We report a trinuclear dysprosium single-molecule magnet,[Dy_(3)(μ_(3)-CO_(3))(Clbbpen)_(3)](CF_(3)SO_(3))·6MeCN,which has a perfectly equilateral triangular structure.The Ising-like anisotropy of each Dy(III)si...We report a trinuclear dysprosium single-molecule magnet,[Dy_(3)(μ_(3)-CO_(3))(Clbbpen)_(3)](CF_(3)SO_(3))·6MeCN,which has a perfectly equilateral triangular structure.The Ising-like anisotropy of each Dy(III)site is oriented almost normal to the triangular plane,and magnetic dipole interactions between the spins cause an antiparallel Ising ground state.Crossing of the antiferromagnetic states by the ferromagnetic state occurs at ca.0.2 T and gives rise to a characteristic step in magnetic hysteresis loops.This molecule thus serves as a perfectly triangular model system to explore frustrated Ising anisotropy.展开更多
基金supported by the National Key Research and Development Program of China(2018YFA0306001)the NSFC(Grant No.,21620102002,21771200,21822508,21821003)+2 种基金the Pearl River Talent Plan of Guangdong(2017BT01C161)The Royal Society for a University Research FellowshipThe University of Manchester for a President’s Doctoral Scholarship award.
文摘We report a trinuclear dysprosium single-molecule magnet,[Dy_(3)(μ_(3)-CO_(3))(Clbbpen)_(3)](CF_(3)SO_(3))·6MeCN,which has a perfectly equilateral triangular structure.The Ising-like anisotropy of each Dy(III)site is oriented almost normal to the triangular plane,and magnetic dipole interactions between the spins cause an antiparallel Ising ground state.Crossing of the antiferromagnetic states by the ferromagnetic state occurs at ca.0.2 T and gives rise to a characteristic step in magnetic hysteresis loops.This molecule thus serves as a perfectly triangular model system to explore frustrated Ising anisotropy.
