggested. Based on density functional theory, the exact equation of state is obtained and the mutual transformations of the crystal structures in such systems are studied. The description takes into account the fact impossibility of hard-sphere particles which have the same spatial occupation place.展开更多
The latest economic data released by China’s National Bureau of Statistics for April 2025 underscores the country’s robust economic recovery and structural transformation.Industrial production surged by 6.1 percent ...The latest economic data released by China’s National Bureau of Statistics for April 2025 underscores the country’s robust economic recovery and structural transformation.Industrial production surged by 6.1 percent year on year,propelled by breakthroughs in advanced manufacturing,from high-tech industries to cutting-edge equipment sectors.展开更多
In order to investigate the ion irradiation effect on the corrosion behavior and microstructure of Zircaloy-4, the Zircaloy-4 film were prepared by electron beam deposition on the Zircaloy-4 specimen surface and irra...In order to investigate the ion irradiation effect on the corrosion behavior and microstructure of Zircaloy-4, the Zircaloy-4 film were prepared by electron beam deposition on the Zircaloy-4 specimen surface and irradiated by Kr ions using an accelerator at an energy of 300 keV with the dose from 1×1015 to 3×1016ions/cm2. The post-irradiation corrosion tests were conducted to rank the corrosion resistance of the resulting specimens by potentiodynamic polarization curve measurements in a 0.5 mol/L H2SO4 water so- lution at room temperature. Transmission electron microscopy (TEM) was employed to examine the microstructural change in the surface. The potentiodynamic tests show that with the irradiation dose increasing, the passive current density, closely related to the surface corrosion resistance, decreases firstly and increases subsequently. The mechanism of the corrosion behavior transformation is due to the amorphous phase formation firstly and the amorphous phase destruction and the polycrystalline structure formation in the irradiated surface subsequently.展开更多
This paper uses the panel data of 17 cities in Shandong Province from 2003 to 2018 to construct a panel model to empirically study the impact of foreign direct investment(FDI)on the industrial structure.The results sh...This paper uses the panel data of 17 cities in Shandong Province from 2003 to 2018 to construct a panel model to empirically study the impact of foreign direct investment(FDI)on the industrial structure.The results show that two-way investment,financial industry development,and policy variables have significant roles in promoting the advancement of the industrial structure in the province.In the future implementation of the“Going Global”strategy in Shandong Province,the cooperation between two-way investment and the financial industry should be strengthened,the level of regional financial development should be improved,and the impact of two-way investment on the optimization and upgrading of the industrial structure should be reinforced.展开更多
The character of structural changes in the surface layer of titanium carbide （TiC） with Ni-Cr alloy binder was investigated theoretically and experimentally after electron-beam treatment of the material surface. The...The character of structural changes in the surface layer of titanium carbide （TiC） with Ni-Cr alloy binder was investigated theoretically and experimentally after electron-beam treatment of the material surface. The thermal influence of the electron-beam irradiation on the surface layer microstructure of the composite fine-grained material was mathematically analyzed. Quantitative estimations of the depth of the zone in microstructural phase transformations were carried out. The microstructure and concentration profile of Ti distribution in the metallic binder over the cross section of the surface layer with microstructural phase transformations after electron-pulse treatment of the hard metal surface were experimentally investigated.展开更多
The oxidation behavior of three biodiesels of different origins,viz.rapeseed oil derived biodiesel,soybean oil derived biodiesel and waste oil based biodiesel,were tested on an oxidation tester.The chemical compositio...The oxidation behavior of three biodiesels of different origins,viz.rapeseed oil derived biodiesel,soybean oil derived biodiesel and waste oil based biodiesel,were tested on an oxidation tester.The chemical compositions of the biodiesels were characterized by gas chromatography.Thereafter,the structural transformation of fatty acid methyl ester(FAME)of the biodiesels was analyzed by an infrared spectrometer and an ultraviolet absorption spectrometer.The results demonstrated that the oxidation behavior of biodiesels of different origins was closely related to the composition and distribution of FAMEs.Higher concentration of unsaturated FAME with multi-double bonds exhibited poorer oxidation resistance.Furthermore,cis-trans isomerization transformation occurred in the unsaturated FAME molecules and conjugated double-bond produced during the oxidation process of biodiesel.Greater cis-trans variations corresponded to deeper oxidation degree.The higher the content of unsaturated FAME with multi-double bonds in a biodiesel,the more the conjugated double bonds was formed.展开更多
