This paper uses the ARW-WRF model to carry out a numerical simulation of a warm-sector heavy rainfall event over southern China on the 22-23 May, 2014. A composite analysis method was used to analyze the evolution pro...This paper uses the ARW-WRF model to carry out a numerical simulation of a warm-sector heavy rainfall event over southern China on the 22-23 May, 2014. A composite analysis method was used to analyze the evolution process and structural features of the convective cells on a convection line during this rainfall event. This analysis identified three stages:(1) Stage of activation: the equivalent potential temperature surfaces as lower layers start to bulge and form warm cells and weak vertical convective cloud towers which are subject to the impact of low-level warm moist updrafts in the rainfall sector;(2) Stage of development: the warm cells continue to bulge and form warm air columns and the convective cloud towers develop upwards becoming stronger as they rise;(3) Stage of maturity: the warm air columns start to connect with the stable layer in the upper air; the convective cloud tower will bend and tilt westward with each increasing in height, and the convection cell is characterized by a "crescent-shaped echo" above the 700 h Pa plane. During this stage the internal temperature of the cell is higher than the ambient temperature and the dynamic structural field is manifested as intensive vertical upward movement. The large-value centers of the northerly and westerly winds in the middle layer correspond to the warm moist center in the cells and the relatively cold center south of the warm air column. Further analysis shows that the formation of the "crescent-shaped" convective cell is associated with horizontal vorticity. Horizontal vorticity in the center and west of the warm cell experiences stronger cyclonic and anticyclonic shear transformation over time; this not only causes the original suborbicular cell echo shape to develop into a crescent-like shape, but also makes a convection line consisting of cells that develop to the northwest.展开更多
With the development of information fusion,knowledge graph completion tasks have received a lot of attention.some studies investigate the broader underlying problems of linguistics,while embedding learning has a narro...With the development of information fusion,knowledge graph completion tasks have received a lot of attention.some studies investigate the broader underlying problems of linguistics,while embedding learning has a narrow focus.This poses significant challenges due to the heterogeneity of coarse-graining patterns.Then,to settle the whole matter,a framework for completion is designed,named Triple Encoder-Scoring Module(TEsm).The model employs an alternating two-branch structure that fuses local features into the interaction pattern of the triplet itself by perfectly combining distance and structure models.Moreover,it is mapped to a uniform shared space.Upon completion,an ensemble inference method is proposed to query multiple predictions from different graphs using a weight classifier.Experiments show that the experimental dataset used for the completion task is DBpedia,which contains five different linguistic subsets..Our extensive experimental results demonstrate that TEsm can efficiently and smoothly solve the optimal completion task,validating the performance of the proposed model.展开更多
The daily 1°× 1° data of the Aviation （AVN） model, the black body temperature （TBB） data of cloud top, and cloud images by geostationary meteorological satellite （GMS） are used to identify a dew-p...The daily 1°× 1° data of the Aviation （AVN） model, the black body temperature （TBB） data of cloud top, and cloud images by geostationary meteorological satellite （GMS） are used to identify a dew-point front near the periphery of the western Pacific subtropical high （WPSH）. The results clearly demonstrate the existence of the dew-point front, and its thermodynamic and dynamic structural characteristics are analyzed in detail. The dew-point front is a transitional belt between the moist southwest monsoon flow and the dry adiabatic sinking flow near the WPSH, manifested by a large horizontal moisture gradient in the mid-lower troposphere and conjugated with the mei-yu front to form a predominant double-front structure associated with intense rainfall in the mei-yu period. The mei-yu front is located between 30° and 35°N, vertically extends from the ground level to the upper level and shifts northward. The dew-point front is to the south of the mei-yu front and lies up against the periphery of the WPSH. Generally, it is located between 850 hPa and 500 hPa. On the dew-point front side, the southwesterly prevails at the lower level and the northeasterly at the upper level; this wind distribution is different from that on the mei-yu front side. Vertical ascending motion exists between the two fronts, and there are descending motions on the north side of the mei^yu front and on the south side of the dew-point front~ which form a secondary circulation. The dynamics of the double fronts also have some interesting features. At the lower level, positive vertical vorticity and obvious convergence between the two fronts are clearly identified. At the mid-lower level, negative local change of the divergence （corresponding to increasing convergence） is often embedded in the two fronts or against the mei-yu front. Most cloud clusters occur between the two fronts and propagate down stream in a wave-like manner.展开更多
Structure features play an important role in machine learning models for the materials investigation.Here,two topology-based features for the representation of material structure,specifically structure graph and algeb...Structure features play an important role in machine learning models for the materials investigation.Here,two topology-based features for the representation of material structure,specifically structure graph and algebraic topology,are introduced.We present the fundamental mathematical concepts underlying these techniques and how they encode material properties.Furthermore,we discuss the practical applications and enhancements of these features made in specific material predicting tasks.This review may provide suggestions on the selection of suitable structural features and inspire creativity in developing robust descriptors for diverse applications.展开更多
