It is a challenge to determine the dominant topological characteristics of mechanical properties of adhesive interfaces.In this paper,we used graph theory and molecular dynamics simulation to investigate the influence...It is a challenge to determine the dominant topological characteristics of mechanical properties of adhesive interfaces.In this paper,we used graph theory and molecular dynamics simulation to investigate the influence of topological characteristics on the strength and toughness of highly cross-linked polymer interface systems.Based on the microstructure of the adhesive system,we extracted the dominant topological characteristics,including the connectivity degree(D)that determines the yield strength,and the average node-path(P)and the simple cycles proportions(R)that determine the deformability and load-bearing capacity during the void propagation respectively,which co-determine the toughness.The influence of the wall-effect on the dominant topological characteristics was also analyzed.The results showed that the interfacial yield strength increases with the increase of D,while the toughness increases with the increase of P and R.The wall-effect has a significant influence on D,P,and R.The strong wall-effect causes the enrichment of amino groups near the wall and insufficient cross-linking away from the wall,leading to the lower D and R,i.e.,the lower yield strength and load-bearing capacity during the void propagation.With the attenuation of the wall-effect,the D increases gradually,while the P and the R first increase and then decrease,showing an optimized wall-effect for the toughness of the adhesive interface.This paper reveals the dominant topological characteristics of adhesive interfacial strength and toughness,providing a new way to modulate the mechanical properties of polymer adhesive interface systems.展开更多
Based on the 3 factors and 3 levels orthogonal experiment method,compositional effects of Mg,Si,and Ti addition on the microstructures,tensile properties,and fracture behaviors of the high-pressure die-casting Al-x Mg...Based on the 3 factors and 3 levels orthogonal experiment method,compositional effects of Mg,Si,and Ti addition on the microstructures,tensile properties,and fracture behaviors of the high-pressure die-casting Al-x Mg-y Si-z Ti alloys have been investigated.The analysis of variance shows that both Mg and Si apparently infl uence the tensile properties of the alloys,while Ti does not.The tensile mechanical properties are comprehensively infl uenced by the amount of eutectic phase(α-Al+Mg2Si),the average grain size,and the content of Mg dissolved intoα-Al matrix.The optimized alloy is Al-7.49 Mg-3.08 Si-0.01 Ti(wt%),which exhibits tensile yield strength of 219 MPa,ultimate tensile strength of 401 MPa,and elongation of 10.5%.Furthermore,contour maps,showing the relationship among compositions,microstructure characteristics,and the tensile properties are constructed,which provide guidelines for developing high strength and toughness Al–Mg–Si–Ti alloys for high-pressure die-casting.展开更多
The effect of W on the microstructure and the mechanical properties of ultrahigh strength low alloy steels was carried out. The microstructure of 30Cr3Si2Mn2NiMoNb and 30Cr3Si2Mn2NiMoNbW steels under quenched conditio...The effect of W on the microstructure and the mechanical properties of ultrahigh strength low alloy steels was carried out. The microstructure of 30Cr3Si2Mn2NiMoNb and 30Cr3Si2Mn2NiMoNbW steels under quenched conditions were investigated by metallographic microscope, scanning electron microscope （SEM）, X-ray diffrac- tion （XRD）, and transmission electron microscope （TEM）. Thermodynamic cal- culation was also conducted. The results showed that the addition of W made undissolved carbides more and finer, which exerted strong pinning force on migrat- ing packet boundary and improved tensile strength significantly. M6C particles in 30Cr3Si2Mn2NiMoNb steel were disappeared above 1193 K, while the M6C particles in 30Cr3Si2Mn2NiMoNbW steel were disappeared above 1253 K, the calculation results were in agreement with the experimental.展开更多
High-nitrogen stainless bearing steel(HNSBS)with ultra-high tensile strength(∼2403 MPa)and good toughness(∼80.0 J)was obtained by V-microalloying,overcoming the strength-toughness trade-off of conventional V-free HN...High-nitrogen stainless bearing steel(HNSBS)with ultra-high tensile strength(∼2403 MPa)and good toughness(∼80.0 J)was obtained by V-microalloying,overcoming the strength-toughness trade-off of conventional V-free HNSBS.In this work,since V-microalloying facilitated the enrichment of interstitial atoms(C and N)in precipitates,the content of interstitial atoms in the matrix was reduced accordingly(i.e.,interstitial partitioning).On the one hand,V-microalloying reduced the substantial intergranular precipitates and transformed the precipitates from M_(23)C_(6)+M_(2)N into V-containing M_(23)C_(6)+M_(2)N+MN with multi-scale particle sizes,causing a coupling strengthening effect,which contributed to the toughness and additional strength increase.On the other hand,V-microalloying controlled interstitial partitioning,effectively refined coarse retained austenite(RA),increased the fraction of dislocation martensite,and reduced the fraction of twin martensite.The more film-like RA and dislocation martensite with high dislocation density coordinated plastic deformation and prevented crack propagation,thus obviously enhancing the strength and toughness of 0.2 V steel.This study provides a new route to develop high-performance HNSBS for aerospace applications.展开更多