基金Under the auspices of the National Natural Science Foundation of China(No.41371146,41671123)National Social Science Foundation of China(No.13BJY067)
文摘Employing decoupling index and industrial structure characteristic bias index methods, this study analyzed the spatial-temporal characteristics of industrial structure transformations and their resulting carbon emissions in the Xuzhou Metropolitan Area from 2000 to 2014, with a focus on their relationships and driving factors. Our research indicates that carbon emission intensity from industrial structures in the Xuzhou Metropolitan Area at first showed an increasing trend, which then decreased. Furthermore, the relationship between emissions and industrial economic growth has been trending toward absolute decoupling. From the perspective of the center-periphery, the Xuzhou Metropolitan Area formed a concentric pattern, where both progress towards low emissions and the level of technological advancement gradually diminished from the center to the periphery. In terms of variation across provinces, the ISCB index in the eastern Henan has decreased the slowest, followed by the southern Shandong and the northern Anhui, with the northern Jiangsu ranking last. During this period, resource-and labor-intensive industries were the primary growth industries in the northern Anhui and the eastern Henan, while labor-intensive industries dominated the southern Shandong and capital-intensive industries dominated the northern Jiangsu. In terms of city types, the spatial pattern for industrial structure indicates that recession resource-based cities had higher carbon emission intensities than mature resource-based cities, followed by non-resource-based cities and regenerative resource-based cities. Generally, the industrial structure in the Xuzhou Metropolitan Area has transformed from being resource-intensive to capital-intensive, and has been trending toward technology-intensive as resource availability has been exploited to exhaustion and then been regenerated. Industrial structure has been the leading factor causing heterogeneity of carbon emission intensities between metropolitan cities. Therefore, the key to optimizing the industrial structure and layout of metropolitan areas is to promote industrial structure transformation and improve the system controlling collaborative industrial development between cities.
基金Under the auspices of Knowledge Innovation Program of Chinese Academy of Sciences (No. KCZX2-307-01)
文摘Land, as a key factor of production, is an appropriate indicator of national and regional economic structure transformation. Land use in the Changjiang （Yangtze） River Basin （CRB） since the 1950s has experienced these changes. Industrialization has been the most powerful force of the change in the regional development of the CRB. Virtually all regional resources were put into this effort to modernize the industrial production and urban construction systems of the CRB whose industrialization and urbanization has been a success story, with impressive structural change in both production and land use. These changes are evident ih modem urban areas, but even more in traditionally rural areas. The regression analysis of regional development in the CRB over an extended period shows that the dominant factor in regional land use change is widespread industrialization in rural areas rather than the expansion of urban area. Thus, urbanization has had a limited influence on land use change in the CRB. A major task in realizing more sustainable land use in the future development of CRB is to relocate industrial activities from rural to urban areas.
基金supported by the National Natural Science Foundation of China under grant No.59972026.
文摘Orthorhombic LiMnO2 cathode materials were synthesized successfully at lower temperature by sol-gel method. When LiMnO2 precursor prepared by sol-gel method was fired in air, the product was a mixture of spinel structure LiMn2O4 and rock-salt structure Li2MnO3, whereas in argon single-phase orthorhombic LiMnO2 could obtain at the range of 750℃ to 920℃. The substitution of Mn by Zn2+ or Co3+ in LiMnO2 led to the structure of LiMnO2 transiting to Qα-LiFeO2. The results of electrochemical cycles indicated that the discharged capacity of orthorhombic-LiMnO2 was smaller at the initial stages, then gradually increased with the increasing of cycle number, finally the capacity stabilized to certain value after about 10th cycles. This phenomenon reveals that there is an activation process for orthorhombic LiMnO2 cathode materials during electrochemical cycles, which is a phase transition process from orthorhombic LiMnO2 to tetragonal spinel Li2Mn2O4. The capacity of orthorhombic LiMnO2 synthesized at lower temperature is larger than that synthesized at high temperature.
