Understanding the evolution of microstructures in nuclear fuels under high-burn-up conditions is critical for extending fuel refueling cycles and enhancing nuclear reactor safety.In this study,a phase-field model is p...Understanding the evolution of microstructures in nuclear fuels under high-burn-up conditions is critical for extending fuel refueling cycles and enhancing nuclear reactor safety.In this study,a phase-field model is proposed to examine the evolution of high-burn-up structures in polycrystalline UO_(2).The formation and growth of recrystallized grains were initially investigated.It was demonstrated that recrystallization kinetics adhere to the Kolmogorov–Johnson–Mehl–Avrami(KJMA)equation,and that recrystallization represents a process of free-energy reduction.Subsequently,the microstructural evolution in UO_(2) was analyzed as the burn up increased.Gas bubbles acted as additional nucleation sites,thereby augmenting the recrystallization kinetics,whereas the presence of recrystallized grains accelerated bubble growth by increasing the number of grain boundaries.The observed variations in the recrystallization kinetics and porosity with burn-up closely align with experimental findings.Furthermore,the influence of grain size on microstructure evolution was investigated.Larger grain sizes were found to decrease porosity and the occurrence of high-burn-up structures.展开更多
The infinite-layer nickelates,proposed as analogs to superconducting cuprates,provide a promising platform for exploring the mechanisms of unconventional superconductivity.However,the superconductivity has been exclus...The infinite-layer nickelates,proposed as analogs to superconducting cuprates,provide a promising platform for exploring the mechanisms of unconventional superconductivity.However,the superconductivity has been exclusively observed in thin films under atmospheric pressure,underscoring the critical role of the heterointerface.展开更多
Some of the most interesting areas in aerospace science and technologies are on either higher,faster,and larger systems or lower,slower,and smaller flying capabilities.In this paper,we present our perspectives on the ...Some of the most interesting areas in aerospace science and technologies are on either higher,faster,and larger systems or lower,slower,and smaller flying capabilities.In this paper,we present our perspectives on the aerodynamics related to small,fixed-wing as well as flapping-wing flight vehicles.From an evolutionary viewpoint,flyers have gone through many iterations,adaptations,and optimizations to balance their biological functions,including flight.In the low-Reynolds-number regime,the aerodynamic characteristics around a solid object differ from those observed at the scale of passenger-airplanes.Consequently,the optimal airfoil and wing shapes vary with vehicle size.As vehicle dimensions vary,non-proportional scaling between surface areas and weight shifts the dominance of physical mechanisms,leading to distinct operational parameters and technical requirements.With smaller flight vehicles,structural flexibility as well as anisotropic material properties become more pronounced,which causes qualitative changes in aerodynamics.The flapping motion of the wings,the interactions between wings,the synergistic characteristics of wing and tail,and the development of soft structures for better agility and flight performance are discussed.Low-Reynolds-number aerodynamics require collaborative innovation to optimize shape,motion,and structure of vehicles in accordance with the scaling laws.Together,progress on these fronts is reshaping the design paradigm of air vehicles and other types of robots with shrinking physical dimensions and more versatile capabilities to meet wider ranges of missions.展开更多
The compression and energy absorption properties of foam geopolymers increase stress wave attenuation under explosion impacts,reducing the vibration effect on the structure.Explosion tests were conducted using several...The compression and energy absorption properties of foam geopolymers increase stress wave attenuation under explosion impacts,reducing the vibration effect on the structure.Explosion tests were conducted using several composite structure models,including a concrete lining structure(CLS)without foam geopolymer and six foam geopolymer composite structures(FGCS)with different backfill parameters,to study the dynamic response and wave dissipation mechanisms of FGCS under explosive loading.Pressure,strain,and vibration responses at different locations were synchronously tested.The damage modes and dynamic responses of different models were compared,and how wave elimination and energy absorption efficiencies were affected by foam geopolymer backfill parameters was analyzed.The results showed that the foam geopolymer absorbed and dissipated the impact energy through continuous compressive deformation under high strain rates and dynamic loading,reducing the strain in the liner structure by 52%and increasing the pressure attenuation rate by 28%.Additionally,the foam geopolymer backfill reduced structural vibration and liner deformation,with the FGCS structure showing 35%less displacement and 70%less acceleration compared to the CLS.The FGCS model with thicker,less dense foam geopolymer backfill,having more pores and higher porosity,demonstrated better compression and energy absorption under dynamic impact,increasing stress wave attenuation efficiency.By analyzing the stress wave propagation and the compression characteristics of the porous medium,it was concluded that the stress transfer ratio of FGCS-ρ-579 was 77%lower than that of CLS,and the transmitted wave energy was 90%lower.The results of this study provide a scientific basis for optimizing underground composite structure interlayer parameters.展开更多
The high safety of aqueous magnesium ion batteries(AMIBs)contrasts with their limited electrochemical performance.To overcome electrolyte-induced parasitic reactions,it is essential to understand the dynamic evolution...The high safety of aqueous magnesium ion batteries(AMIBs)contrasts with their limited electrochemical performance.To overcome electrolyte-induced parasitic reactions,it is essential to understand the dynamic evolution of concentration-dependent metal ion solvation structures(MISSs).This study systematically reveals the solvation structure evolution of MgCl_(2) aqueous solutions across a full concentration range(0-30 M)and its impact on electrochemical properties using molecular dynamics simulations and density functional theory calculations.Results indicate that six characteristic solvation configurations exist,exhibiting a dynamic,concentration-dependent inter-evolution defined as the solvation structure evolutionary processes(SSEP).The four-phase glass transition mechanism in solvation structure evolution is revealed by analyzing the percentage of each type of solvation structure in different concentrations.The study shows that conductivity is directly related to the dynamic transitions of dominant solvation structures,with a shift in the Mg^(2+) coordination mode—from octahedral through pentahedral intermediates to tetrahedral—revealing a concentration-dependent ion transport mechanism.At low concentrations,free-state stochastic diffusion predominates,reaching a maximum conductivity before transitioning to relay transport within a restricted network at high concentrations.Key contributions include:a general strategy for electrolyte design based on the solvation structure evolution process,which quantitatively correlates structural occupancy with migration properties,and the“Concentration Window”regulation model that balances high conductivity with reduced side reactions.These findings clarify the structural origins of anomalous conductivity in highly concentrated electrolytes and establish a mapping between microstructural evolution and macroscopic performance,providing a theoretical basis for engineering high-security electrolytes of AMIBs.展开更多
