The results of the 2022-2025 study conducted for the vulnerability assessment of pastures and for the development of improvement measures on the degraded land sections in the arid and semi-arid provinces of the Caucas...The results of the 2022-2025 study conducted for the vulnerability assessment of pastures and for the development of improvement measures on the degraded land sections in the arid and semi-arid provinces of the Caucasus under the global climate change conditions are introduced in the current article.The main goal of our scientific work is to study and assess the current ecological and resource state of natural phytocenoses,pastures and hayfields in the arid and semi-arid landscapes under climate change.The paper presents the results of determining the areas and levels of degradation of the natural biogeocenoses and biogeocenoses of the pastures and hayfields in the mountain and highland landscapes.The results were obtained using remote sensing,field and laboratory studies and analyses.The conducted studies have revealed that along 34,174.5 ha pasture and 1342.0 meadows areas of the pastures at the Areni,Yeghegis,Yeghegnadzor and Vayq consolidated administrative territories situated in the arid and semi-arid zones of the Vayots Dzor Region high degradation was recorded in about 6508 hectares of pasture and 407 hectares of meadows areas,which is related to irregular and uncontrolled economic mismanagement of the local population and global climate change.To improve the ecological condition,accessibility and quality of ecosystem services of the pastures,hayfields and natural meadows,comprehensive restoration bioecological and agrotechnical measures have been proposed.They are aimed at improving the air,water and nutrient regimes of soils,at their bioprotection,as well as at the general increase in area and at improving the economic characteristics of the vegetation cover.Such measures on the ecosystem basis are appropriate in the context of enriching the qualitative composition of plants with useful ecological and economic bioecological characteristics,taking into account the characteristics of landscapes,weather and climatic conditions,and agricultural opportunities.展开更多
We theoretically investigate the excited state intramolecular proton transfer(ESIPT) behavior of the novel fluorophore bis-imine derivative molecule HNP which was designed based on the intersection of 1-(hydrazonometh...We theoretically investigate the excited state intramolecular proton transfer(ESIPT) behavior of the novel fluorophore bis-imine derivative molecule HNP which was designed based on the intersection of 1-(hydrazonomethyl)-naphthalene-2-ol and 1-pyrenecarboxaldehyde. Especially, the density functional theory(DFT) and time-dependent density functional theory(TDDFT) methods for HNP monomer are introduced. Moreover, the "our own n-layered integrated molecular orbital and molecular mechanics"(ONIOM) method(TDDFT:universal force field(UFF)) is used to reveal the aggregation-induced emission(AIE) effect on the ESIPT process for HNP in crystal. Our results confirm that the ESIPT process happens upon the photoexcitation for the HNP monomer and HNP in crystal, which is distinctly monitored by the optimized geometric structures and the potential energy curves. In addition, the results of potential energy curves reveal that the ESIPT process in HNP will be promoted by the AIE effect. Furthermore, the highest occupied molecular orbital(HOMO) and lowest unoccupied molecular orbital(LUMO) for the HNP monomer and HNP in crystal have been calculated. The calculation demonstrates that the electron density decrease of proton donor caused by excitation promotes the ESIPT process. In addition, we find that the variation of atomic dipole moment corrected Hirshfeld population(ADCH) charge for proton acceptor induced by the AIE effect facilitates the ESIPT process. The results will be expected to deepen the understanding of ESIPT dynamics for luminophore under the AIE effect and provide insight into future design of high-efficient AIE compounds.展开更多
Starting from Wigner’s definition of the function named now after him we systematically develop different representation of this quasiprobability with emphasis on symmetric representations concerning the canonical va...Starting from Wigner’s definition of the function named now after him we systematically develop different representation of this quasiprobability with emphasis on symmetric representations concerning the canonical variables (q,p) of phase space and using the known relation to the parity operator. One of the representations is by means of the Laguerre 2D polynomials which is particularly effective in quantum optics. For the coherent states we show that their Fourier transforms are again coherent states. We calculate the Wigner quasiprobability to the eigenstates of a particle in a square well with infinitely high impenetrable walls which is not smooth in the spatial coordinate and vanishes outside the wall boundaries. It is not well suited for the calculation of expectation values. A great place takes on the calculation of the Wigner quasiprobability for coherent phase states in quantum optics which is essentially new. We show that an unorthodox entire function plays there a role in most formulae which makes all calculations difficult. The Wigner quasiprobability for coherent phase states is calculated and graphically represented but due to the involved unorthodox function it may be considered only as illustration and is not suited for the calculation of expectation values. By another approach via the number representation of the states and using the recently developed summation formula by means of Generalized Eulerian numbers it becomes possible to calculate in approximations with good convergence the basic expectation values, in particular, the basic uncertainties which are additionally represented in graphics. Both considered examples, the square well and the coherent phase states, belong to systems with SU (1,1) symmetry with the same index K=1/2 of unitary irreducible representations.展开更多