基金Supported by National Natural Science Foundation Project(41101098)Youth Project of Xianning University(KY10044,KY10043)
文摘Scarcity of land resources and transformation of industrial structure is a pair of contradictory elements.We derive the characteristics of land use structure and industrial structure transformation in Xining City using Transformation Coefficient(TC):first,in the period 1999-2000,the land use structure coefficient(θ1) declined by 79.55%,but the overall evolution trend is gentle;second,the transformation coefficient of industrial structure(θ2) tended to decline ceaselessly on the whole,a decrease of 36.09%(overall,the transformation coefficient of industrial structure is slightly greater than the land use structure coefficient);third,the inter-annual variation of the two experienced ups and downs(in the period 1999-2007,the inter-annual variation was great and in the period 2008-2010,the inter-annual variation tended to be gentle).On the basis of autocorrelation and co-integration model,we draw the following conclusions through analysis:first,the land use structure in Xining City plays a role in promoting industrial structure transformation;second,there is a long-term equilibrium relationship between the two.Finally,relevant policy recommendations are put forward for the industrial development in Xining City.
文摘Under the guidance of national policies,the“coal to gas”project has become one of the important measures to promote the transformation of energy structure in China.Foshan,an important industrial town in Guangdong province,the implementation of the“coal to gas”policy has demonstrated significance for the optimization of the national energy structure.Through the analysis of the change in Foshan’s energy consumption structure and the implementation of the policy,this paper found that there were some challenges in the policy implementation process,such as high economic cost,lagging infrastructure,low social acceptance,and lack of technical personnel.To address this,suggestions are put forward,including increasing financial subsidies,improving laws and regulations,promoting technological innovation,and encouraging social inclusion policies.These recommendations aim to provide guidance and reference for the remaining“coal to gas”projects and the development of clean energy.
基金This study was supported by:The Late-Stage Support Program of the National Social Science Fund of China“Supply-Side Structural Reform and the Dual Structural Transformation of China's Economy”(Grant No.22FJLB009)The National Natural Science Fund of China for Young Scholars“The Dual Structural Transformation of China’s Economy:A Theoretical Analysis and Empirical Test Based on the Supply-Side Structural Reform”(Grant No.71703056).
文摘Occupational structural transformation is a common pattern during the steady growth of GDP per capita in major economies worldwide.In recent years,there has been a decline in the employment share of goods occupation and an increase in service occupation within the Chinese manufacturing industry,presenting a trend of occupational structural transformation and rapid development of service-oriented manufacturing.It is an important driving force and typical performance of the high-end,intelligent,and green development of the manufacturing industry.As a strategic general technology which leads the new round of technological revolution and industrial transformation,artificial intelligence(AI)has become a new fundamental force to accelerate the occupational structural transformation and service-oriented manufacturing development in China.Thus,this paper establishes a dynamic general equilibrium model with AI technology and occupational heterogeneity,showing the endogenous mechanism of occupational structural transformation.We find that when AI technology is biased towards goods occupation,and the elasticity of substitution between goods occupation and service occupation is less than 1,then AI will drive the transformation of occupational structure from goods to service within the manufacturing sector,increase the proportion of service-oriented manufacturing,improve labor productivity of manufacturing relative to service and stabilize the real output share of manufacturing.Promoting deeper integration of different occupations,intensifying R&D in AI technology and reducing labor mobility barriers between occupations can effectively accelerate the occupational structural transformation and industrial structural upgrading.We use theoretical analysis and numerical simulation method to show the theoretical mechanism by which AI affects occupational structural transformation and industrial structural transformation from a macroeconomic perspective,and put forward policy implications on how to promote the service-oriented manufacturing development and accelerate the construction of modern industrial system through AI innovation.
基金supported by the National Natural Science Foundation of China(No.61133006)the National High-Tech Research and Development(863)Program of China(No.2012AA010901)
文摘Structure Data Layout Optimization （SDLO） is a prevailing compiler optimization technique to improve cache efficiency. Structure transformation is a critical step for SDLO. Diversity of transformation methods and existence of complex data types are major challenges for structure transformation. We have designed and implemented STrans, a well-defined system which provides controllable and comprehensive functionality on structure transformation. Compared to known systems, it has less limitation on data types for transformation. In this paper we give formal definition of the approach STrans transforms data types. We have also designed Transformation Specification Language, a mini language to configure how to transform structures, which can be either manually tuned or generated by compiler. STrans supports three kinds of transformation methods, i.e., splitting, peeling, and pool-splitting, and works well on different combinations of compound data types. STrans is the transformation system used in ASLOP and is well tested for all benchmarks for ASLOR
基金the research results of the"Research on Major Issues of Building an Autonomous and Controllable Modern Sector System under the Economic Conditions of a Large Country"(No.21&ZD099)a major project of the National Social Science Fund of China,and the"Internal Mechanism,Effect Evaluation and Policy Innovation of the Optimization and Transformation of Economic Structure Driven by Digital Technologies"(No.2021YJSB037),one of the postgraduate research innovation projects in Tianjin.