To improve the competitive relationship between strength and toughness,the effect of low undercooling in austenite(γ)on the microstructure and mechanical properties of commercial vanadium-containing wheel steels was ...To improve the competitive relationship between strength and toughness,the effect of low undercooling in austenite(γ)on the microstructure and mechanical properties of commercial vanadium-containing wheel steels was studied using an optical microscope(OM),a scanning electron microscope(SEM),a transmission electron microscope(TEM),and mechanical property tests.The results show that when the wheel steel is slightly cooled to an appropriate temperature above A c3 point for a short time after it has been austenitized at an elevated temperature,the solid-solved vanadium is pre-precipitated in the form of V(C,N)second phase semicoherent with the matrix in the originalγgrain.This phase hardly participates in matrix strengthening.Due to the small mismatch between V(C,N)and ferrite(α),during the subsequent-cooling phase transformation stage,the pre-precipitated second phase becomes theαnucleation point,causing granular and ellipsoidal intragranular ferrite(IGF,with an average size of 4-6μm)to nucleate in the originalγ.The IGF production and strength loss increases with the increasing undercooling degree.Based on this,Masteel Co.,Ltd.has developed a new heat-treatment step-cooling process that can promote the formation of IGF,considerably improving the level and uniformity of fracture toughness on the premise that the strength and hardness of the wheel are almost unchanged.展开更多
The demand for oil casing steel with ultra-high strength and excellent impact toughness for safe application in ultra-deep wells is pressing.In improving the combination of strength,ductility,and impact toughness,the ...The demand for oil casing steel with ultra-high strength and excellent impact toughness for safe application in ultra-deep wells is pressing.In improving the combination of strength,ductility,and impact toughness,the designed Cr-Mo-V micro-alloyed oil casing steel was quenched at 800,900,and 1000℃,followed by tempering at 600,680,and 760℃,respectively,to obtain distinct microstruc-tures.The results showed that the microstructure of the samples quenched at 800℃ followed by tempering comprised untransformed ferrite and large undissolved carbides,which considerably deteriorated tensile strength and impact toughness.For other conditions,the nuc-leated carbides and the boundaries are key factors that balance the tensile strength from 1226 to 971 MPa and the impact toughness from 65 to 236 J.From the perspective of carbide,optimal precipitation strengthening is achieved with a smaller carbide size obtained by a low tempering temperature of 600℃,while larger-sized carbides would remarkably soften the matrix to improve the toughness but deteriorate the tensile strength.Additionally,an increase in prior austenite grain size with the corresponding enlarged sub-boundaries obtained by high quenching temperatures substantially diminishes grain refinement strengthening,dislocation strengthening,and the energy absorbed in the crack propagation process,which is unfavorable to strength and toughness.展开更多
Renewable 2,5-furandicarboxylic acid-based polyesters are one of the most promising materials for achieving plastic replacement in the age of energy and environmental crisis.However,their properties still cannot compe...Renewable 2,5-furandicarboxylic acid-based polyesters are one of the most promising materials for achieving plastic replacement in the age of energy and environmental crisis.However,their properties still cannot compete with those of petrochemical-based plastics,owing to insufficient molecular and/or microstructure designs.Herein,we utilize the Ti_(3)C_(2)T_(x)-based MXene nanosheets for decorating carbon nanotube(CNT)and obtaining the structurally stable and highly dispersed dendritic heterostructured MXene@CNT,that can act as multi-roles,i.e.,polycondensation catalyst,crystal nucleator,and interface enhancer of polyester.The biobased MXene@CNT/polybutylene furandicarboxylate(PBF)(denoted as MCP)nanocomposites are synthesized by the strategy of“in situ catalytic polymerization and hot-pressing”.Benefiting from the multi-scale interactions(i.e.,covalent bonds,hydrogen bonds,and physical interlocks)in hybrid structure,the MCP presents exceptional mechanical strength(≈101 MPa),stiffness(≈3.1 GPa),toughness(≈130 MJ m^(-3)),and barrier properties(e.g.,O_(2)0.0187 barrer,CO_(2)0.0264 barrer,and H2O 1.57×10^(-14) g cm cm^(-2) s Pa)that are higher than most reported bio-based materials and engineering plastics.Moreover,it also displays satisfactory multifunctionality with high reprocessability(90%strength retention after 5 recycling),UV resistance(blocking 85%UVA rays),and solvent-resistant properties.As a state-of-art high-performance and multifunctional material,the novel bio-based MCP nanocomposite offers a more sustainable alternative to petrochemical-based plastics in packaging and engineering material fields.More importantly,our catalysis-interfacial strengthening integration strategy opens a door for designing and constructing high-performance bio-based polyester materials in future.展开更多
