Polysynthetic twinned(PST)TiAl single crystal possesses great potentials for high-temperature applications due to its excellent combination of strength,ductility and creep resistance.However,a critical property for hi...Polysynthetic twinned(PST)TiAl single crystal possesses great potentials for high-temperature applications due to its excellent combination of strength,ductility and creep resistance.However,a critical property for high-temperature application of such material involving high-temperature fatigue properties remains unknown.Here,the high-temperature high-cycle fatigue performance of PST TiAl single crystal has been studied.The result shows that PST TiAl single crystal can withstand more than 107 cyclic loadings at 975℃ under a stress amplitude of 270 MPa,which is significantly higher than traditional TiAl alloys.Experimental observations and atomistic simulations indicate that the improvement of fatigue resistance is attributed to the plastic strain delocalization in uniform lamellar structure,and the plastic deformation is well-distributed and sufficient in each lamella.Even in theα2 lamella with difficult slippage,a large number of stacking fault structures can be observed.The{c+a}dislocations inα2 tend to dissociate into a Frank partial with b=1/6<2^(-)20^(-)3>,forming a ribbon of I1 fault which ensures the continuity of deformation.展开更多
Ultrastrong nanolayered metallic composites are usually subjected to low ductility due to plastic instability during deformation.Here we investigated the shear instability of a newly designed heterogeneous nanolayered...Ultrastrong nanolayered metallic composites are usually subjected to low ductility due to plastic instability during deformation.Here we investigated the shear instability of a newly designed heterogeneous nanolayered Cu/Zr composites by microindentation.The heterogeneity in size was generated by inserting a few thin Cu-Zr bilayers with an individual layer thickness of 2.5-10 nm into the interface region of the Cu/Zr layered composites with an individual layer thickness of 100 nm.The microindentation tests showed that multiple shear bands appeared in the heterogeneous composite with one bilayer,whereas only a single shear band was formed in that with two or three bilayers.Most importantly,the layer strain in the multi-shear band region is much smaller than that in the single-shear band area.For example,the strain of the 100 nm layers within the shear band in the composite with one 10 nm bilayer could reach as low as 2.8,which was less than half of that in the composite with three 10 nm bilayers,i.e.,6.1.These fndings demonstrated that strain delocalization can be achieved through shear band multiplication if an appropriate number of thin bilayers were used as interlayers in the 100 nm Cu/Zr composites.Besides,compared with the homogeneous composite with an individual layer thickness of 100 nm and the bimodal composite which is composed of alternating one 100 nm Cu-Zr bilayer and two 10 nm CuZr bilayers,the heterogeneous composite with one bilayer displayed a higher strength(2.15 GPa)and a favorable resistance to strain localization.展开更多
The pursuit of simultaneously high wear resistance and excellent lubrication in multi‐principal element alloy(MPEA)composites is often hindered by a fundamental trade‐off,which is exacerbated by the agglomeration of...The pursuit of simultaneously high wear resistance and excellent lubrication in multi‐principal element alloy(MPEA)composites is often hindered by a fundamental trade‐off,which is exacerbated by the agglomeration of high‐content graphene reinforcements.This compromise becomes particularly severe in composites with high‐content graphene reinforcements,whose agglomeration leads to embrittlement and lubrication failure.Here,a flake powder-metallurgy strategy is developed to construct a self‐assembled lamellar structure in graphene/CoCrNi MPEA composites(Gr/MPEA_(AL)).This approach enables the uniform dispersion of a high graphene content(3.0 wt%),which is unattainable by conventional methods.The resulting composite exhibits a rare dual enhancement in performance:an order‐of‐magnitude improvement in wear resistance coupled with a low coefficient of friction.Intriguingly,the tribological behavior shows significant anisotropy,with optimal performance observed when sliding perpendicular to the lamellae.Through a multi‐scale methodology combining molecular dynamics simulations,finite element analysis,and systematic experiments,it is revealed that this exceptional performance stems from the synergy of high‐density deformation nanotwins,efficient strain delocalization,and abundant graphene‐derived lubricating sites.This work establishes a general paradigm for designing composite architectures that reconcile traditionally incompatible properties,offering broad implications for developing next‐generation structural materials with integrated mechanical robustness and surface functionality for safety‐critical applications.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.51731006,51771093,91860104)the support of the National Key Laboratory for Precision Hot Processing of Metals,Harbin Institute of Technology(Grant No.6142909190104)Fundamental Research Funds for the Central Universities(Grant No.30919011295)。
文摘Polysynthetic twinned(PST)TiAl single crystal possesses great potentials for high-temperature applications due to its excellent combination of strength,ductility and creep resistance.However,a critical property for high-temperature application of such material involving high-temperature fatigue properties remains unknown.Here,the high-temperature high-cycle fatigue performance of PST TiAl single crystal has been studied.The result shows that PST TiAl single crystal can withstand more than 107 cyclic loadings at 975℃ under a stress amplitude of 270 MPa,which is significantly higher than traditional TiAl alloys.Experimental observations and atomistic simulations indicate that the improvement of fatigue resistance is attributed to the plastic strain delocalization in uniform lamellar structure,and the plastic deformation is well-distributed and sufficient in each lamella.Even in theα2 lamella with difficult slippage,a large number of stacking fault structures can be observed.The{c+a}dislocations inα2 tend to dissociate into a Frank partial with b=1/6<2^(-)20^(-)3>,forming a ribbon of I1 fault which ensures the continuity of deformation.