Ecological stoichiometry plays an important role in revealing the mechanisms underlying biogeochemical cycles and ecosystem functions.Abiotic factors have strong effects on N-P stoichiometry,yet the impact of plant co...Ecological stoichiometry plays an important role in revealing the mechanisms underlying biogeochemical cycles and ecosystem functions.Abiotic factors have strong effects on N-P stoichiometry,yet the impact of plant community structure,especially in forests,has not been fully elucidated.We investigated 68 plots in larch forests in northern China to explore how plant community structure and environmental factors affect the N-P stoichiometry of soil and leaves.The results showed significant differences in soil and leaf N-P stoichiometry among the three larch forests,P concentration and N:P ratio of leaves were significantly related to those of soil.Except for larch forest type,N-P stoichiometry was also regulated by elevation,climatic factors,and community structure.With increasing age(from 25 to 236 years),soil N and N:P ratio significantly increased,especially in the topsoil.With increasing mean DBH,leaf N concentration and N:P ratio also increased,indicating a shift in nutrient limitations with stand growth.These findings provide evidence that plant community structure and environmental factors regulate soil and leaf N-P stoichiometry,which is critically important for understanding biogeochemical cycles and forest management undergoing natural succession.展开更多
We report a study on the electronic structure and chemical bonding of the PB and AsB diatomic molecules using high-resolution photoelectron imaging of cryogenically-cooled PB^(−)and AsB^(−)anions.The electron affiniti...We report a study on the electronic structure and chemical bonding of the PB and AsB diatomic molecules using high-resolution photoelectron imaging of cryogenically-cooled PB^(−)and AsB^(−)anions.The electron affinities of PB and AsB are measured to be 2.751(1)and 2.600(1)eV,respectively.The ground states of the PB^(−)and AsB−anions are determined to be ^(2)Σ^(+) with a σ^(1)π^(4) valence electron configuration.The ground states of neutral PB and AsB are found to be ^(3)Π_(2) with a σ^(1)π^(3) electron configuration.The spin-orbit excited states(^(3)Π_(1) and ^(3)Π_(0)),as well as two low-lying singlet excited states(^(1)Σ^(+)and ^(1)Π),are observed.Unusual spectroscopic characteristics are observed in the ^(3)Π_(2) ground state of AsB,probably due to state mixing with a higher-lying ^(1)Δ_(2) state.The current work provides extensive electronic and spectroscopic information for the PB and AsB molecules.展开更多
Based on the observational data from 60 short-period stations deployed in the Jishishan M6.2 earthquake epicenter and adjacent regions(Gansu Province,2023),this study inverted the near-surface S-wave velocity structur...Based on the observational data from 60 short-period stations deployed in the Jishishan M6.2 earthquake epicenter and adjacent regions(Gansu Province,2023),this study inverted the near-surface S-wave velocity structure through teleseismic receiver function analysis by using the amplitude of direct P-wave.The results reveal that the epicentral area(Liugou Township and surroundings)exhibits markedly low S-wave velocities of 400-600 m/s,with a mean value of(500±50)m/s.In contrast,intermountain basins-Guanting Basin and Dahejia Basin-demonstrate significantly elevated velocities,exceeding the epicentral zone by 100-300 m/s,with values concentrated at 600-900 m/s.Notably,localized areas such as Jintian Village and Caotan Village maintain stable S-wave velocities of(700±30)m/s.The western margin tectonic belt of Jishishan displays distinctive velocity differentiation:A pronounced velocity gradient zone along the 35.8°N latitude boundary separates northern areas(<550 m/s)from southern regions(>750 m/s).These findings demonstrate significant spatial heterogeneity in shallow S-wave velocity structures,primarily controlled by three factors:(1)topographic-geomorphic units,(2)stratigraphic lithological contrasts,and(3)anthropogenic modifications.The persistent low-velocity anomalies(<600 m/s)in the epicentral zone and northern Yellow River T2 terrace likely correlate with Quaternary unconsolidated sediments,enhanced groundwater circulation,and bedrock weathering.These results provide critical geophysical constraints for understanding both the seismogenic environment of the Jishishan earthquake and its damage distribution patterns.Furthermore,they establish a foundational framework for regional seismic intensity evaluation,site amplification analysis,and secondary hazard risk assessment.展开更多
This paper provides an overview of the recent advancements in magnetic structured triboelectric nanogenerators(MSTENGs)and their potential for energy harvesting and sensing in coastal bridge infrastructure.This paper ...This paper provides an overview of the recent advancements in magnetic structured triboelectric nanogenerators(MSTENGs)and their potential for energy harvesting and sensing in coastal bridge infrastructure.This paper begins with a brief discussion on the fundamental physics modes of triboelectric nanogenerators(TENGs),triboelectric series,and factors affecting TENG power generation and transmission,providing a foundation for the subsequent sections.The review focuses on the different types of MSTENGs and their applications in coastal infrastructure.Specifically,it covers magnetic spherical TENG networks,magnet-assisted TENGs,MSTENGs for bridges,and magnetic multilayer structures based on TENGs.The advantages and limitations of each type of MSTENG are discussed in detail,highlighting their respective suitability for different coastal bridge infrastructure applications.In addition,the paper addresses the challenges and provides insights into the future of MSTENGs.These include the need for improved durability and sustainability of MSTENGs in harsh coastal environments,increasing their power-output levels to fulfll high energy needs,and the requirement for collaborative efforts between academia,industry,and government institutions to optimize MSTENG performance.展开更多
[2+2]-Type cyclobutane derivatives comprise a large family of natural products with diverse molecular architectures.However,the structure elucidation of the cyclobutane ring,including its connection mode and stereoche...[2+2]-Type cyclobutane derivatives comprise a large family of natural products with diverse molecular architectures.However,the structure elucidation of the cyclobutane ring,including its connection mode and stereochemistry,presents a significant challenge.Plumerubradins A-C(1-3),three novel iridoid glycoside[2+2]dimers featuring a highly functionalized cyclobutane core and multiple stereogenic centers,were isolated from the flowers of Plumeria rubra.Through biomimetic semisynthesis and chemical degradation of compounds 1-3,synthesis of phenylpropanoid-derived[2+2]dimers 7-10,combined with extensive spectroscopic analysis,single-crystal X-ray crystallography,and microcrystal electron diffraction experiments,the structures with absolute configurations of 1-3 were unequivocally elucidated.Furthermore,quantum mechanics-based^(1)H NMR iterative full spin analysis successfully established the correlations between the signal patterns of cyclobutane protons and the structural information of the cyclobutane ring in phenylpropanoid-derived[2+2]dimers,providing a diagnostic tool for the rapid structural elucidation of[2+2]-type cyclobutane derivatives.展开更多
Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'...Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'-bipyridine]were successfully synthesized by the volatilization of the solution at room temperature.The crystal structures of six complexes were determined by single-crystal X-ray diffraction technology.The results showed that the complexes all have a binuclear structure,and the structures contain free ethanol molecules.Moreover,the coordination number of the central metal of each structural unit is eight.Adjacent structural units interact with each other through hydrogen bonds and further expand to form 1D chain-like and 2D planar structures.After conducting a systematic study on the luminescence properties of complexes 1-4,their emission and excitation spectra were obtained.Experimental results indicated that the fluorescence lifetimes of complexes 2 and 3 were 0.807 and 0.845 ms,respectively.The emission spectral data of complexes 1-4 were imported into the CIE chromaticity coordinate system,and their corre sponding luminescent regions cover the yellow light,red light,green light,and orange-red light bands,respectively.Within the temperature range of 299.15-1300 K,the thermal decomposition processes of the six complexes were comprehensively analyzed by using TG-DSC/FTIR/MS technology.The hypothesis of the gradual loss of ligand groups during the decomposition process was verified by detecting the escaped gas,3D infrared spectroscopy,and ion fragment information detected by mass spectrometry.The specific decomposition path is as follows:firstly,free ethanol molecules and neutral ligands are removed,and finally,acidic ligands are released;the final product is the corresponding metal oxide.CCDC:2430420,1;2430422,2;2430419,3;2430424,4;2430421,5;2430423,6.展开更多
In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented...In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented product FGPA-G 2-H on Aβ25-35-induced PC 12 cells were explored.The structure of GPA-G 2-H was determined by means of zeta potential analysis,FTIR,HPLC,XRD,GC-MS and NMR.The backbone of GPA-G 2-H was mainly composed of→4)-α-D-Glcp-(1→with branches substituted at O-3.Notably,GPA-G 2-H was degraded by intestinal microbiota in vitro with total sugar content and pH value decreasing,and short-chain fatty acids(SCFAs)increasing.Moreover,GPA-G 2-H significantly promoted the proliferation of Lactobacillus,Muribaculaceae and Weissella,thereby making positive alterations in intestinal microbiota composition.Additionally,FGPA-G 2-H activated the Nrf 2/HO-1 signaling pathway,enhanced HO-1,NQO 1,SOD and GSH-Px,while inhabited Keap 1,MDA and LDH,which alleviated Aβ-induced oxidative stress in PC 12 cells.These provide a solid theoretical basis for the further development of ginseng polysaccharides as functional food and antioxidant drugs.展开更多
Quinoid structures are considered to be conducive to the charge transport of organic molecules,but this hypothesis is rarely proven at single-molecule level.Herein,as a proof of concept,the single-molecule conductance...Quinoid structures are considered to be conducive to the charge transport of organic molecules,but this hypothesis is rarely proven at single-molecule level.Herein,as a proof of concept,the single-molecule conductance of two furan-based isomers,3,3'-bis(4-(methylthio)phenyl)-2,2'-bifuran(2,2'-SMPBF)and 4,4'-bis(4-(methylthio)phenyl)-3,3'-bifuran(3,3'-SMPBF),is investigated by the scanning tunneling microscopy break junction(STM-BJ)technique and theoretical simulation.2,2'-SMPBF prefers to adopt a nearly planar conformation with intact alternating single and double bonds extended via2,2'-bifuran moiety and therefore exhibits goodπ-conjugation and a prominent quinoid structure.However,theπ-conjugation of 3,3'-SMPBF is interrupted due to ineffective cross-conjugation in the 3,3'-bifuran moiety,leading to the absence of a quinoid structure.2,2'-SMPBF displays switchable multiple conductances induced by the interconversion between folded and unfolded conformations and an abnormal rebound of conductance along with the increases of electrode displacement,which is demonstrated to be caused by the quinoid structure in a nearly planar conformation during the stretching process.However,3,3'-SMPBF without a quinoid structure in unfolded conformation exhibits extremely low conductance that cannot be captured in STM-BJ measurements.These results reveal the significant contribution of quinoid structure to molecular charge transport and provide valuable information on the structure-transport relationship for the design of efficient organic semiconductors.展开更多
This study designs four types of liquid-filled cylindrical shell structures to investigate their protection characteristics against explosive shock waves and high-speed fragments.Bare charge and charge-driven prefabri...This study designs four types of liquid-filled cylindrical shell structures to investigate their protection characteristics against explosive shock waves and high-speed fragments.Bare charge and charge-driven prefabricated fragments are employed to examine the damage under blast shock waves and combined blast and fragments loading on various liquid-filled cylindrical shell structures.The test results are compared to numerical calculations and theoretical analysis for the structure's deformation,the liquid medium's movement,and the pressure waves'propagation characteristics under different liquid-filling methods.The results showed that the filling method influences the blast protection and the struc-ture's energy absorption performance.The external filling method reduces the structural deformation,and the internal filling method increases the damage effect.The gapped internal filling method improves the structure's energy absorption efficiency.The pressure wave loading on the liquid-filled cylindrical shell structure differs depending on filling methods.Explosive shock waves and high-speed fragments show a damage enhancement effect on the liquid-filled cylindrical shell structure,depending on the thickness of the internal liquid container layer.The specific impulse on the inner surface of the cylindrical shell positively correlates to the radial deformation of the cylindrical shell structure,and the external liquid layer limits the radial structural deformation.展开更多
This paper theoretically investigates the influence of a cylindrical PN junction on the propagation characteristics of shear cylindrical waves(SCWs)in an infinitely long piezoelectric semiconductor(PS)concentric cylin...This paper theoretically investigates the influence of a cylindrical PN junction on the propagation characteristics of shear cylindrical waves(SCWs)in an infinitely long piezoelectric semiconductor(PS)concentric cylinder structure.This PS concentric cylinder structure is composed of three regions:an inner PS cylinder,an outer PS cylindrical shell,and a cylindrical PN junction at the interface between the two aforementioned regions.First,the basic equations of the PS concentric cylinder structure are derived,taking into account the coupling of the mechanical displacement,electric potential,and charge carrier perturbation in the cylindrical coordinate system.Next,a mathematical model for the SCWs in this PS concentric cylinder structure is established,utilizing the spectral method and considering the physical characteristics of the cylindrical PN junction.Finally,the dispersion and attenuation curves of the SCWs are numerically calculated to discuss the influence of the interface effect resulting from the cylindrical PN junction.It is found that the existence of a cylindrical PN junction can either reduce or enhance the mechanical-to-electrical energy conversion,which is closely related to the doping mode,doping concentration,and curvature radius of the cylindrical interface.A reasonable design of the aforementioned parameters can optimize the wave motion in acoustic equipment formed by PS media with different frequencies or wavelengths.The construction and resolution of the mathematical model as well as the analysis of physical mechanisms can offer theoretical guidance for improving the efficiency of energy conversion from mechanical energy to electrical energy and optimizing the acoustic performance of energy harvesting devices.展开更多
