As one photovoltaic supernova,perovskite solar cells(PSCs)have exhibited certified power conversion efficiencies exceeding 27%.Yet,the presence of enormous defects,mainly for the dominant iodine vacancy(VI),always ind...As one photovoltaic supernova,perovskite solar cells(PSCs)have exhibited certified power conversion efficiencies exceeding 27%.Yet,the presence of enormous defects,mainly for the dominant iodine vacancy(VI),always induces nonradiative recombination,ion migration,and triggers autocatalytic iodine oxidation into volatile I_(2) and charge-localization-mediated metallic Pb0clusters,which accelerate device failure and therefore hamper commercialization.However,popularly reported strategies that simultaneously enable vacancy passivation and iodine scavenging remain insufficient,highlighting the need for new additives.Herein,we employ 4-cyanophenylhydrazine hydrochloride(CPHCl)as an iodine-related synergistic redox-coordination stabilizer to address intrinsic instability and interface chemistry issues.After systematically characterizations,we demonstrate that CPHCl not only specifically eliminates I_(2) intermediates by leveraging the redox-active hydrazine group(NH–NH_(2))(I_(2)+NH–NH_(2)→2HI+N=NH),but also passivates Pb^(2+)/FA^(+) related defects viaπ-backdonation and hydrogen bonding by the electron-donating cyano(C≡N)group,synergistically modulating the crystallization kinetics and improving the final quality of the perovskite film.As a result,vacancy-mediated I-ion migration and degradation are significantly relieved,enabling an enhanced efficiency of 25.56%for the p-i-n inverted PSC with exceptional operational stability.This work provides a deep insight into screening perovskite stabilizers for advancing toward commercial longevity.展开更多
This study evaluates the stabilizing effect of lignin, extracted from Eucalyptus globulus, on an energetic composite of nitrated cellulose carbamate (NCC) plasticized with diethylene glycol dinitrate (DEGDN), compared...This study evaluates the stabilizing effect of lignin, extracted from Eucalyptus globulus, on an energetic composite of nitrated cellulose carbamate (NCC) plasticized with diethylene glycol dinitrate (DEGDN), compared to conventional stabilizers 2-nitrodiphenylamine (2-NDPA) and 1,3-dimethyl-1,3-diphenylurea (C-II). FTIR analysis confirms lignin's capacity to scavenge nitroxyl radicals formed during thermolysis of nitrocarbamate and nitrate ester bonds, thereby inhibiting decomposition. Moreover, the incorporation of C-II, 2-NDPA, and lignin significantly raised the peak temperature of the main thermolysis, as confirmed by DSC and TGA, indicating a progressive stability enhancement in the order: NCC/DEGDN < NCC/DEGDN/C-II < NCC/DEGDN/lignin < NCC/DEGDN/2-NDPA. Additionally, the effect of each stabilizer on the decomposition pathway was characterized by TGA-FTIR. The findings show that stabilizer type significantly affects the intensity of gaseous products released during decomposition without altering their nature. Notably, NH2 groups formed during NCC degradation play a key role in nitrogen conversion, particularly by reducing toxic NO emissions.展开更多
The application of poly(butylene adipate-co-terephthalate)(PBAT)biodegradable plastics has long been constrained by insufficient light aging resistance.Hindered amine light stabilizers(HALSs),known as eco-friendly add...The application of poly(butylene adipate-co-terephthalate)(PBAT)biodegradable plastics has long been constrained by insufficient light aging resistance.Hindered amine light stabilizers(HALSs),known as eco-friendly additives,can scavenge free radicals to enhance polymer durability.However,rough choices have resulted in wastage of resources and environmental pressure.Based on the application of plastic films as the background for use,this study systematically evaluates application effects of five HALSs.The films underwent accelerated aging for various durations and were further investigated by a combination of experiments and molecular simulation.Results showed that all HALSs mitigated PBAT light aging,with Chimassorb-944(UV-944)and Tinuvin-770(UV-770)performing the best for real applications.Quantum chemical calculation results showed that UV-944 had stronger anti migration ability.After 300 h of aging,films with UV-944 and UV-770 retained superior tensile strength and elongation at break in the transverse direction compared to neat PBAT films.Polymeric HALSs provided better long-term stability than small-molecule ones.Further spectra analysis indicated that stronger C―O bonds in HALS/PBAT composites correlated with improved photostability.This study offers valuable insights into improving weather resistance of PBAT biodegradable films and optimizing the real application of HALSs.展开更多
This study investigates the use of a low-carbon soil stabilizer called SDG,which is made up of granulated blast furnace slag (GGBFS),desulfurization gypsum (DG),and calcium carbide slag (CCS),to solidify the soil.The ...This study investigates the use of a low-carbon soil stabilizer called SDG,which is made up of granulated blast furnace slag (GGBFS),desulfurization gypsum (DG),and calcium carbide slag (CCS),to solidify the soil.The impact of SDG components on the strength and durability of solidified soil was analysed through a series of tests,including unconfined compressive strength,water stability coefficient,water absorption rate,drying-wetting cycles,and shrinkage tests.Furthermore,microstructure characteristics were analysed using X-ray diffraction (XRD) and scanning electron microscopy (SEM).The study shows that the solidified soil has excellent strength and durability when the SDG stabilizer contains 60% GGBGS,10% DG,and 30% CCS.Additionally,increasing the DG content negatively affects the soil's resistance to water.The SDG stabilizer has potential chemical cementitious characteristics and the calcium carbide slag is rich in calcium ions,which undergo an ion exchange reaction with minerals in the soil.These findings offer new ideas for the development of soil stabilizers.展开更多
