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医疗失效模式与效应分析在手术安全核查Time-out环节中的应用
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作者 陈红 张春瑾 +1 位作者 吴波 王禾 《护理学杂志》 北大核心 2026年第6期54-58,共5页
目的探讨医疗失效模式与效应分析在手术安全核查Time-out环节中的应用效果,为提升手术室护理质量提供参考。方法采用历史对照性研究,将2023年8-10月的11204例手术患者作为对照组,在Time-out环节中采用常规手术安全核查方式;2024年5-7月... 目的探讨医疗失效模式与效应分析在手术安全核查Time-out环节中的应用效果,为提升手术室护理质量提供参考。方法采用历史对照性研究,将2023年8-10月的11204例手术患者作为对照组,在Time-out环节中采用常规手术安全核查方式;2024年5-7月的11543例手术患者作为观察组,通过成立医疗失效模式与效应分析小组确定手术室Time-out核查环节中的失效模式,分析根本原因,拟定行动计划并组织实施。结果观察组Time-out规范执行率、手术及麻醉风险陈述确切率、安全核查单填写准确率、安全核查单归档率显著优于对照组(均P<0.05)。结论应用医疗失效模式与效应分析对手术安全核查Time-out环节进行规范管理,可以有效提升Time-out核查流程执行的规范性,保障手术患者安全。 展开更多
关键词 手术室 医疗失效模式与效应分析 手术安全核查 术前暂停核查 护理安全 护理管理
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洁定HS6617蒸汽灭菌器POST.TIMEOUT故障维修3例 被引量:4
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作者 谢德斌 《医疗卫生装备》 CAS 2017年第6期158-160,共3页
0引言根据《消毒技术规范》要求,对使用过的手术器械包,除部分不耐高温的,一般采用压力蒸汽灭菌的方法进行灭菌处理。我院于2004年购入3台瑞典洁定HS6617蒸汽灭菌器,该灭菌器是基于压力蒸汽灭菌原理制造而成的,通过选择不同的应用程序,... 0引言根据《消毒技术规范》要求,对使用过的手术器械包,除部分不耐高温的,一般采用压力蒸汽灭菌的方法进行灭菌处理。我院于2004年购入3台瑞典洁定HS6617蒸汽灭菌器,该灭菌器是基于压力蒸汽灭菌原理制造而成的,通过选择不同的应用程序,可对大多数材料进行灭菌处理[1]。 展开更多
关键词 洁定HS6617蒸汽灭菌器 POST.timeout报警 故障维修
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核电厂应急柴油机启动超时问题分析与处理
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作者 殷玉龙 李豪 +1 位作者 张兰岐 白文强 《电力安全技术》 2026年第2期51-54,共4页
某核电厂18PA6B型应急柴油机在检修后的启动试验中,发生单排启动超时问题,对启动空气系统、燃油系统、进排气系统、控制与传动系统进行梳理排查、原因分析及设备调整,最终发现是由于北方冬夏季气候差异导致进入气缸氧气含量不同引发该问... 某核电厂18PA6B型应急柴油机在检修后的启动试验中,发生单排启动超时问题,对启动空气系统、燃油系统、进排气系统、控制与传动系统进行梳理排查、原因分析及设备调整,最终发现是由于北方冬夏季气候差异导致进入气缸氧气含量不同引发该问题,并通过寻优调节调速器油门CD1、CD2的设定值消除了此缺陷,为该型号应急柴油机单排启动超时问题处理及调速器参数寻优提供借鉴。 展开更多
关键词 应急柴油机 启动超时 冬夏季差异 调速器参数
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基于命中信息压缩的流表空闲超时方法
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作者 阎封宜 刘磊 《电子设计工程》 2026年第2期145-149,158,共6页
随着网络技术的发展和新兴业务带来的用户需求增长,网络规模不断扩大,流表项的数量迅速增加。为解决SDN网络中大规模流表空闲超时处理的资源占用问题,提出一种基于命中信息压缩的流表空闲超时机制。该机制由数据平面软硬协同实现,在硬... 随着网络技术的发展和新兴业务带来的用户需求增长,网络规模不断扩大,流表项的数量迅速增加。为解决SDN网络中大规模流表空闲超时处理的资源占用问题,提出一种基于命中信息压缩的流表空闲超时机制。该机制由数据平面软硬协同实现,在硬件上进行流表匹配命中情况的统计,对命中信息进行压缩存储;软件定时与硬件进行压缩信息同步,计算并判断表项的超时情况。测试结果表明,相较于无压缩存储机制,该方法能够在1M条表项、支持数据包100 Gbps转发速率的前提下,节约90%的硬件存储空间。 展开更多
关键词 软件定义网络 流表 空闲超时 压缩
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万兆同轴宽带接入网HIMAC 3.0的拆帧重排序方法
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作者 黄一明 潘伟涛 邱智亮 《电子科技》 2026年第1期25-31,共7页
高性能同轴电缆网络(High Performance Network Over Coax,HINOC)技术是一种光纤同轴混合接入技术,已发展至第3代。为了实现万兆以太网的接入速率,第3代HINOC引入了多信道绑定机制。但该机制在有效扩展HINOC网络信道带宽的同时易导致HIM... 高性能同轴电缆网络(High Performance Network Over Coax,HINOC)技术是一种光纤同轴混合接入技术,已发展至第3代。为了实现万兆以太网的接入速率,第3代HINOC引入了多信道绑定机制。但该机制在有效扩展HINOC网络信道带宽的同时易导致HIMAC(HINOC Medium Access Control)拆帧端接收的数据流失序。针对该问题,文中提出了一种拆帧重排序方法。通过重排序队列缓存管理、入队逻辑地址计算、超时判断及清空以及出队判断等关键技术的设计和实现来解决多信道绑定机制引起的拆帧乱序问题,并对其关键功能点进行仿真验证和板级验证。实验结果表明,所提方法能够有效处理多信道绑定导致的乱序问题,并且能够确保系统在遇到错误情况时稳定运行,具有较强的鲁棒性,满足万兆同轴宽带接入HIMAC 3.0的功能和性能要求。 展开更多
关键词 万兆同轴宽带接入 HIMAC 3.0 多信道绑定 数据帧乱序 拆帧 重排序 超时清空 队列缓存
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Analysis on the Problems in Start-up and Debugging of Two 600 MW Generating Units in Yangzhou No.2 Thermal Power Plant
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作者 蒯狄正 《Electricity》 2001年第2期11-15,共5页
The problems including excessive flow of attemperating water for boiler, failure of butterfly valve at the outlet of circulating water pump, burnt-out of thyristor for excitation regulator, load variation rate of CCS ... The problems including excessive flow of attemperating water for boiler, failure of butterfly valve at the outlet of circulating water pump, burnt-out of thyristor for excitation regulator, load variation rate of CCS not complying with the contract target, etc. occurred during start-up and debugging of two 600 MW generating units in Yangzhou No.2 Thermal Power Plant. Through analysis on these problems. the remedial measures were put forward, to which can be referred for similar units. 展开更多