The Deep Seismic Sounding( DSS) projects carried out from the 1970 s in the lower Yangtze region and its neighboring area were reviewed in this paper,then the basic wave group features of those wide angle reflection /...The Deep Seismic Sounding( DSS) projects carried out from the 1970 s in the lower Yangtze region and its neighboring area were reviewed in this paper,then the basic wave group features of those wide angle reflection / refraction record sections,and of the crustal structure are summarized. It shows that there were in total five clear wave groups on the record sections,which include the first arrival Pg,the reflection P1 from the bottom interface of the upper crust,the reflection P3 from the bottom interface of the middle crust,the strong reflection Pm from the Moho boundary,and the refraction Pn from uppermost mantle. In general,these phases are easily consistently traced and compared,despite some first arrivals being delayed or arriving earlier than normal due to the shallow sedimentary cover or bedrocks. In particular,in the Dabie Mountain region the seismic events of a few gathered shots always have weak reflection energy,are twisted,or exhibit disorganized waveforms, which could be attributed to the disruption variations of reflection depth,the broken Moho,and the discontinuity of the reflection boundary within crust. The regional crustal structures are composed of the upper,middle and lower crust,of which the middle and lower layers can be divided into two weak reflection ones. The crustal thickness of the North China and Yangtze platform are 30km- 36 km,and the Moho exhibits a flat geometry despite some local uplifts. The average pressure velocity in lower crust beneath this two tectonic area is 6. 7 ± 0. 3km / s. Nevertheless,beneath the Dabieshan area the crustal thickness is 32km- 41 km,the Moho bends down sharply andtakes an abrupt 4km- 7km dislocation in the vertical direction. The average pressure velocity in the lower crust beneath the Dabieshan area is 6. 8 ± 0. 2km / s.展开更多
1 Introduction The huize Zn-Pb ore district in Yunnan province is locatedinthecentralsouthernofthe Sichuan—Yunnan—GuizhouPb-ZnPoly-metallic Mineralization Area in the southwestern margin of the Yangtze Block,and is ...1 Introduction The huize Zn-Pb ore district in Yunnan province is locatedinthecentralsouthernofthe Sichuan—Yunnan—GuizhouPb-ZnPoly-metallic Mineralization Area in the southwestern margin of the Yangtze Block,and is strictly controlled by fault structures.It has developed to one of the famous production bases of lead&zinc and germanium in China.展开更多
Additive manufacturing(AM)has made significant progress in recent years and has been successfully applied in various fields owing to its ability to manufacture complex geometries.This method efficiently expands the de...Additive manufacturing(AM)has made significant progress in recent years and has been successfully applied in various fields owing to its ability to manufacture complex geometries.This method efficiently expands the design space,allowing for the creation of products with better performance than ever before.With the emergence of new manufacturing technologies,new design methods are required to efficiently utilize the expanded design space.Therefore,topology optimization methods have attracted the attention of researchers because of their ability to generate new and optimized designs without requiring prior experience.The combination of AM and topology optimization has proven to be a powerful tool for structural innovation in design and manufacturing.However,it is important to note that AM does not eliminate all manufacturing restrictions but instead replaces them with a different set of design considerations that designers must consider for the successful implementation of these technologies.This has motivated research on topology optimization methods that incorporate manufacturable constraints for AM structures.In this paper,we present a survey of the latest studies in this research area,with a particular focus on developments in China.Additionally,we discuss the existing research gaps and future development trends.展开更多
The catalyst layers(CLs) electrode is the key component of the membrane electrode assembly(MEA) in proton exchange membrane fuel cells(PEMFCs). Conventional electrodes for PEMFCs are composed of carbon-supported, iono...The catalyst layers(CLs) electrode is the key component of the membrane electrode assembly(MEA) in proton exchange membrane fuel cells(PEMFCs). Conventional electrodes for PEMFCs are composed of carbon-supported, ionomer, and Pt nanoparticles, all immersed together and sprayed with a micron-level thickness of CLs. They have a performance trade-off where increasing the Pt loading leads to higher performance of abundant triple-phase boundary areas but increases the electrode cost. Major challenges must be overcome before realizing its wide commercialization. Literature research revealed that it is impossible to achieve performance and durability targets with only high-performance catalysts, so the controllable design of CLs architecture in MEAs for PEMFCs must now be the top priority to meet industry goals. From this perspective, a 3D ordered electrode circumvents this issue with a support-free architecture and ultrathin thickness while reducing noble metal Pt loadings. Herein, we discuss the motivation in-depth and summarize the necessary CLs structural features for designing ultralow Pt loading electrodes. Critical issues that remain in progress for 3D ordered CLs must be studied and characterized. Furthermore, approaches for 3D ordered CLs architecture electrode development, involving material design, structure optimization, preparation technology, and characterization techniques, are summarized and are expected to be next-generation CLs for PEMFCs. Finally, the review concludes with perspectives on possible research directions of CL architecture to address the significant challenges in the future.展开更多
The Kyushu–Palau Ridge(KPR),an anti-S-shaped submarine highland at the center of the Philippine Sea Plate(PSP),is considered the residual arc of the Izu–Bonin–Mariana Island Arc,which retains key information about ...The Kyushu–Palau Ridge(KPR),an anti-S-shaped submarine highland at the center of the Philippine Sea Plate(PSP),is considered the residual arc of the Izu–Bonin–Mariana Island Arc,which retains key information about the cessation of the Western Philippine Basin(WPB)expansion and the Parece Vela Basin(PVB)breakup.Herein,using the new generation of satellite altimetry gravity data,high-precision seafloor topography data,and newly acquired ship-borne gravity data,the topographic and gravity characteristics of the KPR mid-southern section and adjacent region are depicted.The distribution characteristics of the faults were delineated using the normalized vertical derivative–total horizontal derivative method(NVDR-THDR)and the minimum curvature potential field separation method.The Moho depth and crustal thickness were inverted using the rapid inversion method for a double-interface model with depth constraints.Based on these results,the crust structure features in the KPR mid-southern section,and the“triangular”structure geological significance where the KPR and Central Basin Rift(CBR)of the WPB intersect are interpreted.The KPR crustal thickness is approximately 6–16 km,with a distinct discontinuity that is slightly thicker than the normal oceanic crust.The KPR mid-southern section crust structure was divided into four segments(S1–S4)from north to south,formed by the CBR eastward extension joint action and clockwise rotation of the PVB expansion axis and the Mindanao fault zone blocking effect.展开更多