Purpose: There have been many studies on the effects of different types of backpacks on posture from a biomechanical perspective and on the center of gravity. Considering the effects of autonomic nervous system activi...Purpose: There have been many studies on the effects of different types of backpacks on posture from a biomechanical perspective and on the center of gravity. Considering the effects of autonomic nervous system activity and mood associated with backpacks in mountaineering and hiking, research is also needed from a psychological perspective. In this study, the effects of adjusting the backpack shoulder stabilizer were preliminarily tested in terms of subjective fatigue and changes in autonomic nervous activity after hiking. Methods: The experimental 15 healthy participants hiked the mountain under two conditions: 1) without adjusting the stabilizer, a feature of the backpack (NAH condition), and 2) with the stabilizer adjusted (AH condition). First, all participants hiked the mountain in the NAH condition, and after a 30-minute break, they began the hike in the AH condition after confirming that a) their heart rate had recovered and b) they were in good physical condition. Results: HR was significantly lower after each hiking session than during the session. RMSSD was significantly lower pre-AH and post-AH than the NAH condition, but there was no significant difference between the NAH condition and either post-NAH or post-AH. Additionally, RMSSD was significantly lower in the AH condition than pre-AH or post-AH. The shoulders and back were significantly more burdened in the NAH condition than in the AH condition. The pleasure level was significantly higher in the AH condition than in the NAH condition. Conclusion: The results showed that also adjusting the position of the waist belt when adjusting the shoulder stabilizer, which is mainly used for the neck and shoulders, has a significant positive effect on the subjective burden on the upper body and parasympathetic nervous system activity after hiking.展开更多
Oil-based drilling fluids possess excellent properties such as shale inhibition, cuttings suspension, and superior lubrication, making them essential in the development of unconventional oil and gas reservoirs.However...Oil-based drilling fluids possess excellent properties such as shale inhibition, cuttings suspension, and superior lubrication, making them essential in the development of unconventional oil and gas reservoirs.However, wellbore instability, caused by the invasion of drilling fluids into shale formations, remains a significant challenge for the safe and efficient extraction of shale oil and gas. This work reports the preparation of mesoporous SiO2nanoparticles with low surface energy, utilized as multifunctional agents to enhance the performance of oil-based drilling fluids aimed at improving wellbore stability. The results indicate that the coating prepared from these nanoparticles exhibit excellent hydrophobicity and antifouling properties, increasing the water contact angle from 32°to 146°and oil contact angle from 24°to134.8°. Additionally, these nanoparticles exhibit exceptional chemical stability and thermal resistance.Incorporating these nanoparticles into oil-based drilling fluids reduced the surface energy of the mud cake from 34.99 to 8.17 m J·m-2and increased the roughness of shale from 0.26 to 2.39 μm. These modifications rendered the mud cake and shale surfaces amphiphobic, effectively mitigating capillary infiltration and delaying the long-term strength degradation of shale in oil-based drilling fluids. After 28days of immersion in oil-based drilling fluid, shale cores treated with MF-SiO2exhibited a 30.5% increase in compressive strength compared to untreated cores. Additionally, these nanoparticles demonstrated the ability to penetrate and seal rock pores, reducing the API filtration volume of the drilling fluid from11.2 to 7.6 m L. This study introduces a novel approach to enhance the development of shale gas and oil resources, offering a promising strategy for wellbore stabilization in oil-based drilling fluid systems.展开更多
In order to solve the drifting away of thermal fog droplets during thermal spraying and the incompatibility between fog droplet carrier and conventional com- mercial agro-chemicals, the fog droplet carrier, surfactant...In order to solve the drifting away of thermal fog droplets during thermal spraying and the incompatibility between fog droplet carrier and conventional com- mercial agro-chemicals, the fog droplet carrier, surfactant, condensation nucleus ma- terial and antifreeze, dispersant, thickener and defoamer were screened and assem- bled to develop a thermal fog sedimentation stabilizer in this study, thereby provid- ing technical support for application and promotion of thermal spraying technology in pest and disease control in crops.展开更多
The synergistic stabilization effect of different metal lanolin fatty acids as natural-based thermal stabilizers for poly（vinyl chloride） （PVC） including calcium lanolin fatty acid （Calan2）,zinc lanolin fatty ac...The synergistic stabilization effect of different metal lanolin fatty acids as natural-based thermal stabilizers for poly（vinyl chloride） （PVC） including calcium lanolin fatty acid （Calan2）,zinc lanolin fatty acid （Znlan2） and lanthanum lanolin fatty acid （Lalan3） were studied through Congo red testing,color measurements,FTIR analyses and thermal behavior in this paper. The results showed that Lalan3/Calan2/Znlan2 stabilizers exhibited more excellent thermal stabilization efficiency to PVC than Calan2/Znlan2 thermal stabilizers,and the optimal mass ratio of Lalan3/Calan2/Znlan2 was 8：9：3. At last,the effect of degradation mechanism on PVC and synergistic stabilization was also investigated by FTIR analyses and thermal behavior.展开更多
Over 2 x 10(8) tons of polymers are produced every year, and a large portion of polymers faces the degradation problem. There are many effective methods to protect polymers against degradation and the addition of stab...Over 2 x 10(8) tons of polymers are produced every year, and a large portion of polymers faces the degradation problem. There are many effective methods to protect polymers against degradation and the addition of stabilizers to polymer remains the most convenient and effective way of enhancing polymer life and performance. In this article, a series of effective stabilizers with optimal molecular weight (MW), including common, monomeric and polymeric stabilizers (antioxidant and light stabilizer) were synthesized using isocyanation, controlled isocyanation, hydrosilylation, epoxide addition, macroreaction of stabilizing functional compounds and polymerization of monomeric stabilizers. The structure and performance of these new stabilizers were characterized by using IR, NMR, MS, UV-spectra, XPS and elemental analysis. The current development of stabilizer synthesis was also reviewed.展开更多