关键词 start-up and debugging problems analysis remedial measures 600 MW generating unit
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Start-up of anaerobic ammonia oxidation bioreactor with nitrifying activated sludge 被引量:26
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作者 ZHENGPing LINFeng-mei +1 位作者 HUBao-lan CHENJian-song 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2004年第1期13-16,共4页
The anaerobic ammonia oxidation(Anammox) bioreactor was successfully started up with the nitrifying activated sludge. After anaerobically operated for 105 d, the bioreactor reached a good performance with removal perc... The anaerobic ammonia oxidation(Anammox) bioreactor was successfully started up with the nitrifying activated sludge. After anaerobically operated for 105 d, the bioreactor reached a good performance with removal percentage of both ammonia and nitrite higher than 95% and volumetric total nitrogen removal as high as 149.55 mmol/(L·d). The soft padding made an important contribution to the high efficiency and stability because it held a large amount of biomass in the bioreactor. 展开更多
关键词 Anammox bioreactor nitrifying activated sludge start-up
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Fast start-up anammox process using Acyl-homoserine lactones(AHLs) containing supernatant 被引量:8
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作者 Ran Zhao Hanmin Zhang +1 位作者 Fan Zhang Fenglin Yang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2018年第3期127-132,共6页
N-dodecanoyl homoserine lactone(C(12)-HSL)was detected in the supernatant of an anammox granular sludge reactor(AGSR).C(12)-HSL could enhance the specific anammox activity of anammox biomass.Adding C(12)-HSL... N-dodecanoyl homoserine lactone(C(12)-HSL)was detected in the supernatant of an anammox granular sludge reactor(AGSR).C(12)-HSL could enhance the specific anammox activity of anammox biomass.Adding C(12)-HSL-containing AGSR supernatant into the continuously stirred tank reactors reduced the start-up time of the anammox process from80 to 66 days.Moreover,the nitrogen loading rate was also enhanced to 1.6 times that of the control reactor.AHLs could increase the secretion of extracellular polymeric substances and anammox obtained better enrichment with the addition of AHLs-containing AGSR supernatant.Denaturing gradient gel electrophoresis analysis further revealed that AHLs played a role in mediating microbial community parameters.In conclusion,adding AHL-containing supernatant could be an effective and economical way to accelerate the start-up of anammox. 展开更多
关键词 ANAMMOX Quorum sensing Biomass supernatant start-up acceleration
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A method to refine the start-up scheme of compression and refrigeration systems in ethylene plants via dynamic simulation 被引量:2
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作者 Shengfu Zhang Yongchen Zhao +2 位作者 Tong Qiu Guang Song Jinsong Zhao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2016年第8期1007-1012,共6页
Starting the cracking gas compressor and precooling the refrigeration system are keys to start-up of an ethylene plant and accounts for up to 50% of the total start-up time and plant flare emissions. Premature feeding... Starting the cracking gas compressor and precooling the refrigeration system are keys to start-up of an ethylene plant and accounts for up to 50% of the total start-up time and plant flare emissions. Premature feeding of cracking furnaces can be avoided if the cracking gas compressor is started and the refrigeration system is precooled in advance using mixed gas as the start-up working medium(SWM). Start-up scenario with mixed gas as SWM could significantly reduce the emission loss and shorten the precooling time. Research shows that making appropriate start-up scheme is important not only to ensure operational safety and feasibility, but also to reduce energy consumption. In this paper, a method is proposed to