To mill fine and well-defined micro-dimpled structures,a machining manner of spiral trajectory tool reciprocating motion,where the tool repeats the process of‘feed milling–retract–cutting feed–feed milling again’...To mill fine and well-defined micro-dimpled structures,a machining manner of spiral trajectory tool reciprocating motion,where the tool repeats the process of‘feed milling–retract–cutting feed–feed milling again’along the spiral trajectory,was proposed.From the kinematics analysis,it is found that the machining quality of micro-dimpled structures is highly dependent on the machining trajectory using spiral trajectory tool reciprocating motion.To reveal this causation,simulation modelling and experimental studies were carried out.A simulation model was developed to quantitatively and qualitatively investigate the influence of the trajectory discretization strategies(constant-angle and constant-arc length)and parameters(discrete angle,discrete arc length,and pitch)on surface texture and residual height of micro-dimpled structures.Subsequently,micro-dimpled structures were milled under different trajectory discretization strategies and parameters with spiral trajectory tool reciprocating motion.A comprehensive comparison between the milled results and simulation analysis was made based on geometry accuracy,surface morphology and surface roughness of milled dimples.Meanwhile,the errors and factors affecting the above three aspects were analyzed.The results demonstrate both the feasibility of the established simulation model and the machining capability of this machining way in milling high-quality micro-dimpled structures.Spiral trajectory tool reciprocating motion provides a new machining way for milling micro-dimpled structures and micro-dimpled functional surfaces.And an appropriate machining trajectory can be generated based on the optimized trajectory parameters,thus contributing to the improvement of machining quality and efficiency.展开更多
To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content ...To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.展开更多
Fine-grained nuclear graphite is a key material in high-temperature gas-cooled reactors(HTGRs).During air ingress accidents,core graphite components undergo severe oxidation,threatening structural integrity.Therefore,...Fine-grained nuclear graphite is a key material in high-temperature gas-cooled reactors(HTGRs).During air ingress accidents,core graphite components undergo severe oxidation,threatening structural integrity.Therefore,understanding the oxidation behavior of nuclear graphite is essential for reactor safety.The influence of oxidation involves multiple factors,including temperature,sample size,oxidant,impurities,filler type and size,etc.The size of the filler particles plays a crucial role in this study.Five ultrafine-and superfine-grained nuclear graphite samples(5.9-34.4μm)are manufactured using identical raw materials and manufacturing processes.Isothermal oxidation tests conducted at 650℃-750℃ are used to study the oxidation behavior.Additionally,comprehensive characterization is performed to analyze the crystal structure,surface morphology,and nanoscale to microscale pore structure of the samples.Results indicate that oxidation behavior cannot be predicted solely based on filler grain size.Reactive site concentration,characterized by active surface area,dominates the chemical reaction kinetics,whereas pore tortuosity,quantified by the structural parameterΨ,plays a key role in regulating oxidant diffusion.These findings clarify the dual role of microstructure in oxidation mechanisms and establish a theoretical and experimental basis for the design of high-performance nuclear graphite capable of long-term service in high-temperature gas-cooled reactors.展开更多
Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is p...Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.展开更多
Vacancy defects,as fundamental disruptions in metallic lattices,play an important role in shaping the mechanical and electronic properties of aluminum crystals.However,the influence of vacancy position under coupled t...Vacancy defects,as fundamental disruptions in metallic lattices,play an important role in shaping the mechanical and electronic properties of aluminum crystals.However,the influence of vacancy position under coupled thermomechanical fields remains insufficiently understood.In this study,transmission and scanning electron microscopy were employed to observe dislocation structures and grain boundary heterogeneities in processed aluminum alloys,suggesting stress concentrations and microstructural inhomogeneities associated with vacancy accumulation.To complement these observations,first-principles calculations and molecular dynamics simulations were conducted for seven single-vacancy configurations in face-centered cubic aluminum.The stress response,total energy,density of states(DOS),and differential charge density were examined under varying compressive strain(ε=0–0.1)and temperature(0–600 K).The results indicate that face-centered vacancies tend to reduce mechanical strength and perturb electronic states near the Fermi level,whereas corner and edge vacancies appear to have weaker effects.Elevated temperatures may partially restore electronic uniformity through thermal excitation.Overall,these findings suggest that vacancy position exerts a critical but position-dependent influence on coupled structure-property relationships,offering theoretical insights and preliminary experimental support for defect-engineered aluminum alloy design.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.U20B2013 and 12205286)the National Key Research and Development Program of China(Grant No.2022YFB1902401)。
文摘Understanding the evolution of microstructures in nuclear fuels under high-burn-up conditions is critical for extending fuel refueling cycles and enhancing nuclear reactor safety.In this study,a phase-field model is proposed to examine the evolution of high-burn-up structures in polycrystalline UO_(2).The formation and growth of recrystallized grains were initially investigated.It was demonstrated that recrystallization kinetics adhere to the Kolmogorov–Johnson–Mehl–Avrami(KJMA)equation,and that recrystallization represents a process of free-energy reduction.Subsequently,the microstructural evolution in UO_(2) was analyzed as the burn up increased.Gas bubbles acted as additional nucleation sites,thereby augmenting the recrystallization kinetics,whereas the presence of recrystallized grains accelerated bubble growth by increasing the number of grain boundaries.The observed variations in the recrystallization kinetics and porosity with burn-up closely align with experimental findings.Furthermore,the influence of grain size on microstructure evolution was investigated.Larger grain sizes were found to decrease porosity and the occurrence of high-burn-up structures.