After developing the concept of displaced squeezed vacuum states in the non-unitary approach and establishing the connection to the unitary approach we calculate their quasiprobabilities and expectation values in gene...After developing the concept of displaced squeezed vacuum states in the non-unitary approach and establishing the connection to the unitary approach we calculate their quasiprobabilities and expectation values in general form. Then we consider the displacement of the squeezed vacuum states and calculate their photon statistics and their quasiprobabilities. The expectation values of the displaced states are related to the expectation values of the undisplaced states and are calculated for some simplest cases which are sufficient to discuss their categorization as sub-Poissonian and super-Poissonian statistics. A large set of these states do not belong to sub- or to super-Poissonian states but are also not Poissonian states. We illustrate in examples their photon distributions. This shows that the notions of sub- and of super-Poissonian statistics and their use for the definition of nonclassicality of states are problematic. In Appendix A we present the most important relations for SU (1,1) treatment of squeezing and the disentanglement of their operators. Some initial members of sequences of expectation values for squeezed vacuum states are collected in Appendix E.展开更多
In this paper the results of dynamic NMR studies on ethylmethylamino-tertiary-butyl-phenylborane (EMABPB) with or without light are reported. The NMR data were recorded on a Bruker 400 MHz NMR equipped with our custom...In this paper the results of dynamic NMR studies on ethylmethylamino-tertiary-butyl-phenylborane (EMABPB) with or without light are reported. The NMR data were recorded on a Bruker 400 MHz NMR equipped with our custom-made optical probe and with our custom-made 450 watts (W) monochromatic light sources. The molecular photochemistry including twisted intramolecular charge-transfer-excited-state (TICT) of the EMABPB in several solvents has been investigated. These results indicate that the aminoborane demonstrates multiple configurations in CD3Cl and CD2Cl2 resulting in the shifts of the signals of the alkyl groups on the nitrogen and boron. This indicates that there are some time-dependent changes at constant temperature over the irradiation interval. At ﹣60°C and the presence of light (λ = 265 nm), we observed a large change in the populations of the two sites, and this by itself indicates a modification in the rotation around the boron nitrogen bond in the excited state. By considering the existence of the TICT state, many important energy technologies may be developed with higher efficiency by controlling the back-electron transfer processes.展开更多
The specific mechanisms by which acupuncture affects the central nervous system are unclear. In the International Standard Scalp Acupuncture system, acupuncture needles are applied at the middle line of the vertex, an...The specific mechanisms by which acupuncture affects the central nervous system are unclear. In the International Standard Scalp Acupuncture system, acupuncture needles are applied at the middle line of the vertex, anterior parietal-temporal oblique line, and the posterior parietal-temporal oblique line. We conducted a single-arm prospective clinical trial in which seven healthy elderly volunteers (three men and four women;50–70 years old) received International Standard Scalp Acupuncture at MS5 (the mid-sagittal line between Baihui (DU20) and Qianding (DU21)), the left MS6 (line joining Sishencong (EX-HN1) and Xuanli (GB6)), and the left MS7 (line joining DU20 and Qubin (GB7)). After acupuncture, resting-state functional magnetic resonance imaging demonstrated changes in the fractional amplitude of low frequency fluctuations and regional homogeneity in various areas, showing remarkable enhancement of regional homogeneity in the bilateral anterior cingulate, left medial frontal gyrus, supramarginal gyrus, right middle frontal gyrus, and inferior frontal gyrus. Functional connectivity based on a seed region at the right middle frontal gyrus (42, 51, 9) decreased at the bilateral medial superior frontal gyrus. Our data preliminarily indicates that the international standard scalp acupuncture in healthy elderly participants specifcally enhances the correlation between the brain regions involved in cognition and implementation of the brain network regulation system and the surrounding adjacent brain regions. The study was approved by the Ethics Committee of the China-Japan Union Hospital at Jilin University, China, on July 18, 2016 (approval No. 2016ks043).展开更多
Heterogeneity of biological samples is usually considered a major obstacle for three-dimensional (3D) structure determination of macromolecular complexes. Heterogeneity may occur at the level of composition or conform...Heterogeneity of biological samples is usually considered a major obstacle for three-dimensional (3D) structure determination of macromolecular complexes. Heterogeneity may occur at the level of composition or conformational variability of complexes and affects most 3D structure determination methods that rely on signal averaging. Here, an approach is described that allows sorting structural states based on a 3D statistical approach, the 3D sampling and classification (3D-SC) of 3D structures derived from single particles imaged by cryo electron microscopy (cryo-EM). The method is based on jackknifing & bootstrapping of 3D sub-ensembles and 3D multivariate statistical analysis followed by 3D classification. The robustness of the statistical sorting procedure is corroborated using model data from an RNA polymerase structure and experimental data from a ribosome complex. It allows resolving multiple states within heterogeneous complexes that thus become amendable for a structural analysis despite of their highly flexible nature. The method has important implications for high-resolution structural studies and allows describing structure ensembles to provide insights into the dynamics of multi-component macromolecular assemblies.展开更多
The intrinsic antiferromagnetic topological insulators in the Mn-Bi-Te family,composed of superlattice-like MnBi_(2)Te_(4)/(Bi_(2)Te_(3))_(n)(n=0,1,2,3,...)layered structure,present intriguing states of matter such as...The intrinsic antiferromagnetic topological insulators in the Mn-Bi-Te family,composed of superlattice-like MnBi_(2)Te_(4)/(Bi_(2)Te_(3))_(n)(n=0,1,2,3,...)layered structure,present intriguing states of matter such as quantum anomalous Hall effect and the axion insulator.However,the surface state gap,which is the prerequisite for the observation of these states,remains elusive.Here by molecular beam epitaxy,we obtain two types of MnBi_(4)Te_(7)films with the exclusive Bi_(2)Te_(3)(BT)or MnBi_(2)Te_(4)(MBT)terminations.By scanning tunneling spectroscopy,the mass terms in the surface states are identified on both surface terminations.Experimental results reveal the existence of a hybridization gap of approximately 23 meV in surface states on the BT termination.This gap comes from the hybridization between the surface states and the spin-split states in the adjacent MBT layer.On the MBT termination,an exchange mass term of about 28±2 meV in surface states is identified by taking magnetic-field-dependent Landau level spectra as well as theoretical simulations.In addition,the mass term varies with the field in the film with a heavy BiMn doping level in the Mn layers.These findings demonstrate the existence of mass terms in surface states on both types of terminations in our epitaxial MnBi_(4)Te_(7)films investigated by local probes.展开更多