select suitable start-up operational parameters of compression and refrigeration system with sufficient safe operating ranges and short precooling time. The complex interrelation among key parameters of start-up is analyzed. It is found that higher energy consumption, especially for super high-pressure steam(SS), can promote operational safety and shorten the precooling time during start-up.Based on steady-state and dynamic simulation, appropriate operating parameter ranges are determined with reasonable SS consumption. A real case study demonstrates that an appropriate start-up scheme will optimize the operation. 展开更多
关键词 start-up ETHYLENE PLANT start-up working MEDIUM MIXED gas RUN Compression system
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A comparison study of the start-up of a MnO_x filter for catalytic oxidative removal of ammonium from groundwater and surface water 被引量:6
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作者 Ya Cheng Ye Li +3 位作者 Tinglin Huang Yuankui Sun Xinxin Shi Yuezong Shao 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2018年第3期327-334,共8页
As an efficient method for ammonium(NH4~+)removal,contact catalytic oxidation technology has drawn much attention recently,due to its good low temperature resistance and short start-up period.Two identical filters ... As an efficient method for ammonium(NH4~+)removal,contact catalytic oxidation technology has drawn much attention recently,due to its good low temperature resistance and short start-up period.Two identical filters were employed to compare the process for ammonium removal during the start-up period for ammonium removal in groundwater(Filter-N)and surface water(Filter-S)treatment.Two types of source water(groundwater and surface water)were used as the feed waters for the filtration trials.Although the same initiating method was used,Filter-N exhibited much better ammonium removal performance than Filter-S.The differences in catalytic activity among these two filters were probed using X-ray diffraction(XRD),scanning electron microscopy(SEM),X-ray photoelectron spectroscopy(XPS),and compositional analysis.XRD results indicated that different manganese oxide species were formed in Filter-N and Filter-S.Furthermore,the Mn3p XPS spectra taken on the surface of the filter films revealed that the average manganese valence of the inactive manganese oxide film collected from Filter-S(FS-MnOx)was higher than in the film collected from Filter-N(FN-MnOx).Mn(IV)was identified as the predominant oxidation state in FS-MnOxand Mn(III)was identified as the predominant oxidation state in FN-MnOx.The results of compositional analyses suggested that polyaluminum ferric chloride(PAFC)used during the surface water treatment was an important factor in the mineralogy and reactivity of MnOx.This study provides the theoretical basis for promoting the wide application of the technology and has great practical significance. 展开更多
关键词 Ammonium removal Surface water Underground water start-up Catalytic oxidation FILTRATION
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M/G/1 Vacation Queueing Systems with Server Timeout 被引量:2
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作者 Oliver C. Ibe 《American Journal of Operations Research》 2015年第2期77-88,共12页
We consider a single-server vacation queueing system that operates in the following manner. When the server returns from a vacation, it observes the following rule. If there is at least one customer in the system, the... We consider a single-server vacation queueing system that operates in the following manner. When the server returns from a vacation, it observes the following rule. If there is at least one customer in the system, the server commences service and serves exhaustively before taking another vacation. If the server finds the system empty, it waits a fixed time c. At the expiration of this time, the server commences another vacation if no customer has arrived;otherwise, it serves exhaustively before commencing another vacation. Analytical results are derived for the mean waiting time in the system. The timeout scheme is shown to be a generalized scheme of which both the single vacation and multiple vacations schemes are special cases, with c=&infin;and c=0, respectively. The model is extended to the N-policy vacation queueing system. 展开更多
