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Apically guiding electron/mass transfer reaction induced by Ag/FeN_(x)Mott-Schottky effect within a hollow star reactor toward high performance zinc-air batteries 被引量:1
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作者 Kaixiang Shi Kaixin Wang +7 位作者 Tong Li Junhao Li Jie Ren Xu Li Yonggang Min Zhouguang Lu Wei Tan Quanbing Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期106-116,I0004,共12页
The disparity in the transfer of carriers(electrons/mass)during the reaction in zinc-air batteries(ZABs)results in sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),along with e... The disparity in the transfer of carriers(electrons/mass)during the reaction in zinc-air batteries(ZABs)results in sluggish kinetics of the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),along with elevated overpotentials,thereby imposing additional constraints on its utilization.Therefore,the pre-design and target-development of inexpensive,high-performance,and long-term stable bifunctional catalysts are urgently needed.In this work,an apically guiding dual-functional electrocatalyst(Ag-FeN_(x)-N-C)was prepared,in which a hierarchical porous nitrogen-doped carbon with three-dimensional(3D)hollow star-shaped structure is used as a substrate and high-conductivity Ag nanoparticles are coupled with iron nitride(FeN_(x))nanoparticles.Theoretical calculations indicate that the Mott-Schottky heterojunction as an inherent electric field comes from the two-phase bound of Ag and FeN_(x),of which electron accumulation in the FeN_(x)phase region and electron depletion in the Ag phase region promote orientated-guiding charge migration.The effective modulation of local electronic structures felicitously reforms the d-band electron-group distribution,and intellectually tunes the masstransfer reaction energy barriers for both ORR/OER.Additionally,the hollow star-s haped hierarchical porous structure provides an apical region for fast mass transfer.Experimental results show that the halfwave potential for ORR is 0.914 V,and the overpotential for OER is only 327 mV at 10 mA cm^(-2).A rechargeable ZAB with Ag-FeN_(x)-N-C as the air cathode demonstrates long-term cycling performance exceeding 1500 cycles(500 h),with a power density of 180 mW cm^(-2).Moreover,when employing AgFeN_(x)-N-C as the air cathode,flexible ZABs demonstrate a notable open-circuit voltage of 1.42 V and achieve a maximum power density of 65.6 mW cm^(-2).Ag-FeN_(x)-N-C shows guiding electron/mass transfer route and apical reaction microenvironment for the electrocatalyst architecture in the exploration prospects of ZABs. 展开更多
关键词 Hollow star structure Mott-Schottky effect Apically guiding effect Bifunctional catalysis Zinc-air batteries
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The effect of dynamical quark mass on the calculation of a strange quark star's structure
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作者 Gholam Hossein Bordbar Babak Ziaei 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2012年第5期540-550,共11页
We discuss the dynamical behavior of strange quark matter components, in particular the effects of density dependent quark mass on the equation of state of strange quark matter. The dynamical masses of quarks are comp... We discuss the dynamical behavior of strange quark matter components, in particular the effects of density dependent quark mass on the equation of state of strange quark matter. The dynamical masses of quarks are computed within the Nambu-Jona-Lasinio model, then we perform strange quark matter calculations em- ploying the MIT bag model with these dynamical masses. For the sake of compar- ing dynamical mass interaction with QCD quark-quark interaction, we consider the one-gluon-exchange term as the effective interaction between quarks for the MIT bag model. Our dynamical approach illustrates an improvement in the obtained equation of state values. We also investigate the structure of the strange quark star using Tolman- Oppenheimer-Volkoff equations for all applied models. Our results show that dynamical mass interaction leads to lower values for gravitational mass. 展开更多
关键词 stars dense matter - equation of state - ISM structure -- supemova remnants
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Calculation of the structural properties of a strange quark star in the presence of a strong magnetic field using a density dependent bag constant 被引量:1
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作者 Gholam Hossein Bordbar Hajar Bahri Fatemeh Kayanikhoo 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2012年第9期1280-1290,共11页
We have calculated the structural properties of a strange quark star with a static model in the presence of a strong magnetic field. To this end, we use the MIT bag model with a density dependent bag constant. To para... We have calculated the structural properties of a strange quark star with a static model in the presence of a strong magnetic field. To this end, we use the MIT bag model with a density dependent bag constant. To parameterize the density dependence of the bag constant, we have used our results for the lowest order constrained variational calculation of the asymmetric nuclear matter. By calculating the equation of state of strange quark matter, we have shown that the pressure of this system increases by increasing both density and magnetic field. Finally, we have investigated the effect of density dependence of the bag constant on the structural properties of a strange quark star. 展开更多
关键词 stars: dense matter equation of state ISM: structure supernova remnants