基金supported by the National Natural Science Foundation of China[52125307(to P.G.),12404192(to R.C.S),12274061(to L.Q.)]Key Research and Development Program from the Ministry of Science and Technology(2023YFA1406301)the support from the New Cornerstone Science Foundation through the XPLORER PRIZE。
文摘The infinite-layer nickelates,proposed as analogs to superconducting cuprates,provide a promising platform for exploring the mechanisms of unconventional superconductivity.However,the superconductivity has been exclusively observed in thin films under atmospheric pressure,underscoring the critical role of the heterointerface.
基金supported by the Research Grants Council(RGC)of the Government of Hong Kong Special Administrative Region(HKSAR)with RGC/GRF Project(Grant Nos.16206321 and 14113824).
文摘Some of the most interesting areas in aerospace science and technologies are on either higher,faster,and larger systems or lower,slower,and smaller flying capabilities.In this paper,we present our perspectives on the aerodynamics related to small,fixed-wing as well as flapping-wing flight vehicles.From an evolutionary viewpoint,flyers have gone through many iterations,adaptations,and optimizations to balance their biological functions,including flight.In the low-Reynolds-number regime,the aerodynamic characteristics around a solid object differ from those observed at the scale of passenger-airplanes.Consequently,the optimal airfoil and wing shapes vary with vehicle size.As vehicle dimensions vary,non-proportional scaling between surface areas and weight shifts the dominance of physical mechanisms,leading to distinct operational parameters and technical requirements.With smaller flight vehicles,structural flexibility as well as anisotropic material properties become more pronounced,which causes qualitative changes in aerodynamics.The flapping motion of the wings,the interactions between wings,the synergistic characteristics of wing and tail,and the development of soft structures for better agility and flight performance are discussed.Low-Reynolds-number aerodynamics require collaborative innovation to optimize shape,motion,and structure of vehicles in accordance with the scaling laws.Together,progress on these fronts is reshaping the design paradigm of air vehicles and other types of robots with shrinking physical dimensions and more versatile capabilities to meet wider ranges of missions.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.52378401,12202494)the Fundamental Research Funds for the Central Universities(Grant No.30922010918)。
文摘The compression and energy absorption properties of foam geopolymers increase stress wave attenuation under explosion impacts,reducing the vibration effect on the structure.Explosion tests were conducted using several composite structure models,including a concrete lining structure(CLS)without foam geopolymer and six foam geopolymer composite structures(FGCS)with different backfill parameters,to study the dynamic response and wave dissipation mechanisms of FGCS under explosive loading.Pressure,strain,and vibration responses at different locations were synchronously tested.The damage modes and dynamic responses of different models were compared,and how wave elimination and energy absorption efficiencies were affected by foam geopolymer backfill parameters was analyzed.The results showed that the foam geopolymer absorbed and dissipated the impact energy through continuous compressive deformation under high strain rates and dynamic loading,reducing the strain in the liner structure by 52%and increasing the pressure attenuation rate by 28%.Additionally,the foam geopolymer backfill reduced structural vibration and liner deformation,with the FGCS structure showing 35%less displacement and 70%less acceleration compared to the CLS.The FGCS model with thicker,less dense foam geopolymer backfill,having more pores and higher porosity,demonstrated better compression and energy absorption under dynamic impact,increasing stress wave attenuation efficiency.By analyzing the stress wave propagation and the compression characteristics of the porous medium,it was concluded that the stress transfer ratio of FGCS-ρ-579 was 77%lower than that of CLS,and the transmitted wave energy was 90%lower.The results of this study provide a scientific basis for optimizing underground composite structure interlayer parameters.
基金supported by the National Natural Science Foundation of China(No.11047164)the National Key Laboratory of Infrared Detection Technologies(No.IRDT-23-S01)the Shanghai Explorer Program(No.24TS1403400)。
文摘The high safety of aqueous magnesium ion batteries(AMIBs)contrasts with their limited electrochemical performance.To overcome electrolyte-induced parasitic reactions,it is essential to understand the dynamic evolution of concentration-dependent metal ion solvation structures(MISSs).This study systematically reveals the solvation structure evolution of MgCl_(2) aqueous solutions across a full concentration range(0-30 M)and its impact on electrochemical properties using molecular dynamics simulations and density functional theory calculations.Results indicate that six characteristic solvation configurations exist,exhibiting a dynamic,concentration-dependent inter-evolution defined as the solvation structure evolutionary processes(SSEP).The four-phase glass transition mechanism in solvation structure evolution is revealed by analyzing the percentage of each type of solvation structure in different concentrations.The study shows that conductivity is directly related to the dynamic transitions of dominant solvation structures,with a shift in the Mg^(2+) coordination mode—from octahedral through pentahedral intermediates to tetrahedral—revealing a concentration-dependent ion transport mechanism.At low concentrations,free-state stochastic diffusion predominates,reaching a maximum conductivity before transitioning to relay transport within a restricted network at high concentrations.Key contributions include:a general strategy for electrolyte design based on the solvation structure evolution process,which quantitatively correlates structural occupancy with migration properties,and the“Concentration Window”regulation model that balances high conductivity with reduced side reactions.These findings clarify the structural origins of anomalous conductivity in highly concentrated electrolytes and establish a mapping between microstructural evolution and macroscopic performance,providing a theoretical basis for engineering high-security electrolytes of AMIBs.
基金supported by the National Natural Science Foundation of China(No.32201426,No.31988102)the Major Program for Basic Research Project of Yunnan Province(No.202101BC070002)the Key Research and Development Program of Yunnan Provin ce(No.202303AC100009).