关键词 VACATION QUEUEING Systems timeout POLICIES Performance Analysis N-POLICY with timeout
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Start-up current adaptive control for sensorless high-speed brushless DC motors based on inverse system method and internal mode controller 被引量:9
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作者 He Yanzhao Zheng Shiqiang Fang Jiancheng 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2017年第1期358-367,共10页
The start-up current control of the high-speed brushless DC(HS-BLDC) motor is a challenging research topic. To effectively control the start-up current of the sensorless HS-BLDC motor, an adaptive control method is ... The start-up current control of the high-speed brushless DC(HS-BLDC) motor is a challenging research topic. To effectively control the start-up current of the sensorless HS-BLDC motor, an adaptive control method is proposed based on the adaptive neural network(ANN)inverse system and the two degrees of freedom(2-DOF) internal model controller(IMC). The HS-BLDC motor is identified by the online least squares support vector machine(OLS-SVM) algorithm to regulate the ANN inverse controller parameters in real time. A pseudo linear system is developed by introducing the constructed real-time inverse system into the original HS-BLDC motor system. Based on the characteristics of the pseudo linear system, an extra closed-loop feedback control strategy based on the 2-DOF IMC is proposed to improve the transient response performance and enhance the stability of the control system. The simulation and experimental results show that the proposed control method is effective and perfect start-up current tracking performance is achieved. 展开更多
关键词 Adaptive control Brushless DC motors Inverse systems Internal model controller Neural networks start-up Support vector machines
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DDoS Defense Algorithm Based on Multi-Segment Timeout Technology 被引量:1
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作者 DU Ruizhong YANG Xiaohui MA Xiaoxue HE Xinfeng 《Wuhan University Journal of Natural Sciences》 CAS 2006年第6期1823-1826,共4页
Through the analysis to the DDoS(distributed denial of service) attack, it will conclude that at different time segments, the arrive rate of normal SYN (Synchronization) package are similar, while the abnormal pac... Through the analysis to the DDoS(distributed denial of service) attack, it will conclude that at different time segments, the arrive rate of normal SYN (Synchronization) package are similar, while the abnormal packages are different with the normal ones. Toward this situation a DDoS defense algorithm based on multi-segment timeout technology is presented, more than one timeout segment are set to control the net flow. Experiment results show that in the case of little flow, multi-segment timeout has the ability dynamic defense, so the system performance is improved and the system has high response rate. 展开更多
关键词 DDoS(distributed denial of service) multi-segments timeout dynamic defense net flow analysis
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The exact solution of Stokes' second problem including start-up process with fractional element 被引量:3
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作者 Kaixin Hu Keqin Zhu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2009年第5期577-582,共6页