Structure features need complicated pre-processing, and are probably domain-dependent. To reduce time cost of pre-processing, we propose a novel neural network architecture which is a bi-directional long-short-term-me...Structure features need complicated pre-processing, and are probably domain-dependent. To reduce time cost of pre-processing, we propose a novel neural network architecture which is a bi-directional long-short-term-memory recurrent-neural-network（Bi-LSTM-RNN） model based on low-cost sequence features such as words and part-of-speech（POS） tags, to classify the relation of two entities. First, this model performs bi-directional recurrent computation along the tokens of sentences. Then, the sequence is divided into five parts and standard pooling functions are applied over the token representations of each part. Finally, the token representations are concatenated and fed into a softmax layer for relation classification. We evaluate our model on two standard benchmark datasets in different domains, namely Sem Eval-2010 Task 8 and Bio NLP-ST 2016 Task BB3. In Sem Eval-2010 Task 8, the performance of our model matches those of the state-of-the-art models, achieving 83.0% in F1. In Bio NLP-ST 2016 Task BB3, our model obtains F1 51.3% which is comparable with that of the best system. Moreover, we find that the context between two target entities plays an important role in relation classification and it can be a replacement of the shortest dependency path.展开更多
In this paper, a series of Sb-doped and Bi-doped Cu_(2)Sn_(1-x)M_(x)Se_(3) samples(M = Sb, Bi) are prepared by vacuum melting combined with the spark plasma sintering process. The effects of different atomic doping am...In this paper, a series of Sb-doped and Bi-doped Cu_(2)Sn_(1-x)M_(x)Se_(3) samples(M = Sb, Bi) are prepared by vacuum melting combined with the spark plasma sintering process. The effects of different atomic doping amounts on their properties are discussed. Structural studies indicate that all obtained samples comprise a single Cu_(2)SnSe_(3) phase. Sb and Bi atoms are experimentally demonstrated to be efficient cation dopants for increasing the transport performance. Compared with that doping on the cation site,Bi doping is much more efficient in increasing the electron concentration of the Cu_(2)SnSe_(3) system. Ultimately, a high figure of merit of 0.36 is achieved in the Cu_(2)Sn_(0.94)Sb_(0.06) Se_(3) sample at 773 K due to the enhanced power factor and lowered lattice thermal conductivity,which are 1.73 times higher than those of the pure sample.Our results provide an efficient approach to enhance thermoelectric performance via other doping atoms, which could also be applied to copper-based chalcogenide materials.展开更多
Based on the definition of a logic structure feature to relate logically functional requirements to geometric representation independent upon detailed geometric representation, this paper presents an idea of logical s...Based on the definition of a logic structure feature to relate logically functional requirements to geometric representation independent upon detailed geometric representation, this paper presents an idea of logical structure modeling for computer aided conceptual design and makes attempt to establish a representation formalism of logic structure modeling. The definition and representation of logical structure feature are given and an assembly module definition for supporting top down conceptual design is also proposed. The proposed scheme contributes to several aspects of conceptual design research, especially to provide elementarily a formal methodology for computer aided conceptual design system development and operation.展开更多
The south coastal of Taizhou lies on the magmatic rock belt along the southeast coast of China,which has a complex regional geological structures,intense tectonic movement,and frequent magmatic activities.On the basis...The south coastal of Taizhou lies on the magmatic rock belt along the southeast coast of China,which has a complex regional geological structures,intense tectonic movement,and frequent magmatic activities.On the basis of the latest aeromagnetic data,combined with regional geology,gravity,and magnetic susceptibility information,integrated interpretation of the regional aeromagnetic anomalies and their refl ected faults was completed.According to the block features in diff erent zones of the reduction to the pole aeromagnetic data,the magnetic field characteristics and relationship with the structure division were described in detail.The different characteristics of the magnetic field are the concentrated reflection of tectonic movements,magmatic activities,and stratigraphic distributions;the fault structure,especially deep and large fault structures,was inferred and studied.The fault structures were mainly distributed in the NE,NNE,and NW directions,with approximately equal spacing between them.The magnetic anomaly is mainly characterized by the boundary,gradient zones,and beaded anomalies in a different magnetic field.The faults are not only important tectonic boundaries in this region but also tectonic belts that control the distribution of mineralization.Under the interaction of these faults,they form the basic structural pattern of the east-west zone and the north-south block.The NE faults have the largest scale and obviously control the diff erent magnetic fi elds and magmatic activities.The results can provide a reference for further study of the distribution and activity characteristics of magmatic rocks in the coastal zone.展开更多
The ring has been a romantic fascination throughout the ages,embodying not only beauty and order but also harboring numerous undisclosed properties awaiting discovery.In the realm of supramolecular chemistry,macrocycl...The ring has been a romantic fascination throughout the ages,embodying not only beauty and order but also harboring numerous undisclosed properties awaiting discovery.In the realm of supramolecular chemistry,macrocycles,with a cyclic structure and a central cavity like a doughnut,captivate the attention of scientists[1].In 1967,Pedersen's groundbreaking revelation that alkali metal ions could"fall into"the cavities of a cyclic ether named crown ether,even in organic solvents,unveiled a novel universe of macrocycle chemistry.Since then,numerous macrocyclic structures in nature have been discovered,isolated,and scrutinized.Drawing inspiration from nature,chemists endeavor to explore the vast potential of macrocyclic compounds by designing and synthesizing artificial macrocycles with diverse structural features and recognition properties.展开更多
As a vectorial property,polarization encodes high-dimensional information of light.Polarization-based imaging can characterize detailed structural features of biomedical samples label-freely.However,compared with othe...As a vectorial property,polarization encodes high-dimensional information of light.Polarization-based imaging can characterize detailed structural features of biomedical samples label-freely.However,compared with other fundamental properties of light,such as intensity,wavelength and phase,polarization has a shorter application history in biomedicine,because of the requirement for both advanced polarization optical components and computational approaches,which can be achieved nowadays with the fast theoretical and hardware development.展开更多
A recent paper published in Journal of the American Chemical Society by W.Zhang and co-workers reported a ground-breaking advance by establishing 209 Bi and 127 I ultra-wideline solid-state NMR(UW SSNMR)as powerful to...A recent paper published in Journal of the American Chemical Society by W.Zhang and co-workers reported a ground-breaking advance by establishing 209 Bi and 127 I ultra-wideline solid-state NMR(UW SSNMR)as powerful tools for probing bismuth and iodine ions in metal-organic frameworks(MOFs),despite the severe challenges associated with their exceptionally large quadrupolar interactions,and enabled the elucidation of key structural features that are otherwise difficult to access[1].展开更多
