In order to enhance the NC programming efficiency and quality of aircraft structural parts （ASPs）, an intelligent NC programming pattern driven by process schemes is presented. In this pattern, the NC machining cell...In order to enhance the NC programming efficiency and quality of aircraft structural parts （ASPs）, an intelligent NC programming pattern driven by process schemes is presented. In this pattern, the NC machining cell is the minimal organizational structure in the technological process, consisting of an operation machining volume cell, and the type and parameters of the machining operation. After the machining cell construction, the final NC program can be easily obtained in a CAD/CAM system by instantiating the machining operation for each machining cell. Accordingly, how to automatically establish the machining cells is a key issue in intelligent NC program- ming. On the basis of the NC machining craft of ASP, the paper aims to make an in-depth research on this issue. Firstly, some new terms about the residual volume and the machinable volume are defined, and then, the technological process is modeled with a process scheme. Secondly, the approach to building the machining cells is introduced, in which real-time complement machining is mainly considered to avoid interference and overcutting. Thirdly, the implementing algorithm is designed and applied to the Intelligent NC Programming System of ASP. Finally, the developed algorithm is validated through two case studies.展开更多
Deformation resulting from residual stress has been a significant issue in machining.As allowance allocation can directly impact the residual stress on part deformation,it is essential for deformation control.However,...Deformation resulting from residual stress has been a significant issue in machining.As allowance allocation can directly impact the residual stress on part deformation,it is essential for deformation control.However,it is difficult to adjust allowance allocation by traditional simulation methods based on residual stress,as the residual stress cannot be accurately measured or predicted,and many unexpected factors during machining process cannot be simulated accurately.Different from traditional methods,this paper proposes an allowance allocation method based on dynamic approximation via online inspection data for deformation control of structural parts.An Autoregressive Integrated Moving Average(ARIMA)model for dynamic allowance allocation is established so as to approach the minimum deformation,which is based on the in-process deformation inspection data during the alternative machining process of upside and downside.The effectiveness of the method is verified both by simulation cases and real machining experiments of aircraft structural parts,and the results show that part deformation can be significantly reduced.展开更多
High-performance five-axis computer numerical control machine tools are widely used in the processing of Aeronautical Structural parts. With the increase of service life, the precision of CNC machine tools equipped by...High-performance five-axis computer numerical control machine tools are widely used in the processing of Aeronautical Structural parts. With the increase of service life, the precision of CNC machine tools equipped by aeronautical manufacturing enterprises is declining day by day, while the new generation of aircraft structural parts <span style="font-family:Verdana;">are</span><span style="font-family:Verdana;"> developing towards integration, large-scale, complexity, thin-walled and lightweight. It is very easy to produce dimension overshoot and surface quality defects due to unstable processing technology. The machining accuracy of aircraft structural parts is also affected by complex factors such as cutting load, cutting stability, tool error, workpiece deformation, fixture deformation, etc. Because of the complexity of structure and characteristics of Aeronautical Structural parts, the consistency and stability of cutting process are poor. It is easy to cause machining accuracy problems due to tool wear, breakage and cutting chatter. Relevant scholars have carried out a lot of basic research on NC machining accuracy control and achieved fruitful results, but the research on NC machining accuracy control of Aeronautical structural parts is still less. This paper elaborates from three aspects: error modeling method of NC machine tools, error compensation method, prediction and control of machining accuracy, and combines the characteristics of Aeronautical Structural parts, the development trend and demand of NC machining accuracy control technology are put forward.</span>展开更多
A light?weight design method of integrated structural topology and size co?optimization for the force?performance?structure of complex structural parts is presented in this paper. Firstly, the supporting function of a...A light?weight design method of integrated structural topology and size co?optimization for the force?performance?structure of complex structural parts is presented in this paper. Firstly, the supporting function of a complex structural part is built to map the force transmission, where the force exerted areas and constraints are considered as connecting structure and the structural configuration, to determine the part performance as well as the force routines. Then the connecting structure design model, aiming to optimize the static and dynamic performances on connection configuration, is developed, and the optimum design of the characteristic parameters is carried out by means of the collaborative optimization method, namely, the integrated structural topology optimization and size optimization. In this design model, the objective is to maximize the connecting stiffness. Based on the relationship between the force and the structural configuration of a part, the optimal force transmission routine that can meet the performance requirements is obtained using the structural topology optimization technology. Accordingly, the light?weight design of conceptual configuration for complex parts under multi?objective and multi?condition can be realized. Finally, based on the proposed collaborative optimization design method, the optimal performance and optimal structure of the complex parts with light weight are realized, and the reasonable structural unit configuration and size charac?teristic parameters are obtained. A bed structure of gantry?type machining center is designed by using the proposed light?weight structure design method in this paper, as an illustrative example. The bed after the design optimization is lighter 8% than original one, and the rail deformation is reduced by 5%. Moreover, the lightweight design of the bed is achieved with enhanced performance to show the effectiveness of the proposed method.展开更多
Die-forging structural parts are widely used in the main load-bearing components of aircrafts because of their excellent mechanical properties and fatigue resistance.However,the forming and heat treatment processes of...Die-forging structural parts are widely used in the main load-bearing components of aircrafts because of their excellent mechanical properties and fatigue resistance.However,the forming and heat treatment processes of die-forging structural parts are complex,leading to high levels of internal stress and a complex distribution of residual stress fields(RSFs),which affect the deformation,fatigue life,and failure of structural parts throughout their lifecycles.Hence,the global RSF can provide the basis for process control.The existing RSF inference method based on deformation force data can utilize monitoring data to infer the global RSF of a regular part.However,owing to the irregular geometry of die-forging structural parts and the complexity of the RSF,it is challenging to solve ill-conditioned problems during the inference process,which makes it difficult to obtain the RSF accurately.This paper presents a global RSF inference method for the die-forging structural parts based on the fusion of monitoring data and distribution prior.Prior knowledge was derived from the RSF distribution trends obtained through finite element analysis.This enables the low-dimensional characterization of the RSF,reducing the number of parameters required to solve the equations.The effectiveness of this method was validated in both simulation and actual environments.展开更多