The start-up process of Stokes' second problem of a viscoelastic material with fractional element is studied. The fluid above an infinite flat plane is set in motion by a sudden acceleration of the plate to steady os... The start-up process of Stokes' second problem of a viscoelastic material with fractional element is studied. The fluid above an infinite flat plane is set in motion by a sudden acceleration of the plate to steady oscillation. Exact solutions are obtained by using Laplace transform and Fourier transform. It is found that the relationship between the first peak value and the one of equal-amplitude oscillations depends on the distance from the plate. The amplitude decreases for increasing frequency and increasing distance. 展开更多
关键词 Stokes' second problem start-up process Fractional element Laplace transform Fourier transform
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The start-up of biohydrogen-producing process by bioaugmentation in the EGSB reactor 被引量:5
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作者 王相晶 Ren Nanqi +1 位作者 Xiang Wensheng Guo Wanqian 《High Technology Letters》 EI CAS 2006年第3期328-332,共5页
Expanded granular sludge bed (EGSB) reactor and bioaugmentation were employed to investigate biohydrogen production with molasses wastewater. The start-up experiments consisted of two stages. In the first stage (0 ... Expanded granular sludge bed (EGSB) reactor and bioaugmentation were employed to investigate biohydrogen production with molasses wastewater. The start-up experiments consisted of two stages. In the first stage (0 - 24d) seeded with activated sludge, the butyric acid type-fermentation formed when the initial expanding rate, organic loading rate (OLR), the initial redox potential (ORP) and hydraulic retention time (HRT) were 10%, 10.0 kg COD/(m^3·d), -215 mV and 6.7 h, respectively. At the beginning of the second stage on day 25, the novel hydrogen-producing fermentative bacterial strain B49 (AF481148 in EMBL) were inoculated into the reactor under the condition of OLR 16. 0 kg COD/(m^3·d), ORP and HRT about - 139 mV and 6.7 h, respectively, and then the reaction system transformed to ethanol-type fermentation gradually with the increase in OLR. When OLR, ORP and HRT were about 94.3 kg COD/(m^3·d), -250 mV and 1.7 h, respectively, the system achieved the maximum hydrogen-producing rate of 282.6 mL H2/L reactor·h and hydrogen percentage of 51% -53% in the biogas. 展开更多
关键词 start-up biohydrogen production BIOAUGMENTATION hydrogen-producing bacterial strain B49 EGSB reactor
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A Concept for Safe and Less Expensive Acceleration of a Marine Steam Turbine Start-up 被引量:1
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作者 Mateusz Bryk Jerzy Głuch 《哈尔滨工程大学学报(英文版)》 CSCD 2023年第2期381-394,共14页
This paper analyses the issue of accelerated start-up of a marine steam turbine,which is an important problem because the start-up of a steam machine involves the combustion of fuel that is not transformed into useful... This paper analyses the issue of accelerated start-up of a marine steam turbine,which is an important problem because the start-up of a steam machine involves the combustion of fuel that is not transformed into useful energy.To find novel technologies that offer improvements in this aspect is essential due to restrictions on reducing ship emissions.Thus,the shorter the start-up time,the better for the environment and economy.High-pressure(HP)part of the turbine originally located on the Queen Elizabeth II unit was analysed.Advanced numerical calculations by thermal fluid-solid-interaction(Thermal FSI)were carried out.A series of simulations were performed for the accelerated start-up with controlled steam injection.A description of the chosen calculation methodology and the results obtained by simulation are included in this paper.The stress occurring during the accelerated start-up are approximately 40 MPa higher than those during the reference start-up.The relative elongations between the rotor and the hull during accelerated start-up reach a maximum value of 0.89 mm(0.83 mm for ultra-fast start-up).Reducing the steam turbine start-up time by 75%results in a 36.7 tons reduction in fuel consumption for start-up,resulting in an annual savings of 5372 USD.In conclusion,the concept proposed by the authors is safe,less expensive and does not affect the life of the turbine.In addition,results and applications from Siemens prove that additional injection of cooling steam is possible. 展开更多