Covalent organic frameworks(COFs)semiconductor materials have garnered significant attention in solar to chemical energy conversion owing to their unique properties,including structural tunability,pre-design capabilit...Covalent organic frameworks(COFs)semiconductor materials have garnered significant attention in solar to chemical energy conversion owing to their unique properties,including structural tunability,pre-design capability,large surface area,abundant pore structures,high crystallinity,excellent chemical stability,suitable energy-band structure,fast charge carrier transfer and so on.These intrinsic features endow COFs with the remarkable candidates for various photocatalytic applications including photocatalytic H_(2) generation from water reduction,CO_(2) reduction,degradation of organic pollutants,N_(2) fixation,H_(2)O_(2) evolution,and even organic synthesis.Here,this review comprehensively summarizes the recent advancements in COF-based materials for the above photocatalytic reactions,including the historic overview of the COF in the photocatalysis field,the fundamentals and design philosophy of COF-based photocatalysts,the advances of synthesis strategies,the structural characteristics and diversities,the practical applications in various photocatalytic fields as well as the challenges and future development direction in terms of COFs material and application perspectives.We sincerely hope this review can offer symbolic guidelines for future development COF semiconductor materials in this promising field.展开更多
A squall line on 14 June 2009 in the provinces of Jiangsu and Anhui was well simulated using the Advanced Regional Prediction System （ARPS） model. Based on high resolution spatial and temporal data, a detailed analy...A squall line on 14 June 2009 in the provinces of Jiangsu and Anhui was well simulated using the Advanced Regional Prediction System （ARPS） model. Based on high resolution spatial and temporal data, a detailed analysis of the structural features and propagation mechanisms of the squall line was conducted. The dynamic and thermodynamic structural charac- teristics and their causes were analyzed in detail. Unbalanced flows were found to play a key role in initiating gravity waves during the squall line＇s development. The spread and development of the gravity waves were sustained by convection in the wave-CISK process. The squall line＇s propagation and development mainly relied on the combined effect of gravity waves at the midlevel and cold outflow along the gust front. New cells were continuously forced by the cold pool outflow and were enhanced and lifted by the intense upward motion. At a particular phase, the new cells merged with the updraft of the gravity waves, leading to an intense updraft that strengthened the squall line.展开更多
Fushun oil shale(FOS) was subjected to thermal dissolution(TD) under different conditions. The results show that the optimal solvent, temperature, time, and ratio of solvent to FOS are ethanol, 300 °C, 2 h, and 5...Fushun oil shale(FOS) was subjected to thermal dissolution(TD) under different conditions. The results show that the optimal solvent, temperature, time, and ratio of solvent to FOS are ethanol, 300 °C, 2 h, and 5 ml·g^(-1),respectively and the corresponding yield of the soluble portion(SP) is 32.2%(daf), which is much higher than the oil content of FOS(ca. 6%), suggesting that TD in ethanol is an excellent way to extract organics from FOS.According to 3 direct analyses, aliphatic moieties in FOS are the most abundant followed by C\\O-containing moieties and each cluster in FOS has 3 conjugated aromatic rings on average with fewer substituents. According to the analysis with a gas chromatograph/mass spectrometer, alkanes are predominant in all the SPs. A number of alkenes were identified in the SPs from the TD, while none of the alkenes were detected in acetone-SP obtained at room temperature, implying that the TD can destroy the π-π and intertwining interactions between alkenes and macromolecular structures in FOS. Moreover, a small amount of alkyl-substituted phenols and alkoxysubstituted phenols were detected in ethanol-SP from the TD, which could be the products from ethanolyzing the macromolecular moiety of FOS.展开更多
In order to expand the advantages of strong durability and high compressive strength of calcium silicate hydrates(C-S-H),at the same time to make up for the poor early mechanical strength of magnesium silicate hydrate...In order to expand the advantages of strong durability and high compressive strength of calcium silicate hydrates(C-S-H),at the same time to make up for the poor early mechanical strength of magnesium silicate hydrates (M-S-H),we present the features and advantages of C-S-H and M-S-H and a comprehensive review of the progress on CaO-MgO-SiO_(2)-H_(2)O.Moreover,we systematically describe natural calcium and magnesium silicate minerals and thermodynamic properties of CaO-MgO-SiO_(2)-H_(2)O.The effect of magnesium on C-S-H and calcium on M-S-H is summarized deeply;the formation and structural feature of CaO-MgO-SiO_(2)-H_(2)O is also explained in detail.Finally,the development of calcium and magnesium silicate hydrates in the future is pointed out,and the further research is discussed and estimated.展开更多
基金National Basic Research Program of China(Project 973:2013CB430103)National Natural Science Foundation of China(41530427)+1 种基金Chinese Academy of Meteorological Sciences(2015LASW-A07)State Key Laboratory of Severe Weather,Chinese Academy of Meteorological Sciences
文摘This paper uses the ARW-WRF model to carry out a numerical simulation of a warm-sector heavy rainfall event over southern China on the 22-23 May, 2014. A composite analysis method was used to analyze the evolution process and structural features of the convective cells on a convection line during this rainfall event. This analysis identified three stages:(1) Stage of activation: the equivalent potential temperature surfaces as lower layers start to bulge and form warm cells and weak vertical convective cloud towers which are subject to the impact of low-level warm moist updrafts in the rainfall sector;(2) Stage of development: the warm cells continue to bulge and form warm air columns and the convective cloud towers develop upwards becoming stronger as they rise;(3) Stage of maturity: the warm air columns start to connect with the stable layer in the upper air; the convective cloud tower will bend and tilt westward with each increasing in height, and the convection cell is characterized by a "crescent-shaped echo" above the 700 h Pa plane. During this stage the internal temperature of the cell is higher than the ambient temperature and the dynamic structural field is manifested as intensive vertical upward movement. The large-value centers of the northerly and westerly winds in the middle layer correspond to the warm moist center in the cells and the relatively cold center south of the warm air column. Further analysis shows that the formation of the "crescent-shaped" convective cell is associated with horizontal vorticity. Horizontal vorticity in the center and west of the warm cell experiences stronger cyclonic and anticyclonic shear transformation over time; this not only causes the original suborbicular cell echo shape to develop into a crescent-like shape, but also makes a convection line consisting of cells that develop to the northwest.