We examine possible funding sources for constructing Climate Change Haven Communities on a global basis. Areas of the planet that have the potential to house persons migrating to “safe havens” in their own or other ...We examine possible funding sources for constructing Climate Change Haven Communities on a global basis. Areas of the planet that have the potential to house persons migrating to “safe havens” in their own or other countries will require the rapid construction of communities capable of supporting them, their families, businesses and farms. However, different political-economic conditions are found across the areas which can serve as locations for these Climate Change Haven Communities. We develop funding and construction strategies for the United States (free-market capitalism), France and Spain (European Union supported economies), and Taiwan region (state-directed economy). The proposals for the Taiwan region should also be applicable to the rest of China.展开更多
This letter demonstrates an experimental approach to measuring the angular-momentum-resolved population of excited states in laser-produced argon ions.By measuring the spectra of free induction decay emissions corresp...This letter demonstrates an experimental approach to measuring the angular-momentum-resolved population of excited states in laser-produced argon ions.By measuring the spectra of free induction decay emissions corresponding to the resonant transitions between Rydberg states,the relative population of the Rydberg states is obtained with known Einstein A-coefficients.This study deepens the mechanistic understanding of coherent dynamics in laser-driven ionic excited states,and establishes experimental benchmarks essential for validating and refining advanced quantum kinetic models in strong-field physics.展开更多
Multitarget stool DNA(mt-sDNA) testing was approved for average risk colorectal cancer(CRC) screening by the United States Food and Drug Administration and thereafter reimbursed for use by the Medicare program(2014).T...Multitarget stool DNA(mt-sDNA) testing was approved for average risk colorectal cancer(CRC) screening by the United States Food and Drug Administration and thereafter reimbursed for use by the Medicare program(2014).The United States Preventive Services Task Force(USPSTF) October 2015 draft recommendation for CRC screening included mt-s DNA as an "alternative" screening test that "may be useful in select clinical circumstances",despite its very high sensitivity for early stage CRC.The evidence supporting mt-s DNA for routine screening use is robust.The clinical efficacy of mt-s DNA as measured by sensitivity,specificity,life-years gained(LYG),and CRC deaths averted is similar to or exceeds that of the other more specifically recommended screening options included in the draft document,especially those requiring annual testing adherence.In a population with primarily irregular screening participation,tests with the highest point sensitivity and reasonable specificity are more likely to favorably impact CRC related morbidity and mortality than those depending on annual adherence.This paper reviews the evidence supporting mt-s DNA for routine screening and demonstrates,using USPSTF's modeling data,that mt-s DNA at three-year intervals provides significant clinical net benefits and fewer complications per LYG than annual fecal immunochemical testing,high sensitivity guaiac based fecal occult blood testing and 10-year colonoscopy screening.展开更多
Dear Editor,The letter deals with the distributed state and fault estimation of the whole physical layer for cyber-physical systems(CPSs) when the cyber layer suffers from DoS attacks. With the advancement of embedded...Dear Editor,The letter deals with the distributed state and fault estimation of the whole physical layer for cyber-physical systems(CPSs) when the cyber layer suffers from DoS attacks. With the advancement of embedded computing, communication and related hardware technologies, CPSs have attracted extensive attention and have been widely used in power system, traffic network, refrigeration system and other fields.展开更多
Dear Editor,This letter focuses on how an attacker can design suitable improved zero-dynamics (ZD) attack signal based on state estimates of target system. Improved ZD attack is to change zero dynamic gain matrix of a...Dear Editor,This letter focuses on how an attacker can design suitable improved zero-dynamics (ZD) attack signal based on state estimates of target system. Improved ZD attack is to change zero dynamic gain matrix of attack signal to a matrix with determinant greater than 1.展开更多
The ultrafast excitation dynamics of atoms and molecules exposed to circularly polarized two-color(CPTC)laser fields constitute a fascinating topic in attosecond science. Although extensive research has established th...The ultrafast excitation dynamics of atoms and molecules exposed to circularly polarized two-color(CPTC)laser fields constitute a fascinating topic in attosecond science. Although extensive research has established the relationship between the Rydberg state excitation(RSE) yields and the CPTC field parameters, such as field amplitude ratios and helicity of two components, the role of the relative phase(φ) in modulating RSE efficiency remains unclear. In this work, we theoretically investigate the φ dependence of RSE and ionization yields in the co-rotating and counter-rotating circularly polarized two-color(CPTC) few-cycle laser fields by a semiclassical model. We find that, in co-rotating CPTC fields, both RSE and ionization yields display pronounced oscillations as a function of φ and these oscillations are significantly suppressed in the counter-rotating configuration, particularly for ionization yields. Moreover, the ratio of RSE to ionization yields exhibits an out-of-phase oscillatory pattern between low-and high-intensity regimes. These results can be comprehended by the unique feature of φ dependence of CPTC few-cycle fields, based on our semiclassical analysis. Our results demonstrate that phase-controlled CPTC fields offer a versatile tool for steering ultrafast ionization and RSE dynamics of atoms and molecules.展开更多