The fatigue resistance of metallic materials is generally attributed to both strength and toughness.Unfortunately,these properties are mutually exclusive in most materials.Classical theories like Paris’law only provi...The fatigue resistance of metallic materials is generally attributed to both strength and toughness.Unfortunately,these properties are mutually exclusive in most materials.Classical theories like Paris’law only provide some data correlation schemes rather than a predictive capability,which cannot satisfactorily guide the anti-fatigue design.In this study,for the first time,the predictive fatigue crack growth rate law is proposed by considering the effects of both strength and toughness.Accordingly,a quantitative criterion is established for judging the fatigue crack resistance of high-strength steels.The predictive law would provide a unique view to the quantitative anti-fatigue design of metallic materials.展开更多
Lightweight,highly strong and bio-based structural materials remain a long-lasting challenge.Here,inspired by nacre,a lightweight and high mechanical performance cellulosic material was fabricated via a facile and eff...Lightweight,highly strong and bio-based structural materials remain a long-lasting challenge.Here,inspired by nacre,a lightweight and high mechanical performance cellulosic material was fabricated via a facile and effective top-down approach and the resulting material has a high tensile strength of149.21 MPa and toughness of 1.91 MJ/m^(3).More specifically,the natural balsawood(NW) was subjected to a simple chemical treatment,removing most lignin and partial hemicellulose,follow by freeze-drying,forming wood aerogel(WA).The delignification process produced many pores and exposed numerous aligned cellulose nanofibers.Afterwards,the WA absorbed a quantity of moisture and was directly densified to form above high-performance cellulosic material.Such treatment imitates highly ordered"brick-and-mortar" arrangement of nacre,in which water molecules plays the role of mortar and cellulose nanofibrils make the brick part.The lightweight and good mechanical properties make this material promising for new energy car,aerospace,etc.This paper also explains the strengthening mechanism for making biomimetic materials by water molecules-induced hydrogen bonding and will open a new path for designing high-performance bio-based structural materials.展开更多
High-performance multifunctional polymeric materials integrated with high fire safety,excel-lent mechanical performances and electromagnetic interference(EMI)shielding properties have great prospects in practical appl...High-performance multifunctional polymeric materials integrated with high fire safety,excel-lent mechanical performances and electromagnetic interference(EMI)shielding properties have great prospects in practical applications.However,designing highly fire-safe and mechanically ro-bust EMI shielding nanocomposites remains a great challenge.Herein,hierarchical thermoplastic polyurethane/cyclophosphazene functionalized titanium carbide/carbon fiber fabric(TPU/CP-Ti_(3)C_(2)T_(x)/CF)nanocomposites with high fire safety and mechanical strength and toughness were prepared through the methods of melt blending,layer-by-layer stacking and thermocompression.The TPU/CP-Ti_(3)C_(2)T_(x)showed improved thermal stability.Moreover,the peak of heat release rate and total heat release of the hi-erarchical TPU sample containing 4.0 wt.%CP-Ti_(3)C_(2)T_(x)were respectively reduced by 64.4%and 31.8%relative to those of pure TPU,which were far higher than those of other TPU-based nanocomposites.The averaged EMI shielding effectiveness value of the hierarchical TPU/CP-Ti_(3)C_(2)T_(x)-2.0/CF nanocomposite reached 30.0 dB,which could satisfy the requirement for commercial applications.Furthermore,the ten-sile strength of TPU/CP-Ti_(3)C_(2)T_(x)-2.0/CF achieved 43.2 MPa,and the ductility and toughness increased by 28.4%and 84.3%respectively compared to those of TPU/CF.Interfacial hydrogen bonding in combination with catalytic carbonization of CP-Ti_(3)C_(2)T_(x)nanosheets and continuous conductive network of CF were re-sponsible for the superior fire safety,excellent EMI shielding and outstanding mechanical performances.This work offers a promising strategy to prepare multifunctional TPU-based nanocomposites,which have the potential for large-scale application in the fields of electronics,electrical equipment and 5 G facilities.展开更多