基金Supported by Science and Technology Innovation Action Plan"of Shanghai Science and Technology Commission for Social Development Project(21DZ1204900)。
文摘With the development of information fusion,knowledge graph completion tasks have received a lot of attention.some studies investigate the broader underlying problems of linguistics,while embedding learning has a narrow focus.This poses significant challenges due to the heterogeneity of coarse-graining patterns.Then,to settle the whole matter,a framework for completion is designed,named Triple Encoder-Scoring Module(TEsm).The model employs an alternating two-branch structure that fuses local features into the interaction pattern of the triplet itself by perfectly combining distance and structure models.Moreover,it is mapped to a uniform shared space.Upon completion,an ensemble inference method is proposed to query multiple predictions from different graphs using a weight classifier.Experiments show that the experimental dataset used for the completion task is DBpedia,which contains five different linguistic subsets..Our extensive experimental results demonstrate that TEsm can efficiently and smoothly solve the optimal completion task,validating the performance of the proposed model.
基金projects of the National Natural Science Foundation of China(Grant Nos.40405007 , 40505009)the National Key Basic Research and Development Project of China(Grant No.2004CB418302) projects of Chinese Academy of Sciences (Nos.KZCX3-SW-225 and 2005r-2-16)
文摘The daily 1°× 1° data of the Aviation （AVN） model, the black body temperature （TBB） data of cloud top, and cloud images by geostationary meteorological satellite （GMS） are used to identify a dew-point front near the periphery of the western Pacific subtropical high （WPSH）. The results clearly demonstrate the existence of the dew-point front, and its thermodynamic and dynamic structural characteristics are analyzed in detail. The dew-point front is a transitional belt between the moist southwest monsoon flow and the dry adiabatic sinking flow near the WPSH, manifested by a large horizontal moisture gradient in the mid-lower troposphere and conjugated with the mei-yu front to form a predominant double-front structure associated with intense rainfall in the mei-yu period. The mei-yu front is located between 30° and 35°N, vertically extends from the ground level to the upper level and shifts northward. The dew-point front is to the south of the mei-yu front and lies up against the periphery of the WPSH. Generally, it is located between 850 hPa and 500 hPa. On the dew-point front side, the southwesterly prevails at the lower level and the northeasterly at the upper level; this wind distribution is different from that on the mei-yu front side. Vertical ascending motion exists between the two fronts, and there are descending motions on the north side of the mei^yu front and on the south side of the dew-point front~ which form a secondary circulation. The dynamics of the double fronts also have some interesting features. At the lower level, positive vertical vorticity and obvious convergence between the two fronts are clearly identified. At the mid-lower level, negative local change of the divergence （corresponding to increasing convergence） is often embedded in the two fronts or against the mei-yu front. Most cloud clusters occur between the two fronts and propagate down stream in a wave-like manner.
基金support from the Guangdong Basic and Applied Basic Research Foundation(2020A1515110843),Young S&T Talent Training Program of Guangdong Provincial Association for S&T(SKXRC202211)Chemistry and Chemical Engineering Guangdong Laboratory(1922018)+3 种基金Soft Science Research Project of Guangdong Province(2017B030301013)National Natural Science Foundation of China(22109003)Natural Science Foundation of Shenzhen(JCYJ20190813110605381)the Major Science and Technology Infrastructure Project of Material Genome Big-science Facilities Platform supported by Municipal Development and Reform Commission of Shenzhen.
文摘Structure features play an important role in machine learning models for the materials investigation.Here,two topology-based features for the representation of material structure,specifically structure graph and algebraic topology,are introduced.We present the fundamental mathematical concepts underlying these techniques and how they encode material properties.Furthermore,we discuss the practical applications and enhancements of these features made in specific material predicting tasks.This review may provide suggestions on the selection of suitable structural features and inspire creativity in developing robust descriptors for diverse applications.