关键词 Marine steam turbine start-up Ultra-fast start-up Thermal stress Relative elongations Fuel savings Energy management
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Start-up and Performance of a Novel Reactor----Jet Biogas Inter-loop Anaerobic Fluidized Bed 被引量:2
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作者 邓志毅 韦朝海 周秀峰 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2008年第1期143-150,共8页
A novel anaerobic reactor, jet biogas inter-loop anaerobic fluidized bed (JBILAFB), was designed and constructed. The start-up and performance of the reactor was investigated in the Process. of .artificial glucose w... A novel anaerobic reactor, jet biogas inter-loop anaerobic fluidized bed (JBILAFB), was designed and constructed. The start-up and performance of the reactor was investigated in the Process. of .artificial glucose wastewater treatment. With the wastewater recycle ratio of 2.5 : 1, the recycled wastewater with biogas could mix sludge and wastewater in the JBILAFB reactor completely. The start-up of the JBILAFB reactor could be completed in less than 70 d through maintenance of hydraulic retention time (HR^I") and stepwise increase of feed total organic carbon (TOC) concentration. After the start-up, with the volumetric TOC loadings of 14.3 kg·m ^-3·d^-1, the TOC removal ratio, the effluent pH, and the volatile fatty acids (VFA)/alkalinity of the JBILAFB reactor were more than 80%, close to 7.0 and less than 0.4, respectively. Moreover, CH4 was produced at more than 70% of the theoretical value, The reactor exhibited high stability under the condition of high volumetric TOC loading. Sludge granules in the JBILAFB reactor were developed during the start-up and their sizes were enlarged with the stepwise increase of volumetric TOC loadings from 0.8 kg.m^-3.d ^-1 to 14.3 kg.m^-3.d^-1. Granules, an offwhite color and a similar spherical shape, were mainly comprised of global-like bacteria. These had good methanogenic activity and settleability, which were formed probably through adhesion of the bacteria. Some inorganic metal compounds such as Fe, Ca, Mg, Al, etc. were advantageous to the formation of the granules. 展开更多
关键词 anaerobic reactor jet biogas inter-loop anaerobic fluidized bed wastewater treatment start-up granule sludge
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Experimental research on characteristic of start-up pressure wave propagation in gelled crude oil by large-scale flow loop 被引量:1
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作者 崔秀国 艾慕阳 +2 位作者 姜保良 霍连风 张立新 《Journal of Central South University》 SCIE EI CAS 2008年第S1期467-470,共4页
In order to research start-up pressure wave propagation mechanism and determine pressure wave speed in gelled crude oil pipelines accurately,experiment of Large-scale flow loop was carried out.In the experiment,start-... In order to research start-up pressure wave propagation mechanism and determine pressure wave speed in gelled crude oil pipelines accurately,experiment of Large-scale flow loop was carried out.In the experiment,start-up pressure wave speeds under various operation conditions were measured,and effects of correlative factors on pressure wave were analyzed.The experimental and theoretical analysis shows that thermal shrinkage and structural properties of gelled crude oils are key factors influencing on start-up pressure wave propagation.The quantitative analysis for these effects can be done by using volume expansion coefficient and structural property parameter of gelled crude oil.A new calculation model of pressure wave speed was developed on the basis of Large-scale flow loop experiment and theoretical analysis. 展开更多