The research analyzed characters of soil stabilizer and detailed the solidification mechanism.Furthermore,new type soil stabilizer Q2 was used in a base of Beijing Vocational College of Agriculture and a solidified ro...The research analyzed characters of soil stabilizer and detailed the solidification mechanism.Furthermore,new type soil stabilizer Q2 was used in a base of Beijing Vocational College of Agriculture and a solidified road with length of 250 m,width of 4 m and thickness of 0.25 m were constructed.The road was tested with an agricultural truck and subgrade tolerance to freezing was tested also.It is suggested that new type soil stabilizer would reduce construction cost of road,protect environment,and reduce construction period,with high value of application.展开更多
A novel technique for the optimal tuning of power system stabilizer (PSS) was proposed,by integrating the modified particle swarm optimization (MPSO) with the chaos (MPSOC).Firstly,a modification in the particle swarm...A novel technique for the optimal tuning of power system stabilizer (PSS) was proposed,by integrating the modified particle swarm optimization (MPSO) with the chaos (MPSOC).Firstly,a modification in the particle swarm optimization (PSO) was made by introducing passive congregation (PC).It helps each swarm member in receiving a multitude of information from other members and thus decreases the possibility of a failed attempt at detection or a meaningless search.Secondly,the MPSO and chaos were hybridized (MPSOC) to improve the global searching capability and prevent the premature convergence due to local minima.The robustness of the proposed PSS tuning technique was verified on a multi-machine power system under different operating conditions.The performance of the proposed MPSOC was compared to the MPSO,PSO and GA through eigenvalue analysis,nonlinear time-domain simulation and statistical tests.Eigenvalue analysis shows acceptable damping of the low-frequency modes and time domain simulations also show that the oscillations of synchronous machines can be rapidly damped for power systems with the proposed PSSs.The results show that the presented algorithm has a faster convergence rate with higher degree of accuracy than the GA,PSO and MPSO.展开更多
The change in the thickness of water films of special clay particles such as sliding clay, red clay, and expansive clay is an important factor in producing geological disasters and geological environmental damage. In ...The change in the thickness of water films of special clay particles such as sliding clay, red clay, and expansive clay is an important factor in producing geological disasters and geological environmental damage. In order to reduce the thickness of water films, ionic soil stabilizer （ISS） is used to treat sliding clay, red clay, and expansive clay. Direct shear test of sliding clay and shrinkage, free swell rate, zeta potential, and cation-exchange capacity of red clay and expansive clay are carried out. The results show that as the plastic indexes of special clay soil decrease, the shear strength of sliding clay increases, the shrinkage and free swell rate of red clay and expansive clay decrease, and the thickness of the water film thins after treatment with the ionic soil stabilizer. Therefore, the geological engineering disasters caused by changes in the thickness of water films of special clay can be effectively inhibited.展开更多
A stabilized soil structure formation model was introduced. In order to form compact stabilized soil structure, cementitious hydrates were needed to wrap and bind the soil aggregates. Meanwhile, expansible hydrates we...A stabilized soil structure formation model was introduced. In order to form compact stabilized soil structure, cementitious hydrates were needed to wrap and bind the soil aggregates. Meanwhile, expansible hydrates were needed to squeeze and fill the pores, especially the pores in the aggregates. The experimental results show that the influences of various chemical characteristic factors of soil on the strength of the stabilized soil are boiled down, for the influence on the concentration of Ca（OH）2 in the pore solution of the stabilized soil, and the amount of CSH generated by cement. Finally an optimization design method is proposed, with which the stabilizer can be designed according to characteristics of soil samples.展开更多
Rare earth compounds can be used as PVC thermal stabilizers. According to the infrared spectra of the mixture of PVC and some stearates, the mechanism of stabilization of different stearates was studied. The specialty...Rare earth compounds can be used as PVC thermal stabilizers. According to the infrared spectra of the mixture of PVC and some stearates, the mechanism of stabilization of different stearates was studied. The specialty of rare earth stabilizers was found. They can change the conformation of PVC and restrain the elimination of HCl. From this aspect, the unique synergetic effect with other stabilizers of rare earth compounds can be explained.展开更多