Reinforced concrete buildings may experience partial damage after earthquakes or some human-induced actions.A decision about the future of those buildings requires detailed analyses,while determining the dynamic chara...Reinforced concrete buildings may experience partial damage after earthquakes or some human-induced actions.A decision about the future of those buildings requires detailed analyses,while determining the dynamic characteristics of a real building in its pre-and post-event situations can guide the analysis.Hence,this study was planned to monitor the dynamic response of an existing six-story,reinforced concrete building with regard to structural damage.The modal characteristics of the original building were initially determined by the use of operational modal analysis.Next,three steps of progressive structural damage were applied to the building.The first damage level peeled off the clear cover of a beam and three columns on a corner of the building’s ground floor.whereas the second and third levels completely razed the damaged columns.Operational modal analysis was repeated at each damage stage to extract the frequencies and detailed mode shapes.Moreover,numerical models based on the finite element method were constructed to confirm the obtained experimental findings.The well-agreed experimental and numerical findings revealed the damage sensitivity of the building’s dynamic response.The quantified amount of frequency change favored a retrofit of the partially damaged buildings rather than their replacement.展开更多
Increasing the sintering rate of powder compact is a critical challenge of powder metallurgical materials,and adjusting component distribution in particles aggregate present significant effect on the microstructure of...Increasing the sintering rate of powder compact is a critical challenge of powder metallurgical materials,and adjusting component distribution in particles aggregate present significant effect on the microstructure of sintered product,especially for multi-phase compact with local heterogeneity.Here,a case study of W–Ni–Co powder compact was adopted to illustrate the novel strategy to enhance the sintering of multi-phase compact with desired microstructure by adjusting the particle configurations.The plasma synthesis route was developed for the first time to independently adjust the configurations of W–Ni–Co nanopowders with core-shell and homogeneous structures,which facilitates to ascertain the sintering response induced exclusively by particle configurations.Comparison on sintering response further indicates that core-shell powder presents greatly promoted sintering than homogeneous one,and full-dense and uniform compact with grain size of 1.37μm was obtained by solid sintering,which is several to dozens of times smaller than that obtained by conventional liquid sintering.Theoretical and experimental Investigation on elemental immigration visualized the distinct mass diffusion behavior of powder compacts,and clarified the mass transport path promoted densification mechanism determined by powder configurations.Importantly,full-coherent phase interface induced superior strength and plasticity in alloy sintered using core-shell powder,which highlights the importance of microstructural regulation on improving the mechanical property that superior than most of previously reported tungsten heavy alloys.In summary,this work paves a new way for fast sintering of multi-phase compacts,and provides intrinsic understandings on densification mechanism of powder compact.展开更多
To deepen understanding of the evolution of coal char microstructural properties of coal char during the co-pyrolysis of coking coal with additives,this study incorporated two typical additives,coal tar pitch(CTP)and ...To deepen understanding of the evolution of coal char microstructural properties of coal char during the co-pyrolysis of coking coal with additives,this study incorporated two typical additives,coal tar pitch(CTP)and waste plastic(HDPE),into a blended coal sample and carried out pyrolysis experiments.The pyrolysis process and the microstructure of char were systematically characterized using various analytical techniques,including thermogravimetric analysis(TGA),X-ray diffraction(XRD)and Raman spectroscopy.Data correlation analysis was performed to reveal the mechanism of carbon structural ordering evolution within the critical temperature range(350−600℃)from colloidal layer formation to semi-coke conversion in coking coal,and to elucidate the regulatory effects of different additives on coal pyrolysis pathways.The results indicate that HDPE releases free radicals during high-temperature pyrolysis,accelerating the pyrolysis reaction and increase the yield of volatile components.Conversely,CTP facilitates pyrolysis at low temperatures through its light components,thereby delaying high-temperature reactions due to the colloidal layer’s effect.XRD results indicate that during the process of pyrolysis,there is a progressive decrease in the interlayer spacing of aromatic layers(d002),while the aromatic ring stacking height(L_(c))and lateral size(L_(a))undergo significant of carbon skeleton ordering.Further comparative reveals that CTP partially suppresses structural ordering at low temperatures,whereas HDPE promotes the condensation and alignment of aromatic clusters via a free radical mechanism.Raman spectroscopy reveals a two-stage reorganization mechanism in the microstructure of the coal char:the decrease in the I_(D)/I_(G)ratio between 350 and 550℃is primarily attributed to the cleavage of aliphatic side chains and cross-linking bonds,leading to a reduction in defective structures;whereas the increase in ID/IG between 550 and 600℃is closely associated with enhanced condensation reactions of aromatic structures.Correlation analysis further demonstrates progressive graphitization during pyrolysis,with a significant positive correlation(R^(2)>0.85)observed between d002 and the full width at half maximum of the G-band(FWHM-G).展开更多
The single-event susceptibility of three silicon carbide(SiC)metal-oxide-semiconductor field-effect transistor(MOSFET)power devices structures(planar,trench and double trench)is researched by the technology computer-a...The single-event susceptibility of three silicon carbide(SiC)metal-oxide-semiconductor field-effect transistor(MOSFET)power devices structures(planar,trench and double trench)is researched by the technology computer-aided design(TCAD)simulation.Comparative analysis of the heavy-ion irradiation effects on three device structures reveals distinct susceptibility characteristics.The gate oxide region is identified as the most sensitive position in planar devices,while trench and doubletrench structures exhibit no localized sensitive regions.Furthermore,the single-event susceptibility demonstrates strong depth dependence across all three structures,with enhanced vulnerability observed at greater ion penetration depths.展开更多
This paper reports the preparation of three di‑iron complexes containing a thiazole moiety.Esterification of complex[Fe_(2)(CO)_(6)(μ‑SCH_(2)CH(CH_(2)OH)S)](1)with 4‑methylthiazole‑5‑carboxylic acid gave the correspo...This paper reports the preparation of three di‑iron complexes containing a thiazole moiety.Esterification of complex[Fe_(2)(CO)_(6)(μ‑SCH_(2)CH(CH_(2)OH)S)](1)with 4‑methylthiazole‑5‑carboxylic acid gave the corresponding ester[Fe_(2)(CO)_(6)(μ‑tedt)](2),where tedt=SCH_(2)CH(CH_(2)OOC(5‑C_(3)HNSCH_(3)))S.Further reactions of complex 2 with tri(ptolyl)phosphine(tp)or tris(4‑fluorophenyl)phosphine(fp)gave the phosphine‑substituted derivatives[Fe_(2)(CO)_(5)(tp)(μ‑tedt)](3)and[Fe_(2)(CO)_(5)(fp)(μ‑tedt)](4).The structures of the newly prepared complexes were elucidated by elemental analysis,NMR,IR,and X‑ray photoelectron spectroscopy.Moreover,single‑crystal X‑ray diffraction analysis confirmed their molecular structures,showing that they contain a di‑iron core ligated by a bridged dithiolate bearing a thiazole moiety and terminal carbonyls.The electrochemical and electrocatalytic proton reduction were probed by cyclic voltammetry,revealing that three complexes can catalyze the reduction of protons to H_(2) under the electrochemical conditions.For comparison,complex 4 possessed the best efficiency with a turnover frequency of 23.5 s^(-1)at 10 mmol·L^(-1)HOAc concentration.In addition,the fungicidal activity of these complexes was also investigated in this study.CCDC:2477511,2;2477512,3;2477513,4.展开更多