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Star formation properties in barred galaxies (SFB) Ⅱ. NGC 2903 and NGC 7080
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作者 Zhi-Min Zhou Chen Cao Hong Wu 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2012年第3期235-248,共14页
Stellar bars are important for the secular evolution of disk galaxies because they can drive gas into the galactic central regions. To investigate the star formation properties in barred galaxies, we presented a multi... Stellar bars are important for the secular evolution of disk galaxies because they can drive gas into the galactic central regions. To investigate the star formation properties in barred galaxies, we presented a multi-wavelength study of two barred galaxies: NGC 2903 and NGC 7080. We performed the three-component bulge-diskbar decomposition using the 3.6 μm images, and identified the bulges in the two galaxies as pseudobulges. Based on the narrowband Hα images, the star formation clumps were identified and analyzed. The clumps in the bulge regions have the highest surface densities of star formation rates in both galaxies, while the star formation activities in the bar of NGC 2903 are more intense than those in the bar of NGC 7080. Finally, we compared our results with the scenario of bar-driven secular evolution in previous studies, and discussed the possible evolutionary stages of the two galaxies. 展开更多
关键词 galaxies: evolution—galaxies: individual (NGC 2903 NGC 7080)—galaxies: star formation—galaxies: structure
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STUDY ON HIGH PERFORMANCE ANTI—WEAR ADDITIVES FROM WATER—SOLUBLE POLYMERIC LUBRICANT
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作者 官文超 Tsutom Kagiya 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1995年第4期338-346,共9页
A series of high performance lubricants of water-soluble polymers with telechelic or star structures has been studied. Their average molecular weights (M) over bar are 1800-6000. The chemical structures of the lubrica... A series of high performance lubricants of water-soluble polymers with telechelic or star structures has been studied. Their average molecular weights (M) over bar are 1800-6000. The chemical structures of the lubricants are characterized by their hydrophilic groups (-CH2CH2O-), -COOH, -OH, -CONH2 and antiwear active elements (S,P,Zn and Mo). The results of assessing for the anti-wear property indicate that this kind of water-soluble polymeric lubricants possesses excellent watersolubility, lubricity and anti-wear property. A preliminary study on the anti-wear mechanism of the polymers is performed by means of electron probe and scanning electron microscopy (SEM). 展开更多
关键词 ANTIWEAR LUBRICANT friction water-soluble polymer star structure
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Stellar Abundance and Galactic Chemical Evolution through LAMOST Spectroscopic Survey 被引量:1
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作者 Gang Zhao Yu-Qin Chen +5 位作者 Jian-Rong Shi Yan-Chun Liang Jin-Liang Hou Li Chen Hua-Wei Zhang Ai-Gen Li 《Chinese Journal of Astronomy and Astrophysics》 CSCD 2006年第3期265-280,共16页
A project of a spectroscopic survey of Galactic structure and evolution with a Large sky Area Multi-Object fiber Spectroscopic Telescope (LAMOST) is presented. The spectroscopic survey consists of two observational ... A project of a spectroscopic survey of Galactic structure and evolution with a Large sky Area Multi-Object fiber Spectroscopic Telescope (LAMOST) is presented. The spectroscopic survey consists of two observational modes for various targets in our Galaxy. One is a major survey of the Milky Way aimed at a systematic study of the stellar abundance and Galactic chemical evolution through low resolution (R = 1000 2000) spectroscopy. Another is a follow-up observation with medium resolution (R = 10000) spectrographs aimed at detailed studies of the selected stars with different chemical composition, kinematics and dynamics. 展开更多
关键词 techniques: spectroscopic - stars: abundances - Galaxy: structure - Galaxy:abundances - Galaxy: kinematics and dynamics - Galaxy: evolution
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The YNEV stellar evolution and oscillation code
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作者 Qian-Sheng Zhang 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2015年第4期549-568,共20页
We have developed a new stellar evolution and oscillation code YNEV, which calculates the structures and evolutions of stars, taking into account hydrogen and helium burning. A nonlocal turbulent convection theory and... We have developed a new stellar evolution and oscillation code YNEV, which calculates the structures and evolutions of stars, taking into account hydrogen and helium burning. A nonlocal turbulent convection theory and an updated over- shoot mixing model are optional in this code. The YNEV code can evolve low- and intermediate-mass stars from the pre-main sequence to a thermally pulsing asymptotic branch giant or white dwarf. The YNEV oscillation code calculates the eigenfrequen- cies and eigenfunctions of the adiabatic oscillations for a given stellar structure. The input physics and numerical scheme adopted in the code are introduced. Examples of solar models, stellar evolutionary tracks of low- and intermediate-mass stars with different convection theories (i.e. mixing-length theory and nonlocal turbulent con- vection theory), and stellar oscillations are shown. 展开更多
关键词 stars -- stellar structure -- stellar evolution -- stellar oscillations
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