In addition to soil samples, conventional soil maps, and experienced soil surveyors, text about soils(e.g., soil survey reports) is an important potential data source for extracting soil–environment relationships. Co...In addition to soil samples, conventional soil maps, and experienced soil surveyors, text about soils(e.g., soil survey reports) is an important potential data source for extracting soil–environment relationships. Considering that the words describing soil–environment relationships are often mixed with unrelated words, the first step is to extract the needed words and organize them in a structured way. This paper applies natural language processing(NLP) techniques to automatically extract and structure information from soil survey reports regarding soil–environment relationships. The method includes two steps:(1) construction of a knowledge frame and(2) information extraction using either a rule-based method or a statistic-based method for different types of information. For uniformly written text information, the rule-based approach was used to extract information. These types of variables include slope, elevation, accumulated temperature, annual mean temperature, annual precipitation, and frost-free period. For information contained in text written in diverse styles, the statistic-based method was adopted. These types of variables include landform and parent material. The soil species of China soil survey reports were selected as the experimental dataset. Precision(P), recall(R), and F1-measure(F1) were used to evaluate the performances of the method. For the rule-based method, the P values were 1, the R values were above 92%, and the F1 values were above 96% for all the involved variables. For the method based on the conditional random fields(CRFs), the P, R and F1 values for the parent material were, respectively, 84.15, 83.13, and 83.64%; the values for landform were 88.33, 76.81, and 82.17%, respectively. To explore the impact of text types on the performance of the CRFs-based method, CRFs models were trained and validated separately by the descriptive texts of soil types and typical profiles. For parent material, the maximum F1 value for the descriptive text of soil types was 90.7%, while the maximum F1 value for the descriptive text of soil profiles was only 75%. For landform, the maximum F1 value for the descriptive text of soil types was 85.33%, which was similar to that of the descriptive text of soil profiles(i.e., 85.71%). These results suggest that NLP techniques are effective for the extraction and structuration of soil–environment relationship information from a text data source.展开更多
This paper considers accounting regulation research from a structuration and cultural perspective. Therefore, accounting regulation research spans over three spheres of enquiry： （1） an accounting focus of standard-...This paper considers accounting regulation research from a structuration and cultural perspective. Therefore, accounting regulation research spans over three spheres of enquiry： （1） an accounting focus of standard-setting; （2） a cultural analysis in an empirical context; and （3） the use of a research methodology drawn from Anthony Giddens＇ structuration theory. In such approach, accounting regulation research analyzes the accounting regulation actors drawing upon the cultures in their standard-setting actions and interactions, referring to Giddens＇ three structural properties of meaning, power, and morality. The integration of these three spheres of enquiry is not entirely original. A few prior studies have similar combinations： Although they stress the uses and consequences of accounting systems in producing and reproducing organizational culture and negotiating meaning at the organizational level, this paper chooses the research approach of contextual analysis of accounting systems at more macro-societal and cultural levels. This different research interest and design provides this paper with its distinguishable characteristic from the prior similar studies.展开更多
An integration of organization culture in the conceptualization and development of Enterprise Resource Planning Systems （ERPs） is critical for an organization to reap potential benefits of the system. In this paper,...An integration of organization culture in the conceptualization and development of Enterprise Resource Planning Systems （ERPs） is critical for an organization to reap potential benefits of the system. In this paper, the authors present an analytical approach through the Structuration Theory： How a university can assess its culture for the purposes of design and development of the ERPs. The authors extend the Structuration Theory by integrating it with the Activity Theory to provide the means of evaluating the activities that the system is to perform. The modified Orlikowski model is applied to depict the relationship between institutional properties, human agents, and technology in the university setup and how this offers a more inclusive approach to ERP systems development and implementation.展开更多
Currently,the enhancement in electromagnetic interference(EMI)performance of polymeric composite generally relies on either improving electrical conductivity(σ)for stronger electromagnetic(EM)reflections or tailoring...Currently,the enhancement in electromagnetic interference(EMI)performance of polymeric composite generally relies on either improving electrical conductivity(σ)for stronger electromagnetic(EM)reflections or tailoring structure for higher EM resonances.Herein,we proposed a novel technique called cyclic pulsating pressure enhanced segregating structuration(CPP-SS),which can reinforce these two factors simultaneously.The structural information was supplied by optical microscopy(OM)and scanning electron microscopy(SEM),both of which confirmed the formation and evolution of segregate structured ultra-high molecular weight polyethylene(UHMWPE)/graphene composites.Then,the result showed that CPP-SS can significantly improve theσof samples.Ultimately,advanced specific EMI shielding efficiency of 31.1 d B/mm was achieved for UHMWPE/graphene composite at 1-mm thickness and a low graphene loading of 5 wt%.Meanwhile,it also confirmed that the intrinsic disadvantage of poor mechanical properties of conventional segregated structure composites can be surpassed.This work is believed to provide a fundamental understanding of the structural and performance evolutions of segregated structured composites prepared under CPPSS,and to bring us a simple and efficient approach for fabricating high-performance,strong and light-weight polymeric EMI shields.展开更多