Nickel-rich cathodes(NRCs)hold great promise for next-generation high-energy lithium-ion batteries(LIBs)due to high specific energy and low cost.However,the higher Ni content exacerbates the instability issues associa...Nickel-rich cathodes(NRCs)hold great promise for next-generation high-energy lithium-ion batteries(LIBs)due to high specific energy and low cost.However,the higher Ni content exacerbates the instability issues associated with structural degradation and side reactions during electrochemical cycling.Herein,we demonstrate the possibility of preparing NRCs,typically Li Ni_(0.9)Co_(0.05)Mn_(0.05)O_(2)(NCM9055),with much-improved mechanical and chemical stability based on the surface coating of the hydroxide precursors.Specifically,a conformal nanoshell containing both Al^(3+)and W^(6+)was first deposited around the precursor particles,and the following high-temperature lithiation produced the targeted NCM9055 with favorable structural features,where Al3+existed as a bulk dopant to enhance the structural stability while the high-valent W^(6+)promoted the microstructural evolution into radially-architectured elongated primary particles.Such a structural engineering benefiting from the Al^(3+)/W^(6+)co-modification endowed the prepared NCM9055 cathode(NCM9055-Al W)with much-improved cycling stability,as revealed by a high-capacity retention of 98.0%after 100 cycles(tested at 0.5 C,4.3 V)as compared to only 79.0%for the pristine cathode without Al^(3+)/W^(6+).The NCM9055-15Al W cathode also showed a high-rate capability with extraordinary structural stability against mechanical failure.Our study highlighted the enormous potential of precursor multi-element treatment as an effective tool in structural refinement of NRCs to circumvent their stability challenge for their applications in high-energy LIBs.展开更多
Transition-metal dichalcogenides hosting multiple competing structural and electronic phases are thus ideal platforms for constructing polytype heterostructures with emergent quantum properties.However,controlling pha...Transition-metal dichalcogenides hosting multiple competing structural and electronic phases are thus ideal platforms for constructing polytype heterostructures with emergent quantum properties.However,controlling phase transitions to form diverse heterostructures inside a single crystal remains challenging.In this study,we realize vertical/lateral polytype heterostructures in a hole-doped Mott insulator via thermal annealing-induced structural transitions.Raman spectroscopy,atomic force microscopy and scanning Kelvin probe force microscopy confirm the coexistence of T-H polytype heterostructures.Atomic-scale scanning tunneling microscopy/spectroscopy measurements reveal the transparent effect in 1H/1T vertical heterostructures,where positive bias voltage induces in a pronounced superposition of the√13×√13 CDW of the 1T-layer on the 1H-layer.By systematically comparing the 1T/1H and 1T/1T interfaces,we demonstrate that the metallic 1H-layer induces a Coulomb screening effect on the 1T-layer,suppressing the formation of CDW domain walls and forming more ordered electronic states.These results clarify the interfacial coupling between distinct quantum many-body phases and establish a controllable pathway for constructing two-dimensional polytype heterostructures with tunable electronic properties.展开更多
From cracking the code of viruses to mentoring the next generation of scientists,the former president of Nankai University has contributed a lot to turning microscopic discoveries into monumental shields for global he...From cracking the code of viruses to mentoring the next generation of scientists,the former president of Nankai University has contributed a lot to turning microscopic discoveries into monumental shields for global health.OVER the past 40 years,one man has distinguished himself through a deep commitment to researching protein structures of high pathogenic viruses,and published numerous significant works in top international scientific journals.展开更多
Plastome variation,including single spontaneous nucleotide substitutions and single insertions/deletions,is the major source of leaf variegation in plants.Additionally,one recent study has showed that a simple plastom...Plastome variation,including single spontaneous nucleotide substitutions and single insertions/deletions,is the major source of leaf variegation in plants.Additionally,one recent study has showed that a simple plastome structural variation,which is induced by one pair of small inverted repeats,can also result in leaf variegation.Here we show a complex plastome structural variation caused by intermolecular and intramolecular recombination across three pairs of small inverted repeats accounts for leaf variegation in a widely cultivated shrub Heptapleurum ellipticum(Araliaceae).This plastome structural variation contains two deletions and two duplications,resulting in dramatic expansion of IRs,substantial contraction of LSC and loss of 11 genes that essential for photosynthesis.Plastome heteroplasmy was detected in both green and albino sectors of variegated leaves.Relative to green sectors,albino sectors in the variegated leaves exhibit significantly reduced expression for the 11 genes lost in the mutated plastome as well as 26 other genes,but significantly increased expression for one gene related to translation apparatus.Optical and transmission electron microscopy observations showed that mesophyll cells of albino sectors possess plastids lacking grana lamellae,which likely carry the mutated plastome and contribute to albinism.In both sectors,the first layer of spongy mesophyll cells beneath the lower epidermis contains normal chloroplasts,suggesting periclinal division of the lower epidermis during development.Our study demonstrates that multiple small repeats can collectively mediate intra-and inter-molecular recombination in plastome and offers a new mechanism accounting for leaf variegation in plants.展开更多
Recent advances in geoscience have underscored the critical role of abiogenic processes in petroleum formation,especially the formation and polymerization of methane.However,whether a direct carbon-H_(2) reaction can ...Recent advances in geoscience have underscored the critical role of abiogenic processes in petroleum formation,especially the formation and polymerization of methane.However,whether a direct carbon-H_(2) reaction can produce C_(2+)hydrocarbons(e.g.,ethane and propane)beyond methane remains an open question.Here,we demonstrate the direct synthesis of ethane and propane via reactions between amorphous carbon and H_(2) under upper mantle conditions(2-10 GPa and 800-1200℃).A systematic investigation reveals that increasing structural disorder in carbon precursors,from graphite to glassy carbon-Ⅱ and carbon black,enhances the production of C_(2)-C_(3) hydrocarbons.Through integrated X-ray diffraction and reverse Monte Carlo simulations,we establish that the continuous random atomic network structures in amorphous carbon enable one-step synthesis of heavy hydrocarbons with H_(2).These models establish a direct link between atomic-scale carbon structures and the one-step synthesis of C_(2+) hydrocarbons under H_(2)-rich,high-pressure,and high-temperature conditions—potentially revealing an efficient mechanism for the abiotic production of C_(2+) hydrocarbons in the upper mantle.展开更多