文摘Industry interaction is becoming an important approach to promoting highquality economic development.In this paper,the multi-sector general equilibrium model is developed to clarify the theoretical mechanism among industry interaction,structure transformation,and high-quality economic development;the empirical tests are carried out based on the provincial panel data from 2000 to 2017;and the empowerment paths for digital technologies are explored to drive high-quality economic development.The findings are as follows.(1)The industry interaction can promote high-qualityy economic development in China on the whole,but it shows a significant imbalance and a healthy two-way promotion mode have not been formed.(2)The impact of industry interaction on high-quality economic development is significantly heterogeneous at the sector and regional levels.(3)The current unhealthy industry interaction may widen the productivity gap between manufacturing and service sectors,and transform China's economic into service-oriented structure,thus leading the economic development to a vicious circle of“low efficiency to low-end servitization and further to lower efficiency”and hindering the sustainability of high-quality economic development:.(4)Digitaltlechnologies can break the development dilemma and achieve high-quality economic development by alleviating structural contradictions,boosting healthy industry interaction,and narrowing the productivity gap among sectors.The conclusions provide empirical evidence for the government to promote the integration of advanced manufacturing and modern service sectors and achieve highquality economic development.
文摘After the end of the cold war, the Asia-Pacific security structure has experienced great changes, especially on the occasion of the current "power-sharing" and "power-shifting" between China and the United States in the Asia-Pacific region, the Asia-Pacific security structure adjustment is especially significant. On the one hand, the Alliance structure with the United States as the pivot has experienced transformation from a hub-spokes system to a network, has formed the hierarchical layout of new alliance, quasi-alliance and potential alliance, On the other hand, emerging economies represented by China and Russia, while reinforcing the existing coordinate security framework, reshape the Asia-Pacific and even the whole Eurasia geopolitical posture through strategic initiatives such as the Belt and Road Initiative, the Eurasian Economic Union. As the third force in the Asia-Pacific security architecture, the Association of South-East Asian Nations(ASEAN) with the construction of a series of multilateral security mechanisms provides dialogue platform for the two security architectures led by major countries, and has also become one of the feasible paths to realize the future holistic security architecture in the Asia-Pacific region. Meanwhile, the major countries strategic competitions have intensified, which has gradually eroded the ASEAN ‘s cohesion, neutrality and even the central position in a holistic security architecture. The future's reconstruction of the Asia-Pacific security architecture needs to find new strategic consensus and reconfirm the ASEAN central position.
基金financially supported by National Natural Science Foundation of China(51872188)Shenzhen Basic Research Program(SGDX20201103093600004)+3 种基金Special Funds for the Development of Strategic Emerging Industries in Shenzhen(20180309154519685)SZU Top Ranking Project(860-00000210)Basic and Applied Basic Research Foundation of Guangdong Province(2019A1515110294)the Postdoctoral Science Foundation of China(2020M672798).
文摘Tumor-targeted delivery of nanomedicine is of great importance to improve therapeutic efficacy of cancer and minimize systemic side effects.Unfortunately,nowadays the targeting efficiency of nanomedicine toward tumor is still quite limited and far from clinical requirements.In this work,we develop an innovative peptide-based nanoparticle to realize light-triggered nitric oxide(NO)release and structural transformation for enhanced intratumoral retention and simultaneously sensitizing photodynamic therapy(PDT).The designed nanoparticle is self-assembled from a chimeric peptide monomer,TPP-RRRKLVFFK-Ce6,which contains a photosensitive moiety(chlorin e6,Ce6),aβ-sheet-forming peptide domain(Lys-Leu-Val-Phe-Phe,KLVFF),an oligoarginine domain(RRR)as NO donor and a triphenylphosphonium(TPP)moiety for targeting mitochondria.When irradiated by light,the constructed nanoparticles undergo rapid structural transformation from nanosphere to nanorod,enabling to achieve a significantly higher intratumoral accumulation by 3.26 times compared to that without light irradiation.More importantly,the conversion of generated NO and reactive oxygen species(ROS)in a light-responsive way to peroxynitrite anions(ONOO)with higher cytotoxicity enables NO to sensitize PDT in cancer treatment.Both in vitro and in vivo studies demonstrate that NO sensitized PDT based on the well-designed transformable nanoparticles enables to eradicate tumors efficiently.The light-triggered transformable nanoplatform developed in this work provides a new strategy for enhanced intratumoral retention and improved therapeutic outcome.