文摘Ecological stoichiometry plays an important role in revealing the mechanisms underlying biogeochemical cycles and ecosystem functions.Abiotic factors have strong effects on N-P stoichiometry,yet the impact of plant community structure,especially in forests,has not been fully elucidated.We investigated 68 plots in larch forests in northern China to explore how plant community structure and environmental factors affect the N-P stoichiometry of soil and leaves.The results showed significant differences in soil and leaf N-P stoichiometry among the three larch forests,P concentration and N:P ratio of leaves were significantly related to those of soil.Except for larch forest type,N-P stoichiometry was also regulated by elevation,climatic factors,and community structure.With increasing age(from 25 to 236 years),soil N and N:P ratio significantly increased,especially in the topsoil.With increasing mean DBH,leaf N concentration and N:P ratio also increased,indicating a shift in nutrient limitations with stand growth.These findings provide evidence that plant community structure and environmental factors regulate soil and leaf N-P stoichiometry,which is critically important for understanding biogeochemical cycles and forest management undergoing natural succession.
基金supported by the National Science Foundation (Grant No.CHE-2403841)。
文摘We report a study on the electronic structure and chemical bonding of the PB and AsB diatomic molecules using high-resolution photoelectron imaging of cryogenically-cooled PB^(−)and AsB^(−)anions.The electron affinities of PB and AsB are measured to be 2.751(1)and 2.600(1)eV,respectively.The ground states of the PB^(−)and AsB−anions are determined to be ^(2)Σ^(+) with a σ^(1)π^(4) valence electron configuration.The ground states of neutral PB and AsB are found to be ^(3)Π_(2) with a σ^(1)π^(3) electron configuration.The spin-orbit excited states(^(3)Π_(1) and ^(3)Π_(0)),as well as two low-lying singlet excited states(^(1)Σ^(+)and ^(1)Π),are observed.Unusual spectroscopic characteristics are observed in the ^(3)Π_(2) ground state of AsB,probably due to state mixing with a higher-lying ^(1)Δ_(2) state.The current work provides extensive electronic and spectroscopic information for the PB and AsB molecules.
基金project is supported in part by Broadband Seismic 3D Array Detection(PhaseⅠ),Deep Earth Probe and Mineral Resources Exploration-National Science and Technology Major Project(Grant No.2024ZD1000300)National Natural Science Foundation of China(42204061)Gansu Jishishan 6.2 magnitude earthquake scientific investigation(DQJB23Y45)program。
文摘Based on the observational data from 60 short-period stations deployed in the Jishishan M6.2 earthquake epicenter and adjacent regions(Gansu Province,2023),this study inverted the near-surface S-wave velocity structure through teleseismic receiver function analysis by using the amplitude of direct P-wave.The results reveal that the epicentral area(Liugou Township and surroundings)exhibits markedly low S-wave velocities of 400-600 m/s,with a mean value of(500±50)m/s.In contrast,intermountain basins-Guanting Basin and Dahejia Basin-demonstrate significantly elevated velocities,exceeding the epicentral zone by 100-300 m/s,with values concentrated at 600-900 m/s.Notably,localized areas such as Jintian Village and Caotan Village maintain stable S-wave velocities of(700±30)m/s.The western margin tectonic belt of Jishishan displays distinctive velocity differentiation:A pronounced velocity gradient zone along the 35.8°N latitude boundary separates northern areas(<550 m/s)from southern regions(>750 m/s).These findings demonstrate significant spatial heterogeneity in shallow S-wave velocity structures,primarily controlled by three factors:(1)topographic-geomorphic units,(2)stratigraphic lithological contrasts,and(3)anthropogenic modifications.The persistent low-velocity anomalies(<600 m/s)in the epicentral zone and northern Yellow River T2 terrace likely correlate with Quaternary unconsolidated sediments,enhanced groundwater circulation,and bedrock weathering.These results provide critical geophysical constraints for understanding both the seismogenic environment of the Jishishan earthquake and its damage distribution patterns.Furthermore,they establish a foundational framework for regional seismic intensity evaluation,site amplification analysis,and secondary hazard risk assessment.
文摘This paper provides an overview of the recent advancements in magnetic structured triboelectric nanogenerators(MSTENGs)and their potential for energy harvesting and sensing in coastal bridge infrastructure.This paper begins with a brief discussion on the fundamental physics modes of triboelectric nanogenerators(TENGs),triboelectric series,and factors affecting TENG power generation and transmission,providing a foundation for the subsequent sections.The review focuses on the different types of MSTENGs and their applications in coastal infrastructure.Specifically,it covers magnetic spherical TENG networks,magnet-assisted TENGs,MSTENGs for bridges,and magnetic multilayer structures based on TENGs.The advantages and limitations of each type of MSTENG are discussed in detail,highlighting their respective suitability for different coastal bridge infrastructure applications.In addition,the paper addresses the challenges and provides insights into the future of MSTENGs.These include the need for improved durability and sustainability of MSTENGs in harsh coastal environments,increasing their power-output levels to fulfll high energy needs,and the requirement for collaborative efforts between academia,industry,and government institutions to optimize MSTENG performance.
基金supported by the National Key R&D Program of China(No.2023YFC3503902)the National Natural Science Foundation of China(Nos.82293681(82293680)and 82321004)+2 种基金the Guangdong Basic and Applied Basic Research Foundation(Nos.2022B1515120015 and 2021A1515111021)the Guangdong Major Project of Basic and Applied Basic Research(No.2023B0303000026)the Science and Technology Projects in Guangzhou(No.202102070001).
文摘[2+2]-Type cyclobutane derivatives comprise a large family of natural products with diverse molecular architectures.However,the structure elucidation of the cyclobutane ring,including its connection mode and stereochemistry,presents a significant challenge.Plumerubradins A-C(1-3),three novel iridoid glycoside[2+2]dimers featuring a highly functionalized cyclobutane core and multiple stereogenic centers,were isolated from the flowers of Plumeria rubra.Through biomimetic semisynthesis and chemical degradation of compounds 1-3,synthesis of phenylpropanoid-derived[2+2]dimers 7-10,combined with extensive spectroscopic analysis,single-crystal X-ray crystallography,and microcrystal electron diffraction experiments,the structures with absolute configurations of 1-3 were unequivocally elucidated.Furthermore,quantum mechanics-based^(1)H NMR iterative full spin analysis successfully established the correlations between the signal patterns of cyclobutane protons and the structural information of the cyclobutane ring in phenylpropanoid-derived[2+2]dimers,providing a diagnostic tool for the rapid structural elucidation of[2+2]-type cyclobutane derivatives.