Structural variation is an important source of genetic variation in wheat and have been important in the evolution of the wheat's genome.Few studies have examined the relationship between structural variations and...Structural variation is an important source of genetic variation in wheat and have been important in the evolution of the wheat's genome.Few studies have examined the relationship between structural variations and agronomy and drought tolerance.The present study identified structural chromosome variations(SCVs)in a doubled haploid(DH)population and backcross introgression lines(BC5F3)derived from Jinmai 47 and Jinmai 84 using fluorescence in situ hybridization(FISH).There are one simple translocation,10 present/absent variations(PAVs),and one copy number variation(CNV)between Jinmai 47 and Jinmai 84,which distributed in 10 chromosomes.Eight SCVs were associated with 15 agronomic traits.A PAV recombination occurred on chromosome 2A,which was associated with grain number per spike(GNS).The 1BL/1RS translocation and PAV.2D were associated with significant reductions in plant height,deriving from the effects on LI2-LI4,LI2-LI4 and UI,respectively respectively.PAV.2D was also contributed to an increase of 3.13%for GNS,1BL/1RS significantly increased spikelet number,grain length(GL),and grain thickness(GT).The effect of PAV.4A.1 on GL,PAV.6A on spike length(SL)and thousand-grain weight(TGW),PAV.6B on SL,GT and TGW were identified and verified.PAVs on chromosomes 2A,6A,1D,2D,and a CNV on chromosome 4B were associated with the drought tolerance coefficients.Additive and interaction effects among SCVs were observed.Many previously cloned key genes and yield-related QTL were found in polymorphic regions of PAV.2B,PAV.2D,and CNV.4B.Altogether,this study confirmed the genetic effect of SCVs on agronomy and drought tolerance,and identification of these SCVs will facilitate genetic improvement of wheat through marker-assisted selection.展开更多
Flexible and wearable sensors offer immense potential for rehabilitation medicine,but most rely solely on electrical signals,lacking real-time visual feedback and limiting trainee's interactivity.Inspired by the s...Flexible and wearable sensors offer immense potential for rehabilitation medicine,but most rely solely on electrical signals,lacking real-time visual feedback and limiting trainee's interactivity.Inspired by the structural coloration of Cyanocitta stelleri feathers,we developed a dual-mode sensor by utilizing black conductive polymer hydrogel(CPH)-enhanced structural color strategy.This sensor integrates a hydroxypropyl cellulose(HPC)-based structural color interface with a designed CPH sensing component.Highly visible light-absorbing CPH(absorption rate>88%)serves as the critical substrate for enhancing structural color performance.By absorbing incoherent scattered light and suppressing background interference,it significantly enhances the saturation of structural color,thereby achieving a high contrast index of 4.92.Unlike the faint and hardly visible structural colors on non-black substrates,the HPC on CPH displays vivid,highly perceptible colors and desirable mechanochromic behavior.Moreover,the CPH acts as a flexible sensing element,fortified by hydrogen and coordination bond networks,and exhibits exceptional electromechanical properties,including 867.1 kPa tensile strength,strain sensitivity(gauge factor of 4.24),and outstanding durability(over 4400 cycles).Compared to traditional single-mode sensors,the integrated sensor provides real-time visual and digital dual feedback,enhancing the accuracy and interactivity of rehabilitation assessments.This technology holds promise for advancing next-generation rehabilitation medicine.展开更多
China has set its economic growth target for 2026 in the range of 4.5-5 percent.After three consecutive years of aiming for growth of around 5 percent,the slightly adjusted range reflects a prudent assessment of a com...China has set its economic growth target for 2026 in the range of 4.5-5 percent.After three consecutive years of aiming for growth of around 5 percent,the slightly adjusted range reflects a prudent assessment of a complex global environment while still signalling a commitment to stable development.展开更多
Background:Rats are often used to prepare skin defect models.However,the skin defect sizes of the models prepared by researchers are different,and the lack of consensus on the critical-size defect makes it difficult t...Background:Rats are often used to prepare skin defect models.However,the skin defect sizes of the models prepared by researchers are different,and the lack of consensus on the critical-size defect makes it difficult to compare their research results.Methods:The time for wound closure was evaluated and recorded through gross observation.The regression equation between the healing time and the diameter of skin defect was established,which can be used to predict the healing time for a certain skin defect size in rats.Histochemical and immunohistochemical staining was used to observe the regeneration and reconstruction of skin appendages,and the functional skin repair was quantitatively scored.Results:The critical-size defect of rats was determined based on the maximum capacity of structural skin repair,and the functional skin repair was quantitatively scored based on the regeneration and reconstruction of skin appendages.The allowable range of critical-size skin defect of SD rats lies between 45 and 50 mm in diameter.The concept of structural repair and the category of functional repair of injured skin are put forward.The regression equation between the structural skin healing time and defect diameters is established.Conclusion:The allowable range of skin critical-size defect of SD rats lies between 45 and 50 mm in diameter.The regression equation between the structural skin healing time and defect diameters can be used to predict the healing time for a certain skin defect size in rats.展开更多
Achieving high energy and power densities is currently a core challenge in the fabrication of energy storage materials.Although numerous high-capacity materials have been developed,conventional planar electrodes canno...Achieving high energy and power densities is currently a core challenge in the fabrication of energy storage materials.Although numerous high-capacity materials have been developed,conventional planar electrodes cannot achieve high active material loading and efficient ion/electron transport simultaneously.By contrast,three-dimensional(3D)structures have attracted increasing interest because of their capacity to enhance active material utilization,shorten ion and electron transport pathways,reduce interfacial impedance,and provide spatial accommodation for volume expansion.Additive manufacturing(AM)technology effectively fabricates energy-storage materials with 3D structures by accurately constructing complex 3D structures via layer-by-layer deposition.Recent studies have employed AM to construct ordered 3D electrodes that can optimize ion/electron transport,regulate electric field distribution,or improve the electrode-electrolyte interface,thereby contributing to enhanced kinetic performance and cycling stability.This review systematically summarizes the applications of several AM technologies in the fabrication of energy storage materials and analyzes their respective advantages and limitations.Subsequently,the advantages of AM technology in the fabrication of energy storage materials and several major optimization strategies are comprehensively discussed.Finally,the major challenges and potential applications of AM technology in energy storage material optimization are discussed.展开更多
基金supported by National Science and Technology Major Project (No.2012ZX04010051)
文摘In order to enhance the NC programming efficiency and quality of aircraft structural parts （ASPs）, an intelligent NC programming pattern driven by process schemes is presented. In this pattern, the NC machining cell is the minimal organizational structure in the technological process, consisting of an operation machining volume cell, and the type and parameters of the machining operation. After the machining cell construction, the final NC program can be easily obtained in a CAD/CAM system by instantiating the machining operation for each machining cell. Accordingly, how to automatically establish the machining cells is a key issue in intelligent NC program- ming. On the basis of the NC machining craft of ASP, the paper aims to make an in-depth research on this issue. Firstly, some new terms about the residual volume and the machinable volume are defined, and then, the technological process is modeled with a process scheme. Secondly, the approach to building the machining cells is introduced, in which real-time complement machining is mainly considered to avoid interference and overcutting. Thirdly, the implementing algorithm is designed and applied to the Intelligent NC Programming System of ASP. Finally, the developed algorithm is validated through two case studies.