Epoxy resin-reinforced graphite composites have found extensive application as bipolar plates in fuel cells for stationary power supplies,valued for their lightweight nature and exceptional durability.To enhance the i...Epoxy resin-reinforced graphite composites have found extensive application as bipolar plates in fuel cells for stationary power supplies,valued for their lightweight nature and exceptional durability.To enhance the interfacial properties between graphite and epoxy resin(EP),surface oxidation of graphite was carried out using diverse functional groups.Experimental assessments illustrated that the composites with graphite oxide resulted in heightened mechanical strength and toughness compared to pristine graphite,which could be attributed to the excellent interface connection.Moreover,these composites displayed remarkable conductivity while simultaneously retaining their mechanical attributes.Furthermore,molecular dynamics simulations outcomes unveiled that the inclusion of oxygen-containing functional groups on the graphite surface augmented the interfacial energy with EP,and the interface morphology between graphite and resin exhibited heightened stability throughout the stretching process.This simple and effective technique presents opportunities for improving composites interfaces,enabling high load transfer efficiency,and opens up a potential path for developing strong and tough composite bipolar plates for fuel cells.展开更多
Metallic glass matrix composites(BMGCs)with compositions of[(Zr_(0.5)Cu_(0.5))_(0.925)Al_(0.07)Sn_(0.005)]_(100-x)Ta_(x)(atomic fraction,%,x=3,5,7)were successfully prepared via dealloying in metallic melt.The reinfor...Metallic glass matrix composites(BMGCs)with compositions of[(Zr_(0.5)Cu_(0.5))_(0.925)Al_(0.07)Sn_(0.005)]_(100-x)Ta_(x)(atomic fraction,%,x=3,5,7)were successfully prepared via dealloying in metallic melt.The reinforcing phase in these alloys has core-shell hybrid structure with Ta-rich particles as core and B2-CuZr as shell.In this method,the dealloyed Ta from Zr-Ta pre-alloys maintained in solid state and aggregated to form the fine Ta-rich phase in the final products.This effectively decreases the size of Ta-rich phase compared with that prepared via conventional arc-melting,where the Ta-rich phase was formed through dissolving and precipitation.Among the three compositions,[(Zr_(0.5)Cu_(0.5))_(0.925)Al_(0.07)Sn_(0.005)]_(95)Ta_(5) showed the highest plastic strain of 11.2%,much higher than that of the arc-melted counterparts(4.3%).Such improvement in mechanical properties was related with the refined core-shell hybrid reinforcing structure,which could hinder the rapid propagation of main shear band more efficiently and cause them to branch and proliferate at the interface.展开更多
Carbyne,the linear chain of carbon,promises the strongest and toughest material but possesses a Peierls instability(alternating single-bonds and triple-bonds)that reduces its strength and toughness.Herein,we computati...Carbyne,the linear chain of carbon,promises the strongest and toughest material but possesses a Peierls instability(alternating single-bonds and triple-bonds)that reduces its strength and toughness.Herein,we computationally found that the gravimetric strength,strain-to-failure,and gravimetric toughness can be improved from 74 GPa·g^(-1)·cm^(3),18%,and 9.4 k J·g^(-1)for pristine carbyne to the highest values of 106 GPa·g^(-1)·cm^(3),26%,and 19.0 k J·g^(-1)for carbyne upon hole injection of+0.07 e/atom,indicating the charged carbyne with record-breaking mechanical performance.Based on the analyses of the atomic and electronic structures,the underlying mechanism behind the record-breaking mechanical performance was revealed as the suppressed and even eliminated bond alternation of carbyne upon charge injection.展开更多
In order to clarify effects of prior pancaked austenitic structure on microstructure and mechanical properties of transformed martensite in ausformed steel,a super-thin pancaked austenite was processed by multi-pass r...In order to clarify effects of prior pancaked austenitic structure on microstructure and mechanical properties of transformed martensite in ausformed steel,a super-thin pancaked austenite was processed by multi-pass rolling in a 0.03-2.6Mn0.06Nb-0.01Ti(wt%) low alloy steel.The evolution of prior pancaked austenite grain during multi-pass rolling was studied using Ni-30Fe model alloy.Related with the structure and texture in the prior super-thin pancaked austenite in Ni-30Fe alloy,the texture and anisotropy of mechanical properties of transformed martensite in the studied ausformed steel were focused on.There were mainly three kinds of rolling texture components in the super-thin pancaked austenite:Goss {110} 001,copper {112} 111 and brass {110} 112.They were further transformed into the weak {001} 110 and strong {112} 110,{111} 112 texture components in the martensitic structure.The orientation relationship(OR) of lath martensite transformation from pancaked austenite in the ausformed steel deviated larger from the exact Kurdjumov-Sachs(K-S) OR than in the case of equiaxed austenite without deformation.The tensile and yield strengths of the ausformed martensitic steel first decreased and then increased as the angle between tension direction and rolling direction increased.The main reason for the anisotropy of strength was considered as the texture component {112} 110 in martensite.However,the anisotropy of impact toughness was more complex and the main reasons for it are unknown.展开更多
基金supported by the National Key R&D Program of China(Grant No.2021YFA0719200)the National Natural Science Foundation of China(Grant Nos.12272391,12232020,and 11672314)the CAS Project for Young Scientists in Basic Research(Grant No.YSBR-096).