基金funded by the Special Public Welfare Industry Research of China Earthquake Administration(201408023)Academician Chen Yong Workstation Special Funds of Yunnan Province and Natural Science Foundation of China(41374062,41174075)
文摘The Deep Seismic Sounding( DSS) projects carried out from the 1970 s in the lower Yangtze region and its neighboring area were reviewed in this paper,then the basic wave group features of those wide angle reflection / refraction record sections,and of the crustal structure are summarized. It shows that there were in total five clear wave groups on the record sections,which include the first arrival Pg,the reflection P1 from the bottom interface of the upper crust,the reflection P3 from the bottom interface of the middle crust,the strong reflection Pm from the Moho boundary,and the refraction Pn from uppermost mantle. In general,these phases are easily consistently traced and compared,despite some first arrivals being delayed or arriving earlier than normal due to the shallow sedimentary cover or bedrocks. In particular,in the Dabie Mountain region the seismic events of a few gathered shots always have weak reflection energy,are twisted,or exhibit disorganized waveforms, which could be attributed to the disruption variations of reflection depth,the broken Moho,and the discontinuity of the reflection boundary within crust. The regional crustal structures are composed of the upper,middle and lower crust,of which the middle and lower layers can be divided into two weak reflection ones. The crustal thickness of the North China and Yangtze platform are 30km- 36 km,and the Moho exhibits a flat geometry despite some local uplifts. The average pressure velocity in lower crust beneath this two tectonic area is 6. 7 ± 0. 3km / s. Nevertheless,beneath the Dabieshan area the crustal thickness is 32km- 41 km,the Moho bends down sharply andtakes an abrupt 4km- 7km dislocation in the vertical direction. The average pressure velocity in the lower crust beneath the Dabieshan area is 6. 8 ± 0. 2km / s.
基金supported by the Funds for the program of the National Natural Science Foundation (Noes. 41572060, U1133602)Projects of YM Lab (2011)Innovation Team of Yunnan province and KMUST (2008,2012)
文摘1 Introduction The huize Zn-Pb ore district in Yunnan province is locatedinthecentralsouthernofthe Sichuan—Yunnan—GuizhouPb-ZnPoly-metallic Mineralization Area in the southwestern margin of the Yangtze Block,and is strictly controlled by fault structures.It has developed to one of the famous production bases of lead&zinc and germanium in China.
基金supported by National Natural Science Foundation of China(Grant Nos.12272076,U2341232,11332004,and U1808215)the 111 Project of China(Grant No.B14013).
文摘Additive manufacturing(AM)has made significant progress in recent years and has been successfully applied in various fields owing to its ability to manufacture complex geometries.This method efficiently expands the design space,allowing for the creation of products with better performance than ever before.With the emergence of new manufacturing technologies,new design methods are required to efficiently utilize the expanded design space.Therefore,topology optimization methods have attracted the attention of researchers because of their ability to generate new and optimized designs without requiring prior experience.The combination of AM and topology optimization has proven to be a powerful tool for structural innovation in design and manufacturing.However,it is important to note that AM does not eliminate all manufacturing restrictions but instead replaces them with a different set of design considerations that designers must consider for the successful implementation of these technologies.This has motivated research on topology optimization methods that incorporate manufacturable constraints for AM structures.In this paper,we present a survey of the latest studies in this research area,with a particular focus on developments in China.Additionally,we discuss the existing research gaps and future development trends.
基金funded by the Natural Science Foundation of Shandong Province, China (ZR2023MB049)the China Postdoctoral Science Foundation (2020M670483)the Science Foundation of Weifang University (2023BS11)。
文摘The catalyst layers(CLs) electrode is the key component of the membrane electrode assembly(MEA) in proton exchange membrane fuel cells(PEMFCs). Conventional electrodes for PEMFCs are composed of carbon-supported, ionomer, and Pt nanoparticles, all immersed together and sprayed with a micron-level thickness of CLs. They have a performance trade-off where increasing the Pt loading leads to higher performance of abundant triple-phase boundary areas but increases the electrode cost. Major challenges must be overcome before realizing its wide commercialization. Literature research revealed that it is impossible to achieve performance and durability targets with only high-performance catalysts, so the controllable design of CLs architecture in MEAs for PEMFCs must now be the top priority to meet industry goals. From this perspective, a 3D ordered electrode circumvents this issue with a support-free architecture and ultrathin thickness while reducing noble metal Pt loadings. Herein, we discuss the motivation in-depth and summarize the necessary CLs structural features for designing ultralow Pt loading electrodes. Critical issues that remain in progress for 3D ordered CLs must be studied and characterized. Furthermore, approaches for 3D ordered CLs architecture electrode development, involving material design, structure optimization, preparation technology, and characterization techniques, are summarized and are expected to be next-generation CLs for PEMFCs. Finally, the review concludes with perspectives on possible research directions of CL architecture to address the significant challenges in the future.
基金‘Research on Deep Structural Differences between Potential Oil-rich Depressions in Offshore basins of China Sea’from the scientific and technological project of CNOOC Research Institute Co.,Ltd.,under contract No.CCL2021RCPS0167KQN‘Resource Potential,Accumulation Mechanism and Breakthrough Direction of Potential Oil-rich Depressions in Offshore China Sea’,under contract No.220226220101+1 种基金the Project of China Geological Survey under contract No.DD20191003the National Natural Science Foundation of Shandong Province of China under contract No.ZR2022MD047。
文摘The Kyushu–Palau Ridge(KPR),an anti-S-shaped submarine highland at the center of the Philippine Sea Plate(PSP),is considered the residual arc of the Izu–Bonin–Mariana Island Arc,which retains key information about the cessation of the Western Philippine Basin(WPB)expansion and the Parece Vela Basin(PVB)breakup.Herein,using the new generation of satellite altimetry gravity data,high-precision seafloor topography data,and newly acquired ship-borne gravity data,the topographic and gravity characteristics of the KPR mid-southern section and adjacent region are depicted.The distribution characteristics of the faults were delineated using the normalized vertical derivative–total horizontal derivative method(NVDR-THDR)and the minimum curvature potential field separation method.The Moho depth and crustal thickness were inverted using the rapid inversion method for a double-interface model with depth constraints.Based on these results,the crust structure features in the KPR mid-southern section,and the“triangular”structure geological significance where the KPR and Central Basin Rift(CBR)of the WPB intersect are interpreted.The KPR crustal thickness is approximately 6–16 km,with a distinct discontinuity that is slightly thicker than the normal oceanic crust.The KPR mid-southern section crust structure was divided into four segments(S1–S4)from north to south,formed by the CBR eastward extension joint action and clockwise rotation of the PVB expansion axis and the Mindanao fault zone blocking effect.