A singlet diatomic molecule naturally carries doubly degenerate ±Λ states when the projection of the total electronic angular momentum onto the internuclear axis is nonzero. These doubly degenerate states contri...A singlet diatomic molecule naturally carries doubly degenerate ±Λ states when the projection of the total electronic angular momentum onto the internuclear axis is nonzero. These doubly degenerate states contribute equally in conventional measurements and are thus treated the same in corresponding simulations. In this study, we demonstrate that in resonant excitation by intense laser pulses, the doubly degenerate ±Λ states must be clearly identified. This is exemplified in the X^(1)Σ → A^(1)Π transition of CO molecules. This distinction becomes especially important in the case of circularly polarized radiation. We attribute this phenomenon to the interference of electron-rotational pathways in the strong-field coupled transition with the ±Λ-state of the excited Π state. This research sheds light on the fundamental aspects of intense laser-molecule interactions when extending conventional theories.展开更多
We propose a novel approach to generate and manipulate topological Floquet bound states in the continuum(BICs)via a class of systems constructed by coupling two identical periodically driven one-dimensional Su-Schrief...We propose a novel approach to generate and manipulate topological Floquet bound states in the continuum(BICs)via a class of systems constructed by coupling two identical periodically driven one-dimensional Su-Schrieffer-Heeger chains.The formation of topological Floquet BICs can be adjusted only by tuning the driving amplitude or frequency,regardless of whether the static system has BICs or not.The interchain bias can only change the localization property of topological Floquet BICs,and a bigger bias can lead to transforming topological Floquet BICs into bound states out of the continuum(BOCs).But it does not change the topological properties of these topological Floquet states.Based on the repulsion effect of edge states,we propose to detect occurrence of topological Floquet BICs and transition point between topological Floquet BICs and BOCs using quantum walk.Our work provided a convenient and realistic approach for the experimental realization and manipulation of BICs in a single-particle quantum system.展开更多
Higher-order topological insulators,which host topologically protected states at boundaries that are at least two dimensions lower than the bulk,are an emerging class of topological materials.They provide great opport...Higher-order topological insulators,which host topologically protected states at boundaries that are at least two dimensions lower than the bulk,are an emerging class of topological materials.They provide great opportunities for exploring novel topological phenomena and fascinating applications.Utilizing a low-temperature scanning tunneling microscope,we construct breathing-kagome lattices with Fe adatoms on Ag(111)and investigate their electronic properties.We observe the higher-order topological boundary states in the topological phase but not in the trivial one,which is consistent with the theory.These states are found to be robust against the removal of bulk or edge adatoms.Further,we show the arbitrary positioning of these states either at corner,edge,or bulk sites by slightly modifying their neighbors.Our study not only demonstrates the formation and robustness of the electronic higher-order topological boundary states in real atomic systems but also provides a route for controlling their positions.展开更多
The quantum geometric tensor(QGT)is a fundamental quantity for characterizing the geometric properties of quantum states and plays an essential role in elucidating various physical phenomena.The traditional QGT,defned...The quantum geometric tensor(QGT)is a fundamental quantity for characterizing the geometric properties of quantum states and plays an essential role in elucidating various physical phenomena.The traditional QGT,defned only for pure states,has limited applicability in realistic scenarios where mixed states are common.To address this limitation,we generalize the defnition of the QGT to mixed states using the purifcation bundle and the covariant derivative.Notably,our proposed defnition reduces to the traditional QGT when mixed states approach pure states.In our framework,the real and imaginary parts of this generalized QGT correspond to the Bures metric and the mean gauge curvature,respectively,endowing it with a broad range of potential applications.Additionally,using our proposed mixed-state QGT,we derive the geodesic equation applicable to mixed states.This work establishes a unifed framework for the geometric analysis of both pure and mixed states,thereby deepening our understanding of the geometric properties of quantum states.展开更多
Topological band theory has been studied for free fermions for decades,and one of the most profound physical results is the bulk-boundary correspondence.Recently a focus in topological physics is extending topological...Topological band theory has been studied for free fermions for decades,and one of the most profound physical results is the bulk-boundary correspondence.Recently a focus in topological physics is extending topological classification to mixed states.Here,we focus on Gaussian mixed states for which the modular Hamiltonians of the density matrix are quadratic free fermion models with U(1)symmetry and can be classified by topological invariants.The bulk-boundary correspondence is then manifested as stable gapless modes of the modular Hamiltonian and degenerate spectrum of the density matrix.In this article,we show that these gapless modes can be detected by the full counting statistics,mathematically described by a function introduced as F(θ).A divergent derivative atθ=πcan be used to probe the gapless modes in the modular Hamiltonian.Based on this,a topological indicator,whose quantization to unity senses topologically nontrivial mixed states,is introduced.We present the physical intuition of these results and also demonstrate these results with concrete models in both one-and two-dimensions.Our results pave the way for revealing the physical significance of topology in mixed states.展开更多