文摘It is a challenge to determine the dominant topological characteristics of mechanical properties of adhesive interfaces.In this paper,we used graph theory and molecular dynamics simulation to investigate the influence of topological characteristics on the strength and toughness of highly cross-linked polymer interface systems.Based on the microstructure of the adhesive system,we extracted the dominant topological characteristics,including the connectivity degree(D)that determines the yield strength,and the average node-path(P)and the simple cycles proportions(R)that determine the deformability and load-bearing capacity during the void propagation respectively,which co-determine the toughness.The influence of the wall-effect on the dominant topological characteristics was also analyzed.The results showed that the interfacial yield strength increases with the increase of D,while the toughness increases with the increase of P and R.The wall-effect has a significant influence on D,P,and R.The strong wall-effect causes the enrichment of amino groups near the wall and insufficient cross-linking away from the wall,leading to the lower D and R,i.e.,the lower yield strength and load-bearing capacity during the void propagation.With the attenuation of the wall-effect,the D increases gradually,while the P and the R first increase and then decrease,showing an optimized wall-effect for the toughness of the adhesive interface.This paper reveals the dominant topological characteristics of adhesive interfacial strength and toughness,providing a new way to modulate the mechanical properties of polymer adhesive interface systems.
基金financially supported by the National Key Research and Development Program of China(No.2016YFB0301001)the Science&Technology Program of Zhaoqing(No.2018K006)。
文摘Based on the 3 factors and 3 levels orthogonal experiment method,compositional effects of Mg,Si,and Ti addition on the microstructures,tensile properties,and fracture behaviors of the high-pressure die-casting Al-x Mg-y Si-z Ti alloys have been investigated.The analysis of variance shows that both Mg and Si apparently infl uence the tensile properties of the alloys,while Ti does not.The tensile mechanical properties are comprehensively infl uenced by the amount of eutectic phase(α-Al+Mg2Si),the average grain size,and the content of Mg dissolved intoα-Al matrix.The optimized alloy is Al-7.49 Mg-3.08 Si-0.01 Ti(wt%),which exhibits tensile yield strength of 219 MPa,ultimate tensile strength of 401 MPa,and elongation of 10.5%.Furthermore,contour maps,showing the relationship among compositions,microstructure characteristics,and the tensile properties are constructed,which provide guidelines for developing high strength and toughness Al–Mg–Si–Ti alloys for high-pressure die-casting.
文摘The effect of W on the microstructure and the mechanical properties of ultrahigh strength low alloy steels was carried out. The microstructure of 30Cr3Si2Mn2NiMoNb and 30Cr3Si2Mn2NiMoNbW steels under quenched conditions were investigated by metallographic microscope, scanning electron microscope （SEM）, X-ray diffrac- tion （XRD）, and transmission electron microscope （TEM）. Thermodynamic cal- culation was also conducted. The results showed that the addition of W made undissolved carbides more and finer, which exerted strong pinning force on migrat- ing packet boundary and improved tensile strength significantly. M6C particles in 30Cr3Si2Mn2NiMoNb steel were disappeared above 1193 K, while the M6C particles in 30Cr3Si2Mn2NiMoNbW steel were disappeared above 1253 K, the calculation results were in agreement with the experimental.
基金sponsored by the National Natural Science Foundation of China(Grant Nos.U1960203,52004060,and 52174308)Fundamental Research Funds for the Central Universities(Grant Nos.N2125017 and N2225031)+1 种基金Program of Introducing Talents of Discipline to Universities(Grant No.B21001)Liaoning Pilot Base Project(No.2022JH24/10200026)。
文摘High-nitrogen stainless bearing steel(HNSBS)with ultra-high tensile strength(∼2403 MPa)and good toughness(∼80.0 J)was obtained by V-microalloying,overcoming the strength-toughness trade-off of conventional V-free HNSBS.In this work,since V-microalloying facilitated the enrichment of interstitial atoms(C and N)in precipitates,the content of interstitial atoms in the matrix was reduced accordingly(i.e.,interstitial partitioning).On the one hand,V-microalloying reduced the substantial intergranular precipitates and transformed the precipitates from M_(23)C_(6)+M_(2)N into V-containing M_(23)C_(6)+M_(2)N+MN with multi-scale particle sizes,causing a coupling strengthening effect,which contributed to the toughness and additional strength increase.On the other hand,V-microalloying controlled interstitial partitioning,effectively refined coarse retained austenite(RA),increased the fraction of dislocation martensite,and reduced the fraction of twin martensite.The more film-like RA and dislocation martensite with high dislocation density coordinated plastic deformation and prevented crack propagation,thus obviously enhancing the strength and toughness of 0.2 V steel.This study provides a new route to develop high-performance HNSBS for aerospace applications.