<div style="text-align:justify;"> <i>Plutella xylostella</i>, pointed out as the most dangerous destroyer of cabbage<span "=""> (<i></i><i><i>Br...<div style="text-align:justify;"> <i>Plutella xylostella</i>, pointed out as the most dangerous destroyer of cabbage<span "=""> (<i></i><i><i>Brassica olerarea</i></i></span>), is a cosmopolitan species. In fact, owing to its large capacity of adaptation, <i></i><i><i>P. xylestella</i></i> colonizes any kind of area. This insect can bring about up to 90% of losses on cabbage farming. To control the insect, Senegalese farmers, very often, resort to high dose of chemical pesticides which are repetitively sprayed. The use of these chemical products gives rise to different varieties of resistant insects, which results in the emergence of different haplotypes between populations. It is in such a context that this study has been undertaken. Our objective is then to contribute to the knowledge of the genetic diversity of <i></i><i><i>P. xylostella</i></i> populations in Senegal. To hit the target, PCR- Sequencing method has been applied on samples from the five following localities: Diofior, Malika, Mboro, Santh Ndong, and Sebikotane. <i></i><i><i>P. xylostella</i></i> from Mboro is genetically different from the other populations. This fact could be due to a different way of using pesticides in this area vis-à-vis of the other localities. On the other hand, between populations of <i></i><i><i>P. xylostella</i></i> from Diofior, Malika, Santh Ndong, and Sebikotane, there is no significant genetic difference. In other respects, phylogenetic trees reveal the existence of two clades: one with individuals from Mboro and the other one with individuals from the other four localities. <i></i><i><i>P. xylostella</i></i> from Mboro distinguishes itself from other populations and then, can be regarded as a sub-population. Thus, the phylogenetic trees reveal the existence of two groups of <i></i><i><i>P. xylostella</i></i> in Senegal. </div>展开更多
Recent observations of Dwarf Satellite Galaxies (DSG) show that they have a clear tendency to stay in particular planes. Explanations with standard physics remain controversial. Recently, I proposed a new explanation ...Recent observations of Dwarf Satellite Galaxies (DSG) show that they have a clear tendency to stay in particular planes. Explanations with standard physics remain controversial. Recently, I proposed a new explanation of the galactic flat rotation curves, introducing a new cosmic acceleration due to expansion. In this paper, I apply this new acceleration to the dynamics of DSG’s (without dark matter). I show that this new acceleration implies planar structures for the DSG trajectories. More generally, it is shown that this acceleration produces a space structuration around any massive center. It remains a candidate to explain several cosmic observations without dark matter.展开更多
To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content ...To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.展开更多
This study introduces superabsorbent polymers(SAP)into recycled concrete and,through freeze-thaw cycle tests,unconfined compressive strength tests,and nuclear magnetic resonance(NMR)analysis,evaluates the freeze-thaw ...This study introduces superabsorbent polymers(SAP)into recycled concrete and,through freeze-thaw cycle tests,unconfined compressive strength tests,and nuclear magnetic resonance(NMR)analysis,evaluates the freeze-thaw resistance and durability of recycled concrete samples under varying freeze-thaw cycles.The results indicate that an appropriate addition of SAP significantly enhances the freeze-thaw resistance of recycled concrete.After 200 freeze-thaw cycles,the RS0.6 sample retained good surface integrity,demonstrating the best performance.Compared to NAC,its mass loss decreased by 1.16%,the relative dynamic modulus improved by 7.01%,and the compressive strength loss rate decreased by 5.41%.Additionally,T2 spectrum analysis revealed that adding SAP optimized the pore structure of recycled concrete and mitigated pore development during freeze-thaw cycles.As the number of freeze-thaw cycles increased,the RS0.3 and RS0.6 samples demonstrated superior frost resistance compared to NAC.However,an excessive amount of SAP increased pore expansion during subsequent freeze-thaw cycles,ultimately weakening frost resistance.展开更多
Waste glass fibers were used as the main raw materials to prepare foamed glass-ceramics with 0-14 wt%H_(3)BO_(3)as a flux agent.The effects of H_(3)BO_(3)on the crystallization process,foaming behavior,and physical pr...Waste glass fibers were used as the main raw materials to prepare foamed glass-ceramics with 0-14 wt%H_(3)BO_(3)as a flux agent.The effects of H_(3)BO_(3)on the crystallization process,foaming behavior,and physical properties of CaO-MgO-Al_(2)O_(3)-SiO_(2)foamed glass-ceramics were investigated.The results showed that the main crystalline phase of the foamed glass-ceramics was anorthite with diopside as a minor crystalline phase,which exhibited a typical surface crystallization process.The addition of H_(3)BO_(3)modified the surface of glass powders and inhibited crystal precipitation obviously.The low melting point of H_(3)BO_(3)and the decrease of crystallinity jointly promoted the growth of pores,resulting in a reduction of bulk density and an increase in porosity.The compressive strength and thermal conductivity of the samples were linearly related to the bulk density.In particular,the sample added with 10 wt%H_(3)BO_(3)exhibited excellent properties,possessing a low coefficient of thermal conductivity 0.081 W/(m·K)and relatively high compressive strength 3.36 MPa.展开更多
Cement stands as a dominant contributor to global energy consumption and carbon emissions in the construction industry.With the upgrading of infrastructure and the improvement of building standards,traditional cement ...Cement stands as a dominant contributor to global energy consumption and carbon emissions in the construction industry.With the upgrading of infrastructure and the improvement of building standards,traditional cement fails to reconcile ecological responsibility with advanced functional performance.By incorporating tailored fillers into cement matrices,the resulting composites achieve enhanced thermoelectric(TE)conversion capabilities.These materials can harness solar radiation from building envelopes and recover waste heat from indoor thermal gradients,facilitating bidirectional energy conversion.This review offers a comprehensive and timely overview of cementbased thermoelectric materials(CTEMs),integrating material design,device fabrication,and diverse applications into a holistic perspective.It summarizes recent advancements in TE performance enhancement,encompassing fillers optimization and matrices innovation.Additionally,the review consolidates fabrication strategies and performance evaluations of cement-based thermoelectric devices(CTEDs),providing detailed discussions on their roles in monitoring and protection,energy harvesting,and smart building.We also address sustainability,durability,and lifecycle considerations of CTEMs,which are essential for real-world deployment.Finally,we outline future research directions in materials design,device engineering,and scalable manufacturing to foster the practical application of CTEMs in sustainable and intelligent infrastructure.展开更多
Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always...Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always struggle to balance mechanical properties and thermal insulation,resulting in their inability to meet the demands for both washing resistance and personal protection.Herein,inspired by the natural spring-like structures of cucumber tendrils,a superelastic and washable micro/nanofibrous sponge(MNFS)based on biomimetic helical fibers is directly prepared utilizing multiple-jet electrospinning technology for high-performance thermal insulation.By regulating the conductivity of polyvinylidene fluoride solution,multiple-jet ejection and multiple-stage whipping of jets are achieved,and further control of phase separation rates enables the rapid solidification of jets to form spring-like helical fibers,which are directly entangled to assemble MNFS.The resulting MNFS exhibits superelasticity that can withstand large tensile strain(200%),1000 cyclic tensile or compression deformations,and retain good resilience even in liquid nitrogen(-196℃).Furthermore,the MNFS shows efficient thermal insulation with low thermal conductivity(24.85 mW m^(-1)K^(-1)),close to the value of dry air,and remains structural stability even after cyclic washing.This work offers new possibilities for advanced fibrous sponges in transportation,environmental,and energy applications.展开更多
Single-atom catalysts(SACs)have garnered significant attention in lithium-sulfur(Li-S)batteries for their potential to mitigate the severe polysulfide shuttle effect and sluggish redox kinetics.However,the development...Single-atom catalysts(SACs)have garnered significant attention in lithium-sulfur(Li-S)batteries for their potential to mitigate the severe polysulfide shuttle effect and sluggish redox kinetics.However,the development of highly efficient SACs and a comprehensive understanding of their structure-activity relationships remain enormously challenging.Herein,a novel kind of Fe-based SAC featuring an asymmetric FeN_(5)-TeN_(4) coordination structure was precisely designed by introducing Te atom adjacent to the Fe active center to enhance the catalytic activity.Theoretical calculations reveal that the neighboring Te atom modulates the local coordination environment of the central Fe site,elevating the d-band center closer to the Fermi level and strengthening the d-p orbital hybridization between the catalyst and sulfur species,thereby immobilizing polysulfides and improving the bidirectional catalysis of Li-S redox.Consequently,the Fe-Te atom pair catalyst endows Li-S batteries with exceptional rate performance,achieving a high specific capacity of 735 mAh g^(−1) at 5 C,and remarkable cycling stability with a low decay rate of 0.038%per cycle over 1000 cycles at 1 C.This work provides fundamental insights into the electronic structure modulation of SACs and establishes a clear correlation between precisely engineered atomic configurations and their enhanced catalytic performance in Li-S electrochemistry.展开更多
Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes...Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes with SiO_(2)and Al_(2)O_(3)ratios were investigated using various techniques.It is found that when SiO_(2)is replaced by Al_(2)O_(3),the Q^(4) to Q^(3) transition of silicon-oxygen network decreases while the aluminum-oxygen network increases,which result in the transformation of Si-O-Si bonds to Si-O-Al bonds and an increase in glass network connectivity even though the intermolecular bond strength decreases.The glass transition temperature(T_(g))increases continuously,while the thermal expansion coefficient increases and high-temperature viscosity first decreases and then increases.Meanwhile,the elastic modulus values increase from 93 to 102 GPa.This indicates that the elastic modulus is mainly affected by packing factor and dissociation energy,and elements with higher packing factors and dissociation energies supplant those with lower values,resulting in increased rigidity within the glass.展开更多
To investigate the pore structure of graphene oxide modified polymer cement mortar(GOPM)under salt-freeze-thaw(SFT)coupling effects and its impact on deterioration,this study modifies polymer cement mortar(EMCM)with g...To investigate the pore structure of graphene oxide modified polymer cement mortar(GOPM)under salt-freeze-thaw(SFT)coupling effects and its impact on deterioration,this study modifies polymer cement mortar(EMCM)with graphene oxide(GO).The micro-pore structure of GOPM is characterized using LF-NMR and SEM.Fractal theory is applied to calculate the fractal dimension of pore volume,and the deterioration patterns are analyzed based on the evolution characteristics of capillary pores.The experimental results indicate that,after 25 salt-freeze-thaw cycles(SFTc),SO2-4 ions penetrate the matrix,generating corrosion products that fill existing pores and enhance the compactness of the specimen.As the number of cycles increases,the ongoing formation and expansion of corrosion products within the matrix,combined with persistent freezing forces,and result in the degradation of the pore structure.Therefore,the mass loss rate(MLR)of the specimens shows a trend of first decreasing and then increasing,while the relative dynamic elastic modulus(RDEM)initially increases and then decreases.Compared to the PC group specimens,the G3PM group specimens show a 28.71% reduction in MLR and a 31.42% increase in RDEM after 150 SFTc.The fractal dimensions of the transition pores,capillary pores,and macropores in the G3PM specimens first increase and then decrease as the number of SFTc increases.Among them,the capillary pores show the highest correlation with MLR and RDEM,with correlation coefficients of 0.97438 and 0.98555,respectively.展开更多
GEMIN5 is a predominantly cytoplasmic multifunctional protein, known to be involved in recognizing snRNAs through its WD40 repeats domain placed at the N-terminus. A dimerization domain in the middle region acts as a ...GEMIN5 is a predominantly cytoplasmic multifunctional protein, known to be involved in recognizing snRNAs through its WD40 repeats domain placed at the N-terminus. A dimerization domain in the middle region acts as a hub for protein–protein interaction, while a non-canonical RNA-binding site is placed towards the C-terminus. The singular organization of structural domains present in GEMIN5 enables this protein to perform multiple functions through its ability to interact with distinct partners, both RNAs and proteins. This protein exerts a different role in translation regulation depending on its physiological state, such that while GEMIN5 down-regulates global RNA translation, the C-terminal half of the protein promotes translation of its mRNA. Additionally, GEMIN5 is responsible for the preferential partitioning of mRNAs into polysomes. Besides selective translation, GEMIN5 forms part of distinct ribonucleoprotein complexes, reflecting the dynamic organization of macromolecular complexes in response to internal and external signals. In accordance with its contribution to fundamental cellular processes, recent reports described clinical loss of function mutants suggesting that GEMIN5 deficiency is detrimental to cell growth and survival. Remarkably, patients carrying GEMIN5 biallelic variants suffer from neurodevelopmental delay, hypotonia, and cerebellar ataxia. Molecular analyses of individual variants, which are defective in protein dimerization, display decreased levels of ribosome association, reinforcing the involvement of the protein in translation regulation. Importantly, the number of clinical variants and the phenotypic spectrum associated with GEMIN5 disorders is increasing as the knowledge of the protein functions and the pathways linked to its activity augments. Here we discuss relevant advances concerning the functional and structural features of GEMIN5 and its separate domains in RNA-binding, protein interactome, and translation regulation, and how these data can help to understand the involvement of protein malfunction in clinical variants found in patients developing neurodevelopmental disorders.展开更多
Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is p...Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.展开更多
Lithium-ion batteries(LIBs),while dominant in energy storage due to high energy density and cycling stability,suffer from severe capacity decay,rate capability degradation,and lithium dendrite formation under low-temp...Lithium-ion batteries(LIBs),while dominant in energy storage due to high energy density and cycling stability,suffer from severe capacity decay,rate capability degradation,and lithium dendrite formation under low-temperature(LT)operation.Therefore,a more comprehensive and systematic understanding of LIB behavior at LT is urgently required.This review article comprehensively reviews recent advancements in electrolyte engineering strategies aimed at improving the low-temperature operational capabilities of LIBs.The study methodically examines critical performance-limiting mechanisms through fundamental analysis of four primary challenges:insufficient ionic conductivity under cryogenic conditions,kinetically hindered charge transfer processes,Li+transport limitations across the solidelectrolyte interphase(SEI),and uncontrolled lithium dendrite growth.The work elaborates on innovative optimization approaches encompassing lithium salt molecular design with tailored dissociation characteristics,solvent matrix optimization through dielectric constant and viscosity regulation,interfacial engineering additives for constructing low-impedance SEI layers,and gel-polymer composite electrolyte systems.Notably,particular emphasis is placed on emerging machine learning-guided electrolyte formulation strategies that enable high-throughput virtual screening of constituent combinations and prediction of structure-property relationships.These artificial intelligence-assisted rational design frameworks demonstrate significant potential for accelerating the development of next-generation LT electrolytes by establishing quantitative composition-performance correlations through advanced data-driven methodologies.展开更多
Octopuses,due to their flexible arms,marvelous adaptability,and powerful suckers,are able to effortlessly grasp and disengage various objects in the marine surrounding without causing devastation.However,manipulating ...Octopuses,due to their flexible arms,marvelous adaptability,and powerful suckers,are able to effortlessly grasp and disengage various objects in the marine surrounding without causing devastation.However,manipulating delicate objects such as soft and fragile foods underwater require gentle contact and stable adhesion,which poses a serious challenge to now available soft grippers.Inspired by the sucker infundibulum structure and flexible tentacles of octopus,herein we developed a hydraulically actuated hydrogel soft gripper with adaptive maneuverability by coupling multiple hydrogen bond-mediated supramolecular hydrogels and vat polymerization three-dimensional printing,in which hydrogel bionic sucker is composed of a tunable curvature membrane,a negative pressure cavity,and a pneumatic chamber.The design of the sucker structure with the alterable curvature membrane is conducive to realize the reliable and gentle switchable adhesion of the hydrogel soft gripper.As a proof-of-concept,the adaptive hydrogel soft gripper is capable of implement diversified underwater tasks,including gingerly grasping fragile foods like egg yolks and tofu,as well as underwater robots and vehicles that station-keeping and crawling based on switchable adhesion.This study therefore provides a transformative strategy for the design of novel soft grippers that will render promising utilities for underwater exploration soft robotics.展开更多
基金supported by the National Natural Science Foundation of China (41431177 and 41601413)the National Basic Research Program of China (2015CB954102)+1 种基金the Natural Science Research Program of Jiangsu Province, China (BK20150975 and 14KJA170001)the Outstanding Innovation Team in Colleges and Universities in Jiangsu Province, China
文摘In addition to soil samples, conventional soil maps, and experienced soil surveyors, text about soils(e.g., soil survey reports) is an important potential data source for extracting soil–environment relationships. Considering that the words describing soil–environment relationships are often mixed with unrelated words, the first step is to extract the needed words and organize them in a structured way. This paper applies natural language processing(NLP) techniques to automatically extract and structure information from soil survey reports regarding soil–environment relationships. The method includes two steps:(1) construction of a knowledge frame and(2) information extraction using either a rule-based method or a statistic-based method for different types of information. For uniformly written text information, the rule-based approach was used to extract information. These types of variables include slope, elevation, accumulated temperature, annual mean temperature, annual precipitation, and frost-free period. For information contained in text written in diverse styles, the statistic-based method was adopted. These types of variables include landform and parent material. The soil species of China soil survey reports were selected as the experimental dataset. Precision(P), recall(R), and F1-measure(F1) were used to evaluate the performances of the method. For the rule-based method, the P values were 1, the R values were above 92%, and the F1 values were above 96% for all the involved variables. For the method based on the conditional random fields(CRFs), the P, R and F1 values for the parent material were, respectively, 84.15, 83.13, and 83.64%; the values for landform were 88.33, 76.81, and 82.17%, respectively. To explore the impact of text types on the performance of the CRFs-based method, CRFs models were trained and validated separately by the descriptive texts of soil types and typical profiles. For parent material, the maximum F1 value for the descriptive text of soil types was 90.7%, while the maximum F1 value for the descriptive text of soil profiles was only 75%. For landform, the maximum F1 value for the descriptive text of soil types was 85.33%, which was similar to that of the descriptive text of soil profiles(i.e., 85.71%). These results suggest that NLP techniques are effective for the extraction and structuration of soil–environment relationship information from a text data source.