The objective of this work is to construct a nanosuspension drug delivery system of probucol,a BCS II drug,in order to improve its dissolution and oral bioavailability.The wet milling procedure using planetary beads-m...The objective of this work is to construct a nanosuspension drug delivery system of probucol,a BCS II drug,in order to improve its dissolution and oral bioavailability.The wet milling procedure using planetary beads-milling equipment was utilized to grind the raw probucol to ultrafine nanoparticle/nanocrystal aqueous suspension that was further solidified by freeze-drying process.Cellulose derivatives of different substitution groups and molecular weights,including HPMC,HPC,and MC,were evaluated as the primary stabilizer of probucol nanosuspension.Ternary stabilizers system composed of a primary stabilizer(cellulose derivative,i.e.HPC),a nonionic surfactant(Pluronic R F68),and an anionic surfactant(SDS)was employed to obtain probucol nanosuspension of finer particle size and enhanced dissolution in aqueous media.The probucol nanosuspension with good physical stability showed no obvious change of particle size even after storing over 7 d at 4°C or 25°C.The solidified probucol nanosuspension with trehalose as the cryoprotectant showed the highest dissolution rate(>60%at 2 h)compared to other cryoprotectant.The in vivo pharmacokinetic evaluation indicated about 15-folds higher AUC value of the probucol nanosuspension compared to that of coarse probucol suspension after oral administration to rats.The probucol nanosuspension prepared by wet-milling and ternary stabilizers system may find wide applications for improving the dissolution and oral absorption of water-insoluble drugs.展开更多
Geophysical inversion under different stabilizers has different descriptions of the target body boundary,especially in complex geological structures.In this paper,we present an extremum boundary inversion algorithm ba...Geophysical inversion under different stabilizers has different descriptions of the target body boundary,especially in complex geological structures.In this paper,we present an extremum boundary inversion algorithm based on different stabilizers for electrical interface recognition.Firstly,we use the smoothest and minimum-support stabilizing functional to study the applicability of adaptive regularization inversion algorithm.Then,an electrical interface recognition method based on different stabilizers is developed by introducing extremum boundary inversion algorithm.The testing shows that the adaptive regularization inversion method does work for different stabilizers and has a low dependence on the initial models.The ratio of the smooth and focusing upper and lower boundaries obtained using the extremum boundary inversion algorithm can clearly demarcate electrical interfaces.We apply the inversion algorithm to the magnetotelluric(MT)data collected from a preselected area of a high-level-waste clay-rock repository site in the Tamusu area.We recognized regional structures with smooth inversion and the local details with focusing inversion and determined the thickness of the target layer combined with the geological and drilling information,which meets the requirement for the site of the high-level waste clay-rock repository.展开更多
The vibration characteristics of composite vertical stabilizer skin structures play a critical role in damping effects designed for overcoming the air disturbances experienced by aircraft structural components during ...The vibration characteristics of composite vertical stabilizer skin structures play a critical role in damping effects designed for overcoming the air disturbances experienced by aircraft structural components during flight.The first-order fundamental frequencies and their corresponding damping characteristics of the vertical stabilizer skin structure tow-steered by automatic fiber placement technique were optimized with the parameterized trajectories and plies as design variables.Firstly,the vibration and damping numerical models were derived based on Kirchhoff laminate theory,the Rayleigh-Ritz method,and the Strain Energy Method.Then the optimization model was developed by adopting the self-adaptive Differential Evolution Multi-objective optimization algorithm and incorporating the solution method of Pareto Front.The constraints of this optimization model considered the experimentally obtained minimum turning radius of prepregs tow-steered in automatic fiber placement process obtained from experimental tests.Finally,the comparison of numerical simulation results was conducted for the optimized trajectories and the conventional straight trajectories under various boundary conditions,and the numerical results were partially validated through damping and frequency tests.The results indicate the vibration characteristics of the composite vertical stabilizer skin structure can be enhanced to a large extent by optimizing fiber trajectories,and the enhancement percentage is affected by the boundary conditions of the actual structure.展开更多
The ZrO2-Al2O3 ceramic composites were prepared by appropriate techniques with commercial ZrO2 and Al2O3 powders as raw materials and Y2O3 as stabilizer. The results indicate that with the introduction of Al2O3 into t...The ZrO2-Al2O3 ceramic composites were prepared by appropriate techniques with commercial ZrO2 and Al2O3 powders as raw materials and Y2O3 as stabilizer. The results indicate that with the introduction of Al2O3 into the ZrO2 matrix where the quantity of additive Y2O3 is 3.5% (mole fraction), the growth of ZrO2 grains is efficiently inhibited, which helps the ZrO2 grains exist in a metastable tetragonal manner; thus higher strength and toughness are acquired. When the content of alumina is 20% (mass fraction), the bending strength and fracture toughness of the composites are 676.7 MPa and 10 MPa·m1/2 respectively, the mechanical behaviors are close to those prepared with ZrO2 and Al2O3 powders synthesized through wet chemical approach. The mechanical behaviors of the composites are well improved owing to the dispersion toughening of alumina grains and phase transformation toughening of zirconia grains.展开更多
Power system stability is enhanced through a novel stabilizer developed around an adaptive fuzzy sliding mode approach which applies the Nussbaum gain to a nonlinear model of a single-machine infinite-bus （SMIB） and...Power system stability is enhanced through a novel stabilizer developed around an adaptive fuzzy sliding mode approach which applies the Nussbaum gain to a nonlinear model of a single-machine infinite-bus （SMIB） and multi-machine power system stabilizer subjected to a three phase fault. The Nussbaum gain is used to avoid the positive sign constraint and the problem of controllability of the system. A comparative simulation study is presented to evaluate the achieved performance.展开更多