文摘To improve the competitive relationship between strength and toughness,the effect of low undercooling in austenite(γ)on the microstructure and mechanical properties of commercial vanadium-containing wheel steels was studied using an optical microscope(OM),a scanning electron microscope(SEM),a transmission electron microscope(TEM),and mechanical property tests.The results show that when the wheel steel is slightly cooled to an appropriate temperature above A c3 point for a short time after it has been austenitized at an elevated temperature,the solid-solved vanadium is pre-precipitated in the form of V(C,N)second phase semicoherent with the matrix in the originalγgrain.This phase hardly participates in matrix strengthening.Due to the small mismatch between V(C,N)and ferrite(α),during the subsequent-cooling phase transformation stage,the pre-precipitated second phase becomes theαnucleation point,causing granular and ellipsoidal intragranular ferrite(IGF,with an average size of 4-6μm)to nucleate in the originalγ.The IGF production and strength loss increases with the increasing undercooling degree.Based on this,Masteel Co.,Ltd.has developed a new heat-treatment step-cooling process that can promote the formation of IGF,considerably improving the level and uniformity of fracture toughness on the premise that the strength and hardness of the wheel are almost unchanged.
基金supported from the National Nat-ural Science Foundation of China(Nos.52274342 and 52130408)the Fundamental Research Funds for the Central Universities of Central South University,China(No.1053320213826).
文摘The demand for oil casing steel with ultra-high strength and excellent impact toughness for safe application in ultra-deep wells is pressing.In improving the combination of strength,ductility,and impact toughness,the designed Cr-Mo-V micro-alloyed oil casing steel was quenched at 800,900,and 1000℃,followed by tempering at 600,680,and 760℃,respectively,to obtain distinct microstruc-tures.The results showed that the microstructure of the samples quenched at 800℃ followed by tempering comprised untransformed ferrite and large undissolved carbides,which considerably deteriorated tensile strength and impact toughness.For other conditions,the nuc-leated carbides and the boundaries are key factors that balance the tensile strength from 1226 to 971 MPa and the impact toughness from 65 to 236 J.From the perspective of carbide,optimal precipitation strengthening is achieved with a smaller carbide size obtained by a low tempering temperature of 600℃,while larger-sized carbides would remarkably soften the matrix to improve the toughness but deteriorate the tensile strength.Additionally,an increase in prior austenite grain size with the corresponding enlarged sub-boundaries obtained by high quenching temperatures substantially diminishes grain refinement strengthening,dislocation strengthening,and the energy absorbed in the crack propagation process,which is unfavorable to strength and toughness.
基金financial supports from the National Natural Science Foundation of China(Grant No.NSFC52473104)National Key R&D Program of China(Grant No.2022YFC2104500)+3 种基金Zhejiang Provincial Natural Science Foundation of China(Grant No.Y24B040002)Ningbo 2025 Key Scientific Research Programs(Grant No.2022Z160)the China Postdoctoral Science Foundation(Grant No.2023M733601)the Ningbo Natural Science Foundation(Grant No.2023I333&2023J409).
文摘Renewable 2,5-furandicarboxylic acid-based polyesters are one of the most promising materials for achieving plastic replacement in the age of energy and environmental crisis.However,their properties still cannot compete with those of petrochemical-based plastics,owing to insufficient molecular and/or microstructure designs.Herein,we utilize the Ti_(3)C_(2)T_(x)-based MXene nanosheets for decorating carbon nanotube(CNT)and obtaining the structurally stable and highly dispersed dendritic heterostructured MXene@CNT,that can act as multi-roles,i.e.,polycondensation catalyst,crystal nucleator,and interface enhancer of polyester.The biobased MXene@CNT/polybutylene furandicarboxylate(PBF)(denoted as MCP)nanocomposites are synthesized by the strategy of“in situ catalytic polymerization and hot-pressing”.Benefiting from the multi-scale interactions(i.e.,covalent bonds,hydrogen bonds,and physical interlocks)in hybrid structure,the MCP presents exceptional mechanical strength(≈101 MPa),stiffness(≈3.1 GPa),toughness(≈130 MJ m^(-3)),and barrier properties(e.g.,O_(2)0.0187 barrer,CO_(2)0.0264 barrer,and H2O 1.57×10^(-14) g cm cm^(-2) s Pa)that are higher than most reported bio-based materials and engineering plastics.Moreover,it also displays satisfactory multifunctionality with high reprocessability(90%strength retention after 5 recycling),UV resistance(blocking 85%UVA rays),and solvent-resistant properties.As a state-of-art high-performance and multifunctional material,the novel bio-based MCP nanocomposite offers a more sustainable alternative to petrochemical-based plastics in packaging and engineering material fields.More importantly,our catalysis-interfacial strengthening integration strategy opens a door for designing and constructing high-performance bio-based polyester materials in future.