A commentary on an anode-free cell design with electrochemically stable sodium borohydride solid electrolyte and pelletized aluminium current collector for sodium all-solid-state batteries is presented.First,the viabl...A commentary on an anode-free cell design with electrochemically stable sodium borohydride solid electrolyte and pelletized aluminium current collector for sodium all-solid-state batteries is presented.First,the viable strategies for implementing anode-free configuration utilizing solid-state electrolytes are briefly reviewed.Then,the remarkable work of Meng et al.on designing an anode-free sodium all-solid-state battery is elucidated.Finally,the significance of Meng’s work is discussed.展开更多
基金the framework of the Project 21T-4C045 of the Higher Education and Science Committee(RA)。
文摘The results of the 2022-2025 study conducted for the vulnerability assessment of pastures and for the development of improvement measures on the degraded land sections in the arid and semi-arid provinces of the Caucasus under the global climate change conditions are introduced in the current article.The main goal of our scientific work is to study and assess the current ecological and resource state of natural phytocenoses,pastures and hayfields in the arid and semi-arid landscapes under climate change.The paper presents the results of determining the areas and levels of degradation of the natural biogeocenoses and biogeocenoses of the pastures and hayfields in the mountain and highland landscapes.The results were obtained using remote sensing,field and laboratory studies and analyses.The conducted studies have revealed that along 34,174.5 ha pasture and 1342.0 meadows areas of the pastures at the Areni,Yeghegis,Yeghegnadzor and Vayq consolidated administrative territories situated in the arid and semi-arid zones of the Vayots Dzor Region high degradation was recorded in about 6508 hectares of pasture and 407 hectares of meadows areas,which is related to irregular and uncontrolled economic mismanagement of the local population and global climate change.To improve the ecological condition,accessibility and quality of ecosystem services of the pastures,hayfields and natural meadows,comprehensive restoration bioecological and agrotechnical measures have been proposed.They are aimed at improving the air,water and nutrient regimes of soils,at their bioprotection,as well as at the general increase in area and at improving the economic characteristics of the vegetation cover.Such measures on the ecosystem basis are appropriate in the context of enriching the qualitative composition of plants with useful ecological and economic bioecological characteristics,taking into account the characteristics of landscapes,weather and climatic conditions,and agricultural opportunities.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11574115 and 11704146)
文摘We theoretically investigate the excited state intramolecular proton transfer(ESIPT) behavior of the novel fluorophore bis-imine derivative molecule HNP which was designed based on the intersection of 1-(hydrazonomethyl)-naphthalene-2-ol and 1-pyrenecarboxaldehyde. Especially, the density functional theory(DFT) and time-dependent density functional theory(TDDFT) methods for HNP monomer are introduced. Moreover, the "our own n-layered integrated molecular orbital and molecular mechanics"(ONIOM) method(TDDFT:universal force field(UFF)) is used to reveal the aggregation-induced emission(AIE) effect on the ESIPT process for HNP in crystal. Our results confirm that the ESIPT process happens upon the photoexcitation for the HNP monomer and HNP in crystal, which is distinctly monitored by the optimized geometric structures and the potential energy curves. In addition, the results of potential energy curves reveal that the ESIPT process in HNP will be promoted by the AIE effect. Furthermore, the highest occupied molecular orbital(HOMO) and lowest unoccupied molecular orbital(LUMO) for the HNP monomer and HNP in crystal have been calculated. The calculation demonstrates that the electron density decrease of proton donor caused by excitation promotes the ESIPT process. In addition, we find that the variation of atomic dipole moment corrected Hirshfeld population(ADCH) charge for proton acceptor induced by the AIE effect facilitates the ESIPT process. The results will be expected to deepen the understanding of ESIPT dynamics for luminophore under the AIE effect and provide insight into future design of high-efficient AIE compounds.
文摘Starting from Wigner’s definition of the function named now after him we systematically develop different representation of this quasiprobability with emphasis on symmetric representations concerning the canonical variables (q,p) of phase space and using the known relation to the parity operator. One of the representations is by means of the Laguerre 2D polynomials which is particularly effective in quantum optics. For the coherent states we show that their Fourier transforms are again coherent states. We calculate the Wigner quasiprobability to the eigenstates of a particle in a square well with infinitely high impenetrable walls which is not smooth in the spatial coordinate and vanishes outside the wall boundaries. It is not well suited for the calculation of expectation values. A great place takes on the calculation of the Wigner quasiprobability for coherent phase states in quantum optics which is essentially new. We show that an unorthodox entire function plays there a role in most formulae which makes all calculations difficult. The Wigner quasiprobability for coherent phase states is calculated and graphically represented but due to the involved unorthodox function it may be considered only as illustration and is not suited for the calculation of expectation values. By another approach via the number representation of the states and using the recently developed summation formula by means of Generalized Eulerian numbers it becomes possible to calculate in approximations with good convergence the basic expectation values, in particular, the basic uncertainties which are additionally represented in graphics. Both considered examples, the square well and the coherent phase states, belong to systems with SU (1,1) symmetry with the same index K=1/2 of unitary irreducible representations.