基金co-supported by the National Natural Science Foundation of China(No.51775278)National Science Fund of China for Distinguished Young Scholars(No.51925505)。
文摘Deformation resulting from residual stress has been a significant issue in machining.As allowance allocation can directly impact the residual stress on part deformation,it is essential for deformation control.However,it is difficult to adjust allowance allocation by traditional simulation methods based on residual stress,as the residual stress cannot be accurately measured or predicted,and many unexpected factors during machining process cannot be simulated accurately.Different from traditional methods,this paper proposes an allowance allocation method based on dynamic approximation via online inspection data for deformation control of structural parts.An Autoregressive Integrated Moving Average(ARIMA)model for dynamic allowance allocation is established so as to approach the minimum deformation,which is based on the in-process deformation inspection data during the alternative machining process of upside and downside.The effectiveness of the method is verified both by simulation cases and real machining experiments of aircraft structural parts,and the results show that part deformation can be significantly reduced.
文摘High-performance five-axis computer numerical control machine tools are widely used in the processing of Aeronautical Structural parts. With the increase of service life, the precision of CNC machine tools equipped by aeronautical manufacturing enterprises is declining day by day, while the new generation of aircraft structural parts <span style="font-family:Verdana;">are</span><span style="font-family:Verdana;"> developing towards integration, large-scale, complexity, thin-walled and lightweight. It is very easy to produce dimension overshoot and surface quality defects due to unstable processing technology. The machining accuracy of aircraft structural parts is also affected by complex factors such as cutting load, cutting stability, tool error, workpiece deformation, fixture deformation, etc. Because of the complexity of structure and characteristics of Aeronautical Structural parts, the consistency and stability of cutting process are poor. It is easy to cause machining accuracy problems due to tool wear, breakage and cutting chatter. Relevant scholars have carried out a lot of basic research on NC machining accuracy control and achieved fruitful results, but the research on NC machining accuracy control of Aeronautical structural parts is still less. This paper elaborates from three aspects: error modeling method of NC machine tools, error compensation method, prediction and control of machining accuracy, and combines the characteristics of Aeronautical Structural parts, the development trend and demand of NC machining accuracy control technology are put forward.</span>
基金Supported by National Science and Technology Major Project(Grant No.2015ZX04014021)
文摘A light?weight design method of integrated structural topology and size co?optimization for the force?performance?structure of complex structural parts is presented in this paper. Firstly, the supporting function of a complex structural part is built to map the force transmission, where the force exerted areas and constraints are considered as connecting structure and the structural configuration, to determine the part performance as well as the force routines. Then the connecting structure design model, aiming to optimize the static and dynamic performances on connection configuration, is developed, and the optimum design of the characteristic parameters is carried out by means of the collaborative optimization method, namely, the integrated structural topology optimization and size optimization. In this design model, the objective is to maximize the connecting stiffness. Based on the relationship between the force and the structural configuration of a part, the optimal force transmission routine that can meet the performance requirements is obtained using the structural topology optimization technology. Accordingly, the light?weight design of conceptual configuration for complex parts under multi?objective and multi?condition can be realized. Finally, based on the proposed collaborative optimization design method, the optimal performance and optimal structure of the complex parts with light weight are realized, and the reasonable structural unit configuration and size charac?teristic parameters are obtained. A bed structure of gantry?type machining center is designed by using the proposed light?weight structure design method in this paper, as an illustrative example. The bed after the design optimization is lighter 8% than original one, and the rail deformation is reduced by 5%. Moreover, the lightweight design of the bed is achieved with enhanced performance to show the effectiveness of the proposed method.
基金funded by the National Natural Science Foundation of China,No.52175467the National Science Fund of China for Distinguished Young Scholars,No.51925505the Shanghai Aerospace Science and Technology Innovation Fund,No.sast2022-056.
文摘Die-forging structural parts are widely used in the main load-bearing components of aircrafts because of their excellent mechanical properties and fatigue resistance.However,the forming and heat treatment processes of die-forging structural parts are complex,leading to high levels of internal stress and a complex distribution of residual stress fields(RSFs),which affect the deformation,fatigue life,and failure of structural parts throughout their lifecycles.Hence,the global RSF can provide the basis for process control.The existing RSF inference method based on deformation force data can utilize monitoring data to infer the global RSF of a regular part.However,owing to the irregular geometry of die-forging structural parts and the complexity of the RSF,it is challenging to solve ill-conditioned problems during the inference process,which makes it difficult to obtain the RSF accurately.This paper presents a global RSF inference method for the die-forging structural parts based on the fusion of monitoring data and distribution prior.Prior knowledge was derived from the RSF distribution trends obtained through finite element analysis.This enables the low-dimensional characterization of the RSF,reducing the number of parameters required to solve the equations.The effectiveness of this method was validated in both simulation and actual environments.
基金supported by the Scientific and Technological Research Council of Türkiye(TUBITAK)under Research Grant 116M254.
文摘Reinforced concrete buildings may experience partial damage after earthquakes or some human-induced actions.A decision about the future of those buildings requires detailed analyses,while determining the dynamic characteristics of a real building in its pre-and post-event situations can guide the analysis.Hence,this study was planned to monitor the dynamic response of an existing six-story,reinforced concrete building with regard to structural damage.The modal characteristics of the original building were initially determined by the use of operational modal analysis.Next,three steps of progressive structural damage were applied to the building.The first damage level peeled off the clear cover of a beam and three columns on a corner of the building’s ground floor.whereas the second and third levels completely razed the damaged columns.Operational modal analysis was repeated at each damage stage to extract the frequencies and detailed mode shapes.Moreover,numerical models based on the finite element method were constructed to confirm the obtained experimental findings.The well-agreed experimental and numerical findings revealed the damage sensitivity of the building’s dynamic response.The quantified amount of frequency change favored a retrofit of the partially damaged buildings rather than their replacement.