关键词 gelled CRUDE oil start-up pressure wave PROPAGATION CHARACTERISTIC lager-scale FLOW LOOP
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Stress-Structure Relationship of the Reversible Associating Polymer Network under Start-up Shear Flow 被引量:1
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作者 Ai-Qing Liu Li-Jun Liu +3 位作者 Wen-Sheng Xu Xiao-Lei Xu Ji-Zhong Chen Li-Jia An 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2021年第3期387-396,I0008,共11页
We adopt Langevin dynamics to explore the stress-structure relationship of telechelic reversible associating polymer gel during startup shear flow, with shear strengths varying from Wi=12.6 to Wi=12640. At weak shear ... We adopt Langevin dynamics to explore the stress-structure relationship of telechelic reversible associating polymer gel during startup shear flow, with shear strengths varying from Wi=12.6 to Wi=12640. At weak shear flow Wi=12.6, the shear stress proportionally increases with shear strain at short times, followed by a strain hardening behavior and then passes through a maximum(σmax, γmax) and finally decreases until it reaches the steady state. During the evolution of stress, the gel network is only slightly broken and essentially maintains its framework, and the strain hardening behavior originates from the excessive stretching of chains. On the other hand, the stress-strain curve at intermediate shear flow Wi=505.6 shows two differences from that at Wi=12.6, namely, the absence of strain hardening and a dramatic increase of stress at large strains,which is caused by the rupture of gel network at small strains and the network recovery at large strains, respectively. Finally, at very strong shear flow Wi=6319.7, the gel network is immediately broken by shear flow and the stress-strain curve exhibits similar behaviors to those of classical polymeric liquids. 展开更多
关键词 Associating polymer start-up shear Stress-structure relationship
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Molecular Dynamics Study of Star Polymer Melts under Start-up Shear 被引量:1
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作者 Dong-Dong Wang Kai-Feng Yu +1 位作者 Xiao-Lei Xu Wen-Sheng Xu 《Chinese Journal of Polymer Science》 SCIE EI CAS CSCD 2022年第7期807-816,共10页
It has been established that star polymers with a large number of arms display both the conventional chain relaxation and a slower interchain relaxation due to the formation of hard cores,which is called the local str... It has been established that star polymers with a large number of arms display both the conventional chain relaxation and a slower interchain relaxation due to the formation of hard cores,which is called the local structural relaxation.Here,we demonstrate that this unique relaxation property of multi-arm stars leads to unusual rheological behaviors.We study the response of star polymer melts with various arm numbers to start-up shear flow via nonequilibrium molecular dynamics simulation.Our simulation results indicate that the stress-strain response of multi-arm star polymer melts differs from that of star polymers with a small number of arms in both quantitative and qualitative manners.While the multi-arm star polymer melts exhibit an overshoot peak in the stress-strain curve both at relatively small and sufficiently large shear rates,two overshoot peaks appear when the flow strength is comparable to the relaxation time of the star polymers.This double stress overshoot is absent in linear polymers and star polymers with a small number of arms and is evidently related to the presence of the local structural relaxation in star polymers with a large number of arms.We present a detailed analysis of the conformational and dynamical properties of star polymer melts under start-up shear to gain a molecular understanding of their stress response. 展开更多
关键词 SIMULATION Star polymer start-up shear
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