基金supported by the National Natural Science Foundation of China(Grant No.51474031)
文摘304 austenitic stainless steel was cold rolled in the range of 20%-80%reductions and then annealed at 700-900°C for 60 sto obtain nano/ultrafine-grained（NG/UFG）structure.Transmission electron microscopy,electron backscatter diffraction and X-ray diffraction were used to characterize the resulting microstructures.The results showed that with the increase of cold reduction,the content of martensite was increased.The steel performed work hardening during cold-working owing to the occurrence of strain induced martensite which nucleated in single shear bands.Further rolling broke up the lath-type martensite into dislocation-cell type martensite because of the formation of slip bands.Samples annealed at 800-960°C for 60 swere of NG/UFG structure with different percentage of nanocrystalline（60-100 nm）and ultrafine（100-500 nm）grains,submicron size（500-1000 nm）grains and micron size（〉1000 nm）grains.The value of the Gibbs free energy exhibited that the reversion mechanism of the reversion process was shear controlled by the annealing temperature.For a certain annealing time during the reversion process,austenite nucleated first on dislocation-cell type martensite and the grains grew up subsequently and eventually to be micrometer/submicrometer grains,while the nucleation of austenite on lath-type martensite occurred later resulting in nanocrystalline/ultrafine grains.The existence of the NG/UFG structure led to a higher strength and toughness during tensile test.
文摘The microstructure of CdI2 thin film grown during vapor-phase deposition was investigated by scanning electron microscopy (SEM). The thin film deposited on Si crystal consists of numerous sunflower-like aggregates. These aggregates display well self-assembly characteristics. The size of Sunflower-like aggregates is between 12 and 44 μm. Each sunflower-like aggregate is surrounded with many adjacent wings-'petals'. The structure of central region of the 'sunflower' is obviously difFerent from that of the 'petal'. Electron spectroscopy for chemical analysis (ESCA) was employed in determining the chemical valence of the thin film. Self-organization efFect is used to explain the coring growth process of CdI2 thin film
基金supported by the NKRD Program of China(No.2021YFA1500401)the National Natural Science Foundation of China(Nos.21821003,21890380)the LIRTP of Guangdong Pearl River Talents Program(No.2017BT01C161)。
文摘The intimate host-anion interactions will regulate thermodynamics and kinetics in the self-assembly of cationic cages mimicking biological counterparts.Herein,we report construction and transformation of three Pd(Ⅱ)-based metal-organic cages(MOCs)depending on different anions.Stoichiometric conversions of the lantern-shaped MOC-34 into either octahedral MOC-35 or tricapped trigonal prism MOC-36 are induced by BF_(4)^(–)or NO_(3)^(–),respectively.MOC-36 is kinetically favored and can undergo quantitative conversion to the thermodynamically preferred MOC-35 upon heating,accelerated by excess BF_(4)^(–)to motivate dissociative dynamics of Pd-vertices and lower activation barrier of cage transformation.The vip encapsulation behaviors of MOC-35 and MOC-36 have also been tested.These results manifest a significance of host-anion dynamics beyond complementary anion template,shedding light on the understanding of intricate anion recognition in nature.
基金supported by the project of the National Social Science Foundation of China entitled“Research on the Mechanism of Deep Integration of Modern Services Industry and Advanced Manufacturing Industry Driven by Digital Technology Innovation”(Project No.21BJY144).
文摘Based on Joseph Schumpeter’s theory of“creative destruction,”we constructed a multi-sectoral endogenous growth model that integrates the agriculture,manufacturing,and service sectors.Employing numerical simulation,we investigated the dynamic influence of technological innovation on the industrial structural transformation in two key aspects:the level of innovation and the research and development(R&D)efficiency within industries.Our findings indicate that technological innovation plays a pivotal role in advancing industrial structural transformation.Enhancements in both the level of innovation and R&D efficiency within industries are instrumental in fostering industrial structural transformation.Specifically,the enhancements in the level of innovation or R&D efficiency within the agricultural sector hasten its transition toward the manufacturing sector,while such enhancement within the manufacturing sector expedites its transition toward the service sector.However,such enhancements within the service sector tend to decelerate the transition from manufacturing to service.In light of this,it is essential to harness technological innovation to enhance the level of innovation and R&D efficiency in industries to facilitate the transition of traditional industries into high-value-added and emerging ones.Meanwhile,tailored technological innovation strategies should be implemented to boost a balanced industrial structural transformation within industries.