文摘After developing the concept of displaced squeezed vacuum states in the non-unitary approach and establishing the connection to the unitary approach we calculate their quasiprobabilities and expectation values in general form. Then we consider the displacement of the squeezed vacuum states and calculate their photon statistics and their quasiprobabilities. The expectation values of the displaced states are related to the expectation values of the undisplaced states and are calculated for some simplest cases which are sufficient to discuss their categorization as sub-Poissonian and super-Poissonian statistics. A large set of these states do not belong to sub- or to super-Poissonian states but are also not Poissonian states. We illustrate in examples their photon distributions. This shows that the notions of sub- and of super-Poissonian statistics and their use for the definition of nonclassicality of states are problematic. In Appendix A we present the most important relations for SU (1,1) treatment of squeezing and the disentanglement of their operators. Some initial members of sequences of expectation values for squeezed vacuum states are collected in Appendix E.
文摘In this paper the results of dynamic NMR studies on ethylmethylamino-tertiary-butyl-phenylborane (EMABPB) with or without light are reported. The NMR data were recorded on a Bruker 400 MHz NMR equipped with our custom-made optical probe and with our custom-made 450 watts (W) monochromatic light sources. The molecular photochemistry including twisted intramolecular charge-transfer-excited-state (TICT) of the EMABPB in several solvents has been investigated. These results indicate that the aminoborane demonstrates multiple configurations in CD3Cl and CD2Cl2 resulting in the shifts of the signals of the alkyl groups on the nitrogen and boron. This indicates that there are some time-dependent changes at constant temperature over the irradiation interval. At ﹣60°C and the presence of light (λ = 265 nm), we observed a large change in the populations of the two sites, and this by itself indicates a modification in the rotation around the boron nitrogen bond in the excited state. By considering the existence of the TICT state, many important energy technologies may be developed with higher efficiency by controlling the back-electron transfer processes.
基金funded by the National Natural Science Foundation of China,No.81403455(to JQC)
文摘The specific mechanisms by which acupuncture affects the central nervous system are unclear. In the International Standard Scalp Acupuncture system, acupuncture needles are applied at the middle line of the vertex, anterior parietal-temporal oblique line, and the posterior parietal-temporal oblique line. We conducted a single-arm prospective clinical trial in which seven healthy elderly volunteers (three men and four women;50–70 years old) received International Standard Scalp Acupuncture at MS5 (the mid-sagittal line between Baihui (DU20) and Qianding (DU21)), the left MS6 (line joining Sishencong (EX-HN1) and Xuanli (GB6)), and the left MS7 (line joining DU20 and Qubin (GB7)). After acupuncture, resting-state functional magnetic resonance imaging demonstrated changes in the fractional amplitude of low frequency fluctuations and regional homogeneity in various areas, showing remarkable enhancement of regional homogeneity in the bilateral anterior cingulate, left medial frontal gyrus, supramarginal gyrus, right middle frontal gyrus, and inferior frontal gyrus. Functional connectivity based on a seed region at the right middle frontal gyrus (42, 51, 9) decreased at the bilateral medial superior frontal gyrus. Our data preliminarily indicates that the international standard scalp acupuncture in healthy elderly participants specifcally enhances the correlation between the brain regions involved in cognition and implementation of the brain network regulation system and the surrounding adjacent brain regions. The study was approved by the Ethics Committee of the China-Japan Union Hospital at Jilin University, China, on July 18, 2016 (approval No. 2016ks043).
文摘Heterogeneity of biological samples is usually considered a major obstacle for three-dimensional (3D) structure determination of macromolecular complexes. Heterogeneity may occur at the level of composition or conformational variability of complexes and affects most 3D structure determination methods that rely on signal averaging. Here, an approach is described that allows sorting structural states based on a 3D statistical approach, the 3D sampling and classification (3D-SC) of 3D structures derived from single particles imaged by cryo electron microscopy (cryo-EM). The method is based on jackknifing & bootstrapping of 3D sub-ensembles and 3D multivariate statistical analysis followed by 3D classification. The robustness of the statistical sorting procedure is corroborated using model data from an RNA polymerase structure and experimental data from a ribosome complex. It allows resolving multiple states within heterogeneous complexes that thus become amendable for a structural analysis despite of their highly flexible nature. The method has important implications for high-resolution structural studies and allows describing structure ensembles to provide insights into the dynamics of multi-component macromolecular assemblies.
基金supported by the National Key R&D Program of China(Grant No.2022YFA1403102)the National Natural Science Foundation of China(Grant Nos.12474478,92065102,and 61804056).
文摘The intrinsic antiferromagnetic topological insulators in the Mn-Bi-Te family,composed of superlattice-like MnBi_(2)Te_(4)/(Bi_(2)Te_(3))_(n)(n=0,1,2,3,...)layered structure,present intriguing states of matter such as quantum anomalous Hall effect and the axion insulator.However,the surface state gap,which is the prerequisite for the observation of these states,remains elusive.Here by molecular beam epitaxy,we obtain two types of MnBi_(4)Te_(7)films with the exclusive Bi_(2)Te_(3)(BT)or MnBi_(2)Te_(4)(MBT)terminations.By scanning tunneling spectroscopy,the mass terms in the surface states are identified on both surface terminations.Experimental results reveal the existence of a hybridization gap of approximately 23 meV in surface states on the BT termination.This gap comes from the hybridization between the surface states and the spin-split states in the adjacent MBT layer.On the MBT termination,an exchange mass term of about 28±2 meV in surface states is identified by taking magnetic-field-dependent Landau level spectra as well as theoretical simulations.In addition,the mass term varies with the field in the film with a heavy BiMn doping level in the Mn layers.These findings demonstrate the existence of mass terms in surface states on both types of terminations in our epitaxial MnBi_(4)Te_(7)films investigated by local probes.