基金fnancially supported by the National Natural Science Foundation of China(No.11872380)the Natural Science Foundation of Hunan Province(Nos.2019JJ50750 and 2020JJ3043)+1 种基金the start-up funding from Central South University,Chinathe Joint Research Found Liaoning-Shenyang National Laboratory for Materials Science(No.2019JH3/3010029)。
文摘Ultrastrong nanolayered metallic composites are usually subjected to low ductility due to plastic instability during deformation.Here we investigated the shear instability of a newly designed heterogeneous nanolayered Cu/Zr composites by microindentation.The heterogeneity in size was generated by inserting a few thin Cu-Zr bilayers with an individual layer thickness of 2.5-10 nm into the interface region of the Cu/Zr layered composites with an individual layer thickness of 100 nm.The microindentation tests showed that multiple shear bands appeared in the heterogeneous composite with one bilayer,whereas only a single shear band was formed in that with two or three bilayers.Most importantly,the layer strain in the multi-shear band region is much smaller than that in the single-shear band area.For example,the strain of the 100 nm layers within the shear band in the composite with one 10 nm bilayer could reach as low as 2.8,which was less than half of that in the composite with three 10 nm bilayers,i.e.,6.1.These fndings demonstrated that strain delocalization can be achieved through shear band multiplication if an appropriate number of thin bilayers were used as interlayers in the 100 nm Cu/Zr composites.Besides,compared with the homogeneous composite with an individual layer thickness of 100 nm and the bimodal composite which is composed of alternating one 100 nm Cu-Zr bilayer and two 10 nm CuZr bilayers,the heterogeneous composite with one bilayer displayed a higher strength(2.15 GPa)and a favorable resistance to strain localization.
基金supported by Guangdong Basic and Applied Basic Research Foundation(No.2024A1515012378)Natural Science Foundation of China(Nos.52471093,52274367)+3 种基金fund of the State Key Laboratory of Solidification Processing in NPU(No.2025‐QZ‐03)the Practice and Innovation Funds for Graduate Students of Northwestern Polytechnical University(No.PF2025041)Fundamental Research Projects of Science&Technology Innovation and development Plan in Yantai City(No.2024JCYJ099)project(No.ZR2024QE213)supported by Shandong Provincial Natural Science Foundation.
文摘The pursuit of simultaneously high wear resistance and excellent lubrication in multi‐principal element alloy(MPEA)composites is often hindered by a fundamental trade‐off,which is exacerbated by the agglomeration of high‐content graphene reinforcements.This compromise becomes particularly severe in composites with high‐content graphene reinforcements,whose agglomeration leads to embrittlement and lubrication failure.Here,a flake powder-metallurgy strategy is developed to construct a self‐assembled lamellar structure in graphene/CoCrNi MPEA composites(Gr/MPEA_(AL)).This approach enables the uniform dispersion of a high graphene content(3.0 wt%),which is unattainable by conventional methods.The resulting composite exhibits a rare dual enhancement in performance:an order‐of‐magnitude improvement in wear resistance coupled with a low coefficient of friction.Intriguingly,the tribological behavior shows significant anisotropy,with optimal performance observed when sliding perpendicular to the lamellae.Through a multi‐scale methodology combining molecular dynamics simulations,finite element analysis,and systematic experiments,it is revealed that this exceptional performance stems from the synergy of high‐density deformation nanotwins,efficient strain delocalization,and abundant graphene‐derived lubricating sites.This work establishes a general paradigm for designing composite architectures that reconcile traditionally incompatible properties,offering broad implications for developing next‐generation structural materials with integrated mechanical robustness and surface functionality for safety‐critical applications.