文摘This paper considers accounting regulation research from a structuration and cultural perspective. Therefore, accounting regulation research spans over three spheres of enquiry： （1） an accounting focus of standard-setting; （2） a cultural analysis in an empirical context; and （3） the use of a research methodology drawn from Anthony Giddens＇ structuration theory. In such approach, accounting regulation research analyzes the accounting regulation actors drawing upon the cultures in their standard-setting actions and interactions, referring to Giddens＇ three structural properties of meaning, power, and morality. The integration of these three spheres of enquiry is not entirely original. A few prior studies have similar combinations： Although they stress the uses and consequences of accounting systems in producing and reproducing organizational culture and negotiating meaning at the organizational level, this paper chooses the research approach of contextual analysis of accounting systems at more macro-societal and cultural levels. This different research interest and design provides this paper with its distinguishable characteristic from the prior similar studies.
文摘An integration of organization culture in the conceptualization and development of Enterprise Resource Planning Systems （ERPs） is critical for an organization to reap potential benefits of the system. In this paper, the authors present an analytical approach through the Structuration Theory： How a university can assess its culture for the purposes of design and development of the ERPs. The authors extend the Structuration Theory by integrating it with the Activity Theory to provide the means of evaluating the activities that the system is to perform. The modified Orlikowski model is applied to depict the relationship between institutional properties, human agents, and technology in the university setup and how this offers a more inclusive approach to ERP systems development and implementation.
基金financially supported by the National Key Research and Development Program of China(No.2016YFB0302300)the China Postdoctoral Science Foundation(No.2019M652883)+1 种基金the Guangdong Basic and Applied Basic Research Foundation(No.2020A1515110467)the financial support from the opening project of Guangdong provincial key laboratory of technique and equipment for macromolecular advanced manufacturing,South China University of Technology,China。
文摘Currently,the enhancement in electromagnetic interference(EMI)performance of polymeric composite generally relies on either improving electrical conductivity(σ)for stronger electromagnetic(EM)reflections or tailoring structure for higher EM resonances.Herein,we proposed a novel technique called cyclic pulsating pressure enhanced segregating structuration(CPP-SS),which can reinforce these two factors simultaneously.The structural information was supplied by optical microscopy(OM)and scanning electron microscopy(SEM),both of which confirmed the formation and evolution of segregate structured ultra-high molecular weight polyethylene(UHMWPE)/graphene composites.Then,the result showed that CPP-SS can significantly improve theσof samples.Ultimately,advanced specific EMI shielding efficiency of 31.1 d B/mm was achieved for UHMWPE/graphene composite at 1-mm thickness and a low graphene loading of 5 wt%.Meanwhile,it also confirmed that the intrinsic disadvantage of poor mechanical properties of conventional segregated structure composites can be surpassed.This work is believed to provide a fundamental understanding of the structural and performance evolutions of segregated structured composites prepared under CPPSS,and to bring us a simple and efficient approach for fabricating high-performance,strong and light-weight polymeric EMI shields.
文摘<div style="text-align:justify;"> <i>Plutella xylostella</i>, pointed out as the most dangerous destroyer of cabbage<span "=""> (<i></i><i><i>Brassica olerarea</i></i></span>), is a cosmopolitan species. In fact, owing to its large capacity of adaptation, <i></i><i><i>P. xylestella</i></i> colonizes any kind of area. This insect can bring about up to 90% of losses on cabbage farming. To control the insect, Senegalese farmers, very often, resort to high dose of chemical pesticides which are repetitively sprayed. The use of these chemical products gives rise to different varieties of resistant insects, which results in the emergence of different haplotypes between populations. It is in such a context that this study has been undertaken. Our objective is then to contribute to the knowledge of the genetic diversity of <i></i><i><i>P. xylostella</i></i> populations in Senegal. To hit the target, PCR- Sequencing method has been applied on samples from the five following localities: Diofior, Malika, Mboro, Santh Ndong, and Sebikotane. <i></i><i><i>P. xylostella</i></i> from Mboro is genetically different from the other populations. This fact could be due to a different way of using pesticides in this area vis-à-vis of the other localities. On the other hand, between populations of <i></i><i><i>P. xylostella</i></i> from Diofior, Malika, Santh Ndong, and Sebikotane, there is no significant genetic difference. In other respects, phylogenetic trees reveal the existence of two clades: one with individuals from Mboro and the other one with individuals from the other four localities. <i></i><i><i>P. xylostella</i></i> from Mboro distinguishes itself from other populations and then, can be regarded as a sub-population. Thus, the phylogenetic trees reveal the existence of two groups of <i></i><i><i>P. xylostella</i></i> in Senegal. </div>
文摘Recent observations of Dwarf Satellite Galaxies (DSG) show that they have a clear tendency to stay in particular planes. Explanations with standard physics remain controversial. Recently, I proposed a new explanation of the galactic flat rotation curves, introducing a new cosmic acceleration due to expansion. In this paper, I apply this new acceleration to the dynamics of DSG’s (without dark matter). I show that this new acceleration implies planar structures for the DSG trajectories. More generally, it is shown that this acceleration produces a space structuration around any massive center. It remains a candidate to explain several cosmic observations without dark matter.