Knowing methane desorption characteristics is essential to define the contribution of adsorbed gas to gas well production.To evaluate the synthetic effect of a clay stabilizer solution on methane desorption kinetics a...Knowing methane desorption characteristics is essential to define the contribution of adsorbed gas to gas well production.To evaluate the synthetic effect of a clay stabilizer solution on methane desorption kinetics and isotherms pertaining to Longmaxi shale,an experimental setup was designed based on the volumetric method.The objective was to conduct experiments on methane adsorption and desorption kinetics and isotherms before and after clay stabilizer treatments.The experimental data were a good fit for both the intraparticle diffusion model and the Freundlich isotherm model.We analyzed the effect of the clay stabilizer on desorption kinetics and isotherms.Results show that clay stabilizer can obviously improve the diffusion rate constant and reduce the methane adsorption amount.Moreover,we analyzed the desorption efficiency before and after treatment as well as the adsorbed methane content.The results show that a higher desorption efficiency after treatment can be observed when the pressure is higher than 6.84 MPa.Meanwhile,the adsorbed methane content before and after treatment all increase when the pressure decreases,and clay stabilizer can obviously promote the adsorbed methane to free gas when the pressure is lower than 19 MPa.This can also be applied to the optimization formulation of slickwater and the design of gas well production.展开更多
基金partly funded by the National Natural Science Foundation of China(62204098,62304124,62374105,22309107)Natural Science Foundation of Shandong Province(ZR2024QE036,ZR2024QB021,ZR2023QB281)+1 种基金Special Fund of Taishan Scholar Program of Shandong Province(tsqnz20221141)Qingdao Natural Science Foundation(24-4-4-zrjj-21-jch,25-1-1-114-zyydjch)。
文摘As one photovoltaic supernova,perovskite solar cells(PSCs)have exhibited certified power conversion efficiencies exceeding 27%.Yet,the presence of enormous defects,mainly for the dominant iodine vacancy(VI),always induces nonradiative recombination,ion migration,and triggers autocatalytic iodine oxidation into volatile I_(2) and charge-localization-mediated metallic Pb0clusters,which accelerate device failure and therefore hamper commercialization.However,popularly reported strategies that simultaneously enable vacancy passivation and iodine scavenging remain insufficient,highlighting the need for new additives.Herein,we employ 4-cyanophenylhydrazine hydrochloride(CPHCl)as an iodine-related synergistic redox-coordination stabilizer to address intrinsic instability and interface chemistry issues.After systematically characterizations,we demonstrate that CPHCl not only specifically eliminates I_(2) intermediates by leveraging the redox-active hydrazine group(NH–NH_(2))(I_(2)+NH–NH_(2)→2HI+N=NH),but also passivates Pb^(2+)/FA^(+) related defects viaπ-backdonation and hydrogen bonding by the electron-donating cyano(C≡N)group,synergistically modulating the crystallization kinetics and improving the final quality of the perovskite film.As a result,vacancy-mediated I-ion migration and degradation are significantly relieved,enabling an enhanced efficiency of 25.56%for the p-i-n inverted PSC with exceptional operational stability.This work provides a deep insight into screening perovskite stabilizers for advancing toward commercial longevity.
文摘This study evaluates the stabilizing effect of lignin, extracted from Eucalyptus globulus, on an energetic composite of nitrated cellulose carbamate (NCC) plasticized with diethylene glycol dinitrate (DEGDN), compared to conventional stabilizers 2-nitrodiphenylamine (2-NDPA) and 1,3-dimethyl-1,3-diphenylurea (C-II). FTIR analysis confirms lignin's capacity to scavenge nitroxyl radicals formed during thermolysis of nitrocarbamate and nitrate ester bonds, thereby inhibiting decomposition. Moreover, the incorporation of C-II, 2-NDPA, and lignin significantly raised the peak temperature of the main thermolysis, as confirmed by DSC and TGA, indicating a progressive stability enhancement in the order: NCC/DEGDN < NCC/DEGDN/C-II < NCC/DEGDN/lignin < NCC/DEGDN/2-NDPA. Additionally, the effect of each stabilizer on the decomposition pathway was characterized by TGA-FTIR. The findings show that stabilizer type significantly affects the intensity of gaseous products released during decomposition without altering their nature. Notably, NH2 groups formed during NCC degradation play a key role in nitrogen conversion, particularly by reducing toxic NO emissions.
基金supported by the Key Research and Development Task Project of Xinjiang Uygur Autonomous Region(No.2022B02033)the National Natural Science Foundation of China(Nos.42211530566 and 42311530066)+2 种基金the NSFC-FNRS Joint Program BIOAGRIFILM(No.FNRS PINT-BILATM 2022)the Science and Technology Project of Bijie Tobacco Company of Guizhou Province(No.2022520500240192)the Agricultural Science and Technology Innovation Program(ASTIP)。
文摘The application of poly(butylene adipate-co-terephthalate)(PBAT)biodegradable plastics has long been constrained by insufficient light aging resistance.Hindered amine light stabilizers(HALSs),known as eco-friendly additives,can scavenge free radicals to enhance polymer durability.However,rough choices have resulted in wastage of resources and environmental pressure.Based on the application of plastic films as the background for use,this study systematically evaluates application effects of five HALSs.The films underwent accelerated aging for various durations and were further investigated by a combination of experiments and molecular simulation.Results showed that all HALSs mitigated PBAT light aging,with Chimassorb-944(UV-944)and Tinuvin-770(UV-770)performing the best for real applications.Quantum chemical calculation results showed that UV-944 had stronger anti migration ability.After 300 h of aging,films with UV-944 and UV-770 retained superior tensile strength and elongation at break in the transverse direction compared to neat PBAT films.Polymeric HALSs provided better long-term stability than small-molecule ones.Further spectra analysis indicated that stronger C―O bonds in HALS/PBAT composites correlated with improved photostability.This study offers valuable insights into improving weather resistance of PBAT biodegradable films and optimizing the real application of HALSs.