文摘A simple model of the closely packed structure for system of hard-sphere particles interacting via the long-range Newtonian type attraction is suggested. Based on density functional theory, the exact equation of state is obtained and the mutual transformations of the crystal structures in such systems are studied. The description takes into account the fact impossibility of hard-sphere particles which have the same spatial occupation place.
文摘The latest economic data released by China’s National Bureau of Statistics for April 2025 underscores the country’s robust economic recovery and structural transformation.Industrial production surged by 6.1 percent year on year,propelled by breakthroughs in advanced manufacturing,from high-tech industries to cutting-edge equipment sectors.
文摘In order to investigate the ion irradiation effect on the corrosion behavior and microstructure of Zircaloy-4, the Zircaloy-4 film were prepared by electron beam deposition on the Zircaloy-4 specimen surface and irradiated by Kr ions using an accelerator at an energy of 300 keV with the dose from 1×1015 to 3×1016ions/cm2. The post-irradiation corrosion tests were conducted to rank the corrosion resistance of the resulting specimens by potentiodynamic polarization curve measurements in a 0.5 mol/L H2SO4 water so- lution at room temperature. Transmission electron microscopy (TEM) was employed to examine the microstructural change in the surface. The potentiodynamic tests show that with the irradiation dose increasing, the passive current density, closely related to the surface corrosion resistance, decreases firstly and increases subsequently. The mechanism of the corrosion behavior transformation is due to the amorphous phase formation firstly and the amorphous phase destruction and the polycrystalline structure formation in the irradiated surface subsequently.
基金the phased result of the general project“Analysis of the Impact of Shandong Province’s Two-Way Investment on the Transformation and Upgrading of Industrial Structure under the Background of‘High-Quality Development’”and the 2020 Shandong Province Key R&D Program(Soft Science Project)(Project Number:2020RKB01339).
文摘This paper uses the panel data of 17 cities in Shandong Province from 2003 to 2018 to construct a panel model to empirically study the impact of foreign direct investment(FDI)on the industrial structure.The results show that two-way investment,financial industry development,and policy variables have significant roles in promoting the advancement of the industrial structure in the province.In the future implementation of the“Going Global”strategy in Shandong Province,the cooperation between two-way investment and the financial industry should be strengthened,the level of regional financial development should be improved,and the impact of two-way investment on the optimization and upgrading of the industrial structure should be reinforced.
文摘The character of structural changes in the surface layer of titanium carbide （TiC） with Ni-Cr alloy binder was investigated theoretically and experimentally after electron-beam treatment of the material surface. The thermal influence of the electron-beam irradiation on the surface layer microstructure of the composite fine-grained material was mathematically analyzed. Quantitative estimations of the depth of the zone in microstructural phase transformations were carried out. The microstructure and concentration profile of Ti distribution in the metallic binder over the cross section of the surface layer with microstructural phase transformations after electron-pulse treatment of the hard metal surface were experimentally investigated.
基金the financial support from the National Natual Science Foundation of China(No.51375491)the Natural Science Foundation of Chongqing(Project No.2011JJA90020)the Science Foundation for Young Teachers of Logistical Engineering University
文摘The oxidation behavior of three biodiesels of different origins,viz.rapeseed oil derived biodiesel,soybean oil derived biodiesel and waste oil based biodiesel,were tested on an oxidation tester.The chemical compositions of the biodiesels were characterized by gas chromatography.Thereafter,the structural transformation of fatty acid methyl ester(FAME)of the biodiesels was analyzed by an infrared spectrometer and an ultraviolet absorption spectrometer.The results demonstrated that the oxidation behavior of biodiesels of different origins was closely related to the composition and distribution of FAMEs.Higher concentration of unsaturated FAME with multi-double bonds exhibited poorer oxidation resistance.Furthermore,cis-trans isomerization transformation occurred in the unsaturated FAME molecules and conjugated double-bond produced during the oxidation process of biodiesel.Greater cis-trans variations corresponded to deeper oxidation degree.The higher the content of unsaturated FAME with multi-double bonds in a biodiesel,the more the conjugated double bonds was formed.