基金Supported by the Science and Technology Cooperation and Exchange special project of Cooperation of Shanxi Province(202404041101014)the Fundamental Research Program of Shanxi Province(202403021212333)+3 种基金the Joint Funds of the National Natural Science Foundation of China(U24A20555)the Lvliang Key R&D of University-Local Cooperation(2023XDHZ10)the Initiation Fund for Doctoral Research of Taiyuan University of Science and Technology(20242026)the Outstanding Doctor Funding Award of Shanxi Province(20242080).
文摘To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.
基金Funded by the Science and Technology Program of Gansu Province(Nos.25JRRA497,23ZDFA017)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB0950000)High-level Talent Funding of Kashi。
文摘This study introduces superabsorbent polymers(SAP)into recycled concrete and,through freeze-thaw cycle tests,unconfined compressive strength tests,and nuclear magnetic resonance(NMR)analysis,evaluates the freeze-thaw resistance and durability of recycled concrete samples under varying freeze-thaw cycles.The results indicate that an appropriate addition of SAP significantly enhances the freeze-thaw resistance of recycled concrete.After 200 freeze-thaw cycles,the RS0.6 sample retained good surface integrity,demonstrating the best performance.Compared to NAC,its mass loss decreased by 1.16%,the relative dynamic modulus improved by 7.01%,and the compressive strength loss rate decreased by 5.41%.Additionally,T2 spectrum analysis revealed that adding SAP optimized the pore structure of recycled concrete and mitigated pore development during freeze-thaw cycles.As the number of freeze-thaw cycles increased,the RS0.3 and RS0.6 samples demonstrated superior frost resistance compared to NAC.However,an excessive amount of SAP increased pore expansion during subsequent freeze-thaw cycles,ultimately weakening frost resistance.
基金Funded by Shandong Provincial Youth Innovation Team Development Plan of Colleges and Universities(No.2022KJ100)National Natural Science Foundation of China(No.52172019)。
文摘Waste glass fibers were used as the main raw materials to prepare foamed glass-ceramics with 0-14 wt%H_(3)BO_(3)as a flux agent.The effects of H_(3)BO_(3)on the crystallization process,foaming behavior,and physical properties of CaO-MgO-Al_(2)O_(3)-SiO_(2)foamed glass-ceramics were investigated.The results showed that the main crystalline phase of the foamed glass-ceramics was anorthite with diopside as a minor crystalline phase,which exhibited a typical surface crystallization process.The addition of H_(3)BO_(3)modified the surface of glass powders and inhibited crystal precipitation obviously.The low melting point of H_(3)BO_(3)and the decrease of crystallinity jointly promoted the growth of pores,resulting in a reduction of bulk density and an increase in porosity.The compressive strength and thermal conductivity of the samples were linearly related to the bulk density.In particular,the sample added with 10 wt%H_(3)BO_(3)exhibited excellent properties,possessing a low coefficient of thermal conductivity 0.081 W/(m·K)and relatively high compressive strength 3.36 MPa.
基金supported by the National Natural Science Foundation of China(No.52242305).
文摘Cement stands as a dominant contributor to global energy consumption and carbon emissions in the construction industry.With the upgrading of infrastructure and the improvement of building standards,traditional cement fails to reconcile ecological responsibility with advanced functional performance.By incorporating tailored fillers into cement matrices,the resulting composites achieve enhanced thermoelectric(TE)conversion capabilities.These materials can harness solar radiation from building envelopes and recover waste heat from indoor thermal gradients,facilitating bidirectional energy conversion.This review offers a comprehensive and timely overview of cementbased thermoelectric materials(CTEMs),integrating material design,device fabrication,and diverse applications into a holistic perspective.It summarizes recent advancements in TE performance enhancement,encompassing fillers optimization and matrices innovation.Additionally,the review consolidates fabrication strategies and performance evaluations of cement-based thermoelectric devices(CTEDs),providing detailed discussions on their roles in monitoring and protection,energy harvesting,and smart building.We also address sustainability,durability,and lifecycle considerations of CTEMs,which are essential for real-world deployment.Finally,we outline future research directions in materials design,device engineering,and scalable manufacturing to foster the practical application of CTEMs in sustainable and intelligent infrastructure.