基金Funded by the National Key R&D Program of China (No. 2022YFC3803405)the China State Construction Key Laboratory Project (No. ZJXJ-PT-2022-14)。
文摘This study investigates the use of a low-carbon soil stabilizer called SDG,which is made up of granulated blast furnace slag (GGBFS),desulfurization gypsum (DG),and calcium carbide slag (CCS),to solidify the soil.The impact of SDG components on the strength and durability of solidified soil was analysed through a series of tests,including unconfined compressive strength,water stability coefficient,water absorption rate,drying-wetting cycles,and shrinkage tests.Furthermore,microstructure characteristics were analysed using X-ray diffraction (XRD) and scanning electron microscopy (SEM).The study shows that the solidified soil has excellent strength and durability when the SDG stabilizer contains 60% GGBGS,10% DG,and 30% CCS.Additionally,increasing the DG content negatively affects the soil's resistance to water.The SDG stabilizer has potential chemical cementitious characteristics and the calcium carbide slag is rich in calcium ions,which undergo an ion exchange reaction with minerals in the soil.These findings offer new ideas for the development of soil stabilizers.
文摘Purpose: There have been many studies on the effects of different types of backpacks on posture from a biomechanical perspective and on the center of gravity. Considering the effects of autonomic nervous system activity and mood associated with backpacks in mountaineering and hiking, research is also needed from a psychological perspective. In this study, the effects of adjusting the backpack shoulder stabilizer were preliminarily tested in terms of subjective fatigue and changes in autonomic nervous activity after hiking. Methods: The experimental 15 healthy participants hiked the mountain under two conditions: 1) without adjusting the stabilizer, a feature of the backpack (NAH condition), and 2) with the stabilizer adjusted (AH condition). First, all participants hiked the mountain in the NAH condition, and after a 30-minute break, they began the hike in the AH condition after confirming that a) their heart rate had recovered and b) they were in good physical condition. Results: HR was significantly lower after each hiking session than during the session. RMSSD was significantly lower pre-AH and post-AH than the NAH condition, but there was no significant difference between the NAH condition and either post-NAH or post-AH. Additionally, RMSSD was significantly lower in the AH condition than pre-AH or post-AH. The shoulders and back were significantly more burdened in the NAH condition than in the AH condition. The pleasure level was significantly higher in the AH condition than in the NAH condition. Conclusion: The results showed that also adjusting the position of the waist belt when adjusting the shoulder stabilizer, which is mainly used for the neck and shoulders, has a significant positive effect on the subjective burden on the upper body and parasympathetic nervous system activity after hiking.
基金support from the National Natural:Science Foundation of China(NO.52174014)the National Natural Science Foundation Basic Science Center(NO.52288101).
文摘Oil-based drilling fluids possess excellent properties such as shale inhibition, cuttings suspension, and superior lubrication, making them essential in the development of unconventional oil and gas reservoirs.However, wellbore instability, caused by the invasion of drilling fluids into shale formations, remains a significant challenge for the safe and efficient extraction of shale oil and gas. This work reports the preparation of mesoporous SiO2nanoparticles with low surface energy, utilized as multifunctional agents to enhance the performance of oil-based drilling fluids aimed at improving wellbore stability. The results indicate that the coating prepared from these nanoparticles exhibit excellent hydrophobicity and antifouling properties, increasing the water contact angle from 32°to 146°and oil contact angle from 24°to134.8°. Additionally, these nanoparticles exhibit exceptional chemical stability and thermal resistance.Incorporating these nanoparticles into oil-based drilling fluids reduced the surface energy of the mud cake from 34.99 to 8.17 m J·m-2and increased the roughness of shale from 0.26 to 2.39 μm. These modifications rendered the mud cake and shale surfaces amphiphobic, effectively mitigating capillary infiltration and delaying the long-term strength degradation of shale in oil-based drilling fluids. After 28days of immersion in oil-based drilling fluid, shale cores treated with MF-SiO2exhibited a 30.5% increase in compressive strength compared to untreated cores. Additionally, these nanoparticles demonstrated the ability to penetrate and seal rock pores, reducing the API filtration volume of the drilling fluid from11.2 to 7.6 m L. This study introduces a novel approach to enhance the development of shale gas and oil resources, offering a promising strategy for wellbore stabilization in oil-based drilling fluid systems.
基金Supported by Anhui Agricultural Science and Technology Innovation Fund(16A1132)Science and Technology Major Project of Anhui Province(15CZZ03132)Special Fund for Talent Development in Anhui Province(13C1109)~~
文摘In order to solve the drifting away of thermal fog droplets during thermal spraying and the incompatibility between fog droplet carrier and conventional com- mercial agro-chemicals, the fog droplet carrier, surfactant, condensation nucleus ma- terial and antifreeze, dispersant, thickener and defoamer were screened and assem- bled to develop a thermal fog sedimentation stabilizer in this study, thereby provid- ing technical support for application and promotion of thermal spraying technology in pest and disease control in crops.
基金Project supported by the Natural Science Foundation of Fujian Province (2007HZ0001-2)
文摘The synergistic stabilization effect of different metal lanolin fatty acids as natural-based thermal stabilizers for poly（vinyl chloride） （PVC） including calcium lanolin fatty acid （Calan2）,zinc lanolin fatty acid （Znlan2） and lanthanum lanolin fatty acid （Lalan3） were studied through Congo red testing,color measurements,FTIR analyses and thermal behavior in this paper. The results showed that Lalan3/Calan2/Znlan2 stabilizers exhibited more excellent thermal stabilization efficiency to PVC than Calan2/Znlan2 thermal stabilizers,and the optimal mass ratio of Lalan3/Calan2/Znlan2 was 8：9：3. At last,the effect of degradation mechanism on PVC and synergistic stabilization was also investigated by FTIR analyses and thermal behavior.
