Rational design and performance promotion are eternal topics and ultimate goals in catalyst preparation.In contrast,trial–and–error is still the common method people take.Therefore,it is important to develop methods...Rational design and performance promotion are eternal topics and ultimate goals in catalyst preparation.In contrast,trial–and–error is still the common method people take.Therefore,it is important to develop methods to intrinsically enhance the performance of catalysts.The most effective solutions are the one from a kinetic perspective based on clear knowledge of the reaction mechanism.This paper describes rate-determining step cognition and modulation to promote CO oxidation on highly dispersed Pt on CeO_(2).The different degrees of metal–support interactions due to variation of hydroxyl density of support could alter the structure of active species and the ability of oxygen activation apparently,further shift the rate-determining step from oxygen activation to oxygen reverse spillover kinetically.The transformation of rate-determining step could enhance the intrinsic activity significantly,and decrease the T_(50) approximately 140℃.The findings of this research exemplify the universal and effective method of performance elevation by rate-determining step modulation,which is promising for application in different systems.展开更多
Pulse step modulator （PSM） topology is applied to the EAST auxiliary heating system, which consists of a neutral beam injection （NBI） and the related microwave heating system. This paper firstly analyzes the merit...Pulse step modulator （PSM） topology is applied to the EAST auxiliary heating system, which consists of a neutral beam injection （NBI） and the related microwave heating system. This paper firstly analyzes the merits and demerits of the traditional PSM modules adopted by other international companies, and then optimizes the topology of the module using the analysis results. Finally, a new topology for the PSM module （a three-phase neutral-point diode-clamped rectifier） is proposed. This new module overcomes the problems of traditional modules and has better cost-effective performance. The experimental results verify that the new module is feasible for engineering applications.展开更多
基金the National Key R&D Program of China (2021YFA1501302)the National Natural Science Foundation of China (22121004,U1862207)+1 种基金the Haihe Laboratory of Sustainable Chemical Transformations and the Program of Introducing Talents of Discipline to Universities (BP0618007) for financial supportsupported by the XPLORER PRIZE
文摘Rational design and performance promotion are eternal topics and ultimate goals in catalyst preparation.In contrast,trial–and–error is still the common method people take.Therefore,it is important to develop methods to intrinsically enhance the performance of catalysts.The most effective solutions are the one from a kinetic perspective based on clear knowledge of the reaction mechanism.This paper describes rate-determining step cognition and modulation to promote CO oxidation on highly dispersed Pt on CeO_(2).The different degrees of metal–support interactions due to variation of hydroxyl density of support could alter the structure of active species and the ability of oxygen activation apparently,further shift the rate-determining step from oxygen activation to oxygen reverse spillover kinetically.The transformation of rate-determining step could enhance the intrinsic activity significantly,and decrease the T_(50) approximately 140℃.The findings of this research exemplify the universal and effective method of performance elevation by rate-determining step modulation,which is promising for application in different systems.
文摘Pulse step modulator （PSM） topology is applied to the EAST auxiliary heating system, which consists of a neutral beam injection （NBI） and the related microwave heating system. This paper firstly analyzes the merits and demerits of the traditional PSM modules adopted by other international companies, and then optimizes the topology of the module using the analysis results. Finally, a new topology for the PSM module （a three-phase neutral-point diode-clamped rectifier） is proposed. This new module overcomes the problems of traditional modules and has better cost-effective performance. The experimental results verify that the new module is feasible for engineering applications.