基金Supported by the China Postdoctoral Science Foundation(2014T70722)the Humanities and Social Science Foundation of Ministry of Education of China(16YJCZH004)
文摘Structure features need complicated pre-processing, and are probably domain-dependent. To reduce time cost of pre-processing, we propose a novel neural network architecture which is a bi-directional long-short-term-memory recurrent-neural-network（Bi-LSTM-RNN） model based on low-cost sequence features such as words and part-of-speech（POS） tags, to classify the relation of two entities. First, this model performs bi-directional recurrent computation along the tokens of sentences. Then, the sequence is divided into five parts and standard pooling functions are applied over the token representations of each part. Finally, the token representations are concatenated and fed into a softmax layer for relation classification. We evaluate our model on two standard benchmark datasets in different domains, namely Sem Eval-2010 Task 8 and Bio NLP-ST 2016 Task BB3. In Sem Eval-2010 Task 8, the performance of our model matches those of the state-of-the-art models, achieving 83.0% in F1. In Bio NLP-ST 2016 Task BB3, our model obtains F1 51.3% which is comparable with that of the best system. Moreover, we find that the context between two target entities plays an important role in relation classification and it can be a replacement of the shortest dependency path.
基金financially supported by the National Key Research and Development Program of China(No.2019YFA0210003)the National Natural Science Foundation of China(Nos.11775163 and 11875208)。
文摘In this paper, a series of Sb-doped and Bi-doped Cu_(2)Sn_(1-x)M_(x)Se_(3) samples(M = Sb, Bi) are prepared by vacuum melting combined with the spark plasma sintering process. The effects of different atomic doping amounts on their properties are discussed. Structural studies indicate that all obtained samples comprise a single Cu_(2)SnSe_(3) phase. Sb and Bi atoms are experimentally demonstrated to be efficient cation dopants for increasing the transport performance. Compared with that doping on the cation site,Bi doping is much more efficient in increasing the electron concentration of the Cu_(2)SnSe_(3) system. Ultimately, a high figure of merit of 0.36 is achieved in the Cu_(2)Sn_(0.94)Sb_(0.06) Se_(3) sample at 773 K due to the enhanced power factor and lowered lattice thermal conductivity,which are 1.73 times higher than those of the pure sample.Our results provide an efficient approach to enhance thermoelectric performance via other doping atoms, which could also be applied to copper-based chalcogenide materials.
文摘Based on the definition of a logic structure feature to relate logically functional requirements to geometric representation independent upon detailed geometric representation, this paper presents an idea of logical structure modeling for computer aided conceptual design and makes attempt to establish a representation formalism of logic structure modeling. The definition and representation of logical structure feature are given and an assembly module definition for supporting top down conceptual design is also proposed. The proposed scheme contributes to several aspects of conceptual design research, especially to provide elementarily a formal methodology for computer aided conceptual design system development and operation.
基金This work was supported by the National Key Research and Development Program of China(2017YFC0601706 and 2017YFC0601705)Investigation and application of airborne geophysical remote sensing in Bohai Coastal Zone(DD20160150).
文摘The south coastal of Taizhou lies on the magmatic rock belt along the southeast coast of China,which has a complex regional geological structures,intense tectonic movement,and frequent magmatic activities.On the basis of the latest aeromagnetic data,combined with regional geology,gravity,and magnetic susceptibility information,integrated interpretation of the regional aeromagnetic anomalies and their refl ected faults was completed.According to the block features in diff erent zones of the reduction to the pole aeromagnetic data,the magnetic field characteristics and relationship with the structure division were described in detail.The different characteristics of the magnetic field are the concentrated reflection of tectonic movements,magmatic activities,and stratigraphic distributions;the fault structure,especially deep and large fault structures,was inferred and studied.The fault structures were mainly distributed in the NE,NNE,and NW directions,with approximately equal spacing between them.The magnetic anomaly is mainly characterized by the boundary,gradient zones,and beaded anomalies in a different magnetic field.The faults are not only important tectonic boundaries in this region but also tectonic belts that control the distribution of mineralization.Under the interaction of these faults,they form the basic structural pattern of the east-west zone and the north-south block.The NE faults have the largest scale and obviously control the diff erent magnetic fi elds and magmatic activities.The results can provide a reference for further study of the distribution and activity characteristics of magmatic rocks in the coastal zone.
文摘The ring has been a romantic fascination throughout the ages,embodying not only beauty and order but also harboring numerous undisclosed properties awaiting discovery.In the realm of supramolecular chemistry,macrocycles,with a cyclic structure and a central cavity like a doughnut,captivate the attention of scientists[1].In 1967,Pedersen's groundbreaking revelation that alkali metal ions could"fall into"the cavities of a cyclic ether named crown ether,even in organic solvents,unveiled a novel universe of macrocycle chemistry.Since then,numerous macrocyclic structures in nature have been discovered,isolated,and scrutinized.Drawing inspiration from nature,chemists endeavor to explore the vast potential of macrocyclic compounds by designing and synthesizing artificial macrocycles with diverse structural features and recognition properties.