基金supported by the National Natural Science Foundation of China(No.52130407,52174342,52441408)Beijing Natural Science Foundation(No.2232044,IS23050).
文摘Increasing the sintering rate of powder compact is a critical challenge of powder metallurgical materials,and adjusting component distribution in particles aggregate present significant effect on the microstructure of sintered product,especially for multi-phase compact with local heterogeneity.Here,a case study of W–Ni–Co powder compact was adopted to illustrate the novel strategy to enhance the sintering of multi-phase compact with desired microstructure by adjusting the particle configurations.The plasma synthesis route was developed for the first time to independently adjust the configurations of W–Ni–Co nanopowders with core-shell and homogeneous structures,which facilitates to ascertain the sintering response induced exclusively by particle configurations.Comparison on sintering response further indicates that core-shell powder presents greatly promoted sintering than homogeneous one,and full-dense and uniform compact with grain size of 1.37μm was obtained by solid sintering,which is several to dozens of times smaller than that obtained by conventional liquid sintering.Theoretical and experimental Investigation on elemental immigration visualized the distinct mass diffusion behavior of powder compacts,and clarified the mass transport path promoted densification mechanism determined by powder configurations.Importantly,full-coherent phase interface induced superior strength and plasticity in alloy sintered using core-shell powder,which highlights the importance of microstructural regulation on improving the mechanical property that superior than most of previously reported tungsten heavy alloys.In summary,this work paves a new way for fast sintering of multi-phase compacts,and provides intrinsic understandings on densification mechanism of powder compact.
基金Supported by National Natural Science Foundation of China(22378180,22078141)Education Department Foundation of Liaoning Province(JYTMS20230960)。
文摘To deepen understanding of the evolution of coal char microstructural properties of coal char during the co-pyrolysis of coking coal with additives,this study incorporated two typical additives,coal tar pitch(CTP)and waste plastic(HDPE),into a blended coal sample and carried out pyrolysis experiments.The pyrolysis process and the microstructure of char were systematically characterized using various analytical techniques,including thermogravimetric analysis(TGA),X-ray diffraction(XRD)and Raman spectroscopy.Data correlation analysis was performed to reveal the mechanism of carbon structural ordering evolution within the critical temperature range(350−600℃)from colloidal layer formation to semi-coke conversion in coking coal,and to elucidate the regulatory effects of different additives on coal pyrolysis pathways.The results indicate that HDPE releases free radicals during high-temperature pyrolysis,accelerating the pyrolysis reaction and increase the yield of volatile components.Conversely,CTP facilitates pyrolysis at low temperatures through its light components,thereby delaying high-temperature reactions due to the colloidal layer’s effect.XRD results indicate that during the process of pyrolysis,there is a progressive decrease in the interlayer spacing of aromatic layers(d002),while the aromatic ring stacking height(L_(c))and lateral size(L_(a))undergo significant of carbon skeleton ordering.Further comparative reveals that CTP partially suppresses structural ordering at low temperatures,whereas HDPE promotes the condensation and alignment of aromatic clusters via a free radical mechanism.Raman spectroscopy reveals a two-stage reorganization mechanism in the microstructure of the coal char:the decrease in the I_(D)/I_(G)ratio between 350 and 550℃is primarily attributed to the cleavage of aliphatic side chains and cross-linking bonds,leading to a reduction in defective structures;whereas the increase in ID/IG between 550 and 600℃is closely associated with enhanced condensation reactions of aromatic structures.Correlation analysis further demonstrates progressive graphitization during pyrolysis,with a significant positive correlation(R^(2)>0.85)observed between d002 and the full width at half maximum of the G-band(FWHM-G).
基金National Key Research and Development Program of China(2023YFA1609000)National Natural Science Foundation of China(62474190,U22B2043,U2267210)。
文摘The single-event susceptibility of three silicon carbide(SiC)metal-oxide-semiconductor field-effect transistor(MOSFET)power devices structures(planar,trench and double trench)is researched by the technology computer-aided design(TCAD)simulation.Comparative analysis of the heavy-ion irradiation effects on three device structures reveals distinct susceptibility characteristics.The gate oxide region is identified as the most sensitive position in planar devices,while trench and doubletrench structures exhibit no localized sensitive regions.Furthermore,the single-event susceptibility demonstrates strong depth dependence across all three structures,with enhanced vulnerability observed at greater ion penetration depths.
文摘This paper reports the preparation of three di‑iron complexes containing a thiazole moiety.Esterification of complex[Fe_(2)(CO)_(6)(μ‑SCH_(2)CH(CH_(2)OH)S)](1)with 4‑methylthiazole‑5‑carboxylic acid gave the corresponding ester[Fe_(2)(CO)_(6)(μ‑tedt)](2),where tedt=SCH_(2)CH(CH_(2)OOC(5‑C_(3)HNSCH_(3)))S.Further reactions of complex 2 with tri(ptolyl)phosphine(tp)or tris(4‑fluorophenyl)phosphine(fp)gave the phosphine‑substituted derivatives[Fe_(2)(CO)_(5)(tp)(μ‑tedt)](3)and[Fe_(2)(CO)_(5)(fp)(μ‑tedt)](4).The structures of the newly prepared complexes were elucidated by elemental analysis,NMR,IR,and X‑ray photoelectron spectroscopy.Moreover,single‑crystal X‑ray diffraction analysis confirmed their molecular structures,showing that they contain a di‑iron core ligated by a bridged dithiolate bearing a thiazole moiety and terminal carbonyls.The electrochemical and electrocatalytic proton reduction were probed by cyclic voltammetry,revealing that three complexes can catalyze the reduction of protons to H_(2) under the electrochemical conditions.For comparison,complex 4 possessed the best efficiency with a turnover frequency of 23.5 s^(-1)at 10 mmol·L^(-1)HOAc concentration.In addition,the fungicidal activity of these complexes was also investigated in this study.CCDC:2477511,2;2477512,3;2477513,4.