文摘We examine possible funding sources for constructing Climate Change Haven Communities on a global basis. Areas of the planet that have the potential to house persons migrating to “safe havens” in their own or other countries will require the rapid construction of communities capable of supporting them, their families, businesses and farms. However, different political-economic conditions are found across the areas which can serve as locations for these Climate Change Haven Communities. We develop funding and construction strategies for the United States (free-market capitalism), France and Spain (European Union supported economies), and Taiwan region (state-directed economy). The proposals for the Taiwan region should also be applicable to the rest of China.
基金supported by the National Natural Science Foundation of China(Grant Nos.12234020,12474281,12450403,and 12274461)the Science and Technology Innovation Program of Hunan Province(Grant No.2022RC1193)。
文摘This letter demonstrates an experimental approach to measuring the angular-momentum-resolved population of excited states in laser-produced argon ions.By measuring the spectra of free induction decay emissions corresponding to the resonant transitions between Rydberg states,the relative population of the Rydberg states is obtained with known Einstein A-coefficients.This study deepens the mechanistic understanding of coherent dynamics in laser-driven ionic excited states,and establishes experimental benchmarks essential for validating and refining advanced quantum kinetic models in strong-field physics.
文摘Multitarget stool DNA(mt-sDNA) testing was approved for average risk colorectal cancer(CRC) screening by the United States Food and Drug Administration and thereafter reimbursed for use by the Medicare program(2014).The United States Preventive Services Task Force(USPSTF) October 2015 draft recommendation for CRC screening included mt-s DNA as an "alternative" screening test that "may be useful in select clinical circumstances",despite its very high sensitivity for early stage CRC.The evidence supporting mt-s DNA for routine screening use is robust.The clinical efficacy of mt-s DNA as measured by sensitivity,specificity,life-years gained(LYG),and CRC deaths averted is similar to or exceeds that of the other more specifically recommended screening options included in the draft document,especially those requiring annual testing adherence.In a population with primarily irregular screening participation,tests with the highest point sensitivity and reasonable specificity are more likely to favorably impact CRC related morbidity and mortality than those depending on annual adherence.This paper reviews the evidence supporting mt-s DNA for routine screening and demonstrates,using USPSTF's modeling data,that mt-s DNA at three-year intervals provides significant clinical net benefits and fewer complications per LYG than annual fecal immunochemical testing,high sensitivity guaiac based fecal occult blood testing and 10-year colonoscopy screening.
基金supported by the National Natural Science Foundation of China(62303273,62373226)the National Research Foundation,Singapore through the Medium Sized Center for Advanced Robotics Technology Innovation(WP2.7)
文摘Dear Editor,The letter deals with the distributed state and fault estimation of the whole physical layer for cyber-physical systems(CPSs) when the cyber layer suffers from DoS attacks. With the advancement of embedded computing, communication and related hardware technologies, CPSs have attracted extensive attention and have been widely used in power system, traffic network, refrigeration system and other fields.
基金supported in part by the National Natural Science Foundation of China(61873106,62303109)Start-Up Research Fund of Southeast University(RF1028623002)Shenzhen Science and Technology Program(JCYJ20230807114609019)
文摘Dear Editor,This letter focuses on how an attacker can design suitable improved zero-dynamics (ZD) attack signal based on state estimates of target system. Improved ZD attack is to change zero dynamic gain matrix of attack signal to a matrix with determinant greater than 1.
基金supported by the National Natural Science Foundation of China (Nos. 12121004, 12274273, and 12450402)the Science and Technology Department of Hubei Province (No. 2020CFA029)+1 种基金CAS Project for Young Scientists in Basic Research (No. YSBR-091)the Youth Innovation Promotion Association CAS (No. 2021328)。
文摘The ultrafast excitation dynamics of atoms and molecules exposed to circularly polarized two-color(CPTC)laser fields constitute a fascinating topic in attosecond science. Although extensive research has established the relationship between the Rydberg state excitation(RSE) yields and the CPTC field parameters, such as field amplitude ratios and helicity of two components, the role of the relative phase(φ) in modulating RSE efficiency remains unclear. In this work, we theoretically investigate the φ dependence of RSE and ionization yields in the co-rotating and counter-rotating circularly polarized two-color(CPTC) few-cycle laser fields by a semiclassical model. We find that, in co-rotating CPTC fields, both RSE and ionization yields display pronounced oscillations as a function of φ and these oscillations are significantly suppressed in the counter-rotating configuration, particularly for ionization yields. Moreover, the ratio of RSE to ionization yields exhibits an out-of-phase oscillatory pattern between low-and high-intensity regimes. These results can be comprehended by the unique feature of φ dependence of CPTC few-cycle fields, based on our semiclassical analysis. Our results demonstrate that phase-controlled CPTC fields offer a versatile tool for steering ultrafast ionization and RSE dynamics of atoms and molecules.
基金supported by the National Natural Science Foundation of China(Grant No.12374238)the Postdoctoral Science Foundation of Shaanxi Province (Grant No.2024BSHSDZZ148)Ministry of Science and Higher Education of Russian Federation (Grant No.FSRZ 2023-0006)。
文摘A singlet diatomic molecule naturally carries doubly degenerate ±Λ states when the projection of the total electronic angular momentum onto the internuclear axis is nonzero. These doubly degenerate states contribute equally in conventional measurements and are thus treated the same in corresponding simulations. In this study, we demonstrate that in resonant excitation by intense laser pulses, the doubly degenerate ±Λ states must be clearly identified. This is exemplified in the X^(1)Σ → A^(1)Π transition of CO molecules. This distinction becomes especially important in the case of circularly polarized radiation. We attribute this phenomenon to the interference of electron-rotational pathways in the strong-field coupled transition with the ±Λ-state of the excited Π state. This research sheds light on the fundamental aspects of intense laser-molecule interactions when extending conventional theories.