文摘As a vectorial property,polarization encodes high-dimensional information of light.Polarization-based imaging can characterize detailed structural features of biomedical samples label-freely.However,compared with other fundamental properties of light,such as intensity,wavelength and phase,polarization has a shorter application history in biomedicine,because of the requirement for both advanced polarization optical components and computational approaches,which can be achieved nowadays with the fast theoretical and hardware development.
基金supported by the National Natural Science Foundation of China(Grants 22472075 and 22272075).
文摘A recent paper published in Journal of the American Chemical Society by W.Zhang and co-workers reported a ground-breaking advance by establishing 209 Bi and 127 I ultra-wideline solid-state NMR(UW SSNMR)as powerful tools for probing bismuth and iodine ions in metal-organic frameworks(MOFs),despite the severe challenges associated with their exceptionally large quadrupolar interactions,and enabled the elucidation of key structural features that are otherwise difficult to access[1].
文摘Covalent organic frameworks(COFs)semiconductor materials have garnered significant attention in solar to chemical energy conversion owing to their unique properties,including structural tunability,pre-design capability,large surface area,abundant pore structures,high crystallinity,excellent chemical stability,suitable energy-band structure,fast charge carrier transfer and so on.These intrinsic features endow COFs with the remarkable candidates for various photocatalytic applications including photocatalytic H_(2) generation from water reduction,CO_(2) reduction,degradation of organic pollutants,N_(2) fixation,H_(2)O_(2) evolution,and even organic synthesis.Here,this review comprehensively summarizes the recent advancements in COF-based materials for the above photocatalytic reactions,including the historic overview of the COF in the photocatalysis field,the fundamentals and design philosophy of COF-based photocatalysts,the advances of synthesis strategies,the structural characteristics and diversities,the practical applications in various photocatalytic fields as well as the challenges and future development direction in terms of COFs material and application perspectives.We sincerely hope this review can offer symbolic guidelines for future development COF semiconductor materials in this promising field.
基金supported by the National Basic Research Program of China (Grant No. 2013CB 430105)the Key Program of the Chinese Academy of Sciences (Grant No. KZZD-EW-05)+1 种基金the project of CAMS (Chinese Academy of Meteorological Sciences) (Grant No. 2011LASWB15)the National Natural Sciences Foundation of China (Grant No. 41175060)
文摘A squall line on 14 June 2009 in the provinces of Jiangsu and Anhui was well simulated using the Advanced Regional Prediction System （ARPS） model. Based on high resolution spatial and temporal data, a detailed analysis of the structural features and propagation mechanisms of the squall line was conducted. The dynamic and thermodynamic structural charac- teristics and their causes were analyzed in detail. Unbalanced flows were found to play a key role in initiating gravity waves during the squall line＇s development. The spread and development of the gravity waves were sustained by convection in the wave-CISK process. The squall line＇s propagation and development mainly relied on the combined effect of gravity waves at the midlevel and cold outflow along the gust front. New cells were continuously forced by the cold pool outflow and were enhanced and lifted by the intense upward motion. At a particular phase, the new cells merged with the updraft of the gravity waves, leading to an intense updraft that strengthened the squall line.
基金Supported by the Fundamental Research Funds for the Central Universities(2017BSCXB27)the Research and the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX17_1507)
文摘Fushun oil shale(FOS) was subjected to thermal dissolution(TD) under different conditions. The results show that the optimal solvent, temperature, time, and ratio of solvent to FOS are ethanol, 300 °C, 2 h, and 5 ml·g^(-1),respectively and the corresponding yield of the soluble portion(SP) is 32.2%(daf), which is much higher than the oil content of FOS(ca. 6%), suggesting that TD in ethanol is an excellent way to extract organics from FOS.According to 3 direct analyses, aliphatic moieties in FOS are the most abundant followed by C\\O-containing moieties and each cluster in FOS has 3 conjugated aromatic rings on average with fewer substituents. According to the analysis with a gas chromatograph/mass spectrometer, alkanes are predominant in all the SPs. A number of alkenes were identified in the SPs from the TD, while none of the alkenes were detected in acetone-SP obtained at room temperature, implying that the TD can destroy the π-π and intertwining interactions between alkenes and macromolecular structures in FOS. Moreover, a small amount of alkyl-substituted phenols and alkoxysubstituted phenols were detected in ethanol-SP from the TD, which could be the products from ethanolyzing the macromolecular moiety of FOS.
基金Funded by Natural Science Basic Research Plan in Shaanxi Province of China (Nos.2021JQ-500, 2021GY-203, 2023-JCYB-096)Shaanxi Provincial Education Department of Key Scientific Research Plan (No.20JS079)Shaanxi Provincial Education Department of Normal Scientific Research Plan (No.20JK0727)。
文摘In order to expand the advantages of strong durability and high compressive strength of calcium silicate hydrates(C-S-H),at the same time to make up for the poor early mechanical strength of magnesium silicate hydrates (M-S-H),we present the features and advantages of C-S-H and M-S-H and a comprehensive review of the progress on CaO-MgO-SiO_(2)-H_(2)O.Moreover,we systematically describe natural calcium and magnesium silicate minerals and thermodynamic properties of CaO-MgO-SiO_(2)-H_(2)O.The effect of magnesium on C-S-H and calcium on M-S-H is summarized deeply;the formation and structural feature of CaO-MgO-SiO_(2)-H_(2)O is also explained in detail.Finally,the development of calcium and magnesium silicate hydrates in the future is pointed out,and the further research is discussed and estimated.