文摘Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'-bipyridine]were successfully synthesized by the volatilization of the solution at room temperature.The crystal structures of six complexes were determined by single-crystal X-ray diffraction technology.The results showed that the complexes all have a binuclear structure,and the structures contain free ethanol molecules.Moreover,the coordination number of the central metal of each structural unit is eight.Adjacent structural units interact with each other through hydrogen bonds and further expand to form 1D chain-like and 2D planar structures.After conducting a systematic study on the luminescence properties of complexes 1-4,their emission and excitation spectra were obtained.Experimental results indicated that the fluorescence lifetimes of complexes 2 and 3 were 0.807 and 0.845 ms,respectively.The emission spectral data of complexes 1-4 were imported into the CIE chromaticity coordinate system,and their corre sponding luminescent regions cover the yellow light,red light,green light,and orange-red light bands,respectively.Within the temperature range of 299.15-1300 K,the thermal decomposition processes of the six complexes were comprehensively analyzed by using TG-DSC/FTIR/MS technology.The hypothesis of the gradual loss of ligand groups during the decomposition process was verified by detecting the escaped gas,3D infrared spectroscopy,and ion fragment information detected by mass spectrometry.The specific decomposition path is as follows:firstly,free ethanol molecules and neutral ligands are removed,and finally,acidic ligands are released;the final product is the corresponding metal oxide.CCDC:2430420,1;2430422,2;2430419,3;2430424,4;2430421,5;2430423,6.
基金Supported by the National Key Research and Development Program of Traditional Chinese Medicine Modernization Project,China(No.2023YFC3504000)the Science and Technology Development Project of Jilin Province,China(No.20240404043ZP)the Science and Technology Innovation Cooperation Project of Changchun Science and Technology Bureau and Chinese Academy of Sciences,China(No.23SH14)。
文摘In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented product FGPA-G 2-H on Aβ25-35-induced PC 12 cells were explored.The structure of GPA-G 2-H was determined by means of zeta potential analysis,FTIR,HPLC,XRD,GC-MS and NMR.The backbone of GPA-G 2-H was mainly composed of→4)-α-D-Glcp-(1→with branches substituted at O-3.Notably,GPA-G 2-H was degraded by intestinal microbiota in vitro with total sugar content and pH value decreasing,and short-chain fatty acids(SCFAs)increasing.Moreover,GPA-G 2-H significantly promoted the proliferation of Lactobacillus,Muribaculaceae and Weissella,thereby making positive alterations in intestinal microbiota composition.Additionally,FGPA-G 2-H activated the Nrf 2/HO-1 signaling pathway,enhanced HO-1,NQO 1,SOD and GSH-Px,while inhabited Keap 1,MDA and LDH,which alleviated Aβ-induced oxidative stress in PC 12 cells.These provide a solid theoretical basis for the further development of ginseng polysaccharides as functional food and antioxidant drugs.
基金financially supported by the National Natural Science Foundation of China(Nos.U23A20594,22375066 and 21788102)Guang Dong Basic and Applied Basic Research Foundation(No.2023B1515040003)。
文摘Quinoid structures are considered to be conducive to the charge transport of organic molecules,but this hypothesis is rarely proven at single-molecule level.Herein,as a proof of concept,the single-molecule conductance of two furan-based isomers,3,3'-bis(4-(methylthio)phenyl)-2,2'-bifuran(2,2'-SMPBF)and 4,4'-bis(4-(methylthio)phenyl)-3,3'-bifuran(3,3'-SMPBF),is investigated by the scanning tunneling microscopy break junction(STM-BJ)technique and theoretical simulation.2,2'-SMPBF prefers to adopt a nearly planar conformation with intact alternating single and double bonds extended via2,2'-bifuran moiety and therefore exhibits goodπ-conjugation and a prominent quinoid structure.However,theπ-conjugation of 3,3'-SMPBF is interrupted due to ineffective cross-conjugation in the 3,3'-bifuran moiety,leading to the absence of a quinoid structure.2,2'-SMPBF displays switchable multiple conductances induced by the interconversion between folded and unfolded conformations and an abnormal rebound of conductance along with the increases of electrode displacement,which is demonstrated to be caused by the quinoid structure in a nearly planar conformation during the stretching process.However,3,3'-SMPBF without a quinoid structure in unfolded conformation exhibits extremely low conductance that cannot be captured in STM-BJ measurements.These results reveal the significant contribution of quinoid structure to molecular charge transport and provide valuable information on the structure-transport relationship for the design of efficient organic semiconductors.
基金the National Natural Science Foundation of China(Grant Nos.52371342,52271338,52101378 and 51979277)。
文摘This study designs four types of liquid-filled cylindrical shell structures to investigate their protection characteristics against explosive shock waves and high-speed fragments.Bare charge and charge-driven prefabricated fragments are employed to examine the damage under blast shock waves and combined blast and fragments loading on various liquid-filled cylindrical shell structures.The test results are compared to numerical calculations and theoretical analysis for the structure's deformation,the liquid medium's movement,and the pressure waves'propagation characteristics under different liquid-filling methods.The results showed that the filling method influences the blast protection and the struc-ture's energy absorption performance.The external filling method reduces the structural deformation,and the internal filling method increases the damage effect.The gapped internal filling method improves the structure's energy absorption efficiency.The pressure wave loading on the liquid-filled cylindrical shell structure differs depending on filling methods.Explosive shock waves and high-speed fragments show a damage enhancement effect on the liquid-filled cylindrical shell structure,depending on the thickness of the internal liquid container layer.The specific impulse on the inner surface of the cylindrical shell positively correlates to the radial deformation of the cylindrical shell structure,and the external liquid layer limits the radial structural deformation.