基金supported by the National Natural Science Foundation of China(Grant Nos.12175315 and 12205385)。
文摘We propose a novel approach to generate and manipulate topological Floquet bound states in the continuum(BICs)via a class of systems constructed by coupling two identical periodically driven one-dimensional Su-Schrieffer-Heeger chains.The formation of topological Floquet BICs can be adjusted only by tuning the driving amplitude or frequency,regardless of whether the static system has BICs or not.The interchain bias can only change the localization property of topological Floquet BICs,and a bigger bias can lead to transforming topological Floquet BICs into bound states out of the continuum(BOCs).But it does not change the topological properties of these topological Floquet states.Based on the repulsion effect of edge states,we propose to detect occurrence of topological Floquet BICs and transition point between topological Floquet BICs and BOCs using quantum walk.Our work provided a convenient and realistic approach for the experimental realization and manipulation of BICs in a single-particle quantum system.
基金supported by the National Key R&D Program of China(Grant Nos.2024YFA140850,2022YFA1403601,and 2023YFC2410501)the National Natural Science Foundation of China(Grants Nos.12241402,12474059,12274203,12374113,and 12274204)。
文摘Higher-order topological insulators,which host topologically protected states at boundaries that are at least two dimensions lower than the bulk,are an emerging class of topological materials.They provide great opportunities for exploring novel topological phenomena and fascinating applications.Utilizing a low-temperature scanning tunneling microscope,we construct breathing-kagome lattices with Fe adatoms on Ag(111)and investigate their electronic properties.We observe the higher-order topological boundary states in the topological phase but not in the trivial one,which is consistent with the theory.These states are found to be robust against the removal of bulk or edge adatoms.Further,we show the arbitrary positioning of these states either at corner,edge,or bulk sites by slightly modifying their neighbors.Our study not only demonstrates the formation and robustness of the electronic higher-order topological boundary states in real atomic systems but also provides a route for controlling their positions.
基金supported by the National Natural Science Foundation of China(Grant Nos.12347104,U24A2017,12461160276,and 12175075)the National Key Research and Development Program of China(Grant No.2023YFC2205802)+1 种基金the Natural Science Foundation of Jiangsu Province(Grant Nos.BK20243060 and BK20233001)in part by the State Key Laboratory of Advanced Optical Communication Systems and Networks,China。
文摘The quantum geometric tensor(QGT)is a fundamental quantity for characterizing the geometric properties of quantum states and plays an essential role in elucidating various physical phenomena.The traditional QGT,defned only for pure states,has limited applicability in realistic scenarios where mixed states are common.To address this limitation,we generalize the defnition of the QGT to mixed states using the purifcation bundle and the covariant derivative.Notably,our proposed defnition reduces to the traditional QGT when mixed states approach pure states.In our framework,the real and imaginary parts of this generalized QGT correspond to the Bures metric and the mean gauge curvature,respectively,endowing it with a broad range of potential applications.Additionally,using our proposed mixed-state QGT,we derive the geodesic equation applicable to mixed states.This work establishes a unifed framework for the geometric analysis of both pure and mixed states,thereby deepening our understanding of the geometric properties of quantum states.
基金supported by the National Key R&D Program of China(Grant No.2023YFA1406702)the Innovation Program for Quantum Science and Technology 2021ZD0302005+1 种基金the XPLORER Prizepartly supported by the Start-up Research Fund of Southeast University(RF1028624190)。
文摘Topological band theory has been studied for free fermions for decades,and one of the most profound physical results is the bulk-boundary correspondence.Recently a focus in topological physics is extending topological classification to mixed states.Here,we focus on Gaussian mixed states for which the modular Hamiltonians of the density matrix are quadratic free fermion models with U(1)symmetry and can be classified by topological invariants.The bulk-boundary correspondence is then manifested as stable gapless modes of the modular Hamiltonian and degenerate spectrum of the density matrix.In this article,we show that these gapless modes can be detected by the full counting statistics,mathematically described by a function introduced as F(θ).A divergent derivative atθ=πcan be used to probe the gapless modes in the modular Hamiltonian.Based on this,a topological indicator,whose quantization to unity senses topologically nontrivial mixed states,is introduced.We present the physical intuition of these results and also demonstrate these results with concrete models in both one-and two-dimensions.Our results pave the way for revealing the physical significance of topology in mixed states.
基金grateful for support from the National Natural Science Foundation of China(Nos.52472247,52172229,21401145)Fundamental Research Funds for the Central Universities(No.104972024KFYjc0079).
文摘A commentary on an anode-free cell design with electrochemically stable sodium borohydride solid electrolyte and pelletized aluminium current collector for sodium all-solid-state batteries is presented.First,the viable strategies for implementing anode-free configuration utilizing solid-state electrolytes are briefly reviewed.Then,the remarkable work of Meng et al.on designing an anode-free sodium all-solid-state battery is elucidated.Finally,the significance of Meng’s work is discussed.