基金The work cited in this review was supported by the National Natural Science Foundation of China (No, 928700801 and No 2880201)
文摘Over 2 x 10(8) tons of polymers are produced every year, and a large portion of polymers faces the degradation problem. There are many effective methods to protect polymers against degradation and the addition of stabilizers to polymer remains the most convenient and effective way of enhancing polymer life and performance. In this article, a series of effective stabilizers with optimal molecular weight (MW), including common, monomeric and polymeric stabilizers (antioxidant and light stabilizer) were synthesized using isocyanation, controlled isocyanation, hydrosilylation, epoxide addition, macroreaction of stabilizing functional compounds and polymerization of monomeric stabilizers. The structure and performance of these new stabilizers were characterized by using IR, NMR, MS, UV-spectra, XPS and elemental analysis. The current development of stabilizer synthesis was also reviewed.
基金Beijing Agricultural Science and Technology Project(2013011202)~~
文摘The research analyzed characters of soil stabilizer and detailed the solidification mechanism.Furthermore,new type soil stabilizer Q2 was used in a base of Beijing Vocational College of Agriculture and a solidified road with length of 250 m,width of 4 m and thickness of 0.25 m were constructed.The road was tested with an agricultural truck and subgrade tolerance to freezing was tested also.It is suggested that new type soil stabilizer would reduce construction cost of road,protect environment,and reduce construction period,with high value of application.
文摘A novel technique for the optimal tuning of power system stabilizer (PSS) was proposed,by integrating the modified particle swarm optimization (MPSO) with the chaos (MPSOC).Firstly,a modification in the particle swarm optimization (PSO) was made by introducing passive congregation (PC).It helps each swarm member in receiving a multitude of information from other members and thus decreases the possibility of a failed attempt at detection or a meaningless search.Secondly,the MPSO and chaos were hybridized (MPSOC) to improve the global searching capability and prevent the premature convergence due to local minima.The robustness of the proposed PSS tuning technique was verified on a multi-machine power system under different operating conditions.The performance of the proposed MPSOC was compared to the MPSO,PSO and GA through eigenvalue analysis,nonlinear time-domain simulation and statistical tests.Eigenvalue analysis shows acceptable damping of the low-frequency modes and time domain simulations also show that the oscillations of synchronous machines can be rapidly damped for power systems with the proposed PSSs.The results show that the presented algorithm has a faster convergence rate with higher degree of accuracy than the GA,PSO and MPSO.
基金supported by the National Natural Science Foundation of China (Nos. 40972185, 41002102)Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 200804910504)
文摘The change in the thickness of water films of special clay particles such as sliding clay, red clay, and expansive clay is an important factor in producing geological disasters and geological environmental damage. In order to reduce the thickness of water films, ionic soil stabilizer （ISS） is used to treat sliding clay, red clay, and expansive clay. Direct shear test of sliding clay and shrinkage, free swell rate, zeta potential, and cation-exchange capacity of red clay and expansive clay are carried out. The results show that as the plastic indexes of special clay soil decrease, the shear strength of sliding clay increases, the shrinkage and free swell rate of red clay and expansive clay decrease, and the thickness of the water film thins after treatment with the ionic soil stabilizer. Therefore, the geological engineering disasters caused by changes in the thickness of water films of special clay can be effectively inhibited.
基金Funded by the National Natural Science Foundation of China(No. 50278007)
文摘A stabilized soil structure formation model was introduced. In order to form compact stabilized soil structure, cementitious hydrates were needed to wrap and bind the soil aggregates. Meanwhile, expansible hydrates were needed to squeeze and fill the pores, especially the pores in the aggregates. The experimental results show that the influences of various chemical characteristic factors of soil on the strength of the stabilized soil are boiled down, for the influence on the concentration of Ca（OH）2 in the pore solution of the stabilized soil, and the amount of CSH generated by cement. Finally an optimization design method is proposed, with which the stabilizer can be designed according to characteristics of soil samples.
文摘Rare earth compounds can be used as PVC thermal stabilizers. According to the infrared spectra of the mixture of PVC and some stearates, the mechanism of stabilization of different stearates was studied. The specialty of rare earth stabilizers was found. They can change the conformation of PVC and restrain the elimination of HCl. From this aspect, the unique synergetic effect with other stabilizers of rare earth compounds can be explained.
基金financial support from the National Basic Research Program of China(973 Program,No.2009CB930300)
文摘The objective of this work is to construct a nanosuspension drug delivery system of probucol,a BCS II drug,in order to improve its dissolution and oral bioavailability.The wet milling procedure using planetary beads-milling equipment was utilized to grind the raw probucol to ultrafine nanoparticle/nanocrystal aqueous suspension that was further solidified by freeze-drying process.Cellulose derivatives of different substitution groups and molecular weights,including HPMC,HPC,and MC,were evaluated as the primary stabilizer of probucol nanosuspension.Ternary stabilizers system composed of a primary stabilizer(cellulose derivative,i.e.HPC),a nonionic surfactant(Pluronic R F68),and an anionic surfactant(SDS)was employed to obtain probucol nanosuspension of finer particle size and enhanced dissolution in aqueous media.The probucol nanosuspension with good physical stability showed no obvious change of particle size even after storing over 7 d at 4°C or 25°C.The solidified probucol nanosuspension with trehalose as the cryoprotectant showed the highest dissolution rate(>60%at 2 h)compared to other cryoprotectant.The in vivo pharmacokinetic evaluation indicated about 15-folds higher AUC value of the probucol nanosuspension compared to that of coarse probucol suspension after oral administration to rats.The probucol nanosuspension prepared by wet-milling and ternary stabilizers system may find wide applications for improving the dissolution and oral absorption of water-insoluble drugs.