基金financially supported by the National Natural Science Foundation of China(Nos.51771208 and U1664253)the Strategic Priority Research Program of the Chinese Academy of Sciences(Nos.XDB22020202 and XDC04040502)+3 种基金the Liao Ning Revitalization Talents Program(No.XLYC1808027)the Youth Innovation Promotion Association CAS(No.2018226)the Special Fund Project of High-tech Industrialization Cooperation between Jilin Province and CAS(No.2020SYHZ0008)the National Science and Technology Major Project(No.2017-VI-0003–0073)。
文摘The fatigue resistance of metallic materials is generally attributed to both strength and toughness.Unfortunately,these properties are mutually exclusive in most materials.Classical theories like Paris’law only provide some data correlation schemes rather than a predictive capability,which cannot satisfactorily guide the anti-fatigue design.In this study,for the first time,the predictive fatigue crack growth rate law is proposed by considering the effects of both strength and toughness.Accordingly,a quantitative criterion is established for judging the fatigue crack resistance of high-strength steels.The predictive law would provide a unique view to the quantitative anti-fatigue design of metallic materials.
基金supported by the National Natural Science Foundation of China (No.51803093)National Science Foundation of Jiangsu Province (No.BK20180770)。
文摘Lightweight,highly strong and bio-based structural materials remain a long-lasting challenge.Here,inspired by nacre,a lightweight and high mechanical performance cellulosic material was fabricated via a facile and effective top-down approach and the resulting material has a high tensile strength of149.21 MPa and toughness of 1.91 MJ/m^(3).More specifically,the natural balsawood(NW) was subjected to a simple chemical treatment,removing most lignin and partial hemicellulose,follow by freeze-drying,forming wood aerogel(WA).The delignification process produced many pores and exposed numerous aligned cellulose nanofibers.Afterwards,the WA absorbed a quantity of moisture and was directly densified to form above high-performance cellulosic material.Such treatment imitates highly ordered"brick-and-mortar" arrangement of nacre,in which water molecules plays the role of mortar and cellulose nanofibrils make the brick part.The lightweight and good mechanical properties make this material promising for new energy car,aerospace,etc.This paper also explains the strengthening mechanism for making biomimetic materials by water molecules-induced hydrogen bonding and will open a new path for designing high-performance bio-based structural materials.
基金This work was financially supported by the National Natural Science Foundation of China(No.52173070)the Opening Test-ing Funds for the Valuable Equipments of Fuzhou University(No.2023T013).
文摘High-performance multifunctional polymeric materials integrated with high fire safety,excel-lent mechanical performances and electromagnetic interference(EMI)shielding properties have great prospects in practical applications.However,designing highly fire-safe and mechanically ro-bust EMI shielding nanocomposites remains a great challenge.Herein,hierarchical thermoplastic polyurethane/cyclophosphazene functionalized titanium carbide/carbon fiber fabric(TPU/CP-Ti_(3)C_(2)T_(x)/CF)nanocomposites with high fire safety and mechanical strength and toughness were prepared through the methods of melt blending,layer-by-layer stacking and thermocompression.The TPU/CP-Ti_(3)C_(2)T_(x)showed improved thermal stability.Moreover,the peak of heat release rate and total heat release of the hi-erarchical TPU sample containing 4.0 wt.%CP-Ti_(3)C_(2)T_(x)were respectively reduced by 64.4%and 31.8%relative to those of pure TPU,which were far higher than those of other TPU-based nanocomposites.The averaged EMI shielding effectiveness value of the hierarchical TPU/CP-Ti_(3)C_(2)T_(x)-2.0/CF nanocomposite reached 30.0 dB,which could satisfy the requirement for commercial applications.Furthermore,the ten-sile strength of TPU/CP-Ti_(3)C_(2)T_(x)-2.0/CF achieved 43.2 MPa,and the ductility and toughness increased by 28.4%and 84.3%respectively compared to those of TPU/CF.Interfacial hydrogen bonding in combination with catalytic carbonization of CP-Ti_(3)C_(2)T_(x)nanosheets and continuous conductive network of CF were re-sponsible for the superior fire safety,excellent EMI shielding and outstanding mechanical performances.This work offers a promising strategy to prepare multifunctional TPU-based nanocomposites,which have the potential for large-scale application in the fields of electronics,electrical equipment and 5 G facilities.