基金supported by the National Key R&D Program of China(Grant No.2022YFB2404402)the National Natural Science Foundation of China(Grant Nos.22025507,22421001,and 22409200)+1 种基金the Strategic Priority Research Program of the Chinese Academy of SciencesGrant No.XDB 1040200。
文摘Nickel-rich cathodes(NRCs)hold great promise for next-generation high-energy lithium-ion batteries(LIBs)due to high specific energy and low cost.However,the higher Ni content exacerbates the instability issues associated with structural degradation and side reactions during electrochemical cycling.Herein,we demonstrate the possibility of preparing NRCs,typically Li Ni_(0.9)Co_(0.05)Mn_(0.05)O_(2)(NCM9055),with much-improved mechanical and chemical stability based on the surface coating of the hydroxide precursors.Specifically,a conformal nanoshell containing both Al^(3+)and W^(6+)was first deposited around the precursor particles,and the following high-temperature lithiation produced the targeted NCM9055 with favorable structural features,where Al3+existed as a bulk dopant to enhance the structural stability while the high-valent W^(6+)promoted the microstructural evolution into radially-architectured elongated primary particles.Such a structural engineering benefiting from the Al^(3+)/W^(6+)co-modification endowed the prepared NCM9055 cathode(NCM9055-Al W)with much-improved cycling stability,as revealed by a high-capacity retention of 98.0%after 100 cycles(tested at 0.5 C,4.3 V)as compared to only 79.0%for the pristine cathode without Al^(3+)/W^(6+).The NCM9055-15Al W cathode also showed a high-rate capability with extraordinary structural stability against mechanical failure.Our study highlighted the enormous potential of precursor multi-element treatment as an effective tool in structural refinement of NRCs to circumvent their stability challenge for their applications in high-energy LIBs.
基金supported by the National Natural Science Foundation of China (Grant Nos.92477128,92580137,92477205,12374200,11604063,11974422,and 12104504)the National Key R&D Program of China (MOST) (Grant No.2023YFA1406500)+3 种基金the Strategic Priority Research Program (Chinese Academy of Sciences,CAS) (Grant No.XDB30000000)the Fundamental Research Funds for the Central Universities and Research Funds of Renmin University of China (Grant No.21XNLG27)supported by the Outstanding Innovative Talents Cultivation Funded Programs 2023 of the Renmin University of Chinaan outcome of “Two-dimensional anisotropic series of materials FePd2+xTe2:a structural modulation study from the atomic scale to the mesoscopic scale” (RUC25QSDL128),funded by the “Qiushi Academic-Dongliang” Talent Cultivation Project at Renmin University of China in 2025。
文摘Transition-metal dichalcogenides hosting multiple competing structural and electronic phases are thus ideal platforms for constructing polytype heterostructures with emergent quantum properties.However,controlling phase transitions to form diverse heterostructures inside a single crystal remains challenging.In this study,we realize vertical/lateral polytype heterostructures in a hole-doped Mott insulator via thermal annealing-induced structural transitions.Raman spectroscopy,atomic force microscopy and scanning Kelvin probe force microscopy confirm the coexistence of T-H polytype heterostructures.Atomic-scale scanning tunneling microscopy/spectroscopy measurements reveal the transparent effect in 1H/1T vertical heterostructures,where positive bias voltage induces in a pronounced superposition of the√13×√13 CDW of the 1T-layer on the 1H-layer.By systematically comparing the 1T/1H and 1T/1T interfaces,we demonstrate that the metallic 1H-layer induces a Coulomb screening effect on the 1T-layer,suppressing the formation of CDW domain walls and forming more ordered electronic states.These results clarify the interfacial coupling between distinct quantum many-body phases and establish a controllable pathway for constructing two-dimensional polytype heterostructures with tunable electronic properties.
文摘From cracking the code of viruses to mentoring the next generation of scientists,the former president of Nankai University has contributed a lot to turning microscopic discoveries into monumental shields for global health.OVER the past 40 years,one man has distinguished himself through a deep commitment to researching protein structures of high pathogenic viruses,and published numerous significant works in top international scientific journals.
基金supported financially by the National Natural Science Foundation of China(31811530297 and 32170217).
文摘Plastome variation,including single spontaneous nucleotide substitutions and single insertions/deletions,is the major source of leaf variegation in plants.Additionally,one recent study has showed that a simple plastome structural variation,which is induced by one pair of small inverted repeats,can also result in leaf variegation.Here we show a complex plastome structural variation caused by intermolecular and intramolecular recombination across three pairs of small inverted repeats accounts for leaf variegation in a widely cultivated shrub Heptapleurum ellipticum(Araliaceae).This plastome structural variation contains two deletions and two duplications,resulting in dramatic expansion of IRs,substantial contraction of LSC and loss of 11 genes that essential for photosynthesis.Plastome heteroplasmy was detected in both green and albino sectors of variegated leaves.Relative to green sectors,albino sectors in the variegated leaves exhibit significantly reduced expression for the 11 genes lost in the mutated plastome as well as 26 other genes,but significantly increased expression for one gene related to translation apparatus.Optical and transmission electron microscopy observations showed that mesophyll cells of albino sectors possess plastids lacking grana lamellae,which likely carry the mutated plastome and contribute to albinism.In both sectors,the first layer of spongy mesophyll cells beneath the lower epidermis contains normal chloroplasts,suggesting periclinal division of the lower epidermis during development.Our study demonstrates that multiple small repeats can collectively mediate intra-and inter-molecular recombination in plastome and offers a new mechanism accounting for leaf variegation in plants.
基金mainly supported by the Natural Science Foundation of China (Grant Nos. 52288102, 52090020, and 52372261)the Natural Science Foundation of Hebei Province (Grant No. E202403045)+1 种基金the S&T Program of Hebei (Grant No. 225A1102D)the Ministry of Education Chang Jiang Scholar Professor Program (Grant No. T2022241)
文摘Recent advances in geoscience have underscored the critical role of abiogenic processes in petroleum formation,especially the formation and polymerization of methane.However,whether a direct carbon-H_(2) reaction can produce C_(2+)hydrocarbons(e.g.,ethane and propane)beyond methane remains an open question.Here,we demonstrate the direct synthesis of ethane and propane via reactions between amorphous carbon and H_(2) under upper mantle conditions(2-10 GPa and 800-1200℃).A systematic investigation reveals that increasing structural disorder in carbon precursors,from graphite to glassy carbon-Ⅱ and carbon black,enhances the production of C_(2)-C_(3) hydrocarbons.Through integrated X-ray diffraction and reverse Monte Carlo simulations,we establish that the continuous random atomic network structures in amorphous carbon enable one-step synthesis of heavy hydrocarbons with H_(2).These models establish a direct link between atomic-scale carbon structures and the one-step synthesis of C_(2+) hydrocarbons under H_(2)-rich,high-pressure,and high-temperature conditions—potentially revealing an efficient mechanism for the abiotic production of C_(2+) hydrocarbons in the upper mantle.