基金Project supported by the National Natural Science Foundation of China(Nos.12202039,52204085,and 52474123)。
文摘This paper theoretically investigates the influence of a cylindrical PN junction on the propagation characteristics of shear cylindrical waves(SCWs)in an infinitely long piezoelectric semiconductor(PS)concentric cylinder structure.This PS concentric cylinder structure is composed of three regions:an inner PS cylinder,an outer PS cylindrical shell,and a cylindrical PN junction at the interface between the two aforementioned regions.First,the basic equations of the PS concentric cylinder structure are derived,taking into account the coupling of the mechanical displacement,electric potential,and charge carrier perturbation in the cylindrical coordinate system.Next,a mathematical model for the SCWs in this PS concentric cylinder structure is established,utilizing the spectral method and considering the physical characteristics of the cylindrical PN junction.Finally,the dispersion and attenuation curves of the SCWs are numerically calculated to discuss the influence of the interface effect resulting from the cylindrical PN junction.It is found that the existence of a cylindrical PN junction can either reduce or enhance the mechanical-to-electrical energy conversion,which is closely related to the doping mode,doping concentration,and curvature radius of the cylindrical interface.A reasonable design of the aforementioned parameters can optimize the wave motion in acoustic equipment formed by PS media with different frequencies or wavelengths.The construction and resolution of the mathematical model as well as the analysis of physical mechanisms can offer theoretical guidance for improving the efficiency of energy conversion from mechanical energy to electrical energy and optimizing the acoustic performance of energy harvesting devices.
基金co-supported the National Natural Science Foundation of China(No.52235010)the Heilongjiang Postdoctoral Fund(No.LBH-Z22136)the New Era Longjiang Excellent Master and Doctoral Dissertation Fund(No.LJYXL2022-057).
文摘To mill fine and well-defined micro-dimpled structures,a machining manner of spiral trajectory tool reciprocating motion,where the tool repeats the process of‘feed milling–retract–cutting feed–feed milling again’along the spiral trajectory,was proposed.From the kinematics analysis,it is found that the machining quality of micro-dimpled structures is highly dependent on the machining trajectory using spiral trajectory tool reciprocating motion.To reveal this causation,simulation modelling and experimental studies were carried out.A simulation model was developed to quantitatively and qualitatively investigate the influence of the trajectory discretization strategies(constant-angle and constant-arc length)and parameters(discrete angle,discrete arc length,and pitch)on surface texture and residual height of micro-dimpled structures.Subsequently,micro-dimpled structures were milled under different trajectory discretization strategies and parameters with spiral trajectory tool reciprocating motion.A comprehensive comparison between the milled results and simulation analysis was made based on geometry accuracy,surface morphology and surface roughness of milled dimples.Meanwhile,the errors and factors affecting the above three aspects were analyzed.The results demonstrate both the feasibility of the established simulation model and the machining capability of this machining way in milling high-quality micro-dimpled structures.Spiral trajectory tool reciprocating motion provides a new machining way for milling micro-dimpled structures and micro-dimpled functional surfaces.And an appropriate machining trajectory can be generated based on the optimized trajectory parameters,thus contributing to the improvement of machining quality and efficiency.
基金Supported by the Science and Technology Cooperation and Exchange special project of Cooperation of Shanxi Province(202404041101014)the Fundamental Research Program of Shanxi Province(202403021212333)+3 种基金the Joint Funds of the National Natural Science Foundation of China(U24A20555)the Lvliang Key R&D of University-Local Cooperation(2023XDHZ10)the Initiation Fund for Doctoral Research of Taiyuan University of Science and Technology(20242026)the Outstanding Doctor Funding Award of Shanxi Province(20242080).
文摘To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.
基金supported by the National Key Research and Development Program of China(2024YFA1612900)the National Natural Science Foundation of China(Grant No.52103365 and No.12375270)the Guangdong Innovative and Entrepreneurial Research Team Program,China(Grant No.2021ZT09L227).
文摘Fine-grained nuclear graphite is a key material in high-temperature gas-cooled reactors(HTGRs).During air ingress accidents,core graphite components undergo severe oxidation,threatening structural integrity.Therefore,understanding the oxidation behavior of nuclear graphite is essential for reactor safety.The influence of oxidation involves multiple factors,including temperature,sample size,oxidant,impurities,filler type and size,etc.The size of the filler particles plays a crucial role in this study.Five ultrafine-and superfine-grained nuclear graphite samples(5.9-34.4μm)are manufactured using identical raw materials and manufacturing processes.Isothermal oxidation tests conducted at 650℃-750℃ are used to study the oxidation behavior.Additionally,comprehensive characterization is performed to analyze the crystal structure,surface morphology,and nanoscale to microscale pore structure of the samples.Results indicate that oxidation behavior cannot be predicted solely based on filler grain size.Reactive site concentration,characterized by active surface area,dominates the chemical reaction kinetics,whereas pore tortuosity,quantified by the structural parameterΨ,plays a key role in regulating oxidant diffusion.These findings clarify the dual role of microstructure in oxidation mechanisms and establish a theoretical and experimental basis for the design of high-performance nuclear graphite capable of long-term service in high-temperature gas-cooled reactors.
基金supported by National Natural Science Foundation of China(No.52025055 and 52275571)Basic Research Operation Fund of China(No.xzy012024024).
文摘Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.
基金supported by the Research Project on Strengthening the Construction of an Important Ecological Security Barrier in Northern China by Higher Education Institutions in the Inner Mongolia Autonomous Region(STAQZX202313)the Inner Mongolia Autonomous Region Education Science‘14th Five-Year Plan’2024 Annual Research Project(NGJGH2024635).
文摘Vacancy defects,as fundamental disruptions in metallic lattices,play an important role in shaping the mechanical and electronic properties of aluminum crystals.However,the influence of vacancy position under coupled thermomechanical fields remains insufficiently understood.In this study,transmission and scanning electron microscopy were employed to observe dislocation structures and grain boundary heterogeneities in processed aluminum alloys,suggesting stress concentrations and microstructural inhomogeneities associated with vacancy accumulation.To complement these observations,first-principles calculations and molecular dynamics simulations were conducted for seven single-vacancy configurations in face-centered cubic aluminum.The stress response,total energy,density of states(DOS),and differential charge density were examined under varying compressive strain(ε=0–0.1)and temperature(0–600 K).The results indicate that face-centered vacancies tend to reduce mechanical strength and perturb electronic states near the Fermi level,whereas corner and edge vacancies appear to have weaker effects.Elevated temperatures may partially restore electronic uniformity through thermal excitation.Overall,these findings suggest that vacancy position exerts a critical but position-dependent influence on coupled structure-property relationships,offering theoretical insights and preliminary experimental support for defect-engineered aluminum alloy design.