基金supported by the National Natural Science Foundation of China(Nos.41604104,41674077 and 41404057)PRC High-level Radioactive Waste Geological Disposal Project([2014] No.1578)+2 种基金Open Fund of State Key Laboratory of Marine Geology(Tongji University)(MGK1704)Jiangxi Province Youth Science Fund(No.20171BAB213031)Scientific Research Starting Foundation for Doctors of East China University of Technology(DHBK201403)
文摘Geophysical inversion under different stabilizers has different descriptions of the target body boundary,especially in complex geological structures.In this paper,we present an extremum boundary inversion algorithm based on different stabilizers for electrical interface recognition.Firstly,we use the smoothest and minimum-support stabilizing functional to study the applicability of adaptive regularization inversion algorithm.Then,an electrical interface recognition method based on different stabilizers is developed by introducing extremum boundary inversion algorithm.The testing shows that the adaptive regularization inversion method does work for different stabilizers and has a low dependence on the initial models.The ratio of the smooth and focusing upper and lower boundaries obtained using the extremum boundary inversion algorithm can clearly demarcate electrical interfaces.We apply the inversion algorithm to the magnetotelluric(MT)data collected from a preselected area of a high-level-waste clay-rock repository site in the Tamusu area.We recognized regional structures with smooth inversion and the local details with focusing inversion and determined the thickness of the target layer combined with the geological and drilling information,which meets the requirement for the site of the high-level waste clay-rock repository.
基金co-supported by the National Natural Science Foundation of China(Nos.51875159,52175311,52175133,12102115,52005446)the Fok Ying Tung Education Foundation,China(No.171046)the Fundamental Research Funds for the Central Universities,China(Nos.JZ2021HGTA0178,JZ2020HGQA0197)。
文摘The vibration characteristics of composite vertical stabilizer skin structures play a critical role in damping effects designed for overcoming the air disturbances experienced by aircraft structural components during flight.The first-order fundamental frequencies and their corresponding damping characteristics of the vertical stabilizer skin structure tow-steered by automatic fiber placement technique were optimized with the parameterized trajectories and plies as design variables.Firstly,the vibration and damping numerical models were derived based on Kirchhoff laminate theory,the Rayleigh-Ritz method,and the Strain Energy Method.Then the optimization model was developed by adopting the self-adaptive Differential Evolution Multi-objective optimization algorithm and incorporating the solution method of Pareto Front.The constraints of this optimization model considered the experimentally obtained minimum turning radius of prepregs tow-steered in automatic fiber placement process obtained from experimental tests.Finally,the comparison of numerical simulation results was conducted for the optimized trajectories and the conventional straight trajectories under various boundary conditions,and the numerical results were partially validated through damping and frequency tests.The results indicate the vibration characteristics of the composite vertical stabilizer skin structure can be enhanced to a large extent by optimizing fiber trajectories,and the enhancement percentage is affected by the boundary conditions of the actual structure.
文摘The ZrO2-Al2O3 ceramic composites were prepared by appropriate techniques with commercial ZrO2 and Al2O3 powders as raw materials and Y2O3 as stabilizer. The results indicate that with the introduction of Al2O3 into the ZrO2 matrix where the quantity of additive Y2O3 is 3.5% (mole fraction), the growth of ZrO2 grains is efficiently inhibited, which helps the ZrO2 grains exist in a metastable tetragonal manner; thus higher strength and toughness are acquired. When the content of alumina is 20% (mass fraction), the bending strength and fracture toughness of the composites are 676.7 MPa and 10 MPa·m1/2 respectively, the mechanical behaviors are close to those prepared with ZrO2 and Al2O3 powders synthesized through wet chemical approach. The mechanical behaviors of the composites are well improved owing to the dispersion toughening of alumina grains and phase transformation toughening of zirconia grains.
文摘Power system stability is enhanced through a novel stabilizer developed around an adaptive fuzzy sliding mode approach which applies the Nussbaum gain to a nonlinear model of a single-machine infinite-bus （SMIB） and multi-machine power system stabilizer subjected to a three phase fault. The Nussbaum gain is used to avoid the positive sign constraint and the problem of controllability of the system. A comparative simulation study is presented to evaluate the achieved performance.
基金supported by the China Scholarship Council(No.201908505143)the Chongqing Research Program of Basic Research and Frontier Technology(No.cstc2017jcyj AX0290/No.cstc2018jcyj AX0563)。
文摘Knowing methane desorption characteristics is essential to define the contribution of adsorbed gas to gas well production.To evaluate the synthetic effect of a clay stabilizer solution on methane desorption kinetics and isotherms pertaining to Longmaxi shale,an experimental setup was designed based on the volumetric method.The objective was to conduct experiments on methane adsorption and desorption kinetics and isotherms before and after clay stabilizer treatments.The experimental data were a good fit for both the intraparticle diffusion model and the Freundlich isotherm model.We analyzed the effect of the clay stabilizer on desorption kinetics and isotherms.Results show that clay stabilizer can obviously improve the diffusion rate constant and reduce the methane adsorption amount.Moreover,we analyzed the desorption efficiency before and after treatment as well as the adsorbed methane content.The results show that a higher desorption efficiency after treatment can be observed when the pressure is higher than 6.84 MPa.Meanwhile,the adsorbed methane content before and after treatment all increase when the pressure decreases,and clay stabilizer can obviously promote the adsorbed methane to free gas when the pressure is lower than 19 MPa.This can also be applied to the optimization formulation of slickwater and the design of gas well production.