基金supported by Young Elite Scientists Sponsorship Program by China Association for Science and Technology(No.2022QNRC001)the National Natural Science Foundation of China(No.52273053)the Chenguang Program of Shanghai Education Development Foundation and Shanghai Municipal Education Commission(No.21CGA41)。
文摘Extreme cold weather seriously harms human thermoregulatory system,necessitating high-performance insulating garments to maintain body temperature.However,as the core insulating layer,advanced fibrous materials always struggle to balance mechanical properties and thermal insulation,resulting in their inability to meet the demands for both washing resistance and personal protection.Herein,inspired by the natural spring-like structures of cucumber tendrils,a superelastic and washable micro/nanofibrous sponge(MNFS)based on biomimetic helical fibers is directly prepared utilizing multiple-jet electrospinning technology for high-performance thermal insulation.By regulating the conductivity of polyvinylidene fluoride solution,multiple-jet ejection and multiple-stage whipping of jets are achieved,and further control of phase separation rates enables the rapid solidification of jets to form spring-like helical fibers,which are directly entangled to assemble MNFS.The resulting MNFS exhibits superelasticity that can withstand large tensile strain(200%),1000 cyclic tensile or compression deformations,and retain good resilience even in liquid nitrogen(-196℃).Furthermore,the MNFS shows efficient thermal insulation with low thermal conductivity(24.85 mW m^(-1)K^(-1)),close to the value of dry air,and remains structural stability even after cyclic washing.This work offers new possibilities for advanced fibrous sponges in transportation,environmental,and energy applications.
基金supported by the National Natural Science Foundation(52302284,22002086,22204096)Shanghai Sailing Program(23YF1412200)the Fundamental Research Funds for the Central Universities(22120240314).
文摘Single-atom catalysts(SACs)have garnered significant attention in lithium-sulfur(Li-S)batteries for their potential to mitigate the severe polysulfide shuttle effect and sluggish redox kinetics.However,the development of highly efficient SACs and a comprehensive understanding of their structure-activity relationships remain enormously challenging.Herein,a novel kind of Fe-based SAC featuring an asymmetric FeN_(5)-TeN_(4) coordination structure was precisely designed by introducing Te atom adjacent to the Fe active center to enhance the catalytic activity.Theoretical calculations reveal that the neighboring Te atom modulates the local coordination environment of the central Fe site,elevating the d-band center closer to the Fermi level and strengthening the d-p orbital hybridization between the catalyst and sulfur species,thereby immobilizing polysulfides and improving the bidirectional catalysis of Li-S redox.Consequently,the Fe-Te atom pair catalyst endows Li-S batteries with exceptional rate performance,achieving a high specific capacity of 735 mAh g^(−1) at 5 C,and remarkable cycling stability with a low decay rate of 0.038%per cycle over 1000 cycles at 1 C.This work provides fundamental insights into the electronic structure modulation of SACs and establishes a clear correlation between precisely engineered atomic configurations and their enhanced catalytic performance in Li-S electrochemistry.
基金Supported by the National Key Research Program(No.2024-1129-954-112)National Natural Science Foundation of China(No.52372033)Guangxi Science and Technology Major Program(No.AA24263054)。
文摘Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes with SiO_(2)and Al_(2)O_(3)ratios were investigated using various techniques.It is found that when SiO_(2)is replaced by Al_(2)O_(3),the Q^(4) to Q^(3) transition of silicon-oxygen network decreases while the aluminum-oxygen network increases,which result in the transformation of Si-O-Si bonds to Si-O-Al bonds and an increase in glass network connectivity even though the intermolecular bond strength decreases.The glass transition temperature(T_(g))increases continuously,while the thermal expansion coefficient increases and high-temperature viscosity first decreases and then increases.Meanwhile,the elastic modulus values increase from 93 to 102 GPa.This indicates that the elastic modulus is mainly affected by packing factor and dissociation energy,and elements with higher packing factors and dissociation energies supplant those with lower values,resulting in increased rigidity within the glass.
基金Funded by the National Natural Science Foundation of China(Nos.5226804252468035)。
文摘To investigate the pore structure of graphene oxide modified polymer cement mortar(GOPM)under salt-freeze-thaw(SFT)coupling effects and its impact on deterioration,this study modifies polymer cement mortar(EMCM)with graphene oxide(GO).The micro-pore structure of GOPM is characterized using LF-NMR and SEM.Fractal theory is applied to calculate the fractal dimension of pore volume,and the deterioration patterns are analyzed based on the evolution characteristics of capillary pores.The experimental results indicate that,after 25 salt-freeze-thaw cycles(SFTc),SO2-4 ions penetrate the matrix,generating corrosion products that fill existing pores and enhance the compactness of the specimen.As the number of cycles increases,the ongoing formation and expansion of corrosion products within the matrix,combined with persistent freezing forces,and result in the degradation of the pore structure.Therefore,the mass loss rate(MLR)of the specimens shows a trend of first decreasing and then increasing,while the relative dynamic elastic modulus(RDEM)initially increases and then decreases.Compared to the PC group specimens,the G3PM group specimens show a 28.71% reduction in MLR and a 31.42% increase in RDEM after 150 SFTc.The fractal dimensions of the transition pores,capillary pores,and macropores in the G3PM specimens first increase and then decrease as the number of SFTc increases.Among them,the capillary pores show the highest correlation with MLR and RDEM,with correlation coefficients of 0.97438 and 0.98555,respectively.
