Organometallic iridium(Ⅲ)complexes with AIE properties have received much attention for their potential in the photoelectric and biomedical fields;however,the development of such materials remains challenging due to ...Organometallic iridium(Ⅲ)complexes with AIE properties have received much attention for their potential in the photoelectric and biomedical fields;however,the development of such materials remains challenging due to the lack of a precise design strategy.Herein,a family of cationic iridium(Ⅲ)complexes with pyridine-azole ancillary ligands,in which 1-(2,4-difluorophenyl)-1H-pyrazole is a cyclometalated ligand,have been strategically synthesized.展开更多
基金support from the National Natural Science Foundation of China(22175033 and 51902124)the Technology Development Plan of Jilin Science and Technology Department(20230101046JC).
文摘Organometallic iridium(Ⅲ)complexes with AIE properties have received much attention for their potential in the photoelectric and biomedical fields;however,the development of such materials remains challenging due to the lack of a precise design strategy.Herein,a family of cationic iridium(Ⅲ)complexes with pyridine-azole ancillary ligands,in which 1-(2,4-difluorophenyl)-1H-pyrazole is a cyclometalated ligand,have been strategically synthesized.