基金supported by the Science and Technology Major Project of Shanxi Province,China(202201140601025-2,202302140601001)the Agricultural Science Research Project of Shanxi Agricultural University,China(2023BQ108)+1 种基金the Senior Foreign Experts Introducing Project,China(G202204011L)the Science and Technology Innovation Young Talent Team of Shanxi Province,China(202204051001019)。
文摘Structural variation is an important source of genetic variation in wheat and have been important in the evolution of the wheat's genome.Few studies have examined the relationship between structural variations and agronomy and drought tolerance.The present study identified structural chromosome variations(SCVs)in a doubled haploid(DH)population and backcross introgression lines(BC5F3)derived from Jinmai 47 and Jinmai 84 using fluorescence in situ hybridization(FISH).There are one simple translocation,10 present/absent variations(PAVs),and one copy number variation(CNV)between Jinmai 47 and Jinmai 84,which distributed in 10 chromosomes.Eight SCVs were associated with 15 agronomic traits.A PAV recombination occurred on chromosome 2A,which was associated with grain number per spike(GNS).The 1BL/1RS translocation and PAV.2D were associated with significant reductions in plant height,deriving from the effects on LI2-LI4,LI2-LI4 and UI,respectively respectively.PAV.2D was also contributed to an increase of 3.13%for GNS,1BL/1RS significantly increased spikelet number,grain length(GL),and grain thickness(GT).The effect of PAV.4A.1 on GL,PAV.6A on spike length(SL)and thousand-grain weight(TGW),PAV.6B on SL,GT and TGW were identified and verified.PAVs on chromosomes 2A,6A,1D,2D,and a CNV on chromosome 4B were associated with the drought tolerance coefficients.Additive and interaction effects among SCVs were observed.Many previously cloned key genes and yield-related QTL were found in polymorphic regions of PAV.2B,PAV.2D,and CNV.4B.Altogether,this study confirmed the genetic effect of SCVs on agronomy and drought tolerance,and identification of these SCVs will facilitate genetic improvement of wheat through marker-assisted selection.
基金supported by the Science and Technology Development Fund,Macao SAR(0065/2023/AFJ,0116/2022/A3)the National Natural Science Foundation of China(52402166)+4 种基金the Natural Science Foundation of Guangdong Province(2025A1515011120)the Australian Research Council(DE220100154)the financial support from the Science and Technology Development Fund(FDCT),Macao SAR(No.0149/2022/A),and(No.0046/2024/AFJ)Guangdong Science and Technology Department(2023QN10C305)for this workthe financial support from the National Natural Science Foundation of China(Grant No.22305185)。
文摘Flexible and wearable sensors offer immense potential for rehabilitation medicine,but most rely solely on electrical signals,lacking real-time visual feedback and limiting trainee's interactivity.Inspired by the structural coloration of Cyanocitta stelleri feathers,we developed a dual-mode sensor by utilizing black conductive polymer hydrogel(CPH)-enhanced structural color strategy.This sensor integrates a hydroxypropyl cellulose(HPC)-based structural color interface with a designed CPH sensing component.Highly visible light-absorbing CPH(absorption rate>88%)serves as the critical substrate for enhancing structural color performance.By absorbing incoherent scattered light and suppressing background interference,it significantly enhances the saturation of structural color,thereby achieving a high contrast index of 4.92.Unlike the faint and hardly visible structural colors on non-black substrates,the HPC on CPH displays vivid,highly perceptible colors and desirable mechanochromic behavior.Moreover,the CPH acts as a flexible sensing element,fortified by hydrogen and coordination bond networks,and exhibits exceptional electromechanical properties,including 867.1 kPa tensile strength,strain sensitivity(gauge factor of 4.24),and outstanding durability(over 4400 cycles).Compared to traditional single-mode sensors,the integrated sensor provides real-time visual and digital dual feedback,enhancing the accuracy and interactivity of rehabilitation assessments.This technology holds promise for advancing next-generation rehabilitation medicine.
文摘China has set its economic growth target for 2026 in the range of 4.5-5 percent.After three consecutive years of aiming for growth of around 5 percent,the slightly adjusted range reflects a prudent assessment of a complex global environment while still signalling a commitment to stable development.
基金National Key Research and Development Program of China,Grant/Award Number:2023YFC2410403。
文摘Background:Rats are often used to prepare skin defect models.However,the skin defect sizes of the models prepared by researchers are different,and the lack of consensus on the critical-size defect makes it difficult to compare their research results.Methods:The time for wound closure was evaluated and recorded through gross observation.The regression equation between the healing time and the diameter of skin defect was established,which can be used to predict the healing time for a certain skin defect size in rats.Histochemical and immunohistochemical staining was used to observe the regeneration and reconstruction of skin appendages,and the functional skin repair was quantitatively scored.Results:The critical-size defect of rats was determined based on the maximum capacity of structural skin repair,and the functional skin repair was quantitatively scored based on the regeneration and reconstruction of skin appendages.The allowable range of critical-size skin defect of SD rats lies between 45 and 50 mm in diameter.The concept of structural repair and the category of functional repair of injured skin are put forward.The regression equation between the structural skin healing time and defect diameters is established.Conclusion:The allowable range of skin critical-size defect of SD rats lies between 45 and 50 mm in diameter.The regression equation between the structural skin healing time and defect diameters can be used to predict the healing time for a certain skin defect size in rats.
基金support of the National Natural Science Foundation of China(No.52574411)Beijing Natural Science Foundation(No.2242043).
文摘Achieving high energy and power densities is currently a core challenge in the fabrication of energy storage materials.Although numerous high-capacity materials have been developed,conventional planar electrodes cannot achieve high active material loading and efficient ion/electron transport simultaneously.By contrast,three-dimensional(3D)structures have attracted increasing interest because of their capacity to enhance active material utilization,shorten ion and electron transport pathways,reduce interfacial impedance,and provide spatial accommodation for volume expansion.Additive manufacturing(AM)technology effectively fabricates energy-storage materials with 3D structures by accurately constructing complex 3D structures via layer-by-layer deposition.Recent studies have employed AM to construct ordered 3D electrodes that can optimize ion/electron transport,regulate electric field distribution,or improve the electrode-electrolyte interface,thereby contributing to enhanced kinetic performance and cycling stability.This review systematically summarizes the applications of several AM technologies in the fabrication of energy storage materials and analyzes their respective advantages and limitations.Subsequently,the advantages of AM technology in the fabrication of energy storage materials and several major optimization strategies are comprehensively discussed.Finally,the major challenges and potential applications of AM technology in energy storage material optimization are discussed.