基金partially supported by grants PID2020-115096RB-I00 and PID2023-148273NB-I00 from Ministerio de Ciencia y Universidad (MICIU/AEI)(to EMS)。
文摘GEMIN5 is a predominantly cytoplasmic multifunctional protein, known to be involved in recognizing snRNAs through its WD40 repeats domain placed at the N-terminus. A dimerization domain in the middle region acts as a hub for protein–protein interaction, while a non-canonical RNA-binding site is placed towards the C-terminus. The singular organization of structural domains present in GEMIN5 enables this protein to perform multiple functions through its ability to interact with distinct partners, both RNAs and proteins. This protein exerts a different role in translation regulation depending on its physiological state, such that while GEMIN5 down-regulates global RNA translation, the C-terminal half of the protein promotes translation of its mRNA. Additionally, GEMIN5 is responsible for the preferential partitioning of mRNAs into polysomes. Besides selective translation, GEMIN5 forms part of distinct ribonucleoprotein complexes, reflecting the dynamic organization of macromolecular complexes in response to internal and external signals. In accordance with its contribution to fundamental cellular processes, recent reports described clinical loss of function mutants suggesting that GEMIN5 deficiency is detrimental to cell growth and survival. Remarkably, patients carrying GEMIN5 biallelic variants suffer from neurodevelopmental delay, hypotonia, and cerebellar ataxia. Molecular analyses of individual variants, which are defective in protein dimerization, display decreased levels of ribosome association, reinforcing the involvement of the protein in translation regulation. Importantly, the number of clinical variants and the phenotypic spectrum associated with GEMIN5 disorders is increasing as the knowledge of the protein functions and the pathways linked to its activity augments. Here we discuss relevant advances concerning the functional and structural features of GEMIN5 and its separate domains in RNA-binding, protein interactome, and translation regulation, and how these data can help to understand the involvement of protein malfunction in clinical variants found in patients developing neurodevelopmental disorders.
基金supported by National Natural Science Foundation of China(No.52025055 and 52275571)Basic Research Operation Fund of China(No.xzy012024024).
文摘Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.
基金the financial support from the Key Project of Shaanxi Provincial Natural Science Foundation-Key Project of Laboratory(2025SYS-SYSZD-117)the Natural Science Basic Research Program of Shaanxi(2025JCYBQN-125)+8 种基金Young Talent Fund of Xi'an Association for Science and Technology(0959202513002)the Key Industrial Chain Technology Research Program of Xi'an(24ZDCYJSGG0048)the Key Research and Development Program of Xianyang(L2023-ZDYF-SF-077)Postdoctoral Fellowship Program of CPSF(GZC20241442)Shaanxi Postdoctoral Science Foundation(2024BSHSDZZ070)Research Funds for the Interdisciplinary Projects,CHU(300104240913)the Fundamental Research Funds for the Central Universities,CHU(300102385739,300102384201,300102384103)the Scientific Innovation Practice Project of Postgraduate of Chang'an University(300103725063)the financial support from the Australian Research Council。
文摘Lithium-ion batteries(LIBs),while dominant in energy storage due to high energy density and cycling stability,suffer from severe capacity decay,rate capability degradation,and lithium dendrite formation under low-temperature(LT)operation.Therefore,a more comprehensive and systematic understanding of LIB behavior at LT is urgently required.This review article comprehensively reviews recent advancements in electrolyte engineering strategies aimed at improving the low-temperature operational capabilities of LIBs.The study methodically examines critical performance-limiting mechanisms through fundamental analysis of four primary challenges:insufficient ionic conductivity under cryogenic conditions,kinetically hindered charge transfer processes,Li+transport limitations across the solidelectrolyte interphase(SEI),and uncontrolled lithium dendrite growth.The work elaborates on innovative optimization approaches encompassing lithium salt molecular design with tailored dissociation characteristics,solvent matrix optimization through dielectric constant and viscosity regulation,interfacial engineering additives for constructing low-impedance SEI layers,and gel-polymer composite electrolyte systems.Notably,particular emphasis is placed on emerging machine learning-guided electrolyte formulation strategies that enable high-throughput virtual screening of constituent combinations and prediction of structure-property relationships.These artificial intelligence-assisted rational design frameworks demonstrate significant potential for accelerating the development of next-generation LT electrolytes by establishing quantitative composition-performance correlations through advanced data-driven methodologies.
基金the financial support from the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB0470303)the National Key Research and Development Program of China (2022YFB4600101)+5 种基金the National Natural Science Foundation of China (52175201)the Research Program of Science and Technology Department of Gansu Province (24JRRA059, 24JRRA044, and 24YFFA014)the Science Fund of Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai (AMGM2024F12)the Major Program (ZYFZFX-2) of the Lanzhou Institute of Chemical Physics, CASthe Special Research Assistant Project of the Chinese Academy of Sciencesthe Oasis Scholar of Shihezi University
文摘Octopuses,due to their flexible arms,marvelous adaptability,and powerful suckers,are able to effortlessly grasp and disengage various objects in the marine surrounding without causing devastation.However,manipulating delicate objects such as soft and fragile foods underwater require gentle contact and stable adhesion,which poses a serious challenge to now available soft grippers.Inspired by the sucker infundibulum structure and flexible tentacles of octopus,herein we developed a hydraulically actuated hydrogel soft gripper with adaptive maneuverability by coupling multiple hydrogen bond-mediated supramolecular hydrogels and vat polymerization three-dimensional printing,in which hydrogel bionic sucker is composed of a tunable curvature membrane,a negative pressure cavity,and a pneumatic chamber.The design of the sucker structure with the alterable curvature membrane is conducive to realize the reliable and gentle switchable adhesion of the hydrogel soft gripper.As a proof-of-concept,the adaptive hydrogel soft gripper is capable of implement diversified underwater tasks,including gingerly grasping fragile foods like egg yolks and tofu,as well as underwater robots and vehicles that station-keeping and crawling based on switchable adhesion.This study therefore provides a transformative strategy for the design of novel soft grippers that will render promising utilities for underwater exploration soft robotics.