基金the financial supports from the National Key R&D Program of China(No.2020YFB1505901)。
文摘Epoxy resin-reinforced graphite composites have found extensive application as bipolar plates in fuel cells for stationary power supplies,valued for their lightweight nature and exceptional durability.To enhance the interfacial properties between graphite and epoxy resin(EP),surface oxidation of graphite was carried out using diverse functional groups.Experimental assessments illustrated that the composites with graphite oxide resulted in heightened mechanical strength and toughness compared to pristine graphite,which could be attributed to the excellent interface connection.Moreover,these composites displayed remarkable conductivity while simultaneously retaining their mechanical attributes.Furthermore,molecular dynamics simulations outcomes unveiled that the inclusion of oxygen-containing functional groups on the graphite surface augmented the interfacial energy with EP,and the interface morphology between graphite and resin exhibited heightened stability throughout the stretching process.This simple and effective technique presents opportunities for improving composites interfaces,enabling high load transfer efficiency,and opens up a potential path for developing strong and tough composite bipolar plates for fuel cells.
基金supported by the National Natural Science Foundation of China(Nos.52101138,52201075)Natural Science Foundation of Hubei Province,China(Nos.2023AFB798,2022CFB614)+3 种基金Shenzhen Science and Technology Program,China(No.JCYJ20220530160813032)State Key Laboratory of Solidification Processing in NWPU,China(Nos.SKLSP202309,SKLSP202308)Guangdong Basic and Applied Basic Research Foundation,China(No.2022A1515011227)State Key Laboratory of Powder Metallurgy of Central South University,China(No.Sklpm-KF-05).
文摘Metallic glass matrix composites(BMGCs)with compositions of[(Zr_(0.5)Cu_(0.5))_(0.925)Al_(0.07)Sn_(0.005)]_(100-x)Ta_(x)(atomic fraction,%,x=3,5,7)were successfully prepared via dealloying in metallic melt.The reinforcing phase in these alloys has core-shell hybrid structure with Ta-rich particles as core and B2-CuZr as shell.In this method,the dealloyed Ta from Zr-Ta pre-alloys maintained in solid state and aggregated to form the fine Ta-rich phase in the final products.This effectively decreases the size of Ta-rich phase compared with that prepared via conventional arc-melting,where the Ta-rich phase was formed through dissolving and precipitation.Among the three compositions,[(Zr_(0.5)Cu_(0.5))_(0.925)Al_(0.07)Sn_(0.005)]_(95)Ta_(5) showed the highest plastic strain of 11.2%,much higher than that of the arc-melted counterparts(4.3%).Such improvement in mechanical properties was related with the refined core-shell hybrid reinforcing structure,which could hinder the rapid propagation of main shear band more efficiently and cause them to branch and proliferate at the interface.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12172261 and 11972263)
文摘Carbyne,the linear chain of carbon,promises the strongest and toughest material but possesses a Peierls instability(alternating single-bonds and triple-bonds)that reduces its strength and toughness.Herein,we computationally found that the gravimetric strength,strain-to-failure,and gravimetric toughness can be improved from 74 GPa·g^(-1)·cm^(3),18%,and 9.4 k J·g^(-1)for pristine carbyne to the highest values of 106 GPa·g^(-1)·cm^(3),26%,and 19.0 k J·g^(-1)for carbyne upon hole injection of+0.07 e/atom,indicating the charged carbyne with record-breaking mechanical performance.Based on the analyses of the atomic and electronic structures,the underlying mechanism behind the record-breaking mechanical performance was revealed as the suppressed and even eliminated bond alternation of carbyne upon charge injection.
基金supported by the National Basic Research Program of China("973" Program) (Grant No. 2010CB630805)the National Natural Science Foundation of China (Grant No. 51071089 and 51171087)
文摘In order to clarify effects of prior pancaked austenitic structure on microstructure and mechanical properties of transformed martensite in ausformed steel,a super-thin pancaked austenite was processed by multi-pass rolling in a 0.03-2.6Mn0.06Nb-0.01Ti(wt%) low alloy steel.The evolution of prior pancaked austenite grain during multi-pass rolling was studied using Ni-30Fe model alloy.Related with the structure and texture in the prior super-thin pancaked austenite in Ni-30Fe alloy,the texture and anisotropy of mechanical properties of transformed martensite in the studied ausformed steel were focused on.There were mainly three kinds of rolling texture components in the super-thin pancaked austenite:Goss {110} 001,copper {112} 111 and brass {110} 112.They were further transformed into the weak {001} 110 and strong {112} 110,{111} 112 texture components in the martensitic structure.The orientation relationship(OR) of lath martensite transformation from pancaked austenite in the ausformed steel deviated larger from the exact Kurdjumov-Sachs(K-S) OR than in the case of equiaxed austenite without deformation.The tensile and yield strengths of the ausformed martensitic steel first decreased and then increased as the angle between tension direction and rolling direction increased.The main reason for the anisotropy of strength was considered as the texture component {112} 110 in martensite.However,the anisotropy of impact toughness was more complex and the main reasons for it are unknown.
